TW200939963A - Pesticidal mixtures - Google Patents

Abstract

The present invention relates to synergistic mixtures comprising, as active components, an insecticidal compound I selected from the nicotinic receptor agonists/antagonists compounds and one or two further fungicidal compounds in synergistic effective amounts.

Description

200939963 VI. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD The present invention relates to a synergistic mixture which comprises a synergistically effective amount of the following components as an active ingredient, 1) selected from the following nicotinic receptor agonist/antagonist compounds Insecticidal compound I: acetamiprid, clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram; And ❹ 2) - a fungicidal compound II selected from the group consisting of: triticonazole, fluquinconazole, prothioconazole, difenophene (difenoconazole), ipconazole, flutriafol and tebuconazole; 3) - or two other fungicidal compounds selected from the group consisting of: methylpoly Thiophanate-methyl), prochloraz, pyraclostrobin, azoxystrobin, trifloxystrobin, oressastrobin, metalaxyl, dysprosium Dimethomorph, Ν_(3',4·,5'-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1Η-pyrazole-4-carboxamide, Ν-[2-(4·-Trifluoromethylthio)-biphenyl]-3-difluoromethyl-1-indolyl-1Η-pyrazole-4-decylamine, Ν-(3',4 ·-Digas-5-fluorobiphenyl-2-yl)-3-difluorodecyl-1-methylcarbazole-4-decylamine (common name: bixafen), Ν·[ 2-(1,3-Dimethylbutyl)-phenyl]-1,3-dimethyl-5-fluoro-111-pyrazole-4-cartoamine, 1<[-(2-bicyclopropyl Base-2-138195.doc 200939963 phenyl-phenyl)-3-difluorodecyl-1-methyl-1 Η-° than salivary 4- 4-carbamide (sedaxane), N-[ l,2,3,4-Tetrahydro-9-(1-methylethyl)_14_ 曱naphthalen-5-yl]-3-(dimethylfluorenyl)-1-methyl-1H-" Salivary _4_carbamamine (common name: isopyrazam) and N-[2-(l,3-dimethylbutyl)-3-thienyl]-1-methyl-3- ( Trifluoromethyl)-1Η-η is more than 嗤-4-decylamine (common name: 0 to 0 penthiopyrad). The present invention further relates to a binary mixture comprising sub-excise and cyclosporine as an active ingredient. The above-mentioned mixture is hereinafter also referred to as "the mixture of the present invention". Further, the present invention relates to a method for controlling pests (this means including animal pests and harmful fungi) using the mixture of the present invention, and compound compounds Use of II and Compound 111 (or Compounds I and H as defined above) for the preparation of such mixtures, and compositions comprising such mixtures. In one embodiment, the invention provides for the control of animal pests (such as insects, mites or The method of nematode" comprises contacting the animal pest (insect, cockroach or nematode) or its food source, habitat, breeding ground or its location with a pesticidally effective amount of a mixture of the invention. Further 'in another embodiment' The invention also relates to a method of protecting a plant from attack or infestation by an animal pest (insect, worm or nematode) comprising contacting the plant or the soil or water from which the plant is grown with a pesticidally effective amount of a mixture of the invention. In addition, the present invention also encompasses a plant-protecting material that protects against harmful pests such as fungi or insects, spiders or lines. A method of infusing comprising contacting a plant propagation material with a pesticidally effective amount of a mixture of the invention. 138195.doc 200939963 It should be understood that the term "plant propagation material" denotes all reproductive parts of a plant, such as seeds and vegetative plants. Substances, such as cuttings (tubers) and tubers (eg potatoes), can be used for plant proliferation. This includes seeds, root fruits, tubers, bulbs, rhizomes, #, sprouts and other parts of plants, including seedlings and young plants, To be transplanted after germination or after emergence from the soil. Such young plants may also be protected by whole or partial treatment by dipping or pouring prior to transplantation. In a particularly preferred embodiment, the term reproductive material is indicated. In addition, the invention relates to a method of using the mixture of the invention to control the presence of a fungus, and the use of the compound and the compound η and the compound or the compounds I and II as defined above for the preparation of such mixtures, and Compositions of such mixtures. The present invention additionally relates to synergistic enhancements with improved plant health A plant protection active ingredient mixture and a method of applying the mixture of the present invention to a plant. [Prior Art] A compound of the formula I, the formula π and the formula III and its insecticidal action and a method for producing the same are generally known. , commercially available compounds can be found in The Pesticide

Manual, 13th edition, British Crop Protection Council (2003) and other publications. Metalaxyl is a fungicide herein, which comprises: gendane; consists of equal or greater than 50% by weight of the R enantiomer and equal to or less than 50% of the S enantiomer. Destroy; a ruthenium consisting of 85% by weight or more of the R enantiomer and 15% or less of the S enantiomer; from 92 138195.doc 200939963% by weight of the R enantiomer and Deuterium consisting of 8% or less of the S enantiomer; statin consisting of 97% by weight or more of the R enantiomer, 3% or less of the S enantiomer; and metalaxyl (mefenoxam) (i.e., more than 97.5% of R-Delta or Verbroxol and 2.5% or less of the S enantiomer). See, for example, the Pesticide Manual, 11th Edition (1997), The British Crop Protection Council, London, page 792; and the

Pesticide Manual, 11th Ed. (1997), The British Crop Protection Council, London, page 794 ° A binary mixture comprising cotinine along with a large number of potential fungicidal mash mixed collaterals is disclosed in WO 99/63826. A combination comprising acesulfame and a clear disclosure of edetamine together with a large number of potential fungicidal mixed collocations is disclosed in WO 96/3 045. Mixtures of cyclosporin and poker are disclosed in EP 467 972, EP 466 612 and PCT/EP2007/063417. A mixture of cyclosporine and pyrimethanil is disclosed in FR 2742310. A combination of poker pull and pyrimethanil is disclosed in DE 43 18372. A mixture of a neonicotinoid and a strobilurin is disclosed in WO 06/069654, WO 06/089876, and WO 06/23899. WO 06/23899 also discloses a mixture of edetamine and other fungicides. WO 08/006541 discloses a mixture of a pyridoxamine having a fungicide which may optionally comprise an insecticide. WO 97/22254 discloses a mixture of cyanosine and azoles such as cyclosporin, pyrimethanil and pram. WO 08/095891 comprises a mixture of cotinidine and cyclosporine 138195.doc 200939963. WO 06/128655 discloses a mixture of a neonicotinoid analog with several azoles, and a mixture of a plurality of insecticides which can be combined with several fungicides. WO 06/24333 describes neonicotinoid analog formulations which may comprise at least one other fungicide as the second component. A binary mixture comprising the specified carboguanamine, epoxiconazole or metconazole, which may comprise other commercial insecticides. Suitable ternary blends mentioned elsewhere are glyphosate, sulphosate, gluphosinate, tefluthrin, terbufos, and taosson. Chlorpyrifos), chloroethoxyfos, tebupirimfos, phenoxycarb, diofenolan, pymetrozine, imazethapyr , imazamox, imimazzy, imazapic, imazaquin or dimethenamid-P, especially glyphosate Phosphine, phosphinothricin, glufosinate or succinimide, fipronil, edetamine, arbutin, enebramycin, carbofuran, butyl plus guaia Carbosulfan), benfuracarb, dartnam, locust · #, 赛速安, konidine, diflubenzuron, flufenoxuron, teflubenzuron, race Alpha-cypermethrin and metaflumizone, especially fipronil, edetamine, and arbutin Plus Baofu, Sai Su, Kenidin, Flufenprox, Defulong, α_赛灭宁 and US Fluoride (European application No. 8152〇59, No. 5, European application No. 08155881.9, Europe Application No. 07119858.4 and 〇丁/丑?2008/051955). 138195.doc 200939963 A combination comprising a combination of a specified carboguanamine and anthraquinone and a combination of the indoleamine, the compound of the formula I, and the methylpreservation of the formula I is disclosed in WO 07/017416. Combinations of a guanamine compound of formula I with methyl valproate are disclosed in PCT/EP2008/051331 and in PCT/EP2008/051375. Combinations of specific guanamines of carboxyguanamine with neonicotinoids and fungicides are disclosed in WO 08/000377. A general disclosure of guanamines of carboxyguanamine along with macrofungicides or several insecticides is set forth in WO 07/128756. However, specific binary, ternary and quaternary mixtures of the invention based on Compound I and Compound π and Compound 111 (or Compounds I and π as defined above) are not disclosed. In addition, there is no mention of a specific combination of the compound and II as defined above. A typical problem in the field of pest control is the need to reduce the dose rate of the active ingredient to reduce or avoid adverse environmental or toxicological effects while still allowing effective pest control. Regarding the present invention, the term pest includes animal pests and harmful fungi. Another problem faced is the need for pest control agents that are effective against a wide range of pests, such as animal pests and harmful fungi. There is also a need for a pest control agent that combines potent activity with long-term control (ie, rapid action and long-lasting action). Another difficulty associated with the use of insecticides is that repeated and specialized application of individual insecticidal compounds in many cases leads to rapid selection of pests (which means that animal pests that have produced natural or adapted resistance to the active compound in question and Harmful fungi). Thus 'pests that help prevent or overcome resistance 138195.doc 200939963 Control Agent Presence Needed>> Another potential problem in the present invention is the composition of the improved plant, usually and hereinafter referred to as "plant health" The need for a method. The term plant health includes improvements in various categories of plants that are not associated with pest control. By way of example, advantageous features which may be mentioned are improved crop characteristics including: emergence, crop yield, protein content, oil content, starch content, more developed roots (improved root growth), improved Stress tolerance (eg, resistance to drought, heat, salt, uv, water, cold), ® reduced ethylene (reducing production and/or inhibition of acceptance), tillering, plant height increase, larger leaves, more Less dead base leaves, stronger strong tillers, more green color, pigment content, photosynthetic activity, need less input (such as fertilizer or water), less seeds, more production tillers, early flowering, early grain ripening, Small plants fall down (falling), enhance bud growth, enhance plant vigor, enhance plant standing, and early and better germination ^ any other advantage known to those skilled in the art [invention] Accordingly, it is an object of the present invention to provide a solution to the problem of reducing the dose rate and/or (iv) the range of activity and/or combining strong activity with long-term control and/or resistance management and/or promoting plant health. Insecticide mixture. We have found that this goal is achieved, in part or in whole, by a complex mixture comprising the active compounds defined at the outset. In particular, it has been found that the person as defined at the beginning does not significantly enhance the pest resistance effect compared to the possible control rate of the individual compound, and/or when applied to plants, parts of plants, seeds, or When it is grown, 138195.doc 200939963 is suitable for improving plant health. It has been found that the effects of the mixtures according to the invention are far more durable than the fungicidal and/or insecticidal and/or plant health improving effects of the active compounds present alone in the mixture. In addition, we have found that simultaneous application of compound j and compound II and compound III (or compounds 1 and 11 as defined above) or compound I and compound II and compound „1 (or compound 1 as defined above) And 11) permitting enhanced control (collaborative mixture) of pests (which means animal pests and harmful fungi) compared to possible control rates of individual compounds. Preferably, the ternary or quaternary mixture according to the invention comprises Cannidine, edamine, acesulfame or arbutin 'better cotinine, idacaine or cyanohydrin as compound I. Preferred compound II is cyclosporine, propionate thiocyanate, more preferably Preferably, compound III is selected from the group consisting of: thiophene chlorhexate, poker larva, baikemin, acesulfame, halal, ν_(3ι, 4,, 5, _Trifluorobiphenyl 2-yl)-3-_fluoromethylmethyl 吼 吼 吼 甲 甲 甲 酿 酿 2- [2-(1,3_dimethylbutyl)_ stupid]·13 曱_5 fluoride old pyrazole carbenamide Ν-(2-bicyclopropyl-2-yl phenyl)_3_difluoromethyl small methyl (1) (tetra) · 4 · methotrexate (common name: match达先)胜(10),3_dimethyl butyl butyl) 3- succinyl W-mercapto _3_(trimethyl sulfhydryl)_m_吼sal _4• snail amine (commonly used:: thifluzamide ) 'Better Poker, Hundreds of Sensitive, Ethylamine, Destroyed and Called + 嗤-4·Carbamine' Best Poker, Hundreds of Kemin, Destroy and __(3·, 4,, 5 , tri-Ibi-2-yl) 3-difluoromethyl small methyl-1Hh4_cartoamine. '138195.doc 200939963 is preferably a ternary mixture of the invention containing cytosine as compound i. Preferably, the present invention comprises a quaternary mixture of the invention as a compound I. Preferred is a ternary mixture of the invention containing edaamine as compound I. A quaternary mixture of the invention comprising edaamine as compound I is preferred. Preferably, the ternary mixture of the present invention containing cotinine as the compound I. It is preferably a quaternary mixture of the present invention containing cotinine as the compound I. Preferred is a ternary mixture of the invention containing cyclosporine as the compound II. Preferably, the quaternary mixture of the present invention containing cyclosporine as compound II is preferably a ternary mixture of the invention containing poker as compound III. Preferably, the quaternary mixture of the present invention containing poker as the compound III is preferably a ternary mixture of the invention containing hexamin as the compound III. It is preferably a quaternary mixture of the invention containing hexamin as the compound III. Preferably, the present invention is a ternary mixture of the present invention containing sedative as the compound III. Preferably, the quaternary mixture of the present invention containing epoxidin as the compound III. Preferably, the ternary of the invention containing the trifluoro-sensitive compound III The mixture is preferably a quaternary mixture of the invention containing trifluoro-sensitive as compound III. A ternary mixture of the invention containing atramine as compound III is preferred. Preferred is a quaternary mixture of the invention comprising atornamine as compound III. Preferred is a ternary mixture of the invention comprising degalazine as compound III. Preferred is a quaternary mixture of the invention comprising degalazine as compound III. Preferably, it contains ruthenium-(3·,4·,5'-trifluorobiphenyl-2-yl)-3-difluorodecyl-1-methyl-1Η-pyrazole-4-carboxamide as a compound III. The ternary mixture of the invention. Preferably, it contains Ν-(3',4',5'-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl- 138195.doc -11 · 200939963 1H-pyrazole- 4-Mergamine as a quaternary mixture of the invention in the invention. Preferably, N-[2-(l,3-dimethylbutyl)phenyl]-13 dimethyl-5-fluoro-1H-pyrazole-4-carboxamide is used as the compound ΙΠ2 ternary mixture of the invention . Preferably, the invention is a quaternary of the invention containing Ν-(3,4,5-difluorobiphenyl-2-yl)-3-difluoroindenyl "methyl-1-pyridyl-4-carbamide" as compound m Preferably, the mixture contains Ν·[2-(1,3-dimethylbutyl)phenyl]-1,3-didecyl-5-fluoro-1Η-pyrazole-4-carboxamide as the compound 1 Inventive ternary mixture. Preferably, it contains Ν-(2-biscyclopropyl-phenyl)_3-difluoromethyl-fluorenyl-hydrazinyl- 1 -pyrazole·4-decylamine (Sida) The quaternary mixture of the present invention m is preferably a ternary mixture of the present invention containing cuminamide as the compound III. It is preferably a quaternary mixture of the present invention containing pirfenium as a compound hydrazine. The weight ratio of the agonist/antagonist compound I, the fungicidal compound π and one of the other fungicides III is 1:1:100:100 to 100:1:1, preferably (10): :(10), more preferably 1:2〇: 2〇 to 20:1:1 〇 contains the final receptor agonist/antagonist compound, the fungicide compound Η and the two other fungicides III The weight ratio of the mixture is 1:1 〇〇: 1〇 :1〇〇 to 1〇〇: 1:1:1, preferably 50:1:1:1 to 1:5〇:5〇:5〇, better 1:20:20:20 to 20:1: 1:1. The weight ratio of the binary mixture comprising arbutin and cyclosporin as the active component is from 1:100 to 100:1 'preferably 50:1 to 1:5 〇, more preferably 1:2 〇 to 2. For its intended use, the compound j listed in the table below (where compound j 138195.doc -12- 200939963 is nicidine, idamine or cyanohydrin), compound π (which is cyclosporin) ), one or two compounds ΙΙΙ (wherein compound III is selected from the group consisting of prothioconazole, poker, chlordane, baikemin, epothilone, trifluoro-sensitive, sulfhydryl, azotomin, compound The following ternary and quaternary mixtures of la, Id, Ie or Ig) are preferred. In addition to the abbreviations of Table 1, the following abbreviations are also used herein: I is a compound I II is a compound II 〇 111 (1) = 1 Compound III 111(2)=The second compound III TMX is Sai'an I. Yidamine C is the nicotine PC=Protease 嗤ττζ=Cyclosporin Ρζ=Poker Μ 灭 = 灭 乐 Ρ = 克 克 敏_ 0=Epoxylamine τ=Trifluoro-sensitive ΤΡΜ=Methylpoly-safe Α=Atomin

Ia=N-(3',4',5'-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-indolyl-1H-pyrazole-4-carboxamide, Id=N -[2-(l,3-dimercaptobutyl)-phenyl]-1,3-didecyl-5-fluoro-1H-pyrazole-4-carboxamide, Ie=N-(2- Bicyclopropyl-2-yl-phenyl)-3-difluorodecyl-1-methyl-1H-"biazole-4-carboxamide (Cedarian),

Ig=0 than the sales of the mesamine Table No. I II III (1) 111 (2) R-1 C TTZ Pz R-2 C TTZ Pz M R-3 C TTZ Pz P R-4 C TTZ Pz 0 R-5 C TTZ Pz T R-6 C TTZ Pz A R-7 C TTZ Pz la R-8 C TTZ Pz Id R-9 C TTZ Pz Ie 138195.doc -13- 200939963 No. I II III(1) 111(2) R-10 C TTZ Pz Ig R-ll C TTZ Pz TPM R-12 C TTZ M R-13 C TTZ MP R-14 C TTZ M o R-15 C TTZ MT R-16 C TTZ MA R-17 C TTZ M la R-18 C TTZ M Id R-19 C TTZ M Ie R-20 C TTZ M Ig R-21 C TTZ M TPM R-22 C TTZ P R-23 C TTZ P 0 R-24 C TTZ PT R-25 C TTZ PA R -26 C TTZ P la R-27 C TTZ P Id R-28 C TTZ P Ie R-29 C TTZ P Ig R-30 C TTZ P TPM R-31 C TTZ o R-32 C TTZ o T R-33 C TTZ 0 A R-34 c TTZ o la R-35 c TTZ o Id R-36 c TTZ o Ie R-37 c TTZ o Ig R-38 c TTZ Pz TPM R-39 c TTZ T R-40 c TTZ TA R-41 c TTZ T la R-42 c TTZ T Id R-43 c TTZ T Ie R-44 c TTZ T ig R-45 c TTZ T TPM R-46 c TTZ A - R-47 c TTZ A Ia R-48 c TTZ A Id R-49 c TTZ A Ie R-50 c TTZ A Is_ 138195.doc -14- 200939963 No. I II III(l) 111(2) R-51 C TTZ AT PM R-52 C TTZ A TPM R-53 C TTZ la - R-54 C TTZ la Id R-55 C TTZ la Ie R-56 C TTZ la ig R-57 C TTZ la TPM R-58 C TTZ Id R -59 C TTZ Id Ie R-60 C TTZ Id ig R-61 C TTZ Ie ig R-62 C TTZ Ie TPM R-63 C TTZ Ig - R-64 C TTZ Ig TPM R-65 C TTZ TPM - R- 66 ΊΜΧ TTZ Pz R-67 TMX TTZ Pz M R-68 TMX TTZ Pz P R-69 TMX TTZ Pz 0 R-70 TMX TTZ Pz T R-71 TMX TTZ Pz A R-72 TMX TTZ Pz la R-73 TMX TTZ Pz Id R-74 TMX TTZ Pz Ie R-75 TMX TTZ Pz ig R-76 TMX TTZ Pz TPM R-77 TMX TTZ M R-78 TMX TTZ MP R-79 TMX TTZ M 0 R-80 TMX TTZ MT R -81 TMX TTZ MA R-82 TMX TTZ M la R-83 TMX TTZ M Id R-84 TMX TTZ M Ie R-85 TMX TTZ M Ig R-86 TMX TTZ M TPM R-87 TMX TTZ P R-88 TMX TTZ P 〇R-89 TMX TTZ PT R-90 TMX TTZ PA R-91 TMX TTZ P la 138195.doc 15 200939963

No. I II III(1) 111(2) R-92 TMX TTZ P Id R-93 TMX TTZ P Ie R-94 TMX TTZ P Ig R-95 TMX TTZ P TPM R-96 TMX TTZ o R-97 TMX TTZ o T R -98 TMX TTZ 0 A R-99 TMX TTZ 0 la R-100 TMX TTZ 0 Id R-101 TMX TTZ o Ie R-102 TMX TTZ o is R-103 TMX TTZ Pz TPM R-104 TMX TTZ T - R- 105 TMX TTZ TA R-106 TMX TTZ T la R-107 TMX TTZ T Id R-108 TMX TTZ T Ie R-109 TMX TTZ T Ig R-110 TMX TTZ T TPM R-lll TMX TTZ A - R-112 TMX TTZ A Ia R-113 TMX TTZ A Id R-114 TMX TTZ A Ie R-115 TMX TTZ A is R-116 TMX TTZ A TPM R-117 TMX TTZ A TPM R-118 TMX TTZ la R-119 TMX TTZ la Id R-120 TMX TTZ la Ie R-121 TMX TTZ la Ig R-122 TMX TTZ la TPM R-123 TMX TTZ Id R-124 TMX TTZ Id Ie R-125 TMX TTZ Id Ig R-126 TMX TTZ Ie Ig R -127 TMX TTZ Ie TPM R-128 TMX TTZ Ig - R-129 TMX TTZ Ig TPM R-130 TMX TTZ TPM R-131 I TTZ Pz R-132 I TTZ Pz M 138195.doc -16- 200939963 No. I II III(1) 111(2) R-133 II TTZ Pz P R-134 I TTZ Pz 0 R-135 I TTZ Pz T R-136 I TTZ Pz A R-137 I TTZ Pz la R-138 I TTZ P z Id R-139 I TTZ Pz Ie R-140 I TTZ Pz Ig R-141 I TTZ Pz TPM R-142 I TTZ M - R-143 I TTZ MP R-144 I TTZ M o R-145 I TTZ MT R -146 I TTZ MA R-147 I TTZ M la R-148 I TTZ M Id R-149 I TTZ M Ie R-150 I TTZ M Ig R-151 I TTZ M TPM R-152 I TTZ P R-153 I TTZ P 〇R-154 I TTZ PT R-155 I TTZ PA R-156 I TTZ P la R-157 I TTZ P Id R-158 I TTZ P Ie R-159 I TTZ P Ig R-160 I TTZ P TPM R-161 I TTZ 0 - R-162 I TTZ 0 T R-163 I TTZ 0 A R-164 I TTZ 0 la R-165 I TTZ 0 Id R-166 I TTZ o Ie R-167 I TTZ o Ig R -168 I TTZ Pz TPM R-169 I TTZ T - R-170 I TTZ TA R-171 I TTZ T la R-172 I TTZ T Id R-173 I TTZ T Ie 138195.doc 17 200939963 No. I II III(1) 111 (2) R-174 I TTZ T Ig R-175 I TTZ T TPM R-176 I TTZ A R-177 I TTZ A la R-178 I TTZ A Id R-179 I TTZ A Ie R-180 I TTZ A Ig R-181 I TTZ A TPM R-182 I TTZ A TPM R-183 I TTZ la R-184 I TTZ la Id R-185 I TTZ la Ie R-186 I TTZ la Ig R-187 I TTZ la TPM R -188 I TTZ Id - R-189 I TTZ Id Ie R-190 I TTZ Id Ig R-191 I TTZ Ie Ig R-192 I TTZ Ie TPM R-193 I TTZ Ig _ R-194 I TTZ Ig TPM R-195 I TTZ TPM - Among these mixtures, the following mixtures are especially preferred: R-1, R- 3. R-13, R-12, R-22, R-26, R-27, R-28, R-29, R-30, R-65, R-66, R-68, R-78, R-77, R-87, R-91, R-92, R-93, R-94, R-95, R-130, R-131, R-133, R-143, R-142, R- 152, R-156, R-157, R-158, R-159, R-160 and R-195. Within this subset, the following mixtures are preferred: 11-1, 11-3, 11-13, 11-12, R-22, R_26, R_27, R-28, R-29, R-30, R-65 , R-66, R-68, R-78, R-77, R-87, R-91, R-92, R-93, R-94, R-95, R-130, R-131, R -133, R-143, R-142, R-152, R-156, R-157, R-158, R-159, R-160 and R-195. 138195.doc -18- 200939963 The inventive mixture may additionally contain one or more insecticides, fungicides, herbicides. For use in accordance with the present invention, the mixtures according to the present invention can be converted into conventional formulations such as solutions, emulsions, suspensions, powders, powders, pastes and granules. The use form depends on the particular intended purpose; in each case it should ensure a fine and uniform distribution of the mixture according to the invention. Formulations are prepared in a known manner (see US 3,060,084, EP-A 707 445 (Liquid Concentrate), Browning: "Agglomeration", Chemical © Engineering, December 4, 1967, 147-48, Perry's Chemical

Engineer's Handbook, 4th edition, McGraw-Hill, New York, 1963, S. 8-57 and subsequent content, WO 91/13546, US 4,172,714, US 4,144,050, US 3,920,442 ' US 5,180,587 > US 5,232,701 'US 5,208,030 ' GB 2,095,558 'US 3,299,566 · Klingman : Weed Control as a Science (J. Wiley & Sons > New York, 1961), Hance et al.: Weed Control Handbook (8th ed., Blackwell Scientific, Oxford, 1989) and Mollet, See H. and Grubemann, A. : Formulation technology (Wiley VCH Verlag > Weinheim » 2001)) ° • Agrochemical formulations can also be included in agrochemical formulations. The auxiliaries used depend on the particular application form and the active substance. Examples of suitable auxiliaries are solvents, solid carriers, dispersants or emulsifiers (such as other solubilizers, protective colloids, surfactants and adhesives), organic and inorganic thickeners, bactericides, antifreeze agents, defoamers , where appropriate, a colorant and a tackifier or binder (eg, for seed treatment formulations). 138195.doc -19· 200939963 The suitable solvent is water, organic solvent, , m ^ 1 such as mineral oil with a medium to high boiling point, such as kerosene or diesel, in addition to coal tar and plants or animals / original Oil; aliphatic, cyclic, and tricyclic, such as toluene, xylene, snail*, tetrahydronaphthalene, alkylated naphthalene or ruthenium, any organism, alcohol, such as methanol, ethanol, propanol, Butanol and cyclohexanol. Sterols, ketones, such as cyclohexanone and γ-butane vinegar; fatty acid dimethyl broth, „amine fatty acid and fatty acid esters and strong polar solvents, such as amines, such as hydrazine -Methylpyrrolidone. Solid carrier is mineral soil, “" 贞 such as phthalate, tannin, talc, kaolin limestone, lime, white ridge, red basalt, loess, clay, dolomite, diatomaceous earth, sulfuric acid Calcium, Magnesium Sulfate, Magnesium Oxide, Ground Synthetic Materials: Fertilizers, such as sulphuric acid, disc acid, nitric acid, glandular and plant-derived products such as cereal flour, bark powder, wood chips and nut shell powder, cellulose powder and other solids Carrier. Suitable surfactants (adjuvants, wetting agents, tackifiers, dispersants or emulsifiers) are aromatic sulfonic acids (such as lignin sulfonic acid (B〇rresperse type 8, Borregard, Norway), phenolic acid, naphthalene sulfonic acid ...❶^^8 type, Akz〇

Nobel ’ U.S.A.), dibutyl naphthalene acid (Nekal® type, BASF,

Germany)) and alkali metal, alkaline earth metal and ammonium salts of fatty acids; alkyl sulfonates, alkyl aryl sulfonates, alkyl sulfates, lauryl ether sulfates, fatty alcohol sulfates and sulfated cetyl alcohol Ester, heptadecyl ester and stearyl alcohol ester, sulfated fatty alcohol glycol ether 'in addition to condensate of naphthalene or naphthalenesulfonic acid with phenol and furfural, polyoxyethylene octylphenyl ether, ethoxylated Octyl benzene, octyl benzene, decyl benzene, pyryl phenyl polyethylene glycol, tributyl phenyl polyglycol ether, tristearyl phenyl polyglycol ether, alkyl Aryl polyether alcohol, alcohol 138195.doc -20· 200939963 and fatty alcohol/ethylene oxide condensate, ethoxylated gas oil, polyoxyethylene alkyl ether, ethoxylated polypropylene oxide, lauryl polyethylene Alcohol ether acetal, sorbitol ester, lignin sulfite waste liquid and protein, denatured protein, polysaccharide (such as methyl cellulose), hydrophobic modified starch, polyvinyl alcohol (Mowiol® type, Clariant, Switzerland) , poly-acid vinegar (Sokolan® type, BASF, Germany), poly- oxy-oxyl compound, polyethylene amine (Lupasol® type, B ASF, Germany), polyethylene 0 to B each biting ketone and its copolymer 8 稠 thickener (that is, to impart a modified fluidity to the formulation, ie high viscosity under static conditions and during stirring) Examples of low viscosity compounds are poly-audio and organic and inorganic clays such as Xanthan gum (Kelzan®, CP Kelco, USA), Rhodopol® 23 (Rhodia, France), Veegum® (RT Vanderbilt, USA). ) or Attaclay® (Engelhard Corp,, NJ, USA) o For the preservation and stabilization of the formulation, a biocide can be added. Examples of suitable fungicides are based on the following: di-p-phenol and benzyl alcohol hemi-restriction aldehyde

A (Proxel® from ICI or Acticide® RS from Thor Chemie and Kathon® MK from Rohm & Haas) and 嗔 嗔 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 衍生物 衍生物 衍生物 衍生物 衍生物 衍生物 衍生物 衍生物 衍生物 衍生物Different 嗔 坐 吓 ( (from Thor Chemie

Acticide® MBS) 实例 Examples of suitable anti-moisture agents are ethylene glycol, propylene glycol, gland and glycerol. Examples of antifoaming agents are polyoxin emulsions (such as Silikon® SRE, Wacker, Germany or Rhodorsil®, Rhodia, France), long-chain alcohols, fatty hydrazines, fatty acid salts, fluoroorganic compounds, and mixtures thereof. 138195.doc • 21 200939963 Suitable colorants are low water soluble pigments and water soluble dyes. Examples to be mentioned are the name rhodamin B, CI Pigment Red 112, CI Solvent Red 1, Pigment Blue 15:4, Pigment Blue 15:3, Pigment Blue 15:2, Pigment Blue 15.1, Pigment Blue 80, pigment yellow! , Pigment Yellow 13, Pigment Red 112, Pigment Red 48:2, Pigment Red 48:1, Pigment Red 57:1, Pigment Red 53:1, Pigment Orange 43, Pigment Orange 34, Pigment Orange 5, Pigment Green%, Pigment Green 7, Pigment White 6, Pigment 榇25, Alkaline Purpura, Alkaline Violet 49, Acid Red 5丨, Acid Red 52, Acid Red 14, Acid Blue 9, Acid Yellow 23, Alkaline Red 〇, Alkali Sexual red 108. Examples of tackifiers or binders are polyethylene glycol β-butanone, polyethylene acetate, polyvinyl alcohol and cellulose ether (Tyl〇se8, which is used to print, to swollen.. Powder, spreading materials And the powder may be prepared by mixing or simultaneously grinding the compound I and / or II and, where appropriate, other actives f with at least one solid carrier. The granules may be prepared by combining the active materials with a solid carrier, For example, coated granules, impregnated granules and granules. Examples of solid carriers are mineral soils such as tannins, vinegar, talc, kaolin, American activated clay, limestone, lime, white #, red basalt, Loess, clay, dolomite, Shixiazao soil, sulfur_, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers such as ammonium sulfate, acid, cotton, gland, and plant-derived products, such as glutinous rice, Bark powder, wood 4 and nut shell powder, cellulose powder and other solid carriers. Examples of formulation types are: 1. Composition type for dilution with water 138195.doc -22- 200939963 i) Water soluble concentrate (§ L, l S) will be 1 〇 heavy Parts of the compound of the present invention is dissolved in a mixture of 90 parts by weight of water or a water-soluble solvent. Instead, a wetting agent or other auxiliaries are added. After dilution with water, the active substance is dissolved. In this way, a formulation having an active substance content of 10% by weight is obtained. Ii) Dispersible Concentrate (DC) A compound of 20 parts by weight of the inventive mixture is dissolved in parts by weight of cyclohexanone while adding 1 part by weight of a dispersing agent such as polyvinylpyrrolidine. The dispersion was diluted with water to obtain a dispersion. The active substance content is 20% by weight ^ (1)) Emulsifiable concentrate (EC) 15 parts by weight of the compound of the present invention is dissolved in "parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and hydrazine" Sesame oil ethoxylate (in each case 5 parts by weight) diluted with water to give an emulsion. The composition has an active substance content of 15% by weight. iv) Emulsion (EW, hydrazine, ES) 25 parts by weight of the inventive mixture The compound was dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and mannose oil ethoxylate (in each case 5 parts by weight). This mixture was introduced by means of an emulsifier (Uhraturrax). To 30 parts by weight of water and made into a homogeneous emulsion. The emulsion is known by dilution with water. The composition has an active substance content of 25% by weight. v) Suspension (SC, OD, FS) 20 parts by weight in a stirred ball mill The compound of the mixture of the present invention is pulverized by adding 1 part by weight of a dispersing agent and a wetting agent and 7 parts by weight of water or an organic solvent to obtain a fine active substance suspension, which is diluted with water to obtain 138195.doc -23- 20 0939963 Stable suspension of active substance. The active substance content of the composition is 2% by weight. V1) Water-dispersible granules and water-soluble granules (W (J, SG) Weight-damaged compound of the mixture of the invention finely ground At the same time, adding 5 〇 weight of dispersant and wetting agent and preparing by means of technical electrical equipment (such as extrusion, spray tower, fluidized bed) as water-dispersible or water-soluble granules, diluted with water to obtain activity The stable dispersion or solution of the substance has a composition content of 50% by weight. vii) water dispersible powder and water-soluble powder (wp, sp, ss, ws) grind 75 weight in the rotor 4 sub-grinder The compound of the mixture of the invention is simultaneously added with 25 parts by weight of a dispersing agent and a wetting agent, and is diluted with water to obtain a stable dispersion or solution of the active substance. The composition substance content is 75% by weight. Glue (GF) 2G parts by weight of the compound of the present invention is pulverized in a ball mill while adding 10 parts by weight of a dispersing agent, 1 s heavy sclerosing gelling agent humectant and 70 parts of water or organic solvent To obtain an active hoarding fine suspension. Dilute with water to obtain a stable suspension of the active substance, thereby obtaining a composition having a right 20% (w/w) active substance. 2. There is a combination of application in undiluted form. Type ix) dusting powder (DP, DS) 5 parts by weight of the compound of the present invention is finely mixed, and the fine powdered kaolin of the gamma Qg parts is intimately mixed. This gives a live weight of 5% by weight. Dusting composition. Material content is 5 138195.doc • 24-200939963 x) Granules (gr, fg, gg, mg) The weight of the mixture of the compounds of the invention is finely ground and associated with the carrier of 99.5 = amount of injury Hehe. The current method is squeezing, spray drying or fluidization. This gives granules in an undiluted form with an active substance content of 5% by weight. Xi) ULV solution (ul)

Parts by weight of the compound of the present invention are dissolved in 9 parts by weight of an organic solvent (e.g., dinon benzene). This gave a composition in an undiluted form with an active substance content of 10% by weight. Agrochemical formulations are generally included between 1% by weight and % by weight of 〇. 较佳, preferably between (U% by weight and 90% by weight, most preferably 〇5 by weight. Read 9 〇 by weight. The active substance is a compound of the mixture of the invention in a purity of from 9% to 1% by weight, preferably to Wei (according to the spectrum of the spectrum). The compound of the mixture of the invention can be sprayed, atomized, dusted, exhibited Dust, brush, impregnate or pour to use as it is or in the form of its composition 'for example, in direct sprayable solutions, powders, suspensions, dispersions, emulsions, oil dispersions, pastes, dusting The product, the spread material or the granules are used in the form of the application. The application form depends entirely on the intended purpose; it is desirable in each case to ensure the finest possible distribution of the compounds present in the mixture of the invention. The aqueous application form can be added by adding water Prepared from emulsion concentrates, pastes or wettable powders (sprayable powders, oil dispersions). For the preparation of emulsions, pastes or oil dispersions, by means of septics, tackifiers, dispersants or emulsifiers The agent will be as it is or dissolved The substance in the oil or solvent is homogenized in water. Alternatively, 138195.doc •25· 200939963 may be prepared by concentration of active substances, wetting agents, tackifiers, dispersants or emulsifiers and, where appropriate, solvents or oils. And the concentrates are suitable for dilution with water. The concentration of the active substance used in (iv) can vary over a relatively wide range. Typically, p is from 0.0001% to 10% by weight of the compound of the mixture of the invention. Preferably, 0 001% to 1%. The compound of the mixture of the present invention can also be successfully used in an ultra-low volume process (ULV), which may be applied to contain more than 95% by weight of active #质之Composition m can be applied to the active substance without additives. Various types of oils, wetting agents, adjuvants, herbicides, fungicides, other insecticides or fungicides can be added to the active compound, as appropriate until use. Immediately before the addition (tank mixing). The compound of the present invention may be mixed with the compound of the present invention at a weight ratio of 1:100 to i00: i, preferably i: i 〇 to 丨〇: 0. May contain such as nitrate Fertilizers, phytotoxins, and plant growth regulators and safeners for glandular, carbonated, and phytate. They may be used in combination with the above-mentioned compositions in sequence or in combination, and may be added only immediately before use (tank mixing). The plant may be sprayed with the composition of the invention before or after treatment with the fertilizer. The compounds contained in the mixture as defined above may be applied simultaneously (i.e., jointly or independently) or continuously, in the case of separate application. The sequence generally has no effect on the results of the control measures. It will be understood in accordance with the present invention that Compounds I and II and Compound 111 (or compounds as defined in 138195.doc -26-200939963 above) represent at least a compound coffee and a compound m ( Or a compound as defined above) is present at the same site in an effective amount (ie, a pest such as a harmful fungus to be controlled and an animal pest such as an insect, a spider or a scorpion < its habitat, such as an infested plant, Plant propagation material (especially seeds), surface, material or soil and plants, plant propagation material to be protected from fungal attack ( Seed), soil, surface, material or space). This can be done simultaneously (in combination (for example in the form of a tank mix) or independently) or continuously with compounds 1 and 11 and compounds or compounds as defined above! And II), wherein the time interval between individual administrations is selected to ensure that the active substance applied first is still present in the active site at the time of administration of the other active substance. The order of application is not critical to the work of the present invention. In the binary, ternary and quaternary mixtures of the invention, the weight ratio of the compound will generally depend on the identity of the compound of the mixture of the invention. φ The compounds of the inventive mixtures may be used individually or may be partially or completely mixed with each other to prepare a composition according to the invention. It may also be further packaged and used in the form of a combination composition, such as a partial kit. In one embodiment of the invention, the kit may include one or more (including all) components that can be used to prepare the subject agrochemical composition. For example, a kit may comprise compounds I and II and a compound hydrazine (or a compound and hydrazine as defined above) and/or an adjuvant component and/or another insecticidal compound (such as an insecticide or herbicide) and / or growth regulator components. One or more of the components may have been combined or pre-provisioned. In providing the two or more components to the kit order, they are in the 138195.doc • 27- 200939963 embodiment. The components may have been combined and packaged as such in vials, bottles, cans, sachets, bags or small. In a single container of cans. In other embodiments, two or more components of the kit may be individually packaged, i.e., not pre-provisioned. Thus, the kit can include one or more separate containers, such as vials, cans, bottles, sachets, bags or cans, each containing a separate component of the agrochemical composition. The components of the kit may be administered in two forms separately or together with the other components or in the form of a component of the combination composition according to the invention for use in the preparation of a composition according to the invention. The user typically applies the composition according to the invention from a pred dose device, a backpack spray, a spray tank or a sprayer. The agrochemical composition herein consists of water and/or a buffer to the desired application concentration, possibly with the addition of further auxiliaries, and thus a ready-to-use spray liquid or agrochemical composition according to the invention. The effective area of agriculture per hectare is usually applied from 50 liters to 50 liters, preferably 1 liter to 4 liters of ready-to-use spray liquid. An individual compound of a mixture of the invention formulated as a composition (or formulation) according to the examples 'such as a portion of a kit or a portion of a binary or ternary or quaternary mixed composition, which may be used by the user himself in a spray tank Mix in, and add other additives (tank mix) as appropriate. In a further embodiment, the component of the individual compound or part of the premixed component of the inventive mixture formulated as a composition, for example comprising a compound and a compound or a compound as defined above, can be tolerated by the user in the spray tank. Other additives and additives (tank mixing) may be added as appropriate. In another embodiment, the individual components or parts of the composition according to the invention are 138195.doc -28-200939963 divided premixed components, for example comprising a compound and π and a compound hydrazine (or compounds I and II as defined above) The components can be combined (for example after tank mixing) or continuously. As indicated above, the invention comprises a method of controlling pests (meaning animal pests and harmful fungi), wherein the pest, its habitat, the breeding ground, its location or the plant to be protected from pests are treated with a pesticidally effective amount of a mixture. , soil or plant propagation material (preferably seed). Advantageously, the mixture of the invention is suitable for controlling the following fungal plant diseases: ornamental plants, vegetables (eg Candida albicans white rust (Pupae sylvestris) and hollyhocks (eg Brah's ginseng white rust (i (10) (4)) White rust fungus SPP.K white rust); vegetables, rapeseed (C. oxysporum (L. or Brassica genus) (bean ""%") Bacteria (Suihua (10) (4)), fruits, rice, soybeans, potatoes (eg, Alternaria solani (L. oxysporum) or Phytophthora erythraea (L. cerevisiae), tomato (eg, S. cerevisiae or black) Phytophthora ssp.) and wheat sPP.) (Spirulina leaf spot); snails on sugar beets and vegetables (but (10) spp.); shells and vegetables Is a spp.) 'For example, wheat husks on wheat (children (7) (charcoal) and barley on barley (I 6 with heart palpitations; corn (such as umbilical cord blood snails (D. /«)叩山··〇), 榖 (such as wheat root rot, Helminthosporium (and (10) Wm·(10)a): spot disease), rice (such as Helicobacter pylori (7) and snail on turf Genus (5φο/α...spp) and Helminthosporium spp.) (teleomorph: genus genus (10) spp.)); genus (eg wheat or barley) of 138195. Doc -29- 200939963 Cobs powdery mildew (gM/wiwb five/wwer/a) (formerly known as white powdery mildew (jErysz'p/je 5Τ<3/7ΐζ·«ί·5)) (powder disease); Fruits and berries (eg grass), vegetables (eg lettuce, carrots, celery and cabbage)' Rape, flowers, vines, forest plants and Botrytis cinerea on wheat (Β〇ί〇Ή·5 cz'« Erea) (sex type: Bofryotinia / wcA: e/ia «a): gray mold; lettuce on lettuce / aciwcae) (downy mildew); broadleaf tree And the long clam shell on the evergreen tree (synonymous long-shelled fungus (Wc^ioma)) genus (rot or wilt), such as the long clam shell on the eucalyptus tree (C. w/w〇 (Dutch eucalyptus) Disease); corn, rice, sugar beet (such as C. 6eiico/a), licorice, vegetables, coffee, soybeans (such as soybean gray spot pathogen (C. 5·〇_/ζ_ηα) or Kikuchi Sclerotium (C. A: ^wc/n_z·)) And rice sphaeroides spp.) (soy leaf spot); tomato (such as tomato leaf mold (C. / w / vmw): leaf emblem) and the genus of the genus of the genus (C / ac / c ^ Por/wm spp.), for example, C. / zer6arwm (black ear) on wheat; ryegrass on clam (C/aWcep·? /jwr/jwrea) (erk horn); corn (C. car6o «wm), mites (such as Helminthosporium (C. · 5αί! · νΜί), deformation (anamorph): wheat root rot flat snail Spores and rice (eg C. wz; ya6ea «ws), deformation: larvae of rice root-knot nematode (//. or_yzi^) (deformation: umbilical cord Helminthosporum of 5φ〇/αΗ5·)) genus (leaf spot); cotton (such as cotton thorns (C., corn (such as Phyllostachys praecox (C·, soft fruit, potato (such as ball thorns) C. coccodes·): dark spots), beans (eg Bean Stings (C. ./z_«£/emwi/n'a«ww)) 138195.doc -30- 200939963 and soybeans (eg (C. or acne spores (C. on the spurs (Co//eioirz_c/2wm) (sexual type: anthracnose (G/c> mere/) /a)) genus (anthrax). Phytophthora (CoWc/wm spp.), such as Rhizoctonia solani (C. (Fusarium oxysporum f.); multi-sporobacteria on soybeans and ornamental plants (Corywej^ora 〇ίζ·5ίζ) · ζ·οο/<3) (leaf spot); Cyclospora spp.), for example, the olive peacock plaque on the tree (C.; fruit trees, vines (such as A. serrata (C) . Sexual type: New Phytophthora (Neonectria: Black Foot)

Disease)) and the genus Cymbidium on ornamental plants (eg if the tree rots or the ivy declines, there is a sexual type: iVecir/fl! spp. or iVeoweciWfl spp.) Soybean on soybean (Z)emai£?/?/iora wec;<2ir0:) (sexual type: Phytophthora (7?σ5^//ζ·«ί·α)) And stem rot); Dkpori/ze spp., such as soybean black spot disease on soybean (D. /7/zaseo/orww) (damping off); corn, cereal (such as Barley (eg, wood wheat net spot, pathogen (£)· iere*s·), net blotch) and wheat (eg, wheat worm (Ζλ ir/iicz'-repeniz··?): brown spot)), In the rice and turf, the genus Helminthosporium (synonymous Helminthosporium, genus: genus genus (i^rewop/iora)); the vine (Esca) (top blight, stroke), It is made up of the genus Pseudomonas aeruginosa (·Ρ〇Γ»ίζ·ίζ·;7〇Γζ·β pwwciflia) (synonym: Pseudomonas sinensis, M. terracotta, 厚·mediterranea) Phaeomonie Ua chlamydospora { ^ Μ Μ ^ M {Phaeoacremonium c Hlamydosporum)), parasitic bottle #菌{Phaeoacremonium 138195.doc -31- 200939963 a/eop/n'/MW) and / or caused by the genus of the genus of the genus of the genus Pythium (P. sinensis). Pyrz_)), soft fruit (Raspberry bacillus (V. veweia): anthracnose) and vine (black cancer, sputum sputum (£. : anthracnose) on the genus Cysticercus CC/Wwoe Spp.); Phytophthora infestans CE«〇^/t>wa (leaf smut); black bacterium of the genus Helicococcus on the wheat (five picoccww spp.) (black mold); beet (beet powdery mildew) £. 6eiae)), vegetables (such as cowpea powdery mildew (5./?ζ··5ϊ·)), such as cucurbitaceae (such as 抱·白cz cz_c/i〇racearwm), cabbage, rapeseed (eg Erfip/ie 〇spp.) on powdery mildew (f. crwczyerarwm); powdery mildew/αία on fruit trees, vines and ornamental trees (grape rot) (Eutypa canker) or top blight, deformation: Lata false sac /αία), synonym of Libertella blepharis), corn Jl's umbilical cage (Exserohilum) (synonymous snail ) genus (such as Helminthosporium fulvum (V. iwrcz_cww)); Phytophthora on various plants (FwiariwmK serotype: Gibberella (G76 heart π / / α 〇) genus (wild wilt, root or stem) Rot), such as Fusarium oxysporum (F. gra/w/wearw/w) or Fusarium oxysporum (F. cw/wc?rww) on cereals (eg small d wheat or barley) (root rot, scab or Head withered), Fusarium oxysporum on F. (F., Fusarium sinensis on soybean (F. ·5·ο/β«ζ·) and · Fusarium oxysporum on corn (F. vernW/hWi/ e·?); cereals (such as wheat or barley) and corn sclerotium (Gaewwa ««om ce«s grawim'j) (take-all); mites (such as cereals) Gibberella (G. zeae) and rice (for example, the genus Gibberella (G /if//free wrc?z·): Bakanae disease) (GAZ>ere// a spp·); vines, pomegranates and others 138195.doc -32- 200939963 Phytophthora capsici (G/omere//a and cotton anthracnose on cotton (Gl; rice on rice) Grainstaining complex, Staphylococcus aureus on vine (Gwz·(9) (black Disease), Phyllostachys pubescens and the genus of the genus Bacillus spp.) 'For example, Sabina rust fungus on the pear (G. (rust); corn, cereal and long worms on rice (synonym inside the umbilical cord) Helminthosporium, sexual type: Helminthosporium); rust genus 'for example, coffee bacillus rust (7/. ναίίαίΓή:) (coffee leaf rust); vine grape leaf spot on vine (/ •saWopjb c/aWwora) (synonym Wisdom of the genus Wii·?)), soybean and cotton on the bean sclerotium p/mseo/iwa) (synonym bean globulin (ρ/;αίβο/ζ·«)) (root and stem rot); Fusarium oxysporum on M. (such as wheat or barley) (M/croc^c/n· m'va/e) (synonym: Fusarium oxysporum «ίνβ/e) (pink snow mold); powdery mildew on soybean (Microjp/mena £/〇7«*5〇〇 (powder disease); brown rot (Mom7im_〇f spp.), for example, stone fruit And other Rosaceae plants on the fruit brown rot fungi (M / aJca), fruit plexus spores (M. / rwci / co / a) and pomelo brown rot fungi (M / rwc? i with e « a) ( Flowers and twigs withered, brown rot); cereals, bananas, soft fruits and fallen flowers Mycosp/mere//a spp. 'M. gram/m'co/a on wheat (Deformation: Sepiorza ir"/c; Z_), Phytophthora or Phytophthora on the banana (Μ· /(/&«?&) (black banana leaf spot); cabbage (eg P. Zjrawiccze) , rapeseed (eg P. paraWi/ca), onions (eg, artichoke downy mildew (C. esirwcior)), tobacco (tobacco downy mildew (household Μ6α£?ζ·«ύ〇) and Soybean (eg 138195.doc -33- 200939963 P. waw AwWca) on the genus Downy Mildew (Per〇„〇iP〇ra (Grape Downy Mildew); Soybean Rust on Soybean (aA:o) ;?i〇ra pac/z less r/ζίζϊ·) and Phytophthora serrata (·Ρ. we/6o/wz'ae) (soybean rust); for example in vines (eg lemon dry blight (P. and Bacillus thuringiensis (·Ρ. ieiraipora)) and soybean (eg, brown rot of the bean stem (/*·regaia): stem rot) on the genus Capreolus (Horda /α/op/iora spp.); And cabbage black rot fungus on cabbage (household / / «gam) (root and stem rot) Beet polymyx on beet (P. heart root rot, leaf spot and moist rot); hollyhock, vine (eg P. WikoM: stalk and leaf spot) and soybean (eg stem rot) : Phytophthora sojae (household. corpse / ^ πο / Ο, sexual type: soybean black spot disease / ^aieo / orwm)) on the genus Pseudomonas (P / jomo /? ·? / ·? spp.) ; brown spot disease of corn brown spot on corn; various plants, such as red pepper and eucalyptus (such as Phytophthora capsici (/*. ca/mW)), soybean (such as Phytophthora mausoleum (corpse wegasperma) , synonymous with Phytophthora sojae (soy'ae), potato and suzanne (eg Phytophthora infestans (·Ρ· ϊ·«/αία«·5): late blight) and broad-leaved trees (eg Phytophthora capsici (household) RaworMW): Phytophthora (P/jyiop/zi/ioro! spp.) on the oak (dead oak) (wild, root, leaf, fruit and stem rot); cross on cabbage, canola, radish and other plants Flowering plant Rhizobium pathogen {Plasmodiophora 6ra5sz'cae) (root nodule disease); Helicobacter (Aimopara spp.), such as Phytophthora capsici (P. Wiico/) ) (vinevine grape downy mildew) and sunflower dew on sunflower (/3. /mhie mountain 7); Rosaceae, hops, pear fruit and soft fruit on the fork of the genus Such as *57? heart to <3 spp.) (powder disease), such as 138195.doc -34- 200939963 apple powdery mildew (P. / ewcoir / c / m); such as cereals (such as barley and wheat) (Polycide sclerotium (P. and beet (Beet polymyxa (6eiae))) on the genus Spp () and viral diseases transmitted by it; mites (such as wheat or barley) Wheat-based rot pathogen/zerpoiWc/zoii/es) (eye point, sexual type: blast fungus (Γαραία; pseudo-downy mildew on various plants (ΡΜΜί^; 7πσ«0ι^0Μ) (grape downy mildew), For example, the genus Pseudomonas cepacia (P. cwZjmWj) on the cucurbitaceae plant or the genus Pseudomonas sinensis on the hops (/5; the grape horn spot on the vine plant 叩 ez heart tracheiphila) (red fire disease (re&lt ; i fire disease) or Rothen's disease (rotbrenner'), deformation: bottle stem emblem (household / ^ / 叩 / ^ π)); various plants on the rust fungus CPttcc / mi spp.) (rust), such as cereals ( Such as small , barley or rye) and asparagus (such as the gingival bacterium (/>. aiSp<2r sigh) on brown broth CP. brown or leaf rust), strip-shaped rust fungus (house • sirn/ormb ) (striped or yellow rust), barley rust (houseau ^^·) (dwarf rust), rust rust (i>. gramkb) (stem or black rust) or leaf bacterium (ρ recon mountain ία) (brown or leaf rust); Phytophthora infestans on wheat (/Ve«op/?〇ra (deformation: umbilical cord blood spores) (tanose spots) or round nucleus on barley (house ieres) ( Net spot); Pythium genus (桫spp·), such as rice blast fungus (p or less zae) on rice (sex type: rice blast fungus ((10) (9) is the state of California "a), rice fever) and P grbea on turf and cereal; turf, rice, wheat, cotton, cotton, rape, sunflower, soybean, sugar beet, vegetable and various other plants of the genus Pythium spp.) (wet rot) (eg ultimate 138195.doc •35· 200939963 Pythium (·Ρ.w/i/wwm) or Pythium fuliginea (P.; Phytophthora (and aww/ar/α spp.), such as gum sigma on barley Ningzhu spore (Λ. co//o -Qg7n·) (Sacral leaf spot, physiological leaf spot) and beet column on beet (and _; cotton, rice, potato, turf, corn, rape, potato, beet, vegetables and various other plants) Rhizoctonia spp.), such as Rhizoctonia solani on soybean (Λ. ·?ο/α«〇 (root and stem rot), Rhizoctonia solani (sheath sheath blight) or Rhizoctonia solani on wheat or barley (brother cerea/b) (Rhizoctonia spring blight); Rhizopus oryzae on grass, carrot, cabbage, vine and tomato (and Kopwsjio/omT'er) (black mold, soft rot); Rhyne ho sporium • seca/h on barley, rye and triticale (bristles); Sarocladium oryzae) S. attenuatum (sheath rot); Sclerotinia SPP.) (stalk rot or white mold) on vegetables and field crops, such as rapeseed, sunflower (eg Sclerotium (eg Sclerotium) & jc/eroiz'orM/w" and soybean (for example, sclerotium (S. or Sclerotinia sclerotiorum); Sac in the various plants] Soybean brown rot (& brown spot) on soybean, wheat husk on wheat (1) (shell snail) and scorpion sinensis (51. nodorum) (synonym Nematoum)) (Stagonospora blotch); squid on the vine, synonym of powdery mildew (five people). Township fVzecaior) (powder disease, deformation: grape powder spore ( OiWw hunger iwcAreri)); corn (eg, zebra worm (孓iwdcww), synonymous with zebra zebra 138195.doc -36- 200939963 {Helminthosporium iwrcz'crww)) and turf on the turf spp.) Leaf blight); corn (eg, smut): sorghum and sorghum and sugarcane (5>/mce/oi/zec<3 spp.) (smut) /Saccharomyces cerevisiae on the plant of the genus Paniculata; the potato powder pathogen on the horse bell>sw6ierrii«ea) (powder disease) and the viral disease transmitted therethrough; the long ear on the scorpion SVagowospora spp. (SVagowospora spp.), such as the stalk of the stalk of S. serrata (S. «σί/orwm) Type: Ascomycete (Lepic^p/zaeria «oi/orw/w) [synonymous wheat leaf blight «οί/orww)]. Potatoes on the potato squamous cell carcinoma (c/^ir/ww (potato cancer); ectoparasite spp.), such as the genus of the genus of the genus (Γ. de/orwawiK) Leaf disease) and Lee's outer bacterium on the plum (T7·prwm·) (Li bag fruit disease). Tobacco, pome fruits, vegetables, soybeans and cotton on the genus Xanthomonas (77H'e/aWopiz··? spp.) (black root rot), such as Pythium genus (Γ. 6iZJicro/a) (synonym Pleurotus (C/m/ara e/sigh; genus of the genus Phytophthora (77//βη·α spp.) (common bunt or stinking smut), such as wheat on wheat腥黑 菌(Γ· ir(1)ci) (synonymous wheat net 腥. caries), wheat 遐 黑 w w w w w w w w co co co co co co co co co co co co co co co co co co co co co co co co co co co co co co Smut (dwarf bunt); barley or wheat on the snowy brown sclerotium sclerotium (Γ>77/ζΜ/α/«cijtrwaiiz) (grey snow mold); <^siz\s spp·), for example, rye smut (t/. occWM) on rye (stem smut); C/romyces spp. on vegetables (C/romyces spp.) Mine), such as beans (eg Bean Bean 138195.doc • 37- 200939963 (t/· appewi/icw/aiw*?), synonym for Phytophthora sojae (C/. p/zaseo/z·) And beets (such as the sweet-spotted spores (R; cereals (such as barley black powder) Bacteria (t/· «Μί/α) and oat powder (t/. avaewae), corn (such as maize black powder fungus (V. 叮山··?): corn smut) and sugar cane Black powder fungus (£/奶 7 〇spp.) (散黑粉病); apple (such as apple black fungus (K and Pseudostellaria spp.) (痂); and various plants Verticillium spp.) (wild disease), such as fruits and ornamental plants, vines, soft fruits, vegetables and field crops, such as strawberries, rapeseed, horse mash and tomato K dahliae. The mixture of the invention is also suitable for controlling harmful fungi in the protection of materials such as wood, paper, paint dispersions, blisters or fabrics and in the protection of stored products. As for wood and building materials Protection, paying particular attention to the following harmful fungi: Ascomycetes, such as Ophiostoma spp., Ceratocystis spp., Aureobasidium pullulan, Sclerophoma Spp.), Chaetomium spp., Humicola spp., Peter shell (Petriella spp.), Trichimis Spp.; Basidiomycetes, such as Coniophora spp., Coriolus spp., Pleurotus (Gloeophyllum spp.), Lentinus spp., Pleurotus spp., Poria spp., Serpula spp., and Tyromyces spp. Deuteromycetes, such as Aspergillus spp., Mycobacterium 138195.doc -38- 200939963 genus (Cladosporium spp.), Penicillium spp., Trichorema spp. Alternaria spp., Paecilomyces spp., and Zygomycetes, such as Mucor spp., and additionally in the protection of stored products, the following yeasts are worthy of Note: Candida spp. and Saccharomyces cerevisae ° for controlling various cultivated plants (such as bananas, cotton, vegetable species (such as cucumber, beans and sorghum), barley, grass, Oatmeal, coffee, © potato, corn A large number of fungi on fruit species, rice, rye, soybeans, tomatoes, vines, wheat, ornamental plants, sugar cane, and on a large number of plant propagation materials, preferably seeds, are particularly important. The mixture of the present invention also exhibits a significant effect against animal pests from the following species: insects from Lepidoptera, Zepz Wopiera, such as small tigers (dgroib, yellow tiger robes, roib ΜγίΜ/η), cotton leaf moth argi// Acea), larvae (dwiicarha gewmaia/b), snail (Jr illusion; rew/π.α co«_/wge//a), larvae gawma), pine scorpion scorpion Moth, Cacoecia murinana, cotton brown moth (Capwa rehcM/α), winter moth (C/ze/waic^/α spruce leaf moth {Choristoneura fumiferana), western spruce leaf butterfly {Choristoneura occidentalism , American worm (Cirphis, apple moth powo„e//a), European pine caterpillar (Dendrolimus pini), genus Diaphania nitidalis, giant jade 138195.doc -39- 200939963 rice mold (Dkiraea grandiosella) 'Egyptian diamond (_Earz_a5 insulana), '], corn tower (Elasmopalpus lignosellus), grape moth (Eupoecilia ambiguella), l machine '\, Evetria bouliana, grain tiger (jFWik, large soil filling (GaZ /eria mellonella), 李小食心义(Grapholitha fu Nebrana), mis's, food heart (Grapholitha, Heliothis armigera., Heliothis virescens, Heliothis zea, I pain (Hellula, Irish wing winter foundation (/ /76er«ia defoliaricT), Hyphantria cw«ea, Hyponomeuta malinellus, idiot ez/er/α/ycoperhcW/a, hemlock ;am6£/i»a! /ϊ·5<^//αη·α), beet night ^{Laphygma exigua) ' Φ ^ ^ i^(Leucoptera coffeella) ' Leucoptera scitella, gold Therefore, the moth (Lithocolletis

Blancardella) 'Lobesia botrana, Loxostege sticticalis ' ^ ^ ^{Lymantria dispar) ' if Jtj phloem {Lymantria monacha), narrow-winged leaf miner {Lyonetia c/erh/ /a), Canopy caterpillar (Ma/aco>soma newsiWa), Cabbage worm (Mamestra brassicae), Douglas sinensis moth (Org scorpion 'α: pseudotsugata), European corn mold (Ojirz'm'a, winter moth ( Panolis flammed), h. bell (XPectinophora gossypiella), variegated tiger (PeWi/roma saucia), sP/ia/era bucephala 'Phhorimaea operculellcf', sample fine dive织{Phyllocnistis citrella' 'Pierb 6r<3i<sz'cae), Greenfly moth (P/ai/ij/jewa παόΓβ), Plutella xylostella 138195.doc -40- 200939963

(Plutella xylostella), Pludoplusia includens, P. serrata (and, Scrobipalpula absoluta, Sitobiga cerealella, S. cerevisiae) (Spargimoi/n·· ? />z7/erk«〇f), grass worm {Spodoptera frugiperda), Spodoptera litura (Spodoptera /z'iiora/zO, Spodoptera litura ((S/Jodopierfl /iiwr<2), sap Moth (TTiawmaiopoea piiyocampa), TbriHx viridana, Trichoplusia ni, Zeiraphera canadensis, beetle (Co/eopiera), for example Pear Changji Ding (JgW/w·? sMwaiwi·), gigrioiw /keaiwir, Agriotes obscurus, Amphimallus solstitialis, European rainbow worm (·^«bawc/rw· ? i/b/jar), cotton boll weevil (/«i/zowo/wwj grandis), apple flower weevil (JwiAowo/WM·? /?o/worwm), side scorpion genus {Aphthona euphoridae), l 0卩子{Athous haemorrhoidalis) 'Linear ecstasy (y4iomarz'a /iwearz'j), big pine small 蠹 (not like iopkgws f, day Dead leaf moth (_β/ζ·ίο/?/ια茗α undata), stupid ~ 良 (Bruchus rufimanus), 筑 i 象 (Bruchus p/jorwm), lentils/e« along), 岭果卷叶甲甲fteiw/ Ae), beet big armor (CawzWa «e do w/osa), bean leaf f (Cerotoma trifurcata), gold in the golden elephant (Cetonia aufata), scutellaria (Ceuthorrhynchus assimilis) dark veins like {Ceuthorrhynchus «αρζ ·), beet cavity beetle (C/zaeiocwewa 138195.doc -41 - 200939963 A (CWocerz'i aiparagz·), Aquila (Ciem'cera πρ·), Longhorned beetle (Z>ia6ro"ea /owgz 'corw^), 半星叶曱(Z)ia6ro"'ca semipunctata) ' Twelve Stars (_Dia6ro"ca i2-/?w«ci<3ia", Diabrotica speciosa > Corn Root Leafhopper (Dia6r<?iz'ca virgifera), Mexican bean ladybug (Epz7ac/ma, tobacco flea (Epitrix hirtipennis), Brazilian standard (Eutinobothrus △ raji/iewsb), pine weevil (//y/oWw aWeib ), Hypera brunneipennis, Hypera postica, spruce octagonal scorpion (//7j typographus) , Lema ❹ bilineata, Lema melanopus, Leptinotarsa decemlineata, Liwom'Mj californicus, Lissorhoptrus oryzophilus, Plum gas (Me/awoiw·? cowmwm'·?), rapeseed 露 曱 aewewi), 布布总角金龟(Me/o/o«i/za /n'ppocasiani), Western May total golden tortoise (Meloiontha Melolontha), Oulema oryzae, Ortiorrhynchus sulcatus 'Otiorrhynchus ovatus' (Otiorrhynchus ovatus) Horseradish 猿 (·ΡΛαβί/ο« cocr/i/eariae), pear leaves Elephant (P/^Z/oWw·?, Phyllotreta chrysocephala, Phyllophaga sp., Gardenia Lili / iori/co/a), Phyllotreta nemorum, Yellow curved strip flea 5ίτζ·ο/αία), Japanese Lijin turtle (·Ρορζ7/ζ·α _/apom'ca), Sitona lineatus (Sitophilus granaria), rope, mosquito (double-winged (Diptera), such as Aedes aegypti (Jec/e·? 138195.doc -42- 200939963 aegypiz·), white Aedes aegypti α/6ορζ·(;ίι^), Aedes aegypti vexaws), Mexican orange rope/Mi/ews, Anopheles maculipennis, Anopheles australis {Anopheles crwdaw·?), white Anopheles sinensis, Anopheles gambiae, Anopheles freeborni, Anopheles sinensis (Jwop/iWej /ewcosp/^rwj), Anopheles sinensis (Jwo/7/ie/ei minimus), Izg ^ {Anopheles quadrimaculatus) ^

Rope (Ciz//i'p/i〇ra νζϋα), Mediterranean solid rope (Cerai/ib capz.iofia), sister's golden rope (C/z7som>; a bezziana), American golden rope (C/jrj^owya) /zomim'vorax), American rice water rope (C/zrj^omj^a wace/Mria), middle room spotted rainbow ^CT/rpops i/z\sca/z\s), static spot h/acea), Atlantic Chrysops atlanticus, Cochliomyia /zo/nz'm_vor〇fx, Cowiar/m'a jorg/n'co/α, Cordylobia anthropophaga, hair Kusong (Cw/icozWej /wrew), Culex quinques (C«/ex;? such as _e«·?), Culex pipiens (Cw/e; c nigripalpus), concealed [Culex quinquefasciatus&quot ;), m. cinerea (Cw/ex iarw/b), yellow-tailed larvae (Cw/heia koawa), black-tailed larvae (Cw/beia me/a«wrt〇, melon flies (£) Acwi CWCMrwiae), Dacws o/eae, Brassica (Brassicae), @@Delia antique, Delia coarctata, Delia pilatura, 卷心茱虫 i (Deiia radicum) ' k $ iron {Dermatobia hominis), ^ 43⁄4 {Fannia ca«kw/aWj), potato flies (Geo Myza 7W;?w«Ciaia),Gasterophilus intestinalis, Glossina 138195.doc -43- 200939963 worWiawj, tongue, tongue (G/ouz'wa /wi'c/ Joe·?), tongue rope (G/ojjka iac/n·(10)zWe·?), Haematobia irritans, phalaenopsis (//ap/ot/ip/ojb egwejirb), genus i^'ppe/otie·? 5pp.), seed rope p/aiwra), striated skin (//); /7〇<ierma lineata) 'Leptoconops torrens' American stalking rope (Lirz 'owjvza sativae) 'Trilobite stalk rope ([zWomyza ir(/b/h·), Goat Green Worm (Iwci/iia caprina), Copper Green Rope (_Lwci/ia cuprina), Green Green Rope (Lucilia seWcaia), Aspen flies (L_ycor/a peciora//·?), 搔 曼 θ θ {Mansonia titillanus) Hesse wheat rope (Μα>»βίί·ο/α ί/eiirwcior), home rope (Mwjca dowesiz'cfl ), 廄 绳 ( (MM5c/«iz 5ia6w/a«5), sheep nose rope ((9e5irw·? oWi1), yellow rope (Opom^za //orww), Swedish straw rope (6^scke// I7 /Wi), beet squash (Pegomya /^iocjyawz·), onion rope (·Ρ/ί〇ΓΖ>ζ·ίϊ α«ίζ · "Μα), cabbage rope (P/zorWa, P/zorWa coarciaia, Phlebotomus argewiz'pei, Columbia spleen (Psorop/zora ◎ co/w/wWae), carrot Rope (7 〇! rosae), Psorophora discolor, Prc?jiww//wm mixtum, cherry fruit fly (Λ/zago/eiz··? cera·^·), Fruit rope (i^ago/eih pomonella), (Sarcophaga haemorrhoidalis), carnivorous genus (iSarco/^crga 57?), bandage (iS7mw/z'ww Wiiaiwm), waste reins (tSVowoxj·? cct /ciira like), Niu Hong: (7^0<3««5·ZjoWwwi·), black horse rope (Γα6β«Μ·5 airaiws), striped horse rope (raZjaww·? /ineo/a) and similar to it ( ΓαάαπΜί jz·所?7ζ_·5), cabbage (77/?w/<a σ/eracea) and European mosquito 138195.doc -44- 200939963 {Tipula paludosa), 蓟马(缕翅目(7Vj3) ^a«opier<3)), such as orchid thrips (Dz.c/zrowoi/iW/?·? cor6ei"), orchid 蓟maya ijp), tobacco brown horse (Fra«Hhie//a/wsca ), 苜吉莉马{Frankliniella occidentalism 花莉马(Frankliniella Orange 蓟 ( ("SWrioi / zrz · / ^ cz'irz ·), rice Lima (77 / r (pj or yzae), South Yellow 蓟 horse (TTiWps; ? a / w 〇 and 蓟 蓟 horse (77irz_;? j tabaci) ', ^ White moth (Isoptera), such as European wood termite (Ca/oierme5 //av/co//i'5·), yellow-footed termite (Lewcoierme·? //αν(ρα) ), Golden White 蠘 {Heterotermes awrewi), Yellow-breasted termites (/iei/cw/herwes /7aW/?ei), Virginia termites Wrgz'm'cws), Southern European netted termites, Golden flower termites (rer/ Wei natalensis)^. % ^ ^{Coptotermes formosanus) latitude (Blattaria-Blattodea), such as German cockroach (_5/a"e//a gerwawz'ca), Asian latitude o^a/ N'wae), ❹洲大蠊(Perip丨cmeta americana) '日本大灿(_Per(p/a«eia japonica) ' ^ ^ A ^ (Periplaneta 6rM««ea), Black-breasted cockroach (Periplaneta fuiigginosa ), Australian album (Peripianeta australasiae') Blatta orientalis 'Hemiptera, such as yicroiierwww hilare, Blissus leucopterus, tobacco ticket Plaque wall · {Cyrtopeltis woiaiwj), cotton red bee cz'gw/aiw>s), cotton wool (Ayii/ercw·? intermedius), maiden eagle (Eurygaater 138195.doc -45- 200939963 integriceps), cotton brown (Euschistus impictiventris), Leptoglossus phyllopus, Lygus iineolaris, green blind owl (Zygwi praiew ·?), rice green bee (iVezara WWdw/i〇, beet inspection net wall ( Piesmci quadrata), Solubea insularis, Thyanta perditor's, paper yard [Acyrthosiphon o/ioftryc/n··?), larch ball money (dc/e/ge·? /arick), Buckthorn potato money (dp/nWw/α wasiwriz·/), broad bean money/αΖ?αβ), strawberry root wealth/br6e>s〇, frequency fruit money (d/?//,·??, cotton money (Jp /n'j

Gojijvpz’z·), Gooseberry (^4;?/π’·5 groj^w/arz’ae), Rat Li Cai (Jp/n·*?

, 绣菊菊财(/4/?/π_·ί «spiz-aeco/a), elder wood money (々?/π·ί sambuci), paper worm (Acyrthosiphon pisum), potato long must (jw /<3C〇ri/?wm ·5〇/απί), silver leaf powder wind (JJemiWa arge«"/o/"), Li/ze/ic^ryh), peach black short-tailed money (Brac/ iycflMi/wi·perj/cae), Meicai {Brachycaudus prurticola), Cabbage ({{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{{ Chaetosiphon /ragae/b/h·), 蘼 蘼 蘼 额 ( (Crjv^iomyzwi rzD), 杉杉绵财{Dreyfusia nordmannianae), fir vertebrate (·DRy/iwsz'flt piceae), apple cut-off (Ayiap/π? rac/icro/a), apple ditch without net money {Dysaulacorthum pseudosolani), frequency pink inferior ^ (£>>^α/7/π_5, pear tree awning money ργί·), stupid Bean micro-leaf (jB/wpoi^ca/aZiae), Mei Daweicai/7rw«i), tea recommended bitter food (//^perowwi/s /aciwcae), Mai Changfucai (Macr〇i(p) /iMW 138195.doc -46 - 200939963 avewae), big 戟 管 ( (MacroWp/zwm, Fan Wei long money (Macrosip / Zcm rosae), Megahoura Wciae, Melanaphis pyrarius, Metopolophium dirhodum, Myzus persicae, Afyzws izjca/om'cwj, cherry Black tumor money (M_yzwi cerom), flower butterfly lamp money (M less zwi varz'awi), wormen money (iVotiowoWa riMi-wz'gr/), brown rice chaos {Nilaparvata /wgew·?), borage Roots and thin money w?? △ MrjizriMJ), cane flying wind (·ΡβΓΑ:/«5ίβ//α iacc/jarz'czWa), sisal fatigue © ^ (Phorodon humuli) ^ ^(Psylla mali) s ^ ^^{Psylla pz>,·), winter onion through the tumor (ii/iopa/oTwyzw·?, corn management

Field (Rhopalosiphum maidis), Wo number tube farm (Rhopalosiphum /?α山·), fruit and grass money (Λ/ζορβ/ί) ί//>/ΐΜ»ζ /«ieriMw), Marais round tail pair ( «Sap/jap/n·*? wa/a), Mali Yuanwei Cai (Sap/jap/n··?ma/i·), Mai Erqian {Schizaphis graminum), Pear Mian Cai (Sc/n' Zowewra /awwgiwoia), Mai Chang Guan Cai (57ioZ?/ow ανβπαβ), greenhouse white powder wind {Trialeurodes vaporariorum), Tokuptera aurantiiand ' grape root nodules (K/ieM·? Wii/o/z7), temperate zone Bed bugs (C7me: x: /eciM/ar/w·?), tropical bedbugs (Ciwex Aemz__pierw5), old ages (/Jei/wWw·?, Cone genus (TWaioma?/?;?·) and wheeled hunting Wall {Arilus critatus) > Moth, bee, wasp, ore bee (Hymenoptera), such as Xinjiang leaf bee rc^ae), tropical leaf-cutting ant (Αία ce/Aa/oies), leopard cut Leaf ants (Jiia capigwara), tropical leaf-cutting ants, smooth leaf-cut moths (Αία / aeWgaia), strong leaf-cutting ants (Αία Γοέζ^ία), six 138195.doc -47- 200939963 孔切叶 sacrifice iexdew·?), Texas cut leaf ant iexawa) iCrematogaster spp.), Li f dance {Hoplocampa minuta), apple bee iesiw mountain _«ea), kitchen ants (Mowomor/ww p/zaraowb), fire ants ("So/ewophi, external red fire ant (JSolenopsis invictcT) , ticket, woven (Solenopsis richterf), Solonopsis xylonf, k- (Pogonomyrmex barbatus) 'California red harvest ant (jPogowoAWFweA: cfl/z/orw/cw·?), tropical head moth

(Pheidole megacephala), killing moth {Dasymutilla occidentalis), JBombus spp., Vespula Wwawosa, common wasp (·Ρα"ανβ·57?Μ/α vw/garb), Western wasp (Paravespula pennsylvanica), German wasp (Paravejpw/a germanica) ' Μ ^ {Dolichovespula macw/αία), Vespa cra6ro, Po/iiies, Camp ant {Camponotus floridartus, anti-Pi root soil (Linepithema humile), 蟀 蟀, 蚱 、, * 皇 目 (Orthoptera), such as the total 蟀 (dc / ieia c / o / wesiica), European 蝼蛄 (Gr ^ / oia / pa ^ τ _) ;//οία//7α), 坛 a (LocMWa migratoria) 'Double belt 蚱 fierce (Me/a«op/ws άζ_νζ7ίαίΜ·ϊ), red-legged keen (Me/imop/w·? /emwrrw6rMW), Mexico Melanoplus wexicaw MJ, Me/awop/w·? sanguinipes, Me/a«o/7/wi jpreiwi, Nomadacris septemfasciata, (5c/zi5iocerc<2 americana) 'Sc/ibiocerca gregaria, Moroccan 戟 竣 (·0〇£?ζ·〇ίί Μ/-Μ·ϊ /waroccaww·?), greenhouse chrysalis 138195.doc -48- 200939963 asynamorus) 'Senegal 蚱 • s sewega/ewWj), variegated 乍 乍 (Zowozerws variegatus), rice production (Hieroglyphus Indian yellow sandal worm (ATrawsiarz'a a«gw/(/era), Italy (Calliptamus italicus), Australian catastrophe (C/zorioiceiej terminifera) anti-demolition (Locustana pardalina),

Arachnoidea, such as the arachnid (Acarina), such as the soft aphid, the hard tomb (/jco mountain · ί / ββ) and the genus Sarcoptidae, such as: American flower t monument (Amb丨yomma americanum) ' ^ ^ ^ i^· (Amblyomma variegatum) ' ja (Ambryomma maculatum), Persian concealed (drgas perWcw·?), with a ring of cattle monument (5oo/?/n7wi annulatus), Boophihis decoloratus: '), BoophiZus microplua, Dermacentor silvarum, Dermacewior andersoni 'Dermacewior varia6z'/z··?) Yuanbao mechanical monument (i/_ya/o/wm<2 irw«caiww), sheep hard monument (inodes r/cz'wws), South African acupuncture treatment (/jcoi/es rwZ?z'cw«i/wj), Black-footed hard palate (/jcoc/es jca/7M/arz's), Ixodes holocyclus, Pacific hard palate (/xoi/e·? pacificus), rabbit monument (Ornithodorus moubata), {Ornithodorus hermsi), returning to the hot wall chaos (Orm'i/zot/orMJ iwrieaia), Bai's poultry thorns «small 6acoiz·), ear stagnation (Otobius megnini), thorny moth (Defma) Nyssus galHnae), Psoroptes ovis 'Rhipicephalus sanguineus, Rhipicephalus appendiculatus, Rhipicephalus evertsi, Sarcoptes scabief ·, anti-vine 138195.doc -49- 200939963

{Eriophyidae spp.), such as the scorpion snail (Jcm/ms scr/z/ec/ziewi/a//), the orange rust (P/2_y//〇co/?iraia o/ez'vora ) and citrus lean worm (five Wop/zye·? >s/ze/i/o«i·); TarJowemWae spp., such as primrose/?α//ζ·ί/ Μ«?) and polyphagous line 瞒{Polyphagotarsonemus latus) ',Tenuipalpidae •ypp.), such as purple-red short-stalked snail (·δΓβνζ·/?α//7Μ5 /7/ioewz'cb); Leaf genus (reira^yc/nWae, such as ZWrartyc/jMJ cinnabarinus) # ^ H iSj # (Tetranychus ^awzawaz·), Pacific red leaf worm (reirawyc/iws /?iZc(/VcMs), cotton red The lack of spiders (reirawyc/zwi Ο ie/aWwj) and cotton leaf worms (TWrawyc/iWi wri/cae), fruit-red scars (Pawcmyc/^M·? m/twz'), orange full claw ci / W) and grassland melon worm (O/z'go^yc/jws; lacking) draweWa, such as the black widow ball spider (Zairodeciws maciirn·?) and the color concealed spider {Loxosceles reclusa) }

Flea (Siphonaptera), such as QCtenocephalides felis, Ctenocephalides canis, Xenopsylla cheopis, Pulex irritans, Tunga and Tunga Striped squid {Nosopsyllus fasciatus) > Silverfish, firebrat (Thysanura), such as Lepisma saccharina and Thermobia domestica, entertaining (lipus) (Chilopoda)), such as the armband (•Scwi/gera coleoptrata) » Millipod (Diplopoda), such as the genus Beetle (A/^rcews 138195.doc -50- 200939963 spp.) ' 蠼螋 ( Dermaptera, such as the European ball python (/br/Vcw/a auricularia) > chaos (Phthiraptera), such as humanus capitis), Pediculus humanus corporis, And the wind {Pthirus pubis), the cattle blind wind {Haematopinus ewrpierwwj), the bloody chaos, the long-headed cow wind (Linognathus Wiw/z'), the cattle biting wind (5oWco/a, chicken wind ❹ M ^{Solenopotes capillatus) » Plant parasitic nematodes, such as nodule nematodes, falling Peanut root nodule arewaria), Chitwood root nodule (Me/oWogywe c/n'iwooc^·), short root nodule nematode exz_gwc?), northern root nodule preparation (Meloidogyne hapla), southern nodule line preparation (Meloidogyne incognita) ' A ^ }MA {Meloidogyne javanica)^ Nematode species; cyst nematode, larvae rostochiensis, Globodera pallida, cytidine iaZ>acwm, and other cyst nematodes (G/c) ?6〇i/era) species; wheat cyst nematode (//eierodera avenae), soybean cyst nematode {Heterodera glycines), sugar beet cyst nematode (i/eieroc/era sc/mc/?...), clover cyst Nematodes (//eier〇i/er<3 ir(/b/i7) and other cyst nematodes (feet eierodera) species; nematodes, nematode nematodes (dwgMiwi? /wnejia), wheat worms 4«^ ·ΜΖ·«α iriWcz·) and other nematodes {Anguina) ^ ; Stem and leaf nematode, leaf bud preparation (Aphelenchoides 138195.doc 200939963 besseyi), Phytophthora 7] Aphelenchoides ffagcifiae, beginning of inulin Line preparation (Aphelenchoides and other leaf bud nematodes; Aphis elegans, Nematodes (Se/ Owo/aiww·? /o«gicawc^iw·?) and other species of thorn nematodes; pine nematodes, pine wood nematodes (Swri'ap/ze/ewc/zws x_y/o/?/n7w·?) and other umbrellas Nematodes (BwrM/^e/enc/zM·?) species; C. elegans, CWcowema, CWco«eme//a, CWccmemoWe·? Ne. elegans (Meiocr/ccmewfl); stem and bulb nematode, horse bell borer nematode (Diiy/ewc/jM·? t/esirwcior), corn stem nematode (Dz'iy/ewcAMJ ❹山·; 7MCZ·), food Stem nematode wj/cre/io/?//agws) and other stem nematodes; cone nematode 'Do/ic/zooforwj' species; spiral nematode, double-spiral nematode (dihystera), multi-snail, Helicotylenchus multicinctus against other spiral nematodes; snails and other snails (and o0^e"cAw51); sheath nematode 'sheathworm heart ·<^£^〇/^〇&quot ;β) species and the genus Hemicriconemoides, Hirshmcmnie Ha species; Spear-shaped nematodes, Coronaria elegans (open 0 (7) ~ so · 5), C. berghei (//op/o /a/mw·? ga/eaiws) and He has a spore-like nematode; pseudo-root nodule, abnormal pearl nematode and other pearl nematodes; needle nematodes, arachnid and rwi e/owWie>s) and other nematodes (Z(10)gzi/orw); nail nematodes, nail nematodes (households) Species; root rot nematode, short-rooted rot nematode (cadmium ac/^Mrws), coffee short-body elephant worm i (Pratylenchus coffeae), mouth-negative nematode i (Pratylenchus 138195.doc -52- 200939963 cwrWiaiwj), gangrene nematode ( /Vaiy/ewc/zMJ, California root rot nematode (fVae/ewcw·? we^7eciwj), puncture root rot nematode (/VaO^/ewc/jws, S. striata (Praiy/ewc/iw·? 5crz' 6«erz·), the root rot nematode vm/ww·?), the short-spotted nematode (Prariy/ewc/zw·? zeae) and other root rot nematodes (Praiy/ewc/zwi); (iiai/iwapAe/ewc/iM·? cocop/zzYw·?) and other thin rods (Radinaphelenchus); perforated nematodes, similar to perforated nematodes (Λίϊί^ρ/ζο/Μ·? ·5Ζ·;/Π · / ί·ϊ) and other 孑I* nematodes (ββί/ορ/ίο/“·?) species; kidney shape.© Nematodes, kidney-shaped kidney nematodes (ΛσΟ^/ertc/iw/M·? rewz/ Or/wz?) and other kidney shapes Nematode (and oO^/ewc/zM/w·?) species; Shield nematode ("ScMie//o«ewa" species; Residual nematode, primitive burr nematode (TWc/iodorw·? />Γϊ·/ηζ· Ίί·νΜί) and other species of the genus Nematode (TWc/zoi/orwi); the genus Trichosanthes (Parair/c/^i/orw·? mkor) and other species of Parairz'cAoi/orwj; Nematodes, horse-toothed dwarf nematodes (T^/enc/zor/^wc/zM·? c/ayic^z·), ductal dwarf nematodes (T^ewc/zor/^wcAw·? £/w6iw« s) and other dwarf nematodes (ry/enc/zor/^wc^wj) species and Merlin's nematode (MeWzWw*?) species; orange worms, citrus semi-pricked root nematodes (T^ewc/zw/w· ? sewipeneircm·?) and other citrus nematodes (T^/ene/iw/Ms) species; S. elegans, American sword nematode • (Xiphinema americanum), Xiphinema index, species; and other plants Parasitic nematode species. [Embodiment] The mixture according to the present invention can be applied to any and all developmental stages of pests such as eggs, larvae, pupa and adults. The pest can be controlled by contacting the target pest, its food source, habitat, breeding ground or its location with a pesticidal effective amount of the inventive mixture or a composition comprising the mixture. Eight "Location" means a plant, plant propagation material (preferably seed), soil, area, material or environment in which the pest is growing or growing. In general, "insecticidal effective amount" means achieving an observable effect on growth, including necrosis, death, delay, prevention and removal, destruction or other means of reducing the incidence and activity of the target organism. The amount of insecticidal effective amount of the inventive mixture or composition comprising the mixture is variable for the various mixtures/compositions used in the present invention. The pesticidally effective amount of the mixture/composition should also vary depending on the general conditions such as the desired insecticidal effect and duration, weather, target species, location, mode of administration, and the like. As indicated above, the invention comprises a method of improving the health of a plant, wherein the plant, the locus where the plant is growing or expected to grow, or the plant propagation material from which the plant is grown is treated as a plant healthily effective amount of the inventive mixture. The term "plant effective amount" means that the mixture of the invention is sufficient to achieve a plant health effect as defined below. More exemplary information regarding amounts, modes of administration, and suitable ratios to be used are given below. It is well known that this amount can vary over a wide range and depends on various factors, such as the cultivated plant or material being treated and the climatic conditions. When preparing a mixture, it is preferred to use a pure active compound, and an anti-antibiotic can be added thereto as needed. Other active compounds of pests (such as insecticides, herbicides, fungicides) or other herbicidal or growth-regulating active compounds or fertilizers 138195.doc •54- 200939963 as other active ingredients. By insecticidal effective amount of activity The compound is used to treat a fungus or plant, a plant propagation material, preferably a seed, a material or soil to be protected from fungal attack, using the mixture of the invention in a material, plant or plant propagation material, preferably a seed. It can be carried out before and after pest infestation. Depending on the type of compound and the desired effect In the method of attacking harmful fungi, the application rate of the mixture according to the invention is 〇, 3 g/ha to 2 g/ha, preferably 5 g/ha to 2 g/ha, more preferably 5 〇 In grams/ha to 9〇〇g/ha, especially 5〇g/ha to 75〇g/ha. In the method of combating animal pests (insects, mites or nematodes) depending on the type of compound and the desired effect, according to this method The application rate of the mixture of the invention is 〇, 3 g/ha to 2000 g/ha, preferably 5 g/ha to 2 g/ha, more preferably 50 g/ha to 900 g/ha, especially 5 gram / hectare to 750 g / ha. The mixture of the invention or a combination of such mixtures can also be used to protect plants from attack or infestation of animal pests (insects, mites or line bombs), including contact with plants, or plants are growing In the context of the present invention, the term plant refers to whole plants, parts of plants or propagation material of plants. Plants which can be treated with the mixture of the invention and the propagation material of such plants include all genetically inherited Plants or transgenic plants, such as crops that are tolerant to herbicides or fungicides or insecticides by breeding (including genetic engineering methods), or plants with modified characteristics compared to existing plants 138195 .doc -55- 200939963, which may be produced, for example, by conventional breeding methods and/or mutants or by recombinant procedures. For example, the mixture according to the invention may also be applied (by seed treatment, Spray treatment forms, in furrows or by any other means, plants that have been modified by breeding, mutation induction or genetic engineering, including but not limited to agricultural biotechnology being marketed or under development Products (see http://www.bio.org/speeches/pubs/er/agri_products.asp) Genetically modified plants have been genetically modified by recombinant DNA techniques to allow for cross breeding under natural conditions. Mutants or natural recombination cannot be easily obtained from plants. One or more genes have generally been integrated into the genetic material of genetically modified plants to modify certain characteristics of the plant. Such genetic modifications also include, but are not limited to, post-translational modifications such as prenylation, acetamylation or farnesylation of proteins, peptides or polypeptides by, for example, glycosylation or polymer addition. Farnesylated moiety or PEG moiety. As a result of conventional methods of breeding or genetic engineering, plants that have been modified by breeding, mutation induction or genetic engineering are, for example, tolerant to specific classes.

Q The application of herbicides such as hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors; acetaminolate synthase (ALS) inhibitors, such as sulfonium urea (see, for example, US 6,222,100, WO 01/82685, WO 00/26390, WO 97/41218, WO 98/02526, WO 98/02527,

WO 04/106529 'WO 05/20673 'WO 03/14357 'WO 03/13225, WO 03/14356, WO 04/16073) or imidazolidinone (see for example US 6,222,100, WO 01/82685, WO 00/ 026390, WO 97/41218, WO 98/002526, WO 98/02527, WO 138195.doc • 56- 200939963 04/106529 'WO 05/20673, WO 03/014357, WO 03/13225, WO 03/14356, WO 04/16073); enolpyruvylshikimate-3-phosphate synthase (EPSPS) inhibitors such as glyphosate (see, for example, WO 92/00377); glutamine Indoleamine synthase (GS) inhibitors, such as glufosinate (see, for example, EP-A 242 236, EP-A 242 246) or oxynil herbicide (see, for example, US 5,559,024). Conventional methods of breeding (mutation induced) have enabled several plants to be tolerant to herbicides, for example, to make Clearfield® summer rape (Canola, BASF SE, Germany) tolerate imipenem, such as imazamox (imazamox). Genetic engineering methods have been used to make cultivated plants such as soybean, cotton, corn, sugar beet and canola tolerant to herbicides such as glyphosate and glufosinate, some of which are under the trademark RoundupReady® (Glyphosate, Monsanto, USA) ) and LibertyLink® (cadherin and f, Bayer CropScience, Germany) are commercially available. Also included are plants capable of synthesizing one or more ® insecticidal proteins by using recombinant DNA techniques, particularly ones from the genus Bacteroides, especially from Bacillus thuringiensis, such as Δ-endotoxins such as CrylA(b), CrylA(c), CrylF, CryIF(a2), CryIIA(b), CrylllA, CrylllB(bl) or Cry9c; plant-based insecticidal proteins (VIP), such as VIP1, VIP2 , VIP3 or VIP3A; insecticidal proteins of the bacterial nematode, such as Photorhabdus spp. or Xenorhabdus. spp.; toxins produced by animals, such as saxitoxin, toxin, and wasp toxin Or 138195.doc -57- 200939963 other insect-specific neurotoxins; toxins produced by fungi, such as streptomyces toxin, plant lectin, such as cowpea or barley lectin; agglutinin; protease inhibition Agents, such as trypsin inhibitors, serine protease inhibitors, potato tuber storage protein (patatin), cystatin (cystatin) or papain inhibitor; ribosome Protein (RIP), such as ricin, corn-RIP, abrin, luffin, saporin or bryodin; steroid metabolism enzyme , such as 3-hydroxysteroid oxidase, quercetin-IDP-glycosyl-transferase, cholesterol oxidase, ecdysone inhibitor or HMG-CoA reductase; ion channel blockers, such as sodium or calcium channel blockers ; juvenile hormone esterase; diuretic hormone receptor (helicokinin receptor); stilben synthase, bibenzyl synthase, chitinase or glucanase. In the context of the present invention, it should also be clearly understood that such pesticidal proteins or toxins are pre-toxin, hybrid proteins, proteins which have been cleaved or otherwise modified. Hybrid proteins are characterized by a new combination of protein domains (see, for example, WO 02/015701). Such toxins or the ability to synthesize such toxins are disclosed in, for example, EP-A 374 753 'WO 93/007278 'WO 95/34656 'EP-A 427 529 ' EP-A 451 878, WO 03/18810 and WO 03/52073 Other examples of genetically modified plants. Methods of making such genetically modified plants are generally known and described by those skilled in the art and are described, for example, in the above publication. These insecticidal proteins contained in genetically modified plants impart to the plants producing these proteins harmful pests to all taxa of arthropods (especially 曱138195.doc -58- 200939963 worms (coleoptera) Tolerance of Coeloptera, two-winged insects (Diptera) and moths (Lepidoptera) and to nematodes (Nematodes). Genetically modified plants capable of synthesizing one or more pesticidal proteins are described, for example, in the above publication, and some of them are commercially available, such as YieldGard® (a corn cultivar producing CrylAb toxin), YieldGard® Plus (creating CrylAb and Cry3Bbl). Toxin corn cultivar), Starlink® (Cry9c toxin-producing corn cultivar), Herculex® RW (production of Cry34Abl, Cry35Abl and enzymatic phosphinothricin-N-acetyltransferase [Phosphinothricin-N-Acetyltransferase, PAT] Corn cultivar); NuCOTN® 33B (cotton cultivar producing CrylAc toxin), Bollgard® 1 (cotton cultivar producing Cryl Ac toxin), Bollgard® 11 (cotton cultivar producing CrylAc and Cry2Ab2 toxin); VIPCOT® (Cotton cultivars producing VIP toxins); NewLeaf® (Cry3A toxin-producing horse-aged cultivars); Bt-Xtra®, NatureGard®, KnockOut®, BiteGard®, Protecta®, Btll (eg Agrisure® CB) and Syngenta Seeds SAS, France's Btl76 (a corn-cultivated cultivar producing CrylAb toxin and PAT enzyme), MI from Syngenta Seeds SAS, France R604 (a maize cultivar producing a modified version of Cry3A toxin, see WO 03/018810), MON 863 from Monsanto Europe SA· 'Belgium (a corn cultivar producing Cry3Bbl toxin), IPC 53 1 from Monsanto Europe SA, Belgium (a cotton cultivar producing a modified version of Cry 1 Ac toxin) and 1507 (a corn cultivar producing Cry IF toxin and PAT enzyme) from Pioneer Overseas Corporation, Belgium. 138195.doc -59- 200939963 In addition, plants which are capable of synthesizing one or more proteins to enhance the resistance or tolerance of their plants to fine @, viral or fungal pathogens by using recombinant 0]^8 techniques are also contemplated. Examples of such proteins are the so-called "pathogenesis-related proteins" (PR proteins, see for example Ep_A 392 225), plant disease resistance genes (for example, the performance of resistance to Phytophthora phytophthora (phyt〇phth〇rainfestan) A potato cultivar that is resistant to the resistance gene of s〇ianum bulb 〇Castanum in Mexico, or a τ4 lysozyme (for example, capable of synthesizing such enhanced resistant bacteria (such as P. amylovora) (Envinia amylvora)) a potato cultivar of resistant protein). Methods of making such genetically modified plants are generally known to those skilled in the art and are described, for example, in the above publications. In addition, it is also possible to synthesize one or more proteins by using recombinant DNA technology to increase productivity (eg, biomass yield, grain yield, powder content, oil content or protein content), for drought, salinity or other Plants that are resistant to environmental factors or to tolerance to pests and fungal, bacterial or viral pathogens of their plants. In addition, 'the use of recombinant DNA technology to contain varying amounts of substance or novel substance content', especially for improving human or animal nutrition, such as the production of health-promoting long-chain omega-3 fatty acids or unsaturated omega-9 fatty acids (eg Nexera®) Oilseed rape, oilseed crop of DOW Agro Sciences 'Canada. In addition, 'plants that contain varying amounts of material or novel substances, especially those that improve the yield of raw materials, such as those that produce increased amounts of amylopectin (eg, Arnfi〇ra® potato, 138195.) are also covered. Doc -60- 200939963 BASF SE, Germany). For the purpose of treating plant-propagating substances (especially seeds), water-soluble concentrates (LS), flowable concentrates (FS), powders for anhydrous treatment (DS), and slurry treatment (WS) are usually used. Water dispersible powders, water soluble powders (SS), emulsions (ES), emulsifiable concentrates (EC) and gels (GF). In a preferred embodiment of the invention, the mixture of the invention is used to protect the roots and shoots (preferably seeds) of the seed and seedlings. The seed treatment can be carried out in a seed box and subsequently planted in the field. For the purpose of seed treatment, the weight quantification in the binary, ternary and quaternary mixtures of the present invention will generally depend on the nature of the compound of the mixture of the invention. Compositions particularly suitable for seed treatment are, for example: A soluble concentrate (SL, LS) D emulsion (EW, EO, ES) E suspension (SC, OD, FS) F water dispersible granules and water soluble Granules (WG, SG) G Water-dispersible powders and water-soluble powders (WP, SP, WS) 凝胶 Gel formulation (GF) I Dust-dissolving powders (DP, DS) These compositions can be diluted Or applied to plant propagation material, especially seeds, in undiluted form. These compositions can be applied to plant propagation material, especially seeds, in diluted or undiluted form. The compositions in question give an active substance concentration of from 0.01% to 60% by weight, preferably from 0.1% to 40% by weight, in the ready-to-use preparation after two to ten times dilution. Administration can be carried out before or during sowing 138195.doc • 61 - 200939963. Methods for applying or rationalizing agricultural compounds and compositions thereof to plant propagation materials, especially seeds, are known in the art and include the application of the propagation material, coating, spheronization, dusting, and soaking. Application method (and in the trench treatment). In a preferred embodiment, the compound or composition thereof is applied to the plant propagation material by treatment such that the seed is not induced, for example by seed dressing, spheronization, coating and dusting. When a material, preferably a seed, is propagated, the application rate of the mixture of the invention is generally used for the formulated product (which typically comprises 1 G g/1 to 75 q... of the active substance). The invention also relates to a propagation product of a plant, and in particular a composition or a mixture comprising two or more active ingredients or a combination of two or more of the compositions as defined above and/or contained therein. A plant propagation material (preferably a seed) of a mixture of (each providing a wounded). The plant propagation material, preferably the seed, comprises a mixture of the invention in an amount of from 0.1 g to 丨〇 kg per 100 kg of plant propagation material, preferably seeds. For example, s, the weight of the compound j herein is preferably in the range of 1 〇〇kg plant © propagation material (preferably seed) 〇 12 〇〇 g, more preferably ι 〇〇 0 plant propagation material (preferably seed) 1 to 2 g and preferably between 1 and 100 g per 1 kg of plant propagation material, preferably seed. For example, § 'The compound π (such as cyclosporine) * ΠΙ (such as thiocarbazone, poker, dexamethasone, daxen) weight is better in each kg of plant propagation material (more Preferably, the seed is 1-200 g, more preferably 5 to 2 g per 100 kg of plant propagation material (preferably seed), and optimally per 100 kg of plant 138195.doc -62-200939963 For the seed) between 5 and 1 〇〇g. For example, in the present case, compound 111 (such as N-(3,,4,5'-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1Η_β is more than 嗤-4- Indoleamine, N-[2-(4,-trifluoromethylthio)-biphenyl]-3·difluoromethyl-1-indolyl-1H-pyrazole-4-cartoamine, N-( 3',4'-di-gas-5-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide (common name: Baisaifen), Ν· [2-(1,3-Dimercaptobutyl)-phenyl]-1,3-dimethyl-5-fluoro-1H-pyrazole-4-carboxamide, Ν-(2·bicyclopropyl -2-yl-styl)-3-difluorodecyl-1-indenyl-1Η-"Bis-4-carbamide (Sida), >^-[1,2,3, 4-tetrahydro-9-(1-mercaptoethyl)-1,4-methylnaphthalen-5-yl]-3-(difluoromethyl)-1-indenyl-1Η-pyrazole-4- Formamide (common name: iso-pyridyl) and [2_(1,3·dimethylbutyl)_3_thienyl]_1_methyl·3_(trifluoromethyl)oxazole-4-decylamine (common name: penthiopyramine is relatively good in weight per 〇〇 〇〇 kg of plant propagation material (preferably seed Hdoo g, more preferably 1 〇〇 kg plant propagation material (preferably seed) 5 to 200 g And optimal for every 1kg of plant propagation material (more Preferably, the seed is between 5 and 1 〇〇g. For example, 'the weight of the compound ΙΠ (such as atropine, baikemin, trifluoro- or acesulfame (especially oxime)) is better. 1 to 2 g of material (preferably seed) per plant, preferably 1 to 50 g per 1 kg of plant propagation material (preferably seed) and optimal per 1 kg of plant propagation material (preferably seed) between 1 and 2 g. The compound of the mixture of the invention is applied independently or in combination by spraying or seeding, seedling, plant or earthworm before or after plant sowing or before or after plant sprouting or Powdering is carried out. The mixture of the invention is contacted (via soil, glass, wall, bed 138195.doc -63· 200939963 and = has a component or animal part) and ingestion ((four) plant part) and the preferred method of application is Human water body 'into the water, through the soil, cracks and gaps, pastures, fertilizer piles, sewers', on the floor, on the wall, or by peripheral spray application and bait. According to another preferred embodiment of the invention, resistance to such as code Ant, termite wasp rope, mosquito a non-crop pest of the butterfly, the genus, or the genus, and the mixture of the invention is prepared as a bait preparation. The museum may be a liquid, solid or semi-solid preparation (such as a gel). _ is a product that is attractive enough to attract insects such as ants, termites, wasps, ropes, mosquitoes, snails, etc. or wefts. The attractant may be selected from foods that are readily known in the art or A pheromone and/or a sex pheromone. The method of controlling insect-borne infectious diseases (such as malaria, dengue and yellow fever, lymphatic filariasis and leishmaniasis) with the mixture of the present invention and its individual compositions also includes a treatment shed House surfaces, air sprays and dipped curtains, tents, clothing items, bed nets, © Tset fly traps or the like. The pesticidal compositions for use in fibers, fabrics, knits, nonwovens, mesh materials or boxes and tarpaulins preferably comprise a composition comprising a mixture of the invention, optionally a repellent, and at least one binder. The mixture of the present invention and compositions comprising the same can be used to protect wooden materials such as trees, wooden fences, sleepers, and the like, as well as buildings such as houses, outbuildings, and work-related materials, as well as building materials, furniture, leather, fibers, and ethylene products. 138195.doc •64· 200939963 Wires and cables are protected from ants and/or termites, B m and are used to control ants and termites from harm to crops or humans (eg volcanic worms: into the house and When in public facilities). In the case of soil treatment or application to pest houses or nests, the amount of active ingredient is from 0.0001 g/1 〇〇W to 500 g/100 m2, preferably 〇〇〇1 g/i 〇"〇m2 to 20g/ L〇〇m2 range. In material protection, the usual application rate is, for example, 0.01 g to 1000 g of active compound per square meter of treated material, ideally per square meter 〇^© to 50 g g of insecticidal composition for impregnating materials. It contains 〇001% by weight to 95% by weight, preferably Oi weight ❶/. Up to 45% by weight, and more preferably 2% to 25% by weight, of at least one repellent and/or insecticide. For use in the bait composition, the active ingredient is typically present in an amount of from 1% by weight to 15% by weight, desirably from 0.001% to 5% by weight of the active compound. The compositions used may also contain other additives such as an artistic solvent for the active substance, a flavoring agent, a preservative, a dye or a bitter agent. Its appeal can also be enhanced by a specific color, shape or texture. For use in the spray compositions, the mixture of active ingredients is present in an amount of from 0.001% by weight to 8% by weight, preferably from 0,01% by weight to % by weight and most preferably from 0.01% by weight to 15% by weight. 138195.doc -65·

Claims (1)

200939963 VII. Scope of application: 1. A mixture comprising a synergistically effective amount of the following as active ingredient: 1) an insecticidal compound I selected from the following receptor agonist/antagonist compounds: Abbott Acetamiprid, clothianidin, dinotefuran, imidacl〇prid, thiamethoxam, nitenpyrani; and 2) selected from A fungicidal compound of the following composition: π: triticonazole, fluquinconazole, prothioconazole, difenoconazole, ipconaz 〇ie), flutriafol and tebuconazole; 3) - or two other fungicidal compounds selected from the group consisting of: thiophanate-methyl, poker Prochloraz, pyraclostrobin, azoxystrobin, trifloxystrobin, oressastrobin, metalaxyl, dimethomorph, 1^ -(3丨,4 ',5'-Trifluorobiphenyl-2-yl)-3-difluoromethyl-1-pyryl-1Η-Π ratio 0 sit-4-cartoamine, N-[2-(4'_ Trifluoromethylsulfanyl)-biphenyl]-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, Ny〆1-digas_5_scrambled biphenyl-2- ))-3-dimethylmethyl-1-indenyl 0 to 0 separaximide (commonly known as bixafen), N-[2-(l,3-dimethylbutyl)-benzene ]]-1,3-dimethyl-5-fluoro-1H-pyrazole-4-decylamine, Ν·(2-biscyclopropyl-2-yl-phenyl)-3-difluoromethyl- 1-methyl-1Η-«Bizozol-4- 138195.doc 200939963 Amine (common name: Saida), Ν-Π, 2,3,4-tetrahydro-9-(1-methyl ) _ 1,4- 1,4-naphthyl-5-yl]-3-(difluoromethyl)-1-methyl-1Η-pyrrole-4-carboxamide (common name: iso-pyrene) and swimming [ 2_(1,3-dimethylbutyl)_3-sodium phenyl]-1-methyl-3-(trifluoromethyl)-1Η-pyrazole-4-carboxamide (* by name.° ratio Penthiopyrad). 2. A mixture of claim 1 which comprises cotinine, edamine or acesulfame as compound I. 3. A mixture according to any one of clauses 2 to 2 which comprises cyclosporin as compound II. 4. A mixture according to any one of claims 1 to 3, which comprises one or two other fungicidal compounds selected from the group consisting of: methylpolyprofen, poker, baikemin, oxime ether Bismuth, vandal, Ν-(3',4,5'-difluorobiphenyl-2-yl)-3-difluoroindolyl_ι_mercapto-1Η_pyrazole_4_ formazan Amine, N [2-(l,3-dimethylbutyl)-phenyl]j, % dimethyl_5_fluoro-1 oxime. Biazole _ 4-decylamine, Ν-(2·bicyclopropyl·2-yl-phenyl)_3_difluoroindolyl-丨-methyl-1Η-pyrazole-4-carboxamide and N- [2-(l,3-Dimethylbutyl)-3.thienyl]-1-methyl-3-(trifluoromethyl)_1Η-pyrazole_4_carbamidamine (common name: pyrithione) Myclonin). 5. A mixture according to any one of claims 1 to 3, which comprises one or two other fungicidal compounds selected from the group consisting of: poker, baikemin, epothilone, and halal And Ν_(3,,4,,5,_Trifluorobenzol-2-yl)-3-difluorodecyl-1-indenyl-1Η-» than olfactory-4-carboxamide. 6. A mixture of hydrazines as a compound I, which comprises as an amine I or a dinidine as a compound I, as a cyclosporin as a compound II, as a compound m, a kekemin 138195.doc 200939963 and a genus. 7. A mixture of claim 1 which comprises Saxon, cyclamate and poker. A mixture of claim 1, which comprises as a compound, edetamine or cannidine, as a compound II, cyclohexazole, as a compound m, and as a poker pull. 9. A mixture comprising a synergistically effective amount of the following as active ingredient: ® 1) an insecticidal compound 1 selected from the group consisting of arsenic; and 2) cyclosporin. A pesticidal composition comprising a liquid or solid carrier and a mixture according to any one of claims 1 to 9. 11. A method of controlling pests and/or improving plant health, wherein (a) the pest, its habitat, breeding ground, its location or the plant, soil or plant propagation material that is awaiting protection from pests; or b) the plant, the locus where the plant is growing or expected to grow, or the plant propagation material from which the plant is grown; treated with an effective amount of a mixture according to any one of claims 1 to 9. 12. A method of protecting plant propagation material from pests, comprising contacting said plant propagation material with a pesticidally effective amount of a mixture of any one of claims -9. 13. The method of claim 12, wherein the mixture of any one of claims 1 to 9 is administered in an amount of from 1 kg of plant propagation material 〇 gi g to 10 kg. 14. The method of claim 11 to 13, wherein compound I and compound II as defined in any one of claims 1 to 9 are administered simultaneously (i.e., jointly or independently) 138195.doc 200939963. 15. A plant propagation material comprising a mixture of any one of claims 1 to 9 in an amount of from 0.01 g to 10 kg per 100 kg of plant propagation material. 138195.doc -4- 200939963 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbolic symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the best display. Chemical formula of the inventive feature: (none) 138195.doc