TW200939960A - Pesticidal mixtures - Google Patents

Abstract

The present invention relates to synergistic mixtures comprising, as active components, pyrimethanil, and an insecticidal compound selected from nicotinic receptor agonists/antagonists compounds and one or two further fungicidal compound(s) in synergistic effective amounts.

Description

200939960 VI. Description of the Invention: [Technical Field] The present invention relates to a synergistic mixture which comprises a synergistically effective amount of the following components as an active ingredient, 1) selected from the following final receptor agonist/antagonist compounds Insecticidal compound - I : acetamiprid, clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram And φ 2) as pyrimamine (pyrimethanil) of compound II; 3) - or two other fungicidal compounds selected from the group consisting of: triticonazole, I 喧Fluquinconazole, prothioconazole, phenyl®| a ring. Difenoconazole, ipconazole, flutriafol, tebuconazole and prochloraz. The present invention further relates to a ternary mixture comprising a synergistically effective amount of each of the following as an active ingredient: ❹ 1) an insecticidal compound I selected from the following nicotinic receptor agonist/antagonist compounds: subctomy, Cannidine, Dartnam, edamine, acesulfame, acesulfame; and 2) two other fungicidal compounds selected from the group consisting of: oxazolidine, fluoroquinazole , prothioconazole, difenoconazole, inobutazole, defoliation, Dekli and poker. The above-mentioned mixture is also referred to as "the mixture of the present invention" hereinafter. 138194.doc 200939960 Furthermore, the present invention relates to a method for controlling pests using the mixture of the invention (this means including animal pests and harmful fungi), and compound compound II and compound m (or a compound as defined above and two compounds) III) Uses for the preparation of such mixtures, and compositions comprising such mixtures. In one embodiment, the invention provides a method of controlling an animal pest, such as an insect, a worm or a nematode, comprising causing the animal pest (insect, coco or nematode) or its food source, habitat, breeding ground or its location to be killed An effective amount of the mixture of the invention is contacted. In another implementation, the invention also relates to a method for protecting a plant from attack or infestation by an animal pest (insect, cockroach or nematode) which comprises killing the plant or the soil or water from which the plant is grown An effective amount of the mixture of the invention is contacted. In addition, the invention also encompasses a method of protecting a plant propagation material from harmful pests, such as fungi or insects, spiders or nematodes, comprising contacting the plant propagation material with a pesticidally effective amount of a mixture of the invention. It should be understood that the term "plant propagation material" means all reproductive parts of plants and vegetatively propagated plants f, such as cuttings ((10) (4) and blocks to (for example, horse yam), i I u ) / for plant proliferation. This includes seeds, roots, fruits, tubers, eight tablespoons of poverty alleviation, "buds, buds and other parts of plants, including seedlings and young plants". They want to emerge after germination or from the soil: young plants can also The term "propagating material" is used to denote seeds by whole or partial treatment by dipping or ploughing prior to transplantation. 4 ^Better embodiment, 138194.doc 200939960 In addition, the present invention relates to a method for controlling harmful fungi using the mixture of the present invention, and Compound I and Compound II and Compound ΙΠ (or Compound I and both as defined above) The use of Compound III) for the preparation of such mixtures, as well as compositions comprising such mixtures. The invention further relates to a plant protection active ingredient mixture having synergistic enhancing effects of improved plant health and a method of applying the mixture of the invention to a plant. [Prior Art] Φ Compounds of the formula I, formula II and formula III and their insecticidal action and their production methods are generally known. For example, commercially available compounds can be found in The Pesticide Manual, 13th Edition, British Crop Protection Council (2003) and other publications. A binary mixture comprising cotinine along with a large number of potential fungicidal mixed collaterals is disclosed in WO 99/63826. A combination comprising acesulfame and a clear disclosure of edetamine together with a large number of potential fungicidal mixed collocations is disclosed in WO 96/3 045. A mixture of cyclosporin and poker is disclosed in EP 467972, EP 466612 and PCT/EP2007/063417. A mixture of cyclosporine and pyrimethanil is disclosed in FR 2742310. A combination of poker pull and pyrimethanil is disclosed in DE 43 1 8372. WO 97/22254 discloses a mixture of cyanosine and azoles such as cyclosporin, pyrimethanil and pram. WO 08/095891 comprises a mixture of cotinine and cyclosporin. WO 06/128655 discloses mixtures of neonicotinoid analogs with several azoles, as well as a large number of insecticides which can be combined with several fungicides. 138194.doc 200939960 WO 06/24333 describes neonicotinoid analog formulations which may comprise at least one other fungicide as the second component. However, specific binary and quaternary mixtures of the present invention based on the compound I and the compound and the compound oxime (or the compound I as defined above and the two compounds oxime) are not explicitly disclosed. Further, there is no mention of a specific combination of the compounds I and II as defined above. A typical problem in the field of pest control is the need to reduce the dose rate of the active ingredient to reduce or avoid adverse environmental or toxicological effects while still allowing effective pest control. Regarding the present invention, the term pest includes animal pests and harmful fungi. Another problem faced is the need for pest control agents that are effective against a wide range of pests (eg animal pests and harmful fungi). It also controls the combination of strong activity and long-term control (ie fast action and long-lasting action). There is a need for the agent. Another difficulty associated with the use of insecticides is that repeated and specialized application of individual insecticidal compounds in many cases leads to rapid selection of pests (which means that animal pests that have produced natural or adapted resistance to the active compound in question and Harmful fungi). Therefore, there is a need for pest control agents that help prevent or overcome resistance. Another potential problem in the present invention is the need for a modified plant composition, a method generally and hereinafter referred to as "plant health". The beta term plant health includes various types of improvements in plants that are not associated with pest control. By way of example, advantageous properties that may be mentioned are improved crop characteristics including: emergence, crop yield, protein content, 138194.doc 200939960 oil content, starch content, more developed roots (modified root growth) ) improved stress tolerance (eg, resistance to drought, heat, salt, uv, water, cold), reduced ethylene (reduced production and/or inhibition of acceptance), tillering, plant height increase, larger Leaves, less dead base leaves, stronger tillers, more green color, pigment content, photosynthetic activity, require less input (such as fertilizer or water), require less plant propagation material (preferably seeds), more Yield • 蘖, early flowering, early glutinous rice ripening, smaller plants falling down (falling), enhanced bud growth, enhanced plant vigor, enhanced plant standing and early and better β germination; or familiar Any other advantages known to the skilled person. SUMMARY OF THE INVENTION Accordingly, it is an object of the present invention to provide insecticidal solutions that address a reduced dose rate and/or enhance the range of activity and/or combine strong activity with long-term control and/or resistance management and/or promote plant health. mixture. We have found that this goal is achieved, in part or in whole, by a mixture comprising the active compounds defined at the outset. In particular, it has been found that mixtures as defined at the outset exhibit significantly enhanced pest resistance compared to the possible control rates of individual compounds, and/or when applied to plants, parts of plants, plant propagation material (preferably Seed) or suitable for improving plant health when it is grown. It has been found that the effects of the mixtures according to the invention are far more durable than the fungicidal and/or insecticidal and/or plant health improving effects of the active compounds present alone in the mixture. In addition, 'we have found that simultaneous (in combination or independent) application of the compound and compound 138194.doc 200939960 compound II and compound III (or compound I and two compounds as defined above) or continuous application of compound I and compound II and compound 111 ( Or the compound I as defined above and the two compounds III) allow enhanced control (synergistic mixture) of pests (which means animal pests and harmful fungi) compared to the possible control rates of the individual compounds. Furthermore, 'we have found that simultaneous application of compound Jf and compound II and compound 111 (or compound I and two compounds as defined above) or compound I and compound II and compound hydrazine (or a compound as defined above) I and the two compounds III) provide enhanced plant health effects (; synergistic mixtures) compared to the possible plant health effects of individual compounds. Preferably, the ternary or quaternary mixture according to the present invention comprises cotinine, edetamine, acesulfame or arsenic, more preferably nicidine, estamide or acesulfame as compound I. The best compound is edetamine or acesulfan. The preferred compound III is β-cyclosporin, flurazepam, prothiotoxin saliva, benzo myroxazole, inobutazole, dimethoate, dekli and poker, more preferably azole ring bacteria, c Thiobacillus and poker pull, the best azoles are cyclosporin and poker pull. It is preferably a ternary mixture of the present invention containing Sai Suam as a compound. It is preferably a quaternary mixture of the invention containing cytosine as a compound hydrazine. Preferred is a ternary mixture of the invention containing edaamine as a compound. It is preferably a quaternary mixture of the present invention containing edaramine as a compound. Preferably, the ternary mixture of the present invention containing cotinine as a compound is used. The ruthenium is a quaternary mixture of the present invention containing cotinine as a compound. Preferred is a ternary mixture of the invention comprising Ila as a compounding worker. 138194.doc 200939960 is preferably a quaternary mixture of the invention comprising Ila as a compound. It is preferably a ternary mixture of the present invention containing lid as a compound. A quaternary mixture of the present invention containing lid as a compound is preferred. A ternary mixture of the present invention containing Ila as a compound is preferred. Preferably, the quaternary mixture of the present invention contains Ila as the compound „. It is preferred to contain the ternary mixture of the present invention as a compound ΙΠ2. It is preferably a quaternary mixture of the present invention containing poker as a compound hydrazine. Cyclosporine is a ternary mixture of the present invention as a compound hydrazine. Preferably, the quaternary mixture of the present invention is contained as a compound III. A ternary mixture of the present invention containing prothioconazole as a compound hydrazine is preferred. Preferably, the quaternary mixture of the invention comprising prothioconazole as a compound hydrazine comprises the weight of each ternary mixture of nicotinic receptor agonist/antagonist compound I, pyrimethanil and one of the other fungicides III. The ratio is i · 丨〇〇: 丨〇〇 to, preferably 50:1:1 to 1:50:50, more preferably 1:20:20 to 20:1:1. Contains nicotinic receptor agonist / The weight ratio of the antagonist ternary mixture of the compound I and the two other fungicides III is 1: 1 〇〇: 1 〇〇 to 1 〇〇: 1 : 1, preferably 50:1:1 to 1: 50:50, better 1:20:20 to 20:1:1. Contains a private receptor agonist/antagonist compound I. The weight ratio of the respective quaternary mixture of spray amine and two other fungicides is 1:100:100: 1〇〇 to 100:1:1:1, preferably 50:1:1:1 To 1:50:50:50, better 1:20:20:20 to 20:1:1:1 化合物About its intended use, compound 1 listed in Table 1 below (where compound 138194.doc 200939960 is赛速安, 达达amine or konidine), compound II (pyrimethamine), one or two compounds III (in which the compound ΠΙ is prothioconazole, cyclohexazole, poker, fluoroquinazole, phenyl ether The following ternary and quaternary mixtures of anthracyclazole, inobutazole, dimethoate or dexamethasone, or a mixture of compound I and two compounds m (wherein the compound is a prothiophenanthine, a ring of bacteria, It is better to use poker, benzene, sputum, sputum, sputum, or squid. In addition to the abbreviations of Table 1, the following abbreviations are used herein: I is compound I π is compound Η iii ( i) is compound m 111 (2) is the second compound in A is 赛速安 B is edetamine C is nicidine PC = thiophene β sitting table 1 τ = cyclosporin Ρ = poker pull F = fluorine喧嗤D = benzene bond A ring CT sitting 1 = inoculum F = Tiefen TC = Dickley number R-1 I — II III(1) 111(2) R-2 pyrimethanil P _ A pyrimethanil τ --- — R-3 PC —--------- R -4 -----— τ—^— R-5 ------ A pyrimethanil----^- R-6 IVU A - τ PC R-7 R-8 A — --- --- — ---- ----- ~~~— R-9 B Pyrimethanil P — R-10 B ~~ Pyrimethanil---- τ -—~---- 138194.doc 200939960

No. I II III(1) 111(2) R-ll B Pyrimethanil PC R-12 B Pyrimethanil PT R-13 B Pyrimethanil P PC R-14 BT PC R-15 B - PT R-16 BP PC R -17 C pyrimethanil P R-18 C pyrimethanil T R-19 C pyrimethanil PC R-20 C pyrimethanil PT R-21 C pyrimethanil P PC R-22 C τ PC R-23 CPT R-24 CP PC R-25 A pyrimethanil I R-26 A pyrimethanil IT R-27 A pyrimethanil I PC R-28 AIT R-29 AI PC R-30 B pyrimethanil I - R- 31 B pyrimethanil IT R-32 B pyrimethanil I PC R-33 B - IT R-34 B - I PC R-35 C pyrimethanil I - R-36 C pyrimethanil IT R-37 C Moldy amine I PC R-38 C - IT R-39 C two I PC 138194.doc • 11 - 200939960

No. I II III(1) 111(2) R-40 A pyrimethanil F - R-41 A pyrimethanil FT R-42 A pyrimethanil F PC R-43 A - FT R-44 A - F PC R-45 B pyrimethanil F - R-46 B pyrimethanil F τ R-47 B pyrimethanil F PC R-48 B - F τ R-49 BF PC R-50 C pyrimethanil F - R-51 C Moldy amine F τ R-52 C pyrimethanil F PC R-53 C - F τ R-54 CF PC R-55 A pyrimethanil TC R-56 A pyrimethanil TC τ R-57 A pyrimethanil TC PC R-58 A - TC τ R-59 A - TC PC R-60 B pyrimethanil TC - R-61 B pyrimethanil TC τ R-62 B pyrimethanil TC PC R-63 B - TC τ R -64 B - TC PC R-65 C pyrimethanil TC - R-66 C pyrimethanil TC τ R-67 C pyrimethanil TC PC 138194.doc -12- 200939960

No. I II 111(1) 111(2) R-68 C TC T R-69 C - TC PC R-70 A pyrimethanil D R-71 A pyrimethanil DT R-72 A pyrimethanil D PC R -73 A - D τ R-74 AD PC R-75 B pyrimethanil D R-76 B pyrimethanil D τ R-77 B pyrimethanil D PC R-78 B _ D τ R-79 B - D PC R-80 C pyrimethanil D - R-81 C pyrimethanil D τ R-82 C pyrimethanil D PC R-83 C - D τ R-84 C - D PC In these mixtures, the following mixtures Particularly preferred: Rl, R-2, R-3, R-4, R, 5, R-6, R-7, R-8, R-9, R-10, R-ll, R-12 , R_13, R-14, R-15, R-16, R-17, R-18, R-19, R-20, R-21, R-22, R-23 and R-24. Within this subset, the following mixtures are preferred: Rl, R-2, R-4, R-5, R-7, R-8, R-9, R-10, R-12, R-13 and R -15, and the following mixtures are more preferred: Rl, R-2, R-4, R-7, R-9, R-10, R-12 and R-15. The mixtures of the invention may additionally contain one or more insecticides, fungicides, 138194.doc • 13-200939960 herbicides. For use in accordance with the present invention, the mixtures according to the present invention can be converted into conventional formulations such as solutions, emulsions, suspensions, powders, powders, pastes and granules. The use form depends on the particular intended purpose; in each case it should ensure a fine and uniform distribution of the mixture according to the invention. Formulations are prepared in a known manner (see US 3,060,084, EP-A 7〇7 445 (Liquid Concentrate), Browning: "Agglomeration", Chemical

Engineering, December 4, 1967, 147-48, Perry's Chemical

Engineer's Handbook, 4th edition, McGraw-Hill, New York, 1963, S. 8_57 and subsequent content, WO 91/13546, US 4,172,714, US 4,144,050, US 3,920,442, US 5,180,587 'US 5,232,701 ' US 5,208,030 'GB 2,095,558 ' US 3,299,566 > Klingman: Weed Control as a Science (J. Wiley & Sons,

New York, 1961), Hance et al.: Weed Control Handbook (8th edition, Blackwell Scientific, Oxford, 1989) and Mollet, H. and

Grubemann, A. :Formulation technology (Wiley VCH Verlag, Weinheim, 2001)) o Agrochemical formulations may also be included as a customary adjuvant in agrochemical formulations. The auxiliaries used depend on the particular application form and the active substance. Examples of suitable auxiliaries are solvents, solid carriers, dispersants or emulsifiers (such as other solubilizers, protective colloids, surfactants and adhesives), organic and inorganic thickeners, bactericides, antifreeze agents, defoamers , where appropriate, a colorant and a tackifier or binder (eg, for seed treatment formulations). Suitable solvents are water, organic solvents, such as minerals with medium to high boiling point 138194.doc •14· 200939960 oil fractions, such as kerosene or diesel, in addition to coal tar and oils of vegetable or animal origin; aliphatic, cyclic and aromatic a hydrocarbon such as toluene, xylene, stone butterfly, tetrahydronaphthalene, alkylated naphthalene or a derivative thereof; alcohol such as methanol, ethanol, propanol, butanol and cyclohexanol. _, such as cyclohexanone and 丫-butyrolactone; fatty acid dimethylamine, a fatty acid and a fatty acid ester, and a strong polar solvent such as an amine such as N-methylpyrrolidinium. The solid carrier is mineral soil, such as Shiqi acid vinegar, Shixi gum, talc, kaolin, limestone, lime, white H, red basalt, loess, clay, white clouds.

Stone, diatomaceous earth, sulfuric acid, sulfuric acid, oxidized town, ground synthetic materials, fertilizers, such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea and plant-derived products, such as flour, bark powder, wood chips and nut shell powder, Cellulose powder and other solid carriers. Suitable surfactants (adjuvants, wetting agents, tackifiers, dispersants or emulsifiers) are aromatic sulfonic acids (such as lignin sulfonic acid (Borresperse type 8,

Borregard, Norway), phenolsulfonic acid, naphthalenesulfonic acid (Morwet 8 type, AkZ0 Nobel ' U.S.A.), dibutyl naphthalenesulfonic acid (Nekal® type, BASF,

Germany)) and alkali metal, alkaline earth metal and ammonium salts of fatty acids; alkyl sulfonates, alkyl aryl acid esters, alkyl sulfates, lauryl ether sulfates, fatty alcohol sulfates and sulfated cetyl alcohol Ester, heptadecyl ester and stearyl alcohol, sulfated fatty alcohol glycol ether, in addition to condensate of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethylene octylphenyl ether, ethoxylated isooctane Phenol, octylphenol, nonylphenol, alkylphenyl polyglycol ether, tributylphenyl polyglycol ether, tristearyl phenyl polyglycol ether, alkyl aryl polyether Alcohol, alcohol and fatty alcohol/ethylene oxide condensate, ethoxylated castor oil, polyoxyethylene 13S194.doc 15 200939960 olefinic group, ethoxylated polypropylene oxide, lauryl polyethylene glycol ether shrinkage, Sorbitol ester, lignin sulfite waste liquor and protein, denatured protein, polysaccharide (eg thioglycol), hydrophobic modified starch, polyvinyl alcohol (Mowiol® type, Clariant, Switzerland), poly-sour vinegar (Sokolan® type, BASF, Germany), polyalkoxylate, polyvinylamine (Lupasol® type, BA) SF, Germany), polyvinylpyrrolidone and copolymers thereof. Thickeners (i.e., compounds which impart a modified fluidity to the formulation, i.e., a compound having a high viscosity under static conditions and a low viscosity during agitation) are polysaccharides and organic and inorganic clays, such as three. Xanthan gum (Kelzan®, CP Kelco, USA), Rhodopol® 23 (Rhodia, France), Veegum® (R, T. Vanderbilt, USA) or Attaclay® (Engelhard Corp., NJ, USA). A bactericide may be added for the preservation and stabilization of the formulation. Examples of suitable bactericides are based on the following: bisphenol and benzyl alcohol hemiacetal (Proxel® from ICI or Acticide® RS from Thor Chemie and Kathon® MK from Rohm & Haas) and isothiazole Derivatives of ketones, such as ketones and benzopyrene (from Acticide® MBS from Thor Chemie). Examples of suitable anti-aging agents are ethylene glycol, propylene glycol, gland and glycerol. Examples of antifoaming agents are polyoxynoxy emulsions (such as Silikon® SRE, Wacker, Germany or Rhodorsil®, Rhodia, France), long chain alcohols, fatty acids, salts of fatty acids, fluoroorganic compounds and mixtures thereof. Suitable colorants are low water soluble pigments and water soluble dyes. To be mentioned 138194.doc • 16· 200939960 Example is the name rhodamine B (rhodamin ^ τ & ^ , ^ 4t C.1. Pigment Red 112, CI Solvent Red 1, Pigment Blue 15:4, Pigment Blue Η , , ,Supervisor 15:3, Pigment Blue 15:2, Pigment Blue 15:1, Pigment Blue 80, Pigment Astragalus, Yan λ 0 Shoulder only 13, Pigment Red 112, Pigment, Worker 48:2, Pigment Red 48:1, Pigment Red 5 ._ .1, Pigment Red 53:1, Pigment Dial 43, Pigment Orange 34, Pigment Orange 5, Yan.^,, Pigment Green 36, Pigment Green 7, Pigment White 6, Pigment Brown 25, alkaline purple 10, test, 丨 陵 兔 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49 49

Examples of tackifiers or adhesives are polyvinylpyrrolidone, polyvinyl acetate vinegar, polyethyl gestitol and cellulose shim (Tylose8, yangbu (10) (four) granules, spreads (four) and powders can be mixed or Simultaneously grinding the compound! and/or hydrazine and, where appropriate, other active substances with at least one solid carrier. The granules can be prepared by combining the active substance with a solid carrier, such as coated granules, impregnated granules. Agents and granules. Examples of solids are mineral soils such as tannins, phthalates, talc, kaolin, American activated clay, limestone, lime, white peony, red basalt, loess, clay, dolomite, and diatom Soil, barium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, and plant-derived products such as flour, bark powder, wood chips and nut shell powder, cellulose powder and Other solid carriers. Examples of formulation types are: 1 • Types of compositions for dilution with water i) Water-soluble concentrates (SL, LS) I38194.doc 17 200939960 ίο重量份本The compound was dissolved in a mixture of bright 9〇 parts by weight of water or a water / co-I · green / Mixture. Instead, a wetting agent or other auxiliaries are added. After dilution with water, the active substance is dissolved.卩This side <, a formulation having an active substance content of 10% by weight is obtained. Ii) Dispersible Concentrate (DC) A compound of the present invention in a mixture of 20 parts by weight is dissolved in 7 parts by weight of cyclohexanone while adding a part by weight of a dispersing agent such as polyethyl hydrazine beta. The dispersion was diluted with water to obtain a dispersion. The active substance content was 20% by weight 〇/〇. Iii) Emulsifying concentrate (EC) 15 parts by weight of a compound of the invention mixture is dissolved in 75 parts by weight of one toluene, while adding calcium dodecylbenzenesulfonate and castor oil ethoxylate (in 5 parts by weight in each case). Dilute with water to give an emulsion. The composition has an active substance content of 15% by weight. Iv) Emulsion (EW, EO, ES) 25 parts by weight of a compound of the invention mixture is dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each In the case of 5 parts by weight). This compound was introduced into 3 parts by weight of water by means of an emulsifier (Ultraturrax) and made into a uniform emulsion. Dilute with water to know the emulsion. The composition has an active substance content of 25% by weight. v) Suspension (SC, 〇D, FS) 2 parts by weight of the compound of the present invention is pulverized in a stirred ball mill while adding 10 parts by weight of a dispersing agent and a wetting agent and 7 parts by weight of water or organic The solvent is used to obtain a fine active substance suspension. Dilute with water to obtain a stable suspension of live 1·biomass. The active substance content in the composition is aggravation 138194.doc 200939960% by weight Ο V1) water dispersible granules and water-soluble granules (WG, SG) The compound of the mixture of the present invention is finely ground, and the weight of the wound is dispersed. The agent and the wetting agent are prepared as water-dispersible or water-soluble granules by means of technical electrical equipment (for example, dusting, spray tower, fluidized bed), and are diluted with water to obtain a sputum dispersion or solution of the active material. The composition has an active substance content of 50% by weight. Vii) Water-dispersible powder and water-soluble powder, sp, ss, ws) 75 parts by weight of the sigma of the mixture of the invention is ground in a rotor-stator mill while adding 25 parts by weight of a dispersant, a wetting agent and a silicone. Dilute with water to obtain a mash dispersion or solution of the active material. The active substance content of the composition was 75 weight. /〇» viii) Gel (GF) In a stirred ball mill, 20 parts by weight of the compound of the present invention is pulverized while adding 10 parts by weight of a dispersing agent, hydrazine by weight of a gelling agent humectant and 70 parts of water or organic The solvent is used to obtain a fine suspension of the active substance. Dilution with water gave a stable suspension of the active substance, whereby a composition having 20% (w/w) of active substance was obtained. 2. Type of composition to be applied in undiluted form ix) dusting powder (DP, DS) 5 parts by weight of the compound of the invention mixture are finely ground and intimately mixed with "parts by weight of fine powdered kaolin." A dusting composition having an active substance content of 5% by weight. X) granules (GR, FG, GG, MG) 138194.doc -19· 200939960 0.5 parts by weight of a compound of the mixture of the invention finely grinded Agent association. The current method is extrusion, ^ fog drying or fluidized bed. This gives an active substance content of 〇 5 wt. / granules used. From undiluted form xi) ULV solution (UL) (iv) parts by weight of the compound of the mixture of the invention are dissolved in (iv) parts by weight of an organic solvent: for example xylene. This gives a composition which is applied in undiluted form at an active substance content of 10% by weight. Agrochemical formulations generally comprise Between 0.01% by weight and 95% by weight 'preferably between (M% by weight and 90% by weight) is preferably between 5% by weight and 9% by weight of active substance. 1〇〇%, preferably 9 states to 100% (according to N The purity of the MR spectrum is the compound of the mixture of the invention. The compound of the mixture of the invention can be used as it is by means of spraying, atomizing, dusting, spreading, brushing, dipping or pouring, or in the form of its composition. 'For example, in the form of a direct sprayable solution, a powder, a suspension, a dispersion, an emulsion, an oil dispersion, a paste, a dusting product, a spreading substance or a granule. The application form is entirely dependent on the intended purpose; It is desirable in each case to ensure the finest possible distribution of the compounds present in the mixture of the invention. The aqueous application form can be prepared by adding water from an emulsion concentrate, a paste or a thirsty powder (sprayable powder, oil dispersion) For the preparation of emulsions, pastes or oil dispersions, the substance f which is as it is or dissolved in an oil or solvent can be homogenized in water by means of a wetting agent, a tackifier, a dispersing agent or an emulsifier. a concentrate consisting of an active substance, a wetting agent, a tackifier, a dispersing agent or a milk and, if appropriate, a solvent or an oil, and such concentrates are suitable Dilution with water. The concentration of the active substance in the ready-to-use preparation can vary within a relatively wide range. Generally, it is from 0.0001% to 10% by weight, based on the weight of the compound of the present invention, preferably 0.001% to 1〇/〇. The compound of the mixture of the invention can also be successfully used in an ultra-low-volume process (ULV), which may apply a composition comprising more than 95% by weight of active substance, or even without additives In the case of application of the active substance. Various types of oils, wetting agents 'adjuvants, herbicides, fungicides, other insecticides or fungicides can be added to the active compound, as appropriate until immediately before use (slot) mixing). These agents may be mixed with the compound of the present invention in a weight ratio of from 1:100 to 100:1, preferably from 1:10 to 10:1. The compositions of the present invention may also contain fertilizers such as nitrates, ureas, potassium carbonates and perphosphates, phytotoxins and plant growth regulators and safeners. It may be used in sequence or in combination with the above-mentioned compositions, and may be added only shortly before use (tank mixing). For example, the plants can be sprayed with the compositions of the invention before or after treatment with the fertilizer. The compounds contained in the mixture as defined above may be administered simultaneously (i.e., jointly or independently) or continuously, and in the case of separate application, the sequence generally has no effect on the results of the control measures. According to the invention, it is to be understood that the compounds I and II and the compound πι (or the compound I and the two compounds III as defined above) represent at least the compounds I and II and the 138194.doc -21 - 200939960 compound III (or as defined above) Compound J and both compounds are present in an effective amount at the site of action (ie pests such as harmful fungi and animal pests to be controlled, such as insects 'spiders or nematodes, or their habitats, such as infested plants, plants) Propagating material (especially seeds), surface, material or soil 2 and plants, plant propagation material (especially seeds), soil, surface, material or space to be protected from fungal attack by simultaneous (for example with a trough) In the form of a combination) or independently, D or a continuous application of Compounds I and II and Compound 111 (or Compound J as defined above and two Compounds III), wherein the time interval between individual administrations is selected to ensure first administration The active substance is still present in the active site in a sufficient amount at the time of application of the other active substance. The order of application is not critical to the work of the present invention. In the ternary and quaternary mixtures of the invention, the weight ratio of the compound will generally depend on the identity of the compound of the mixture of the invention. The compounds of the mixtures of the invention may be used individually or may be partially or completely mixed with each other to prepare according to the invention. Compositions. It may also be further packaged and used in the form of a combination composition, such as a kit of parts. In one embodiment of the invention, a 'set may include one or more (including all) that may be used to prepare a target agricultural product. A component of a chemical composition. For example, a kit may include compounds I and II and a compound (or a compound as defined above and two compounds III) and/or an adjuvant component and/or another insecticidal compound. (eg insecticide or herbicide) and/or growth regulator component. One of the components may be combined or pre-formulated. In the case where two or more components are provided in the kit, In embodiments, the components may have been combined and sealed as such 138194.doc • 22· 200939960 in a single container such as a vial, bottle, can, pouch, bag or can. In other embodiments Two or more components of the kit may be individually packaged, ie, not pre-provisioned. Thus, the kit may include one or more separate containers such as vials, cans, bottles, sachets, bags or cans, Each container contains a separate component of the chemical composition for I. The components of the kit can be used in two forms separately or together with or for the preparation of a composition according to the invention. The composition is administered in the form of a component. The user typically applies the composition according to the invention from a pred dose device, a piggyback spray device, a spray tank or a sprinkler. In this document I, the agrochemical composition is The water and/or buffer is formed to the desired application concentration, and other auxiliaries may be added as appropriate, and thus a ready-to-use spray liquid or agrochemical composition according to the present invention is obtained. The effective area per hectare is usually applied from 50 liters to _ liters, preferably (10) liters to full liters of ready-to-use spray liquid. According to one embodiment, the individual compounds of the present invention formulated as a composition (or formulation), such as a portion of a kit or a portion of a ternary or quaternary mixture, may be mixed by the user himself in a spray tank, and suitably Additional auxiliaries (tank mix) can be added. In another embodiment, the individual compound or partially pre-mixed component of the mixture of the invention formulated as a composition, for example, a component comprising a compound coffee and a compound hydrazine (or a compound as defined above and two compounds HI) may be The user mixes in the spray tank and may add other auxiliaries and additives (tank mix) as appropriate. In another embodiment, the individual component or portion of the composition according to the invention is 138194.doc -23-200939960, premixed component, for example comprising compound 1 and π and compound hydrazine (or compound I as defined above) The components of the two compounds III) can be combined (for example after tank mixing) or continuously. As indicated above, the invention comprises a method of controlling pests (meaning animal pests and harmful fungi), wherein the pest, its habitat, the breeding ground, its location or the plant to be protected from pests are treated with a pesticidally effective amount of a mixture. , soil or plant propagation material (preferably seed). Advantageously, the mixtures according to the invention are suitable for controlling the following fungal plant diseases: ornamental plants, vegetables (for example Candida albicans (L. c.) and) and hollyhocks (for example, Brassica albicans (white on A) Rust spp.) (white rust); vegetables, canola (Alternaria alternata (child or Brassica sp.), beet (Alternaria alternata (儿k(10)以)), fruit, rice, soybean, horse yam (such as Alternaria solani μ/(10)/) or Alternaria alternata (I a/ier „aii〇), tomato (such as the cross Sporozoites or Alternaria ssp.) and wheat sPP.) (Alternaria spp.); Aphanomyces SPP. on beets and vegetables; alfalfa and vegetables The upper shell of the genus Spp.) 'for example, the wheat sclerotium on wheat is charcoal disease) and the barley husk on the barley (Ji Yulai (for example, Yuxi Gong snail snail (/>. Machiyama»), mites (for example, wheat root rot umbilical snails hold 0 vertical: spot disease), rice (such as rice flat umbilical scorpion. (10) (4)) and turf on the turf (8) > ο / α...spp ) Umbilical hernia Genus SPP.) (teleomorph: Helicobacter (Coc; ^ 〇 6o / wj spp.)); cereals (such as wheat or barley) of the grass 138194.doc •24- 200939960 White powdery mildew (gram/wb 5/wmeria) (formerly known as powdery mildew (grawim)) (powder disease); fruits and berries (such as strawberries), vegetables (eg, lettuce, carrots, celery and cabbage), Rape, flower, vine, forest plant and Botrytis cinerea on wheat (jgoiryih ckere < 3) (sex type: Botrytis cinerea (5oir_yoiz_m_a: gray mold); lettuce on lettuce / aciwcae) (downy mildew); broad-leaved tree and long-shelled scorpion on the evergreen tree, synonymous with Phytophthora capsici (ap/n_cm〇ma)) (rot or wither wilting), such as eucalyptus Clam shell (C. m/w〇 (Dutch eucalyptus); corn, rice, sugar beet (eg beet brown spot disease (C., sugar cane, vegetables, coffee, soybeans (eg soybean gray spot pathogen (C. *?〇7 ·ζ·«α) or Kikuchi's spot disease (C. A:z'A:Mc/n)·)) and the genus Cercojpora spp. (soybean leaf spot) ; Fanzhuang (such as F. sylvestris (C. / w / vwm): leaf emblem) and the buds of the genus (C / ac / ospor / ww spp.), such as black buds on wheat Mildew (C. (black ear); ryegrass on cereals (C/avkepi prpwrecO (ergot); corn (Ccar sylvestris (c car) (10)), scorpion (eg Helminthosporium (c), anamorph: wheat root rot, and larvae (eg, Helminthosporium) (C. claw yarn with (10) (10) is 'deformation: rice larvae ( // 〇r:)) on the Helicobacter pylori (deformation. Spirulina spp. (//^/讲/^; 2〇1^〇^^历〇f 5z>o/arz\〇 ) genus (leaf spot); cotton (such as cotton thorn spores (C., corn (such as C. graw (6) co / c?)), soft fruit, horse yam (such as sphaerocephala (C. coccoA·?): dark spots), beans (such as Phytophthora sinensis (c and soybeans (such as cockroach (c. irw«caiww) or 138194.doc -25. 200939960 wins the thorns (C. g /oeosporio/i/e·?)) C. sinensis (CW/eioiWc/zww) (sexual type: charcoal pathogen (G7owere//a)) genus . Corifciwm spp., such as Fusarium oxysporum (C. (Exo sheath wilt); Casochomycetes cajW/co/a on soybeans and ornamental plants) (leaf spots) Cyclospora (C>c/oco«iwm spp.), such as the olive peacock (C. o/eagiwwm) on olive trees; fruit trees, vines (eg Liriodendron chinense (C. liriodendri) >Sexual type: Phytophthora capsici (A/>o«eciWa/Buhuaxin)/): Black Foot Disease and A. faecalis on ornamental plants (For example, if the tree rots or the ivy declines, there is a sexual type: iVeciria spp. or Weowecir/a spp.); the deuteromycete on soybean (Dewaiop/zora «ecairix (Sexual type: Phytophthora (root and stem rot); genus Dz'apori/je spp., such as soybean black spot disease on soybean (Ζ>·p/mseo/orww) (damping off); corn, cereals (such as barley (such as barley bacillus (D. ieres), net blotch) and wheat (such as wheat bacterium (£). to 〇 /-re Corpse πίζ,): 椋 brown spot)), rice and grass In the upper umbilical snail (synonym spirospores, sexual type: nucleomonas (i^yrewop/zorat)) genus; esculent plants on Esca (top blight, stroke), which consist of spots Formitiporia pwwciaia (synonym Pseudomonas sinensis (Carcass / " 仙5 punctata) 'M. squad (F· wei / herranea), thick Puccinia (/? / ?<3日0所0«/€//<3<7/7/<3 lecture>^〇15/?£)广<3) (formerly known as the thick bottle emblem {Phaeoacremonium chlamydosporum) ) 'Phaeoacremonium aleophilum' reverse / good $i genus 138194.doc -26- 200939960 caused; pome fruit (Pear cancer cystitis (5. /?_yri)), soft fruit ( E. H. sp. (E. H. sp.); Phytophthora indica (·Ε«〇^/σ^α or; vzae) (leaf smut); black bacterium of the genus Black bacterium (five picoccwm spp.) (black mold); beet (beet white powder) Bacteria (f. fteiae), vegetables (such as cowpea powdery mildew (five ρ·ί〇), For example, the genus of the genus Polygonaceae (such as the genus Bacillus subtilis (five ci'c/^racearww)), cabbage, rapeseed (such as cruciferous powdery mildew (£. © crwci/erarww)) >>^ζ·/?/ζ6 spp.) (powder disease); Curvularia on fruit trees, vines and ornamental trees (five wi_y/?<3 /αία) (Eutypa canker) Or top blight, deformation: Cytosporina lata (synonym, Z^eWe//a fe/ep/zarh); snails on corn (£x«sero) /n7MW) (synonymous snail) genus (such as corn burrows (5. iwrdcw / w)); various plant sputum (sexual type: Gibberella (Gi06ere / / a)) genus ( Wilt disease, root or stem rot), such as Fusarium graminearum (F. or F. culmorum (plate rot, scab or head withered) on tomato (eg wheat or barley), tomato Fusarium oxysporum (F. ox>^/7〇rww), Fusarium oxysporum (_F. ·5〇/α«ί) on soybean and Fusarium oxysporum on corn (F. verizW/Z/oWei ); cereals (such as wheat or barley) and corn on corn Capsule (GaeMmawwo/wyee·? graw/wh) (take-all); cereals (such as G. zeae) and rice (eg, M. aureus (G. /) wjr7A: Mn9〇: Bakanae disease) Gibberella (GAZ> ere//at spp.); vines, pome fruits and other plants on the circumference 138194.doc -27- 200939960 Shellfish (G/owere//a ci/^w/αία) and cotton anthracis (G. gowxpzj) on cotton; grain-staining complex on rice; staphylococcus aureus on vine Gwz'gwarAo! ά Wwe//z'/) (black rot); Caiweaceae plant and rust fungus spp.), such as Sabina rust on pear (G. (rust); corn , mites and long worms on rice (synonym umbilical genus, genus: spores. genus); rust genus, such as coffee _ Shangzhi coffee riding ore bacteria (//· να·? Ίαίη·χ)(Cai_Ye recorded disease); Phytophthora infestans on the vine (synonym buddha νζίίί); Soybean and cotton on the bean sclerotium (synonym Bean globulin (ρ/ζαπσΗ« )) (root and stem rot); For example, wheat or barley) is a mva of Chrysosporium) (synonymous Fwiariwm m.va/e) (Pink snow mold); Microsphaera Diffuse) (powder disease, ', exhaust rot bacteria spp〇, such as stone fruit and other plants of the genus Rhododendron (M. / axa), fruit plexus stalk 〇) and brown rot fungus (Μ· /rM£^ge«c〇 (flowers and twigs withered 'brown rot); mites, bananas, soft fruits and groundnuts on the genus Spp.) 'such as M. gramim_cc?/a on wheat (M. gramim_cc?/a) (deformation: Sepia sp. sp. (Sepiorz.a Wiz.c〇, shell needle spotted or fragrant on Fiji luminosporin (from . black banana leaf) Spot disease; cabbage (eg, Brassica campestris (household, rapeseed (eg parasitic downy mildew (household.Mrcw7/c")), onions (eg onion downy mildew (household, heart price)), tobacco ( Tobacco downy mildew (household Μα(10)α)) and soybean (such as soybean downy mildew (household like AwWca)) on the cream 138194.doc -28 - 200939960 mold fungus) (grape downy mildew); soybean rust on soybean ( Phakopsofa pachyrhizi) anti-S·Glue rust (Ρ. meibomiae) (Jiudou Mine); for example, in vines (eg lemon dry blight (Hui irac/2e (p/u7a) and B. sylvestris (P. Ieiraspora)) and soybean (eg, Pleurotus ostreatus (P.: stem rot) on the genus Pleurotus • (P/^a/op/iora spp.); Brassica napus on cabbage and cabbage (P /zowa (roots and stems rot) and beet polymyxa (feline) on the beet (root rot, leaf spot and moist rot); sunflower, vine (eg grape ©© uniaxial mildew (house · Wiko/α ): rods and leaf spots) and soybeans (eg stem rot: Phytophthora sojae (hu.p/mseo/z·), sexual type: soybean black spot disease (Dz'apori/ie ρ/ϊακο/orww)) Pseudomonas genus (P/iowo/m··? spp.); brown spot disease of corn brown spot on corn; various plants, such as red pepper and cucurbitaceae (eg Phytophthora capsici (i>. Caphci)), soybean (eg, Phytophthora macrospermia (i> like perwa), synonymous with Phytophthora sojae (P., potato and tomato (eg Phytophthora infestans (/>.: late blight) and broadleaf trees For example, Phytophthora sojae (raworwm): Phytophthora spp.) (wild wilt, root, leaf, fruit and stem rot); cruciferous on cabbage, canola, radish and other plants Rhizoctonia genus (P/aiwo mountain 'op/zora △ rai> sz'C £7e) (root nodule disease); P/asmopara spp., such as Phytophthora variabilis (P) WHC0/a) (vinevine grape downy mildew) and sunflower dew on sunflower (household; Rosaceae, hops, pear fruit and soft fruit on the silky single-shelled genus SPP.) (white powder Disease), such as apple powdery mildew on the apple (/>. /ewcoirz'c/m); 138194.doc •29 200939960 For example, cereals (such as barley and wheat (polymyx sinensis (household and beet (beetroot) Mucobacteria (ρ. Plus))) Polymyxa (Po/state spp) and viral diseases transmitted therethrough; wheat-based rot fungi on alfalfa (eg wheat or barley) ( household • sewc/ocercc ^pore/b Eye point, sexual type: Phytophthora ("Insulinica"; Pseudomonas on various plants (PJeWc/〇/^r(10) like P〇ra) (Grape downy mildew) For example, the Cuban fake cream emblem on the cucurbitaceae plant (P. cwftewj! '>s) or the hibiscus on the hops, the cream emblem (/> humili), the grape horn spot on the vine Pathogen iPseud〇pezicu!a red fire disease or Roche disease (1 >〇化1> such as 11^), deformation: Phytophthora (Ρ/π·α/0ρ; 20~)); on various plants Of the genus spp.) (rust), such as cereals (such as wheat, barley or rye) and asparagus (such as the genus of the genus Stem (/> brown rust (the brown or leaf rust of the plant), Puccinia striiformis (household iiW (/brw^) (striped or yellow money disease), Puccinia striiformis (p, Aor£/e/) (dwarf rust), P. grisea (p grflmimj) (stem or Black rust) or leaf rust (household rec__7a) (brown or leaf rust); Phytophthora infestans on wheat (〇_〇ρ(6)α r-n along) (deformation: Neisseria pallidum) (tan Spotted) or Helicobacter pylori (网. ierw) (net spot) on barley; Pythium genus (ρ Less Wcw/flrii2 spp), such as rice blast fungus (p. zae) on rice (sexual) Type: Magnaporthe oryzae (Mag«叩g^ea) 'rice fever' and grass Magnaporthe oryzae (/>_gWaa) on skin and cereal; turf, rice, corn, wheat, cotton, canola, geranium, soybean, sugar beet, vegetables and various other plants of the genus Pythium spp·) Wet and decay (for example, Pythium ultimum (R aphcmidermatum); Phytophthora genus (Ramu! aria 138194.doc • 30· 200939960 spp.) 'For example, the gelatin Signin column on barley Spores (and c〇//〇_叮 〇 〇 柱 生理 生理 生理 生理 生理 生理 生理 生理 生理 生理 生理 生理 生理 生理 生理 生理 生理 生理 生理 生理 生理 生理 生理 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( , vegetables and various other plants on the genus Rhizoctonia spp.), such as Rhizoctonia solani on the soybean (brother • so / am ·) (root and stem rot), Rhizoctonia solani (outer rice) Sheath blight) or • Rhizoctonia cereals on wheat or barley (where cerea/^) (Rhizoctonia spring blight); strawberries, carrots, cabbage, © vines and tomatoes Rhizopus oryzae (black mold, soft rot); barley grisea on barley, rye and black wheat (Rhynchosporium se Calis) (邋焦,) 稻 帚 ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory ory Such as rapeseed, sunflower (such as Sclerotinia sclerotiorum (& sc/er (10) (10))) and soybean (for example, sclerotium (Sr〇 / 〇 〇 or sclerotium sclerotiorum bacteria) (SepioWa spp.), such as soybean brown rot (*S. brown spot) on soybean, wheat sphaeroides (& ir/i(6)) on wheat (shell acne), and the stalk on the grain & n〇d〇rum (synonym SYagowojpora nodorum) (Stagonospora blotch); crocheted shell on the vine (%-« /«)(Synonym powdery mildew (five-(four)W continued white powdery mildew, deformation: grape powder spores (〇MC iMC/^r〇); corn (such as corn leaf spot (& iwrc/CMW), synonymous corn Helminthosporium turcicum) 萆 斛 斛 屣 屣 138194.doc -31 - 200939960 (Heart iaspaerk spp.) (leaf blight); corn (such as silk smut (s: silk smut), sorghum and sugarcane on the genus Phytophthora (5^/mce/oi/jeca spp.) (smut) / scorpion scorpion on the cucurbitaceae plant Zaeroi/zeca /w" to powdery mildew); potato powdery mildew j (whitefly disease) on the potato and the viral disease transmitted by it, the genus SiagOwospora spp. For example, the sclerotium on wheat (& «oc/orwm) (sclerotium sclerotium sclerotium serotype). Ascomycobacteria «oi/orww" [synonym wheat leaf blight «oc/orwm )] » Potatoes on the potato squamous cell carcinoma (does e«i/oWoiz'crw; n) (potato cancer); ectobacteria spp.), such as the genus of the outer sac. Leaf disease) and Lee's outer bacterium on the plum (7: prwm·) (Li bag fruit disease). Tobacco, pome fruits, vegetables, soybeans and cotton on the genus Xanthomonas (77nWaWop^ Spp.) (black root rot), such as Pythium fuliginea (Γ. hhco/flK Synonyms cerevisiae (c/za/ara) e/egaws)); genus Phytophthora (77//ei/a spp.) (common smut smut), such as wheat smut on wheat ( 7*. iWi/ci) (Synonymous wheat net awake black bacteria (Τ', , wheat waist bunt) (wheat bunt) and abdomen black stable disease (Τ ', dwarf bunt disease (dwarf bunt) ); wheat on the barley or wheat, snow rot, brown sclerotium (grey snow mold); sphaeroides spp.), such as rye on the rye smut (f / (stem black powder) Disease); the genus Puccinia on the vegetables (in spp·) (clock) 'These vegetables are such as (for example, Bean rust (y 138194.doc -32- 200939960 αρρα山·(3)/加似), synonyms Phytophthora sojae (t/such as e〇/(1) and sugar beet (such as T. 6eiae); cereals (such as barley powdery mildew (t/. (10) heart) and oatmeal black powder Bacteria (".alpha"), corn (such as jade black powder) (C/·talking mountains\〇: corn smut) and black powder fungus on sugar cane (ί/ί...sigh 0 SPP·) (dispersed black powder); apple (such as apple black fungus (κ / (10) Called (10)/(4)) and the genus of the genus Serrata on the pear (heart sPP·) (痂); and the various plants of the genus Verticillium (Keriici///ww2 spp.) (>peripheral disease), Such plants are, for example, fruits and ornamental plants, vines, soft fruits, vegetables and field crops such as strawberries, canola, potatoes and tomatoes on the genus Phytophthora dahliae. The mixtures of the invention are also suitable for use in materials ( For example, the protection of wood, paper, paint dispersions, fibers or fabrics and the control of harmful fungi in the protection of stored products. As for the protection of wood and building materials, pay particular attention to the following harmful truths, ascomycetes, such as long beta Ophiostoma spp., Ceratocystis spp., Aureobasidium pullulan, Sclerophoma spp., Chaetomium spp. Humicola spp., Petriella spp., Trichu Rus spp.); Basidiomycetes, such as Coniophora spp., Coriolus spp., Gloeophyllum spp., Lentinus Spp.), Pleurotus spp., Poria spp., Serpula spp. and Tyromyees spp., Deuteromycetes, such as genus Aspergillus spp.), Cladosporium spp., Penicillium 138194.doc -33- 200939960 (Penicillium spp_), Trichorema spp., Alternaria spp., pseudo-cyan Paecilomyces spp., and Zygomycetes, such as Mucor spp., and additionally in the protection of stored products, the following yeasts are worth noting: Candida spp. And Saccharomyces cerevisae ° for controlling a variety of cultivated plants (such as bananas, cotton, vegetable species (such as cucumbers, beans and cucurbits), barley, grass, oats, coffee, potatoes, corn, fruit species, Rice, rye, soybeans, tomatoes Grape vine, wheat, ornamentals, sugar cane) and a large number of fungi on the (preferably seed) is particularly important in a large number of plant propagation material. The mixture of the invention also exhibits significant effects against animal pests from the following: insects from Lepidoptera, ZepWopiera, such as the small tiger ypd/ow, yellow tigers along the 15th, cotton leaf moth (d/akwa) , Lido genus gemwaifl/k), snail nest moth, Auto 夜 night ^{Autographa gamma) ' ^ J^^^Bupalus piniarius) ' Leaf moth (Cacoec/α, 'Cotton brown tape moth reiz.cw/ a«a), 6rwwaia), Choristoneura fumiferana, Choristoneufa occidentalis, XCirphis unipuncta, apple moth (C>Aa, European pine) Caterpillar pini), Diaphania nitidalis, giant glutinous corn binding (Diatraea gra« mountain, Egyptian diamond money (five hjw/wa), small corn town 138194.doc -34- 200939960 {Elasmopalpus lignosellus), grape moth (Eupoecilia, summer-spotted moth (five veir/α), grainy tiger (Fe/ί/β, big butterfly (Ga//eria me//o«e//a), Li Xiaoxin A (Grapholitha funebrarta), pear ή, Gfapholitha molesta, Heliothis armigera, Bud remorse Organization (// β / ζ · σί / π ·· 5 Wrescrew ·?), The American bollworm (ife / ioi / n ··?, Fill the dish

(Hellula undalis), Hibernia defoliaria, Chinese white moth (/Ϊ7/7Λα«ίΗ<3 cwwea), apple moth (/fypowowewia malinellus), %Keiferia lycopersicella, Wearing a shirt [Lambdina fiscellaria), Laphygma exigua, 叻口_Zewcopiera co^ee/Za, Zewcopiera scitella, Lithocolletis blancardella ), grape fruit small moth, yellow green scorpion (loxojiege sticticalis) 'gypsy moth ί / ζ · · 5_ρ<3"), Lymantria monacha, ^ (Lyonetia clerkella) ' A Curtain A (Malacosoma «ewsirz'a), Mamesiraf ftrashcae, Douglas sinensis (9rg>^a /?56Μί/οί«5Μ^·βίβ), Ostfinia nubilalis, Panolis flammea , red bell preparation {Pectinophora, variegated tiger (·PerzWroma sawcia), squid moth (Ρ / ζα / era Z > wce_p / m / a), potato tuber moth (Phthorimaea operculella), orange squid moth (Phyllocnistis Cz'ire//iz), big cabbage butterfly (Pierz's ftrwWcae) , 绿 绿 绿 {Plathypena scabra), 菜菜织 (Plutella xylostellcf), 夜夜织 (Pseudoplusia z'wc/Mi/e"·?) , potato tuber moth ("ScroWpa/pw/a αόίσ/wia", wheat moth (<S7ioiro guest<3 cere<3/e//a), grape mustard leaf moth (•S^argawoi/n's corpse) i//eria«a), grassworm (Spoi/o/^era/rwgiperiiiJ), Spodoptera litura («Spoc/opiera //iiora/iij, Spodoptera litura (Spodopiera //iwrcr), Loose Moth (77i<3wmaiopoea pz_iyoca/wpa), Green Leaf Moth (7brir0: viridana), Spodoptera litura (TWcAop/wj/a «ί), and Zeiraphera canadensis } Coleoptera (Co/eopiera), such as Pear Gyzy (Jgri/ws 5ί«ΜαίΜ5), DgWoiej /keaiw5, Agriotes obscurus, Amphimallus solstitialis, European rainbow worm (Jwbawc/rwj1 mountain ·5·_ραΓ), cotton boll symbol ^ (^«i/jc^omw·? grandis) > apple flower 曱 (Jw/iowomws poworww), genus Aphthona euphoridae ),red Athous haemorrhoidalis 'Jiowar/α //«earz'j), Blastophagus piniperda, Blitophaga undata, Bruchus rufimanus, paper S · I (Bruchus pborw/w), lentils (·βΓΜ〇/2Μ·5, apple leaf 曱 曱 (Avc/bcws 6eiw/ae), beet big turtle 曱«e6w/〇ia), Bean leaf 曱 (Ceroioma Irzywrcflifl), Ceiom'i/ izwraia, Ceuthorrhynchus assimilis, dark veins (Cewi/zorr/^wc/zws «αρζ·), beet 胫 胫 (C/zaeioenema tibialis), Conoderus vespeftinus, CWocer/ί ai/?arag7·, Ciewz'cera πρ·, Diabrotica/owgz'corm··? ), 半星叶曱(i)z'a6roiica 138194.doc -36- 200939960 •sew/pwwciaia), Twelve Stars (_Dz'aZ?ro"'ca /i-pwwciaiaj, South American Leaf (Dia^ Roiz'ca speciosa) 'Diaftroifco! virgifera' Mexican bean ladybug var/vesi/·?), smoke, grasshopper (Epitrix hirtipennis), Brazil Fu (? Eutinobothrus △ rah / ienW ·), pine weevil a &? Ieiz ··), Egyptian clover protracted as Yue (// ypera, Jing alfalfa weevil posifca), cloud

杉八齿小傻(/ps O^ograp/zws), Zerna bilineata, ticket, Lema me!anopus, horse age set, preparation (Leptinotarsa decemlineata), beet golden needle Insect {Limonius californicus), rice I, [Lissorhoptrus oryzophilus), conformational gas (Me/cz«oiwi·commwm··?), rapeseed (A/igei/ie·? qewew·?), Golden Tortoise (Me/o/owi/m /n'/jpoco^iawz·), Western May Golden Tortoise (Melolontha melolontha), Oulema oryzae, Ortiorrhynchus sulcatus, Strawberry Root曱{Otiorrhynchus ovatus) Horseradish 猿 曱 (/ΆαΜοπ coc/z/eaWae), pear leaf elephant /?_yrz·), rapeseed blue jumper {Phyllotreta chrysocephalcT) 'Paper turtle gold I explosion {Phyllophaga India.), garden Lijin turtle (corporate / / zoriz 'co / a), Phthalocreta nemorum, yellow curved stripe (P / ^ / Zoireiot sirio / αία), Sakamoto Lijin turtle (J °o / 7z7 / Z'a Japow/ca), Sitona lineatus~ and JSitophilus granaria, ropes, mosquitoes (Diptera), such as Aedes aegypti (dei/e·? Aedes albopictus (/iec/es a/Z)〇piciwi), Aedes mosquito (/iec/ei vexaw·?), Mexican orange rope/wi/e«<s), Anopheles sinensis I38194 .doc -37- 200939960 {Anopheles maculipenrtis), Anopheles crucians (Anopheles crucians) 'Anopheles sinensis, Anopheles gambiae ga/w0z'ae), Anopheles stephensi (ziwop/ze/es /ree6orm'), white Anopheles stephensi (d«op/ie/ej /ewcojp/zyrw·?), Anopheles sinensis (dwop/ze/es minimus), Anopheles quadrimaculatus, Jiangtou 1 rope (Ca//ip/iora) Νζϋίΐ), Mediterranean solid rope (Cera"·"···? cap/iaia), sister gold*t (C/zrjKJomyor bezziana), American golden fly (C/zrwowya /?owi«ivora:x:), America Rice water rope (CAr^omya m<3ce//arz'a), middle plaque it t/bca/b), static spot it h/acea), Daxi 洋Yellow iit (Chrysops ai/art"*cw5) ., spiral rope (Coc/j/iom^a hominivorax) 'CowiaWm'a iorg/n'co/α, Cordylobia anthropophaga, Cub/icoic/es /wrews), five-banded Culex pipiens (Cw/ex), Culex pipiens (Cw/ex m-gripa/pw·?), and the library Mosquito (Cw/αC.), CwDeia z'womaia, Cv/beiat me/a«wra, Dacws cwcwrWiae), Dacw«so/eae, Dahwewra _ brassicae 'De/ία antique, wheat rope (Z)e//a £?o<aTci£ Zifl〇, seed rope (De/ία ;?/aiwra), cabbage (De/zcz radicum) ^ K ^{Dermatobia hominis) > ^ WiML^%{Fannia cawicw/arz··?), horse yam Woowyza TWpwwciaia, Gasterophilus intestinalis, Glossina worhiawj, G7〇5i/«ii /?α/ρα"5·, Tongue rope/Mic? z>ei), knee rope (G7〇iW«<3, disturbance angle rope 138194.doc -38 200939960 {Haematobia irritans), Phalaenopsis dive rope (ifap/o mountain equestris), submarine genus (Hippeiates spp .), Hylemyia platura, Hypoderma lineata 'Zepioeowops iorrew, 'Saiz'vae', 'ZaiWowyza ir' (/b/iz_ ), Goat Green Rope (Lwci/z'a caprina) ' ^ 43⁄4 (Lucilia Cuprina), green, green rules {Lucilia

Serz'caia), white poplar (Lycoria peciora), pruritus (Mansonia titillanus) Hessian rope (Ma_yeiio/a deiirwcior), home rope (Mwsca domestica), waste rot rope (MwicMa siarftM/ a”·?), sheep nose rope (Oesirw·? σνζ··5), yellow rope (Opowyza //orww), Swedish straw rope (C^sci«e//a /W〇, beet leaf line) (Pegomya, onion rope (ΡΑο/Ήα, Phorbia brassicae, Phorbia coarctata, silver foot white pheasant (P/z/doiomM·? argeW^pe·?), Columbia stag beetle co/ wmWae), carrot rope (corpse 7<2 rosae), Psorophora discolor, Prosimulium mixtum, Peach fruit fly (Λ/mgo/ei/i1 cera*s〇, apple Solid rope pomonella) 'Sarcop/^aga haemorrhoidalis, Sarco/j/mgo!), bandage (iS7mw"wm W"<3iww), factory for rope c^ /c/iraw), Niu Hong: (Γβ6απΜί ^oWwws), black horse rope (7V^a«w·? airaiw·?), striped horse rope (ΓαάβΤίΜ·? /z'weo/a) and similar rainbow: ( Tabanus similis), Ganbei [Tipula oleracea): T ( (Tipula paludosa), 蓟马 (TT^cmopiero), such as orchid 蓟 138194.doc •39- 200939960 (£>ic/irowoi/zrz&gt ;i, Orchid 蓟马亚种(Dz'c/zromoi/zW/»·? ssp) 'FrankZiniena fusca, rank马{Frankliniella Occident alls'), 花莉马(Frankliniella, orange Hummer (iSWrioi/irz·;?·? czirz·), rice locust (77^φ·ϊ oryzae), southern yellow 蓟马 (77ζ"ζ>·5 /?a/wz·) and smoky horse ( TTzripj tabaci); termites (Isoptera), such as European wood termites (Ca/oiermei //im'co//z··?), yellow-footed termites (Lewcoierme·? //aWpei), golden white Moth {Heterotermes awrew·?), yellow-breasted termites // aW/?ei), Virginia white-streaked Wrgz'm'CMj), Southern European netted termites, and Terwes natalensis anti-home white^(Coptotermes formosanus) ) ', Blattaria-Blattodea' (eg German small germczwica), Asian latitude (·β/αίίβ//α α·5α/π·«αβ), American suspicion (Periplaneta america) Na), ip本大蠊 (Perip/aweia japonica) ' ^ Λ. ^ {Periplaneta 厶, Black-breasted 蠊 {Periplaneta fuligginosa), Australian 蠊 [Periplaneta australasiae) Anti-Oriental Police (Blatta orientalis) '真蝽 ( Hemiptera (Hemiptera), eg green 蝽/n_/are), long hair ew/ewcopierws), tobacco black spotted blind 蝽 {Cyrtopeltis notatus) ' $x. {Dysdercus cingulatus) ' A cotton wool worm (Ayst/ercw · intermedium), wheat Shield H· (Eurygaster / «iegr/ceps), cotton brown cultivar (EMic/n'iiw·? impictiventris), leaf foot edge [Leptoglossus phyllopus), so the grass bee (Lygus ΙίηβοΙαΐ^ "), 138194.doc -40- 200939960 Green blind culture ([Jgws /?raie«jz\s), rice green 蝽 (iVezara νζ> ζ·ί/Μ/α), beet inspection net front (Pjesma quadrata) , Soubea insularis, Thyanta perditor, I 蚜 [Acyrthosiphon o «o6ryc/^i), larch ball money / αηϋ), rat plum horse yam, stupid bean money / aZ> Ae), strawberry roots (々?/n's /or6e5i·), apple money pomi), cotton money gowjp/z·), gooseberry money grojiw/arz'ae), rat li Cai (v 4/?/h_5, Duanju Jucai ("/7/π·>5, Elderberry Finance (^4/?/η··5

Sambuci), sparse 3~ field (Acyrthosiphon pbww), Aulacorthum solani, JBemisia argentifolii, cardwz·), round tail (^rac/^cawi/wi· Ae /icZ/rpi), Peach Black Short Tail (jBrac/^caMi/ws pem'cae), Mei Cai {Brachycaudus prunicola), # M. ^ {Brevicoryne brassicae) 'Capitophorus hornf, cotton worm (Cerosipha gossypii), strawberry hair tube/ragae/bHz·), Cryptomyzus ribis, Dreyfusia nordmanniartae, Drex/Mda piceae, rhyme censored (Djuap/n) raAco/fl), Yanguogou no net money (Z^jaw/acori/zww pjeMi/oio/am·), Ping Pinky (Z^sap/n··? p/a« Iagi«ea), pear tree awning money (/^sap/zb, stupid bean micro-leaf 五 (five mpoizjca /αόαβ), yidalopterus pruni, Hyperomyzus lactucae, long tube (Macrrohp/iMm avewae), Great House (Macros/p/jww euphorbiae) 'MacR〇5ip/zo« rosae, Megowra Wciae, Pear Grass (Me /a« a/?/n'j, 薇薇138194.doc -41 - 200939960 Metopolophium dirhodum, smog (Myzus persicae), winter scallions (ΜγζΜ·? cuca/om_cwi), cherry melanoma ceraW) , Myzws variaw, wormwood (Α^5·σπσνζ·α, brown rice wind (iV7/a/?arvaia /wgew·?), lettuce roots (Pemphigus bursarius)' treatment 'Perkinsiella saccharicida', 麻麻少财((www/ί), MUmu H ma/ί), Psylla pirf, Rhopalomyzus ascalonicus, corn spill management And / / opa / ohp / iwm maic / z · ·?), Rhopalosiphum padf, Rhopalosiphum insertum, ❹ Marais round tail (<S^p/?ap/n ··??ma/α), Mali Yuanwei Cai (Χαρραρ/π··? mali) 'Schizaphis graminum, Avocado singapore {Schizoneura lanuginosa) ' ψ (Sitobion avenae) ' >m white only Trialeurodes vaporariorum, Toxoptera aurantiiand ' grape root nodules (Wiews, temperate bed bugs)

(C/wex /eciw/ar/ws), tropical bed bugs (C/wex /zemipierw·?), old age (/Jec/wWws *yemU), cone bee (7W<3ioma ·?/?/?· ) and the back hunt bee {Arilus critatus) > ants, bees, wasps, ores (Hymenoptera) 'such as Xinjiang leaf bee, tropical leaf moth cep / m / oies), leopard leaf ants Tropical leaf-cutting ants, smooth-leaved ants (Αία laevigata) 'Jiia rc^wsia, six-hole leaf-cutting ants (diia jexi/e«s), Texas leaf-cutting ants (/ίίία iexa«a ), C. cerevisiae (CVemaiogasier ? /? /?.), Lishen (//op/ocaw/iiz m/wwia), frequency fruit bee {Hoplocampa testudinea), kitchen moth (Monomorium 138194.doc -42- 200939960 /?/zaraom'j), fire ants ("SWewopjz·?? gemkflia", external fire ants (Solenopsis invicta), tickets, woven {Solenopsis richteri), southern fire ^ {Solenopsis xyloni) ' It ^ (Pogonomyrmex Barbatus), California red harvest ant (Pogowomyrwex ca/(/br«kw·?), tropical ant (Pheidole megacephcda), taurus (Dasymutilla occidentalis), bumblebee, southern wasp (Rspu/a, common Bee (_Parave5/7w/a vw/g^rij), Western wasp pennsylvanica) ' ^ ^ ^ (Paravespula gerwam.ca), Aphid (Do/z'c々oves/7M/a wacw/αία), yellow border Vejpa cra6ro, Po/ijie·?rwWgz'wosa, CampcmoiMsy/orz'daww·? and Argentine ants (Z«i_wepi7/iewa /zwmi/e),

Total cockroach, cockroach, Orthoptera, such as Acheta domestica, Gryllotalpa gryllo.talpa, Locusta migratoria 'Double band 蚱 (Me /awop/MJ ft/Wiiaiw·?), Red-legged worms/emwrrwferwm), Mexican monuments [Melanoplus wex/ccrwwi·), migrations (Me/a«o/?/M5 scmgwz'm'pe· ?),. Me/imop/wi ipreiwi, Nomadacris septemfasciata, America _ Silver {Schistocerca, Sc/n'siocerca gregarz'a, Moroccan 戟13⁄4. {Dociostaurus maroccanus), iS. ^ ^ ^ {Tachycines asynamorus) 'Senegal 蚱 fier iew.ega/ewhs), variegated worm (Zowozerw·? variegatus) 'Semitic (Hieroglyphus daganensis'), India Draw alba (ATrawwflrria awgwh/era), Italy {Calliptamus italicus) 'Australian catastrophe (C/joz-io/ceiei 138194.doc -43- 200939960 terminifera') uncovers [Locustana pardalina), arachnid ( Arachnoidea), such as the lack of arachnid (Acarina), such as the soft-spotted family, the hard-spotted family (/xo mountain W Ae) and genus, such as: American flower 蜱americanum), adorned flowers > (Amblyomma vaWegaiw/n), 斑花碑(dw^ryomwa macw/aiww), Persian hidden 0彖 monument perhcwi·), with · Boophilus annulatus, full color year [Boophilus, tiny cattle monument (j5oop/^7w>sm cro/7/wW, Dermacentor silvarum, Dermacentor andersonf), variation Dermacewior var/a6z7z'j), Yuanbao mechanical monument (//ya/ommo; truncatum), sheep hard 蜱 (/xoc?e·?, South African hemorrhoids monument (/χοί^·? rwWcwnt/ws), Black foot hard monument (/xot/e·? ·5〇α/?Μ/<3"ζ·3), full ring hard 蜱 (Ixodes holocyclus"), nine years old hard 缉 (Ixodes pacificus"), ν Elephant monument {Ornithodorus moubata), Chi I: 孽 孽 多 fe· 0 {Ornithodorus /jerwh), returning to the hot wall iL (Orm'i/ioi/orw·? iMWcaior), Bai's avian snail {Ornithonyssus bacotf), after v monument {Otobius megninf), hard-toothed hedgehog (Dermawwsws ga/h'«ae), goat healing oWs), Rhipicephalus sanguineus, Rhipicephalus appendiculatus, river Rhipicephalus evertsi, Sarcopies and Spp., such as Jcw/w*s·schlechtendalV, Phyllocoptrata o/ez'vora, and citrus waste Worm (·£>ζ_ορ/7;/α Ae/t/om·); sarjowewzWae spp., such as the grass worm and the multi-food line worm (Po/jp/mg'oiarsoweww·? /aiw·?); genus genus 138194.doc 200939960 (Tenuipalpidae spp.), such as the genus BrevipaZpus phoenicis, Tetranychidae spp., such as the unsalted moth (reirawyc/m ·?, Shen Ze's leaf worm (TWra «less c / zwj fcawzawai), Pacific red leaf worm (T'eirawyc / zMj paci / icw ·?), cotton red spider (7Wra «less c / zms ie / arz' w·?) and cotton leaf worm (re/rawyc/zwi wrifcae), rhododendron red lacking spider (PawowjcAM·? κ/mz·), orange full claw ciiri) and grass small melon snail; ;3«ez'i/a), such as the black widow ball spider (lairodeciw·? waciawi) and the brown concealed spider ([oxosce/e·? rec/wsa), flea (Siphonaptera), For example, I seedlings 蚤 蚤 (Ciewocep / za / zWei · / e / i > s), dog Mei 蚤 (C Iewoeep/m/ic/e·? cam··?), Indian 蚤5Xenopsylla cheopis, Pulex irritans > Tunga penetrans, Nosopsyllus fasciatus, Silverfish, firebrat (Thysanura), such as Zepkwa saccharina anti-micro-coat, (Thermobia domestica) >

Entertainment law (Chilopoda), such as Scwifgera coleoptrata » Millipodidae (Diplopoda) 'iVarcewi spp.' 'Larma (Dermaptera) For example, European ball python (/br/Vcw/a auricularia) > wind (Phthiraptera), such as Pec^cw/wj· humanus capitis, Pediculus humanus corporis, 138194.doc -45- 200939960 and the wind (Ρί/n'rw·? /7«6), the cattle blind wind (//aemaio/ikw·? eMryWemws), Wei Hongwa (Haematopinus · 5μζ··5), Long-headed calf (Z/rtogwai/iM·?: Wiw/z·), bovine bite (BoWco/a 6σνζ·ί), chicken wind (Me/iopow gallinae) ' # It il {Menacanthus ·ί,Γβ /7Π·ΛβΜ·?) and Solenopotes capillatus » Plant parasitic nematodes, such as the root nodule nematode, groundnut nematode arenaWa), Chitwood root nodule nematode (Me/oWogywe chitwoodi) ' ^ :Μ ^ A {Meloidogyne exigwa ), Meloidogyne hapla, Meloidogyne incognita ' ^ {Meloidogyne javanica ) A ^ Nematode Cyst nematode, gold nematode (G7oZ?oc/era rosioc/n'e/m··?), cyanobacteria (G/i? 6oc/era; ?α"/ί/α), tobacco Globodera tabacum against other cystoid nematodes (Globodera); wheat cyst nematode (//eieroc/era ave«ae), soybean cyst nematode (//eieroc/era g/ycz'/ Ie·?), beet cyst nematode (/^eierc^era sc/rnc/zm·), clover cyst nematode (//eieroc/era iW/o/z·/) and other cyst nematodes (10,000 ^ (7) i/era) species; nematode, nematode fungus), wheat granule (dwgwiwa ir (1) and other granule nematodes (4«^·ιπ·«α); stem-leaf nematode, leaf nematode beseyi), grass poison Aphelenchoides fragariae, Portuguese H. elegans (dp heart ri/zemaftoi1!·) and other leaf bud nematodes; thorn nematode, thorn nematode (5e/owc>/aiwM·? /owgi'cawdaiw·? And other species of thorn nematodes; pine nematodes, pine wood nematodes (Bw·5叩 and other species of nematode (i?wrsap/ie/e«c/zw5·); ring 138194.doc -46- 200939960 nematodes, Ringworm (Crz'co«ema) species, Nematodes in the ring (Cricowewe//f l) species, Oicowewoic/es species and Mejochcowema species; stem and bulb nematodes, potato decay nematodes {Ditylenchus destructor), corn i dyilenchus ί/φίοτα·, fungus stem nematode Myce/z'op/zagw·?) and other species of stem nematodes; cone nematodes, cone-shaped nematodes (Do/z'c/zoi/orwj) species; spiral nematodes, dihystera, dihystera, multi-nails, and images ^(Helicotylenchus multicinctus) Liangzhu other species of helicidae; Z. elegans (ZioO^ewc/zw·? /-oftwWwi·) and other species of the genus Spinosa; sheath worm, sheath nematode and sheath-like nematode (// Em/cr/cowemoWei); root-knot nematode (//7"ΑΑΜίϊ««ίβ//α) species; spear-shaped nematode, Columbus elegans (ugly opMMiwwi co/w/w6mj), C. berghei (i /op/o/a/mwj ga/eaiwj) and other species of the genus Corydalis; pseudo-root nodule, abnormal pearl nematode and other pearl nematodes; needle nematodes, arachidida (lowgz'i/orws and other worms) (ZcmgWorwi) species; N. elegans, N. elegans (corporate arae/enc/zMs) species; root rot nematodes, short root rot nematodes (iVfliy/ewc/iw ·? brac/^t/rz^), coffee worm short body nematode (^VaO^ewc/iM·? cojeae), curved nematode cMrWiaiwi), gangrene nematode (/Vaiy/ewc/zws gooc?e>>z ·), California root rot nematode weg/eciwj), puncture root rot nematode (iVae/eMc/zws /?e«eir<3«5), short-lived nematode (Prae/ewc/zMA··5£; ·Ζ);7β"ζ'), disabled root rot nematode (/VaO^/ewc/zwi vw/«wi), maize short-body nematode (PraO^ewc/^ws zeae) and other root rot nematodes (Prai; v/e«c/iwi); coconut 138194.doc -47 200939960 Radinaphelenchus cocophilus against other fine samples slippery 7] (Radinaphelenchus') after, perforated nematodes, similar to perforated nematodes (Radophohis simi !is) anti-other perforation line (Radopholus), kidney-shaped nematode, kidney-shaped nematode reW/ormz··?) and other nematode species; Shield nematode ("Scwie//o«ewia" species; Root-knot nematodes, primitive squid nematodes (7Wc/z〇i/orw·? pr/wii/vMj) and other species of nematode (TWc/zoi/orwj); micro-striated nematodes (Parairz'c/joi/orw·? Mz'wor) and other species of the genus Trichinella (Parair/c/joi/orw·?); dwarf line , horse-toothed dwarf nematode (Ty/enc/zor/zync/zws c/a}io^H·), ductal dwarf nematode (T^e/^/zor/zywc/zw·? <^μ6ζ ·μ·5) and other dwarf nematodes (T^/enchor/zywc/zw·?) species and Merlin's nematode (MerhWMi) species; phase·C. elegans, mandarin-inserted half-pricked root-worm (7W printed Mw/ws sem) ^peneiraw·?) and other citrus nematodes (7>/β«£?/2Μ/Μ·?) species; sword nematodes, Xiphinema americanum', Xiphineema index, crack Nematodes (A7p/^«ema i/z'veri/cat/i/fliwm) and other species of the nematode (X/p/n'wewa); and other plant parasitic nematodes 0 ❹ [Embodiment] The mixture of the invention can be applied to any and all stages of development of the pest, such as eggs, larvae, pupa and adults. The pest can be controlled by contacting the target pest, its food source, habitat, breeding ground or its location with a pesticidal effective amount of the inventive mixture or a composition comprising the mixture. "Location" means a plant, plant propagation material (preferably seed), soil, area, material or environment in which the pest is growing or growing. In general, "insecticidal effective amount" means the desired mixture of the invention or 138194.doc -48-200939960 comprising the amount of the composition of the mixture to achieve an observable effect on growth, including necrosis, death , Delay, Obstruction, and Removal, Destruction, or Potential Reduction of the Occurrence and Activity of Target Organisms The effective amount of q insects is variable for the various mixtures/compositions used in the present invention. The pesticidally effective amount of the mixture/composition should also vary depending on the general conditions such as the desired insecticidal effect and duration, weather, target species, location, mode of administration, and the like.

The term "plant effective amount" means an amount of the mixture of the present invention sufficient to achieve a plant health effect as defined below. More illustrative information regarding amounts, modes of administration, and suitable ratios to be used are given below. In summary, it is well known to those skilled in the art that this amount can vary over a wide range and depends on various factors, such as the cultivated plant or material being treated and the climatic conditions. When preparing a mixture, it is preferred to use a purely active compound as it is possible to add other active compounds against pests (such as insecticides, herbicides, fungicides) or other herbicidal or growth regulating active compounds or fertilizers as other activities as needed. Component. The mixture of the invention is employed by treating the fungus or plant, plant propagation material (preferably seed), material or soil to be protected from fungal attack with a pesticidally effective amount of the active compound. The application can be carried out before and after the infection of the material, plant or plant propagation material, preferably the seed, by the pest. In the method of combating harmful fungi depending on the type of the compound and the desired effect, the application rate of the mixture according to the invention is 〇, 3 g/ha to 2 g/ha, preferably 5 g/ha to 2000 G/h, preferably 5 gram/ha to 900 gram/ha, especially 50 gram/ha to 75 gram/gong 138194.doc -49-200939960. In the method of combating animal pests (insects, cocci or nematodes) depending on the type of the compound and the desired effect, the application rate of the mixture according to the invention is 〇, 3 g/ha to 2000 g/ha, preferably 5 g/ Hectare to 2 gram/ha, more preferably 50 gram/ha to 900 gram/ha, especially 5 gram/ha to 750 gram/ha. The mixture of the invention or a combination of such mixtures can also be used to protect plants Invasion or infestation of animal pests (insects, mites or nematodes), including plant selection, or soil or water in which the plant is growing. In the context of the present invention, the term plant refers to a whole plant, a part of a plant or a propagation material of a plant. Plants which can be treated with the mixtures of the invention and the propagation material of such plants include all genetically modified plants or genetically modified plants, for example tolerant to herbicides or fungicides or insecticides by breeding (including genetic engineering methods) A crop that acts, or a plant having modified characteristics compared to an existing plant, which can be produced, for example, by conventional breeding methods and/or mutants or by recombinant procedures. By way of example, the mixture according to the invention may also be applied (in seed treatment, spray treatment, in furrows or by any other means) to have been modified by monthly, mutation-induced or genetic engineering. Plants, including, but not limited to, agricultural biotech products that are being sold or are under development (see P. www.bio.org/speeches/pubs/er/agri_p(7) plus (10)). Plants that have been modified and modified have been genetically modified by recombinant DNA techniques and are not readily available under natural conditions by cross-breeding, mutation or natural recombination 138194.doc 200939960. One or more genes have generally been integrated into the genetic material of genetically modified plants to modify certain characteristics of the plant. Such genetic modifications also include, but are not limited to, targeted post-translational modifications to proteins, peptides or polypeptides, such as prenylation, acetamylation or farnesylation, by, for example, glycosylation or polymer addition. Farnesylated moiety or PEG moiety.

As a result of conventional methods of breeding or genetic engineering, plants that have been modified by breeding, mutation induction or genetic engineering, for example, are tolerant to the application of a particular class of herbicides such as hydroxyphenylpyruvate II. An oxygenated enzyme (HPPD) inhibitor; an acetaminolate synthase (ALS) inhibitor, such as a sulfonium urea (see, for example, US 6,222,100, WO 01/82685, WO 00/26390, WO 97/41218, WO 98) /02 526, WO 98/02527, WO 04/106529, WO 05/20673, WO 03/14357, WO 03/13225, WO 03/14356, WO 04/16073) or imidazolidinone (see for example US 6,222,100 ' WO 01 /82685, WO 00/026390, WO 97/41218, WO 98/002526, WO 98/02527, WO

04/106529, WO 05/20673, WO 03/014357 > WO ® 03/13225, WO 03/14356, WO 04/16073); enol acetone oxalic acid-3-acid vinegar synthase (enolpyruvylshikimate-3) -phosphate synthase, EPSPS) inhibitors, such as glyphosate (see, for example, WO 92/00377); glutamine indole synthase (GS) inhibitors, such as glufosinate (see, for example, EP-A) 242 236, EP-A 242 246) or oxynil herbicide (see, for example, US 5,559,024). A number of cultivated plants have been subjected to herbicides by conventional methods of breeding (mutation induced), for example, to make Clearfield® summer rape 138194.doc 51 200939960 (Canola, BASF SE, Germany) rich in miso ketones, such as sputum Oxygen grass smoke (imazamox). Genetic engineering methods have been used to make cultivated plants such as soybean, cotton, corn, sugar beet and canola tolerant to herbicides such as glyphosate and glufosinate, some of which are under the trademark RoundupReady® (Glyphosate, Monsanto, USA) And commercially available as LibertyLink® (Bayer CropScience, Germany). Also included is a plant capable of synthesizing one or more pesticidal proteins by using recombinant DNA techniques, particularly ones from the genus Bacteroides, especially from Bacillus thuringiensis, such as δ - endotoxin, such as CrylA (b), CrylA (c), CrylF, CryIF (a2), CryIIA (b), Crylll A, Crylll B (bl) or Cry9c; plant insecticidal protein (VIP) 'eg VIP1, VIP2 VIP3 or VIP3A; a pesticidal protein of the bacterium, such as Photorhabdus spp. or Xenorhabdus spp.; a toxin produced by an animal, such as a toxin, a toxin, a wasp, or other Insect-specific neurotoxins; toxins produced by fungi such as streptomyces toxins, plant lectins such as porridge or barley lectin; agglutinin; protease inhibitors such as chymotrypsin inhibitors, silk Amino acid protease inhibitor, potato tuber storage protein (patatin), cystatin (cystatin) or papain inhibitor; ribosome deactivating protein (RIP) Ricin, corn _RIP, abrin, luffin, saporin or bryodin; steroid metabolism enzymes such as 3-hydroxy sterol oxidation Enzyme, quercetin-IDP-glycosyltransferase, cholesterol oxidase, sputum 138194.doc -52· 200939960

Inhibitors or HMG-CoA reductase; ion channel blockers, such as sodium or calcium channel blockers; juvenile hormone esterase; diuretic hormone receptor (helicokinin receptor); Stilben synthase), bibenzyl synthase, chitinase or glucanase. In the context of the present invention, it should also be clearly understood that such pesticidal proteins or toxins are pre-toxin, hybrid proteins, proteins which have been cleaved or otherwise modified. Hybrid proteins are characterized by a new combination of protein domains (see, for example, WO 02/015701). Such toxins or capable of being synthesized are disclosed, for example, in EP-A 374 753 753, WO 93/007278, WO 95/34656, EP-A 427 529, EP-A 45 1 878, WO 03/1 8810 and WO 03/52073. Other examples of genetically modified plants of such toxins. Methods of making such genetically modified plants are generally known and described by those skilled in the art and are described, for example, in the above publication. These insecticidal proteins contained in genetically modified plants impart to the plants producing these proteins harmful pests to all taxa of arthropods (especially to aphids (Coeloptera), two wings) Insects (Diptera) and Moth (Lepidoptera) ® and tolerance to nematodes (Nematodes). Genetically modified plants capable of synthesizing one or more pesticidal proteins are described, for example, in the above publication, and some of them are commercially available, such as YieldGard® (a corn cultivar producing CrylAb toxin), YieldGard® Plus (creating CrylAb and Cry3Bbl). Toxin corn cultivar), Starlink® (Cry9c toxin-producing corn cultivar), Herculex® RW (producing Cry34Abl, Cry35Abl and Phosphinothricin-N-Acetyltransferase, PAT) Corn cultivar); NuCOTN® 33B (cotton cultivar producing CrylAc toxin 138194.doc -53- 200939960), Bollgard® I (cotton cultivar producing CrylAc toxin), Bollgard® 11 (cotton producing CrylAc and Cry2Ab2 toxin) Variety); VIPCOT® (cotton cultivar producing VIP toxin); NewLeaf8 (potato cultivar producing Cry3A toxin); Bt-Xtra®, NatureGard®, KnockOut®, BiteGard®, Protecta®,

Btll (eg Agrisure® CB) and from Syngenta Seeds SAS,

France's Btl76 (a corn cultivar producing CrylAb toxin and PAT enzyme), MIR604 from Syngenta Seeds SAS, France (a corn cultivar producing a modified version of Cry3A toxin, see WO 03/018810), ® from Monsanto Europe SA, Belgium MON 863 (Cry cultivar producing Cry3Bbl toxin), IPC 531 from Monsanto Europe SA, Belgium (cotton cultivar producing modified version of CrylAc toxin) and 1507 from Pioneer Overseas Corporation, Belgium (creating CrylF toxin and PAT enzyme) Corn cultivar). Also included are plants which are capable of synthesizing one or more proteins by using recombinant DNA techniques to enhance the resistance or tolerance of their plants to bacterial, viral or fungal pathogens. Examples of such proteins are the so-called "pathogenic mechanisms" (PR proteins, see for example EP-A 392 225), plant disease resistance genes (for example, the performance against Phytophthora cinerea (Phytophthorainfestan) is derived from Mexico. Wild potato resistant to late blight potato (Solanum 1) 11113 0 0&3{&11111]1) resistance gene of horse mash cultivar) or butyl lysozyme (for example, capable of synthesizing such enhanced resistance A potato cultivar of a protein resistant to bacteria (such as Erw ini a amyl vor a). Methods of making such genetically modified plants are generally known and described, for example, in the above publications by those skilled in the art 138194. doc-54-200939960. In addition, it is also possible to synthesize one or more proteins by using recombinant DNA technology to increase productivity (for example, biomass yield, grain yield, powder content, oil content or protein content), for drought, salinity or other Plants that are resistant to environmental factors or to tolerance to pests and fungal, bacterial or viral pathogens of their plants. In addition, 'the use of recombinant DNA technology to contain varying amounts of substances or novel substances, especially for improving human or animal nutrition, such as the production of health-promoting long-chain omega-3 fatty acids or unsaturated omega-9 fatty acids (eg Nexera® rapeseed,) Oil crop of DOW Agro Sciences, Canada). In addition, it also covers plants that contain varying amounts of material or novel substances by using recombinant DNA technology, especially to improve the yield of raw materials, such as potatoes that produce increased amounts of powdered flour (eg Amfiora® horse, BASF) SE, Germany). For the purpose of treating plant-propagating substances (especially seeds), water-soluble concentrates (LS), flowable concentrates (FS), powders for anhydrous treatment (Ds), and slurry treatment (WS) are usually used. Water dispersible powders, water soluble powders (ss), emulsions (ES), emulsifiable concentrates (EC) and gels. In a preferred embodiment of the invention, the mixture of the invention is used to protect the roots of seed and seedlings and Bud (preferably seed). The seed treatment can be carried out in a seed box and subsequently planted in the field. For the purpose of seed treatment, the weight quantification in the ternary and quaternary mixtures of the present invention will generally depend on the characteristics of the compound of the mixture of the invention. 138194.doc -55- 200939960 Particularly suitable for seed treatment compositions (for example) are: A soluble concentrate (SL, LS) D emulsion (EW, EO, ES) E suspension (SC, OD, FS) F Water dispersible granules and water-soluble granules, SG) G water dispersible powders and water-soluble powders (WP, SP, WS) H gel formulations (GF) 1 dusting powders (DP, DS) The material can be applied to plant propagation material, especially seeds, in diluted or undiluted form. These compositions can be applied to the plant propagation material 'especially seeds' in diluted or undiluted form. The composition in question is obtained in a ready-to-use preparation after dilution from two to ten times, preferably from 1% by weight to 6% by weight, preferably from about 3% by weight to about 40% by weight of the active substance. Application can be carried out before or during sowing. Methods for applying or treating agricultural compounds and compositions thereof to plant propagation materials, especially seeds, are known in the art and include the application and application of the propagation material. Cloth, spheronization, dusting, and immersion application methods (and in a preferred embodiment in furrow treatment, by methods that do not induce germination, such as by seed dressing, spheronization, coating, and dusting) 'Applying a compound or a composition thereof to a plant propagation material separately. When treating a plant propagation material, preferably a seed, the application rate of the mixture of the invention is generally used for the formulated product (which typically comprises U) g/Ι to 750 g/1 active substance). The invention also relates to a plant reproductive product, and in particular comprises (i.e. coated with 138194.doc -56-200939960 and/or contained) a mixture as defined above or containing two or more Active ingredient a composition of a mixture or a mixture of two or more compositions, each of which provides one of the active ingredients. The plant propagation material, preferably seeds, comprises 100 mg of plant propagation material (preferably seeds). 0" § to 1 〇 kg of the mixture of the invention. For example, 'the weight of the compound I herein is better than 1 〇〇kg of plant propagation material (preferably seed g, more preferably every 1 〇〇 plant) The propagation material (preferably seed) is from 1 to 200 g and preferably between 1 and 1 〇〇g per 1 kg of plant propagation material © (preferably seed). For example, 'the compound 11 or 111 herein The weight is preferably 1200 g per kg of plant propagation material (preferably seed), more preferably 5 to 200 g per 100 kg of plant propagation material (preferably seed), and optimally per 100 kg of plant propagation material (preferably Seed) between 5 and 1 〇〇g. For example, as a compound III, strobilurin (which is a compound azoxystrobin, φ baikemin (Pyracl 〇strobin) ), trifloxystrobin or orimycin 〇rsyastrobin)) (especially oridomycin)) preferably has a weight of 1 to 50 g per 100 kg of plant propagation material (preferably seed g, more preferably 100 kg of plant propagation material (preferably seed)) Preferably, each 1 kg of plant propagation material (preferably seed) is between 1 and 20 g. For example, the weight of compound 1 herein is preferably in the growth of each plant (preferably seed). ) 0120 () g, more preferably every 100 plant propagation material (preferably seed to mouth g, and preferably between 1 and 50 § per 100 plant propagation material (preferably seed). 138194.doc • 57· 200939960 The compound of the mixture of the invention is applied independently or in combination by spraying or dusting the seed, seedling, plant or soil before or after plant seeding or before or after the plant is germinated. The mixtures of the invention are effective by contact (via soil, glass, wall, bed, carpet, plant parts or animal parts) and ingestion (俾 or plant parts) and by feeding and transferring. The preferred method of application is to enter the water body 'through the soil, cracks and gaps, grass, fertilizer piles, sewers' into the water' floor, wall, or by spraying and bait by the peripheral spray. According to another preferred embodiment of the invention, the mixture of the invention is prepared as a bait preparation for use against non-crop pests such as ants, termites, wasps, flies, mosquitoes, mites, mites or mites. The series can be a liquid, solid or semi-solid preparation (e.g., a gel). The bait used in the composition is a product that is sufficiently attractive to attract insects such as ants, white sacrifice, wasps, woven, mosquitoes, crickets, etc. or cockroaches to eat. The attractant may be selected from the food quality or pheromones and/or sex pheromones readily known in the art. The method of controlling infectious diseases transmitted by insects such as dysentery, dengue and yellow fever, lymphatic filariasis and leishmaniasis by the mixture of the present invention and its individual compositions also includes treatment Shed and house surfaces, air spray and dipping curtains, tents, clothing items, bed nets, tset fly traps or the like. The pesticidal compositions for use in fibers, fabrics, knits, nonwovens, mesh materials or boxes and tarpaulins preferably comprise a combination comprising a mixture of the invention, optionally a repellent and at least one binder 138194.doc • 58 - 200939960, things. The mixture of the present invention and the composition comprising the same can be used for protecting wooden materials such as trees, wooden fences, sleepers, etc., and buildings such as houses and outhouses, as well as building materials, furniture, leather, work fibers, and ethylene. Products, wires and cables are protected from ants and/or termites for control. Ants and termites are protected from crops or humans (eg when pests break into houses and public facilities). In the case of soil treatment or application to pest houses or nests, the amount of active ingredient ® is in the range of G._g/1GG m2 to W(9) m2, preferably i m2 to 20g/100m2. In material protection, the usual application rate is, for example, 每1 g to 1 〇〇〇g of active compound per square meter of treated material, ideally 每i Lu to 50 g 平方 per square meter for impregnation The pesticidal composition of the material generally contains 〇〇〇 weight. To 95 weight % / ❶, preferably 0.1% by weight to 45% by weight, and more preferably 丄 by weight to at least one repellent and / or insecticide. For use in a bait composition, the active ingredient is typically present in an amount of from 0.0001% to 15% by weight, desirably from 1% to 5% by weight of the activated animal. The compositions used may also contain other additives such as solvents, flavoring agents, preservatives, dyes or bitterns of the active substance. Its appeal can also be enhanced by a specific color, shape or texture. For use in a spray composition, the mixture of active ingredients is present in an amount of 0.001% by weight. /. Up to 8 inches in weight. /〇, preferably 〇1% by weight to 5% by weight and most preferably 0.01% by weight. /. Up to 15 weights 0/〇. 138194.doc -59-

Claims (1)

200939960 VII. Scope of Application: 1. A mixture comprising a synergistically effective amount of the following components as active ingredients: 1) Insecticidal compound I selected from a nicotinic receptor agonist/antagonist compound: sub-cracking (acetamiprid), clothianidin, dinotefuran, imidacloprid, thiamethoxam, and nitenpyram; and 2) as a compound II (pyrimethanil); and φ 3) - or two other fungicidal compounds III selected from the group consisting of: triticonazole, fluquinconazole, prothiotoxin. Prothioconazole, difenoconazole, ipconazole, flutriafol, tebuconazole, and prochloraz 〇 2. A mixture of claim 1 It contains edaramine or cyanohydrin as compound I. The mixture according to any one of claims 1 to 2, which comprises one or two other fungicidal compounds III selected from the group consisting of oxazoloxazole, prothioconazole and poker. 4. A mixture according to any one of claims 1 to 2 which comprises cyclosporin as compound III. 5. A mixture according to any one of claims 1 to 2 which comprises cyclosporin and poker as compound III. 6. A mixture according to claim 1, which comprises as an amine I of the compound I or a singly 138194.doc 200939960, a pyrimethanil and a cyclosporine. 7. In the case of a mixture of the requested items, it contains Yida or Syracuse, Pyrimethanil and Poker Pull as a compound. 8. A mixture comprising a synergistically effective amount of the following as an active ingredient: 1) an insecticidal compound selected from the group consisting of the following nicotinic receptor agonist/antagonist compounds I. subctomy, cotinine, Dartnam, edamine, acesulfame, nitenpyram; and 2) two other fungicidal compounds selected from the group consisting of HI: oxazolidine, fluoroquinazole, prothiotoxin Oxazole, difenoconazole, inobutazole, dimethoate, dekli and poker. 9. A pesticidal composition comprising a liquid or solid carrier and a mixture of any one of claims 1 to 8 10. A method of controlling pests and/or improving plant health, wherein (a) the pest, a habitat, a breeding ground, a locus thereof, or a plant, soil or plant propagule that is awaiting protection from pests; or (b) the plant, the locus where the plant is growing or expected to grow, or the plant propagule from which the plant is grown Processing with an effective amount of a mixture of any one of the claims 丨 to 8. 11. A method of protecting plant propagation material from pests, comprising contacting the plant propagation material with a pesticidally effective amount of a mixture of any one of claims 1-6 to 8. 12. The method of claim 11, wherein the mixture of any one of claims 1 to 9 is administered in an amount of from 1 〇〇 kg of plant propagation material 〇 gi g to 10 kg. 138194.doc • 2 · 200939960 . The method of claim 1 to 12, wherein the compound I as defined in any one of claims 1 to 9 is applied simultaneously (ie jointly or independently) or subsequently Compound II. A plant propagation material comprising a mixture of any one of claims 1 to 8 in an amount of from 1 g to 10 kg per kg of plant propagation material. 138194.doc 200939960 IV. Designated representative: (1) The representative representative of the case is: (none) (2) The symbolic symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the best indication of the characteristics of the invention. Chemical formula: (none) 138194.doc