TW201009148A - Fabric and textile products - Google Patents

Abstract

Provided are: a fabric having breathability which decreases upon absorption of moisture, and which is made using fibers having a crimp percentage which increases upon absorption of moisture; and textile products made therefrom. This fabric is characterized by the inclusion of crimped fibers (A) wherein the crimp percentage upon moisture absorption (HC%) and the crimp percentage when dry (DC%) have a difference (HC-DC) of 0.5% or more. 'When dry' refers to the condition after leaving a sample for 24 hours in an environment with a temperature of 20 DEG C and relative humidity of 65%, and 'upon moisture absorption' refers to the condition after leaving a sample for 24 hours in an environment with a temperature of 20 DEG C and relative humidity of 90%.

Description

201009148 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a fabric in which the gas permeability of the fabric is reversibly reduced when moisture is absorbed, and a fiber product comprising the fabric. [Prior Art] A fabric which reversibly changes the gas permeability due to a reversible change in the void ratio of the cloth during moisture absorption and drying is also called a moisture-sensitive fabric, and various proposals have been made in recent years. For example, as a fabric having a reduced gas permeability at the time of moisture absorption, a fabric in which a conjugate fiber in which a polyester component and a polyamide component are joined in parallel is used and a crimp ratio is lowered (the length of the appearance becomes long) is absorbed. (See, for example, Japanese Laid-Open Patent Publication No. Hei. No. 2006- 1 8062), or a water-absorbable self-extending yarn (see, for example, JP-A-2005-060918). According to such a cloth having a reduced gas permeability at the time of moisture absorption, when the cloth is used as a clothes, the air permeability of the clothes can be lowered by rain or snow on the clothes, thereby improving warmth and water leakage resistance. effect. The applicant of the present application, in Japanese Patent Application No. 2007-1 83224, proposes a crimped fiber with an increased shrinkage rate. However, in the past, in shirts, shirts, swimwear, and the like which are directly worn on the skin, it is desirable not to see the skin or the underwear transparently. However, when wearing white clothes, there is a problem that it is liable to become transparent when the skin is sweaty and the clothes are wet due to rain. In contrast, there have been many proposals in recent years. For example, JP-A-2007-3 9 846 proposes a method of improving the transparency prevention by reducing the gap between the fibers 201009148 by using a flat-section fiber. In Japanese Laid-Open Patent Publication No. 2005-32548, it is proposed to knead a large amount of fine particles (titanium oxide) in a core of a sheath-core type conjugate fiber to gel the fiber to improve the transparency. Further, Japanese Laid-Open Patent Publication No. 2007-63714 discloses a method of improving the anti-transparency by increasing the specific surface area of the fiber _ by a high-filament fiber having a single-filament fineness of 1.1 dtex or less and increasing the random reflection of light. Although it has a certain effect on the anti-transparency, the disordered reflection of air such as when it is wet is lowered, and there is a problem that the transparency is extremely lowered, and further improvement is desired. Further, Japanese Laid-Open Patent Publication No. Hei. No. 2006-1 1 2009 discloses an invention in which a crimped fiber having a reduced coefficient of shrinkage (longer appearance length) during moisture absorption using the opposite performance to the crimped fiber used in the present invention is described. In the Japanese Patent Publication No. 2007-183224, the present inventors propose a crimped fiber having an increased crimp ratio at the time of moisture absorption. Furthermore, in the past, a woven fabric composed of synthetic fibers or natural fibers has been used for a wide range of applications (see, for example, JP-A-2004-1 37659). The wool fabric is widely used as a clothing material because of its excellent warmth retention. It is used for clothing, clothing, shirts, underwear, etc., such as outerwear, woolen clothes, or sportswear. Bedding, chair or sofa surface materials, carpets, car seat pajamas, or household items have also been widely used. Furthermore, the upright fabric has been widely used in sportswear such as sportswear or woven sweatshirts, diapers or sheets for care, and the like. However, these upright fabrics are usually fixed even if the humidity or moisture changes, and therefore do not have the self-regulating function of feeling the humidity or moisture like animal hair -6-201009148 and changing the length of the hair. On the other hand, a fabric which reversibly changes the porosity of the fabric during moisture absorption and drying and which reversibly changes the gas permeability is also called a moisture-sensitive fabric, and has been proposed in recent years. For example, as a fabric having a reduced gas permeability during moisture absorption, it is proposed to use a composite fiber in which a polyester component and a polyamide component are joined into a side-by-side type, and the crimp ratio is lowered (the length of the appearance becomes long) when the moisture is absorbed. A cloth (for example, JP-A-2006-1 18062) or a water-absorbable self-extending yarn φ (for example, refer to Japanese Laid-Open Patent Publication No. 2005-06 0918). According to the cloth having reduced air permeability during the moisture absorption, when the clothes using the cloth are worn, when the rain or the snow falls on the clothes, the air permeability of the clothes is lowered to improve the warmth retention, and the leakage resistance is improved. effect. In the Japanese Patent Publication No. 2007-1 83224, the present inventors propose a crimped fiber having an increased crimp ratio at the time of moisture absorption. In addition, there has been a proposal for a fabric having a three-layer structure in which the surface of the woven fabric has a three-layer structure. For example, see JP-A-2002-23 5264, JP-A-10-1854 Japanese Patent Laid-Open No. 5-148746). This three-layer fabric is widely used as a cushioning material or a warm clothing because of its cushioning property (elastic strength) or warmth retention. Among them, the bottom structure of the bottom and bottom of the structure is connected by a three-layer structure of the fabric. 'Because the fiber density of the joint is low, the air permeability is high, and it has been widely used for outdoor sports shoes or backpack materials (canvas backpacks) that are easy to sweat. )Wait. In recent years, it has been used as a surface material for a chair or a sofa, and a car seat material because of the low heat sensation. However, in the three-layer construction, even if the humidity or moisture is changed, the thickness is usually fixed, and the cushioning and warmth are not changed. On the other hand, a fabric which reversibly changes the air permeability by reversibly changing the void ratio of the fabric during moisture absorption and drying is also called a moisture-sensitive fabric, and has been proposed in recent years. For example, as a fabric having a reduced gas permeability at the time of moisture absorption, it is proposed to use a composite fiber in which a polyester component and a polyamide component are joined to form a side-by-side type, and when the moisture absorption is reduced, the crimp ratio is lowered (the length of the appearance becomes long). For example, refer to Japanese Laid-Open Patent Publication No. 2006-1 1 8062, or a water-absorbable self-extending yarn (for example, refer to Japanese Laid-Open Patent Publication No. 2005-060918). According to the cloth having reduced air permeability during the moisture absorption, when the clothes using the cloth are worn, when the rain or the snow falls on the clothes, the air permeability of the clothes is lowered to improve the warmth retention, and the leakage resistance is improved. effect. In the Japanese Patent Publication No. 2007-1 83224, the present inventors propose a crimped fiber having an increased crimp ratio at the time of moisture absorption.

In addition, in the case of a fabric composed of a synthetic fiber or a natural fiber, if it is used as a sportswear or a shirt, it may cause a heat sensation due to sweating from the skin. As a method G for digesting the heat sensation of sweating, it is proposed to effectively release the moisture retained in the clothes by increasing the breathability of the cloth during sweating, and if the sweat is stopped, By reducing the air permeability of the fabric and suppressing the coldness caused by the excessive undulation of the water, the fabric can be self-adjusting and ventilating, and the fabric can be self-adjusting and ventilating (see, for example, Japanese Laid-Open Patent Publication No. 2003-41462, JP-A No. 10-77544, JP-A-2002-1 80323). Although these roots can suppress the heat sensation during sweating by improving the air permeability, the cause of the heat sensation is not only the sultry heat in the clothes (the humidity rises), but also the heat of the body due to the heat generated by the body. Therefore, in addition to improving the gas permeability, it is also an effective means to reduce the warmth (to make the thickness of the cloth thin). Furthermore, in the case where two pieces of clothes are worn in an overlapping manner, it is difficult to improve the air permeability, so that the thickness of the cloth is made thinner as a more effective means. However, such a self-adjusting thickness of cloth has not been proposed so far. Further, Japanese Laid-Open Patent Publication No. 2006-119, discloses an invention of a crimped fiber having a reduced shrinkage ratio (longer appearance length) during moisture absorption in contrast to the crimped fiber used in the present invention. In the Japanese Patent Publication No. 2007-183224, the present inventors propose a crimped fiber having an increased crimp ratio at the time of moisture absorption. Furthermore, in recent years, due to the high awareness of personal beauty and health, easy exercise such as jogging or walking or muscle training, or a healthy series of sports represented by swimming or aerobics or yoga is prevailing. The clothes for these sports are required to be close to the body for easy movement, support for body activities, sweat absorption and quick drying. As a material, a polyester or nylon having excellent sweat absorption and quick-drying properties and a polyurethane-like elastic yarn for supporting a snug or supportability are used as a material (see, for example, JP-A-63). Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. In addition, it is also proposed to have a special sewing pattern of the fabrics, thereby improving the clothes that are more suitable for the fit or the movement support function (refer to Japanese Laid-Open Patent Publication No. 2005-290625, No. 20 04-131903, JP-A-2004-- 3 3 9623). However, these systems use the flexibility of various polyurethane fibers to match the body's 'making a good fit to the body' and making clothes smaller than the size of the wearer's body. difficult. Further, Japanese Laid-Open Patent Publication No. Hei. No. 2006-1 1 2009 discloses an invention of a crimped fiber having a reduced shrinkage ratio (longer appearance length) during moisture absorption using the opposite performance to the crimped fiber used in the present invention. In the Japanese Patent Publication No. 2007-183224, the present inventors propose a crimped fiber having an increased crimp ratio at the time of moisture absorption. SUMMARY OF THE INVENTION [Problems to be Solved by the Invention] The present invention has been made in view of the above circumstances, and the first object of the present invention provides an improvement in the crimp ratio when the moisture absorption is used (the appearance length is shortened). A fiber which has a reduced fiber permeability when moisture is absorbed and a fiber product formed using the cloth. Further, a second object of the present invention is to provide a fabric which is improved in transparency by thickening a portion of the fabric when moisture is absorbed, and a fiber product comprising the fabric.

Further, a third object of the present invention is to provide a rag fabric which is a rag fabric having a crimped fiber in a standing portion, and which has a reversible increase in the curling ratio of the squeezing fiber due to moisture absorption. As a result, the thickness of the cloth is reduced, the warmth of the fabric is lowered, the heat sensation during sweating can be reduced, and the fiber product composed of the woven fabric can be provided. A fourth object of the present invention is to provide a three-layer structure fabric which is a three-layer structure fabric composed of a bottom portion of a bottom and a bottom portion of a bottom portion of a base portion of the front and back sides. The crimping fiber which reversibly increases the crimping ratio reduces the thickness of the fabric, and as a result, the warmth of the fabric is lowered, the heat sensation during sweating is reduced, and the fiber product using the fabric -10- 201009148 is provided. Further, a fifth object of the present invention is to provide a fabric comprising a crimped fiber having an increased crimp ratio at the time of moisture absorption, and a crimped fiber having no change in the crimp ratio at the time of unrolling or moisture absorption. The fabric is reduced in thickness when it absorbs moisture - as a result, the warmth of the fabric is lowered, so that the heat of the sweat can be reduced, and the fiber product using the fabric can be provided. Further, a sixth object of the present invention is to provide a fabric which improves the fit of sweat when the ruler φ is reduced by moisture absorption, and a fiber product comprising the fabric. [Means for Solving the Problem] The inventors of the present invention have actively reviewed the results of the above-mentioned first object, and found that in the composite fiber in which the polyester component and the polyamide component are joined into a side-by-side type, When the polyester component formed of the polymerized polyester is used, it is possible to obtain a fiber in which the crimp ratio at the time of moisture absorption is increased (the appearance length is shortened), and the gas permeability at the time of moisture absorption is reduced when the composite fiber is woven into the fabric. The fabric 'and thus repeats the active review to complete the present invention. In other words, • According to the present invention, the following 1 to 19 are provided as means for achieving the above first object. A fabric characterized by comprising a crimped fiber A having a difference in crimp ratio HC (%) during moisture absorption and a crimp ratio DC (%) during drying (HC-DC) of 0.5% or more; wherein In the case of drying, the sample is placed in a state of temperature 20 ° C and humidity 65% RH for 24 hours. On the other hand, when the moisture absorption is -11 - 201009148, the sample is placed at a temperature of 20 ° C and humidity. The state after 24 hours in an environment of 90% RH. 2. The fabric according to the above item 1, wherein the crimped fiber A is a composite fiber obtained by joining two components having different moisture absorption rates into a side-by-side type. __ 3. The fabric according to the above item 2, wherein the component having a low moisture absorption rate is a polyester component, and on the other hand, the component having a higher moisture absorption rate is a polyamide component. 4. The fabric of item 3 above, wherein the polyester component comprises 60 to 99.5 mol% of the ethylene terephthalate unit in the repeating unit constituting the polyester, and the ethylene isophthalate unit It is composed of a copolymerized polyester of 0.5 to 40 mol%, and the polyester component contains 5 to 55 wt% of a polyether ester decylamine relative to the weight of the polyester. 5. The fabric according to the above item 1, wherein the fabric contains the crimped fibers B as non-coiled or moisture-absorbing, and the crimped fibers B are used as the other fibers. The fabric of the above item 5, wherein the fiber b is a poly-ester fiber. The fabric according to the above item 5, wherein the fiber b is a multifilament having a single yarn fineness of ldtex or less and a number of filaments of 30 or more. 8. The fabric of item 5, wherein the fabric is a woven fabric or a knitted fabric, and the crimped fiber A is aligned with the fiber b. 9. The fabric of item 5, wherein the fabric is a woven fabric or a knitted fabric, and the crimped fiber A and the fiber B are alternately disposed as a constituent yarn of the cloth -12-201009148.

10. The fabric of item 5, wherein the fabric is a woven fabric or a woven fabric, and the fabric comprises a core-sheath type composite yarn in which the crimped fiber A is located at a core portion and the fiber B is at a sheath portion. The fabric of the above-mentioned item 1, wherein the fabric is a multi-layer fabric having a multilayer structure of two or more layers, and at least 30% by weight of the total fiber weight constituting the layer in at least one layer is the above Coiled fiber a. Lu 12. The fabric of item 1 above, wherein the fabric is a fabric having a coverage factor CF (when dry) defined in the range of 2000 to 4500, CF=(DWp/ll) 1/2xMWp+ (DWf/1.1 ) 1/2xMWf where DWp is the warp total denier (dtex), MWp is the warp weave density (bar / 2.54cm) ' DWf is the weft total denier (dtex) > M Wf φ is the weft weave density (bar) /2.54cm ). 13. The fabric as described in the above item 1 wherein the fabric is 4 〇 longitudinally arranged, the number of stitches (wale) /2_54 cm or more, and the number of stitches of 50 courses (c〇urse) / 2.54 cm or more. 14. The fabric of item 1 above, wherein the fabric is subjected to a heat and pressure process. The fabric of the above item 1, wherein the fabric is subjected to water repellent processing. 16. The fabric according to item 1 above, wherein the fabric during drying has a gas permeability of -10 to 201009148 of 50 cc/cm2/s or less. 17. The fabric according to item 1 above, wherein the rate of decrease in the gas permeability of the fabric at the time of moisture absorption is defined by the following formula: 10% or more:

Gas permeability reduction rate (%) = (APD-APH) / APDxlOO where 'APD is the gas permeability (cc/em2/s) of the fabric when dry, and ΑΡΗ is the gas permeability (cc/cm2/s) of the fabric when moisture is absorbed. 18. The fabric of item 1, wherein the fabric has a water leakage of 2000 cc or less. Among them, the water leakage was measured by using a Bundesmann rain test apparatus of JIS L 1092, 6.3 (rain test A method), and the amount of water leakage set in a total water amount of 7 liters/min in 10 minutes was measured. 19. A fibrous product obtained by using the fabric of any one of the above 1 to 18 and selected from the group consisting of a garment for outerwear, a garment for sportswear, and a garment for lining. According to the present invention, the fiber having a reduced crimp ratio (decreased appearance length) at the time of moisture absorption can be used to obtain a fabric having reduced gas permeability during moisture absorption and a fiber product comprising the fabric. In addition, the result of the positive review by the inventors of the present invention for the purpose of achieving the above-mentioned second object is that the crimped fiber having an improved crimp ratio at the time of moisture absorption is found to have substantially no change in the crimp ratio at the time of non-crimping or moisture absorption. When the crimped fiber constitutes a fabric, the thickness of the fabric is partially thickened to improve the transparency, and the results of the positive review are repeated, and the present invention has been completed. That is, -14-201009148 provides the following 20 to 28 as a means for achieving the above second object in accordance with the present invention. * 2〇 · The fabric of item 5 above, wherein the thickness from the drying of the fabric. (TD) and the thickness at the time of moisture absorption (TW) are calculated by the following formula: the rate of change is 5% or more: thickness change rate ( %) =( (TW-TD) /TD) χΙΟΟ Among them, the thickness of the so-called drying is the thickness of the cloth in the state of the fabric at a temperature of 20 ° C and a humidity of 65% RH for 24 hours. The thickness at the time of moisture absorption is the thickness of the cloth in a state where the cloth is placed in a temperature of 20 ° C and a humidity of 90% RH for 24 hours. The cloth according to the above item 20, wherein the cloth has a portion (Y portion) composed only of the crimped fibers A and a portion (Z portion) composed only of the fibers B, and the Y portion is formed Continuously connected by direction and / or latitude. The cloth according to the above item 20, wherein the cloth has a portion (Z portion) composed only of the fiber B and a portion (X portion) composed of the crimped fiber A and the fiber B, and the above The X portion is continuously connected in the warp direction and/or the weft direction. The cloth according to the above item 20, wherein the cloth has a portion (X portion) composed of the crimped fiber A and the fiber B, and a portion (Y portion) composed only of the crimped fiber A and The above-mentioned Y portions in the cloth are continuously connected in the warp direction and/or the weft direction. The cloth of the above-mentioned item 20, wherein the cloth has a portion (X portion) composed of the above-mentioned crimped fiber A and the above-mentioned fiber B, and a portion composed only of the above-mentioned crimped fiber A (Y portion) And a portion (Z portion) composed only of the above-mentioned fibers - B, and the above-mentioned Y portions are continuously connected in the warp direction _ and/or the weft direction. The cloth according to the above item 20, wherein the cloth is a multi-layered fabric composed of two or more layers, and has a layer composed of the crimped fibers A and B, and a layer composed only of the fibers B. And the layer of the former is connected to the layer of the latter. 26. The fabric according to the above item 20, wherein the fabric is a multi-layered fabric composed of two or more layers, and has a layer composed of the crimped fibers A and fibers B, and a layer composed only of the crimped fibers A. And the layer of the former is connected to the layer of the latter. 27. The fabric according to the above item 20, wherein the fabric is a multilayer fabric composed of two or more layers, and has a layer composed only of the crimped fibers A and a layer composed only of the fibers B, and the layer of the former Connected to the layer of the latter. A fibrous product, which is obtained by using the fabric according to any one of the items 19 to 26, and is selected from the group consisting of a garment for outerwear, a garment for sportswear, and a garment for lining. According to the present invention as described above, it is possible to obtain a fabric which is improved in transparency by thickening the thickness of the cloth when moisture is absorbed, and a fiber product obtained by using the cloth. In addition, the inventors of the present invention have actively reviewed the results of the above-mentioned third objective - 16-201009148, and found that the upright hairs and the bottom tissues are formed, and the curl ratio is caused by moisture absorption on the hair portions. The increased crimping fiber (longer appearance and shorter length) can obtain the desired rag fabric and fiber product, and is repeated. The positive review thus completes the present invention. That is, according to the present invention, the following - 2 9-3 3 is provided as a means for achieving the above third object. 2 9 · The fabric of item 1 above, which is cut by cut (cut

The pile portion and the bottom pile portion φ constitute a pile fabric, and the pile portion includes the crimped fiber A. The fabric according to the above item 29, wherein the bottom fabric portion is made of polyester fiber. 31. The fabric of item 29, wherein the fabric is subjected to a water absorbing process. The fabric according to the above item 29, wherein the thickness change rate (TD) from the drying of the cloth and the thickness (TW) at the time of moisture absorption are 5% or more calculated by the following formula: thickness change rate (%) = ( ( TD-TW ) /TD ) X 1 〇〇 Among them, the thickness of the so-called drying is the thickness of the cloth in the state of temperature 2 (rc, humidity 65% RH environment for 24 hours, and other aspects) The thickness in the case of moisture absorption is to place the fabric at a temperature of 20. (:, the thickness of the cloth in a state of humidity of 90% RH for 24 hours. 33. - a kind of fiber product, which uses the above items 29 to 32) Any of the fabrics' is selected from the group consisting of clothing, woolen sanitary ware, sweaters, -17- 201009148 garments for outerwear, sportswear, linings, diapers and sheets for care, and other necessities. a group of surface materials such as bedding, a chair or a sofa, a carpet, a car seat material, and an indoor product. $« The above invention 'reversibly increases the curling rate of the above-mentioned crimped fiber by moisture absorption to make the height of the standing hair Smaller, the result is reduced by the thickness of the cloth - In order to reduce the warmth of the fabric, it is possible to reduce the heat sensation when sweating. The raging fabric and the fiber product using the woven fabric. The result of the positive review by the inventors for achieving the above fourth objective The three-layer structure fabric composed of the joint portion between the bottom portion of the surface and the bottom portion of the joint portion in the joint portion is formed by the crimping fiber (the length of the appearance is shortened) in which the crimping ratio is increased during moisture absorption in the joint portion. The present invention has been completed by obtaining a desired three-layer structure fabric and a fiber product, and repeating the positive review. That is, according to the present invention, the following 34 to 38 are provided as means for achieving the above fourth object. 3 4. As described above The fabric according to the item is a three-layer structure fabric composed of a joint portion between the surface of the watch and the bottom portion and a bottom portion of the joint portion, and the crimping fiber A is included in the joint portion. The cloth according to the above aspect, wherein the bottom structure portion is made of a polyester fiber. 36. The cloth according to item 34 above, wherein the cloth is subjected to water absorbing processing. 37. The fabric described in item 34 has a thickness change rate of 5% or more calculated from the thickness (TD) when the cloth is dried and the thickness (TW) at the time of moisture absorption: • 18 - 201009148 Thickness change rate (%) =( (TD-TW) /TD) χΙΟΟ - where 'the thickness of the so-called dryness is to place the fabric at a temperature of 2 (TC, wet-degree 65% RH environment, the thickness of the cloth after 24 hours, another side • The thickness of the surface of the stomach is set to a temperature of 20. (:, the thickness of the cloth in a state of humidity of 90% RH for 24 hours. Lu 38. - Fiber products, which are used The fabric according to any one of the items 34 to 37, which is selected from the group consisting of a clothing material, a wool sanitary garment, a sweater, a garment for outerwear, a sports garment, a garment for lining, a diaper, and a care sheet, etc. A group of materials such as supplies, pajama bedding, chairs or sofas, carpets, car seat materials, and interior products. According to the present invention, the three-layer structure fabric composed of the bottom portion of the surface portion and the bottom portion of the bottom portion of the surface of the surface is retractably increased by the crimping rate in the joint portion during moisture absorption. The thickness of the cloth is made smaller by 0 degree. As a result, it is possible to obtain a three-layer structure fabric in which the heat retention of the fabric is lowered, and the heat is reduced during sweating, and a fiber product using the fabric. Further, the inventors of the present invention have actively reviewed the results of the above-mentioned fifth object, and found that the crimping rate of the crimped fiber having an increased crimp ratio during moisture absorption and the unwinding or moisture absorption in the cloth is substantially absent. The change of the fiber having the crimping can obtain a fabric having a reduced thickness at the time of moisture absorption, and the positive review is repeated to complete the present invention. That is, the following 3 9 to 4 4 are provided as means for achieving the above fifth object in accordance with the present invention. -19- 201009148 39. The fabric according to the above item 5, wherein the thickness change (TD) from the drying of the cloth and the thickness (TW) at the time of moisture absorption are calculated by the following formula: the thickness change rate is 5% or more: thickness variation Rate (%) = ((TD-TW) / TD ) χΙΟΟ where the thickness of the so-called dryness is the thickness of the cloth in a state where the cloth is placed in a temperature of 20 ° C and a humidity of 6 5% RH for 24 hours, and On the one hand, the thickness at the time of moisture absorption is the thickness of the cloth in a state where the cloth is placed in a temperature of 20 ° C and a humidity of 90% RH for 24 hours. The fabric according to the above item 39, wherein the fiber B is a fiber obtained by thermally shrinking a polyester fiber having a boiling water shrinkage ratio of 20% or more. The cloth according to the above item 39, wherein the cloth has a portion (Y portion) containing the crimped fiber A and a portion (Z portion) composed only of the fiber B, and the Y portion is formed in the warp direction. And/or the weft direction is continuously connected. The cloth according to the above item 39, wherein the cloth has a portion (Y portion) containing the crimped fiber A and a portion (Z portion) composed only of the fiber B, and the Y portion and the Z portion are in the cloth. The fabric of the above-mentioned item 39, wherein the fabric is a fabric composed of two layers, wherein the first layer contains the above-mentioned rolls, respectively, in a width of 5 mm or more. The fiber A is condensed, and the second layer is composed only of the fibers B, and the first layer is joined to the second layer portion. 201009148 44. A fiber product comprising the fabric of any of the above-mentioned items 39 to 43 and selected from the group consisting of a garment for outerwear, a garment for sportswear, and a fabric for lining. According to the present invention as described above, the crimped fiber having an increased crimp ratio at the time of moisture absorption and the crimped fiber having no change in the unfolded or moisture-absorbing crimping property, the thickness due to moisture absorption As a result of the reduction, the fabric warming property is lowered. Therefore, it is possible to obtain a fabric which reduces the heat sensation when sweating, and a fiber product which is composed of the cloth φ material. Further, as a result of a positive review by the present inventors for achieving the above-described sixth object, it has been found that the crimped fibers having an improved crimp ratio at the time of moisture absorption and the crimp ratio at the time of unrolling or moisture absorption are substantially unchanged. When the crimped elastic fiber constitutes a cloth, the size of the cloth is reduced by moisture absorption, and the positive review is repeated to complete the present invention. That is, in accordance with the present invention, the following 45 to 57 are provided as means for achieving the above sixth object. The cloth according to the above item 5, wherein the area change rate of the φ area (SD) and the area (SW) when the cloth is dried is 1% or more: area change rate (%) ) = ( (SD-SW) /SD) χΙΟΟ Among them, the area when drying is the cloth area in a state where the cloth is placed in a temperature of 20 ° C and a humidity of 65% RH for 24 hours. On the other hand, the so-called cloth area The area at the time of moisture absorption is the cloth area in a state where the cloth is placed in a temperature of 20 ° C and a humidity of 90% RH for 24 hours. The fabric according to the above item 45, wherein the fiber B is a polyurethane elastic fiber or a polyether ester elastic fiber. The fabric according to the above item 46, which comprises the non-elastic fiber C having the crimping rate which is not changed when the film is not crimped or moisture-absorbed, and is used as the other fiber. 48. The fabric of item 47, wherein the fiber C is a polyester fiber. The cloth according to the above item 47, wherein the cloth has a portion (Y portion) composed of the crimped fiber A and the fiber B, and a portion (Z portion) composed of the inelastic fiber C and the fiber B. And the Y portion is continuously connected in the warp direction and/or the weft direction. The fabric according to the above item 47, wherein the cloth has a portion (Z portion) composed of the inelastic fiber C and the elastic fiber B, and the crimped fiber A and the inelastic fiber C and the elastic The portion (X portion) of the fiber B is formed, and the X portion is continuously connected in the warp direction and/or the weft direction. The fabric according to the above item 47, wherein the cloth has a portion (X portion) composed of the crimped fiber A and the non-elastic fiber C and the elastic fiber b, and the crimped fiber A and the elastic The portion (Y portion) of the fiber B, and the γ portion of the cloth is continuous in the warp direction and/or the weft direction. The cloth of the above-mentioned item 47, wherein the cloth has a portion (X portion) composed of the crimped fiber A and the fiber C and the elastic fiber B, and the crimped fiber A and the elastic fiber b A part (Y part) 'and a part (Ζ part) composed of the above-mentioned inelastic fiber c and the above-mentioned elastic fiber '' and the above-mentioned Υ part is continuous in the warp direction and/or the weft direction. The fabric according to the above item 45, wherein the fabric is a two-layer fabric, one of which is composed only of the crimped fiber bundle, and the other layer is composed only of the fiber B. The fabric of the above-mentioned item 47, wherein the fabric is a multi-layered fabric composed of three or more layers, and has a layer composed of the crimped fiber A and the non-elastic fiber C, and only the non-elastic fiber. The layer formed by C and the layer composed of fiber B. The fabric according to the above item 47, wherein the fabric is a multi-layered fabric composed of three or more layers, and has a layer composed of the crimped fiber A and the inelastic fiber C, and only the crimped fiber. A layer composed of A and a layer composed only of the above elastic fibers B. The fabric according to the above item 47, wherein the fabric is a multi-layer fabric composed of three or more layers, and has a layer composed only of the crimped fibers A and a layer composed only of the inelastic fibers C. And a layer composed only of the above elastic fibers B. A fabric comprising the fabric of any one of the above-mentioned items 45 to 56, and is selected from the group consisting of a garment for outerwear, a sportswear, and a garment for lining. According to the present invention as described above, it is possible to obtain a fabric which is improved in body shape upon sweating when the moisture absorption is small, and a fiber product obtained by using the fabric. These fiber products have an effect of being easy to put on and take off, and being close to the body during exercise and exercise -23-201009148. [Embodiment] _ Hereinafter, embodiments of the present invention related to the above 1 to 19 will be described in detail. _ The fabric of the present invention has a crimped fiber A containing 0.5% or more of the difference (HC-DC) between the crimp ratio HC (%) at the time of moisture absorption and the crimp ratio DC (%) at the time of drying. The crimping ratio of the crimped fiber A at the time of moisture absorption is increased, @ and only the length of the crimped fiber A is shortened. As a result, since the area of the entire cloth becomes small at the time of moisture absorption, the void ratio of the cloth is lowered to lower the air permeability of the cloth. On the other hand, only the length of the crimped fibers A is increased by reducing the crimp ratio of the crimped fibers A during drying. As a result, the overall area of the cloth becomes larger during drying, and the void ratio of the cloth is increased to improve the gas permeability of the cloth. In the case of drying, the sample is placed in a state of a temperature of 20 ° C and a humidity of 65% RH for 24 hours. On the other hand, when the moisture is absorbed, the sample is placed at a temperature of 20 ° C and a humidity of 90%. The state of 24 hours after the RH environment. Wherein, when the difference between the crimping ratio HC of the crimped fiber A and the crimping ratio DC of the crimped fiber A during drying (HC-DC) is less than 0.5%, the moisture permeability of the fabric when moisture is absorbed Not lowering is not good. Further, the crimping ratio DC of the crimped fiber A during drying is preferably in the range of 50 to 80%. On the other hand, the crimping rate HC of the crimped fiber A during moisture absorption is preferably in the range of 60 to 90%. The crimped fiber A is preferably a composite fiber in which two components -24 to 201009148 having different moisture absorption rates are joined together into a side-by-side type. Further, the component having a low moisture absorption rate is preferably a polyester component, and the component of the moisture absorption rate cartridge is a polyamine component. Specifically, it is a composite fiber obtained by joining a polyester component and a polyamide component as follows, and is preferably a crimped fiber having a crimping structure exhibiting a potential crimping property. That is, the above polyamine component is a polymer having a guanamine bond in the main chain, and examples thereof include, for example, nylon 4, nylon 6, nylon 12, nylon 46, and nylon 66. In particular, nylon 6 and nylon 66 are preferable from the viewpoints of cost, versatility, and yarn-making properties. Further, the polyamine component may be copolymerized with a component known as a base, or the polyamide component may contain a pigment such as titanium oxide or carbonium, a conventional antioxidant, an antistatic agent, or light resistant. Agents, etc. On the other hand, the above polyester component preferably accounts for 60-99.5 mol% of the ethylene terephthalate unit in the repeating unit constituting the polyester, and the ethylene isophthalate unit occupies 0.5 to 40 mol. % of the copolymerized polyester of the ear. Generally, the heat shrinkage of the polyester is lower than that of the polyamine, but the heat shrinkage of the polyester is brought close to the polyamine by using the copolymerized polyester as the polyester. As a result, in the crimping and bending structure at the time of drying, in the crimping and bending structure at the time of moisture absorption, it is easy to form a swelled polyamidamide component on the outer side and a polyester component on the inner side, and it is easy to increase the crimp ratio. Among them, when the unit of ethylene terephthalate is less than 60 mol%, the basic physical properties such as the strong elongation of the obtained composite fiber cannot be sufficiently maintained. When the ethylene terephthalate unit exceeds 99.5 mol% and the isophthalic acid ethylene diester does not reach 0.5 mol%, the crimping rate is not increased when the composite fiber absorbs moisture (the appearance of the crimped yarn) The length is not shortened. When it is used as a cloth, there is a problem that sufficient low gas permeability cannot be obtained. -25- 201009148 When ethylene phthalate exceeds 40 mol%, basic properties such as strong elongation of composite fibers cannot be maintained, thermal stability is also deteriorated, and spinning is caused by decomposing foreign matter in the spinning step. The filtration pressure (· filling pressure) of the nozzle portion of the wire mouth is significantly increased. _ These polyesters can be manufactured by any method. For example, for example, polyethylene terephthalate-ethylene formate is directly esterified with terephthalic acid and ethylene glycol. Direct esterification of dimethyl terephthalate lower alkyl ester with ethylene glycol, or reaction of terephthalic acid with ethylene oxide, @ produces terephthalic acid glycol esters and / or its oligomerization Things. The product is then heated under reduced pressure and polycondensed to a desired degree of polymerization to form a bismuth phthalate component and ethylene phthalate component. In addition, a third component may be copolymerized, and the third component is preferably any of a dicarboxylic acid component or a diol component. As the dicarboxylic acid component, for example, phthalic acid, dibromoterephthalic acid, naphthalene dicarboxylic acid, diphenyldicarboxylic acid, diphenoxyethane dicarboxylic acid, such as hydroxydecyl ethoxylate can be exemplified. A difunctional aromatic dicarboxylic acid of benzoic acid, such as a difunctional aliphatic dicarboxylic acid such as azelaic acid, adipic acid or oxalic acid, or 1,4-cyclohexanedicarboxylic acid. Further, a part of the above diol component may be substituted with other diol components, such as cyclohexane-1,4-dimethanol, neopentyl glycol, bisphenol A, bisphenol S, 2, for example. 2-bis(4-indole-hydroxyethoxyphenyl)propane, bis(4-β-hydroxyethoxyphenyl)anthracene, 2,2-bis(3,5-dibromo-4-(2-) An aliphatic, alicyclic or aromatic diol of hydroxyethoxy)phenyl)propane. Further, in the above polyester, a small amount of the other polymerized -26-201009148 may be blended as needed, and a chain branching agent such as pentaerythritol, trimethylolpropane or trimellitic acid may be used in a small amount. In addition, the polyester of the present invention may of course be added with a pigment such as titanium oxide or carbon black, a conventional antioxidant, and an anti-coloring agent in the same manner as the general polyester. The polyester component preferably contains a polyether ester decylamine. When the polyether ester decylamine is contained in the polyester component, the polyester component becomes soft, and when the polyamine component swells during moisture absorption, the polyester component is easily followed, and the shrinkage rate during moisture absorption is easily improved. Therefore, it is better. The polyether ester decylamine is preferably added to the polyester component in an amount of 5 to 55% by weight based on the weight of the polyester component. When it is less than 5% by weight, when the composite fiber absorbs moisture, the crimp ratio does not increase (the length of the crimped fiber is difficult to be shortened), and when it is used as a cloth, there is a problem that sufficient gas permeability cannot be obtained. On the other hand, when it exceeds 55% by weight, there is a problem that the spinning cannot be stably performed. The polyether ester decylamine is preferably an ethylene oxide adduct of a bisphenol having a number average molecular weight of 500 to 5,000 having a carboxyl group at both terminals and a bisphenol having a number average molecular weight of 1,600 to 3,000 ( b) derived. "Derivative" means 'the person who reacts the two components, or the one obtained by copolymerization. • The polyamine (a) having a carboxyl group at both ends is preferably composed of a polyamine moiety and a molecular weight modifier. The polyamine moiety is composed of at least one of (1) an indoleamine ring-opening polymer, (2) a polycondensate of an aminocarboxylic acid, or (3) a polycondensate of a dicarboxylic acid and a diamine. Examples of the guanamine in '(1) are butyrolactam, valeroinamide, caprolactam, heptanoin, dodecane decylamine, undecane decylamine and the like. The aminocarboxylic acid of (2) is exemplified by ω-aminohexanoic acid, ω-amino heptanoic acid, ω-aminooctanoic acid, ω-amino decanoic acid -27-201009148, 11-aminoundecanoic acid, 12-aminododecanoic acid and the like. The (3) dicarboxylic acid is exemplified by adipic acid, sebacic acid, sebacic acid, undecanedioic acid, dodecanedioic acid, isophthalic acid and the like. Further, the diamine of (3) is exemplified by tetramethylene diamine, pentamethylenediamine, hexamethylenediamine, heptamethylenediamine, octamethylenediamine, and decamethylene. Amines, etc. The above-mentioned indoleamine, aminocarboxylic acid-, dicarboxylic acid, and diamine are collectively referred to as a polyamidamine moiety-forming monomer. _ The above-mentioned polyamine moiety which is a polyamine (a) having a carboxyl group at both terminals The exemplified ones of the forming monomers may also be used in combination of two or more types. The preferred ones are hexamethyleneamine, 12-aminododecanoic acid and adipic acid-hexamethylenediamine, the most preferred being caprolactam. The polyamine (a) having a carboxyl group at both ends thereof further uses a dicarboxylic acid component having 4 to 20 carbon atoms as a molecular weight modifier, and in the presence of the above, the polyformamide moiety is formed by a conventional method. The monomers are obtained by ring opening polymerization or polycondensation. Examples of the dicarboxylic acid having a carbon number of 4 to 20 are succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedioic acid, or dodecane two. Fatty acid dicarboxylic acid; aromatic dicarboxylic acid such as terephthalic acid, isophthalic acid, phthalic acid or naphthalene dicarboxylic acid; anthracene, 4-cyclohexane hexane dicarboxylic acid, or bicyclic ring An aliphatic dicarboxylic acid such as hexyl-4,4.dicarboxylic acid; or an alkali metal 5-sulfoisophthalate such as sodium 5-sulfoisophthalate or potassium 5-sulfoisophthalate Wait. Among these, preferred are aliphatic dicarboxylic acids, aromatic dicarboxylic acids, and alkali metal salts of 5-sulfoisophthalic acid. More preferably, it is adipic acid, terephthalic acid, or sodium 5-sulfoisophthalate. When the polyamidene moiety forming monomer is subjected to ring-opening polymerization or polycondensation by a conventional method, the average degree of polymerization is preferably from 2 to 10, more preferably the average poly--28-201009148 is from 3 to 8. As a result, the polyamine moiety has a number average molecular weight of from 100 to 1,000', more preferably from 300 to 700. Further, the polyamine (a) having a carboxyl group at both ends thereof is a component which imparts a polyamine moiety to the both ends of the dicarboxylic acid component having 4 to 20 carbon atoms of the molecular weight modifier; The component of the amine moiety may alternatively be a mixture of a component which imparts a polyamine moiety to the terminal end and a component which imparts a polyamine moiety to the single terminal. In the case of a mixture, the component which imparts a polyfluorene amide moiety to the monomolecular terminal at one end, and the component which gives the polyamine moiety at both ends, is preferably 1 to 10 moles. More preferably, the component imparted to the single terminal with respect to 1 mole is provided with a component of 3 to 8 moles at both ends. Therefore, the amount of the carboxyl group-containing component of the above polyamine moiety-forming monomer can be appropriately adjusted so as to have a mercapto group at both ends. If only indoleamine and/or amino decanoic acid is used as the polyamine moiety-forming monomer, since the molecular weight modifier is a dicarboxylic acid component, a polyamine amine having a carboxyl group at both terminals can be easily produced (a) ). When a polycondensate of a dicarboxylic acid and a diamine is used as a polyimide moiety-forming monomer, for example, a polyamine which has a carboxyl group at both terminals can be produced by a method such as a reaction of a polymer which finally changes a dicarboxylic acid (a) ). The number average molecular weight of the polyamine (a) having a carboxyl group at both ends is usually from 500 to 5,000, preferably from 500 to 3,000. When the number average molecular weight is less than 500, the heat resistance of the polyether ester guanamine itself is lowered. On the other hand, when the reactivity exceeds 5,000, the polyether ester guanamine takes a longer time to manufacture. In order to make the number average molecular weight fall within the range, a dicarboxylic acid component having 4 to 20 carbon atoms may be selected as the molecular weight modifier, and the reaction conditions may be appropriately set in the polymerization of the polyamine moiety. -29- 201009148 In addition, in the bisphenol-based ethylene oxide adduct (b), the bisphenols are exemplified by bisphenol A (4,4'-dihydroxydiphenyl-2,2-propane), double Phenol F (4,4'-dihydroxydiphenylmethane), bisphenol s (4,4'-dihydroxydiphenyl maple.) and 4,4'-dihydroxydiphenyl-2,2-butane Wait. The preferred of these is bisphenol A. The above-mentioned double-cooled ethylene oxide adduct (b) is obtained by a method of adding ethylene oxide to the bisphenols. In addition, ethylene oxide and other alkylene oxides (propylene oxide, 12-butylene oxide, 1,4-1,4-butylene or the like) can be used, but the amount of other alkylene oxide used is all The weight of the oxygen hospital is based on 10% by weight or less. Further, the above-mentioned adduct (b) corresponds to two hydroxyl groups of bisphenols, and it is preferred to polymerize ethylene oxide having an average of 20 to 70 mols and other alkylene oxides (hereinafter referred to as ethylene oxide). . More preferably, it is a polymerization of 3 2 to 60 moles of ethylene oxide. That is, the hydroxy polymerization (addition) corresponding to bisphenol has an adduct of 10 to 35 moles, preferably 16 to 30 moles, more preferably 16 to 20 moles of ethylene oxide. . © The above-mentioned adduct (b) has a number average molecular weight of usually ^600^3,000 Å, especially in the case of using an epoxy oxime addition molar number of 32 to 60. If the 'number average molecular weight is less than 1,600, the antistatic property is insufficient. On the other hand, when it exceeds 3,000', the polyether ester guanamine is required to be produced for a long period of time due to a decrease in reactivity. The number average molecular weight is preferably from 1,800 to 2,400, and the addition molar number of the epoxy enamel or the like is preferably from 32 to 40. When the number average molecular weight is within this range, the molecular weight of the bisphenols is considered to be achieved by adjusting the molar number of addition of ethylene oxide or the like. -30- 201009148 The above adduct (b) is used in the range of 20 to 80% by weight based on the total weight of the above (a) and (b) in the polyether ester guanamine. If the amount of the adduct (b) is less than 20% by weight, the antistatic property of the polyetheresteramine is deteriorated, and on the other hand, when it exceeds 80% by weight, the heat resistance of the polyetheresteramine is lowered. good. More preferably, the adduct (b) is used in the range of 40 to 70% by weight based on the total weight of the above (a) and (b). The relative viscosity of the polyether ester guanamine used in the present invention is 1.5 to 3.5 (0.5% by weight, m-cresol solution, 25 ° C), preferably 2.0 to 3.0. If it is less than 1.5, since the difference in melt viscosity between the base polymer component (polyamide component and polyester component) during kneading is large, it tends to stay in the inside of the tube or in the spinning unit, and spinning for a long time is likely to cause abnormal discharge. The quality of the obtained composite fiber is unstable. On the other hand, if it exceeds 3.5, it will become a cause of yarn breakage during yarn production. The polyether ester decylamine is preferably added to the polyamidene component in an amount of 〇% by weight. When added in a small amount, the hygroscopic elongation of the polyamide component is lowered, and the function of shrinking the moisture at the time of moisture absorption which is the object of the present invention and shrinking the length of the appearance yarn is impaired. The parallel type conjugate fiber may have any fineness, cross-sectional shape, or composite form, and is preferably about 1.5 to 5. Odtex as a single fiber fineness. Further, when the conjugate fiber of the present invention is a hollow conjugate fiber, the sensitivity to humidity is increased, and the bulkiness is also increased. Further, the area ratio of the cross section of the composite fiber of the polyamide component and the polyester component is preferably in the range of polyamine component/polyester component = 30/70 to 70/30, more preferably 40/60 to 60. /40 range. When the conjugate fiber is a multifilament of a plurality of filaments, the total fineness of the multifilament -31 - 201009148 is not particularly limited, but it can be used in the range of 40 to 200 dtex as a material for general clothing. Moreover, the interlacing process can also be performed as needed. - The above composite fiber has a potential crimping property, and as described later, exhibits a potential crimping property upon heat treatment such as dyeing processing. Therefore, when moisture is absorbed, the polyamine component is swollen and stretched, and the polyester component hardly causes the length to change, so that the crimp ratio is improved (the appearance length of the crimped fiber A is shortened). On the other hand, since the polyamide component shrinks during drying, the polyester component hardly changes in the yield, so that the crimp ratio is lowered (the length of the crimped fiber A becomes long).

The above-mentioned crimped fiber A is likely to be improved in shrinkage rate at the time of moisture absorption, and therefore it is preferable to use a non-twisted yarn or a weak twisted yarn of 300 T/m or less. In particular, it is preferable to use no silk. If it is strong silk, if the strong silk is given, the shrinkage rate during moisture absorption is not easy to improve. Further, even if the number of interlaces is about 20 to 60 pieces/m, the warp and weft interlaced air processing and/or the general false twisting processing may be performed. In the fabric of the present invention, the crimped fiber A is preferably contained in an amount of 10% by weight or more based on the weight of the fabric. The cloth may be composed only of the crimped fibers A', or may be a crimped fiber B having no crimping or moisture absorption, and the crimped fibers B, which are not crimped or moisture-absorbent, may be used as the other fibers. These fibers B may be one type or more, or two or more types. Among them, "there is no change in the crimping rate during moisture absorption" is the crimping rate HC during moisture absorption and the crimping ratio during drying : (: the difference (11 (: -0 〇 is less than 0.5%. The fiber B If it is polyethylene terephthalate, polyethylene terephthalate-32- 201009148 trimethyl ester, polybutylene terephthalate and other polyester, nylon 6, nylon 66, etc. Polyamide, polyethylene, poly Polyolefin such as propylene, acrylic acid, p-type or meta-type arylamine, and such modified synthetic fiber, natural fiber, regenerated fiber, semi-synthetic fiber, polyurethane-based elastic yarn, non- A water-absorbing polyether-ester-based elastic yarn, a water-absorbent polyether ester-based elastic yarn, or the like which is suitable for use in a clothing material, and can be freely selected, and the dimensional stability in the case of moisture absorption or the phase of the crimped fiber A described above. Capacitive (mixing, interlacing, interlacing, dyeing) φ In terms of 'polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, Or a polyester fiber composed of the modified polyester obtained by co-polymerizing the above copolymerized component, and if the fiber B is a polyamine group The elastic fiber having an elongation at break of 300% or more, such as an acid ester-based elastic yarn, a non-water-absorbing polyether ester-based elastic yarn, or a water-absorbing polyether ester-based elastic yarn, can increase the fabric density by utilizing the elastic recovery property of the elastic fiber, and can be lowered. The air permeability during drying is preferred. For example, if the elastic fiber is woven in an elongated state, the fabric is densified due to the elastic recovery of the elastic fiber, and the density of the fabric is increased. The number of filaments (the number of filaments) is not particularly limited, but in terms of improving the water absorption of the fabric, and the hygroscopic property of the moisture absorption, the single filament fineness is preferably from 0 to 1 to 5 dtex (more preferably, less than ldtex, and more). Good 〇 jMhex), the number of filaments is preferably in the range of 1 to 200 (more preferably 30 or more, and more preferably 3 〇 to 1 〇〇). In particular, the single filament fineness i dtex and the number of filaments More than 3 filaments are preferred. Further, warp and weft interlaced air is applied to make the number of interlaces to be about 20 to 60/m and/or to apply a normal false twist crimping process so that the crimp ratio becomes 5~ 40% is also fine. -33- 201009148 In the fabric of the present invention, The cloth structure and the number of layers are not particularly limited. For example, a plain weave, a woven fabric, a satin weave or the like, or a plain stitch structure, a double rib, a circular rib, a tuck mesh, and a woven weave are preferably exemplified. The composition of the flat structure, the semi-twisting, etc., but not limited to the ones. The number of layers may be a single layer or a plurality of layers of two or more layers. - The following fabrics for the present invention include the above moisture absorption A preferred embodiment of the above-described crimped fiber A and fiber φ φ arrangement in the case of a crimped fiber A having an increased crimp ratio and a crimped fiber B having no change in crimping or moisture absorption First, in the embodiment (1), the crimped fiber A is aligned with the fiber B, and placed in the warp and/or weft of the fabric or in the braid. In such a configuration, since only the appearance length of the crimped fiber A is shortened at the time of moisture absorption, the density of the cloth is increased (the void ratio is lowered) and the gas permeability is lowered. Next, in the embodiment (2), the crimped fibers A and the fibers B are used as the constituent yarns of the cloth, and the two are alternately arranged. At this time, the crimped fiber A and the fiber B may be in the form of one intersection, a plurality of intersections, one: plural strips @cross, plural strips: one cross, and the combination of the above. In these structures, since only the appearance length of the crimped fibers A is shortened at the time of moisture absorption, the fabric density is increased (the void ratio is lowered) and the gas permeability is lowered. Next, in the embodiment (3), the crimped fiber A and the fiber B are contained in the fabric in which the crimped fiber A is positioned in the core portion and the fiber B is in the sheath portion. In these structures, since only the appearance length of the crimped fibers A is shortened at the time of moisture absorption, the fabric density is increased (the void ratio is lowered) and the gas permeability is lowered. -34- 201009148 Next, in the 'implementation mode (4), the cloth is a multi-layer structure fabric having a multilayer structure of two or more layers, and at least 30% by weight of the total fiber-weight constituting the layer in at least one layer is the above-mentioned crimp Fiber A. In these structures, since only the appearance length of the crimped fibers A is shortened at the time of moisture absorption, the fabric density is increased (the void ratio is lowered) and the gas permeability is lowered. The cloth of the present invention can be easily obtained by, for example, the following production method. First, the polyamine component and the polyester component are conjugated into a φ side-by-side type. In this case, for example, the high viscosity component side and the low viscosity component side discharge hole are separated, and the discharge speed of the high viscosity side is small (the discharge area is increased as described in JP-A-2000-1445-18). The spinning nozzle of the large one is obtained by passing the molten polyester through the high-viscosity side discharge hole and passing the molten polyamine to the side of the low-viscosity side discharge port and joining, and cooling and solidifying. Further, in the present invention, the spinning die at this time may be appropriately designed as a side-by-side hollow composite fiber. The yarn obtained by spinning may be used in the so-called separately extending Φ manner after the winding is temporarily taken up and then heat-treated as needed, and the so-called direct stretching without stretching the unstretched filament and then heat-treating as needed may be used. The method in the extension mode. The spinning speed in the above spinning * can be, for example, a spinning speed of usually about 1,000 to 3,500 m/min. Further, the elongation and the heat treatment are preferably set so that the elongation at break after stretching is from 10 to 60%, usually from about 20 to 45%, depending on the expression of the crimp, the braidability, and the like. Then, the above-mentioned conjugate fiber can be used alone or at the same time, the conjugate fiber can be woven into a cloth with a fiber B having no change in the crimp ratio at the time of non-coiling or moisture absorption, and then subjected to dyeing processing, which is caused by heat during dyeing processing. Composite -35- 201009148 The fiber exhibits a potential crimp (referred to as crimped fiber A). Among them, when weaving into a fabric, the weaving organization is not particularly limited, and the above may be appropriately selected. The temperature of the above dyeing process is preferably from 100 to 140 ° C (more preferably from 110 to 135 ° C). The retention time of the highest temperature is preferably in the range of from 5 to 40 minutes. Under these conditions, by subjecting the fabric to a dyeing process, the composite fiber can exhibit a dry heat final setting by exhibiting a difference in heat shrinkage between the polyester component and the polyamide component. At this time, the temperature at which the dry heat is finalized is 120 to 200 ° C (more preferably 140 to 180 ° C), and the time is preferably in the range of 1 to 3 minutes. However, when the temperature at which the dry heat is finalized is lower than 120 °C, the crease generated during the dyeing process tends to remain, and the dimensional stability of the finished product may be poor. On the contrary, when the temperature at which the dry heat is finalized is higher than 200 ° C, the shrinkage of the composite fiber exhibited during the dyeing process is lowered, and the fiber is hardened and the texture of the original fabric is hardened. The gas permeability is reduced and the windproof property or the water leakage resistance is improved, and the fabric is a fabric having a coverage factor CF (when dry) of 2000 to 4500, or a 40-row needle number / 2.5 4 More than cm (more preferably 50 vertical stitches / 2.5 4 cm or more) and 50 courses of stitches (course) / 2.54 cm or more (more preferably 60 courses of needles / 2.54 cm or more). CF=(DWp/ll) 1/2xMWp+ ( DWf/1 .1 ) 1/2xMWf -36- 201009148 where DWp is the total fineness of the warp (dtex ) ' MWp is the density (bar / 2.54cm ) ' DWf is the weft The total fineness (dtex) of the silk is the weft density (bar/2.54cm). In addition, the fabric is further subjected to heat and pressure processing (calendering or water-repellent processing to make the gas permeability during drying smaller) and windproof It is preferable to use the conventional method for alkali processing, water absorption processing, raising processing, ultraviolet shielding or antibacterial agent, agent, insect repellent, light storage agent, retroreflector, negative ion generator, etc. In the fabric obtained in this way, since the fabric contains a fiber which is curled up at the time of moisture absorption (the length of the appearance is shortened), the fabric is improved (the void ratio is lowered) during moisture absorption, and the gas permeability is lowered. On the other hand, the dry fabric density is lowered (the void ratio is increased) to improve the gas permeability. In this case, the gas permeability of the cloth during drying is preferably 50 cc/cm 2 /s or less (4 〇 CC / cm 2 /s or less). The definition of the formula, the rate of decrease in permeability during moisture absorption is more than 1% Preferably, 30% or more is more preferably 35%. Preferably, the gas permeability reduction rate (%) = (APD-APH) / APDx 1 00 wherein APD is the gas permeability of the cloth when dried (cc/cm2/s ΑΡΗ The moisture permeability (cc/cm2/s) of the fabric during moisture absorption. Moreover, the fabric of the present invention obtains the weaving density of the fabric due to the weaving density at the time of moisture absorption.) The leakage resistance is reduced and the deodorization is given to the machine. ) High -37- 201009148 Excellent water leakage resistance. At this time, the water leakage of the fabric is preferably 2000ee or less. Among them, 'leakage water is JIS L 1 092, 6.3 (rain test A method). Bundesmann rain test The device 'measures the water leakage amount set to a total water volume of 7 liters/min in 10 minutes. Further, according to the present invention, there is provided a cloth using the above-mentioned cloth, and _ selected for the outer garment material, the sports clothing material and the inner lining clothing material. A group of fibrous products comprising the above-mentioned fabrics, which have a reduced gas permeability due to moisture absorption. Therefore, when the fibers are worn, when the rain or snow falls on the fibrous products, the warmth of the fibrous products is obtained. Improve, get leak-proof The effect of the present invention will be described in detail below with reference to the embodiments of the present invention relating to the above 20 to 28. The fabric of the present invention is required to be a crimped fiber A which is improved in the crimp ratio at the time of wetting (hereinafter sometimes referred to as "coiled" The fiber a" or "fiber A" is composed of a crimped fiber B (not sometimes referred to as "fiber B") which has no change in the crimping rate when it is not crimped or wet. The cloth is sweaty or rainy. In the case of moisture absorption, the shrinkage amount of only the crimped fibers A contained in the cloth is increased to make the appearance length shorter. As a result, since the thickness of the cloth is partially thickened (i.e., unevenness occurs) during moisture absorption, a gap is formed between the cloth and the skin to improve the transparency. At this time, the thickness change rate (TD) at the time of drying and the thickness (TW) at the time of wetting can be calculated from the following formula, and it is important that the thickness change rate is 5% or more (preferably 10~). 100%). When the difference in the thickness of -38 - 201009148 is less than 5%, the transparency at the time of moisture absorption cannot be sufficiently exhibited, which is not preferable. Thickness change rate (%) = ( (TW-TD) / TD) χίοο where the thickness during drying is the thickness of the cloth in a state where the cloth is placed in a temperature of 20 ° C and a humidity of 65% RH for 24 hours. The other side is the φ surface, and the thickness at the time of moisture absorption is the thickness of the cloth in a state where the cloth is placed in a temperature of 20 ° C and a humidity of 90% RH for 24 hours. Further, the thickness is the distance between the highest portion and the lowest portion of the cloth shown in Fig. 4. In addition, it can be measured using an ultra-high precision laser displacement gauge (Model LC-2400 manufactured by KEYENCE Corporation). Further, in the present invention, "the increase in the crimp ratio at the time of moisture absorption" is such that the difference (HC-DC) between the crimp ratio HC at the time of wetting and the crimp ratio DC at the time of drying is 0.5% or more. In the case of drying, the cloth is placed in a state of temperature φ 20 ° C and humidity 65% RH for 24 hours. On the other hand, when the moisture is absorbed, the cloth is placed at a temperature of 20 ° C and a humidity of 90% RH. In the environment • State after 24 hours. In the present invention, the crimped fiber A is not particularly limited as long as it is a fiber having an increased crimp ratio at the time of moisture absorption, but a composite fiber obtained by joining a polyester component and a polyamide component into a side-by-side type, and exhibiting a potential roll A crimped fiber having a crimped configuration is preferred. The polyamine component is a polymer having a guanamine bond in the main chain, and examples thereof include, for example, nylon 4, nylon 6, nylon 12, nylon 46, nylon 66-39-201009148, and the like. In particular, Nylon 6 and nylon 66 are preferable from the viewpoints of cost, versatility, and yarn-making properties. Further, the polyamine components may be copolymerized with a conventional component, or may contain a pigment such as oxidized-titanium or carbon black, a conventional antioxidant, an antistatic agent, or the like. Light stabilizer, etc. On the other hand, the above polyester component preferably accounts for 60 to 99.5 mol% of the repeating single-position ethylene terephthalate unit constituting the polyester, and the isophthalic acid dicarboxylate unit accounts for 0.5~. 40 mole % of copolymerized polyester. Generally, the heat shrinkage of the polyester is lower than that of the polyamine, but the heat shrinkage of the polyester can be brought close to the polyamine by using the copolymerized polyester as the polyester. As a result, in the crimped and bent structure at the time of moisture absorption, it is easy to form a structure in which the swollen polyamine component is located outside and the polyester component is located inside, and the crimp ratio is likely to increase. Among them, when the unit of ethylene terephthalate is less than 60 mol%, it is not preferable because the basic physical properties of the strong elongation of the obtained conjugate fiber cannot be sufficiently maintained. When the ethylene terephthalate unit exceeds 99.5 mol% and the isophthalic acid ethylene diester does not reach 0.5 mol%, the crimping rate of the composite fiber is not increased when it absorbs moisture (the length of the crimped filament is not Shorten), and it is difficult to show the fabric © enough to prevent transparency. When the ethylene isophthalate exceeds 40 mol%, the basic physical properties such as the strong elongation of the composite fiber cannot be maintained, and the thermal stability is also deteriorated, and the spinning nozzle is formed due to the decomposable foreign matter in the spinning step. Part of the filtration pressure (filling pressure) increased significantly. The polyesters may be produced by any method, for example, if polyethylene terephthalate is described, in order to directly esterify terephthalic acid with ethylene glycol, such as dimethyl terephthalate Direct esterification of terephthalic acid lower alkyl ester with ethylene glycol, or reaction of terephthalic acid with ethylene oxide, etc., -40- 201009148 to produce terephthalic acid glycol ester and / or its oligomerization Things. The ruthenium is then produced by heating the product under reduced pressure and polycondensing to a desired degree of polymerization, in addition to the ethylene terephthalate component of the polyester and the phthalic acid phthalate. In addition to the ester component, a third component may be copolymerized, and the third component is preferably any of a dicarboxylic acid component or a diol component. As the dicarboxylic acid component, for example, phthalic acid, dibromo-terephthalic acid Φ, naphthalene dicarboxylic acid, diphenyl dicarboxylic acid, diphenoxyethane dicarboxylic acid, such as β-hydroxyl group can be exemplified. A difunctional aromatic dicarboxylic acid of ethoxybenzoic acid, such as a difunctional aliphatic dicarboxylic acid such as azelaic acid, adipic acid or oxalic acid, or 1,4-cyclohexanedicarboxylic acid. Further, a part of the above diol component may be substituted by other diol components, such as, for example, cyclohexane-1,4·dimethanol, neopentyl glycol, bisphenol oxime, bisphenol S, 2, 2-bis(4-β-hydroxyethoxyphenyl)propane, bis(4-β-hydroxyethoxyphenyl)anthracene, 2,2-bis(3,5-dibromo-4-( 2_ Aliphatic, alicyclic, aromatic diols of hydroxyethoxy)phenyl)propane. Further, in the above polyester, a small amount of the other polymer may be blended as needed, and a chain branching agent such as pentaerythritol, trimethylolpropane or trimellitic acid may be used in a small amount. In addition, the polyester of the present invention is of course also added with a pigment such as titanium oxide or carbon black as in the conventional polyester, a conventional antioxidant and an anti-tarnishing agent. The polyester component preferably contains a polyether ester decylamine. When the polyester component contains a polyether ester decylamine, the polyester component becomes soft, and when moisture absorbing, the polyester component is easily followed when the polyamine component is swollen, and the crimp ratio at the time of moisture absorption is apt to increase. Preferably. The polyether ester decylamine is preferably added to the polyester component in an amount of 5 to 55% by weight based on the weight of the poly-41 - 201009148 ester component. If it is less than 5% by weight, the crimping rate does not increase when the composite fiber absorbs moisture (the length of the crimped fiber is difficult to be shortened). When the fabric is used, sufficient transparency can not be obtained. On the other hand, when it exceeds 55% by weight, there is a case where the spinning cannot be stabilized. The polyether ester decylamine is preferably an ethylene oxide addition of a polyamine (a) having a number average molecular weight of 500 to 5,000 at both terminals and a bisphenol having a number average molecular weight of 1,600 to 3,000. Derived from substance (b). "Derivative" means the one obtained by reacting two components, or the one obtained by copolymerization. The polyamine (a) having a carboxyl group at both terminals is preferably composed of a polyamine moiety and a molecular weight modifier. The polyamine moiety is composed of at least one of (1) an indoleamine ring-opening polymer, (2) a polycondensate of an aminocarboxylic acid, or (3) a polycondensate of a dicarboxylic acid and a diamine. , among these, (1)

The indoleamines are exemplified by butyrolactam, valeroguanamine, caprolactam, heptanoin, dodecane decylamine, undecyl decylamine and the like. The aminocarboxylic acid of (2) is exemplified by ω-aminohexanoic acid, ω-amino heptanoic acid, ω-aminooctanoic acid, ω-amino decanoic acid, 11-aminoundecanoic acid, and 12-amino group. Dodecanoic acid, etc. The (3) bis carboxylic acid is exemplified by adipic acid, sebacic acid, sebacic acid, undecanedioic acid, dodecanedioic acid, isophthalic acid and the like. Further, the diamine of (3) is exemplified by tetramethylene diamine, pentamethylene diamine, hexamethylene diamine, heptamethylene diamine, octamethylene diamine, and decamethylene diamine. Wait. The above internal amines, aminocarboxylic acids, dicarboxylic acids, and diamines are generally referred to as polyamine partial forming monomers. The above-mentioned polyamine moiety-forming monomer which is a polyamine (a) having a carboxyl group at both terminals may be exemplified by two or more types. Preferred among these are caprolactam, 12-aminododecanoic acid and adipic acid-hexamethylenediamine, and -42-201009148 the best one is caprolactam. The polyamine (a) having a carboxyl group at both ends thereof further uses a dicarboxylic acid component having a carbon number of 4 to 20 as a molecular weight modifier, and in the presence of the above, the above-mentioned polyamine moiety is formed by a conventional method. The monomer is obtained by ring opening polymerization or polycondensation. Examples of the dicarboxylic acid having a carbon number of 4 to 20 are succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedioic acid, or dodecane. Fatty acid dicarboxylic acid such as diacid; aromatic dicarboxylic acid such as terephthalic acid, isophthalic acid, phthalic acid or naphthalene dicarboxylic acid; 1,4-cyclohexanedicarboxylic acid or bicyclic ring An aliphatic dicarboxylic acid such as hexyl-4,4-dicarboxylic acid; or an alkali metal 5-sulfoisophthalate such as sodium 5-sulfoisophthalate or potassium 5-sulfoisophthalate . Among these, preferred are aliphatic dicarboxylic acids, aromatic dicarboxylic acids, and alkali metal salts of 5-sulfoisophthalic acid. More preferably, it is adipic acid, terephthalic acid, or sodium 5-sulfoisophthalate. When the polyamidene moiety forming monomer is subjected to ring-opening polymerization or polycondensation by a conventional method, the average degree of polymerization is preferably from 2 to 10, and more preferably, the average degree of polymerization is from 3 to 8. As a result, the polyamine moiety has a number average molecular weight of from 100 to 1,000, more preferably from 300 to 700. Further, the polyamine (a) having a carboxyl group at both ends is a component which imparts a polyamine moiety at both ends of a dicarboxylic acid component having 4 to 20 carbon atoms of a molecular weight modifier, and a polyamine moiety is provided at a single terminal. The component may be a mixture of a component which imparts a polyamine moiety at both ends and a component which gives a polyamine moiety at a single terminal. In the case of a mixture, it is preferred that the component which imparts the polyamine moiety to the monomolar terminal at one end and the component which gives the polyamine moiety at both ends becomes 1 to 10 moles. It is better to give a composition of -43 to 201009148 with respect to the single end of 1 mole, and the composition of the two ends is 3 to 8 moles. Therefore, the amount of the carboxyl group-containing component of the above polyamine moiety-forming monomer can be appropriately adjusted so as to have a carboxyl group at both terminals. If only indoleamine and/or an aminocarboxylic acid is used as the mermeric amine moiety-forming monomer, since the molecular weight modifier is a dicarboxylic acid component, a polyamine amine having a carboxyl group at both terminals can be easily produced ( a) . When a polycondensate of a dicarboxylic acid and a diamine is used as a polyamidene moiety-forming monomolecular, for example, a polyalkylamine having a carboxyl group at both terminals can be produced by a method such as a reaction for finally changing a dicarboxylic acid of a polymer. ). The number average molecular weight of the polyamine (a) having a carboxyl group at both ends is usually from 50 to 5,000, preferably from 500 to 3,000. When the number average molecular weight is less than 500, the heat resistance of the polyether ester decylamine itself is lowered. On the other hand, when the reactivity exceeds 5,000, the polyether ester amide is required to be produced for a longer period of time due to a decrease in reactivity. In order to make the number average molecular weight fall within the range, a dicarboxylic acid component having 4 to 20 carbon atoms may be selected as the molecular weight modifier, and the reaction conditions may be appropriately set in the polymerization of the polyamine moiety. Further, among the bisphenol-based ethylene oxide adducts (b), bisphenols are bisphenol A (4,4'-dihydroxydiphenyl-2,2-propane), bisphenol F. (4,4'-dihydroxydiphenylmethane), bisphenol S (4,4'-dihydroxydiphenyl) and 4,4'-dihydroxydiphenyl-2,2-butane. The preferred of these is double 酣A. The above bisphenol-based ethylene oxide adduct (b) is obtained by adding ethylene oxide to the bisphenols by a conventional method. Further, ethylene oxide and other alkylene oxides (propylene oxide, 1,2-butylene oxide, 1,4-butylene oxide, etc.) may be used, but other alkylene oxides may be used in all. Epoxy B-44- 201009148 The weight of the alkane shall prevail, usually below 〖〇% by weight. Further, the above adduct (b) corresponds to two hydroxyl groups of bisphenols, and an average of 20 to 70 moles of ethylene oxide and other alkylene oxides (hereinafter referred to as epoxy epoxides, etc.) are polymerized. good. It is better for the polymerization to have 32 to 60 moles of epoxy, etc. That is, the hydroxy polymerization (addition) corresponding to bisphenol has an adduct of 10 to 35 moles, preferably 16 to 30 moles, more preferably 16 to 20 moles of epoxy enamel. . The number average molecular weight of the above adduct (b) is usually uoo - s, 000 ', especially in the case of using an ethylene oxide addition molar number of 32 to 60. If the average molecular weight is less than 1,600, the antistatic property is insufficient. On the other hand, when it exceeds 3,000, it takes a long time to manufacture the polyetheresteramine due to a decrease in reactivity. The number average molecular weight is preferably from 1,800 to 2,400, and the addition molar number of ethylene oxide or the like is more preferably from 32 to 40. The number average molecular weight is within this range. The molecular weight of the bisphenol can be considered by adjusting the molar number of addition of ethylene oxide or the like. The above-mentioned adduct (b) is used in the range of 20 to 80% by weight based on the total weight of the above (a) and (b) in the polyetheresteramine. When the amount of the adduct (b) is less than 20% by weight, the antistatic property of the polyether ester decylamine is deteriorated, and on the other hand, when it exceeds 80% by weight, the heat resistance of the polyether ester decylamine is lowered. good. More preferably, the adduct (b) is used in the range of 40 to 70% by weight based on the total weight of the above (a) and (b). The relative viscosity of the polyether ester guanamine used in the present invention is 1.5 to 3.5 (0.5% by weight, m-cresol solution, 25 ° C), preferably 2.0 to 3.0. If it is less than 1.5, since it has a large difference in melt viscosity from the base polymer component (polyamide component and poly-45-201009148 ester component) during mixing, it tends to stay in the inside of the catheter or in the spinning assembly, and to perform spinning for a long time. It is easy to cause abnormal discharge and the quality of the obtained composite fiber is unstable. On the other hand, if it exceeds the range of 3.5, it will cause the yarn breakage during the spinning. The polyether ester decylamine is preferably added to the polyamidene component in an amount of 〇% by weight. When added in a small amount, the hygroscopic elongation of the polyamide component is lowered, and the function of shrinking the moisture at the time of moisture absorption which is the object of the present invention and shrinking the length of the appearance yarn is impaired. φ The above-mentioned side-by-side type composite fiber may have any fineness, cross-sectional shape, or composite form, and the single-filament fineness is preferably about 1.5 to 5.0 dtex. Further, when the conjugate fiber of the present invention is a hollow conjugate fiber, the sensitivity to humidity is increased, and the bulkiness is also increased. Further, the area ratio of the cross section of the composite fiber of the polyamide component and the polyester component is preferably in the range of polyamine component/polyester component = 30/70 to 70/30, more preferably 40/60 to 60. /40 range. When the conjugate fiber is a multifilament of a plurality of filaments, the total fineness of the multifilament is not particularly limited, but it can be used as a material for general clothing in the range of 40 to 200 dtex. Moreover, the interlacing process can also be performed as needed. The composite fiber described above exhibits a potential crimping property as described later, and exhibits a potential crimping property upon heat treatment such as dyeing. Therefore, when the moisture absorption is carried out, the polyamide component is swollen and elongated, and the polyester component hardly causes a change in length, so that the crimp ratio is improved (the appearance length of the crimped fiber A is shortened). On the other hand, since the polyamide component shrinks during drying, the polyester component hardly changes in the degree of growth, and thus the crimp ratio is lowered (the length of the crimped fiber A is -46 - 201009148). The above-mentioned crimped fiber A is likely to be improved in shrinkage at the time of moisture absorption, and it is preferable to use a twisted yarn having a twisted yarn or a twisted yarn of 300 T/m or less. In particular, it is preferred to have no silk. If it is strong silk, if it is given strong silk, it will not be easy to increase the shrinkage rate when it absorbs moisture. Further, even if the number of interlaces is about 20 to 60 pieces/m, the warp and weft interlacing air processing and/or the general false twisting processing may be performed. φ On the other hand, the fiber B having the crimped shape which is not changed in the non-crimping or moisture absorption is not particularly limited as long as it is a non-crimped fiber or a fiber having a crimping rate which does not change when moisture is absorbed. The so-called "no change in the crimping rate at the time of moisture absorption" is a difference between the crimping rate HC at the time of moisture absorption and the crimping ratio DC at the time of drying (HC-DC) of less than 0.5%. The fibers B are polyesters such as polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, nylon 6, nylon 66, polyethylene, poly Polyolefin such as propylene, acrylic acid, p-type or meta-type linalylamine, and such modified synthetic fiber, natural fiber, regenerated fiber, semi-synthetic fiber, polyurethane elastic yarn, polyether ester Fibers suitable for clothing such as elastic 'silk' are freely selectable. Among them, in terms of dimensional stability during moisture absorption, or compatibility with the above-mentioned crimped fiber A (mixing property, blending, interlacing property, dyeability), polyethylene terephthalate is used. Preferably, polytrimethylene terephthalate, polybutylene terephthalate, or a polyester fiber composed of the modified polyester obtained by copolymerizing the above copolymerized component. Further, the single-filament fineness and the number of filaments (the number of filaments) of the fiber B are not particularly limited, but the single-filament fineness is improved in terms of improving the water absorption of the fabric and exhibiting the convexity of the concave-47-201009148 when moisture is absorbed. It is preferably in the range of 0.1 to 5 dtex (more preferably 55 to 2 dtex), and the number of filaments is 20 to 2 00 (more preferably 3 to 100). In particular, it is possible to interlace air processing with a warp and weft of about 20 to 60/m or so and to perform general false twist crimping. The fabric of the present invention contains the above-mentioned roll having an improved crimp ratio at the time of moisture absorption. The fin fiber A has a crimped fiber B which has no change in the crimp ratio when it is not crimped or moisture-absorbent. The structure of the cloth is not limited to the structure of the weave and the number of layers. For example, φ is preferably woven in a plain weave, a woven weave, a satin weave, or a woven structure, a double rib, a circular rib, a tuck mesh, a woven weave, a warp weave, a half wow, etc., but Not limited to these. The number of layers may be a single layer or a multilayer of two or more layers. Among them, the reason why the cloth exhibits unevenness due to moisture absorption is that the cloth is composed of a portion which changes (shrinks) due to the moisture absorption size and a portion which does not change even if the moisture absorption size or a small amount of dimensional change, because the cause is relative to the former. The moisture absorption size is changed, and the latter is such that the size is not changed or the dimensional change is small, and the latter is a convex portion to exhibit unevenness when moisture is absorbed, so that the above-mentioned crimping is appropriately configured because the unevenness is effectively exhibited by moisture absorption. Fiber A and fiber B' are quite important. The preferred embodiment of the above-described crimped fiber A and fiber B arrangement contained in the fabric of the present invention will be described below. First, in the embodiment (1), the cloth has a portion (Y portion) composed only of the crimped fibers A and a portion (Z portion) composed only of the fibers B, and the Y portion is formed in the warp direction and / or weft direction -48- 201009148 continuous. In the structure, the Y portion is easily changed (contracted) compared to the Z portion when moisture is absorbed, and since the Y portion in the cloth is continuous in the warp direction and/or the weft direction, the Z portion becomes a convex portion to exhibit unevenness. - In this case, the γ portion is continuous in the warp direction and/or the weft direction. The type is not particularly limited, and may be exemplified by, for example, a fringe pattern, a stripe pattern, a grid pattern, a rhombic pattern schematically represented in FIG. 5, Slate plaid φ pattern and so on. The area ratio of the Z portion to the Y portion is not particularly limited, but in terms of the dimensional stability of the cloth, it is (Z part: Y part), and is 10: 90 to 90: 10 (more preferably 20: Preferably, the range of 80 to 80: 20) is such that the Y portions are blocked from each other by the z portion in the cloth. In this case, the area of the one portion of the Y portion is not particularly limited, and in the range of 0.01 to 4.0 cm 2 (more preferably 0.1 to 1.0 cm 2 ), it is preferable to prevent the clothing from sticking to the skin when sweating. On the other hand, the line width of the Z portion is preferably in the range of 0.5 to 100 mm.

'Next, in the embodiment (2), the fabric has a portion (Z portion) composed only of the above-mentioned fibers B and a portion (X portion) composed of the above-mentioned crimped fibers A and the above-mentioned fibers B, and the above-mentioned X portion becomes Continuous through the direction and / or the weft direction. In this configuration, the X portion is more likely to change in size than the Z portion when wet, and since the X portion in the cloth is continuous in the warp direction and/or the weft direction, the Z portion becomes a convex portion to exhibit unevenness. In this case, it is preferable that the X portion 49-201009148 is a connection pattern, or the area ratio of the two is the same as the embodiment (1). Then, in the embodiment (3), the cloth has the above-mentioned crimped fiber A and the above The portion (X portion) of the fiber B and the portion (Y portion) composed only of the above-mentioned crimped fiber A are formed to be continuous in the warp direction and/or the weft direction. In this configuration, the Y portion is more likely to change in size than the X portion when wet, and since the Y portion in the cloth becomes continuous in the warp direction and/or the weft direction, the X portion becomes a convex portion to exhibit unevenness. At this time, it is preferable that the γ portion is connected to the pattern ’ or the area ratio of the two is the same as that of the embodiment (1). Next, in the embodiment (4), the cloth has a portion (X portion) composed of the above-mentioned crimped fiber A and the above-mentioned fiber B, and a portion (Y portion) composed only of the above-mentioned crimped fiber A, and only the above-mentioned fiber In the portion (part Z) of the B configuration, the Y portion is continuous in the warp direction and/or the weft direction. 10 In this configuration, the Y part is easier to change in size than the other parts (X part or Z part), and since the Y part in the cloth is continuous in the warp direction and/or the weft direction, the other part (X part) Or the Y part) becomes a convex part and exhibits unevenness. In this case, it is preferable that the Y portion is a connection pattern, or the area ratio of the Y portion to the other portions is the same as that of the embodiment (1). Then, in the embodiment (5), the cloth is a multi-layered fabric composed of two or more layers, and has a layer composed of the crimped fibers A and B, and a layer composed of only the above-mentioned fibers B from -50 to 201009148, and The former layer is connected to the latter layer. In the structure, the layer composed of the crimped fiber A and the fiber b has a larger change in the moisture absorption size than the layer composed only of the fiber B, and only the layer composed of the fiber B is not crimped. The portion where the fibers A and the layers of the fibers b are joined is a convex portion and exhibits irregularities. Then, in the embodiment (6), the cloth is a φ multilayer fabric composed of two or more layers and has a layer composed of the crimped fibers A and B, and a layer composed only of the crimped fibers A, and The former layer is connected to the latter layer. In this configuration, only the layer composed of the crimped fibers A has a larger change in the moisture absorption size than the layer composed of the crimped fibers A and B, and the layer composed of the crimped fibers A and B In the middle, the portion which is not connected to the layer composed only of the crimped fibers A is a convex portion and exhibits irregularities. Next, in the embodiment (7), the fabric is a multi-layered fabric composed of two or more layers, and has a layer composed only of the crimped fibers A and a layer composed only of the fibers B, and the former layer and The latter layer is partially connected. In this configuration, only the layer composed of the above-mentioned crimped fibers A has a larger change in the moisture absorption size than the layer composed only of the above-mentioned fibers B, and only the layer composed of the above-mentioned fibers B is not only in the above-mentioned roll. The portion in which the layers of the condensed fibers A are joined becomes a convex portion and exhibits irregularities. The fabric of the present invention can be easily obtained by, for example, the following production method. First, the polyamide component and the polyester component are conjugated into a side-by-side type -51 - 201009148. In this case, for example, the high-viscosity component side and the low-viscosity component side discharge hole can be separated, and the discharge line speed on the high viscosity side can be used as described in JP-A-2000-144. The smaller (extrusion area increased) spinning-die] is obtained by passing the molten polyester through the high-viscosity side discharge hole and allowing the molten polyamine to pass through the low-viscosity side discharge port side and being joined by cooling and solidification. - Get a spun yarn. Further, in the present invention, by appropriately designing the spinning nozzle at this time, _ can be used as a side-by-side hollow composite fiber. The so-called filaments obtained by spinning can be stretched and then heat-treated as needed, and the so-called "extension" can be used for the purpose of not stretching the unstretched filaments and then heat-treating as needed. The method in the extension mode. The spinning speed in the above spinning can be, for example, a spinning speed of usually about 100 〇 to 3,500 m/min. Further, the elongation and the heat treatment are preferably set so that the elongation at break after stretching is from 1 〇 to 60%, and usually from about 20 to 45%, depending on the expression of the crimp, the braidability, and the like. Then, the conjugate fiber and the fiber B having no change in the crimping rate at the time of non-coiling or moisture absorption can be simultaneously woven into a cloth, and then subjected to dyeing processing, and the composite fiber exhibits potential crimping by heat during the dyeing process. (called crimped fiber A). In the case of 'woven into a fabric, the weaving organization is not particularly limited, and the above may be appropriately selected. The temperature of the above dyeing process is 100 to 140 ° C (more preferably 11 〇 to 135 ° C), and the time is preferably in the range of 5 to 40 minutes at the maximum temperature. Under these conditions, by subjecting the fabric to a dyeing process, the above composite fiber can exhibit shrinkage by the heat shrinkage of the polyester component and the polyamide component. The fabric to be dyed is usually subjected to dry heat final setting. At this time, the temperature at which the dry heat is finalized is 120 to 200 ° C (more preferably 140 to 180 ° C), and the time is preferably in the range of 1 to 3 minutes. Among them, when the temperature at which the dry heat is finalized is lower than 120 °C, wrinkles which are generated during the dyeing process tend to remain, and the dimensional stability of the finished product may deteriorate. Conversely, when the temperature at which the dry heat is finalized is higher than 200 ° C, the shrinkage of the composite fiber exhibited during the dyeing process is lowered, and the fiber is hardened and the texture of the original fabric is hardened. In the cloth thus obtained, when the cloth absorbs moisture due to sweating or rain, the length of the crimping fiber A itself is increased to shorten the appearance length. On the other hand, the fiber B has almost no change even if it absorbs moisture. As a result, the fibers B become convex portions due to moisture absorption, and the irregularities are exhibited. Therefore, by the appearance of the concavities and convexities, a gap is formed between the cloth and the human body or the object to improve the anti-transparency. Further, in the cloth thus obtained, if the crimped fiber A contained in the fabric satisfies the requirements of the following (1) to (3) at the same time, it is preferable to obtain an excellent anti-transparency property at the time of moisture absorption. Further, the crimped fiber A having such characteristics can be produced by the above-described manufacturing method. (1) The crimping ratio DC of the crimped fiber A during drying is in the range of 50 to 80%. (2) The crimping rate HC of the crimped fiber A during moisture absorption is in the range of 60 to 90%. (3) The difference between the above-mentioned crimp ratio HC and the crimp ratio DC (HC-DC) is -53- 201009148 0.5% or more. In the case of drying, the sample is placed in a state of a temperature of 20 ° C and a humidity of 65% RH for 24 hours. On the other hand, when the sample is absorbed, the sample is placed at a temperature of 20 ° C and a humidity of 90. The state after 24 hours in the environment of %RH. In addition, the fabric of the present invention may be additionally subjected to various processes such as water absorption processing, raising processing, ultraviolet shielding or antibacterial agents, deodorants, insect repellents, light storage agents, retroreflectors, negative ion generators, and the like. </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; / or the pile part of the loop pile is composed. The pile portion may also be formed on both sides of the surface of the bottom tissue portion, but it is preferably formed on only one side thereof. Further, it is important that the above-mentioned standing portion contains the crimped fiber A having an increased crimp ratio at the time of moisture absorption as the cut pile and/or the pile pile. By the fact that the crimped fiber A is contained in the upset portion as the cut pile and/or the loop pile, as shown in the 'pattern display' in FIGS. 6 and 7, the crimping rate of the crimped fiber A is reversibly due to moisture absorption. Increase the height of the standing hair to be smaller. It is preferable that the crimped fibers A are crimped fibers satisfying the requirements of the following (1) and (2). (1) The crimped fiber A is a composite fiber obtained by joining a polyester component and a polyamide component into a side-by-side type. (2) The crimp ratio HC of the crimped fiber a during moisture absorption and the curl during drying -54- 201009148 The difference in the crimp ratio DC (HC-DC) of the fiber A is 0.5% or more (preferably 5% or more). In the case of drying, the sample is placed in a state of a temperature of 20 ° C and a humidity of 65% RH for 24 hours. On the other hand, when the moisture is absorbed, the sample is placed at a temperature of 20 ° C and humidity. The state after 24 hours in an environment of 90% RH. 9 wherein, when the shrinkage ratio HC of the crimped fiber A at the time of moisture absorption is less than 0.5% of the crimp ratio DC of the crimped fiber A at the time of drying, the fabric is absorbent. Breathability is not degraded. Further, the crimping ratio DC of the crimped fiber A during drying is preferably in the range of 50 to 80%. On the other hand, the crimping ratio HC of the crimped fiber A during moisture absorption is preferably in the range of 60 to 90%. The crimped fiber A is preferably a composite fiber in which a polyester component and a polyamide component are joined together in a side-by-side manner, and is preferably a crimped fiber having a crimped structure exhibiting a latent crimping property. That is, the above-mentioned polyamide component is a polymer having a guanamine bond in the main chain, and examples thereof include, for example, nylon 4, nylon 6, nylon 12, nylon 46, and nylon 66. In particular, nylon 6 and nylon 66 are preferable from the viewpoints of cost, versatility, and yarn-making properties. Further, the polyamine component may be copolymerized with a component known as a base, or the polyamide component may contain a pigment such as titanium oxide or carbon black, a conventional antioxidant, an antistatic agent, and light resistance. Agents, etc. On the other hand, the above polyester component preferably accounts for 60 to 99.5 mol% of the ethylene terephthalate unit in the repeating unit constituting the polyester, and the ethylene isophthalate unit accounts for 0.5 to 40 moles. % of the copolymerized polyester of the ear constitutes -55- 201009148. Generally, the heat shrinkage of the polyester is lower than that of the polyamine, but the heat shrinkage of the polyester is brought close to the polyamine by using the copolymerized polyester as the polyester. As a result, in the crimping and bending structure at the time of drying, in the crimping and bending structure during moisture absorption, it is easy to form the swelled polyamidamide component on the outer side, and the polyester component is located on the inner side, and it is easy to increase the volume. Shrinkage. Among them, when the unit of terephthalic acid-ethylene diester is less than 60 mol%, the basic physical properties such as the strong elongation of the obtained conjugated fiber 1 cannot be sufficiently maintained. When the ethylene terephthalate unit exceeds 99.5 mol% and the isophthalic acid ethylene diester does not reach 0.5 mol%, the crimping rate is not increased when the composite fiber absorbs moisture (the length of the crimped filament is short) If it is not shortened, there is a problem that a sufficient low thickness cannot be obtained as a cloth. When the ethylene isophthalate exceeds 40 mol%, the basic physical properties such as the strong elongation of the composite fiber cannot be maintained, and the thermal stability is also deteriorated, and the spinning port is molded due to the decomposable foreign matter in the spinning step. The filtration pressure (filling pressure) of the mouth portion is significantly increased. The polyesters may be manufactured by any method. For example, for example, polyethylene terephthalate is directly esterified with terephthalic acid to react with ethylene glycol to make dimethyl terephthalate. The ester of the lower alkyl ester of terephthalic acid is directly esterified with ethylene glycol, or the reaction of terephthalic acid with ethylene oxide, etc., to produce a terephthalic acid glycol ester and/or its low polymer. The product is then heated under reduced pressure and polycondensed to a desired degree of polymerization to form a bismuth phthalate component and ethylene phthalate component. In addition, a third component may be copolymerized, and the third component is preferably any of a dicarboxylic acid component or a diol component. As the di-carboxylic acid component of the -56-201009148, for example, phthalic acid, dibromo-terephthalic acid, naphthalene dicarboxylic acid, diphenyldicarboxylic acid, diphenoxyethane dicarboxylic acid, such as hydrazine can be exemplified. _. A difunctional aromatic dicarboxylic acid of ethoxy benzoic acid, such as a dicarboxylic aliphatic dicarboxylic acid of azelaic acid, adipic acid, oxalic acid, 1,4-cyclohexane dihistamine Wait. Further, a part of the above diol component may be substituted with other diol components, such as cyclohexane-1,4-dimethanol, neopentyl glycol, bisphenol A, bisphenol S, 2, for example. 2-bis(4-β-hydroxyethoxyphenyl)propane, double φ(4-β-hydroxyethoxyphenyl)anthracene, 2,2-bis(3,5-dibromo-4-(2) An aliphatic, alicyclic or aromatic diol of - ethoxycarbonyl)phenyl)propane. Further, in the above polyester, a small amount of the other polymer may be blended as needed, and a chain branching agent such as pentaerythritol, trimethylolpropane or trimellitic acid may be used in a small amount. In addition, the polyester of the present invention may of course be added with a pigment such as titanium oxide or carbon black, a conventional antioxidant, or an anti-coloring agent in the same manner as a general polyester. The polyester component preferably contains a polyether ester decylamine. When the polyester component contains φ polyether ester decylamine, the polyester component becomes soft, and when the polyamine component swells during moisture absorption, the polyester component is easily followed, and it is easy to shrink during moisture absorption. The rate is improved and it is better. The polyether ester decylamine is preferably added to the polyester component in an amount of 5 to 55% by weight based on the weight of the polyester component. If it is less than 5% by weight, the crimping rate does not increase when the composite fiber absorbs moisture (the length of the crimped fiber is difficult to be shortened), and there is a problem that a sufficient thickness cannot be obtained as a fabric. On the other hand, when it exceeds 55% by weight, there is a problem that the spinning cannot be stably performed. The polyether ester decylamine is preferably an ethylene oxide compound having a number average molecular weight of -78 to 201009148 of 500-5,000 at both ends and a bisphenol of a number average molecular weight of 1,600 to 3,000. Derived from product (b). "Derivative" means the one obtained by reacting two components, or the one obtained by copolymerization. The polyamine (a) having a carboxyl group at both terminals is preferably composed of a polyamine moiety and a molecular weight modifier. The polyamine moiety is at least one of (1) an indoleamine-ring-opening polymer, (2) a polycondensate of an aminocarboxylic acid, or (3) a dicondensate of a dicarboxylic acid and a diamine. In the above, the guanamine in (1) is exemplified by butane decylamine, valeroguanamine, caprolactam, heptanolactone ©, dodecane decylamine, undecane decylamine, and the like. . The aminocarboxylic acid of (2) is exemplified by ω-aminohexanoic acid, ω-amino heptanoic acid, ω-aminooctanoic acid, ω-amino decanoic acid, 11-aminoundecanoic acid, and 12-amino group. Dodecanoic acid, etc. The (3) dicarboxylic acid is exemplified by adipic acid, sebacic acid, sebacic acid, undecanedioic acid, dodecanedioic acid, isophthalic acid and the like. Further, the diamine of (3.) is exemplified by tetramethylene diamine, pentamethylenediamine, hexamethylenediamine, heptamethylenediamine, octamethylenediamine, and decamethylene. Amines, etc. The above-mentioned indoleamine, aminocarboxylic acid, dicarboxylic acid, and diamine are collectively referred to as a polyamidene moiety-forming monomer.例 The above-mentioned polyamine moiety-forming monomer which is a polyamine (a) having a carboxyl group at both terminals may be exemplified by two or more types. Preferred among these are caprolactam, 12-aminododecanoic acid and adipic acid-hexamethylenediamine, and the most preferred is caprolactam. The polyamine (a) having a carboxyl group at the two ends is further a dicarboxylic acid component having 4 to 20 carbon atoms as a molecular weight modifier, and the polyformamide moiety is formed by a conventional method in the presence of the above. The monomers are obtained by ring opening polymerization or polycondensation. Examples of the dicarboxylic acid having 4 to 20 carbon atoms are succinic acid, glutaric acid-58-201009148, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, -f-alkanedioic acid, or a fatty acid dicarboxylic acid such as dodecanedioic acid; an aromatic dicarboxylic acid such as terephthalic acid, isophthalic acid, phthalic acid or naphthalene dicarboxylic acid; 14-cyclohexanedicarboxylic acid or a bicyclic ring An aliphatic dicarboxylic acid such as hexyl-4,4-dicarboxylic acid; or an alkali metal 5-sulfoisophthalate such as sodium 5-sulfoisophthalate or potassium 5-sulfoisophthalate . Among these, preferred are aliphatic dicarboxylic acids, aromatic dicarboxylic acids, and alkali metal salts of 5-sulfoisophthalic acid. More preferably, it is adipic acid, terephthalic acid, or sodium 5-sulfoisophthalate. When the polyamidene moiety forming monomer is subjected to ring-opening polymerization or polycondensation by a conventional method, the average degree of polymerization is preferably from 2 to 10, and more preferably, the average degree of polymerization is from 3 to 8. As a result, the polyamine moiety has a number average molecular weight of from 100 to 1,000, more preferably from 300 to 700. Further, the polyamine (a) having a carboxyl group at both ends is a component which imparts a polyamine moiety to both ends of a dicarboxylic acid component having 4 to 20 carbon atoms of a molecular weight modifier, and a polyamine moiety is provided at a single terminal. When a component or a mixture of a component which imparts a polyamine moiety at both ends and a component which imparts a polyamine moiety to a single terminal is a mixture, a component of the polyamine moiety is given to a single molar terminal, and both ends are imparted. The composition of the polyamine moiety is preferably 1 to 10 moles. More preferably, the component imparted to the single end with respect to 1 mole is composed of 3 to 8 moles. Therefore, the amount of the carboxyl group-containing component of the above polyamine moiety-forming monomer can be appropriately adjusted so as to have a carboxyl group at both terminals. If only indoleamine and/or an aminocarboxylic acid is used as the polyamine moiety-forming monomer, since the molecular weight modifier is a dicarboxylic acid component, a polyamine amine having a carboxyl group at both terminals can be easily produced (a) ) -59- 201009148. When a polycondensate of a dicarboxylic acid and a diamine is used as a polyamidene moiety-forming monomer, for example, a polyalkylamine having a carboxyl group at both terminals can be produced by a method such as a reaction for finally changing a dicarboxylic acid of a polymer (a). . The number average molecular weight of the polyamine (a) having a carboxyl group at both ends is usually from 500 to 5,000, preferably from 500 to 3,000. When the number average molecular weight is less than 50,000, the heat resistance of the polyether ester decylamine itself is lowered. On the other hand, when the reactivity exceeds 50,000, the polyether ester amide is required to be produced longer. . In order to make the number average molecular weight fall within the range, a dicarboxylic acid component having 4 to 20 carbon atoms may be selected as the molecular weight modifier, and the reaction conditions may be appropriately set in the polymerization of the polyamine moiety. Further, among the bisphenol-based ethylene oxide adducts (b), bisphenols are exemplified by bisphenol A (4,4'-dihydroxydiphenyl-2,2-propane) and bisphenol F (4). 4'-dihydroxydiphenylmethane), bisphenol S (4,4'-dihydroxydiphenyl) and 4,4'-dihydroxydiphenyl-2,2-butane. The preferred of these is bisphenol A. The bisphenol-based ethylene oxide adduct (b) is obtained by a method which is conventionally used for the addition of ethylene oxide to the bisphenols. Further, ethylene oxide and other alkylene oxides (propylene oxide, 1,2-butylene oxide, 1,4·butylene oxide, etc.) may be used, but other alkylene oxides are used in all amounts. The weight of ethylene oxide is generally 'normally below 10% by weight. Further, the above-mentioned adduct (b) corresponds to two hydroxyl groups of bisphenols, and it is preferred to polymerize ethylene oxide having an average of 20 to 70 mols and other alkylene oxides (hereinafter referred to as ethylene oxide). . More preferably, the polymerization has a condition of 32 to 60 moles of ethylene oxide or the like. That is, a hydroxyl group corresponding to bisphenol (addition-60-201009148) has 10 to 35 moles, preferably 16 to 30 moles, more preferably 16 to 20 moles of ethylene oxide, etc. Additives. The number average molecular weight of the above-mentioned adduct (b) is usually from 1,600 to 3,000, particularly preferably from 3 to 60 in terms of an ethylene oxide addition molar number of from 3 to 60. If the number average molecular weight is less than 1,600, the antistatic property is insufficient. On the other hand, when it exceeds 3,000, it takes a long time to manufacture the polyetheresteramine due to a decrease in reactivity. The number average molecular weight is preferably 1,800 to 2,400, and the addition molar number of the epoxy Φ ethane or the like is more preferably 32 to 40. When the number average molecular weight is within this range, the molecular weight of the bisphenol is considered, and it is achieved by adjusting the molar number of addition of ethylene oxide or the like. The above-mentioned adduct (b) is used in the range of 20 to 80% by weight based on the total weight of the above (a) and (b) in the polyetheresteramine. When the amount of the adduct (b) is less than 20% by weight, the antistatic property of the polyether ester decylamine is deteriorated, and on the other hand, when it exceeds 80% by weight, the heat resistance of the polyether ester decylamine is lowered. good. More preferably, the adduct (b) is used in the range of 40 to 70% by weight based on the total weight of the above (a) and (b φ ). The relative viscosity of the polyether ester guanamine used in the present invention is 1.5 to 3.5 (' 〇. 5 wt%, m-cresol solution, 25 ° C), preferably 2.0 to 3.0. If it is less than 1.5, since the difference in melt viscosity between the base polymer component (polyamide component and polyester component) during kneading is large, it tends to stay in the inside of the tube or in the spinning unit, and spinning for a long time is likely to cause abnormal discharge. The quality of the obtained composite fiber is unstable. On the other hand, if it exceeds 3.5, it will become a cause of yarn breakage during yarn production. The amount of the polyether ester decylamine added to the polyamide component is preferably -61 - 201009148. When added in a small amount, the hygroscopic elongation of the polyamide component is lowered, and the function of shrinking the moisture at the time of moisture absorption which is the object of the present invention and shrinking the length of the appearance yarn is impaired. The side-by-side type composite fiber may have any fineness, cross-sectional shape, or composite form, and the monofilament fineness is preferably about 1_5 to 5.0 dtex. Further, the area ratio of the cross section of the composite fiber of the polyamine component and the polyester component is preferably in the range of polyamine component/polyester component = 30/70 to 70/30, more preferably 40/60 to 60. The range of /40. In the woven fabric of the present invention, the fibers constituting the bottom structure portion are preferably polyester fibers. The polyester forming the polyester fiber is exemplified by terephthalic acid as a main acid component and an alkanediol having 2 to 6 carbon atoms, that is, selected from ethylene glycol, trimethylene glycol, and tetramethylene. The at least one diol of the group consisting of diol, pentamethylene glycol, and hexamethylene glycol is preferably a polyester obtained by using a glycol-based diol component. Further, a polyester, a chemical obtained by using a catalyst containing a titanium compound and a phosphorus compound, or a polyfluorene ester recovered from a raw material may be used as disclosed in the specification of International Publication No. WO2004/063435. Further, it may be an aliphatic polyester such as polylactic acid or a polyvalent lactic acid which is sterically misaligned. The above polyester polymer may have a small amount (usually 30 mol% or less) of a copolymerization component as needed. In this case, the difunctional carboxylic acid other than the terephthalic acid used may be, for example, isophthalic acid, naphthalene dicarboxylic acid, diphenyl dicarboxylic acid, diphenoxyethane dicarboxylic acid, β-hydroxyl group. Aromatic, aliphatic, alicyclic ring of ethoxybenzoic acid, p-oxybenzoic acid, 5-sodium sulfoisophthalic acid, adipic acid, sebacic acid, 1,4·cyclohexanedicarboxylic acid Difunctional of the family -62- 201009148 carboxylic acid. Further, the diol compound other than the above diol may be, for example, an aliphatic or alicyclic group such as cyclohexane 1,4- 1,4-methanol, neopentyl glycol, bisphenol A or bisphenol S. Compounds and polyalkylene oxides, and the like. The woven fabric of the present invention can be produced by, for example, the following manufacturing method. First, the above polyamine component and the polyester component are conjugated into a side-by-side type as a pile for fluff. In this case, for example, it is described that the high viscosity component side is separated from the discharge hole φ on the low viscosity component side, and the discharge speed on the high viscosity side is small (spit is discharged), for example, as described in JP-A-2000- 1 445 181. The spinning die having an increased area is obtained by passing the molten polyester through a high-viscosity side discharge hole and passing the molten polyamine to the side of the low-viscosity side discharge port and joining, and cooling and solidifying. Further, in the present invention, the spinning die at this time may be appropriately designed as a side-by-side hollow composite fiber. The so-called separate extension of the yarn obtained by spinning after stretching and then heat-treating as needed may also be carried out by so-called direct extension without temporarily stretching under the unstretched filament and then heat-treating as needed. The method in the way. The spinning speed in the spinning may be, for example, a spinning speed of about 1 000 to 3500 m/min. Further, in the case where the elongation and the heat treatment are set to be 1 to 60%, and usually about 20 to 45%, the elongation after stretching is preferable because of the curling property, the braidability, and the like. The yarns for the piles are preferably in the range of 1.5 to 5.0 dtex of the single yarn, 40 to 200 dtex of the total fineness, and 30 to 150 filaments. These pile yarns (composite fibers) have potential crimping properties and exhibit potential crimping properties when subjected to heat treatment under dyeing processing or the like as will be described later. Therefore, when moisture is absorbed, since the polyamide component is swollen and elongated, and the length of the poly-63-201009148 ester component hardly changes, the crimp ratio (the length of the crimped fiber A is shortened) can be improved. On the other hand, since the polyamide component shrinks during drying and the length of the polyester component hardly changes, the crimp ratio decreases (the appearance length of the crimped fiber A becomes long). Since the above-mentioned pile yarn for fluff is easily improved in moisture absorption at the time of moisture absorption, it is preferable to use a twisted yarn or a weak twist yarn of 300 T/m or less. In particular, it is preferred to have no silk. If it is strong silk, if the strong silk is given, the shrinkage rate during moisture absorption is not easy to improve. Further, even if the number of interlaces is about 20 to 60 /πι, the warp and weft interlaced air processing and/or the general false twist crimping may be performed. On the other hand, the yarn for the bottom structure portion can also, for example, melt-spin the above-mentioned polyester from a general spinning nozzle, and temporarily roll it into an unstretched yarn at a speed of 2000 to 4300 m/min (intermediate alignment yarn). ), and then extended, can also be extended before the take-up. Further, the intermediate alignment yarn may be heated to 180 to 20 (TC in a relaxed state (1.5 to 10% excess feed) by using a heater, thereby becoming an unstretched filament having self-extensibility under heating (intermediate alignment) In the yarn for the bottom structure portion, the fiber form is not particularly limited, and may be a long fiber or a short fiber. Among them, a long fiber (multifilament which is preferably made of no or weak) is exemplified. The bottom tissue portion may be subjected to false twist crimping processing, or Taslan processing or warp and weft interlacing processing, etc. There is no particular limitation on the total fineness, the single filament fineness, and the number of filaments of the yarn. However, in terms of texture, the total fineness is 30 to 400 dtex (more preferably 50 to 200 dtex), and the single fiber fineness is 5.5 to 5 dtex (more preferably 1 to 4 dtex) -64 to 201009148, and the number of filaments It is suitable for the range of 20 to 100. Next, the above-mentioned pile for the pile yarn and the bottom tissue portion are used to make a loop composed of a bottom structure portion and a loop pile portion having a woven structure or a braided structure. Fluff fabric. At this time, the weave structure is not limited, and is exemplified by, for example, velvet. Fabric, weft-wool fabric, sinker fluffy fabric, Lamuer weave, warp-dye-wool weave, etc. When forming the cut pile, the front end of the loop pile is cut by a shearing machine, etc. φ Next, The dyeing process is performed on the woven fabric, and the conjugate fiber contained in the bristles exhibits a potential crimping into a crimped fiber by the heat of the dyeing process. The temperature of the dyeing process is 100 to 140 ° C (better) It is preferably from 110 to 13 5 ° c), and the retention time of the highest temperature is preferably in the range of 5 to 40 minutes. Under these conditions, the composite fiber can be made of polyester by dyeing the fabric. The composition and the polyamide component have poor heat shrinkage and exhibit curling.

The fabric to be dyed is usually subjected to dry heat final setting. At this time, the final setting temperature of dry heat is 120~20 (TC (more preferably 140~180 °C • ), and the time is better in the range of 1-3 minutes. However, when the dry heat is finalized, the temperature is low. At 120 °C, it is easy to leave the creases generated during the dyeing process, and there is a problem that the dimensional stability of the finished product is poor. Conversely, when the final temperature of the dry heat is higher than 200 °C, the dyeing process is performed. The shrinkage of the composite fiber exhibited is reduced, and the fiber is hardened and the texture of the original fabric is hardened. When the absorbent fabric is subjected to water absorption processing, the crimping rate of the above-mentioned crimped fiber-65-201009148 dimension is easily increased. Further, it is preferable to use heat and pressure processing (calendering), water repellent processing, alkali reduction processing, raising processing, ultraviolet shielding or the like in the range which does not impair the main object of the present invention. An antibacterial agent, a deodorant, an insect repellent, a light storage agent, a retroreflector, an anion generator, etc., impart various functions to the function. Further, according to the present invention, the use of the above-mentioned rag fabric can be selected from the case of taking clothes and wool. Raw materials for garments, sweaters, outerwear, sportswear, linings, diapers, and quilts, etc.. Hygiene products, pyjamas, bedding, chairs or sofas, carpet materials, car seat materials, indoors A fibrous product of a group consisting of the above-mentioned fabrics, which have a reversible increase in the crimping rate of the crimped fibers at the time of moisture absorption, thereby reducing the height of the standing hair. The reduction in thickness reduces the heat retention of the fabric and reduces the heat sensation when sweating.

Hereinafter, the embodiments of the present invention related to the above 3 4 to 38 will be described in detail. G The three-layer structure fabric of the present invention is a three-layer structure fabric composed of a bottom structure of the front and back and a joint portion connecting the bottom and bottom of the watch, and the joint portion includes a crimped fiber having an increased crimp ratio at the time of moisture absorption. A. Since the crimping fiber A is contained in the joint portion, as shown in the pattern of Fig. 8, the curling rate of the crimped fiber A reversibly increases when the moisture is absorbed, so that the length of the joint portion becomes shorter. small. As a result, it is possible to reduce the heat sensation when sweating, and the crimped fibers A are preferably made of the crimped fibers satisfying the following requirements (1) and (2) 66 - 201009148. (1) The crimped fiber A is a composite fiber obtained by joining a polyester component and a polyamide component into a side-by-side type. (2) The crimp ratio HC of the crimped fiber A at the time of moisture absorption is curled during drying. The difference in the crimp ratio DC (HC-DC) of the fiber A is 0.5% or more (preferably 5% or more). In the case of drying, the sample is placed in a state of a temperature of 20 ° C and a humidity of φ 65% RH for 24 hours. On the other hand, when the moisture is absorbed, the sample is placed at a temperature of 20 ° C and humidity. The state after 24 hours in an environment of 90% RH. Wherein, when the difference between the crimping ratio HC of the crimped fiber A and the crimping ratio DC of the crimped fiber A during drying (HC-DC) is less than 0.5%, the moisture permeability of the fabric when moisture is absorbed Not lowering is not good. Further, the crimping ratio DC of the crimped fiber A during drying is preferably in the range of 50 to 80%. On the other hand, the crimping rate HC of the crimped fiber A during moisture absorption is preferably in the range of 60 to 90%. The crimped fiber A is preferably a composite fiber in which a polyester component and a polyamide component are joined together in a side-by-side manner, and is preferably a crimped structure having a crimping structure exhibiting a potential crimping property. fiber. That is, the above polyamine component is a polymer having a guanamine bond in the main chain, and examples thereof include, for example, nylon 4, nylon 6, nylon 12, nylon 46, and nylon 66. In particular, nylon 6 and nylon 66 are relatively sturdy in terms of cost, versatility, and yarn-making properties. Further, the polyamine components may be copolymerized with a component known as a base, or the polyamide components may contain titanium oxide or a pigment such as -67-201009148 carbonium, a known antioxidant, and an anti-oxidant. Electrostatic agent, light stabilizer, etc. On the other hand, the above polyester component preferably accounts for 60 to 99.5 mol% of the ethylene terephthalate unit in the repeating unit constituting the polyester, and the ethylene isophthalate unit accounts for 0.5 to 40 moles. % of the copolymerized polyester of the ear. Generally, the heat shrinkage of the polyester is lower than that of the polyamine, but the heat shrinkage of the polyester is brought close to the polyamine by using the copolymerized polyester as the polyester. As a result, in the crimping and bending structure at the time of drying, in the crimping and bending structure at the time of moisture absorption, it is easy to form a swelled polyamidamide component on the outer side and a polyester component on the inner side, and it is easy to increase the crimp ratio. Among them, when the unit of ethylene terephthalate is less than 60 mol%, the basic physical properties such as the strong elongation of the obtained composite fiber cannot be sufficiently maintained. When the ethylene terephthalate unit exceeds 99.5 mol% and the isophthalic acid ethylene diester does not reach 0.5 mol%, the crimping rate is not increased when the composite fiber absorbs moisture (the length of the crimped filament is not long) Shortening), there is a problem that a sufficient low thickness cannot be obtained as a cloth. When the ethylene isophthalate exceeds 40 mol%, the basic physical properties such as the strong elongation of the composite fiber cannot be maintained, and the thermal stability is also deteriorated, and the spinning port is molded due to the decomposable foreign matter in the spinning step. The filtration pressure (filling pressure) of the mouth portion is significantly increased. The polyesters may be produced by any method. For example, for example, polyethylene terephthalate is directly esterified with terephthalic acid and ethylene glycol to make dimethyl terephthalate. The terephthalic acid lower alkyl ester is directly esterified with ethylene glycol, or the terephthalic acid is reacted with ethylene oxide to produce a terephthalic acid glycol ester and/or its low polymer. Then, the product is heated under reduced pressure and polycondensed to a desired degree of polymerization to produce -68 - 201009148. Further, in addition to the terephthalic acid phthalate component constituting the polyester, The three components may also be copolymerized, preferably a dicarboxylic acid component or a diol component. The dicarboxylic acid component may, for example, be phthalic acid, naphthalene dicarboxylic acid, diphenyl dicarboxylic acid or diphenoxyethyl B. a difunctional aromatic dicarboxylic acid φ diacid of oxybenzoic acid, a difunctional aliphatic dicarboxylic acid of oxalic acid, and the like. Further, a part of the above diol component may also be exemplified by such diol components as, for example, cyclohexane-1,4-dibisphenol A, bisphenol S, 2,2-bis(4-β-hydroxyethoxy ( An aliphatic or alicyclic ring of 4-β-hydroxyethoxyphenyl)anthracene or 2,2-bis(ylethoxy)phenyl)propane. Further, in the above polyester, a small amount of the material may be used, and a chain branching agent such as pentaerythritol or tri-tristri-acid may be used in a small amount. In addition to the above, the general polyester of the present invention is also added with an anti-coloring agent such as titanium dioxide or carbon black. The polyester component preferably contains a polyether ester decylamine. When the polyether ester decylamine is present, the polyester component is soft, and when the amine component swells, the polyester component is easily followed, and the shrinkage ratio is improved. The polyether ester decylamine is preferably used in an amount of 5 to 55% by weight based on the weight of the polyester component. When the composite fiber absorbs moisture, the crimp ratio is not increased (the acid ethylene glycol component and the third component, any of the first ones. As for the dibromoterephthalic acid, the hospital dicarboxylic acid, such as β-hydroxyl Acid, such as azelaic acid, hexa-1,4-cyclohexanedicarboxylic acid diol component substitution, methanol, neopentyl glycol, phenyl) propane, bis 3,5-dibromo-4-( 2- The combination of a hydroxy group and an aromatic diol to melt other polymerized hydroxymethylpropane and a benzene-based polyester may of course be used as a conventional antioxidant. When the polyester component is contained in moisture absorption, it is easy to be used in the polymerization. When the amount of the ester component added during moisture absorption is less than 5% by weight, the appearance of the crimped fiber is difficult to be shortened from -69 to 201009148. When the fabric is used, a sufficient thickness reduction cannot be obtained. On the other hand, when it exceeds 55% by weight, there is a problem that the spinning cannot be stably performed. The polyether ester decylamine is preferably a poly phthalamide (3) having a number average molecular weight of 500 to 5,00 () and a number average molecular weight of 1,600 to 3,000. Derived from the alkane adduct (b). "Derivative" means the one obtained by reacting two components, or the one obtained by copolymerization. The polyamine (a) having a carboxyl group at both terminals is preferably composed of a polyamidene moiety and a molecular weight modifier. The polyamine moiety is composed of at least one of (1) an indoleamine ring-opening polymer, (2) a polycondensate of an aminocarboxylic acid, or (3) a polycondensate of a dicarboxylic acid and a diamine. Among these, the guanamine in (1) is exemplified by butane decylamine, valeroinamide, caprolactam, heptanoin, dodecane decylamine, undecyl decylamine and the like. The aminocarboxylic acid of (2) is exemplified by ω-aminohexanoic acid, ω-amino heptanoic acid, ω-aminooctanoic acid, ω-amino decanoic acid, 11-aminoundecanoic acid, and 12-amino group. Dodecanoic acid, etc. The (3) dicarboxylic acid is exemplified by adipic acid, sebacic acid, sebacic acid, undecanedioic acid, dodecane dibasic acid, isophthalic acid and the like. Further, the diamine of (3) is exemplified by tetramethylene diamine, pentamethylene diamine, hexamethylene diamine, heptamethylene diamine, octa Methylene diamine, and decamethylene di Amines, etc. The above-mentioned indoleamine, aminocarboxylic acid, dicarboxylic acid, and diamine are collectively referred to as a polyamidene moiety-forming monomer. The above-mentioned polyamine moiety-forming monomer which is a polyamine (a) having a carboxyl group at both terminals may be exemplified by two or more types. Preferred among these are caprolactam '12-aminododecanoic acid and adipic acid-hexamethylenediamine, and the most preferred is caprolactam. -70- 201009148 The above-mentioned polyamine (a) having a carboxyl group at both ends is further used as a molecular weight modifier using a carbon number 4 to 20 dicarboxylic acid component, and in the presence of the above, the above polycondensation is carried out by a conventional method. The amine moiety-forming monomer is obtained by ring-opening polymerization or polycondensation. Examples of the dicarboxylic acid having 4 to 20 carbon atoms are succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid 'sebacic acid, sebacic acid, undecanedioic acid, or dodecane di Fatty acid dicarboxylic acid; aromatic dicarboxylic acid such as terephthalic acid, isophthalic acid, phthalic acid or naphthalene dicarboxylic acid; 1,4-cycloφ hexane dicarboxylic acid or dicyclohexyl An aliphatic dicarboxylic acid such as a 4,4-dicarboxylic acid; or an alkali metal 5-sulfoisophthalate such as sodium 5-sulfoisophthalate or potassium 5-sulfoisophthalate. Among these, preferred are aliphatic dicarboxylic acids, aromatic dicarboxylic acids, and alkali metal salts of 5-sulfoisophthalic acid. More preferably, it is adipic acid, terephthalic acid, or sodium 5-sulfoisophthalate. When the polyamidene moiety-forming monomer is subjected to ring-opening polymerization or polycondensation by a conventional method, the average degree of polymerization is preferably from 2 to 10, more preferably from 3 to 8. As a result, the number average molecular weight of the polyamine moiety is φ 1 00-1,000 » more preferably 30,000-700. Further, the polyamine (a) having a carboxyl group at both ends is a component which imparts a polyamine moiety at both ends of a dicarboxylic acid component having a carbon number of 4 to 20 of a molecular weight modifier, and a polyamine is provided at a single terminal. A portion of the component may also be a mixture of a component that imparts a polyamine moiety at both ends and a component that imparts a polyamine moiety to the single terminal. In the case of a mixture, it is preferable that the component which imparts the polyamine moiety to the monomolecular terminal at one end and the component of the polyamic acid moiety at both ends becomes 1 to 10 moles. More preferably, it is a component imparted to a single end of 1 mole, and the components imparted at both ends are 3 to 8 moles. Therefore, the amount of the carboxyl group-containing component of the above polyamine moiety-forming monomer can be adjusted to have a carboxyl group at both ends, as appropriate -71 - 201009148. If only indoleamine and/or an aminocarboxylic acid is used as the polyamine moiety-forming monomer, since the molecular weight modifier is a dicarboxylic acid component, a polyamine amine having a carboxyl group at both terminals can be easily produced (a) ). When a polycondensate of a dicarboxylic acid and a diamine is used as a polyimylamine moiety, a polyamine which has a carboxyl group at both terminals can be produced by a method such as a reaction for finally changing a dicarboxylic acid of a polymer. ). The number average molecular weight @ of the polyamine (a) having a carboxyl group at both ends is usually from 50 to 5,000, preferably from 500 to 3,000. When the number average molecular weight is less than 500, the heat resistance of the polyether ester decylamine itself is lowered. On the other hand, when the reactivity exceeds 5,000, the polyether ester amide is required to be produced for a longer period of time due to a decrease in reactivity. In order to make the number average molecular weight fall within the range, a dicarboxylic acid component having 4 to 20 carbon atoms may be selected as the molecular weight modifier, and the reaction conditions may be appropriately set in the polymerization of the polyamine moiety. Further, among the bisphenol-based ethylene oxide adducts (b), bisphenols are exemplified by bisphenol A (4,4'-dihydroxydiphenyl-2,2-propane) and bisphenol F (〇) 4,4'-dihydroxydiphenylmethane), bisphenol S (4,4'-dihydroxydiphenyl maple), and 4,4'-dihydroxydiphenyl-2,2-butane. The preferred of these is bis-A. The above bisphenol-based ethylene oxide adduct (b) is obtained by a method of adding ethylene oxide to the bisphenols. Further, ethylene oxide and other alkylene oxides (propylene oxide, 1,2-butylene oxide, 1,4-butylene oxide, etc.) may be used in combination, but other alkylene oxides are used in all rings. The weight of oxyethane is normal, and is usually 10% by weight or less. -72- 201009148 Further, the above adduct (b) corresponds to two hydroxyl groups of bisphenols, and has an average of 2 to 70 moles of ethylene oxide and other alkylene oxides (hereinafter referred to as rings, oxygen B). The situation in hospitals, etc.) is better. More preferably, the polymerization has a condition of 32 to 60 moles of ethylene oxide or the like. That is, an hydroxy polymerization (addition) corresponding to bisphenol has an adduct of 10 to 35 moles, preferably 16 to 30 moles, more preferably 16 to 20 moles of oxygen. The number average molecular weight of the above-mentioned adduct (b) is usually 1,600 to 3,000 φ', and it is particularly preferable to use an ethylene oxide addition molar number of 32 to 60. If the average molecular weight is less than 1,600, the antistatic property is insufficient. On the other hand, when it exceeds 3,000, it takes a long time to manufacture the polyetheresteramine due to a decrease in reactivity. The number average molecular weight is preferably from 1,800 to 2,400, and the addition molar number of ethylene oxide or the like is more preferably from 32 to 40. When the number average molecular weight is within this range, the molecular weight of the bisphenol is considered, and it is achieved by adjusting the molar number of addition of ethylene oxide or the like. The above adduct (b) is used in the range of 20 to 80% by weight based on the total weight of the above (a) and (b • ) in the polyetheresteramine. If the amount of the addition compound (b) is less than 20% by weight, the antistatic property of the polyether ester decylamine is deteriorated. On the other hand, when it exceeds 80% by weight, the heat resistance of the polyether ester decylamine is high. Reduced poorly. More preferably, the adduct (b) is used in the range of 40 to 70% by weight based on the total weight of the above (a) and (b). The relative viscosity of the polyether ester guanamine used in the present invention is 1.5 to 3.5 (0.5% by weight, m-cresol solution, 25 ° C), preferably 2.0 to 3.0. If it is less than 1.5, the difference in melt viscosity between the base polymer component (polyamide component and polyester component) during mixing is easy to stay in the conduit or in the spinning-73-201009148 wire assembly, and the spinning is performed for a long time. It is easy to cause abnormal discharge and the quality of the obtained composite fiber is unstable. On the other hand, if it exceeds 3.5, it will become a cause of yarn breakage during yarn production. The polyether ester decylamine is preferably added to the polyamine component in an amount of 0% by weight. When added in a small amount, the hygroscopic elongation of the polyamide component is lowered, and the function of the present invention is to shrink and to shrink the length of the appearance yarn. The side-by-side type composite fiber may have any fineness, cross-sectional shape, or composite 0 form, and the single-filament fineness is preferably about 1.5 to 5.0 dtex. Further, the area ratio of the cross-section of the composite fiber of the polyamide component and the polyester component is preferably in the range of polyamine component/polyester component = 30/70 to 70/30, more preferably 40/60-60/ The range of 40. In the woven fabric of the present invention, the fibers constituting the bottom structure portion are preferably polyester fibers. The polyester forming the polyester fiber is exemplified by terephthalic acid as a main acid component and an alkanediol having 2 to 6 carbon atoms, that is, selected from ethylene glycol, trimethylene glycol, and tetramethylene. The at least one diol of the group consisting of diol, pentamethylene glycol, and hexamethylene glycol is preferably a polyester composed of a glycol-based diol component. Further, a polyester, a chemical or a material-recovered polyester obtained by using a catalyst containing a titanium compound and a phosphorus compound may be used as disclosed in the specification of International Publication No. 4/063435. Further, it may be an aliphatic lactic acid such as polylactic acid or a polyvalent lactic acid which is sterically misaligned. The above polyester polymer may have a small amount (usually 30 mol% or less) of a copolymerization component as needed. In this case, the functional residual acid other than terephthalic acid-74-201009148 may be, for example, isophthalic acid, naphthalene dicarboxylic acid, diphenyl dicarboxylic acid, diphenoxyethane dicarboxylic acid, β-Hydroxyethoxybenzoic acid, p-oxybenzoic acid, 5-sodium sulfoisophthalic acid, adipic acid, sebacic acid, aromatics of 1,4-cyclohexanedicarboxylic acid, fat Family, alicyclic difunctional. carboxylic acid. Further, the diol compound other than the above diol may be an aliphatic, alicyclic or aromatic diol compound such as cyclohexane 1,4- 1,4-methanol, neopentyl glycol, bisphenol a or bisphenol s. And polyalkylene oxide and the like. Φ The three-layer construction fabric of the present invention can be produced by the following manufacturing method. First, the above polyamine component and the polyester component are conjugated into a side-by-side type as a yarn for a joint portion. In this case, for example, as described in JP-A-2000-144518, the high-viscosity component side is separated from the discharge hole on the low-viscosity component side, and the discharge speed on the high-viscosity side is small (the discharge area is increased). The spinning nozzle is obtained by passing the molten polyester through a high-viscosity side discharge hole and passing the molten polyamine to the side of the low-viscosity side discharge port and joining, and cooling and solidifying. Further, in the present invention, the spun φ wire nozzle can be appropriately designed as a parallel type hollow composite fiber. The yarn obtained by spinning 'in addition to the so-called 'different extension method', which is extended after being temporarily taken up and then heat-treated as needed, may be used without temporarily taking up the unstretched filament and then heat-treating as needed. The method in the direct extension mode. The spinning speed in the above spinning can be, for example, a spinning speed of about 1 to 3,500 m/min which is usually used. Further, the elongation and heat treatment are set so that the elongation at break after stretching is from 1 〇 to 60%, usually from 20 to 45 °/. Under the left and right conditions, it is preferable because of the performance of curling, the weaving property, and the like. The connecting portions are preferably in the range of a single yarn fineness of 5 to 5.0 dtex, a total fineness of -75 to 201009148, 40 to 200 dtex, and a number of filaments of 30 to 150. The yarns (composite fibers) of the joint portions have potential crimping properties, and exhibit potential caulking properties when subjected to heat treatment under dyeing processing or the like as will be described later. Therefore, when moisture absorption, since the polyamide component is swollen and stretched, and the length of the polyester component hardly changes, the crimp ratio (winding. The appearance length of the fiber A is shortened) can be improved. On the other hand, since the polyamide component shrinks during drying and the length of the polyester component hardly changes, the crimp ratio decreases (the appearance length of the crimped fiber A becomes long). @ The above-mentioned connecting portion is preferably used for the moisture absorption at the time of moisture absorption. Therefore, it is preferable to use a non-twisted yarn or a weak twisted yarn of 3 OOT/m or less. In particular, it is preferred to have no silk. If it is strong silk, if the strong silk is given, the shrinkage rate during moisture absorption is not easy to improve. Further, even if the number of interlaces is about 20 to 60 pieces/m, the warp and weft interlacing air processing and/or the general false twisting processing may be performed. On the other hand, the bottom structure portion can also be melt-spun, for example, from the general spinning nozzle of the polyester, and temporarily rolled into an unstretched yarn (intermediate alignment yarn) at a speed of 2000 to 4300 m/min. , after extension, can also be extended before the take-up. Alternatively, the intermediate alignment yarn may be heated to -180 to 200 ° C using a heater, and heat-treated in a relaxed state (1.5 to 10% of excess feed) to become an unstretched filament having self-extensibility under heating (intermediate alignment) Silk) In the yarn for the bottom structure portion, the fiber form is not particularly limited, and may be a long fiber or a short fiber. Among them, long fibers (multifilaments) which are preferably innocent or weakly entangled are exemplified. The bottom tissue portion can also be used for the fake -76-

201009148 捻 crimping processing, or Taslan processing or warp and weft processing, etc. The total fineness, monofilament fineness, and number of filaments of the yarn are not particularly limited, and the total fineness is 30 to 400 dtex (50 ~200 dtex), the single-filament fineness is 0.5 to 5 dtex (more preferably 1~, and the number of filaments is 20 to 100). Next, the above-mentioned joint portion is knitted with three layers for the yarn and the bottom portion. The fabric is constructed. At this time, the weave structure is not limited to the third layer of the surface layer and the inner layer by the bonding wire (the yarn for the joint portion) of Fig. 2 of the Japanese Patent Publication No. 2002-235264. The layered woven fabric is preferably a cardboard-like three-dimensional fabric as described in Japanese Laid-Open Patent Publication No. 2004-183128. Next, the three-layered fabric is dyed and processed by the heat of the processing. The composite fiber comprises a latent crimped fiber, wherein the temperature of the dyeing process is 100 to 140 ° C (110 to 135 ° C), and the time is maintained at a maximum temperature in the range of 5 to 40. Under the condition, by dyeing the fabric to the above composite Vico exhibits crimping by the heat of the polyester component and the polyamide component. The three-layer fabric of the dyeing process is usually dry-type. At this time, the final setting temperature of dry heat is 120~200 °C. (140~180°C), the time is better in the range of 1~3 minutes. When the temperature of the final setting of the heat is lower than 120°C, the crease of the dyeing force I is easily left, and there will be finished products. Poor dimensional stability 5 丨 processing. 丨, but better for 4dtex) 丝, 丨, for example, as described in: pleated • reported by dyeing: shrinking into better minutes, processing, shrinkage The final decision is better, when the work is a problem. -77- 201009148 Conversely, when the temperature of final heat setting is higher than 20 (TC, the shrinkage of the composite fiber exhibited during dyeing processing is reduced, and the fiber is hardened and the texture of the original fabric is hardened. When the construction fabric is subjected to water absorbing processing, it is preferable to increase the crimp ratio of the crimped fiber at the time of moisture absorption, and it is also possible to additionally apply heat and pressure processing within a range not impairing the main object of the present invention. Emulsion processing, water treatment, conventional method of alkali reduction processing, raising processing, ultraviolet shielding or antibacterial agent, deodorant, insect repellent, light storage agent, retroreflective agent, negative ion generator, etc. Further, according to the present invention, the above-mentioned three-layer structure fabric can be used to provide medical care and hygiene selected from the group consisting of disposable clothing materials, wool sanitary garments, sweaters, outer garment materials, sports clothing materials, lining materials, diapers, and care sheets. a fibrous product of a group of materials such as supplies, pajamas, bedding, chairs or sofas, carpets, car seat materials, and interior products. Since the three-layer structure fabric described above is contained, the shrinkage ratio of the crimped fibers is reversibly increased during moisture absorption, so that the length of the joint portion is reduced. As a result, the heat retention of the fabric is lowered due to the decrease in the thickness of the fabric. The effect of reducing the heat sensation when sweating is achieved. Hereinafter, the embodiment of the present invention related to the above 39 to 44 will be described in detail. The fabric of the present invention must have a crimped fiber A having a higher crimp ratio at the time of wetting (hereinafter It is simply referred to as "coiled fiber a" or "fiber A") and has a crimped fiber B (hereinafter sometimes referred to as "fiber B") which is not curled or wet when it is not wet. 201009148 When sweating or raining, the crimping fiber A contained in the fabric is shortened due to an increase in the amount of shrinkage. As a result, the thickness of the fabric is reduced. • At this time, the fabric can be dried. The thickness (TD) at the time and the thickness (TW) at the time of wetting, the rate of change of the thickness is calculated by the following formula, and it is important that the degree of change of the thickness is 5% or more (preferably 10 to 100%). When the thickness change rate difference is less than 5%, Method of making fabric thickness sufficiently reduced moisture absorption and poor.

Thickness change rate (%) = ((TD-TW) / TD) xlOO where the thickness during drying is the thickness of the cloth after the cloth is placed in a temperature of 20 ° C and a humidity of 65% RH for 24 hours. On the other hand, the thickness at the time of moisture absorption is the thickness of the cloth in a state where the cloth is placed in a temperature of 20 ° C and a humidity of 90% RH for 24 hours. Further, the thickness is the distance φ from the highest portion to the lowest portion of the cloth shown in Fig. 12. In addition, the thickness can be measured using an ultra-high precision laser displacement gauge (Model LC-2400 manufactured by KEYENCE Corporation). In addition, in the present invention, "the increase in the crimp ratio at the time of moisture absorption" is 0.5% or more in the difference between the crimp ratio HC at the time of wetting and the crimp ratio DC at the time of drying (HC-DC). In the case of drying, the cloth is placed in a state of temperature 2 〇 ° C, humidity 65% RH for 24 hours. On the other hand, when the moisture is absorbed, the cloth is placed at a temperature of 20 ° C and a humidity of 90% RH. The state after 24 hours in the environment. In the present invention, the crimped fiber A is not particularly limited as long as it is a fiber having a high crimp ratio at the time of moisture absorption, but a composite fiber obtained by joining a polyester component and a polyamide component into a side-by-side type. It is preferred that the crimped fiber having a crimped configuration exhibiting a potential crimping property. In the above, the polyamine component is a polymer having a guanamine bond in the main chain, and examples thereof include, for example, nylon 4, nylon 6, nylon 12, nylon 46, and nylon 66. In particular, it is preferable that Nie. Dragon 6 and Nylon 66 are preferable from the viewpoints of cost, versatility, and yarn-making property. Further, the polyamine components may be copolymerized with a conventional component, or may contain a pigment such as oxidized titanium or carbon black, a conventional antioxidant, an antistatic agent, or the like. Light stabilizer, etc. On the other hand, the above polyester component preferably comprises 60 to 99.5 mol% of the ethylene terephthalate unit in the repeating unit constituting the polyester and 0.5 to 40 mol of the ethylene isophthalate unit. % of a copolymerized polyester. Generally, the heat shrinkage of the polyester is lower than that of the polyamine, but the heat shrinkage of the polyester can be brought close to the polyamine by using the copolymerized polyester as the polyester. As a result, in the crimped and bent structure at the time of moisture absorption, the swelled polyamine component is likely to be located outside, and the polyester component is located inside, and the crimp ratio is easily increased. Among them, when the unit of ethylene terephthalate is less than 60 mol%, it is not preferable because the basic physical properties of the strong elongation of the obtained conjugate fiber cannot be sufficiently maintained. When the ethylene terephthalate unit exceeds 99.5 mol% and the isophthalic acid ethylene diester does not reach 0.5 mol%, the crimping rate of the composite fiber does not increase when it absorbs moisture (the length of the crimped filament) The thickness of the fabric is not sufficiently reduced when there is moisture absorption. When the ethylene isophthalate exceeds 40 mol%, the basic physical properties such as the strong elongation of the composite fiber cannot be maintained, and the thermal stability is also deteriorated, and the spinning is performed due to the decomposable foreign matter in the spinning step-80-201009148 The filtration pressure (charge pressure) of the wire nozzle portion is significantly increased. The polyesters may be produced by any method, for example, if polyethylene terephthalate is described, in order to directly esterify terephthalic acid with ethylene glycol, such as methyl terephthalate. The ester of terephthalic acid lower alkyl ester is directly esterified with ethylene glycol, or terephthalic acid is reacted with ethylene oxide to form a terephthalic acid glycol ester and/or its low polymer. Then, by heating the product under reduced pressure and polycondensing to a desired degree of polymerization, the polyester comprises ethylene terephthalate component and ethylene isophthalate component. The third component may be copolymerized, and the third component is preferably any of a dicarboxylic acid component or a diol component. As the dicarboxylic acid component, for example, phthalic acid, dibromoterephthalic acid, naphthalene dicarboxylic acid, diphenyldicarboxylic acid, diphenoxyethane dicarboxylic acid, such as β-hydroxyl B can be exemplified. A difunctional aromatic dicarboxylic acid of oxybenzoic acid, such as a dicarboxylic aliphatic dicarboxylic acid such as azelaic acid, adipic acid or oxalic acid, or 14-cyclohexanedicarboxylic acid. Further, a part of the above diol component may be substituted by other diol components, such as, for example, cyclohexane-1,4-dimethanol, neopentyl alcohol, bisphenol A, bisphenol S, 2 , 2-bis(4-β-hydroxyethoxyphenyl)propane, bis(4-β-hydroxyethoxyphenyl)anthracene, 2,2-bis(3,5-dibromo-4-( 2 - an alicyclic, alicyclic or aromatic diol of ethoxypropyl)phenyl). Further, in the above polyester, a small amount of the other polymer may be blended as needed, and a chain branching agent such as pentaerythritol, trimethylolpropane or trimellitic acid may be used in a small amount. In addition, the polyester of the present invention is of course also added with a pigment such as titanium oxide or carbon black in the same manner as a general polyester, and is known as an antioxidant-81-201009148 agent and an anti-tarnishing agent. The polyester component preferably contains a polyether ester decylamine. When the polyester component contains a polyether ester decylamine, the polyester component becomes soft, and when moisture absorbing, the polyester component is easily followed when the polyamine component is swollen, and the crimp ratio at the time of moisture absorption is apt to increase. Preferably. The polyether ester decylamine is preferably added to the polyester component in an amount of 5 to 55% by weight based on the weight of the polyester component. If it is less than 5% by weight, the crimping rate of the composite fiber is not increased when the composite fiber absorbs moisture (the length of the crimped fiber is difficult to be shortened), and the thickness of the fabric when moisture is absorbed may not be sufficiently reduced. @ In addition, when it exceeds 55% by weight, there is a case where the spinning cannot be stabilized. The polyether ester decylamine is preferably an ethylene oxide adduct of a bisphenol having a number average molecular weight of 500 to 5,000 having a carboxyl group at both terminals (a) and a bisphenol having a number average molecular weight of 1,600 to 3,000 ( b) derived. "Derivative" means the one obtained by reacting two components, or the one obtained by copolymerization. The polyamine (a) having a carboxyl group at both terminals is preferably composed of a polyamine moiety and a molecular weight modifier. The polyamine moiety is composed of at least one of (1) an indoleamine ring-opening polymer, (2) a polycondensate of an aminocarboxylic acid, or (3) a polycondensate of a bismuth dicarboxylate and a diamine. In the composition, the indoleamine of (1) ' is exemplified by butane decylamine, valeroinamine, caprolactam, heptane oxime, dodecane decylamine, undecyl decylamine. Wait. The aminocarboxylic acid of (2) is exemplified by ω-aminohexanoic acid 'ω-amino heptanoic acid, ω-aminooctanoic acid, ω·amino decanoic acid, 11-aminoundecanoic acid, 12-amino group Dodecanoic acid, etc. The (3) bis-carboxylic acid is exemplified by adipic acid, sebacic acid, sebacic acid, undecanedioic acid, dodecanedioic acid, isophthalic acid and the like. Further, the diamine of (3) is exemplified by tetramethylene diamine, pentamethylene diamine, hexamethylene diamine, heptamethylene diamine, VIII-82 - 201009148 methyl diamine, ten ya Methyl diamine and the like. The above-mentioned indoleamine, aminocarboxylic acid 'dicarboxylic acid, and diamine are generally referred to as a polyamine moiety-forming monomer." The above-mentioned polyamine derivative having a carboxyl group at both terminals has a partial formability. The monomer can also be used in two or more forms. The preferred ones are caprolactam, 12-aminododecanoic acid and adipic acid-hexamethylenediamine, the most preferred being caprolactam. The polyamidamine (a) having a carboxyl group at both ends is further used as a molecular weight modifier using a dicarboxylic acid component having a carbon number of φ 4 to 20, and the polyformamide moiety is formed by a conventional method in the presence of the above. The monomers are obtained by ring opening polymerization or polycondensation. Examples of the dicarboxylic acid having 4 to 20 carbon atoms are succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedioic acid, or dodecanedioic acid. An aliphatic dicarboxylic acid; an aromatic dicarboxylic acid such as terephthalic acid, isophthalic acid, phthalic acid or naphthalene dicarboxylic acid; 1,4-cyclohexanedicarboxylic acid or dicyclohexyl-4 An aliphatic dicarboxylic acid such as a 4-dicarboxylic acid; or a sodium 5-sulfoisophthalate or a potassium 5-sulfoisophthalate; 5. sulfo- benzene: an alkali metal formate or the like. Among these, preferred are aliphatic dicarboxylic acids, • aromatic dicarboxylic acids, and alkali metal salts of 5-sulfoisophthalic acid. Better for yourself • Acid, terephthalic acid, sodium 5-sulfoisophthalate. When the polyamidene moiety forming monomer is subjected to ring-opening polymerization or polycondensation by a conventional method, the average degree of polymerization is preferably from 2 to 10, and the average degree of polymerization is from 3 to 8. As a result, the polyamine moiety has a number average molecular weight of from 100 to 1,000, more preferably from 300 to 700. Further, the polyamine (a) having a carboxyl group at both ends thereof is a component of the polyamine moiety-83-201009148 at both ends of the dicarboxylic acid component having a carbon number of 4 to 20 of the molecular weight modifier. The component of the polyamine moiety may also be a mixture of a component that imparts a polyamine moiety at both ends and a component that imparts a polyamine moiety to the single terminal. In the case of a mixture, the component which gives the polyamine moiety to the single molar terminal is preferably a component having a polyamine moiety at both ends which is 1 to 1 Torr. More preferably, it is a component imparted to a single end of 1 mole, and the components imparted at both ends are 3 to 8 moles. Therefore, the amount of the carboxyl group-containing component of the above polyamine moiety-forming monomer can be appropriately adjusted so as to have a carboxyl group at both terminals. If only indoleamine and/or aminocarboxylic acid is used as the para-indenic acid moiety-forming monomer, since the molecular weight modifier is a dicarboxylic acid component, a polyamine amine having a carboxyl group at both terminals can be easily produced ( a). When a polycondensate of a dicarboxylic acid and a diamine is used as a polyamidene moiety-forming monomer, for example, a polyalkylamine having a carboxyl group at both terminals can be produced by a method such as a reaction for finally changing a dicarboxylic acid of a polymer (a). . The number average molecular weight of the polyamine (a) having a carboxyl group at both ends is usually from 500 to 5,000, preferably from 500 to 3,000. When the number average molecular weight is less than 500, the heat resistance of the polyether ester decylamine itself is lowered. On the other hand, when 〇 exceeds 5,000, the reactivity is lowered, so that the polyether ester decylamine takes a longer time to manufacture. In order to make the number average molecular weight fall within the range, a dicarboxylic acid component having a carbon number of 4 to 20 may be selected as the molecular weight modifier, and the reaction conditions may be appropriately set in the polymerization of the polyamine moiety. Further, among the bisphenol-based ethylene oxide adducts (b), the bisphenols are exemplified by bisphenol A (4,4'-dihydroxydiphenyl-2,2·propane) and bisphenol F (4). 4'-dihydroxydiphenylmethane), bisphenol S (4,4'-dihydroxydiphenyl) and 4,4'-dihydroxydiphenyl-2,2-butane. The preferred of these is bis-84-201009148 phenol A. The bisphenol-based ethylene oxide adduct (b) is obtained by a method of adding ethylene oxide to the bisphenols. In addition, ethylene oxide and other alkylene oxides (propylene oxide, 1,2-epoxybutylene, 1,4-butylene oxide, etc.) may be used, but other alkylene oxides are used in all amounts. The weight of the ethylene oxide is normal, and is usually 10% by weight or less. Further, the adduct (b) corresponds to two hydroxyl groups of a bisphenol, and the polymerization φ has an average of 20 to 70 mole of ethylene oxide and another alkylene oxide (hereinafter referred to as ethylene oxide). The situation is better. More preferably, the polymerization has a condition of 3 2 to 60 moles of ethylene oxide or the like. That is, an hydroxy group (addition) corresponding to bisphenol has an adduct of 10 to 35 moles, preferably 16 to 30 moles, more preferably 16 to 20 moles of ethylene oxide. The number average molecular weight of the above adduct (b) is usually from 1,600 to 3,000, and particularly preferably from 32 to 60 by using an ethylene oxide addition molar number. If the average molecular weight is less than 1,600, the antistatic property is insufficient. On the other hand, when Φ exceeds 3, the reactivity of the polyether ester decylamine takes a long time due to a decrease in reactivity. The number average molecular weight is preferably from 1,800 to 2,400, and the addition molar number of the epoxy * ethane or the like is more preferably from 32 to 40. The number average molecular weight is within this range. The molecular weight of the bisphenol can be considered by adjusting the molar number of addition of ethylene oxide or the like. The above-mentioned adduct (b) is used in the range of 20 to 80% by weight based on the total weight of the above (a) and (b) in the polyether ester amine. If the amount of the adduct (b) is less than 20% by weight, the antistatic property of the polyether ester decylamine is deteriorated. On the other hand, when it exceeds 80% by weight, the polyether ester decylamine is resistant to -85- 201009148 The heat is not good enough. More preferably, the adduct (b) is used in the range of 40 to 70% by weight based on the total weight of the above (a) and (b). The relative viscosity of the polyether ester guanamine used in the present invention is 1.5 to 3.5 (0.5% by weight, m-cresol solution, 25 ° C), preferably 2.0 to 3.0. If it is less than 1.5, since the difference in melt viscosity between the base polymer component (polyamide component and polyester component) during kneading is large, it tends to stay in the inside of the catheter or in the spinning unit, and spinning for a long time is likely to cause discharge. Abnormality makes the quality of the obtained composite fiber unstable. On the other hand, if it exceeds the range of 3.5, it will be the cause of the broken yarn when the yarn is twisted. The polyether ester decylamine is preferably added to the polyamine component in an amount of 0% by weight. When added in a small amount, the hygroscopic elongation of the polyamide component is lowered, and the function of shrinking the moisture at the time of moisture absorption which is the object of the present invention and shrinking the length of the appearance yarn is impaired. The side-by-side type composite fiber may have any fineness, cross-sectional shape, or composite form, and the single-filament fineness is preferably about 1.5 to 5.0 dtex. Further, when the conjugate fiber of the present invention is made into a hollow conjugate fiber, the sensitivity to humidity is increased and the bulkiness is also increased. Further, the area ratio of the cross-section of the composite fiber of the polyamide component and the polyester component is preferably in the range of the polyamine component/polyester component 1 = 30/70 to 70/30, more preferably 40/60. The range of 60/40. When the conjugate fiber is a multifilament of a plurality of filaments, the total fineness of the multifilament is not particularly limited, but it can be used in the range of 40 to 200 dtex as a material for general clothing. Moreover, the interlacing process can also be performed as needed. The above composite fiber has a potential crimping property, and as described later, exhibits a potential crimping property upon heat treatment such as dyeing processing of -86-201009148. Therefore, the moisture absorption of the polyamide component swells and elongates, and the polyester component hardly causes the formation, so that the crimp ratio is increased (the length of the appearance of the crimped fiber A is shortened, on the one hand, the polyamine component shrinks during drying, and the polycondensation The ester component has a slight change in the degree of growth, so that the crimp ratio is lowered (the length of the crimped fiber A becomes longer). The above-mentioned crimped fiber A is easy to pick up due to the crimping rate when moisture is absorbed. The weak silk of the silk below OOT/m is better, and it is better to have no silk. For example, if strong silk is applied, if the strong twist is given, the suction shrinkage rate is not easily improved, and even if the number of interlacing is It is also possible to carry out the warp and weft interlacing air processing and/or the crimping process in a manner of about /m. On the other hand, the fiber B having no change in the crimping rate during non-coiling or moisture absorption is not a non-crimped fiber or There is no particular limitation on the fiber which has no change in the crimp ratio during moisture absorption. Here, the "change in the roll Φ during moisture absorption" is the difference between the crimp ratio HC at the time of moisture absorption and the DC ratio at the time of drying DC) 〇. 5 %. 'The fiber B is polyethylene terephthalate, polyparaphenylene terephthalate, polybutylene terephthalate and other polyesters, nylon 6, f and other polyamines, polyethylene, polypropylene, etc. Fibers suitable for clothing such as polyolefin, acrylic acid, p-phthalamide, and such modified synthetic fibers, natural fibers, vitamins, semi-synthetic fibers, polyurethane elastic yarns, polyether ester yarns, etc. Free to choose. Among them, the dimensional stability or the compatibility with the above-mentioned crimped fiber A (when the fiber is mixed, the length is changed). The length of the production is not high, because of the length. Especially in the case of wet 20-60, there is a shrinkage of the shrinkage rate. (HC-dicarboxylic acid g-66 or inter-regenerated fiber elastic wetness, cross-87-201009148 ed. interlacing, dyeability In terms of polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, or the copolymerization of the above copolymerized components Polyester fibers composed of polyester are preferred. Further, the single yarn fineness and the number of filaments (the number of filaments) of the fiber B are not particularly limited, but the water absorption property of the fabric is improved, and the unevenness property at the time of moisture absorption is exhibited, and the single yarn fineness is 0, l~ 5dtex (better 〇5~2dtex), preferably 20 to 200 filaments (more preferably 30 to 100). In particular, it is possible to interlace air processing with a warp and weft of about 20 to 60/m or so and to perform general false twist crimping. The fabric of the present invention contains the crimped fiber A having an improved crimp ratio at the time of moisture absorption and the crimped fiber B having no change in the crimp ratio at the time of non-crimping or moisture absorption. The structure of the fabric, the weaving organization and the number of layers are not particularly limited. For example, it is preferably woven as a plain weave, a woven weave, a satin weave, or a jersey structure, a double rib, a circular rib, a tuck mesh, a woven weave, a warp weave, a semi-twist, etc., but not Limited to those who are. The number of layers may be a single layer or a multilayer of two or more layers. In the preferred embodiment (1), as shown in FIG. 12 and FIG. 13, the cloth has a portion (Y portion) including the crimped fiber A and a portion (Z portion) composed only of the fiber B, and The above Y portion is continuous in the warp direction and/or the weft direction. In this case, the pattern in which the Y portion is continuous in the warp direction and/or the weft direction is not particularly limited, but is exemplified by, for example, a fringe pattern, a stripe pattern, a grid pattern, a diamond pattern of the pattern in FIG. 13, and a slate ' Checkered patterns, etc. 201009148 There is no particular limitation on the area ratio of the z part to the y part, but in terms of the dimensional stability of the cloth (Ζ part: Υ part), it is 10: • 9 0~9 0:10 (better 20: The range of 8 0 to 80: 20) is better. The above Y portions are blocked by the Z portion in the cloth. At this time, the area of the Y portion 1 is not particularly limited, but is preferably in the range of 0.01 to 4.0 cm 2 (more preferably 0.1 to 1.0 cm 2 ). On the other hand, the line width of the Z portion is preferably in the range of 0.5 to 100 mm. φ This structure is as shown in Fig. 12, and the portion (Y portion) containing the crimped fiber A during drying is a convex portion, and since the length of the crimped fiber A is shortened during moisture absorption, the convex portion is eliminated and flattened. . Next, in a preferred embodiment (2), as shown in FIG. 10 and FIG. 1, the cloth is composed of two layers, the first layer contains the crimped fibers A, and the second layer is composed only of fibers B. And the first layer is joined to the second layer portion. In this structure, the cross section in the thickness direction is as shown in Fig. 10. One layer (Z φ layer) is composed only of fibers B, and the other layer is composed only of crimped fibers A, and the Z ' layer is joined to the Y layer portion. The surface of the fabric observed from the side of the Y layer is as shown in Fig. 11 ', and the Y layer and the Z layer are connected in a lattice shape, and when dried, the four corner portions of the unconnected Y layer are raised. As a result of the shrinkage of the four corner portions due to moisture absorption, the convex portions disappear, and the entire fabric is flat and the thickness is reduced. The cloth of the present invention can be easily produced, for example, by the following production method. First, the polyamine component and the polyester component are conjugated into a side-by-side type. In this case, for example, the high-viscosity component side and the low-viscosity component side discharge hole are separated, and the high-viscosity side discharge line speed is small, as described in JP-A-2000-144518-89-201009148. (Spinning area is increased), the spinning nozzle is obtained by passing the molten polyester through the high-viscosity side discharge hole and passing the molten polyamine to the low-viscosity side discharge hole side and joining, and obtaining the spun by cooling and solidifying . Further, in the present invention, it is also possible to design the spinning die at this time as a parallel type hollow composite fiber. In addition to the so-called separate extension method of stretching and then heat-treating as needed, the yarn obtained by spinning may also be used as a so-called direct extension without unwinding the unstretched filament and then requiring heat treatment. The method in the extension mode. The spinning speed in the above spinning can be, for example, a spinning speed of about 1,000 to 3,500 m/min which is usually employed. Further, the elongation and the heat treatment are preferably set so that the elongation at break after stretching is from 1 〇 to 60%, and usually from about 20 to 45%, depending on the expression of the crimp, the braidability, and the like. Then, the above-mentioned composite fiber can be simultaneously woven into a fabric with non-crimped or moisture-reducing fiber B, and then dyed, and the composite fiber exhibits potential crimping by heat during dyeing processing ( Known as the crimped fiber A). The fiber B is preferably a polyester fiber having a boiling water shrinkage ratio of 20% or more (preferably, 2 to 5 to 80%). By using the high heat shrinkable fiber as the fiber B, since the fiber B is more contracted than the above composite fiber (the crimped fiber A) by the heat during the dyeing process, when drying, as shown in FIG. 10 or FIG. It is shown that the portion containing the crimped fiber A becomes a convex portion. The high heat shrinkable fiber is selected from, for example, a dicarboxylic acid selected from the group consisting of phthalic acid, naphthalene dicarboxylic acid, adipic acid, and -90-201009148 sebacic acid in addition to the usual dicarboxylic acid component and the alkanediol component. A glycol such as diethylene glycol or polyethylene glycol, or a copolymer of one or more of a group consisting of bisphenol A and bisphenol oxime, which is copolymerized as a third component, is supplied to a general spinning step. In the middle, the unstretched filament strips are obtained, and the filament strips are not stretched, and are directly taken up at a take-up speed of about 3500 m/min. 'The unstretched filament strips are at 60 to 80 ° C. The temperature is slightly extended at a stretching ratio of 1.3 to 1.5 times. Wherein, the acid component is composed of a molar ratio (terephthalic acid/isophthalic acid) of 95/5 to 75/25 of p-benzene φ dicarboxylic acid and isophthalic acid, and the diol component is ethylene glycol or a copolymerized polyester composed of tetramethylene monool (that is, polyethylene terephthalate copolymerized with isophthalic acid) or polybutylene terephthalate copolymerized with isophthalic acid The fiber which is spun and extended is preferred. In addition, when weaving into a fabric, the weaving organization is not particularly limited, and the above may be appropriately selected. The dyeing process has a temperature of 100 to 140 ° C (more preferably 110 to 135 ° C), and the time is maintained at a maximum temperature in the range of 5 to 40 minutes. Under these conditions, by subjecting the fabric to a dyeing process, the composite fiber can exhibit shrinkage by the difference in heat shrinkage between the polyester component and the polyamide component. The fabric to be dyed is usually subjected to dry heat final setting. At this time, the final setting temperature of the dry heat is 120 to 200 ° C (more preferably 140 to 180 ° C), and the time is preferably in the range of 1 to 3 minutes. However, when the temperature at which the dry heat is finalized is lower than 12 (TC, it is easy to leave the crease generated during the dyeing process, and there is a problem that the dimensional stability of the finished product is poor. Conversely, when the dry heat is finalized, the temperature is finalized. When the temperature is higher than 200 °C, the 201009148 fiber shrinkage is reduced during the dyeing process, and the fiber is hardened and the texture of the original fabric is hardened. 0 In the cloth thus obtained, the cloth absorbs moisture due to sweating or rain. In the case of the fabric thus obtained, the crimped fiber A contained in the fabric satisfies the following (1) ~ (at the same time), since the crimping amount of the crimped fiber A itself is increased to shorten the appearance length. In the case of 3), it is easy to reduce the thickness of the cloth during moisture absorption, and the crimped fiber A having such characteristics can be produced by the above-described production method. (1) The crimped fiber A is dried. The crimping ratio DC is in the range of 50 to 80%. (2) The crimping rate HC of the crimped fiber A during moisture absorption is in the range of 60 to 90%. (3) The above-mentioned crimping ratio HC and crimp ratio The difference in DC (HC-DC) is 0.5% or more. Among them, when drying, the sample is placed. In the state of a temperature of 20 ° C and a humidity of 65% RH for 24 hours, on the other hand, in the case of moisture absorption, the sample was placed in an environment of a temperature of 20 ° C and a humidity of 90% RH for 24 hours. In addition, the fabric of the present invention may be additionally provided with a water absorption process, a water splashing process, a raising process, an ultraviolet shielding or an antibacterial agent, a deodorant, an insect repellent, a light storing agent, a retroreflector, an anion generating agent, etc., by a conventional method. Next, the fiber product of the present invention is a fiber product comprising the above-mentioned cloth, which is selected from the group consisting of a clothing for outerwear, a clothing for sportswear, and a clothing for lining. Since the fabric can reduce the thickness of the wet film, it can suppress the heat sensation when sweating. Hereinafter, the embodiment of the present invention relating to 45 to 57 above will be described in detail. The fabric of the present invention must have a crimp ratio at the time of wetting. Obtained crimped fiber A (hereinafter sometimes referred to simply as "crimped fiber A" or "fiber A") and φ crimped fiber B having no change in crimp ratio when not crimped or wetted ( In the following description, the fabric is sometimes referred to as "fiber B". In this configuration, when the fabric absorbs moisture or wets due to sweating, the amount of curl of the conjugate fiber is increased (the length of the fiber is lowered). The size (area) becomes smaller, and the result 'improves the conformity of the clothing composed of the cloth to the wearer's body. At this time, the important area is the area (SD) when the cloth is dried and the area when the moisture is absorbed (SW). The area change rate calculated by the following formula is 1% or more (preferably 3% or more, more preferably 3 to 15%). Area change rate (%) = ((SD-SW) / SD) χΙΟΟ where 'so-called The area when drying is the cloth area in a state where the cloth is placed in a temperature of 20 ° C and a humidity of 65% RH for 24 hours. On the other hand, the area at the time of moisture absorption is to place the cloth at a temperature of 20 ° C, The area of the cloth in a state of humidity of 90% RH after 24 hours. If the above-mentioned area change rate is less than 1%, there is a case where the applicability cannot be improved when sweating, and it is not preferable. Further, in the present invention, "the increase in the crimp ratio at the time of moisture absorption" is such that the difference between the crimp ratio HC at the time of wetting and the crimp ratio DC at the time of drying (HC-DC) is 0.5% or more. In the case of drying, the cloth is placed in a state of a temperature of 20 ° C and a humidity of 65% RH for 24 hours. On the other hand, when the moisture is absorbed, the cloth is placed at a temperature of 20 ° C and a humidity of 90% RH. Next - status after 24 hours. .

In the present invention, the crimped fiber A is not particularly limited as long as it is a fiber having an improved crimp ratio at the time of moisture absorption, but a composite fiber obtained by joining a polyester component and a polyamide component to a G-type, and exhibiting a potential A crimped fiber having a crimped configuration of crimping property is preferred. The polyamine component is a polymer having a guanamine bond in the main chain, and examples thereof include, for example, nylon 4, nylon 6, nylon 12, nylon 46, and nylon 66. In particular, Nylon 6 and nylon 66 are preferable from the viewpoints of cost, versatility, and yarn-making properties. Further, the polyamide components may be copolymerized with a conventional component, or may contain a pigment such as titanium oxide or carbon black, a conventional antioxidant, an antistatic agent, or a light-resistant member. Agent, etc. 〇 On the other hand, the above polyester component preferably accounts for 60 to 99.5 mol% of the ethylene terephthalate unit in the repeating unit constituting the polyester, and the ethylene isophthalate unit occupies 〇 _5~40% by mole of copolymerized polyester. Generally, the heat shrinkage of the polyester is lower than that of the polyamine, but the heat shrinkage of the polyester can be brought close to the polyamine by using the copolymerized polyester as the polyester. As a result, in the crimped and bent structure at the time of moisture absorption, it is easy to form a structure in which the swollen polyamide component is located on the outer side and the polyester component is on the inner side, so that the crimp ratio is easily increased from -94 to 201009148. Among them, when the ethylene terephthalate unit is less than 60 mol%, the basic physical properties of the strong elongation of the obtained composite fiber cannot be sufficiently maintained. When the ethylene terephthalate unit exceeds 99.5 mol% and the isophthalic acid ethylene diester does not reach 0.5 mol%, the crimping rate of the composite fiber is not increased when it absorbs moisture (the length of the crimped filament is not Shorten) 'There is a situation in which it is difficult for the fabric to exhibit sufficient variation. When the ethylene isophthalate exceeds 40 mol%, the basic physical properties such as the strong elongation of the composite fiber cannot be maintained, and the thermal stability of the φ is also deteriorated, and the spinning nozzle is formed due to the decomposable foreign matter in the spinning step. Part of the filtration pressure (filling pressure) increased significantly. The polyesters may be produced by any method, for example, if polyethylene terephthalate is described, in order to directly esterify terephthalic acid with ethylene glycol, such as dimethyl terephthalate The lower alkylene terephthalate is directly esterified with ethylene glycol, or the terephthalic acid is reacted with ethylene oxide to form a terephthalic acid glycol ester and/or a low polymer thereof. Then, by heating the product under reduced pressure and polycondensing to a desired degree of polymerization, the polyester is further composed of a polyethylene terephthalate component and a * isophthalate. In addition to the diester component, a third component may be copolymerized, and the third component is preferably any of a dicarboxylic acid component or a diol component. As the dicarboxylic acid component, for example, phthalic acid, dibromoterephthalic acid, naphthalene dicarboxylic acid, diphenyldicarboxylic acid, diphenoxyethane dicarboxylic acid, such as β-hydroxyl B can be exemplified. A difunctional aromatic dicarboxylic acid of oxybenzoic acid, such as a difunctional aliphatic dicarboxylic acid of azelaic acid, adipic acid, oxalic acid, or 1,4-cyclohexanedicarboxylic acid. Further, other diol components may be substituted for one of the above-mentioned diol components, -95 to 201009148, and examples of such diol components are, for example, cyclohexane-1,4-dimethanol, neopentyl glycol, bisphenol A, and the like. Bisphenol S, 2,2-bis(4-β-hydroxyethoxyphenyl)propane, bis(4-β-hydroxyethoxyphenyl) milled, 2,2-bis(3,5·dibromo -4-. An aliphatic, alicyclic or aromatic diol of (2-hydroxyethoxy)phenyl)propane. Further, in the above polyester, a small amount of the other polymer may be blended as needed, and a chain branching agent such as pentaerythritol, trimethylolpropane or methic acid may be used in a small amount. In addition, the polyester of the present invention is of course also added with a pigment such as titanium oxide or carbonium as in the case of a general polyester, and conventionally known as an antioxidant and an anti-tarnishing agent. The polyester component preferably contains a polyether ester decylamine. When the polyester component contains a polyether ester decylamine, the polyester component becomes soft, and when moisture absorbing, the polyester component is easily followed when the polyamine component is swollen, and the crimp ratio at the time of moisture absorption is apt to increase. Preferably. The polyether ester decylamine is preferably added to the polyester component in an amount of 5 to 55% by weight based on the weight of the polyester component. If it is less than 5% by weight, when the composite fiber absorbs moisture, the crimp ratio does not increase so much (the appearance length of the crimped fiber is difficult to be shortened), and a sufficient dimensional change may not be obtained as a cloth. Further, when it exceeds 55 wt%, there is a case where the spinning cannot be stabilized. The polyether ester decylamine is preferably an ethylene oxide having a number average molecular weight of 500 to 5,000 and a bisphenol having a number average molecular weight of 1,600 to 3,000. Derived from product (b). "Derivative" means the one obtained by reacting two components, or the one obtained by copolymerization. The polyamine (a) having a carboxyl group at both terminals is preferably composed of a polyamine moiety and a molecular weight modifier. The polyamine moiety is at least (1) a decylamine ring-opening polymer, (2) a polycondensate of an aminocarboxylic acid, or (3) a polycondensate of a dicarboxylic acid-96-201009148 and a diamine. Any of the guanamines may be exemplified by butysamine, valeroside, caprolactam, amine, dodecane decylamine, undecyl decylamine and the like. Examples of (2) are ω-aminohexanoic acid, ω-amino heptanoic acid, ω-aminooctanoic acid, acid, 11-aminoundecanoic acid, 12-aminododecanoic acid and the like. (3 Acids are exemplified by adipic acid, sebacic acid, sebacic acid, undecanedioic acid, isophthalic acid, etc. Further, the diamine of (3) is exemplified by tetra-φ amine and pentamethylene diamine. , hexamethylenediamine, heptamethylenediamine, decamethylenediamine, etc. The above-mentioned indoleamines, dicarboxylic acids, diamines are known as polyamine partial forming monomers. The above-mentioned sub-forming monomers which are polyamines (a) having a carboxyl group at both terminals may be exemplified by two or more kinds. These are caprolactam, 12-aminododecanoic acid and hexamethylene. The acid-hexamethylene is preferably caprolactam. The above-mentioned two-terminal polyamines (a) having a carboxyl group and further a dicarboxylic acid component of φ 4 to 20 are used as molecular weight regulators. The above-mentioned polyamine moiety-forming monomer is obtained by encapsulation polymerization. The dicarboxylic acid having 4 to 20 carbon atoms is exemplified by succinic acid, adipic acid, pimelic acid, suberic acid, sebacic acid and sebacic acid. a fatty acid dicarboxylic acid such as acid or dodecanedioic acid; an aromatic dicarboxylic acid hexane dicarboxylic acid such as terephthalic acid, phthalic acid or naphthalene dicarboxylic acid, or An alkali metal salt of aliphatic bis-5-propenyl isophthalate such as hexyl-4,4-dicarboxylic acid or potassium phthalate isophthalate, etc., etc. Preferred in the dicarboxylic acid, dodecyl methylene diamine, and imidate carboxylic acid polyamine moiety of the aliphatic, heptane decyl carboxylic acid ω-amino hydrazine, using carbon number Underneath by ring polymerization or pentane pentanedioate, m-phenylene; 1,4-cyclocarboxylic acid: or 5-sulfo-dicarboxylic acid, -97-201009148 aromatic dicarboxylic acid and 5-sulfonate Bismuth isophthalate metal salt. More preferably, it is adipic acid, terephthalic acid, or sodium 5-sulfoisophthalate. When the polyamidene moiety forming monomer is subjected to ring-opening polymerization or polycondensation by a conventional method, the average degree of polymerization is preferably from 2 to 10, and the average degree of polymerization is from 3 to 8. As a result, the number average molecular weight of the polyamine moiety is from 100 to 1,000, more preferably from 300 to 700. Further, the polyamine (a) having a carboxyl group at both ends is a component which imparts a polyamine moiety to both ends of a dicarboxylic acid component having 4 to 20 carbon atoms of a molecular weight modifier, and a polyamine moiety is provided at a single terminal. The component may also be a mixture of a component which imparts a polyamine moiety at both ends and a component which gives a polyamine moiety at one end. In the case of a mixture, it is preferable that the component which gives the polyamine moiety to the mono-terminal end of the monomolar portion has a composition of the polyamine moiety at both ends to be 1 to 10 moles. More preferably, it is a component imparted to a single end of 1 mole, and the components imparted at both ends are 3 to 8 moles. Therefore, the amount of the carboxyl group-containing component of the above polyamine moiety-forming monomer can be appropriately adjusted so as to have a carboxyl group at both terminals. If only indoleamine and/or an aminocarboxylic acid is used as the polyamine moiety-forming monomer, since the molecular weight modifier is a dicarboxylic acid component, a polyamine amine having a carboxyl group at both terminals can be easily produced (a) ). When a polycondensate of a dicarboxylic acid and a diamine is used as a polyamidene moiety-forming monomer, for example, a polyalkylamine having a carboxyl group at both terminals can be produced by a method such as a reaction for finally changing a dicarboxylic acid of a polymer (a). . The number average molecular weight of the polyamine (a) having a carboxyl group at both ends is usually from 500 to 5,000, preferably from 500 to 3,000. When the number average molecular weight is less than 500, the heat resistance of the polyether ester decylamine itself is lowered. On the other hand, when the -98-201009148 exceeds 5,000, the reactivity is lowered, so the polyether ester decylamine takes longer to manufacture. . In order to make the number average molecular weight fall within the range, the dicarboxylic acid component having 4 to 20 carbon atoms may be used as the molecular weight modifier, and the reaction conditions may be appropriately set in the polymerization of the polyamine moiety. Further, among the bisphenol-based ethylene oxide adducts (b), the bisphenols are exemplified by bisphenol A (4,4'-dihydroxydiphenyl-2,2-propane), bisphenol F ( 4,4'-dihydroxydiphenylmethane), bisphenol S (4,4'-dihydroxydiphenylfluorene φ), and 4,4'-dihydroxydiphenyl-2,2-butane. The preferred of these is bisphenol A. The above bisphenol-based ethylene oxide adduct (b) is obtained by adding ethylene oxide to the bisphenols by a conventional method. Further, ethylene oxide and other alkylene oxides (propylene oxide, 1,2-butylene oxide, 1,4-butylene oxide, etc.) may be used, but the amount of other alkylene oxide used is entirely The weight of the ethylene oxide is normal, and is usually 10% by weight or less. Further, the above adduct (b) corresponds to two hydroxyl groups of bisphenols, and polymerization has an average of 20 to 70 mole of ethylene oxide and other alkylene oxides (hereinafter referred to as ethylene oxide). good. It is better to polymerize with 32~6 〇mole of epoxy 'ethane etc. That is, an hydroxy group (addition) corresponding to bisphenol has an addition of 10 to 35 moles, preferably 16 to 30 moles, more preferably 16 to 20 moles of oxygen. The number average molecular weight of the above-mentioned adduct (b) is usually ι, 6 〇〇 to 3 〇〇〇 ′, and it is particularly preferable to use an ethylene oxide addition molar number of from 3 to 60. If the average molecular weight is less than 1,600, the antistatic property is insufficient. On the other hand, when it exceeds 3,000, the polyether ester decylamine is required to be produced for a long period of time due to a decrease in reactivity. The number average molecular weight is preferably from 1,800 to 2,400, and the molar number of addition of ethylene oxide or the like is more preferably from 32 to 40. The number average molecular weight falls within this range. The molecular weight of the bisphenols can be determined by adjusting the molar number of addition of ethylene oxide or the like. The above-mentioned adduct (b) is used in the range of 20 to 80% by weight based on the total weight of the above (a) and (b) in the polyetheresteramine. If the amount of the adduct (b) is less than 20% by weight, the antistatic property of the polyether ester decylamine is deteriorated. On the other hand, when it exceeds 80% by weight, the heat resistance of the polyether ester decylamine is lowered. Not good. More preferably, the adduct (b) is used in the range of 40 to 70% by weight based on the total weight of the above (a) and (b). The relative viscosity of the polyether ester guanamine used in the present invention is 1.5 to 3.5 (0.5% by weight, m-cresol solution, 25 ° C), preferably 2.0 to 3.0. If it is less than 1.5', the difference in melt viscosity between the base polymer component (polyamide component and polyester component) during kneading is large, so it tends to stay in the inside of the tube or in the spinning unit, and spinning for a long time is likely to cause abnormal discharge. The quality of the obtained composite fiber is unstable. On the other hand, if it exceeds the range of 3.5, it will be the cause of the broken yarn when the yarn is twisted. * The polyether ester decylamine is most suitable for the polyamidamide component in an amount of 〇% by weight. When added in a small amount, the hygroscopic elongation of the polyamide component is lowered, and the function of shrinking the moisture at the time of moisture absorption which is the object of the present invention and shrinking the length of the appearance yarn is impaired. The side-by-side type composite fiber may have any fineness, cross-sectional shape, or composite form, and the single-filament fineness is preferably about 1.5 to 5.0 dtex. Further, when the composite fiber of the present invention is made into a hollow composite fiber, the sensitivity to humidity 201009148 becomes large, and the bulkiness also becomes large. Further, the area ratio of the cross section of the composite fiber of the polyamide component and the polyester component is preferably in the range of polyamine component/polyester component. = 30/70-70/30, more preferably 40/60-60. /40 range. When the conjugate fiber is a multifilament of a plurality of filaments, the total fineness of the multifilament is not particularly limited, but it can be used in the range of 40 to 200 dtex as a material for general clothing. Moreover, the interlacing process can also be performed as needed. φ The above composite fiber has potential crimping properties, and as described later, exhibits a potential crimping property upon heat treatment such as dyeing. Therefore, when the moisture absorption is carried out, the polyamide component is swollen and stretched, and the polyester component hardly causes a change in length, so that the crimp ratio is improved (the appearance length of the crimped fiber A is shortened). On the other hand, since the polyamide component shrinks during drying, the polyester component hardly changes in the degree of growth, and thus the crimp ratio is lowered (the appearance length of the crimped fiber A becomes long). The above-mentioned crimped fiber A is likely to be improved in shrinkage ratio at the time of moisture absorption, and it is preferable to use a twisted yarn or a weak twisted yarn of 300 T/m or less. Especially ', better with no silk. If it is strong silk, if the strong silk is given, the shrinkage rate is not easy to improve when it absorbs moisture. Further, even if the number of interlaces is about 20 to 60 pieces/m, the warp and weft interlacing air processing and/or the general false twisting processing may be performed. On the other hand, the elastic fiber B having the crimped shape which does not change during the non-crimping or moisture absorption is not particularly limited as long as it is a non-crimped fiber or a crimped elastic fiber which does not change when moisture is absorbed. By the presence of the elastic fiber, the feeling of wearing in the state of non-sweating is complemented, and the effect of improving the fit after the sweating is further improved - 101 - 201009148. In the present invention, "there is no change in the crimp ratio at the time of moisture absorption" is a difference (HC-DC) between the crimp ratio HC at the time of moisture absorption and the crimp ratio DC at the time of drying (HC-DC) of less than 0.5%. The fiber B is preferably an elastic fiber having an elongation of 300% or more. Specifically, the exemplified ones are polyurethane elastic fibers or polyester ether elastic fibers. The fabric of the present invention may also contain a non-elastic fiber C which is not crimped or which has a crimping rate which does not change upon moisture absorption. The non-elastic fiber C preferably has fibers of the above-described properties of the crimped fibers A and the elastic fibers B. For example, in order to realize a soft texture, a multifilament fiber having a single filament fineness of 1 dtex or less, a false twisted textured yarn, a multifilament fiber having a good color developability, or a processed yarn can be exemplified. Specifically, it is a polyester such as polyethylene terephthalate, polytrimethylene terephthalate or polybutylene terephthalate, nylon 6, nylon 66, polyacrylamide, polyethylene, polypropylene, etc. Polyolefin, acrylic acid, p-type or meta-linoleamide, and such modified synthetic fibers, natural fibers, regenerated fibers, semi-synthetic fibers, polyurethane-based elastic yarns, polyether ester-based elastic yarns Fibers suitable for clothing are free to choose. Among them, in terms of dimensional stability during moisture absorption or compatibility with the above-mentioned crimped fiber A (mixing property, blending, interlacing property, dyeability), polyethylene terephthalate is used. Preferably, polytrimethylene terephthalate, polybutylene terephthalate, or a polyester fiber composed of the modified polyester obtained by copolymerizing the above copolymerized component. Further, the single yarn fineness and the number of filaments (the number of filaments) of the fiber B are not particularly limited, but the single yarn fineness is 0.1 in terms of improving the water absorption of the cloth and exhibiting the dimensional change performance when moisture is well exhibited. ~5dtex (better -102-201009148 0·5~2dtex), preferably in the range of 20 to 200 filaments (more preferably 30 to 100). In particular, it is also possible to perform warp and weft interlacing air processing and/or general false twist crimping so that the number of interlaces is about 20 to 60/m. The fabric of the present invention contains the above-mentioned crimped fiber A having an increased crimp ratio at the time of moisture absorption, and the crimped elastic fiber B which has no curling property when it is not crimped or moisture-absorbent. The structure of the cloth is not limited to the structure of the weave and the number of layers. For example, φ is preferably woven, such as plain weave, woven fabric, satin weave, or woven structure, double rib, circular rib, tuck mesh, woven weave, warp woven, semi-twisted, etc. Not limited to these. The number of layers may be a single layer or a multilayer of two or more layers. In this case, at least one of the layers of the fabric preferably contains 30% by weight or more of the above-mentioned crimped fibers A in the total fiber weight constituting the layer. In the case of the 'multilayer structure fabric, when the crimped fiber A of 30% by weight or more is not contained in any one layer, the curling force of the crimped fiber A is increased, and the fabric is negatively restrained, so that the fabric cannot be sufficiently obtained. Invention φ The purpose of the service is not good. As for the fabric of the present invention, the crimped fiber A is exemplified by arranging the above-mentioned crimped fiber A with the above-mentioned elastic fiber B and, as the case, the above-mentioned fiber C, to form a warp and/or weft fabric of a woven structure, and the above-mentioned crimped fiber A is aligned with the elastic fiber B and the above-mentioned fiber C as needed to form a so-called bare fabric or the like. Further, in the fabric of the present invention, the crimped fiber A and the elastic fiber B may be such that the crimped fiber A is located in the sheath portion, and the elastic fiber B is placed in the core to form the core-sheath type composite yarn in the cloth. A preferred embodiment of the configuration of the above-mentioned crimped fiber A and fiber B contained in the fabric of the present invention is described below -103-201009148. First, in the embodiment (the cloth has a portion (Y portion) composed of the above A and the elastic fiber B, and a portion composed of the elastic fiber C and the elastic fiber B (the Z portion is formed in the warp direction and / or the latitudinal direction is continuous. When the moisture is absorbed, the size of the Y portion is more easily changed than that of the Z portion, and since the Y portion of the cloth becomes the warp direction and/or the weft, the size of the cloth becomes small when it absorbs moisture. In the case of the Y portion, the warp direction and/or the weft pattern are not particularly limited, and may be, for example, a fringe pattern, a grid pattern, a rhombic pattern pattern pattern displayed in the pattern of Fig. 16, and the like. The area ratio of the Y portion is not particularly limited in terms of material dimensional stability (Z part: Y part) 90 to 90: 10 (more preferably 20: 8 0 to 80: 20). There is no particular limitation on the area in the fabric that blocks the Y portion 1 by the Z portion, but in the range of 〇.〇1~4. good 0.1~1.0 cm2), it prevents the stickiness when sweating. It is better to live. On the other hand, the line width of the Z portion is preferably in the range of 0.5 ~. In the following embodiment (2), the cloth has a portion (Z portion) composed of the above-mentioned dimension C and the fiber B, and a fiber A and the inelastic fiber C and the fiber B; The above-mentioned X portion is formed by the above-mentioned non-fraction in the warp direction and/or the weft-retracting fiber, and in the structure, the (contraction) is continuous, the continuous stripe pattern, the slate side, but the cloth is placed at 1 〇: 〇. At this time, 0 cm2 (more than the skin of the skin of 100 mm, the above-mentioned crimping L portion (X-direction continuous. -104-201009148) In this configuration, the X portion is more likely to change in size when it is wetted than the z portion. And since the X portion of the cloth is continuous in the warp direction and/or the weft direction, the size of the cloth when it absorbs moisture becomes small. At this time, the X portion is in a continuous pattern or the area ratio of the two is suitable to be implemented ( 1) the same degree. In the following embodiment (3), the cloth has a portion (X portion) of the crimped fiber a and the inelastic fiber C and the fiber B, and the crimped fiber A and the above a portion (Y φ portion) of the elastic fiber B in which the Y portion is continuous in the warp direction and/or the weft direction. In this configuration, the Y portion is more likely to change than the X portion when wet. The Y portion of the cloth becomes continuous in the warp direction and/or the weft direction. Therefore, the cloth size becomes smaller when moisture is absorbed. At this time, the Y portion becomes a continuous pattern or the area ratio of the two is preferably the same as the embodiment (1). The extent of the following implementation 4) The cloth has a portion (X portion) φ composed of the crimped fiber A, the fiber C and the elastic fiber B, and a portion (Y portion ') of the crimped fiber A and the elastic fiber B. And a portion (Z portion) composed of the inelastic fiber C and the elastic fiber B, and the Y portion is continuous in the warp direction and/or the weft direction. In the structure, the Y portion is compared with the other portion (X) Part or Z part) The size is more likely to change when moisture is absorbed, and since the Y portion in the cloth is continuous in the warp direction and/or the weft direction, the dimensional change of the cloth when it absorbs moisture is small. At this time, the Y portion becomes continuous. The pattern, or the area ratio of the Y part to the other parts is the same as the implementation state (1). In the following embodiment (5), the cloth is a two-layer fabric, and the -105-201009148 layer is only the above The crimped fiber A constitutes 'the other layer is composed only of the above-mentioned elastic fiber B. This structure is shortened by the length of the crimped fiber A at the time of moisture absorption, so the size of the cloth becomes small. In the following embodiment (6), 'clothing Multilayer consisting of three or more layers The cloth has a layer composed of the crimped fiber A and the non-elastic fiber C, and a layer composed of only the non-elastic fiber c and a layer composed only of the elastic fiber B. The structure is caused by moisture during moisture absorption. The length of the shrinkage fiber A is shortened, so that the cloth size is reduced. Φ In the following embodiment (7), the fabric is a multilayer fabric composed of three or more layers, and has the above-mentioned rolled fiber A and the above-mentioned non-elastic fiber C. The layer is a layer composed only of the above-mentioned crimped fibers A, and a layer composed only of the above-mentioned elastic fibers B. In this structure, since the length of the crimped fibers A is shortened during moisture absorption, the cloth size is reduced. In the embodiment (8), the fabric is a multilayer fabric composed of three or more layers, and has a layer composed only of the above-mentioned rolled fibers A, a layer composed only of the above-mentioned inelastic fibers C, and only the above-mentioned elastic fibers B. The @ layer of composition. In this configuration, since the length of the crimped fibers A becomes short when moisture is absorbed, the size of the cloth becomes small. A fabric of the present invention can be easily produced, for example, by the following manufacturing method. First, the polyamine component and the polyester component are conjugated into a side-by-side type. In this case, for example, the high viscosity component side and the low viscosity component side discharge hole are separated, and the discharge speed of the high viscosity side is small (the discharge area is increased as described in JP-A-2000-1445-18). The spinning nozzle of the large one is obtained by passing the molten polyester through the high-viscosity side discharge hole and passing the molten poly-peptide-106-201009148 amine through the low-viscosity side discharge hole side and joining, and obtaining the spun yarn by cooling and solidifying. . Further, in the present invention, it is also possible to design the spinning die at this time as a parallel type hollow composite fiber. The so-called filaments obtained by spinning may be stretched after being temporarily taken up and then subjected to heat treatment as needed, in addition to the method, the so-called direct extension without stretching the unstretched filaments and then heat treatment as needed may be used. The method in the extension mode. The spinning speed in the above spinning can be, for example, a spinning speed of φ of about 1,000 to 3,500 m/min which is usually used. Further, the elongation and the heat treatment are preferably set so that the elongation at break after stretching is from 10 to 60%, usually from about 20 to 45%, depending on the expression of the crimp, the braidability, and the like. Then, the conjugate fiber can be used at the same time, and the elastic fiber B having no change in the crimp ratio at the time of non-crimping or moisture absorption is woven into a cloth, and then subjected to dyeing processing, and the composite fiber exhibits a potential roll by heat during dyeing processing. Shrinkage (called crimped fiber A). Further, when weaving into a cloth, the elastic fiber B is preferably stretched by 1.2 times or more (preferably 1.5 to 3 times). By elastically kneading the elastic fiber B in this manner, a fabric excellent in conformability is obtained. At this time, when weaving into a fabric, there is no special restriction on the weaving organization, and it is appropriate to select the above. The temperature of the above dyeing process is 100 to 140 ° C (more preferably 11 〇 to 135 ° C), and the time is preferably in the range of 5 to 40 minutes at the highest temperature. Under these conditions, by subjecting the fabric to a dyeing process, the composite fiber can exhibit shrinkage by the difference in heat shrinkage between the polyester component and the polyamide component. The fabric to be dyed is usually subjected to dry heat final setting. At this time -107- 201009148, the final setting temperature of dry heat is 120~200 °C (more preferably 140~180 °C), and the time is preferably within 1~3 minutes. However, when the temperature at which the dry heat is finalized is lower than 120 °C, the crease generated during the dyeing process tends to remain, and the dimensional stability of the finished product may be poor. On the contrary, when the temperature at which the dry heat is finalized is higher than 200 ° C, the shrinkage of the composite fiber exhibited during the dyeing process is lowered, and the fiber is hardened and the texture of the original fabric is hardened. When sweating or raining and absorbing moisture, the length of the appearance is shortened due to an increase in the amount of crimping of the crimped fiber A itself. As a result, the size is made smaller by moisture absorption, and the applicability at the time of sweating is enhanced by the effect of multiplying with the elastic fiber B contained in the cloth. Further, in the cloth thus obtained, when the crimped fiber A contained in the fabric satisfies the following requirements (1) to (3), it is preferable to obtain an excellent dimensional change at the time of moisture absorption. Further, the crimped fiber A having such characteristics can be produced by the above-described manufacturing method. (1) The crimping ratio DC of the crimped fiber A during drying is in the range of 50 to 80%. (2) The crimping rate HC of the crimped fiber A during moisture absorption is in the range of 60 to 90%. (3) The difference between the above-described crimp ratio HC and the crimp ratio DC (HC-DC) is 0.5% or more. In the case of drying, the sample is placed in a temperature of 20 ° C and a humidity of 65% RH for 24 hours. On the other hand, when the moisture is absorbed, the sample is placed at a temperature of 20 ° C and a humidity of 90%. The state of 24 hours 201009148 in the RH environment. In addition, the fabric of the present invention may be additionally provided by the conventional method of water absorption, work, water repellent processing, raising processing, ultraviolet shielding or antibacterial agent, deodorant, insect repellent, light storage agent, retroreflective agent, negative ion generator, and the like. Various processing of functions. In particular, it is an effective means of sweat absorption because it can improve the conformity earlier when sweating. Next, the fiber product of the present invention is a fiber product selected from the group consisting of a garment for a garment, a garment for a garment, and a garment for a liner. Since the fiber product uses the above-mentioned cloth, the size at the time of moisture absorption becomes small, and the conformability at the time of sweating is enhanced. 1 is also described. The limited system of the system is exemplified by the following method. The details of this example are subject to falsehood and explanation. The physical properties of the present embodiment are determined by the following methods. * &lt;Intrinsic Viscosity (IV) &gt; ' For polyethylene terephthalate, a quantitative meter is used, and the solvent is o-chlorophenol, which is obtained at 35 ° C according to the usual method. For nylon 6 shells [J, a mass mixed solvent such as phenol/tetrachloroethane was used in the same manner, and the measurement was carried out at 30 °C. &lt;Number average molecular weight&gt; Polyamide having a number of carboxyl groups at both ends having an average molecular weight of 500 to 5,000-109-201009148 (a) Number average molecular weight of a part and an ethylene oxide adduct of the bisphenol (b) The measurement sample was dissolved in a mass mixed solvent such as trifluoroacetic acid/deuterated chloroform, and NMR was measured. From the measurement result, the repeating unit of each part was specified, and the number average molecular weight was determined from the result. &lt;Weight ratio of polyether ester decylamine&gt; The composite fiber can be controlled by gear pump adjustment conditions, but the method described in (7) can be used to form the polyamine component of the conjugate fiber. The polyester portion was subjected to NMR measurement, and the weight ratio of the polyether ester decylamine in the polyamide component or the polyester component was calculated by analyzing the result &lt; silk shrinkage ratio in the cloth&gt; After 24 hours in an ambient gas of °C and a humidity of 65% RH, a small piece of 30 cm x 30 cm (n number = 5) was cut from the cloth. Next, the filaments which change the amount of curl due to moisture absorption (the side-by-side type composite fiber of modified polyester and polyamine) are taken out from each small piece, and the load of 49/50 mNx9x total tex (100 mg/de) is measured. The length L0 of the yarn was measured, and the length L1 of the yarn under the load of 49/50 mNx9x4/1000x total tex (〇.4 mg/de) was measured after removing the weight for 1 minute. Then, the wire was placed in an atmosphere gas at a temperature of 20 ° C and a humidity of 90% RH for 24 hours, and then the wire length L0' of the 49/50 mNx9x total tex (100 mg/de) load was measured, and after removing the weight for 1 minute, The length L1' of the wire under the load of 49/50 mNx9 x4/1 000 x total tex (0.4 mg/de) was determined. -110- 201009148 Calculate the crimp ratio (DC) during drying, the crimp ratio (HC) during moisture absorption, and the crimp ratio during moisture absorption and drying from the above-mentioned number in the following calculation formula. . Crimping rate during drying DC(%) ={ (L0-L1) /L0} 卷 Crimping rate during moisture absorption HC ( % ) = { ( L0'-L1 ’)/L0’ } X 1〇〇

Difference in shrinkage ratio between moisture absorption and drying (%) = HC-DC ❹ &lt;breathability&gt; JIS L 1096-1998, 6.27.1, Method A (Frazier type gas permeability tester) Method), for a knitted fabric placed at a temperature of 20 ° C and a humidity of 6 5% RH for 24 hours, and a knitted fabric placed at a temperature of 20 ° C and a humidity of 90% RH for 24 hours to measure individual gas permeability (η number = 5) ), and the gas permeability reduction rate is calculated by the following formula. • Gas permeability reduction rate (%) = (APD-APH) / APDxl 00 &quot; where APD is gas permeability at a temperature of 20 ° C and a humidity of 65% RH, and the temperature is 20 ° C, humidity 90% RH Breathability. &lt;Water Leakage&gt; The amount of water leaked in a total water volume of 7 liters/min in 1 minute was measured using a Bundesmann rain test apparatus of JIS L 1 092, 6.3 (rain test A method). -111 - 201009148 &lt;Pinch ratio of false twist crimping yarn&gt; The filament yarn for testing was wound around a gauge machine having a circumference of 1.125 m to prepare a skein having a dry fineness of 3333 dtex. The skein was suspended from the shackle of the ruler plate, and the initial load of 5.9 cN (6 gr) was added underneath, and the skein length LO was measured at a load of 588 cN (600 gr ). Subsequently, the load was immediately removed from the above skein, and the skein was removed from the ruler plate to make the skein immersed in boiling water for 30 minutes, showing curling. The skein after boiling water treatment was taken out from the boiling water, the moisture contained in the skein was sucked off with a filter paper, and air-dried at room temperature for 24 hours. Hang the air-dried skein on the slat of the ruler plate, and add a load of 5 8 8cN ( 60 0gr ) to the bottom, and measure the length Lla of the skein after 1 minute, then remove the load from the skein, and The length L2a of the hank was measured after 1 minute. The crimping ratio (CP) of the test filaments was calculated by the following formula. c P ( % ) = { (Lla-L2a) / L0 } χ 1 0 0 ❹ [Example 1] Intrinsic viscosity (IV) at a spinning temperature of 290 ° C and a spinning speed of 1000 m/min by a conventional method Nylon 6 (Ny6) which is I·1, and 40% by weight of polyether ester decylamine (number average molecular weight of the polyamine (a) moiety is 1 500, ethylene oxide adduct (b) Partial number average molecular weight 2000, relative viscosity 2.2) phthalic acid copolymerized polyethylene terephthalate particles (interpolymerization ratio of isophthalic acid is 〇·5 mol% 201009148, IV = 0.65) The yarn was spun, and then stretched at an elongation temperature of 60 ° C and a stretching ratio of 2.5 times without being wound up, followed by heat setting at 130 ° C to obtain a filament. A polyethylene terephthalate obtained by blending nylon 6 with a polyether ester decylamine was joined into a side-by-side manner in a weight ratio of 50:50 to obtain a composite fiber of 56 dtex/24 fil. Next, using the 36-gauge needle-warp-knit flat knitting machine, the above composite fiber (not boiling water, not showing curling. No twisting) is fully worn on the front shuttle, 33dtex/ 36 fil of polyethylene terephthalate false twist crimping processing wire (winding rate 20%) is full on the rear shuttle, the previous shuttle 10-23, the rear shuttle 12-10 half of the organization, the machine ranks Knitted fabric of twill weave fabric with a number of stitches of 96 rows/2.54 cm. The obtained knitted fabric was subjected to dyeing treatment at 130 ° C for 15 minutes to make the potential crimping property of the composite fiber remarkable, and then dried at a temperature of 100 ° C, followed by dry heat at 160 ° C for final setting for 1 minute. The evaluation results of the obtained knitted fabric are shown in Table 1, and the gas permeability at the time of drying was 39 CC/cm 2 /s, the gas permeability at the time of moisture absorption was 22 cc/cm 2 /s, the gas permeability reduction rate was 44%, and moisture absorption. The air permeability is reduced, and the water leakage resistance is 1190 cc as a non-water-repellent processing*. The knitted fabric is a knitted fabric with high water leakage resistance. The density of the knitted fabric was 70 in the number of stitches/2.54 em, and the number of stitches in the 79 course was 2.54 cm. In the composite fiber extracted from the knitted fabric, the crimping ratio DC during drying is 64%, the crimping rate HC during moisture absorption is 77%, and the crimping ratio during drying and wetting is (HC - DC ) is 1 3 . %. Then, after wearing the knitted fabric (sports clothing), the breathability is reduced and the comfort is comfortable. -113-201009148 [Example 2] In Example 1, the knitted fabric was subjected to dyeing processing, and then subjected to padding treatment using a fluororesin-based water-repellent processing liquid, dried at a temperature of 100 ° C, and then subjected to a temperature of 160 ° C. After the dry heat was finalized for 1 minute, it was heated by press-rolling at a roll temperature of 160 ° C and a nozzle pressure of 580 N/cm (60 kgf/cm) by roller rolling (manufactured by Lee Roll Co., Ltd.). The evaluation results of knitted fabrics are shown in Table 1. The gas permeability at the time of drying is 8 cc/cm 2 /s, and the gas permeability at the time of moisture absorption is 5 (: (: / (: 1112 / 3), the gas permeability reduction rate is 3 8%, and the gas permeability at the time of moisture absorption is lowered, and resistance is obtained. The water-repellent fabric with a water-repellent resistance of 27cc is also extremely high. In addition, in the composite fiber extracted from the knitted fabric, the crimping ratio DC is 62% during drying, and the crimping rate HC during moisture absorption is 73%. The difference in crimp ratio (HC-DC) at the time of wetting was 11%. [Example 3] The 33 dtex/36 fil polyparaphenylene used in Example 1 was used using a 36-gauge needle-knit-knit flat knitting machine. Ethylene diformate false twist crimping processing wire (winding rate 20%) was fully worn on the front shuttle, and the composite fiber 56dtex/24fil used in Example 1 was fully worn on the rear shuttle, previously shuttle 10-23 The half-structure of the rear shuttle 12-10, the number of stitches on the machine is 106 knitting stitches/2.54 cm, and the knitted fabric of the twill weave is knitted. The obtained knitted fabric is dyed at 130 ° C for 15 minutes for dyeing. After processing, the potential crimping performance of the composite fiber is remarkable, and then dried at a temperature of i〇〇°c, followed by dry heat at i6〇°c for final setting for 1 minute. The evaluation result of the woven fabric 201009148 is shown in Table 1, and the gas permeability at the time of drying was 17 cc/cm 2 /s, the gas permeability at the time of moisture absorption was 12 cc/cm 2 /s, the gas permeability reduction rate was 29%, and moisture absorption was performed. Breathable. Sexually degraded, with a water resistance of 1 475cc as a knitted surface without water treatment

Knitted fabric with high water leakage resistance. In addition, the composite of the knitted fabric is extracted. In the fiber, the crimping rate DC is 65% when dry, the crimping rate HC is 79% when moisture is absorbed, and the crimping ratio is poor when wet and wet (HC-DC). It is 14%. Φ [Example 4] In Example 3, the knitted fabric was subjected to dyeing, and then padded with a fluororesin water-repellent treatment liquid, dried at a temperature of 100 ° C, and dried at a temperature of 160 ° C. After the heat was finalized for 1 minute, the knitted fabric obtained by heating and pressing at a roll temperature of 160 ° C and a nozzle pressure of 5 8 8 N/cm (60 kgf/cm) was rolled by a roller (manufactured by Lee Roll). The evaluation results are shown in Table 1. The gas permeability at the time of drying is 3CC/cm2/S, the gas permeability at the time of moisture absorption is 2CC/cm2/s, the gas permeability reduction rate is 33%, and the gas permeability of the ruthenium is reduced at the time of moisture absorption, and the water leakage resistance is also 5 cc. Knitted fabric with extremely high water resistance. In addition, in the composite fiber extracted from the knitted fabric, the shrinkage ratio DC during drying is 61%, the crimping rate HC during moisture absorption is 70%, and the crimp ratio during drying and wetting is poor (HC-DC). It is 9%. [Comparative Example 1] Two kinds of polyesters having different shrinkage ratios were joined into a 50:50 side-by-side 56dtex/24fil crimped composite fiber using a 36-gauge needle-knit-knit flat knitting machine. And the polyethylene terephthalate false twist crimping processing wire (winding rate 20%) of 33 dtex/36 fil -115-201009148 used in Example 1 was fully worn on the rear shuttle, before shuttle 10-23 The half-structure of the rear shuttle 12-10, the number of stitches on the machine, the number of stitches in the 96-row row, and the number of stitches of 2.54 cm are knitted into a twill weave knitted fabric. The obtained knitted fabric was dyed at 130 ° C for 15 minutes to visualize the potential crimping property of the composite fiber, and then dried at a temperature of 10 ° C, followed by dry heat final setting at 16 (TC) 1 minute. The evaluation results of the obtained knitted fabric are shown in Table 1, and the gas permeability at the time of drying was 42 cc/cm 2 /s, the gas permeability at the time of moisture absorption was 41 cc/cm 2 /s, the gas permeability reduction rate was 2%, and moisture absorption. The air permeability is almost unchanged, and the water leakage resistance is also 3 2 40 cc. It is a water-resistant knitted fabric of the usual grade of knitted fabric without water-repellent processing. In addition, in the composite fiber extracted from knitted fabric, when dry The crimp ratio DC was 58%, the crimp ratio HC at the time of moisture absorption was 58%, and the difference in crimp ratio (HC-DC) at the time of drying and wetness was 0%. [Comparative Example 2] In Comparative Example 1, After the dyeing process of the knitted fabric, the fluororesin water-repellent processing liquid is used for padding treatment, dried at a temperature of 10 ° C, and then dried at a temperature of 160 ° C for 1 minute, and then rolled by a roller. Rolling (made by Lee Roll), at a roll temperature of 160 ° C, a nozzle pressure of 60 kgf / cm The evaluation results of the knitted fabric obtained by the heat and pressure processing are shown in Table 1. The gas permeability at the time of drying was 14 cc/cm 2 /s, the gas permeability at the time of moisture absorption was 14 cc/cm 2 /s, and the gas permeability reduction rate was 0%. And the moisture permeability is not changed when moisture absorption, and the water leakage resistance is also a knitted fabric of 1 20 cc and the water leakage resistance which is a normal degree of the water-repellent processed product. In addition, the composite-116-201009148 fiber extracted from the knitted fabric is dried. At this time, the crimp ratio DC is 56%, the crimp ratio HC at the time of moisture absorption is 5 6%, and the curl ratio (HC-DC) at the time of drying and wetting is 0%. Example 1 Example 2 Example 3 Example 4 Comparative Example 1 Comparative Example 2 Winding rate of silk in cloth [%] When dry (DC) 64 62 65 61 58 56 When wet (HC) 77 73 79 70 58 56 Poor (HC-DC) 13 11 14 9 0 9 Gas permeability [cc/cm2/s] When dry 39 8 17 3 42 14 When wet 22 5 12 2 41 14 Decrease rate [%] 44 38 29 33 2 0 Water resistance [CC] 1190 27 1475 5 3240 120 Hereinafter, the invention of the above 20 to 28 will be described in detail by way of examples, and the present invention is not limited thereto. Moreover, the physical properties in the examples are as follows. "Measurer" &lt;Intrinsic Viscosity (IV) &gt; For polyethylene terephthalate's quantitative measurement sample, the solvent is o-chlorophenol, which is obtained by conventional method at 35 ° C. For nylon 6 Similarly, a mass mixed solvent such as benzoquinone/tetrachloroethylene was used, and the measurement was carried out at 3 ° C. &lt;Number average molecular weight&gt; The number average molecular weight of the fluorenyl group at both ends is 500 to 5, and the polyamine of hydrazine-117-201009148 (a) and the ethylene oxide adduct of the bisphenol (b) The partial number average molecular weight was obtained by dissolving the measurement sample in a mass mixed solvent such as trifluoroacetic acid/deuterated chloroform, and measuring NMR. From the results of the measurement, the repeating unit of each part was specified, and the number average molecular weight was determined from the result. &lt;Weight ratio of polyether ester decylamine&gt; The composite fiber can be controlled by gear pump adjustment conditions, but the method described in (7) can be used to form the polyamine component of the conjugate fiber. The polyester portion was subjected to NMR measurement, and the weight ratio of the polyether ester decylamine in the polyamide component or the polyester component was calculated by analyzing the result &lt; silk shrinkage ratio in the cloth&gt; After 24 hours in an ambient gas of °C and a humidity of 65% RH, a small piece of 30 cm x 30 cm (n number = 5) was cut from the cloth. Next, the filaments (the side-by-side type composite fiber of modified polyester and polyamine) which were changed by moisture absorption were taken out from each small piece, and the weight of 49/50 mNx9x total tex (100 mg/de) was measured. The length L0 of the yarn was measured, and the length L1 of the yarn under the load of 49/50 mNx9x4/1000x total tex (〇.4 mg/de) was measured after removing the weight for 1 minute. Then, the wire was placed in an atmosphere gas at a temperature of 20 ° C and a humidity of 90% RH for 24 hours, and then the wire length L0' of the 49/50 mNx9x total tex (100 mg/de) load was measured, and after removing the weight for 1 minute, The wire length L 1 ' under a load of 49/50 mNx9x4/1 000x total tex (0.4 mg/de) was determined. -118- 201009148 The shrinkage ratio (DC) at the time of drying, the crimp ratio (HC) at the time of moisture absorption, and the difference in crimp ratio at the time of moisture absorption and drying were calculated from the above-mentioned number of calculus by the following calculation formula.

Crimping rate during drying DC(%) ={ (L0-L1) /L0} xlOO Coiling rate at moisture absorption HC(%) ={ (L0'-L1')/L0’} χΙΟΟ

Difference in shrinkage ratio between moisture absorption and drying (%) = HC-DC Φ &lt;Thickness change rate&gt; After the cloth is placed in an environment of temperature 20 ° C and humidity 65% RH for 24 hours, it is cut from the cloth. A small piece of 30 cm x 30 cm (n number = 5). Next, the thickness (TD) of the cloth after drying for 24 hours in a temperature of 20 ° C and a humidity of 65% RH was measured using an ultra-high precision laser displacement meter (Model LC-2400 manufactured by KEYENCE Corporation). Next, an ultra-high-precision laser displacement gauge (model LC-2400 manufactured by KEYENCE Corporation) was used to measure the thickness of the fabric after being placed at a temperature of 2 (TC, humidity 90% RH for 24 hours) as the thickness at the time of moisture absorption. (TW) Next, the following formula is used to calculate the rate of change in thickness. In addition, the average 値 of the number of η is obtained. The thickness change rate [%] = ( (TW-TD ) / TD ) Χ 100 &lt; anti-transparency &gt; After placing the cloth in an environment of a temperature of 20 ° C and a humidity of 65% RH for 24 hours, a small piece of 3 0 cm × 3 0 cm (n number = 5) was cut from the cloth. Then, the cloth was covered with -119-201009148 On the white paper of the printed black character, the ease of reading the text is evaluated as the transparency at the time of drying in the following three grades. Level 3································································· The first grade·· character can be read. On the other hand, the cloth is blown with a mist, and evenly sprayed until the moisture content of the cloth is 100% by weight relative to the weight of the fabric, and evaluated as the wet prevention in the same manner as described above. Transparency. [Example 5] In a conventional method, spinning Nylon 6 (Ny6) having an intrinsic viscosity (IV) of 1.1 and a polyether ester decylamine (polyamidamine (a) portion) added at a temperature of 290 ° C and a spinning speed of 1 000 m/min The average molecular weight is 15 00, the number average molecular weight of the ethylene oxide adduct (b) is 2000, and the relative viscosity is 2.2). The phthalic acid copolymerized polyethylene terephthalate particles (interpolymerization of isophthalic acid) The ratio was 〇.5 mol%, IV = 0.65), which was spun, and then stretched at an extension temperature of 60 ° C and a stretching ratio of 2.5 times without stretching, followed by heat setting at 130 ° C to obtain a filament. The polyethylene terephthalate blended with the polyether ester decylamine was joined into a side-by-side type in a weight ratio of 50:50 to obtain a 56 dtex/24 fil crimped composite fiber. Next, the above composite fiber was used ( Without boiling water treatment, no shrinkage. No filature), the above composite fiber and 56 dtex/72 fil general polyethylene terephthalate multi-fiber-120 using a double-twist circular knitting machine with a 28-gauge needle. - 201009148 Silk false twisted processing wire (fiber B) is braided into a braided structure as shown in Figure 1. At 130 ° C, the dyeing process is carried out at a holding time of 15 minutes (dyeing into a fluorescent white which is particularly problematic in preventing transparency), and the potential crimping property of the composite fiber is visualized as the crimped fiber A. The water-absorbent processing agent (polyethylene terephthalate-polyethylene glycol copolymer) in a ratio of 2 ml/liter with respect to the dyeing liquid was subjected to the same bath treatment at the same time as the dyeing process, thereby imparting a water-absorbent processing agent to the knitted fabric. Next, the circular braid was subjected to dry heat final setting at a temperature of 160 °C. In the braid, the cross section in the thickness direction is as shown in Fig. 2. One layer (Z layer) is composed only of fibers B, and the other layer (Y layer) is composed only of crimped fibers A, and the Z layer and the Y layer are partially joined. The surface of the knitted fabric viewed from the side of the Y layer is as shown in FIG. 3, and the Y layer and the Z layer are connected in a lattice shape, and the four corner portions of the unjoined γ layer other than the lattice are shrunk when moisture is absorbed. The four corner portions of the Z layer located on the four corner portions of the above-mentioned Y layer become convex portions and together exhibit unevenness to increase the thickness. The knitted fabric has a thickness change rate of 87% at the time of drying and moisture absorption, and a decrease in transparency (level 3) when it is wet. The evaluation results are shown in Table 2. Then, after the T-shirt (sports clothing) is obtained by using the knitted fabric, the transparency at the time of sweating is reduced, which is preferable. [Example 6] A general-purpose polyethylene terephthalate false twisting machine of 56 dtex/72 fil used in Example 5 was carried out using a 28-gauge needle-warp-knit flat knitting machine, and the rear shuttle was fully worn -121 - 201009148 In the yarn (fiber B), the composite fiber (fiber A) used in Example 5 was set in 8 to 8 outlets on the middle shuttle, and the same composite fiber (fiber A) was set on the front shuttle in 8 to 8 output, and the shuttle was later 1〇-12, 中梭10-12-23-34-45-56-67-78-89-87-76-65-54-43-32-21, front shuttle 89-87-76-65-54 -43-32-21-1 0-12-23-34-45-56-67-78 The organization of the machine, the number of stitches on the machine 60 rows of needles / 2.54cm, the conditions are compiled into the velvet-jing Editing. Next, the knitted fabric was subjected to dyeing modification as in Example 5. In the knitted fabric, the cross section in the thickness direction is composed of a portion (Z portion) composed only of the crimped fibers B and a portion (X portion) composed of the crimped fibers A and B, as shown in Fig. 4 . The surface of the knitted fabric is as shown in Fig. 5. The X portion has a rhombic pattern and is continuous with the entire knitted fabric. When wet, the intermediate portion (Z portion) of the rhombic pattern becomes a convex portion and exhibits irregularities to increase the thickness. In the knitted fabric, the rate of change in thickness during drying and moisture absorption was 113%, and it was also found to reduce the transparency during wetting. The evaluation results are shown in Table 2 [Comparative Example 3] In place of the use of the polyethylene terephthalate polyfilament false twist processing yarn (fiber B) used in Example 5, instead of the composite fiber used in Example 5 (fiber A) The knitted fabric obtained in the same manner as in Example 5 had a thickness change ratio of 0% at the time of drying and moisture absorption, and increased transparency at the time of wetting, and was not satisfactory. The evaluation results are shown in Table 2. -122- 201009148 [Table 2] Table 2 Example 5 Example ό Comparative Example 3 Winding rate of silk in cloth [%] When dry (DC) 67 65 71 When absorbing moisture _ 79 78 71 Poor (HC-DC) 12 13 0 When the thickness is dry [mm] 0.82 0.70 0.89 When moisture absorption [mm] 1.53 1.49 0.89 Rate of change [%] 87 113 0 When the barrier is dry, the level 3, the level 3, the level 3, the level 3, the level 3, the level 1 or lower, The invention of the above 29-3 is explained in detail by way of examples, but the invention is not limited thereto. Further, each physical property in the examples was measured by the following method. &lt;Intrinsic viscosity (IV) &gt; For polyethylene terephthalate, a sample was quantitatively measured, and the solvent was determined by using an o-chlorophenol at 35 ° C according to a conventional method. In the case of nylon 6, a mass mixed solvent such as phenol/tetrachloroethane was used in the same manner, and the measurement was carried out at 30 °C. &lt;Number average molecular weight&gt; The number average molecular weight of the polyamine (a) portion having a carboxyl group having a number average molecular weight of 500 to 5,000 and the ethylene oxide adduct (b) portion of the bisphenol is a sample to be measured It was dissolved in a mass mixed solvent such as deuterated trifluoroacetic acid/deuterated chloroform, and NMR was measured. From the results of the measurement, the repeating unit of each -123-201009148 portion was specified, and the number average molecular weight was determined from the results. &lt;Weight ratio of polyether ester tyramine&gt; The composite fiber can be controlled by gear pump adjustment conditions, but the method described in (7) can be used to form a polyamine component of the composite fiber. The polyester portion was subjected to NMR measurement, and the weight ratio of the polyether ester decylamine in the polyamide component or the polyester component was calculated by analyzing the result &lt; crimping ratio of the crimped fiber&gt; 2 (24 hours after the TC, humidity 65% RH atmosphere gas, the crimped fiber A was taken out from the standing cloth, and the wire length L0 under the load of 49/50 mNx9x total tex (100 mg/de) was measured, The yarn length L1 at a load of 49/50 mNx9x4/1000x total tex (0.4 mg/de) was measured after removing the weight for 1 minute. The wire was then placed in an atmosphere of a temperature of 20 ° C and a humidity of 90% RH for 24 hours. After 'measuring the length L0' of the 49/50mNx9x total tex (100mg/de) load, measuring the weight of 49/50mN after removing the weight for 1 minute&gt;&lt;9x4/1000x total tex (0.4mg/de) load The length of the lower wire L1'. Calculate the crimp ratio (DC) during drying from the above-mentioned number 値The shrinkage ratio (HC) during moisture absorption and the shrinkage rate during moisture absorption and drying. The crimp ratio DC (%) = { ( L0-L1 ) / L0 } X 1〇〇-124- during drying 201009148 Crimping rate HC(%) ={ (L0,-L1,)/L0'} when absorbing moisture

Difference in shrinkage ratio between moisture absorption and drying (%) = HC-DC &lt;Thickness change rate&gt; After placing the fabric at a temperature of 2 (TC, humidity 65% RH for 24 hours, 'cut 30cm x 30cm from the fabric The small piece (n number = 5). Next, the cloth was dried after being placed in a temperature of 20 ° C and a humidity of 65% RH for 24 hours using an ultra-high precision laser displacement meter (model φ LC_240 制造 manufactured by KEYENCE Corporation). Thickness of time (TD). Next, the thickness of the cloth after being placed in a temperature of 20 ° C and a humidity of 90% RH for 24 hours was measured using an ultra-high precision laser displacement gauge (Model LC-2400 manufactured by KEYENCE Corporation). Thickness (TW) at the time of moisture absorption. Next, the thickness change rate was calculated by the following formula. Further, the average 値 of η was found to be 5.

Thickness change rate [%] = ( ( TD - TW ) / TD ) xlOO φ * &lt; false twist crimping processed yarn crimping rate &gt; - Winding filaments for testing are wound around a circumference of 1.125m Around the gauge machine, a skein of 3 333 dtex dry fineness is prepared. The skein was suspended from the shackle of the ruler plate, and an initial load of 5.9 cN (6 gr ) was attached thereto, and the skein length L0 was measured at a load of 588 cN (600 gr ). Subsequently, the load was immediately removed from the above skein, and the skein was removed from the ruler plate, and the skein was immersed in boiling water for 30 minutes to exhibit curling. The skein after boiling water treatment was taken out from the boiling water, and the water contained in the skein was sucked off by filtering -125-201009148 paper, and air-dried at room temperature for 24 hours. Hang the air-dried skein on the slat of the ruler plate, and add 5 8 8cN (load of 600g 下方) to the bottom. After 1 minute, measure the length Lla of the skein, then remove the load from the skein, and After 1 minute, the length L2a of the hank was measured. The following formula was used to calculate the crimp ratio (CP) of the test filaments. CP ( % ) = { ( L 1 a-L2a ) / L0 } χ 1 00 [Implementation Example 7] A nylon 6 (Ny 6 ) having an intrinsic viscosity (IV) of 1.1 and a polyether ester of 40% by weight were added at a spinning temperature of 290 ° C and a spinning speed of 1 000 m/min by a conventional method. The polyamine (polyammonium (a) part of the number average molecular weight of 15 00, the ethylene oxide adduct (b) part of the number average molecular weight of 2000, the relative viscosity of 2.2) between the phthalic acid copolymerized poly-p-phenylene Ethylene formate particles (0.5 mole % of isophthalic acid copolymerization, IV = 0.65) were spun and then stretched at an extension temperature of 6 ° C and a stretching ratio of 2.5 times without coiling, followed by 13 CTC. The heat setting is obtained as a filament. The polyethylene terephthalate blended with nylon 6 and polyether ester decylamine is bonded in a weight ratio of 50:50. In the column type, a composite fiber of 84 dtex/24 fil was obtained. Next, the above conjugate fiber (not subjected to boiling water treatment, which did not exhibit crimping. No crepe) was used as a yarn for fluff. On the other hand, a general pair of U0dtex/48fil was used. Ethylene phthalate multifilament false twisted silk (20% crimping rate) used as a yarn for the bottom tissue section, and the use of 24 gauge-126-201009148 needle sinker fluff circular knitting machine, knitted into a loop pile Next, the dyeing process was carried out at a temperature of 130 ° C for 15 minutes, and the potential crimping property of the conjugate fiber was visualized to become the crimped fiber A. At this time, it was 2 ml / with respect to the dye solution. The ratio of the water absorption plus the agent (polyethylene terephthalate-polyethylene glycol copolymer) is treated in the same bath at the same time as the dyeing process to impart a water-absorbent processing agent to the fabric. Then, at a temperature of 160° The terry woven fabric was dry-heated and finally set for 1 minute, and the density of the velvet woven fabric (hair cloth) obtained by φ was 34 strokes of the warp knitting/2.54 cm, and the number of needles of the weft knitting 36 was 2.54 cm. In the loop pile velvet, the section in the thickness direction As shown in Fig. 6, the pile portion is composed only of the crimped fibers A, and the bottom portion of the structure is composed of the crimped fibers A and the fibers B, and the crimping of the crimped fibers A is increased as compared with the moisture absorption upon drying. As shown in Table 3, the result of the evaluation is that the thickness is reduced by moisture absorption, and the heat sensation suppressing effect at the time of sweating can be expected. Next, the woven fabric is used to obtain the sports clothing, and the sweat is knitted. The thickness was reduced and the heat sensation was reduced. - [Example 8] The woven fabric used in Example 7 was subjected to dyeing processing to obtain a cut pile fabric, and then subjected to dry heat final setting as in Example 7. The density of the resulting fabric is a warp knitting 32-row stitch/2.5 4 cm, and a weft knitting 37 straight stitch/2.54 cm. In the braid, the cross-section in the thickness direction is as shown in Fig. 7, and the raised portion is composed only of the crimped fibers A, and the main portion is composed of the crimped fibers A and the fibers -127-201009148 dimension B, compared to the drying. The crimping of the crimped fiber A increases when wet. As shown in Table 3, the results of the evaluation of the knitted fabrics are those in which the heat-suppressing effect at the time of sweating is expected to be reduced due to the decrease in thickness due to moisture absorption. [Comparative Example 4] Except that a polyethylene terephthalate polyfilament 84 dtex/24 fil (fiber B) having a high shrinkage type of boiling water shrinkage of 30% was used instead of the conjugate fiber used in Example 7, Evaluation of the composition obtained in Example 7 @ The results are shown in Table 3. There is no change in the leakage degree during drying and moisture absorption, and the effect of suppressing the heat sensitivity during sweating cannot be expected. Example 7 Example 8 Comparative Example 4 Drying (DC) 58 56 45 Winding rate of silk in cloth [%] When absorbing moisture (HC) 75 71 45 Poor (HC-DC) 17 15 0 When drying [mm] 2.53 3.24 2.52 Thickness moisture absorption [mm] 1.84 2.07 2.52 Rate of change [%] 27 36 0 Hereinafter, the invention of the above 34-3 8 will be described in detail by way of examples, but the invention is not limited thereto. Further, each physical property in the examples was measured by the following method. &lt;Intrinsic viscosity (IV) &gt; -128- 201009148 For polyethylene terephthalate, a quantitative measurement sample 'solvent using o-chlorophenol was obtained according to a conventional method at 35 ° C. In the case of nylon 6, a mass mixed solvent such as phenol/tetrachloroethane was used in the same manner as measured at 30 °C. &lt;Number average molecular weight&gt; * The number average molecular weight of the polyamine derivative φ (a) having a carboxyl group number average molecular weight of 500 to 5,000 at both ends and the ethylene oxide adduct (b) portion of the bisphenol group will be The measurement sample was dissolved in a mass mixed solvent such as trifluoroacetic acid/deuterated chloroform, and NMR was measured. From the results of the measurement, the repeating unit of each part was specified, and the number average molecular weight was determined from the result. &lt;Weight ratio of polyether ester decylamine&gt; The composite fiber can be controlled by gear pump adjustment conditions, but the method described in (7) can be used to form the polyamine component of the conjugate fiber. The polyester portion was subjected to NMR measurement, and the weight ratio of the polyether ester guanamine in the polyamide component or the polyester component was calculated by analyzing the result φ. The crimp ratio of the crimped fiber was set. After 24 hours in an atmosphere of a temperature of 20 ° C and a humidity of 65% RH, the winding fiber A was taken out from the standing cloth, and the length L0 of the yarn under the load of 49/50 mNx9x total tex (100 mg/de) was measured. After removing the weight for 1 minute, the yarn length L1 under a load of 49/50 mNx9x4/100 〇x total tex (0.4 mg/de) was measured. Then, the wire was placed in an atmosphere gas of temperature -129-201009148 degree 20 ° C and humidity of 90% RH for 24 hours, and then the wire length LO' of the 49/50 mNx9x total tex (100 mg/de) load was measured. The filament length L1' at a load of 49/50 mNx9x4/100〇x total tex (0.4 mg/de) was measured after 1 minute of weight. The shrinkage ratio (DC) at the time of drying, the crimp ratio (HC) at the time of moisture absorption, and the difference in the crimp ratio at the time of moisture absorption and drying were calculated from the above-mentioned number of calculus by the following calculation formula.

Crimping rate DC (%) ={ (L0-L1) /L0} xlOO Crimping rate during moisture absorption HC ( %) = { ( L0'-L1') / L0' } 吸 When absorbing moisture Difference in crimp ratio during drying (%) = HC-DC &lt;Thickness change rate&gt; After the cloth was placed in an environment of a temperature of 20 ° C and a humidity of 65% RH for 24 hours, a small piece of 30 cm X 30 cm was cut from the cloth. (η number = 5). Next, the thickness (TD) of the cloth after drying for 24 hours in a temperature of 2 (TC, humidity 65% RH environment) was measured using an ultra-high-precision laser displacement meter (model LC-2400 manufactured by KEYENCE Corporation). The thickness of the cloth after standing for 24 hours in a temperature of 20 ° C and a humidity of 90% RH was measured using a super high-precision laser displacement meter (Model LC-2400 manufactured by KEYENCE Co., Ltd.) as the thickness (TW) at the time of moisture absorption. Next, the thickness change rate was calculated by the following formula, and the average 値 of the number of η was found to be 5.

Thickness change rate [%] = ( ( TD - TW ) / TD ) xlOO -130 - 201009148 &lt; false twist crimping processed yarn crimping rate &gt; Winding filaments for testing are wound around a circumference of 1.125 Around the metering machine, a skein of dryness of 3 3 33 dtex is prepared. The skein was suspended from the shackle of the ruler plate, and an initial load of 5.9 cN (6 gr) was attached thereto, and the skein length L0 was measured at a load of 5 88 cN (600 gr). Subsequently, the load was immediately removed from the above skein, and the skein was removed from the ruler plate, and the skein was immersed in boiling water for 30 minutes to exhibit curling. The skein after boiling water treatment was taken out from the boiling water, the moisture contained in the skein was sucked off with a filter paper, and air-dried at room temperature for 24 hours. Hang the air-dried skein on the slat of the ruler plate, and add a load of 5 88cN ( 60 0gr ) to the bottom. After 1 minute, measure the length Lla of the skein, then remove the load from the skein, and The length of the skein L2a was measured after 1 minute. The crimping ratio (CP) of the test filaments was calculated by the following formula. CP ( %) = { ( Lla-L2a) / L0 } χ 100 [Example 9] A nylon having an intrinsic viscosity (IV) of 1.1 at a spinning temperature of 290 ° C and a spinning speed of 1000 m/min by a conventional method. 6(Ny6), and the addition of 40% by weight of polyetheresteramine (the number average molecular weight of the polyamine (a) moiety is 1,500, and the number average molecular weight of the ethylene oxide adduct (b) is 2000, relative Viscosity 2.2) Polyethylene terephthalate particles copolymerized with phthalic acid (co-polymerization ratio of isophthalic acid is 0.5 mol% • 131 - 201009148 'ΐν = 0·65) to be spun] The coiling was extended at an extension temperature of 60 ° C and a stretching ratio of 2.5 times, followed by heat setting at 13 (TC) to obtain a filament. Polyethylene terephthalate obtained by blending nylon 6 with a polyether ester decylamine The composite fibers were joined in a weight ratio of 50:50 to obtain a composite fiber of 84 dtex/24 fil. Next, the above-mentioned composite fiber (not subjected to boiling water treatment, which did not exhibit crimping. No twist) was used as the yarn for the joint portion. On the other hand, the use of 1 10dteX/48fil general polyethylene terephthalate multifilament false twist processing silk (roll 24%) as a unit with the ground structure yarns, knitting structures and FIG follow of FIG 2002-23 Publication Laid-Open No. 5264 disclosed 2, the three-layer structure knitted fabric.

Next, the dyeing process was carried out at a temperature of 130 ° C for 15 minutes to maintain the potential crimping property of the conjugate fiber as the crimped fiber A. At this time, the water-repellent processing agent (polyethylene terephthalate-polyethylene glycol copolymer) in a ratio of 2 ml/liter with respect to the dyeing liquid was subjected to the same bath treatment at the same time as the dyeing process, giving the knitted fabric Water absorption process agent. Next, the loop pile fabric was dry-heated at a Q temperature of 160 ° C for 1 minute. The density of the three-layer construction fabric is the number of needles in the warp 3 8 courses / 2 · 5 4 c m, and the number of stitches in the weft - 48 in-line / 2.54 cm. The results of the evaluation of the knitted fabric are shown in Table 4, in order to satisfy the decrease in thickness due to moisture absorption. Then, by using the three-layer structure to obtain a sports clothing, the thickness of the knitted fabric is reduced when sweating, and the heat sensation can be reduced. [Comparative Example 5] -132- 201009148 In addition to the conventional 84 dtex/36 fil polyethylene terephthalate multifilament false twisted textured yarn (winding ratio of 1 5%), instead of the composite fiber used in Example 9, The rest is as in the case of Example 9. As shown in Table 4, the results of the evaluation of the obtained knitted fabrics were such that the thickness at the time of drying and the moisture absorption did not change, and the heat-suppressing effect at the time of sweating could not be expected. [Table 4] Example 9 Comparative Example 5 _hour _ 61 73 Winding rate of the yarn in the fabric [%] When absorbing moisture (HC) 75 73 Poor (HC-DC) 15 0 When drying [mm] 2.50 2.31 Thickness suction When wet [mm] 1.97 2.31 Change rate [%] 21 0 Hereinafter, the invention of the above 39-44 will be described in detail by way of examples, but the invention is not limited thereto. Further, each physical property in the examples was measured by the following method. &lt;Intrinsic viscosity (IV) &gt; For polyethylene terephthalate, a sample was quantitatively measured, and a solvent was obtained by using o-chlorophenol at 35 ° C according to a conventional method. In the case of nylon 6, a mass mixed solvent such as phenol/tetrachloroethane was used in the same manner, and the measurement was carried out at 30 °C. -133- 201009148 &lt;Number average molecular weight&gt; The average number of polyamines (a) having a carboxyl group number average molecular weight of 00 to 5,000 at both ends and the ethylene oxide adduct (b) portion of bisphenols Molecular weight The measurement sample was dissolved in a mass mixed solvent such as trifluoroacetic acid/deuterated chloroform, and NMR was measured. From the results of the measurement, the repeating unit of each part was specified, and the number average molecular weight was determined from the result. &lt;Weight ratio of polyether ester decylamine&gt; The composite fiber can be controlled by gear pump adjustment conditions, but the method described in (7) can be used to form the polyamine component of the conjugate fiber. The polyester portion was subjected to NMR measurement, and the weight ratio of the polyether ester decylamine in the polyamide component or the polyester component was calculated by analyzing the result &lt; silk shrinkage ratio in the cloth&gt; After 24 hours in an ambient gas of °C and a humidity of 65% RH, a small piece of 30 cm x 30 cm (n number = 5) was cut from the cloth. Next, the filaments (the side-by-side type composite fiber of modified polyester and polyamine) which changed by the moisture absorption were taken out from each small piece, and the load of 49/50 mNx9x total tex (100 mg/de) was measured. The length L0 of the yarn was measured, and the length L1 of the yarn under the load of 49/50 mNx9x4/1000x total tex (〇.4 mg/de) was measured after removing the weight for 1 minute. Then, the wire was placed in an ambient gas at a temperature of 20 ° C and a humidity of 90% RH for 24 hours, and then the wire length L0' of the 49/50 mNx9x total tex (100 mg/de) load was measured, and the weight was removed by 1 minute. -134- 201009148 After the clock, the length L 1 ' of the wire under the load of 49/50mNx 9x4/1 000 x total tex (0.4mg/de) was measured. The shrinkage ratio (DC) at the time of drying, the crimp ratio (HC) at the time of moisture absorption, and the crimp ratio at the time of moisture absorption and drying * were calculated from the above-mentioned number of calculus by the following calculation formula. « Crimping rate during drying DC(%) = { (L0-L1) /L0} χΙΟΟ φ Crimping rate during moisture absorption HC(%) = { (LO'-Ll,)/L0’} χΙΟΟ

The difference in crimp ratio between moisture absorption and drying (%) = HC-DC &lt;thickness change rate&gt; After the cloth was placed in an environment of temperature 20 ° C and humidity 65% RH for 24 hours, 30 cm x 30 cm was cut from the cloth. Small pieces (η number = 5). Next, the thickness (TD) of the cloth after drying for 24 φ hours in a temperature of 20 ° C and a humidity of 65% RH was measured using an ultra-high-precision laser displacement meter (Model LC-2400 manufactured by KEYENCE Corporation). Next, it was measured using an ultra-high-precision 'laser displacement meter (Model LC-2400 manufactured by KEYENCE Corporation) - the thickness of the cloth after being placed at a temperature of 2 (TC, humidity 90% RH for 24 hours as the thickness at the time of moisture absorption) (TW) Next, the thickness change rate is calculated by the following equation. Further, the average 値 of the number of n is 5. The thickness change rate [%] = ((TD-TW) / TD ) 〔 [Example 1 0] - 135- 201009148 Nylon 6 (Ny6) having an intrinsic viscosity (IV) of 1.1 and a concentration of 40% by weight at a spinning temperature of 290 ° C and a spinning speed of 10 μm/min by a conventional method The condensation of phthalic acid decylamine (the number average molecular weight of the polyamine (a) part is 1 500 00, the number average molecular weight of the ethylene oxide adduct (b) part is 2000, the relative viscosity is 2.2). Ethylene terephthalate particles (inter-isophthalic acid copolymerization ratio of 0.5 mol%, IV = 0.65) were spun, and then unwound and extended at an extension temperature of 6 (TC, extension ratio of 2.5 times, followed by Heat setting at 130 ° C to obtain a filament. Polyethylene terephthalate blended with nylon 6 and polyether ester decylamine in a weight ratio For the 50:50 method, it is joined into a side-by-side type to obtain a 56 dtex/24 fil crimped composite fiber. On the other hand, the adjusted acid component is composed of a molar ratio of 93/7 of terephthalic acid and isophthalic acid, After the alcohol component is composed of ethylene glycol and has a copolymerized polyester having a relative viscosity of 1.45, the copolymerized polyester resin is melt-spun, and is taken up at a take-up speed of 3 500 m/min to produce a partial alignment without extension. Polymeric polyethylene terephthalate was used as the fiber B. The unstretched multifilament yarn was placed between the first roll at a temperature of 65 ° C and a second roll at a temperature of 75 t without heat setting. On the other hand, a stretching ratio of 1.4 times was used to obtain a non-crimped copolymerized polyester filament yarn of 84 dteX/24 fil (boiling water shrinkage ratio of 30%). Next, the above composite fiber was used (no boiling treatment, no curling was exhibited). Non-twisted wire) and fiber B, using a double-twist circular knitting machine with a 28-gauge needle, braided into a knitted fabric as shown in Fig. 9. Next, at a temperature of 13 ° C, the holding time is 15 minutes. In-136- 201009148 dyeing process to make the composite crimping performance Visualized as a crimped fiber A. At this time, by dyeing a water-absorbent processing agent (polyethylene terephthalate-polyethylene glycol copolymer) in a ratio of 2 ml/liter with respect to the dye liquor At the same time, the same bath treatment was carried out to impart a water-absorbent processing agent to the knitted fabric. Then, the knitted fabric was subjected to dry heat at a temperature of 160 ° C for final setting for one minute.

In the braid, the section in the thickness direction is as shown in Fig. 10. One layer (Z' layer) is composed only of fiber B, and the other layer (Y layer) is composed only of crimped fiber A, and the Z layer and the Y layer are partially formed. link. Fp The surface of the knitted fabric viewed from the side of the Y layer is as shown in Fig. 11. The Y layer and the Z layer are connected in a lattice shape, and the four corner portions of the unjoined Y layer other than the lattice are convex when moisture is absorbed. . As a result of the shrinkage of the four corner portions due to moisture absorption, there is no convex portion, and the braid is flat and the thickness is reduced. In this weave, the rate of change in thickness during drying and moisture absorption was 33%. When the t-shirt (sports material) is used and worn, the heat is reduced in order to satisfy the feeling of sweating when sweating. The evaluation results are shown in Table 5. # ' [Example 1 1]. Using a 28-gauge needle-warp-spinning weaving machine, the rear shuttle is full of the B used in the embodiment 10, and is set to 8 in 8 out on the middle shuttle. In the composite fiber used in the same, the composite fiber (fiber A) is also set on the front shuttle with 8 in 8 out, and then the shuttle 10-12, the middle shuttle 10-12-23-34-45-56-67-78- 89-87-76-65-54-43-32-21, front shuttle 89-87-76-65-54· 43-32-2 1 -1 0- 1 2-23-34-45-56-67 The organization of -78, the number of stitches on the machine is 60, the number of stitches is 2_54cm, and the knitting condition is compiled into a velvet-warp. The knitted fabric was dyed and modified as in Example 10, in the same manner as in Example 10. In the braid, the section in the thickness direction is a portion (Z part) composed of polyethylene oxide polyethylene fiber (fiber B) of '84 dtex/24 fil as shown in Fig. 12 and a crimped fiber A And the fiber part (Y part) is composed. As shown in Fig. 13, the surface of the braid is in the shape of a rhombus pattern and is continuous on the entire knitted fabric. When dried, the rhombic portion (Y portion) becomes a convex portion and exhibits irregularities, but the Y portion shrinks after moisture absorption, and the overall composition Flat and reduced in thickness. In this weave, the rate of change in thickness during drying and moisture absorption was 36%. When the t-shirt (moving material) is used as the clothing, the wearer is reduced in order to satisfy the heat sensitivity during sweating. The evaluation results are shown in Table 5. [Comparative Example 6] The same procedure as in Example 1 was carried out except that a 56 dtex/24 fil polyester crimped yarn (boiling water shrinkage of 10% 'retraction ratio of 15%) was used instead of the crimped fiber A. The evaluation results of the knitted fabric are shown in Table 5. The change rate of the thickness during drying and moisture absorption was 0%, and there was no change. -138- 201009148 [Table 5] Table 5 Example 1 〇 Example 11 Comparative Example 6 Winding rate of silk in cloth [%] When dry (DC) 61 59 68 When absorbing moisture (HC) 76 72 68 Poor (HC -DC) 15 13 0 When the thickness is dry [irnn] 0.97 1.04 0.95 When moisture absorption [mm] 0.65 0.67 0.95 Change rate [%] 33 36 0 Hereinafter, the invention of the above 45-57 will be described in detail by way of examples, but the present invention It is not subject to any of these restrictions. Further, each physical property in the examples was measured by the following method. <Intrinsic Viscosity (IV) &gt; For polyethylene terephthalate, a quantitative sample was measured, and the solvent was obtained by using o-chlorophenol at a conventional temperature of 35 ° C. In the case of nylon 6, a mass mixed solvent such as phenol/tetrachloroethane was used in the same manner, and the measurement was carried out at 30 °C. &lt;Number average molecular weight&gt; The number average molecular weight of the polyamine (a) portion having a carboxyl group having a number average molecular weight of 500 to 5,000 and the ethylene oxide adduct (b) portion of the bisphenol is a sample to be measured It was dissolved in a mass mixed solvent such as deuterated trifluoroacetic acid/deuterated chloroform, and NMR was measured. From the results of the measurement, the repeating unit of each part was specified, and the number average molecular weight was determined from the result. -139- 201009148 &lt;Weight ratio of polyether ester decylamine&gt; The composite fiber can be controlled by gear wheel conditioning conditions, but the method of (7) can be used to form a composite fiber. The guanamine moiety and the polyester moiety were subjected to NMR measurement, and the weight ratio of the polyether ester decylamine in the polyamide component or the polyester component was calculated by analyzing the result &lt;the filament shrinkage ratio in the fabric&gt; After being placed in an atmosphere of a temperature of 20 ° C and a humidity of 65% RH for 24 hours, a small piece of 30 cm x 30 cm (n number = 5) was cut from the cloth. Next, the filaments which change the amount of curl due to moisture absorption (the side-by-side type composite fiber of modified polyester and polyamine) are taken out from each small piece, and the load of 49/50 mNx9x total tex (100 mg/de) is measured. The length L0 of the yarn was measured, and the length L1 of the yarn under the load of 49/50 mNx9x4/1 000x total tex (〇.4 mg/de) was measured after removing the weight for 1 minute. Then, the wire was placed in an atmosphere of a temperature of 20 ° C and a wetness of 90% RH for 24 hours, and then the wire length L0' of the 49/50 mNx9x total tex (100 mg/de) load was measured, and the weight was removed. The length L 1 ' of the wire under the load of 49/50 mNx9 x4/1 000 x total tex (0.4 mg/de) was determined after minutes. The shrinkage ratio (DC) at the time of drying, the crimp ratio (HC) at the time of moisture absorption, and the difference in the crimp ratio at the time of moisture absorption and drying were calculated from the above-mentioned number of calculus by the following calculation formula. -140- 201009148

Crimping rate DC (%) ={ (LO-Ll) /L〇} χίοο The shrinkage rate during moisture absorption HC(%) ={ (LO'-Ll,)/L〇,} xl00 Hygroscopic Difference between the shrinkage rate at the time of drying and drying (%) = HC-DC &lt; Area change rate&gt; Five woven fabric samples of 30 cm in the warp direction and 30 cm in the weft direction were prepared at a temperature of 20 ° C and a humidity of 65% RH. After being left to be conditioned for 24 hours or more, an imprint was applied to each of 20 cm in the sensation and 20 cm in the latitudinal direction. Subsequently, the sample was allowed to stand at a temperature of 20 ° C and a humidity of 90% RH for 24 hours or more, and then the length between the marks in the warp and weft directions (η number = 5) was measured, and the area change rate was calculated from the following formula. Area change rate (%) = ((SD-SW) /SD) χΙΟΟ where SD: temperature 20 ° C 'humidity 65% RH under the direction X latitude _ imprinted inner area (400 cm 2 ), SW: temperature 20 ° C, Humidity 90% RH 'The area inside the imprint of the X latitude. [Example 1 2] Nylon 6 (Ny6) having an intrinsic viscosity (IV) of 1.1 was prepared at a spinning temperature of 290 ° C and a spinning speed of 10 μm/min by a conventional method. 40% by weight of polyether ester decylamine (polyammonium (a) part of the number average molecular weight of 15 00, ethylene oxide adduct (b) part of the number average molecular weight of 2000, relative viscosity of 2.2) between phthalic acid Copolymerized polyethylene terephthalate-141 - 201009148 Ethylene glycol diester particles (inter-isophthalic acid copolymerization ratio of 0.5 mol% 'IV = 0.65) were spun, then not coiled to extend temperature 60 °c The stretching ratio was extended by 2.5 times, followed by heat setting at 130 ° C to obtain a filament shape. A polyethylene terephthalate obtained by blending nylon 6 with a polyether ester decylamine was joined in a side-by-side manner in a weight ratio of 50 · · 50 to obtain a composite fiber of 56 dtex / 24 fil. Next, a single circular knitting machine using a 28 gauge needle, and using the above composite fiber (not subjected to boiling water treatment, showing no crimping. No silk), and the above composite fiber and a general polyurethane of 22 dtex/lfil The elastic yarns (fibers C) were aligned on the braiding machine (bare fiber insertion) and woven into a flat needle tissue fabric in accordance with the texture diagram shown in FIG. At this time, the above-mentioned polyurethane elastic yarn was stretched and kneaded at a draw ratio of 2.0 times. The fabric was slackened (temperature 60 ° C, time 1 minute) and predetermined type (temperature 180 ° C, time 1 minute), and then dyed at a temperature of 130 ° C for 15 minutes to make the potential of the composite fiber The crimping performance is manifested as the crimped fiber A. At this time, the water-repellent processing agent (polyethylene terephthalate-polyethylene glycol copolymer) in a ratio of 2 ml/liter with respect to the dyeing liquid was subjected to the same bath treatment at the same time as the dyeing process, giving the knitted fabric Water absorption process agent. Next, the knitted fabric was dry-heated at a temperature of 160 ° C for 1 minute. The evaluation results of the obtained knitted fabrics are shown in Table 6, which is a knitted fabric having a small area at the time of moisture absorption. When the T-shirt (sports material) is used and worn, the size of the T-shirt is easy to wear when worn, but the size of the T-shirt is small when sweating, and the T-shirt is conformable to the body and feels sporty. - 142 - 201009148 [Example 1 3] A single circular knitting machine using a 28-gauge needle, and the general assembly of the composite fiber used in Example 12 and 3 3dtex/3 6fil was formed by the knitting shown in FIG. Ethylene phthalate multifilament false twist processing yarn (fiber B) and 22 dteX/lfil general polyurethane elastic yarn (fiber C) were knitted. At this time, the above-mentioned polyurethane elastic yarn was stretched and kneaded at a draw ratio of 2.0 times. Next, the knitted fabric was subjected to the same dyeing and finishing treatment as in Example 12. The evaluation results of the obtained knitted fabrics are shown in Table 6, which is a knitted fabric having a small area at the time of moisture absorption. When the t-shirt (sports material) is used and worn, it is easy to wear when worn, but the size of the T-shirt is small when sweating, and the t-shirt is docile to the body and feels sporty. [Example 1 4] The fiber B (3 3dtex/3 6fil) used in Example 13 was worn on the front shuttle using a 28-gauge needle-knit-knit flat knitting machine, and was placed on the shuttle 1 shuttle. The composite fiber A (56 dtex/24 fil) used in the example 12 was set, and the above-mentioned composite fiber A was set by 14 out of 9 in 5 shuttles on the shuttle 2 shuttle, and the shuttle was fitted with the elasticity used in the example 12 Fiber C (22dtex/lfil), and former shuttle: 10-23, medium shuttle 1: 1 0-1 2-23-34-45-56-67-78-89-910-1011.1112-1213-1314-1415· 1514-1413-1312-1211-1110-109-98-87-76-65-54-43-32-21 φ shuttle 2 -143- 201009148 :15 14-1413-13 12-121 1-1 1 10- 109-98-87-76-65-54-43-32-21-10-23-34-45-56-67-78-89-910-1011-1112-1213-1314-1415, after the shuttle: 12 The -10 is organized into a velvet-warp woven fabric. At this time, the above-mentioned polyurethane elastic yarn was stretched and kneaded at a draw ratio of 2.0 times. Then, the knitted fabric was subjected to dyeing modification processing as in Example 12. The evaluation results of the obtained knitted fabrics are shown in Table 6, which is a knitted fabric having a small area at the time of moisture absorption. When the T-shirt (sports material) is used and worn, the size is loose and easy to wear when worn, but the size of the T-shirt becomes small when sweating, and the T-shirt is conformable to the body and feels sporty. [Comparative Example 7] A composite circular fiber A was aligned on a knitting machine using a single circular knitting machine of a 28 gauge needle, and knitted into a jersey tissue fabric as in Example 12. Next, the knitted fabric was subjected to the same dyeing and finishing treatment as in Example 12. The evaluation results of the obtained knitted fabrics are shown in Table 6, which is a knitted fabric having a small area at the time of moisture absorption. However, after using the knitted fabric to make a T-shirt (sports material) and wearing it, the size is loose and easy to wear when wearing, and the size of the T-shirt is not small when sweating, but since the knitted fabric does not contain elastic fibers, the clothes for the body Insufficient fit and lack of satisfactory athleticism. [Comparative Example 8] A circular knitted fabric was knitted as in Example 12 except that a general polytrimethylene terephthalide false twisted yarn of 56 dtex/24 fil was used instead of the composite fiber a in Example 12. Next, the knitted fabric was dyed as in Example 12 -144-201009148. The results of the evaluation of the resulting fabrics are shown in Table 6, which is the area change + $ in the case of moisture absorption. After using this chock to make a T-shirt (sports material) and wearing it, there is no change in the size of the T-shirt before and after the sweat, and there is no change in the conformity of the body, and there is no improvement in exercise. [Table 6] Example 12 Example 13 Example 14 Comparative Example 7 Comparative Example 8 Winding rate of silk in cloth [%] When dry (DC) 63 61 58 61 54 When absorbing moisture (HC) 76 72 72 75 54 Poor (HC-DC) 13 11 14 14 0 When the area of the fabric is dry 400 400 400 400 400 When absorbing moisture 371 374 386 361 400 Rate of change [%] 7.3 6.5 3.5 9.8 0.0 Industrial use possibility ❹ According to the invention, When the moisture absorption is increased (the appearance length becomes shorter), the fiber having a reduced air permeability at the time of moisture absorption and the fiber product using the cloth are provided. When such a fiber product is worn, it is possible to improve the warmth retention by reducing the gas permeability when it is raining or snowing, and to suppress the effect of water infiltrating into the clothes. Further, according to the present invention, it is possible to obtain a cloth which is improved in moisture resistance due to moisture absorption. When such a fabric is used as a garment for outerwear, a fabric for lining, and a sportswear for sports, it is possible to suppress the effect of making the skin or underwear transparent even when the clothes are wet when sweating or raining. -145- 201009148 Further, according to the present invention, in the case where the upright portion contains the crimped fibers, the crimping rate of the crimped fibers is reversibly increased by moisture absorption, and the height of the standing hair becomes small. Providing a fabric which reduces the warmth of the fabric by lowering the thickness of the fabric, and which is capable of reducing the heat sensation during sweating and the fiber product using the raised fabric, is extremely expensive. Further, according to the present invention, the three-layer structure fabric composed of the bottom portion of the surface portion and the joint portion connecting the surface portion of the surface and the bottom portion is formed by the reversible increase of the crimp ratio when the joint portion absorbs moisture. The fiber makes the thickness of the fabric smaller. As a result, it is possible to provide a three-layer structure fabric which can reduce the heat sensation during sweating and a fiber product using the fabric, and the industrial price is extremely high. Further, according to the present invention, a cloth which is reduced in thickness due to moisture absorption can be obtained. When the fabric is used for garments for outerwear, clothing for lining, and sportswear, it has a low heat sensitivity when sweating, and its industrial use price is extremely high. Further, according to the present invention, it is possible to obtain a cloth having improved fit when sweating. When the fabric is used for sportswear or lining, it is easy to put on and take off, and it has the effect of being close to the body during exercise and excellent in sports support. The industrial use price is extremely high. - BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is an example of an organization diagram of a fabric related to the present invention. Fig. 2 is a schematic view showing an example of a cross section of a fabric according to the present invention, wherein (1) is dry and (2) is wet. Fig. 3 is a schematic view showing an example of a fabric related to the present invention. -146- 201009148 Fig. 4 is a schematic view showing an example of a cross section of the fabric of the present invention, wherein (1) is dry and (2) is wet. Fig. 5 is a schematic view showing an example of a fabric related to the present invention. Fig. 6 is a view schematically showing the rag fabric (bucket) of the present invention. Fig. 7 is a view schematically showing the woven fabric (cut velvet) of the present invention. Fig. 8 is a view schematically showing a three-layer structure fabric of the present invention. Figure 9 is an illustration of an organization diagram of a fabric related to the present invention. Fig. 10 is a schematic view showing an example of a cross section of a fabric according to the present invention, wherein (1) is dry and (2) is wet. Fig. 11 is a schematic view showing an example of a fabric related to the present invention. Fig. 12 is a schematic view showing an example of a cross section of a fabric according to the present invention, wherein (1) is dry and (2) is wet. Fig. 13 is a schematic view showing an example of a fabric related to the present invention. Fig. 14 is a view showing an example of the organization of the related fabric of the present invention. Fig. 15 is a view showing an example of the organization of the related fabric of the present invention. Fig. 16 is a schematic view showing an example of a fabric related to the present invention. ' [Main component symbol description] 21 : Z layer 22 : connection portion 23 : Y layer 24 : portion 25 connected to the Z layer : portion not connected to the Z layer 26 : Z portion - 147 - 201009148 27 : X portion 28 : Z portion 29: X portion 51: Z layer 52: connection portion _ 53 : Y layer 54: portion 55 connected to the Z layer: portion not connected to the Z layer 56: Y portion 57: Z portion 58: Z portion 59 : Y part 61 : Z part 62 : Y part 1 ~ 2 4 : Wire order C : Cylinder side © D : Dial side 〇 : Pinch side knitting X : Cylinder side knitting ¥ : Cylinder side ring a : Composite fiber b: Polyester multifilament A: Composite fiber (fiber A) 56dtex/24fil

B: Polyethylene terephthalate multifilament false twist processing yarn (fiber B-148-201009148) 33dtex/36fil C: polyurethane elastic yarn (fiber C) 22dtex/lfil

-149-

Claims (1)

201009148 VII. Patent application scope: 1- A fabric characterized by a difference (HC-DC) between the crimping rate HC (%) when moisture absorption and the crimping ratio DC (%) during drying is 0.5% or more. The crimped fiber A; in the case of drying, the sample is placed in a state of a temperature of 20 ° C and a humidity of 65% RH for 24 hours. On the other hand, when the moisture is absorbed, the sample is placed at a temperature of 20 °. C. The state after 24 hours in an environment with a humidity of 90% RH. 2. The fabric of claim 1, wherein the crimped fiber A is a composite fiber obtained by joining two components having different moisture absorption rates into a side-by-side type. 3. The fabric of claim 2, wherein the component having a lower moisture absorption rate is a polyester component, and on the other hand, the component having a higher moisture absorption rate is a polyamide component. 4. The fabric of claim 3, wherein the polyester component comprises 60 to 99.5 mol% of ethylene terephthalate units in repeating units constituting the polyester, and ethylene isophthalate. The unit is composed of a copolymerized polyester of 0.5 to 40 mol%, and the polyester component contains 5 to 55% by weight of a polyether ester decylamine relative to the weight of the polyester. 5. The fabric of claim 1, wherein the fabric contains the crimped fibers B as non-coiled or moisture-absorbing, and the crimped fibers B are used as the other fibers. 6. The fabric of claim 5, wherein the fiber B is a polyester fiber. -150- 201009148 7. The fabric of claim 5, wherein the fiber b is a multifilament having a single filament fineness of 1 dtex or less and a number of filaments of 30 or more. 8. The fabric of claim 5, wherein the fabric is a fabric or a knitted fabric and is comprised by aligning the crimped fibers A with the fibers B. 9. The fabric of claim 5, wherein the fabric is a fabric or a knitted fabric, and the crimped fibers A and B are alternately disposed as a filament of the fabric. Φ 10. The fabric of claim 5, wherein the fabric is a fabric or a knitted fabric, and the fabric comprises the core-sheath type composite yarn in which the crimping and weaving A is in the core and the fiber B is in the sheath. 11. The fabric of claim 1, wherein the fabric is a multi-layer construction fabric having a multi-layer structure of two or more layers, and at least 30% by weight of the total fiber weight constituting the layer in at least one layer is the above-mentioned crimped fiber A 〇12. For the fabric of the first application of the patent scope, the fabric has the coverage factor CF (dry) in the range of 2000~4500 as defined below. Fabric: CF=(DWp/ll) 1/2xMWp+ ( DWf/1.1 ) 1/2xMWf where DWp is the warp total denier (dtex), MWp is the warp density (bar/2.54cm), DWf is the weft total denier (dtex), and MWf is the weft density ( Article / 2.5 4cm). 13. The fabric of claim 1 wherein the fabric is 40-151 - 201009148. The number of stitches (wale) / 2.54 cm or more and 5 turns of stitches (c〇urse) / 2.54 cm or more. 14. The fabric of claim 1 wherein the fabric is subjected to heat and pressure processing. 15. For the fabric of the first application of the patent scope, the water is processed by the water. 16. The fabric of claim 1 wherein the fabric during drying has a gas permeability of 50 cc/cm2/s or less. 17. For the fabric of the first application of the patent scope, the rate of decrease in the permeability of the fabric when moisture is absorbed is defined as 10% or more by the following formula: The rate of decrease in permeability (%) = (APD-APH) / APDxlOO where APD is The air permeability (ec/cm2/s) of the fabric during drying, and the air permeability (ec/cm2/s) of the fabric when moisture is absorbed. 18. For the fabric of the first application of the patent scope, the leakage water of the fabric is 2000 cc or less, wherein the 'water leakage is determined by using a Bundesmann rain test device of Jis L 1092, 6.3 (rain test A method). The total amount of water is 7 liters / minute of water leakage in 10 minutes. A fibrous product obtained by using the fabric of any one of the above claims, and selected from the group consisting of a garment for outerwear, a garment for lotus, and a garment for lining. 20. For example, in the fabric 1 of the patent application scope 5, the thickness (TD) from the drying of the cloth - 152 - 201009148 and the thickness (TW) at the time of moisture absorption are calculated by the following formula: the thickness change rate is 5% or more: %) =( (TW-TD) /TD) xlOO where the thickness during drying is the thickness of the cloth in a state where the cloth is placed at a temperature of 20 ° C and a wet I degree of 65% RH for 24 hours, and the other side The thickness of the surface is the thickness of the cloth in a state where the cloth is placed in a temperature of 20 ° C and a humidity of 90% RH for 24 hours. 21. The fabric of claim 20, wherein the cloth has a portion (Y portion) composed only of the crimped fibers A and a portion (Z portion) composed only of the fibers B, and the Y portion is formed Continuously connected in the direction and/or the weft direction. 2. The fabric of claim 20, wherein the cloth has a portion (Z portion) composed only of the above-mentioned fibers B and a portion (X portion) composed of the above-mentioned crimped fibers A and the above-mentioned fibers B, and the above X The partial system* is continuously connected in the warp direction and/or the weft direction. 23. The fabric of claim 20, wherein the cloth has a portion (X portion) composed of the crimped fiber A and the fiber B, and a portion (Y portion) composed only of the crimped fiber A, and The above-mentioned Y portion of the fabric is continuously joined to the crucible in the warp direction and/or the weft direction. The fabric of claim 20, wherein the fabric has a portion composed of the crimped fiber A and the fiber B described above. (Part X) and -153- 201009148 only the portion (Y portion) of the crimped fiber A described above and the portion (Ζ portion) composed only of the above fiber bundle, and the above-mentioned warp portion is oriented in the warp direction and/or The weft direction is continuously connected. 25. The fabric of claim 20, wherein the fabric is a multi-layer fabric composed of two or more layers, and has a layer composed of the above-mentioned crimped fiber bundles and fibers B, and a layer composed only of the above-mentioned fibers B, and the former The layer is connected to the layer portion of the latter. 26. The fabric of claim 20, wherein the fabric is a multi-layer fabric composed of two or more layers, and has a layer composed of the crimped fibers A and fibers B, and a layer composed only of the crimped fibers A, And the layer of the former is connected to the layer of the latter. 27. The fabric of claim 20, wherein the fabric is a multi-layer fabric composed of two or more layers, having a layer composed only of the crimped fibers A, and a layer composed only of the fibers B, and the layer of the former Connected to the layer of the latter. 28. A fibrous product obtained by using the fabric of any one of claims 19 to 26, and selected from the group consisting of a garment for outerwear, a garment for sportswear, and a garment for lining. 29. The fabric of claim 1, wherein the fabric is composed of a cut pile and/or a loop pile, and a base fabric composed of a bottom tissue portion, and the above-mentioned standing hair Included in the section A. The fabric of claim 29, wherein the base structure is composed of polyester fibers. -154- 201009148 3 1. For the fabric of claim 29, the fabric is subjected to water absorption processing. 32. The fabric of claim 29, wherein the thickness change (TD) from the drying of the cloth and the thickness (TW) at the time of moisture absorption are calculated to have a thickness change rate of 5% or more: » thickness change rate (%) =( (TD-TW) /TD) χΙΟΟ where the thickness of the so-called drying is the thickness of the cloth in a state where the fabric is placed in a temperature of 20 ° C and a humidity of 65% RH for 24 hours, and the other is called The thickness at the time of moisture absorption is such that the cloth is placed at a temperature of 2 (TC, humidity, 90% RH, and the thickness of the cloth is 24 hours later. 33. - Fiber products] is used in the patent application range 29~32 Any of the fabrics' is selected from the group consisting of clothing, wool sanitary ware, sweaters, outerwear, sportswear, linings, diapers, and quilts, medical and hygiene products, pajamas, and chairs. Or a group of surface materials such as sofas, carpets, car seat materials, and indoor products. 34. The fabric of the scope of the patent application is linked to the bottom of the organization and the bottom of the linked table. Three-layer construction fabric And the above-mentioned joint portion includes the above-mentioned crimped fiber A. 35. The fabric of claim 34, wherein the bottom structure portion is made of polyester fiber. 36. The fabric of claim 34, wherein Applying water absorbing to the fabric. -155- 201009148 37. For the fabric of claim 34, the thickness change rate calculated from the thickness (TD) of the fabric when drying and the thickness (TW) of moisture absorption is as follows. 5% or more: Thickness change rate (%) = ((TD-TW) / TD) χίοο where 'the thickness of the so-called dryness is placed in a state of temperature 2 (rc, humidity 65% RH environment for 24 hours) The thickness of the cloth, on the other hand, the thickness of the so-called moisture absorption is the thickness of the cloth in the state of temperature 2 (rc, humidity 90% RH environment for 24 hours. 38. - a kind of fiber products, which are used Patent application No. 34-37, which is selected from the group consisting of clothing, wool sanitary garments, sweaters, garments for outerwear, sports clothing, lining materials, diapers and sheets for care, etc. Supplies, pajamas and bedding a group consisting of a surface material such as a chair or a sofa, a carpet, a car seat material, and an indoor product. 39. The fabric of claim 5, wherein the thickness (TD) from the drying of the cloth and the thickness during moisture absorption (TW) The thickness change rate calculated by the following formula is 5% or more: Thickness change rate (%) = (( TD - TW) / TD) X 1 〇〇 where the thickness during drying is to place the cloth at temperature 2 The thickness of the fabric in the state of 24 hours after the humidity and 65% RH environment, and the thickness of the so-called moisture absorption is to place the fabric at a temperature of 2 〇, humidity -156- 201009148 9 0% RH The thickness of the cloth in the state after 24 hours. 40. The fabric of claim 39, wherein the fiber B is a fiber obtained by thermally shrinking a polyester fiber having a boiling water shrinkage ratio of 20% or more. [41] The fabric of claim 39, wherein the cloth has a portion (Y portion) containing the crimped fiber A and a portion (Z portion) composed only of the fiber B, and the Y portion is formed by The direction and the φ / or weft direction are continuously connected. 42. The fabric of claim 39, wherein the cloth has a portion (Y portion) containing the crimped fiber A and a portion (Z portion) composed only of the fiber B, and the Y portion and the Z portion are on the cloth. Each of them is arranged in a rhombus pattern or a stripe shape or a rib shape in a width of 5 mm or more. 43. The fabric of claim 39, wherein the fabric is a fabric composed of two layers, wherein the first layer comprises the crimped fiber A, and the second layer comprises only the fiber B, and the first layer is The second layer is partially connected. 44. A fibrous product comprising the fabric of any one of the above-mentioned claims, wherein the fabric is selected from the group consisting of a garment for outerwear, a garment for sportswear, and a garment for lining. 45. The fabric of claim 5, wherein the area change rate (SD) from the drying of the cloth and the area (sw) of the moisture absorption are calculated to be 1% or more: area change rate (%) =(( SD-SW) /SD) χ100 -157- 201009148 where the area of the drying is the cloth area placed in the state of temperature 2 (rc, humidity 65% RH environment for 24 hours, another - In the aspect, the area at the time of moisture absorption is a cloth area which is placed in a state of temperature 2 (rc, wet g 90% RH for 24 hours). 46. The fabric of claim 45, wherein the fiber B is a polyurethane elastic fiber or a polyether ester elastic fiber. 47. The fabric of claim 46, which comprises a crimping ratio which has no change in the crimping ratio when it is not crimped or moisture absorbing. The non-elastic fiber C is used as the other fiber. 48. The fabric of claim 47, wherein the fiber C is a polyester fiber. 49. The fabric of claim 47, wherein the cloth has the crimped fiber A And the part (Y part) composed of the above fiber B The non-elastic fiber C and the portion (Z portion) of the fiber B, and the Y portion is continuously connected in the warp direction and/or the weft direction. 50. The cloth of claim 47, wherein the cloth a portion (Z portion) composed of the inelastic fiber C and the elastic fiber B, and a portion (X portion) composed of the crimped fiber A and the inelastic fiber C and the elastic fiber B, and the X portion The fabric is continuously connected in the warp direction and/or the weft direction. 51. The fabric of claim 47, wherein the fabric has the crimped fiber A and the non-elastic fiber C and the elastic fiber B-158- 201009148 a part (part X), a portion (Y portion) composed of the crimped fiber A and the elastic fiber B, and the γ portion of the cloth is continuously connected in the warp direction and/or the weft direction 52. The fabric of claim 47, wherein the fabric has a portion (X portion) of the crimped fiber A and the fiber C and the elastic fiber b, and a portion (Y portion) composed of the crimped fiber A and the elastic fiber 4B, and a portion (Z portion) composed of the inelastic fiber C and the elastic fiber B, and the Y portion is formed in the warp direction and/or 53. The fabric of claim 45, wherein the fabric is a two-layer fabric, one of which consists solely of the crimped fibers A and the other of which is comprised only of the fibers B. 54. The fabric of claim 47, wherein the fabric is a multi-layered fabric composed of three or more layers, the layer comprising the non-elastic fibers C of the crimped fibers Ag, and only the non-elastic fibers described above. The layer is formed with a layer composed only of fibers B. [5] The fabric of claim 47, wherein the fabric is a multi-layer fabric composed of three or more layers, and has a layer composed of the above-mentioned non-elastic fibers C of the crimped fibers, and only the above-mentioned roll The layer of the reduced fiber a structure @ and the layer composed only of the above elastic fiber B. The fabric of claim 47, wherein the fabric is a multi-layered fabric composed of three or more layers, and has a layer composed only of the above-mentioned crimped fibers n A and a layer composed only of the above-mentioned inelastic fibers c And a layer composed only of elastic fibers B. -159- 201009148 57. A fibrous product comprising the fabric of any one of the claims 45 to 56 and selected from the group consisting of a garment for outerwear, a sportswear, and a garment for lining. G -160-