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TW201007351A - Photomask and photo alignment process using the same - Google Patents

Photomask and photo alignment process using the same Download PDF

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Publication number
TW201007351A
TW201007351A TW97130393A TW97130393A TW201007351A TW 201007351 A TW201007351 A TW 201007351A TW 97130393 A TW97130393 A TW 97130393A TW 97130393 A TW97130393 A TW 97130393A TW 201007351 A TW201007351 A TW 201007351A
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Taiwan
Prior art keywords
light
substrate
lens
wavelength
reticle
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TW97130393A
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Chinese (zh)
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TWI372940B (en
Inventor
Feng-Sheng Lin
Hang-Lian Lee
Jenn-Kuan Kao
Heng-Hsien Li
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Chi Mei Optoelectronics Corp
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Priority to TW097130393A priority Critical patent/TWI372940B/en
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Abstract

A photomask includes a lens array and a wave retarder array. The lens array includes alternatively arranged first lenses and second lenses. Each first lens and each second lens are respectively a trapezoid pillar. The trapezoid pillar has a top surface, a bottom surface parallel with the top surface, two trapezoid surfaces parallel with each other and two inclined surfaces. An area of the top surface is smaller than that of the bottom surface. The line passing through geometry centers of the two trapezoid surfaces of each first lens is a first straight line, the line passing through geometry centers of the two trapezoid surfaces of each second lens is a second straight line, and an angle exists between the first line and the second straight line. The wave retarder array is disposed on the datum constituted by the top surfaces of the lens array, wherein the wave retarder array includes first wave retarders corresponding to the first lenses and second wave retarders corresponding to the second lenses. An acute angle exists between the optical axis of each first wave retarder and each first straight.

Description

201007351 ruu! w^〇ziTW 23669twf.doc/n 九、發明說明: 【發明所屬之技術領域】 本發明是有關於一種光罩,且特別是有關於一種用於 光配向製程的光罩及使用此光罩之光配向製程。 、 【先前技術】 隨著電腦性能的大幅進步以及網際網路、多媒體技術 ❹ 的尚度發展,視訊或影像裝置之體積日漸趨於輕薄。在顯 示器的發展上,隨著光電技術與半導體製造技術的進步二 具有高晝質、空間利用效率佳、低消耗功率、無輻射等優 越特性的液晶顯示器(liquid cryStai display,LCD)已逐漸成 為市场之主流。 圖1繪示為習知之液晶顯示面板之剖面示意圖。請參 照圖1,習知的液晶顯示面板100主要由一對向基板U〇、 —基板120以及一液晶層150所組成,其中液晶層15〇位 φ 於對向基板110與基板120之間。當在對向基板110與基 板120之間施加電場時,液晶層15〇内的液晶分子便會受 到電%的作用而產生偏轉,使得液晶層15〇具有相應於此 電場的光線穿透率。如此一來,液晶顯示面板1〇〇便可以 依據對向基板110與基板120之間的電場大小,而顯示不 同的灰階晝面。 此外’為了對液晶層150内的液晶分子提供穩定的邊 界條件,對向基板11〇與基板12〇上分別配置有配向層no 與配向層140 ’以使液晶分子沿特定的序向排列。另一方 5 201007351 x vvw 〜4_r3ZlTW 23669twf.doc/n 面,近來市場對於液晶顯示器的性能要求多朝向高對比 (hlgh contrast ratio)、快速反應與廣視角等方向發展,然而, 習知所發展出來的配向方法多有其缺點,而無法使液晶分 子達到快速反應與廣視角的需求。 舉例而言,習知最常見的做法是以接觸式的方式對配 向層與進行摩擦(rubbing)處理,以使配向層對液晶層之液晶 分子產生配向效果。然而,這樣的作法需要滾輪(禮的對玻 ⑩ 璃基板表面進行摩擦配向,如此-來,不僅無法針對每個 畫素(pixel)進行多領域(muiti_d〇main)之配向,所以無法達到 廣視角的效果’接觸式的製作方式亦容易使配向層產生微 塵(dust)或是靜電,且由於需要滚輪對玻璃基板進行配向, 當玻璃基板尺寸逐漸增大的情況下,不易應用於大尺寸的 面板製作,容易產生配向不均的問題。 另外,習知技術中亦有使用線性極化的紫外光來照射 光配向材料,其利用光的偏極化來賦予液晶分子傾倒時的 _ 方位角(azimuthal axis)以及利用入射光方向賦予預傾角 (pre-tilt angle)来對配向層做配向,使得配向層分子具有特 定的配向方向,以解決傳統接觸式配向方法容易產的斜 塵與靜電問題。然而,在製作多域垂直配向(multi_d〇main vertical alignment,MVA)的液晶顯示裝置時,需用多種不同 入射方向的紫外光來照射光配向材料,以使液晶分子產生 多種傾斜方向。因此,習知光配向製程需對光配向材料進 行多次紫外光照射,導致光配向製程時間較長。 6 201007351 rvuu/,儿 OZ1TW 23669twf‘doc/n 【發明内容】 本發明提供一種光罩,以簡化光配向製程。 本發明提供一種光配向製程,以縮短製程時間。 ❹ ❹ 本發明提出一種光罩,其包括一透鏡陣列(lens array) 以及一波長延遲器陣列(Wavearmy)。透鏡陣列包括 交替排列的多個第一透鏡與多個第二透鏡,且每一第一透 鏡及每一第二透鏡分別為一梯形柱體。梯形柱體具有相互 平打之一頂面與一底面、相互平行之兩梯形表面以及兩斜 面頂面的面積小於底面。每一第一透鏡之梯形表面之幾 何中心的連線為一第一直線,每一第二透鏡之梯形表面之 戎付中心的連線為一苐二直線,且第一直線與第二直線之 間夾一角度。波長延遲器陣列設置於透鏡陣列之頂面所構 ^的基準面上,且波長延遲器陣列包括多個第一波長延遲 器與夕個弟一波長延遲器,其中第一波長延遲器與第一透 鏡相對’而第二波長延遲器與第二透鏡相對。 在本發明之一實施例中,上述之每一第一波長延遲器 具有第一光軸與每一第一直線之間夾一第一銳角,所夾的 銳角為45度。在一實施例中,第一銳角為45度。 在本發明之一實施例中,上述之每一第二波長延遲器 具有第二光轴與每一第二直線之間夾一第二 π 在本發明之一實施例中,上述之第一直線實質上垂直 第二直線。 在本發明之-實施例中,上述之梯形柱體之斜面 面之間的炎角相同。 - 7 JZ1TW 23669twf.doc/n 201007351 在本發明之一實施例中,上述之梯形柱體之斜面與底 面之間的夾角不完全相同。 一 _ 本發明又提出一種光配向製程,包括下列步驟:首先, 將上述之光罩與一基板進行對位,其中基板具有一光配向 材料層。接著,使-線性極化級由上述光罩而照射光配 向材料層,其中線性極化光的極化方向與第一波長延遲器 所具有之第一光軸之間夾一銳角。 ❿ 在本發明之一實施例中,上述之線性極化光的極化方 向與第一波長延遲器的光轴之間所夾的銳角為45度。 在本發明之一實施例中,上述之光罩之波長延遲器陣 ,更包括多個第二波長延遲器,其與光罩之第二透鏡相對。 每一第二波長延遲器具有第二光軸垂直第二直線,且平行 線性極化光的極化方向。 ,在本發明之一實施例中,上述之基板為矩形基板或正 方形基板,且基板劃分為多個矩形的次晝素區,每一次畫 素區之長邊平行基板之其中兩邊。將光罩與基板進行^ 位二以使每-第-:^線平行每一次畫素區之其中兩邊,並 使每一第二直線平行每一次畫素區之另外兩邊,且每一次 畫素區對應第一透鏡其中之一以及第二透鏡其中之一。 在本發明之一實施例中,上述之基板為矩形基板或正 方形基板,且基板劃分為多個矩形的次晝素區,每一次畫 素區之長邊與基板之每一邊皆夾45度角。將光罩與基板進 打對位,以使每一第一直線平行每一次畫素區之其中兩 邊,並使每一第二直線平行每一次畫素區之另外兩邊且 8 201007351 -—*-OZlTW 23669twf.doc/n 每一次晝素區對應第一透鏡其中之一以及第二透鏡其中之 '· 〇 鲁 ,在本發明之一實施例中,上述之基板為矩形基板或正 方形基板,且基板劃分為多個矩形的次晝素區,每一次書 素區之長邊平行基板之其中兩邊。將光罩與基板進行對 位,以使每一第一直線與每一次晝素區之每一邊皆夾45度 角,並使每一第二直線與每一次畫素區之每一邊皆夾45度 角,且母一次晝素區對應第二透鏡其中之二以及鄰接二第 二透鏡之每一第一透鏡之部分。 在本發明之一實施例中,上述之線性極化光為紫外光。 向 本發明另提出一種光罩,其適於讓一光線穿過,光罩 包括透鏡陣列以及波長延遲器陣列。其中透鏡陣列包含有 ,數個光路彳變區域,光線藉由光路徑改變區域改變其 f射角度。波長延遲輯列,設置於透僻狀上,波長 ,器陣列包含-第—波長延遲器與—第二波長延遲器, I刀光線穿透第—波長延遲器後具有—第—光極化方向, ί—部份光線穿透第二波長延遲II後具有-第二光極化方 之—實施例中,上述之光路徑改變區域包括 二 二筮夕個第一透鏡與多個第二透鏡,且每一第一透 ί器分別與第-波長延遲器以及第二波長延 之#之—實施例中,上述之每—第—透鏡之表面 ° “連線為—第一直線,且每一第一波長延遲器 9 201007351 ruujiv/-tji-/v>ZlTW 23669twf.doc/n 具有第一光軸與每一第一直線之間具有一夾角。 在本發明之一實施例中,上述之每一第二透鏡之表面 之幾何中心的連線為一第二直線,且每一第二波長延遲器 具有第二光軸與每一第二直線之間具有一夾角。 本發明又提出一種光配向製程,包括下列步驟:首先, 提供一基板,將上述之光罩與基板進行對位,其中基板具有 一光配向材料層。光罩適於讓一光線穿過,光罩包括透鏡 春㈣以及波長延勒陣列^其令透鏡_包含有複數個光 路徑改變區域,光線藉由光路徑改變區域改變其出射角 度。波長延遲器陣列,設置於透鏡陣列之上,波長延遲器 陣列包含一第一波長延遲器與一第二波長延遲器,部分^ 線穿透第-波長延遲器後具有—第—光極化方向,另一部 份光線穿透第二波長延遲器後具有一第二光極化方向。之 後,使一線性極化光經由上述光罩而照射光配向材料層, 其中線性極化光的極化方向與第一波長延遲器的光轴之間 | 夾一銳角。 由於本發明之光罩的每一第一透鏡及每一第二透鏡皆 具有兩個斜面,所以可讓線性極化光以多種不同的入射方 向來照射光配向材料層。因此,相較於習知技術,本發明 之光配向製程僅需對光配向材料層照射一次,所以能節省 製程時間。 為讓本發明之上述特徵和優點能更明顯易懂,下文特 舉較佳實施例,並配合所附圖式,作詳細說明如下。 201007351 ……一 JZ1TW 23669twf.doc/n 【實施方式】 本發明之光罩包括一透鏡陣列以及一波長延遲器陣 列。透光基板具有相對的一第一表面與一第二表面,其中 ,鏡陣列是置於第-表面,而波長延遲轉列是配置於 第二表面。以下將先搭配圖式說明本發明之透鏡陣列的設 計原理。201007351 ruu! w^〇ziTW 23669twf.doc/n IX. Description of the Invention: [Technical Field] The present invention relates to a reticle, and more particularly to a reticle for a photo-alignment process and the use thereof The light of the reticle is aligned with the process. [Prior Art] With the dramatic advancement of computer performance and the development of Internet and multimedia technologies, the size of video or video devices has become increasingly thin. In the development of displays, with the advancement of optoelectronic technology and semiconductor manufacturing technology, liquid cryStai displays (LCDs) with superior properties, high space utilization efficiency, low power consumption, and no radiation have gradually become the market. The mainstream. 1 is a schematic cross-sectional view of a conventional liquid crystal display panel. Referring to FIG. 1, a conventional liquid crystal display panel 100 is mainly composed of a pair of substrates U, a substrate 120, and a liquid crystal layer 150, wherein the liquid crystal layer 15 is clamped between the opposite substrate 110 and the substrate 120. When an electric field is applied between the opposite substrate 110 and the substrate 120, the liquid crystal molecules in the liquid crystal layer 15 are deflected by the electric power so that the liquid crystal layer 15 has a light transmittance corresponding to the electric field. In this way, the liquid crystal display panel 1 can display different gray-scale pupils according to the magnitude of the electric field between the opposite substrate 110 and the substrate 120. Further, in order to provide stable boundary conditions for the liquid crystal molecules in the liquid crystal layer 150, the alignment layer no and the alignment layer 140' are disposed on the opposite substrate 11A and the substrate 12, respectively, so that the liquid crystal molecules are aligned in a specific order. The other side 5 201007351 x vvw ~ 4_r3ZlTW 23669twf.doc / n face, the recent market for the performance requirements of liquid crystal displays are directed toward high contrast (hlgh contrast ratio), rapid response and wide viewing angle, however, the development of the conventional The alignment method has its shortcomings, and it cannot meet the requirements of rapid reaction and wide viewing angle of liquid crystal molecules. For example, the most common practice is to rub the alignment layer in a contact manner such that the alignment layer produces an alignment effect on the liquid crystal molecules of the liquid crystal layer. However, such a method requires a roller (the rubbing alignment of the surface of the glass substrate of the glass, so that not only the multi-domain (muiti_d〇main) alignment of each pixel (pixel) cannot be performed, so the wide viewing angle cannot be achieved. The effect of the contact type is also easy to produce dust or static electricity in the alignment layer, and since the roller is required to align the glass substrate, when the size of the glass substrate is gradually increased, it is not easy to be applied to a large-sized panel. In the prior art, it is easy to cause uneven alignment. In addition, in the prior art, linearly polarized ultraviolet light is used to illuminate the optical alignment material, which utilizes polarization of light to impart azimuth to the liquid crystal molecules when they are poured (azimuthal Axis) and using the direction of the incident light to impart a pre-tilt angle to align the alignment layer, so that the alignment layer molecules have a specific alignment direction to solve the problem of oblique dust and static electricity which are easily produced by the conventional contact alignment method. In the production of multi-domain vertical alignment (MVA) liquid crystal display devices, a variety of different incidents are required. The ultraviolet light is irradiated to the light alignment material to cause the liquid crystal molecules to generate a plurality of oblique directions. Therefore, the conventional light alignment process requires multiple ultraviolet light irradiation on the light alignment material, resulting in a long optical alignment process. 6 201007351 rvuu/, OZ1TW 23669twf'doc/n SUMMARY OF THE INVENTION The present invention provides a photomask to simplify the photoalignment process. The present invention provides an optical alignment process to shorten the process time. ❹ ❹ The present invention provides a photomask including a lens array (lens array) and a wavelength retarder array (Wavearmy). The lens array includes a plurality of first lenses and a plurality of second lenses arranged alternately, and each of the first lenses and each of the second lenses is a trapezoidal cylinder The trapezoidal cylinder has a top surface and a bottom surface which are parallel to each other, and two trapezoidal surfaces parallel to each other and the top surfaces of the two inclined surfaces are smaller than the bottom surface. The line connecting the geometric centers of the trapezoidal surfaces of each of the first lenses is a first straight line. a line connecting the center of the trapezoidal surface of each second lens is a straight line, and a corner is formed between the first straight line and the second straight line The wavelength retarder array is disposed on a reference surface of the top surface of the lens array, and the wavelength retarder array comprises a plurality of first wavelength retarders and a sigma-wave retarder, wherein the first wavelength retarder and the first A lens opposite to the second wavelength retarder is opposite to the second lens. In one embodiment of the invention, each of the first wavelength retarders has a first optical axis and a first line between each of the first lines An acute angle, the acute angle of the clip is 45 degrees. In one embodiment, the first acute angle is 45 degrees. In one embodiment of the invention, each of the second wavelength retarders has a second optical axis and each A second π is sandwiched between two straight lines. In one embodiment of the invention, the first straight line is substantially perpendicular to the second straight line. In the embodiment of the invention, the inflammatory angles between the inclined faces of the trapezoidal cylinders are the same. - 7 JZ1TW 23669twf.doc/n 201007351 In an embodiment of the invention, the angle between the inclined surface of the trapezoidal cylinder and the bottom surface is not completely the same. A further embodiment of the invention provides a photo-alignment process comprising the steps of: first aligning the reticle with a substrate, wherein the substrate has a layer of optical alignment material. Next, the linear polarization stage is illuminated by the reticle to the optical alignment material layer, wherein the polarization direction of the linearly polarized light is at an acute angle to the first optical axis of the first wavelength retarder. In one embodiment of the invention, the acute angle between the polarization direction of the linearly polarized light and the optical axis of the first wavelength retarder is 45 degrees. In an embodiment of the invention, the wavelength retarder array of the photomask further includes a plurality of second wavelength retarders opposite to the second lens of the photomask. Each of the second wavelength retarders has a second optical axis perpendicular to the second straight line and parallel to the polarization direction of the linearly polarized light. In an embodiment of the invention, the substrate is a rectangular substrate or a square substrate, and the substrate is divided into a plurality of rectangular sub-tenox regions, and each of the long sides of the pixel region is parallel to two sides of the substrate. The photomask and the substrate are aligned such that each of the -: - lines is parallel to two sides of each pixel region, and each second line is parallel to the other two sides of each pixel region, and each pixel is The region corresponds to one of the first lenses and one of the second lenses. In an embodiment of the invention, the substrate is a rectangular substrate or a square substrate, and the substrate is divided into a plurality of rectangular sub-tenk regions, and each of the long sides of the pixel region is at a 45-degree angle with each side of the substrate. . Aligning the reticle with the substrate such that each first line is parallel to two sides of each pixel region, and each second line is parallel to the other two sides of each pixel region and 8 201007351 - - * - OZlTW 23669 twf.doc/n Each of the pixel regions corresponds to one of the first lenses and the second lens of the second lens. In one embodiment of the present invention, the substrate is a rectangular substrate or a square substrate, and the substrate is divided. As a plurality of rectangular sub-decibation regions, each of the long sides of the pixel region is parallel to two sides of the substrate. Aligning the reticle with the substrate such that each first line is at an angle of 45 degrees to each side of each pixel region, and each second line is clipped 45 degrees to each side of each pixel region The corner, and the primary primary halogen region corresponds to two of the second lenses and a portion of each of the first lenses adjacent to the second lenses. In an embodiment of the invention, the linearly polarized light is ultraviolet light. Further, the present invention provides a reticle adapted to pass a light beam, the reticle comprising a lens array and an array of wavelength retarders. The lens array includes a plurality of optical path variability regions, and the light changes its f-angle by the light path changing region. The wavelength delay is set in a transparent manner, and the wavelength array includes a -first wavelength retarder and a second wavelength retarder. The I knife light passes through the first wavelength retarder and has a -first polarization direction. In the embodiment, the light path changing region includes a first lens and a plurality of second lenses. And each of the first transparent devices and the first-wavelength retarder and the second wavelength-delayed-in the embodiment, the surface of each of the above-mentioned first lenses is "connected to - the first straight line, and each of the first A wavelength retarder 9 201007351 ruujiv/-tji-/v>ZlTW 23669twf.doc/n has an angle between the first optical axis and each of the first straight lines. In an embodiment of the invention, each of the above The line connecting the geometric centers of the surfaces of the two lenses is a second line, and each of the second wavelength retarders has an angle between the second optical axis and each of the second lines. The present invention further provides an optical alignment process. The method includes the following steps: First, providing a substrate, which will be The reticle is aligned with the substrate, wherein the substrate has a layer of optical alignment material. The reticle is adapted to pass a light beam, and the reticle comprises a lens spring (four) and a wavelength Yanler array, which causes the lens _ to contain a plurality of lights In the path changing region, the light changes its exit angle by changing the light path. The wavelength retarder array is disposed on the lens array, and the wavelength retarder array comprises a first wavelength retarder and a second wavelength retarder, and the second wavelength retarder After passing through the first-wave retarder, there is a -first polarization direction, and another portion of the light passes through the second wavelength retarder to have a second polarization direction. Thereafter, a linearly polarized light is transmitted through the light. The cover illuminates the light alignment material layer, wherein the polarization direction of the linearly polarized light and the optical axis of the first wavelength retarder are at an acute angle. Since each of the first lens and each second of the reticle of the present invention The lenses all have two bevels, so that the linearly polarized light can illuminate the photoalignment material layer in a plurality of different incident directions. Therefore, the optical alignment process of the present invention only needs to be aligned with light compared to the prior art. The above-mentioned features and advantages of the present invention can be more clearly understood. The following description of the preferred embodiments, together with the accompanying drawings, will be described in detail below. 201007351 ...... JZ1TW 23669twf.doc/n Embodiments The photomask of the present invention includes a lens array and a wavelength retarder array. The light transmissive substrate has a first surface and a second surface, wherein the mirror array is placed The surface, and the wavelength delay transition is disposed on the second surface. The design principle of the lens array of the present invention will be described below with reference to the drawings.

圖2是光線自-透鏡出射後的光路徑示意圖。請參照 圖2,透鏡200具有多個凹槽21〇,且每一凹槽21〇具有兩 斜面212、214以及-頂面216。透鏡2〇〇的折射率為叫, 而與透鏡200相鄰的介質為空氣,且折射率叫大於空氣的 折射率。由於折射率Νι大於空氣的折射率,所以垂直入射 透鏡20G的光線2G自透鏡2G〇出射後會分成三個方向。更 詳細地說,從凹槽210之頂面別㈣的光線2〇會垂直照 射在光配向材料層50上,而從凹槽21()之斜面212、叫 出射的光線20會斜向照射在光配向材料層%上。 言’透鏡200的材質通常可以選用透光性良好的材& 如聚甲基丙烯酸甲醋(ΡΜΜΑ)、聚丙烯(pp)或 料,而透鏡200的折射率則例如為實質上149。遇口何 假設透鏡200的折射率叫為15,而空 斛 卜則根據司乃耳定律(Sndl,s law)可算出光線2()向二 光配向材料層50的角度θυν與凹槽21〇之斜面傾斜^入, LENS的關係如下: : 式⑴ 式(2) Θ LENS = θ 1 ^ UV~ Θ 2~ Θ \ 2〇i〇〇Z3^z1TW_,2 is a schematic view of a light path after light is emitted from a lens. Referring to Figure 2, lens 200 has a plurality of recesses 21, and each recess 21 has two ramps 212, 214 and a top surface 216. The refractive index of the lens 2〇〇 is called, and the medium adjacent to the lens 200 is air, and the refractive index is called the refractive index of air. Since the refractive index Νι is larger than the refractive index of the air, the light 2G incident perpendicularly to the lens 20G is split into three directions after being emitted from the lens 2G. In more detail, the light rays 2 from the top surface (4) of the groove 210 are vertically irradiated on the light alignment material layer 50, and the light rays 20 emerging from the inclined surface 212 of the groove 21 () are obliquely irradiated. The light alignment material layer is on the %. The material of the lens 200 is usually selected from a material having good light transmittance, such as polymethyl methacrylate (polypropylene), polypropylene (pp) or material, and the refractive index of the lens 200 is, for example, substantially 149. What is the case? The refractive index of the lens 200 is assumed to be 15, and the space is calculated according to the law of Sndl (sndl), and the angle θ υ ν of the ray 2 () to the bismuth aligning material layer 50 and the groove 21 〇 can be calculated. The slope of the slope is inclined, and the relationship of LENS is as follows: : Equation (1) Equation (2) Θ LENS = θ 1 ^ UV~ Θ 2~ Θ \ 2〇i〇〇Z3^z1TW_,

NiSin Θ i — Sin 〇 2 式(3) 其中0 1是光線20入射斜面212時的入射角,而02是 光線20自斜面212出射時的出射角。根據式(1)、式〇與式 (3)可算出下式:NiSin Θ i — Sin 〇 2 Equation (3) where 0 1 is the incident angle when the ray 20 is incident on the ramp 212, and 02 is the exit angle when the ray 20 exits the ramp 212. According to formula (1), formula 式 and formula (3), the following formula can be calculated:

NiSin Θ lens = Sin( Θ υν+ Q LENS)式⑷ 根據式(4)可算出’ 0 υν與0 lens的關係。舉例來說, 當需要θυν=4(Τ時,則6>lens需設計成41。。 ® 光配向材料層50經過光線20的照射後,可區分為五 個區域Al、A2、A3、A4與A5。光配向材料層50之區域 A1可使液晶分子30向左傾斜。光配向材料層5〇之區域A2 可使液晶分子30向右傾斜。此外,由於光配向材料層% 之區域A3是被光線20垂直照射,所以並不會賦予液晶分 子30預傾角(pre-tilt angle)。而且,在區域A3的液晶分子 3〇是位於在區域A1與區域A2之液晶分子30的傾斜方向 的背面,所以在區域A3的液晶分子30不會受到區域A1 象 與區域A2之液晶分子30的推擠而往正確的方向傾斜。 承上述’·光配向材料層5〇之區域A4並未受到光線20 照射’所以不會賦予液晶分子30預傾角。而且,在區域 A4的液晶分子3〇是位於在區域A1與區域A2之液晶分子 的傾斜方向的背面,所以在區域A4的液晶分子30不會 受到區域A1與區域A2之液晶分子30的推擠而往正確的方 向傾斜。此外’光配向材料層50之區域A5受到光線20正 向照射’所以不會賦予液晶分子30預傾角。然而,在區域 八5的液晶分子30是位於在區域A1與區域A2之液晶分子 12 jZlTW23669twf.d〇c/n 201007351 30的傾斜方向的正面,所以在區域A5的液晶分子3〇會受 到區域A1與區域A2之液晶分子3〇的推擠而往正確的方向 傾斜。 當製作多域垂直配向的液晶顯示裝置時,可將區域A1 與區域A2設計成類似透明電極層之狹縫(slit)的功能,並將 區域A5設計成主要顯示區域。如此,可藉由區域Ai與區 域A2之液晶分子3〇傾倒時推擠區域A5的液晶分子,使各 ❹ 領域(domain)的液晶分子30倒向正確的方向。然而,由於 區域A3與區域A4的液晶分子30並不會受到推擠,所以無 法快速倒向預定的方向,導致容易在區域A3與八4產生液 晶分子傾到不正常’而有顯示異常的現象。此外,本發明 亦可將區域A1與區域A2設計成主要顯示區域,然而此意 味著區域A1與區域A2會變大,而區域A4也會隨之變大, 導致顯不異常的區域跟著變大。 圖3是光線自另一種透鏡出射後的光路徑示意圖。透 _ 鏡300為梯形柱狀體’其具有一頂面312、—底面314以及 兩斜面316、318。透鏡300的折射率為凡,而與透鏡3〇〇 相鄰的介質為空氣’且折射率N2大於空氣的折射率。由於 折射率N2大於空氣的折射率,因此以垂直透鏡3〇〇之頂面 312的方向入射透鏡300的光線20自透鏡300出射後會分 成三個方向。更詳細地說,從頂面312入射的光線20 ,自 底面314出射後會垂直照射在光配向材料層50上》從斜面 316、318入射的光線20,自底面314出射後會斜向照射在 光配向材料層50上。 13 201 007^?i^lTW23669twf.doc/n 假設透鏡300的折射率叫為L5,而空氣的折射率為 1,則根據司乃耳疋律(Snell’s law)可算出光線20斜向入射 光配向材料層50的角度0uv與透鏡3〇〇之斜面傾斜角㊀ LENS 的關係如下: 式(5) 式⑹ 式⑺ Θ LENS= 0 4 〇 UV— Θ 6NiSin Θ lens = Sin( Θ υν+ Q LENS) Formula (4) The relationship between '0 υν and 0 lens can be calculated from the equation (4). For example, when θ υ ν = 4 (Τ, then 6 & lens needs to be designed to be 41.) After the light aligning material layer 50 is irradiated by the light 20, it can be divided into five regions Al, A2, A3, A4 and A5. The region A1 of the photo-alignment material layer 50 can tilt the liquid crystal molecules 30 to the left. The region A2 of the photo-alignment material layer 5 can tilt the liquid crystal molecules 30 to the right. Further, since the region A3 of the photo-alignment material layer % is The light ray 20 is vertically irradiated, so that the liquid crystal molecules 30 are not pre-tilt angled. Further, the liquid crystal molecules 3 区域 in the region A3 are located on the back surface of the liquid crystal molecules 30 in the regions A1 and A2, in the oblique direction. Therefore, the liquid crystal molecules 30 in the region A3 are not inclined by the liquid crystal molecules 30 of the region A1 and the region A2, and are inclined in the correct direction. The region A4 of the above-mentioned light-aligning material layer 5 is not irradiated with the light 20 Therefore, the liquid crystal molecules 30 are not pretilted. Further, since the liquid crystal molecules 3 in the region A4 are located on the back surface in the oblique direction of the liquid crystal molecules in the regions A1 and A2, the liquid crystal molecules 30 in the region A4 are not affected by the regions. A1 and area A2 The liquid crystal molecules 30 are pushed and tilted in the correct direction. Further, the region A5 of the optical alignment material layer 50 is irradiated with the light 20 in the forward direction, so that the liquid crystal molecules 30 are not pretilted. However, the liquid crystal molecules in the region 八5 30 is a front surface in the oblique direction of the liquid crystal molecules 12 jZlTW23669twf.d〇c/n 201007351 30 in the region A1 and the region A2, so that the liquid crystal molecules 3 in the region A5 are subjected to the liquid crystal molecules of the regions A1 and A2. Pushing and tilting in the right direction. When making a multi-domain vertical alignment liquid crystal display device, the area A1 and the area A2 can be designed to be similar to the slit of the transparent electrode layer, and the area A5 is designed as the main The display area is such that liquid crystal molecules of the region A5 can be pushed by the liquid crystal molecules 3 of the region Ai and the region A2, so that the liquid crystal molecules 30 of the respective domains are reversed in the correct direction. However, due to the region A3 The liquid crystal molecules 30 in the region A4 are not pushed, so that they cannot be quickly reversed in a predetermined direction, resulting in easy formation of liquid crystal molecules in the regions A3 and VIII, and abnormal display. In addition, the present invention can also design the area A1 and the area A2 as the main display area, however, this means that the area A1 and the area A2 will become larger, and the area A4 will also become larger, resulting in a non-abnormal area following. Figure 3 is a schematic view of the light path after light exits from another lens. The mirror 300 is a trapezoidal column body having a top surface 312, a bottom surface 314 and two slopes 316, 318. The refractive index of the lens 300 For example, the medium adjacent to the lens 3 is air 'and the refractive index N2 is greater than the refractive index of air. Since the refractive index N2 is larger than the refractive index of air, the light 20 entering the lens 300 in the direction of the top surface 312 of the vertical lens 3 is emitted from the lens 300 and split into three directions. In more detail, the light 20 incident from the top surface 312 is emitted from the bottom surface 314 and is vertically incident on the light alignment material layer 50. The light 20 incident from the slopes 316, 318 is obliquely emitted from the bottom surface 314. Light aligning material layer 50. 13 201 007 ^?i^l23669twf.doc/n Assuming that the refractive index of the lens 300 is called L5 and the refractive index of the air is 1, the oblique incident light alignment of the light 20 can be calculated according to Snell's law. The relationship between the angle 0uv of the material layer 50 and the slope inclination angle LENS of the lens 3〇〇 is as follows: Equation (5) Equation (6) Equation (7) Θ LENS= 0 4 〇UV— Θ 6

Sin Θ 4 —N2Sin θ 5Sin Θ 4 —N2Sin θ 5

N2Sin(6>4- 6>5)=Sin6>6 式⑻ 其中Θ4是光線20入射斜面316時的入射角,05是光 線20自斜面316出射時的出射角,是光線2〇自底面314 出射時的出射角。而根據式(5)至式(8)可算出下列關係式:N2Sin(6>4- 6>5)=Sin6>6 Equation (8) where Θ4 is the incident angle when the ray 20 is incident on the slope 316, and 05 is the exit angle when the ray 20 exits the slope 316, and the ray 2 is emitted from the bottom surface 314. The exit angle of the time. According to formula (5) to formula (8), the following relationship can be calculated:

Sin Θ lens — N2Sin θ 5 式(9) N2Sin( θ lens ~ θ 5) = Sin θ υν 式(10) 根據式(9)與式(10)可算出,〜與^咖的關係。舉 例來說’當需要0υν=4〇。時,則0lens需設計成61、 光配向材料層50經過光線20的照射後,可區分為四 個區域Al、A2、A4與A6。區域A1、A2與A4對液晶分 子30的配向方向與上述相同,在此不再重述。此外,光配 向材料層50之區域A6被三種不同入射方向的光線2〇照 射,該區域A6的液晶分子的預傾角會出現不一致的狀況, 而造成顯不上的異常,所以在設計上可藉由增加頂面312 的寬度L來降憾域A6出現的機率,或者藉由適當的晝素 佈局(layout)來抑制區域A6對畫素顯示不均的影響。 承上述,由圖3可推出下列關係式: 201007351 ru〇i^J^〇ZlTW 23669twf.doc/n W/2 = H/tan Θ LENs+H/tan Θ 7 式 〇 〇 若要在設計上需要使得區域A6的長度剛好為〇,則可 以得到如下關係式:Sin Θ lens — N2Sin θ 5 Equation (9) N2Sin( θ lens ~ θ 5) = Sin θ υν Equation (10) The relationship between ~ and ^ coffee can be calculated from equations (9) and (10). For example, 'when 0υν=4〇 is needed. In the case of 0lens, it is designed to be 61. After the light alignment material layer 50 is irradiated by the light 20, it can be divided into four regions A1, A2, A4 and A6. The alignment directions of the regions A1, A2, and A4 with respect to the liquid crystal molecules 30 are the same as described above, and will not be repeated here. In addition, the region A6 of the photo-alignment material layer 50 is irradiated by the light rays 2〇 in three different incident directions, and the pretilt angle of the liquid crystal molecules in the region A6 may be inconsistent, resulting in an abnormality, so the design can be borrowed. The probability of occurrence of the field A6 is reduced by increasing the width L of the top surface 312, or the influence of the area A6 on the unevenness of the pixel display is suppressed by an appropriate pixel layout. According to the above, the following relationship can be derived from Fig. 3: 201007351 ru〇i^J^〇ZlTW 23669twf.doc/n W/2 = H/tan Θ LENs+H/tan Θ 7 If you want to design If the length of the area A6 is just 〇, the following relationship can be obtained:

Dxtan <9 uv+W/2 - H/tan (9 lens = L/2 式(12) 其中Η為透鏡300的高度,d為透鏡300之底面314 至光配向材料層50的距離,β 7 = 9〇。—(Θ4 — Θ5)。假設Θ lens=61°,則根據式(5)、式(9)與式(1〇)可算出0LENS—I 〇 =25.3°,07=64.7。,且 0uv = 4〇。。因此,式(11)與式(12) 可改寫成下列關係式: W/2 = H/tan61 +H/tan64.7 式(13)Dxtan <9 uv+W/2 - H/tan (9 lens = L/2 (12) where Η is the height of the lens 300 and d is the distance from the bottom surface 314 of the lens 300 to the photoalignment material layer 50, β 7 = 9〇.—(Θ4 — Θ5). Assuming Θ lens=61°, 0LENS—I 〇=25.3°, 07=64.7 can be calculated according to equations (5), (9) and (1〇). And 0uv = 4〇. Therefore, equations (11) and (12) can be rewritten into the following relation: W/2 = H/tan61 + H/tan64.7 (13)

Dxtan40+W/2 — H/tan61 = L/2 式(14) 圖4是液晶顯示裝置之一個次晝素區的示意圖。請參 照圖3與圖4,當製作多域垂直配向的液晶顯示裝置,可將 區域A1與區域A2設計成主要顯示區域,所以需盡量擴大 區域A1與區域A2的範圍’以減少液晶顯示装置之各次晝 $ 素區之領域的切割數。若僅在液晶顯示裝置之單一基板的 光配向材料層作領域的切割’铒設各次晝素區對應兩個透 鏡300,且各次畫素區的寬為100#m ’長為30〇em,則 W/2<83.2/zm。由式(13)可算出透鏡3〇〇的高度H< 80.8/zmo 此外,透鏡300與光配向材料層50相隔一距離D時, 光配向材料層50會出現未受到光照射的區域A4。若D = 0, 由式(14)可算出 L/2=83.2/zm—44.9/zm=38.3ym。若 D = l^m,由式Ο4)可算出 44.9/zm 15 201007351 rwiu-tJi^OZlTW 23669twf.d〇c/n = 39,lem。換言之,在D=l/zm時,區域A4的寬度僅約 2x0.8 以 m= 1.6/z m 〇 基於上述,本發明所提出的光罩即包括多個上述之透 鏡300。以下將以實施例搭配圖式來說明本發明之光罩。 圖5是本發明一實施例之光罩的示意圖,圖6是圖5 之透鏡陣列及波長延遲器陣列的局部爆炸立體圖,為清楚 說明透鏡陣列420及波長延遲器陣列430之間各構件的關 ❸ 係,圖6省略了圖5中透光基板410。請參照圖5與圖6, 本實施例之光罩400包括透鏡陣列420以及波長延遲器陣 列430 ’並且在本實施例中,更可於透鏡陣列42〇以及波長 延遲器陣列430之間選擇性地設置透光基板41〇。其中,透 光基板410具有相對的一第一表面412與一第二表面414, 其中透鏡陣列420是配置於第一表面412,而波長延遲器陣 列430是配置於第二表面414 ’值得一提的是’透鏡陣列基 板420也可以與波長延遲器陣列43〇直接結合,而不需要 泛有透光基板410。透鏡陣列420包括交替排列的多個第一透 鏡422與多個第二透鏡424,且每一第一透鏡422及每一第 二透鏡424分別為一梯形柱體(即圖3之透鏡3〇〇),值得注 思的是’本實施例中之第一透鏡422與第二透鏡424用以 改變入射光的出射角度,因此第一透鏡422與第二透鏡424 可稱為光路控改變區域。梯形柱體具有相互平行之一頂面 312與一底面314、兩斜面316、318以及相互平行之兩梯 形表面322、324。頂面312的面積小於底面314,且頂面 312連接第一表面412。每一第一透鏡422之梯形表面322、 16 201007351 ruuitrHjj.OZlTW 23669twf. doc/n 324之幾何中心的連線為一第一直線S1,每一第二透鏡 之梯形表面322、324之幾何中心的連線為一第二直線, 且第一直線S1與第二直線S2之間夾一角度。波長延遲器 陣列430包括與第一透鏡422相對的多個第一波長延遲器 432,且每一第一波長延遲器432的第一光軸〇1與每—第 一直線S1之間爽一銳角。 上述之光罩400中,第一直線S1實質上垂直第二直線 Φ S2。此外,每一第一波長延遲器432的第一光轴〇1與每一 第一直線S1之間所夾的銳角為45度。另外,波長延遲器 陣列430可更包括多個第二波長延遲器434。這些第二波長 延遲器434與第二透鏡424相對,且每一第二波長延遲器 434的第二光軸〇2垂直第二直線82。每一第一波長延遲器 432的第一光軸〇1與每一第二波長延遲器434的第二光轴 02 之間例如失一 45度角。 另外,所有梯形柱體300之斜面316、318與底面314 _ 之間的夾角可全部相同或者是不完全相同。也就是說,部 分梯形柱體300之斜面316、318與314之間的夾角相同, 部分梯形柱體300之斜面316、318與314之間的夾角不同。 如此,可讓光線斜向入射光配向材料層時的入射角不同, 進而使液晶分子具有不同的預傾角。 由於液晶分子的傾斜角度會影響液晶分子的穿透率與 驅動電壓之關係曲線’藉由讓液晶分子具有不同的預傾 角’可使液晶分子有多種穿透率與驅動電壓之關係曲線, 此有助於降低色偏。 17 201007351 K UUJl u-tjjuOZITW 23669twf.doc/n 以下將搭配圖式說明使用本實施例之光罩400的光配 向製程。 圖7A與圖7B繪示本發明一實施例之光配向製程的步 驟流程圖。圖8是本發明一實施例之光配向製程的示意圖’ 其中圖8中之基板500為圖7A與圖7B中基板之示意圖。 請先參照圖7A與圖8,本實施例之光配向製程包括下列步 驟:首先’將上述之光罩400與一基板500進行對位,其 ❹ 中基板500具有一光配向材料層510。基板500例如為矩形 基板或正方形基板’且基板500上劃分有多個矩形的次晝 素區520,每一次晝素區520之長邊522、524平行基板500 之其中兩邊502、504。此外,將光罩400與基板500進行 對位使每一第一直線S1平行每一次晝素區520之其中兩邊 526、528,並使每一第二直線S2平行每一次晝素區520之 另外兩邊522、524,且每一次畫素區520對應其中一個第 一透鏡422以及其中一個第二透鏡424。 | 接著,請參照圖6、圖7B與圖8,使一線性極化光70 經由光罩400而照射光配向材料層510.,其中線性辑化光 70的極化方向與第一波長延遲器432的第一光軸〇1之間 夾第一銳角’且線性極化光70的極化方向與第二波長延 遲器434的第二光軸〇2之間夾一第二銳角。線性極化光 7〇例如為紫外光,而線性極化光70的極化方向72與第一 波長延遲器432的第一光轴〇1之間所夾的銳角例如為45 度。如此’第一波長延遲器432能將線性極化光70的極化 方向成第一極化方向,在本實施例中,入射第一透鏡422Dxtan40+W/2 — H/tan61 = L/2 Equation (14) Figure 4 is a schematic diagram of a secondary halogen region of a liquid crystal display device. Referring to FIG. 3 and FIG. 4, when a multi-domain vertical alignment liquid crystal display device is fabricated, the area A1 and the area A2 can be designed as the main display area, so it is necessary to enlarge the range of the area A1 and the area A2 as much as possible to reduce the liquid crystal display device. The number of cuts in each field of the prime area. If only the light alignment material layer of the single substrate of the liquid crystal display device is used for the cutting of the field, the two pixel regions 300 corresponding to each pixel region are provided, and the width of each pixel region is 100#m 'the length is 30〇em. , then W/2 < 83.2 / zm. The height H of the lens 3A can be calculated from the equation (13). 80.8/zmo Further, when the lens 300 is separated from the photo-alignment material layer 50 by a distance D, the light-aligning material layer 50 is exposed to the region A4 which is not irradiated with light. If D = 0, L/2 = 83.2 / zm - 44.9 / zm = 38.3ym can be calculated from equation (14). If D = l^m, it can be calculated from the formula )4) 44.9/zm 15 201007351 rwiu-tJi^OZlTW 23669twf.d〇c/n = 39,lem. In other words, at D = l/zm, the width of the area A4 is only about 2x0.8 at m = 1.6/z m 〇 Based on the above, the photomask proposed by the present invention includes a plurality of the above-described lenses 300. Hereinafter, the photomask of the present invention will be described by way of an embodiment with reference to the drawings. 5 is a schematic view of a photomask according to an embodiment of the present invention, and FIG. 6 is a partial exploded perspective view of the lens array and the wavelength retarder array of FIG. 5, for clarity of the components between the lens array 420 and the retarder array 430. ❸, FIG. 6 omits the transparent substrate 410 of FIG. Referring to FIG. 5 and FIG. 6, the photomask 400 of the present embodiment includes a lens array 420 and a retarder array 430' and, in the embodiment, is selectively selectable between the lens array 42A and the wavelength retarder array 430. The light-transmitting substrate 41 is disposed. The transparent substrate 410 has a first surface 412 and a second surface 414. The lens array 420 is disposed on the first surface 412, and the wavelength retarder array 430 is disposed on the second surface 414. The lens array substrate 420 can also be directly bonded to the retarder array 43 without the need for a transparent substrate 410. The lens array 420 includes a plurality of first lenses 422 and a plurality of second lenses 424, and each of the first lenses 422 and each of the second lenses 424 is a trapezoidal cylinder (ie, the lens of FIG. 3). It is worth noting that the first lens 422 and the second lens 424 in this embodiment are used to change the exit angle of incident light, and thus the first lens 422 and the second lens 424 may be referred to as optical path change regions. The trapezoidal cylinder has a top surface 312 and a bottom surface 314 that are parallel to each other, two slopes 316, 318, and two stepped surfaces 322, 324 that are parallel to each other. The top surface 312 has an area smaller than the bottom surface 314 and the top surface 312 connects the first surface 412. The line connecting the geometrical center of the trapezoidal surface 322, 16 201007351 ruuitrHjj.OZlTW 23669 twf. doc/n 324 of each first lens 422 is a first straight line S1, and the geometric center of each trapezoidal surface 322, 324 of the second lens is connected. The line is a second straight line, and the first straight line S1 and the second straight line S2 are at an angle. The wavelength retarder array 430 includes a plurality of first wavelength retarders 432 opposite the first lens 422, and the first optical axis 〇1 of each of the first wavelength retarders 432 is sharply spaced from each of the first straight lines S1. In the photomask 400 described above, the first straight line S1 is substantially perpendicular to the second straight line Φ S2 . Further, an acute angle between the first optical axis 〇1 of each of the first wavelength retarders 432 and each of the first straight lines S1 is 45 degrees. Additionally, the wavelength retarder array 430 can further include a plurality of second wavelength retarders 434. These second wavelength retarders 434 are opposite the second lens 424, and the second optical axis 〇2 of each second wavelength retarder 434 is perpendicular to the second straight line 82. The first optical axis 〇1 of each first wavelength retarder 432 and the second optical axis 02 of each second wavelength retarder 434, for example, lose an angle of 45 degrees. In addition, the angles between the slopes 316, 318 of all trapezoidal cylinders 300 and the bottom surface 314 _ may all be the same or not identical. That is to say, the angle between the slopes 316, 318 and 314 of the partial trapezoidal cylinder 300 is the same, and the angle between the slopes 316, 318 and 314 of the partial trapezoidal cylinder 300 is different. In this way, the incident angles when the light is obliquely incident on the light-aligning material layer are different, so that the liquid crystal molecules have different pretilt angles. Since the tilt angle of the liquid crystal molecules affects the relationship between the transmittance of the liquid crystal molecules and the driving voltage, 'the liquid crystal molecules have different pretilt angles', the liquid crystal molecules can have various transmittances and driving voltages. Helps reduce color cast. 17 201007351 K UUJl u-tjjuOZITW 23669twf.doc/n The optical alignment process using the photomask 400 of the present embodiment will be described below with reference to the drawings. 7A and 7B are flow charts showing the steps of the optical alignment process in accordance with an embodiment of the present invention. Figure 8 is a schematic view of a photo-alignment process of an embodiment of the present invention. The substrate 500 of Figure 8 is a schematic view of the substrate of Figures 7A and 7B. Referring to FIG. 7A and FIG. 8, the optical alignment process of the present embodiment includes the following steps: First, the photomask 400 is aligned with a substrate 500, and the substrate 500 has a photoalignment material layer 510. The substrate 500 is, for example, a rectangular substrate or a square substrate', and the substrate 500 is divided into a plurality of rectangular sub-segments 520, and the long sides 522, 524 of each of the pixel regions 520 are parallel to two sides 502, 504 of the substrate 500. In addition, the reticle 400 is aligned with the substrate 500 such that each of the first straight lines S1 is parallel to each of the two sides 526, 528 of the halogen region 520, and each second straight line S2 is parallel to each other of the other two sides of the pixel region 520. 522, 524, and each pixel region 520 corresponds to one of the first lenses 422 and one of the second lenses 424. Next, referring to FIG. 6, FIG. 7B and FIG. 8, a linearly polarized light 70 is irradiated to the photoalignment material layer 510 via the mask 400, wherein the polarization direction of the linearized light 70 and the first wavelength retarder are A first acute angle ′ is sandwiched between the first optical axes 4321 of 432 and a second acute angle is sandwiched between the polarization direction of the linearly polarized light 70 and the second optical axis 〇2 of the second wavelength retarder 434. The linearly polarized light 7 is, for example, ultraviolet light, and the acute angle between the polarization direction 72 of the linearly polarized light 70 and the first optical axis 〇1 of the first wavelength retarder 432 is, for example, 45 degrees. Thus, the first wavelength retarder 432 can direct the polarization direction of the linearly polarized light 70 to the first polarization direction. In the present embodiment, the first lens 422 is incident.

1S 201007351 x ww-r^^OZlTW 23669twf.doc/n 的線性極化光70之極化方向經過第一波長延遲器432改變 其極化方向,使得線性極化光70的極化方向成第一極化方 向且垂直第一直線S1。另外,若所用之光罩4〇〇之波長延 遲器陣列430包括多個第二波長延遲器434,藉由第二波長 延遲器434可以將光線極化方向變成第二極化方向。在本 實施例中,每一第二波長延遲器434的第二光軸〇2平行線 性極化光70的極化方向72,則入射第二透鏡424的線性極 ❹ 化光70之極化方向不會受到改變,仍保持垂直第二直線S2。 由於線性極化光70通過光罩400之第一透鏡422後會 以兩種不同的入射方向照射在光配向材料層5〗〇,且線性極 化光70通過光罩400之第二透鏡424後會以兩種不同的入 射方向照射在光配向材料層510。如此,光配向材料層510 在經過光配向製程後,可使液晶分子有四種傾斜方向(如圖 8之實心箭號所示)。此外,由於本實施例之光配向製程只 需對光配向材料層510照射一次’所以可節省製程時間。 圖9是本發明另一實施例之光配向製程的示意圖。請 參照圖9,本實施例之光配向製程與前述相似,以下僅針對 不同處進行說明。在本實施例中,基板500,之每一次晝素 區520’之長邊522’、524,與基板500,之每一邊502、504、 506、508皆夾45度角。而將光罩4〇〇與基板500,進行對位 後使每一第一直線S1平行每一次晝素區520,之其中兩邊 526’、528’ ’並使每一第二直線S2平行每一次晝素區52〇, 之另外兩邊522’、524,,且每一次畫素區520,對應其中一 個第一透鏡422以及其中一個第二透鏡424。 19 201007351 ruoxu^jx^OZlTW 23669tw£doc/n 如此,光配向材料層510在經過光配向製程後,可使 液晶分子有四種傾斜方向(如圖9之實心箭號所示)。 圖10是本發明另一實施例之光配向製程的示意圖。請 參照圖10 ’本實施例之光配向製程與前述相似,以下僅針 對不同處進行說明。在本實施例中所使用的基板5〇〇與圖8 之基板漏相同’且本實關所使用之光罩的各第一透鏡 422’與第二透鏡424’的尺寸略小於光罩彻之各第一透鏡 422與第二透錄424的尺寸。 圖1〇之格線IV[是光罩之透鏡陣列正向投影在基板的 示意圖。在本實施例中,將光罩與基板5〇〇進行對位使每 一第一直線S1與每一次晝素區52〇之每一邊522、524、 526、528皆夾45度角,並使每一第二直線S2與每一次晝 ,區520之每一邊522、524、526、528皆夾45度角,且 母··入晝素區520對應上述多個第二透鏡424’其中之二以 及鄰接此一第二透鏡424’之每一第一透鏡422,之部分。 _ 如此,光配向材料層51〇在經過光配向製程後,可使 液晶分子有四種傾斜方向(如圖1〇之實心箭號所示)。 由於本發明之光罩的每一第一透鏡及每一第二透鏡皆 具有兩個斜面’所以可讓線性極化光以四種不同的入射方 向,照射光配向材料層。因此,相較於習知技術,本發明 之光配向製程僅需對光配向材料層照射一次,所以能節省 製程時間。 —雖然本發明已以較佳實施例揭露如上,然其並非用以 限疋本發明’任何所屬技術領域中具有通常知識者,在不 20 201007351 ……儿 JZlTW23669twf;doc/n 脫離本發明之精神和範圍内’當可作些許之更動與潤飾’ 因此本發明之保護範圍當視後附之申請專利範園所界定者 為準。 【圖式簡單說明】 圖1緣示為習知之液晶顯示面板之剖面示意圖。 圖2是光線自一透鏡出射後的光路徑示意圖。 ❹ 圖3是光線自另一種透鏡出射後的光路徑示意圖。 圖4是液晶顯示裝置之一個次晝素區的示意圖。 圖5是本發明一實施例之光罩的示意圖。 圖6是圖5之透鏡陣列及波長延遲器陣列的局部爆 立體圖。 圖7A與圖7B繪示本發明一實施例之光配向製 驟流程圖。 刃乂 圖8是本發明一實施例之光配向製程示意圖。 e 圖9是本發明另一實施例之光配向製程ί示意圖。 圖1〇是本發明另-實施例之光配向製程的示意圖。 【主要元件符號說明】 2〇 ·光線 3〇 :液晶分子 50、510 :光配向材料層 7〇 :線性極化光 72 :極化方向 21 OZ1TW 23669twf.doc/n 201007351 100 .液晶顯不面板 110 :對向基板 120 :基板 130、140 :配向層 150 .液晶層 200 :透鏡 210 :凹槽 212、214 :斜面 216 :頂面 300 :梯形柱體 312 :頂面 314 :底面 316、318 :斜面 400 :光罩 410 :透光基板 412 :第一表面 414 :第二表面 420 :透鏡陣列 422 :第一透鏡 424 :第二透鏡 430 :波長延遲器陣列 432 :第一波長延遲器 434 :第二波長延遲器 500、500’ :基板 22 20100735 ljzlTW_c/n 520、520’ :次晝素區 502、504、506、508、522、522,、524、524,、526、 526,、528、528,:邊 A1〜A6 :區域 D :距離 L :寬度 ΟΙ :第一光軸 02 :第二光軸 51 :第一直線 52 :第二直線 0 1 〜0 6、Θ LENS、Θ UV ·角度 231S 201007351 x ww-r^^OZlTW 23669twf.doc/n The polarization direction of the linearly polarized light 70 is changed by the first wavelength retarder 432, so that the polarization direction of the linearly polarized light 70 is first The direction of polarization is perpendicular to the first straight line S1. Further, if the wavelength retarder array 430 of the photomask 4 used includes a plurality of second wavelength retarders 434, the second wavelength retarder 434 can change the direction of polarization of the light into the second polarization direction. In the present embodiment, the second optical axis 〇2 of each second wavelength retarder 434 is parallel to the polarization direction 72 of the linearly polarized light 70, and then the polarization direction of the linearly polarized light 70 incident on the second lens 424 is incident. Will not be changed, still maintain the vertical second line S2. Since the linearly polarized light 70 passes through the first lens 422 of the reticle 400, it will illuminate the photoalignment material layer 5 in two different incident directions, and the linearly polarized light 70 passes through the second lens 424 of the reticle 400. The photoalignment material layer 510 is illuminated in two different incident directions. Thus, after the photo-alignment material layer 510 is subjected to the photo-alignment process, the liquid crystal molecules can be made to have four oblique directions (as shown by the solid arrows in FIG. 8). In addition, since the photo-alignment process of the present embodiment only needs to illuminate the photo-alignment material layer 510 once, the process time can be saved. Figure 9 is a schematic illustration of a photoalignment process in accordance with another embodiment of the present invention. Referring to Fig. 9, the optical alignment process of this embodiment is similar to the foregoing, and the following description is only for different places. In the present embodiment, the long sides 522', 524 of each of the substrate regions 520' of the substrate 500 are at an angle of 45 degrees to each of the sides 502, 504, 506, 508 of the substrate 500. After the photomask 4 is aligned with the substrate 500, each first straight line S1 is parallelized with each of the halogen regions 520, and two sides 526', 528'' are made and each second straight line S2 is paralleled each time. The prime region 52A, the other two sides 522', 524, and each pixel region 520, corresponds to one of the first lens 422 and one of the second lenses 424. 19 201007351 ruoxu^jx^OZlTW 23669tw£doc/n Thus, after the optical alignment material layer 510 is subjected to the photo-alignment process, the liquid crystal molecules can be tilted in four directions (as shown by the solid arrows in FIG. 9). Figure 10 is a schematic illustration of a photoalignment process in accordance with another embodiment of the present invention. Referring to Fig. 10, the optical alignment process of the present embodiment is similar to the foregoing, and only the differences will be described below. The substrate 5〇〇 used in the present embodiment is the same as the substrate drain of FIG. 8 and the first lens 422' and the second lens 424' of the photomask used in the present embodiment are slightly smaller in size than the photomask. The size of each of the first lens 422 and the second through 424. Figure 1 is a schematic diagram of the grid line IV of the reticle of the reticle on the substrate. In this embodiment, the photomask and the substrate 5 are aligned such that each of the first straight lines S1 and each of the sides 522, 524, 526, and 528 of each of the halogen regions 52 are at an angle of 45 degrees, and each a second straight line S2 and each turn, each side 522, 524, 526, 528 of the region 520 is at an angle of 45 degrees, and the parent input region 520 corresponds to two of the plurality of second lenses 424' and Adjacent to each of the first lenses 422 of the second lens 424'. _ Thus, after the photo-alignment material layer 51 is subjected to the photo-alignment process, the liquid crystal molecules can be tilted in four directions (as shown by the solid arrow in Fig. 1). Since each of the first lens and each of the second lenses of the reticle of the present invention has two slopes, linearly polarized light can be irradiated to the layer of light alignment material in four different incident directions. Therefore, compared with the prior art, the photo-alignment process of the present invention only needs to irradiate the photo-alignment material layer once, so that the process time can be saved. - Although the present invention has been disclosed above in the preferred embodiments, it is not intended to limit the invention to any of the ordinary skill in the art, in the absence of 20 201007351 ... JZlTW23669twf; doc / n out of the spirit of the present invention And the scope of the invention may be modified and modified. Therefore, the scope of protection of the present invention is subject to the definition of the patent application. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic cross-sectional view showing a conventional liquid crystal display panel. 2 is a schematic view of a light path after light is emitted from a lens. ❹ Figure 3 is a schematic diagram of the light path after light is emitted from another lens. 4 is a schematic view of a secondary halogen region of a liquid crystal display device. Figure 5 is a schematic illustration of a reticle in accordance with an embodiment of the present invention. Figure 6 is a partial exploded perspective view of the lens array and wavelength retarder array of Figure 5. 7A and 7B are flow charts showing an optical alignment process according to an embodiment of the present invention.乂 Figure 8 is a schematic view of a photo-alignment process in accordance with an embodiment of the present invention. e is a schematic diagram of an optical alignment process according to another embodiment of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic illustration of an optical alignment process in accordance with another embodiment of the present invention. [Description of main component symbols] 2〇·Light 3〇: Liquid crystal molecules 50, 510: Light alignment material layer 7〇: Linearly polarized light 72: Polarization direction 21 OZ1TW 23669twf.doc/n 201007351 100. Liquid crystal display panel 110 : opposite substrate 120 : substrate 130 , 140 : alignment layer 150 . liquid crystal layer 200 : lens 210 : grooves 212 , 214 : bevel 216 : top surface 300 : trapezoidal cylinder 312 : top surface 314 : bottom surface 316 , 318 : bevel 400: reticle 410: transparent substrate 412: first surface 414: second surface 420: lens array 422: first lens 424: second lens 430: wavelength retarder array 432: first wavelength retarder 434: second Wavelength retarder 500, 500': substrate 22 20100735 ljzl TW_c/n 520, 520': secondary pixel regions 502, 504, 506, 508, 522, 522, 524, 524, 526, 526, 528, 528, : Side A1 to A6 : Area D : Distance L : Width ΟΙ : First optical axis 02 : Second optical axis 51 : First straight line 52 : Second straight line 0 1 ~ 0 6 , Θ LENS, Θ UV · Angle 23

Claims (1)

201007351 ▲,一 0Z1TW 23669twf_doc/n 十、申謗專利範面: I一種光罩,包括: 一 一透鏡陣列,包括交替排列的多個第一透鏡與多 ^透鏡’每-第-透鏡及每—第二透鏡分別為—梯形^ ’且該梯形柱體具有相互平行之一頂面與一底面、相互 ”仃^兩梯形表面以及兩斜面,該頂面的面積小於該底 面,每一第一透鏡之該些梯形表面之幾何中心的連線為二 直線,每一第二透鏡之該些梯形表面之幾何中心的連 产為了第二直線,且該第一直線與該第二直線之間夾一角 一波長延遲器陣列,配置於該透鏡陣列之該些頂面所 構成的一基準面上,該波長延遲器陣列包括多個第一波長 L遲器與夕個第一波長延遲器,其中該些第一波長延遲器 與該些第一透鏡相對,而該些第二波長延遲器與該些第二 透鏡相對。 2.如申請專利範圍第1項所述之光罩,其中每一第一波 長延遲器具有一第一光軸與每一第一直線之間夾一第一銳 角。 3.如申請專利範圍第1項所述之光罩,其中每一第二波 長延遲器具有一第二光軸與每一第二直線之間夾一第二銳 角。 4. 如申請專利範圍第2項所述之光罩’其中該第一銳角 為45度。 5. 如申請專利範圍第1項所述之光罩,其中該些第一直 24 uZITW 23669twf.doc/n 201007351 線實質上垂直該些第二直線。 6. 如申請專利範圍第丨項所述之光罩,其中該些梯形柱 體之該些斜面與該些底面之間的夾角相同。 7. 如申請專利範圍第1項所述之光罩,其中該些梯形柱 體之該些斜面與該些底面之間的夾角不完全相同。 8. —種光配向製程,包括: 提供一基板; 參 於該基板上形成一光配向材料層; 將申請專利範圍第1項之光罩與該基板進行對位;以 及 使一線性極化光經由該光罩而照射該光配向材料層, 其中該線性極化光的極化方向與該第一波長延遲器所^有 之第一光轴之間爽一銳角。 9. 如申請專利範圍第8項所述之光配向製程,其中該線 性極化光的極化方向與該第一波長延遲器的光軸之間所夾 t 的銳角為45度。 m 10. 如申請專利範圍第9項所述之光配向製程,其中該 光罩之該波長延遲器陣列更包括多個第二波長延遲器,與 該光罩之該些第二透鏡相對,且每一第二波長延遲^具有 一第二光軸平行該線性極化光的極化方向。 H.如申請專利範圍第8項所述之光配向製程,其中該 基=為矩形基板或正方形基板,且該基板劃分為多個矩^ 的次畫素區,每一次畫素區之長邊平行該基板之其中兩 邊,而將該光罩與該基板進行對位,以使每—第一直線平 25 uZlTW23669twf.doc/n 201007351 行每一次晝素區之其中兩邊,並使每一第二直線平行每一 次晝素區之另外兩邊,且每一次晝素區對應該些第一透鏡 其中之一以及該些第二透鏡其中之一。201007351 ▲, a 0Z1TW 23669twf_doc/n X. Application Patent Specification: I A mask comprising: a lens array comprising a plurality of first lenses alternately arranged with a plurality of lenses 'per-lens and per-- The second lens is respectively - trapezoidal ^ ' and the trapezoidal cylinder has one top surface and one bottom surface parallel to each other, two mutually trapezoidal surfaces and two inclined surfaces, the top surface having an area smaller than the bottom surface, each first lens The connecting lines of the geometric centers of the trapezoidal surfaces are two straight lines, and the geometric centers of the trapezoidal surfaces of each second lens are connected to a second straight line, and a corner is formed between the first straight line and the second straight line. a wavelength retarder array disposed on a reference surface formed by the top surfaces of the lens array, the wavelength retarder array comprising a plurality of first wavelength L delay devices and a first wavelength retarder, wherein the A wavelength retarder is opposite to the first lenses, and the second wavelength retarders are opposite to the second lenses. 2. The photomask of claim 1, wherein each of the first wavelength delays Device A first optical axis is sandwiched between each of the first optical axes and the first optical line. The reticle of claim 1, wherein each of the second wavelength retarders has a second optical axis and each A second acute angle is sandwiched between the two straight lines. 4. The reticle of claim 2, wherein the first acute angle is 45 degrees. 5. The reticle of claim 1, wherein The first straight 24 uZITW 23669 twf.doc/n 201007351 line is substantially perpendicular to the second straight lines. 6. The reticle of claim 2, wherein the slopes of the trapezoidal cylinders The reticle is the same as the reticle of the first aspect of the invention, wherein the angle between the slopes of the trapezoidal cylinders and the bottom surfaces is not exactly the same. The alignment process comprises: providing a substrate; forming a light alignment material layer on the substrate; aligning the photomask of claim 1 with the substrate; and passing a linearly polarized light through the mask Irradiating the layer of light alignment material, wherein the linearity The polarization direction of the illuminating light is an acute angle with the first optical axis of the first wavelength retarder. 9. The optical alignment process of claim 8, wherein the linearly polarized light An acute angle of the polarizing angle between the polarization direction and the optical axis of the first wavelength retarder is 45 degrees. m 10. The optical alignment process of claim 9, wherein the wavelength retarder of the photomask The array further includes a plurality of second wavelength retarders opposite to the second lenses of the reticle, and each of the second wavelength delays has a second optical axis parallel to a polarization direction of the linearly polarized light. The optical alignment process of claim 8, wherein the base = a rectangular substrate or a square substrate, and the substrate is divided into a plurality of sub-pixel regions, wherein the long sides of each pixel region are parallel. Two sides of the substrate, and the photomask is aligned with the substrate such that each of the first straight lines is 25 uZl TW23669 twf.doc/n 201007351 each of the two sides of the pixel region, and each second line is paralleled The other two sides of the Qisu district, and each time the district One of the first lenses and one of the second lenses are corresponding. ❹ 12.如申請專利範圍第8項所述之光配向製程,其中該 基板為矩形基板或正方形基板,且該基板劃分為多個矩形 的次畫素區,每一次畫素區之長邊與該基板之每一邊皆夾 45度角,而將該光罩與該基板進行對位,以使每一第一直 線平行母一次畫素區之其中兩邊,並使每一第二直線平行 每一次晝素區之另外兩邊,且每一次晝素區對應該些第一 透鏡其中之一以及該些第二透鏡其中之一。 13.如申請專利範圍第8項所述之光配向製程,其中該 基,為矩職板或正方形基板,且該基板D為多個矩形 t次晝素區,每一次畫素區之長邊平行該基板之其中兩 ,,,將該光罩與該基板進行對位,以使每一第一直線與 素區之每一邊皆夾45度角,並使每-第二直線ί = —邊皆夾45度角,且每—次畫素區對應 透鏡鏡其中之二以及鄰接該二第二透鏡之每一第一 線性顚第8項所述之統向製程,其中該 1 一5 =種光罩’適於讓—光線穿過,該光罩包括: 變列,其巾親鱗列包含錢數個光路徑改 及光線藉由該些光路徑改變區域改變其出射角 26 wZITW 23669twf.doc/n 201007351 -波長延遲ϋ_,設置於透鏡_之上,波長延遲 器陣列包含-第-波長延遲器與—第二波長延遲器,部分 該光線穿透該第-波長延遲器後具有一第一光極化方向, 另-部份該光線穿透該第二波長延遲器後具有一第二光極 化方向。 16·如申請專利範圍第15項所述之光罩,其中該些光路 徑改變,域包括交替排列的多個第—透鏡與多個第二透 ❹ 鏡三且每一第一透鏡及每一第二透鏡分別與該第一波長延 遲器以及該第二波長延遲器對應排列配置。 17. 如申請專利範圍第15項所述之光罩,其中每一第一 透鏡之該些表面之幾何中^的連線為―第—直線,且每一 第-波長延遲器具有—第―光軸與每—第—直線之間具有 一夾角。 18. 如申請專利範圍第15項所述之光罩,其中每一第二 透鏡之該些表面之幾何中心的連線為一第二直線,且每一 第二波長延遲器具有一第二光軸與每一第二直線之間具有 一夾角。 19. 一種光配向製程,包括: 提供一基板; 於該基板上形成一光配向材料層; 提供一光罩,該光罩適於讓一光線穿過,該光罩包含: ‘ 一透鏡陣列’其中該透鏡陣列包含有複數個光路徑 改變區域,該光線藉由該些光路徑改變區域改變其出射角 度; 27 jZlTW23669twf.doc/n 201007351 一波長延遲器陣列,設置於透鏡陣列之上,波長延 遲器陣列包含一第一波長延遲器與一第二波長延遲器,部 分該光線經由該第一波長延遲器後具有一第一光極化方 向,另一部份該光線穿透該第二波長延遲器後具有一 光極化方向; ^ 一 將該光罩與該基板進行對位;以及 ❹ 使-線性極化光經由該光罩而照射該光配向 其中該線性極化光透過該-光罩可以產生多 以及多個的光極化方向。 町龙^度The optical alignment process of claim 8, wherein the substrate is a rectangular substrate or a square substrate, and the substrate is divided into a plurality of rectangular sub-pixel regions, and the long side of each pixel region is Each side of the substrate is at an angle of 45 degrees, and the reticle is aligned with the substrate such that each first line is parallel to two sides of the primary primary pixel region, and each second line is paralleled each time. The other two sides of the prime zone, and each of the halogen regions corresponds to one of the first lenses and one of the second lenses. 13. The optical alignment process of claim 8, wherein the base is a rectangular or square substrate, and the substrate D is a plurality of rectangular t-dimorphic regions, each long side of the pixel region Parallel to two of the substrates, the photomask is aligned with the substrate such that each of the first straight lines and each of the prime regions are at an angle of 45 degrees, and each of the second straight lines ί = Having a 45 degree angle, and each of the pixel regions corresponds to two of the lens mirrors and a first linear process described in item 8 of the first linear 邻接 adjacent to the second lens, wherein the one 5 = species The reticle is adapted to allow light to pass through, and the reticle comprises: a variable column, the scalar column containing the money, a plurality of light paths, and the light beam changing the exit angle by the light path changing region 26 wZITW 23669twf.doc /n 201007351 - a wavelength delay ϋ_, disposed above the lens_, the wavelength retarder array comprising a -th-wave retarder and a second wavelength retarder, the light having a first pass through the first-wave retarder The direction of polarization of the light, and another portion of the light having a pass through the second wavelength retarder The second photopolarization direction. The reticle of claim 15, wherein the light paths are changed, the domains comprising a plurality of first lenses and a plurality of second lens 316 and each of the first lenses and each The second lens is arranged in alignment with the first wavelength retarder and the second wavelength retarder, respectively. 17. The reticle of claim 15, wherein the line of the surfaces of each of the first lenses is a "first line" and each of the first wavelength retarders has a - The optical axis has an angle with each—the first line. 18. The reticle of claim 15, wherein a line connecting the geometric centers of the surfaces of each of the second lenses is a second line, and each of the second wavelength retarders has a second optical axis There is an angle between each second line. 19. An optical alignment process comprising: providing a substrate; forming a layer of optical alignment material on the substrate; providing a reticle adapted to pass a light, the reticle comprising: 'a lens array' The lens array includes a plurality of light path changing regions, wherein the light changes the exit angle by the light path changing regions; 27 jZlTW23669twf.doc/n 201007351 A wavelength retarder array disposed on the lens array with wavelength delay The array includes a first wavelength retarder and a second wavelength retarder, wherein the light has a first polarization direction of light after the first wavelength retarder, and another portion of the light penetrates the second wavelength delay Having a polarization direction of the light; ^ aligning the reticle with the substrate; and illuminating the linearly polarized light through the reticle to align the light with the linearly polarized light passing through the reticle Multiple and multiple optical polarization directions can be generated. Machimachi 2828
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI413815B (en) * 2010-11-09 2013-11-01 Sumika Technology Co A pattern difference film with a registration mark
CN105892156A (en) * 2016-06-07 2016-08-24 深圳市华星光电技术有限公司 Method for exposing transparent substrate
WO2017210947A1 (en) * 2016-06-07 2017-12-14 深圳市华星光电技术有限公司 Method for performing optical alignment on liquid crystal panel and photomask

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI413815B (en) * 2010-11-09 2013-11-01 Sumika Technology Co A pattern difference film with a registration mark
CN105892156A (en) * 2016-06-07 2016-08-24 深圳市华星光电技术有限公司 Method for exposing transparent substrate
WO2017210947A1 (en) * 2016-06-07 2017-12-14 深圳市华星光电技术有限公司 Method for performing optical alignment on liquid crystal panel and photomask
US10175539B2 (en) 2016-06-07 2019-01-08 Shenzhen China Star Optoelectronics Technology Co., Ltd Method of performing photo alignment to liquid crystal panel and mask
CN105892156B (en) * 2016-06-07 2019-05-03 深圳市华星光电技术有限公司 The method that transparent substrate is exposed
US10527947B2 (en) 2016-06-07 2020-01-07 Shenzhen China Star Optoelectronics Technology Co., Ltd Method for exposing transparent substrate

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