200816549 九、發明說明 【發明所屬之技術領域】 本發明係有關於一種燃料電池與其製造方法,特別是有 關於一種可組接多個電池單元於一平面之燃料電池與其製 造方法。 【先前技術】 隨者全球能源的消耗以及環保意識的抬頭,如石油及火 力之類的傳統%源已經越來越不敷使用,使得關於新式能量 來源的研九也越來越多,燃料電池的研究便是其中相當重要 的一環。 燃料電池之能量轉換效率高,可達百分之四十以上,如 果再配合汽電共生(cogeneration)的技術,將反應時釋放的 廢,、、、回收,總熱效率即可能超過百分之人十。加上,辦料電 池:發電過程幾乎不會造成任何污染。而且,燃料電池的嗓 音置也相當低。目前燃料電池的應用範圍十分廣泛,包括電 Α Ί H太空、軍事等各領域’已有多項產物因應 而生:例如發電廠、備用電池、可攜式電力、堆高機、機器 人、電動車、小型潛水艇、乃至太空船和太空梭的電源。 在各種燃料電池中,質子交換膜(PEM;Proton Exchange Μ=_)燃料電池具有反應溫度低、能量密度高、材料選 =等優點1子交換膜燃料電池之原理係以氫氣為燃料與 ,告:I之^軋發生電化學反應’而產生電能與水,其基本構 3 乂下成種TL件:質子交換膜、氣體擴散層(含觸媒層) 200816549 及雙極板。氣體擴散層係設置質子交換膜之兩側,以分別供 氫氣和氧氣擴散進入並解離,而進行電化學反應來產生電 流。雙極板則分別係設置於質子交換膜與氣體擴散層之組合 的兩側,以傳送氣體和收集電流。 然而,此基本構造之燃料電池一般具有固定電壓,其固 定電壓僅為約1.23V,故必須將串聯多個單元之燃料電池, 以提咼整體的輸出電壓。而習知之堆疊式燃料電池係將多個 燃料電池直接堆疊串聯而成,然而此種堆疊式燃料電池的整 (體體積和重量也相對增加,因而不符合攜帶式電子產品之微 型㈣需求。加上,習知堆疊式燃料電池需設計有鎖固元件 淨氣體輸达系統(如幫浦或風扇广以使燃料電池緊密地組裝 成體it供應氣體燃料,目@ ^ 量、體積及製作成本。 们更 【發明内容】 因此,本發明夕_ + ^ " 造方法,葬一面係在於提供一種燃料電池與其製 ^1敖1、’且裝複數個電池單元電性連接於同-平面上, 以增加整體電壓於山 卞囬上 量。 Μ出,並避免大幅增加燃料電池之體積與重 本發明之另—古 y 方法,藉以使姆料“在於提供一種燃料電池與其製造 内,而無需使用暫法4、 卫軋)直接擴散進入電池單元 ,,M # , /南或抽風裝置來供應燃料,以減少整體嗖 汁構件,因而減少 X* V正骽口又 化之需求。 a之體積和重量’以滿足燃料電池微型 6 200816549 根據本發明之一實施例,此燃料電池至少包含複數個電 池單元、燃料供給裝置、第一壓板及第二壓板。此些電池單 疋係相互電性連接並分別平行地設置於一平面上,其中每一 電池單元至少包含膜電極組、陽極導電片和陰極導電片’。膜 電極組係平行地設置於平面上,陽極導電片係設置於膜電極 組之一側,陰極導電片係設置於膜電極組之另一側。燃料供 給裝々置係設置於電池單元之一側,以供給第一燃肖至電池單 元。第一壓板係設置於此些電池單元之一側,其中第—壓板 具有複數個透孔,以使第二燃料係經由第一壓板之透孔進入 電池單元,而與第一燃料發生電化學反應來產i電能。第二 壓板係設置於此些電池單元之另一側,且位於此些電 和燃料供給裝置之間,以與第一壓板共同壓合組裝此此電、、也 單元於燃料供給裝置上。其+,每一電池單元之陽極導電 片係與其相鄰—侧之電池單元的陰極導電片電性連接。 ⑽又’根據本發明之另_實施例,此燃料電池之此些電,也 早凡至少包含··複數個膜電極組和二導電片組。二 相 :以夾合於此些膜電極組之兩端’而形成此些電池單元於— 二面上,其中每—導電片組至少包含:複數個導電片和連接 =連接部係以絕緣材料製成,用以連接此些導電片成導電 片組,且此些導電片係相互電性連接。 又,根據本發明之一實施例,此燃料電池之製 少包含··排列複數個膜電極組於一、' 会日*丄— 十由上供二個導電片 、广、中母-此些導電片組至少包含:複數 複數個陰極導電片及連接部。 v電片、 逆按:係以絕緣材料製成,用 200816549 以連接此些陽極導雷 、 導電片^ ^ 、 二★極導電片來形成每一此些 、 此些導電片組來對應夾合此此膜電组,並 形成複數個電池單元於 極組,並 後,此些陽極導電片和此此卜 令在形成此些電池單元 g ^ ^ y 一 u往等電片係分別位於此些電池 Π 而連接部係分別位於此些電池單元:兩端 二且母-此些電池單元之陽極導電片係與其相鄰一側之電 池早兀的陰極導電片電性 Μ — 來共同壓〜且… 弟—壓板和-第二壓板 晉單元於—平面上;設置燃料供給裝 ㈣、# 池早7L之—側,且對應於第二麼板,以供給第一 九、:料透過第二麼板至此此 - 板至此些電池早凡中。其中第一壓板具有複 仰一孔,以使一第二燃料係經由第一壓板之透孔進入電池 一而η第一燃料發生電化學反應來產生電能。 、口此本發明之燃料電池可使複數個電池單元電性組 接於一平面上,以增加整體電壓輸出,並避免燃料電池之 體積和重量相對大幅增加之情形。且本發明之燃料電池可 確保燃料電池之結構密合度,以進一步提升燃料電池之發電 率另外,由於無需幫浦或風扇來循環供應氫氣和氧氣, 因而減少整體設計構件。 【實施方式】 “請參照第1圖所示,其繪示依照本發明第一實施例之燃 料電池的爆炸示意圖。本第一實施例的燃料電池至少包括有 複數個電池單元100、第一壓板200、過濾膜300、蓋板400、 燃料供給裝置5〇〇及第二壓板6〇〇。此些電池單元1〇〇係相 200816549 互電性連接,以增加電量輸出,第一壓板2〇〇和第二壓板 600係用以將此些電池單元丨〇〇緊密地組裝於燃料供給裝置 5〇〇上。過濾膜300和蓋板400設置於第一壓板200上,並 可谷沣空氣進入電池單元1〇〇。燃料供給裝置3〇〇係用以供 給氫氣至電池單元1 0 0,以進行發電。 凊參照第1圖和第2圖,第2圖係繪示依照本發明第一 只%例之電池單元的結構示意圖。其中,電池單元1〇〇係由 膜電極組iio、陽極導電片120及陰極導電片13〇所組成, 膜電極組11〇係設置於陽極導電片12〇和陰極導電片13〇 之間。膜電極組1 10係由電解質材料所形成之薄片狀結構, 例如··磷酸型、熔融碳酸鹽型、固態氧化物型或質子交換膜 型電解質材料。膜電極組110之兩側纟自皆形力有觸媒層 (未繪示)’此觸媒層之材料例如:鉑、奈米金、鐵、鈷、鎳、 鉬或含上述金屬的合金混化物,用以加速在膜電極組u〇 内之電化學反應。陽極導電片12〇和陰極導電片13〇係由具 導電性和多孔性之材料所製成之片狀結構,例如:形成有細 小穿孔(未繪示)的金屬薄片、碳纖維或石墨纖維薄片。陽極 導電片12〇和陰極導電片130分別設置於膜電極組11〇之兩 側面,以容許氫氣進入膜電極組110而產生電化學反應,並 傳導電流。當電池單元1 00進行發電時,氫氣可經由陽極導 電片120進入膜電極組110,並解離成電子和氫質子,電子 即流出形成電流。氧氣係經由陰極導電片13〇進入膜電極組 1並使氧、氫質子及回流電子一起還原形成水,並產生 熱能(即電化學反應後之副產物)。 200816549 如第1圖所示,第一實施例中的第一壓板200和第二壓 板600係設置於電池單元ι〇〇之兩側,以共同緊密地壓合組 I此些電池單元1 〇 〇於燃料供給裝置5 〇 〇上。第一壓板2 〇 〇 絕緣材料製成,並開設有複數個透孔2丨〇,藉以當第一壓板 - 200壓合組装此些電池單元ι〇〇時,第一壓板2〇〇之透孔21〇 可供氧氣進入電池單元1 〇〇 ;或使電池單元1 〇〇發電後之副 產物可由透孔2 1 〇排出。第二壓板6〇〇係以多孔材質製成, 以使氫氣通過。過濾膜300係設置於第一壓板2〇〇上,以過 $ 濾空氣中之雜質,避免影響發電效率。蓋板4〇〇設置於過濾 膜300上,蓋板400開設有複數個透孔41〇,以容許外界空 氣進入,且蓋板400係以高剛性之材質製成,以保護整體電 池結構。 如第1圖所示,本第一實施例之燃料供給裝置5〇〇係設 置於電池單元100之另一側,並對應於電池單元1〇〇之陽極 k V電片120,以供給氫氣至電池單元1〇〇。燃料供給裝置5〇〇 係呈風狀,並可儲存鼠軋,例如利用燃料供給裝置5 〇 〇容置 -一種儲氫材料(未繪示),例如:儲氫合金、奈米碳或硼化碳, 來儲存氫氣,。 在一實施例中,燃料供給裝置5〇〇係容置儲氫合金材料 來供給氫氣,儲氫合金材料係一種可儲存氫氣的合金材料, 其具有儲氫量大、容易活化(Aetivati〇n)、吸氮/放氮之化學 反應速率快、使用壽命長及成本低廉等特性,故可減少燃料 供給裝置500之體積和重量,進而減少燃料電池之整體體積 和重量,並可提升整體電池效能。 10 200816549 燃料供給裝置500開設有供料口 51〇和注入口 52〇,燃 料供給裝置500之供料口 510係對應於此些電池單元1〇〇 的整體面積大小而開設’以使氫氣可均勻充足地擴散進入此 . 些電池單元來進行發電,因而確保電池單元100之發電 - 效率。燃料供給裝置500之注入口 520係用以供注入補充燃 料,以避免燃料不足而無法供電的情形。此些電池單元100 和燃料供給裝置500之間可選擇設置調節膜7〇〇,調節膜7〇〇 可調節燃料供給裝置500之氫氣供給壓力或流量,避免燃料 f 供給裝置5〇〇之氫氣供給壓力過大,而破壞電池單元1〇〇 之結構。 明參照第3圖,其繪示依照本發明第一實施例之串聯電 池單元的剖面示意圖。由於單一的電池單元1〇〇僅具有固定 電量輸出,故本發明之燃料電池電性串聯複數個電池單元 100來對應增加整體電量輸出。如第3圖所示,此些電池單 • 凡100係先並列地設置於一平面上,但每二相鄰的電池單元 100a和l〇〇b之間具有一空隙a,藉以分隔出每二電池單元 I 1⑽'和1〇Gb。在—實施例中,空隙a可填入例如係絕緣材 料,以隔絕每二電池單元i 00。當進行電性連接時,每一電 池單元100a之陽極導電片120a係與相鄰一側之另一電池單 元i〇〇b之陰極導電片130b藉由來接線14〇形成電性連接^ 因:形成此些電池單元100a* 1〇〇b的電性串聯,因而本第 一實施例之燃料電池可對應電池單元丨〇〇之串聯數量而择 加整體電量輸出。 曰 值得注意的是’在第3圖甲,耗利用二相鄰的電池單 200816549 元100a和100b來詳細說明,以方便述敘,但本發明之燃料 電池並不因此而限定其電池單元丨〇〇的串聯數量,其係依據 電里輸出的需求而決疋其電池單元100的串聯數量。 請參照第1圖和第3圖,當進行組裝時,此些電池單元 1〇〇係先排列於平面上,並相互電性連接,再由第一壓板2〇〇 和第二壓板600緊密穩固地共同壓合此些電池單元1〇〇於燃 料供給裝置500上,再由蓋板4〇〇地組裝此些電池單元ι〇〇 於燃料供給裝置500上,因而形成本發明之燃料電池。當燃 料電池進行發電時,燃料供給裝置500可均勾充足地供給氫 氣至電池單元1〇〇,外界空氣中的氧氣則可由蓋板4〇〇進入 電池單元100,因而無需幫浦或風扇系統來輔助循環提供燃 料。加上,電池單元⑽係排列設置並電性串聯在燃料供給 裝置500之平面上,故本發明之燃料電池可增加整體輸出電 量’卻不會大幅增加整體厚度體積,而可符合燃料電池微型 化之需求。 請參照第4圖至第6圖,第4圖係綠示依照本發明第二 實施例之-導電片組的展開結構示意圖,第5圖騎示依照 本苐二實施例之電池單元的剖面示意圖,第6圖係繪示依照 本弟二實施例之單一電池單元的立體示意圖。相較第一實施 例’第二實施例之此些電池單元⑽之陽極導電片12〇和陰 ,片㈣的長度較短,並利用一連接部15〇來連接組合 在些%極導電片120和陰極導電片^ ^ 守电片130,而形成一導電片組 15〇 4 ®所使此些陽極導電片12G係位於連接部 之—側’此些陰極導電片⑽係位於連接部15G之另- 12 200816549 =且此些陽極導電片12G和此些陰極導電片叫目互間形 成有電性串聯。連接部15G係以絕緣材料製成,而陽極導電 片120和陰極導電片130之組合位置係對應於電池單元工⑻ 之設置位置。當第4圖至第6圖之實施例的燃料電池粗裝 時,複數個膜電極組110係先排列於一平面上,再由二個導 電片組16〇來對應央合此些膜電極組11〇,(如第5圖和第 6圖所示),並使導電片組16G之陽極導電片i2Q和陰極導 電片130係分別夹住此些膜電極組11〇之兩相對表面,因而 形成複數個電池單元100’其中每一此些電池單元刚之陽 極導電片1 20係與其相鄰一側之電池單元i 〇〇的陰極導電片 藉由接線140來形成電性連接。接著,再由第一壓板2⑻ 和第二壓板600來緊密地壓合組裝電池單元1〇〇於燃料供給 裝置500上,而形成第二實施例之燃料電池。因此,藉由: 個,電片& 160對應夾合此些膜電極組11〇之端,使此些電 池:兀100之整體結構可更加密合地’以避免發生結構組配 不田的情形,因而提升燃料電池的發電效率。 由上述本發明之實施例可知,本發明之燃料電池係可使 九-、料供給褒置所供給之燃料和外界空氣中之氧氣分別均勻 ,足地進入此些電池單元,因而可提升整體發電效率。由於 =^乳係直接由燃料供給裝置和外界空氣進人所供給,故無 “或風扇來彳盾環供應氫氣和氧氣,因而減少整體設計構 件,以減少燃料電池之體積和重量。加上,本發明之燃料電 池之結構密合穩固’因而可進一步提供發電效率。 雖然本發明已以實施例揭露如上,然其並非用以限定本 13 200816549 ’又月任何熟習此技蓺者,/ :c盼触: 肉,木叮a 者在不脫離本發明之精袖4 — 内,當可作各種之更勳 心货砷和範圍 後附之申請專利範圍所界定者為準。 保遵乾圍當視 【圖式簡單說明】 弟1圖係纷示根插★ 炸示意《。 本纟月苐一實施例之燃料電池的爆 —電:丄圖係繪示根據本發明第-實施例之燃料電池之單 電池早凡的結構示意圖。 平 f 3圖錢示根據本發明第—實施例之燃料電 電池早元的剖面示意圖。 第4圖係纷不根據本發明第二實施例之燃料電池之導 電片組的展開結構示意圖。 第5圖係繪不根據本發明第二實施例之燃料電池之電 池單元的剖面圖示意。 第6圖係繪示根據本發明第二實施例之燃料電池之單 一電池單元的立體示意圖。 【主要元件符號說明】 a :空隙 100、100a、100b:電池單元 no、100a、100b :膜電極組 120、120a、120b:陽極導電片 130、130a、130b:陰極導電片 14 200816549 140 :接線 160 :導電片組 200 :第一壓板 300 :過濾膜 4 1 0 :透孔 5 1 0 :供料口 600 :第二壓板 150 :連接部 210 :透孔 400 :蓋板 500 :燃料供給裝置 520 ··注入口 700 ··調節膜BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fuel cell and a method of manufacturing the same, and more particularly to a fuel cell in which a plurality of battery cells can be assembled in a plane and a method of manufacturing the same. [Prior Art] With the global energy consumption and the rise of environmental awareness, traditional % sources such as oil and firepower have become less and less useful, making the research and development of new energy sources more and more, fuel cells The study is a very important part of it. The energy conversion efficiency of fuel cells is high, up to 40%. If combined with the technology of cogeneration of cogeneration, the waste, release, and recovery of the reaction will be more than 100%. ten. Plus, the battery is charged: the power generation process will hardly cause any pollution. Moreover, the sound level of the fuel cell is also quite low. At present, the application range of fuel cells is very wide, including electric Α 太空 H space, military and other fields. There are many products that have been produced: for example, power plants, backup batteries, portable power, stackers, robots, electric vehicles, Power for small submarines, even spacecraft and space shuttles. Among various fuel cells, the proton exchange membrane (PEM; Proton Exchange Μ=_) fuel cell has the advantages of low reaction temperature, high energy density, material selection, etc. The principle of a sub-exchange membrane fuel cell is to use hydrogen as a fuel. :I's ^Electrical reaction to produce electrical energy and water, its basic structure 3 乂 成 成 成 : : : : : : : : : : : : :: proton exchange membrane, gas diffusion layer (including catalyst layer) 200816549 and bipolar plates. The gas diffusion layer is disposed on both sides of the proton exchange membrane to separately diffuse and dissociate hydrogen and oxygen, and perform an electrochemical reaction to generate a current. Bipolar plates are placed on either side of the combination of the proton exchange membrane and the gas diffusion layer to deliver gas and collect current. However, the fuel cell of this basic configuration generally has a fixed voltage and its fixed voltage is only about 1.23V, so it is necessary to connect a plurality of cells of the fuel cell in series to improve the overall output voltage. Conventional stacked fuel cells are formed by directly stacking a plurality of fuel cells in series. However, the overall volume and weight of such stacked fuel cells are relatively increased, and thus do not meet the micro (four) requirements of portable electronic products. In the past, conventional stacked fuel cells need to be designed with a locking component net gas delivery system (such as a pump or a fan to make the fuel cell tightly assembled into a body that supplies gaseous fuel, volume, volume and manufacturing cost. Therefore, the present invention is based on the method of providing a fuel cell and a plurality of battery cells electrically connected to the same plane. In order to increase the overall voltage back to the mountain. Pull out and avoid greatly increasing the volume and weight of the fuel cell. Another method of the invention is to make the material "provide a fuel cell and its manufacture without using it." Temporary method 4, Wei rolling) directly diffuses into the battery unit, M # , / South or the exhaust device to supply fuel to reduce the overall mash component, thus reducing the X* V positive 骽The volume and weight of a 'to meet the fuel cell miniature 6 200816549 According to an embodiment of the invention, the fuel cell comprises at least a plurality of battery cells, a fuel supply device, a first pressure plate and a second pressure plate. Electrically connected to each other and disposed in parallel on a plane, wherein each battery cell comprises at least a membrane electrode assembly, an anode conductive sheet and a cathode conductive sheet. The membrane electrode assembly is disposed in parallel on a plane, and the anode conductive sheet is The cathode conductive sheet is disposed on one side of the membrane electrode group, and the cathode conductive sheet is disposed on the other side of the membrane electrode assembly. The fuel supply device is disposed on one side of the battery unit to supply the first burning element to the battery unit. Provided on one side of the battery cells, wherein the first pressure plate has a plurality of through holes, so that the second fuel system enters the battery unit through the through hole of the first pressure plate, and electrochemically reacts with the first fuel to produce i. Electrical energy. A second pressure plate is disposed on the other side of the battery cells and located between the electrical and fuel supply devices to be assembled with the first pressure plate. The electric conductive unit is also connected to the fuel supply device. The + anode conductive sheet of each battery unit is electrically connected to the cathode conductive sheet of the adjacent side battery unit. (10) Further, according to another embodiment of the present invention The electricity of the fuel cell also includes at least a plurality of membrane electrode sets and two conductive sheet groups. The two phases are formed by sandwiching the two ends of the membrane electrode groups to form the battery cells. — on each of the two sides, each of the conductive sheet groups comprises at least: a plurality of conductive sheets and a connection=connection portion made of an insulating material for connecting the conductive sheets into a conductive sheet group, and the conductive sheets are electrically connected to each other Further, according to an embodiment of the present invention, the fuel cell system comprises a plurality of membrane electrode groups arranged in one, and a plurality of conductive sheets, a wide and a middle mother are provided. - The conductive sheet group comprises at least a plurality of cathode conductive sheets and a connecting portion. vElectronic film, reverse press: made of insulating material, using 200816549 to connect the anode lead, conductive sheet ^ ^, two ★ pole conductive sheet to form each of these, these conductive sheet sets to be correspondingly clamped The membrane group is formed, and a plurality of battery cells are formed in the pole group, and then, the anode conductive sheets and the battery cells are formed in the battery cells g ^ ^ y The battery Π and the connecting portion are respectively located in the battery cells: the two ends of the mother and the anode conductive sheets of the battery cells are electrically connected to the cathode conductive sheets of the battery adjacent to the adjacent side. ... brother - press plate and - second plate press unit on the plane; set the fuel supply device (four), # pool early 7L side, and correspond to the second plate, to supply the first nine, the material through the second This is the end of the board - the board to this battery is early. The first pressure plate has a counter-hole to allow a second fuel to enter the battery through the through hole of the first pressure plate and the first fuel electrochemically reacts to generate electrical energy. The fuel cell of the present invention can electrically connect a plurality of battery cells on a plane to increase the overall voltage output and avoid a relatively large increase in the volume and weight of the fuel cell. Moreover, the fuel cell of the present invention can ensure the structural tightness of the fuel cell to further increase the power generation rate of the fuel cell. In addition, since the pump or the fan is not required to circulate hydrogen and oxygen, the overall design member is reduced. [Embodiment] Please refer to Fig. 1, which shows an exploded view of a fuel cell according to a first embodiment of the present invention. The fuel cell of the first embodiment includes at least a plurality of battery cells 100 and a first pressure plate. 200, the filter membrane 300, the cover plate 400, the fuel supply device 5〇〇 and the second pressure plate 6〇〇. The battery cells 1 are connected to each other in 200816549 to increase the power output, the first pressure plate 2〇〇 And the second pressure plate 600 is used to tightly assemble the battery cells 于 on the fuel supply device 5. The filter film 300 and the cover plate 400 are disposed on the first pressure plate 200, and the valley air enters the battery. The fuel supply device 3 is configured to supply hydrogen gas to the battery unit 100 for power generation. Referring to Figures 1 and 2, Figure 2 shows the first % according to the present invention. The structure of the battery unit is composed of a membrane electrode assembly iio, an anode conductive sheet 120 and a cathode conductive sheet 13〇, and the membrane electrode assembly 11 is disposed on the anode conductive sheet 12 and the cathode. Between the conductive sheets 13 。. The electrode group 1 10 is a sheet-like structure formed of an electrolyte material, for example, a phosphoric acid type, a molten carbonate type, a solid oxide type or a proton exchange membrane type electrolyte material. Both sides of the membrane electrode group 110 are self-forming. a catalyst layer (not shown) of the material of the catalyst layer such as platinum, nano gold, iron, cobalt, nickel, molybdenum or an alloy mixture containing the above metal for accelerating in the membrane electrode assembly The electrochemical reaction. The anode conductive sheet 12A and the cathode conductive sheet 13 are a sheet-like structure made of a material having conductivity and porosity, for example, a metal foil formed with fine perforations (not shown), carbon fiber. Or a graphite fiber sheet. The anode conductive sheet 12A and the cathode conductive sheet 130 are respectively disposed on both sides of the membrane electrode group 11 to allow hydrogen gas to enter the membrane electrode group 110 to generate an electrochemical reaction and conduct current. When the battery unit 100 When power generation is performed, hydrogen gas can enter the membrane electrode assembly 110 via the anode conductive sheet 120, and dissociate into electrons and hydrogen protons, and electrons flow out to form an electric current. Oxygen enters the membrane electrode group 1 via the cathode conductive sheet 13 and makes oxygen. Hydrogen protons and reflux electrons are reduced together to form water, and generate thermal energy (ie, by-product after electrochemical reaction). 200816549 As shown in Fig. 1, the first platen 200 and the second platen 600 in the first embodiment are disposed on The battery cells are unilaterally pressed to collectively tightly press the battery unit 1 to the fuel supply device 5. The first pressure plate 2 is made of an insulating material and is provided with a plurality of transparent materials. a hole 2丨〇, whereby when the first platen-200 is press-fitted to assemble the battery cells ι, the through hole 21 of the first platen 2〇〇 can supply oxygen into the battery unit 1; or the battery unit 1 By-product after power generation can be discharged through the through hole 2 1 〇. The second platen 6 is made of a porous material to allow hydrogen gas to pass therethrough. The filter membrane 300 is disposed on the first pressure plate 2 to filter impurities in the air to avoid affecting power generation efficiency. The cover plate 4 is disposed on the filter film 300. The cover plate 400 is provided with a plurality of through holes 41〇 to allow outside air to enter, and the cover plate 400 is made of a high rigidity material to protect the overall battery structure. As shown in FIG. 1 , the fuel supply device 5 of the first embodiment is disposed on the other side of the battery unit 100 and corresponds to the anode k V electric sheet 120 of the battery unit 1 to supply hydrogen gas to Battery unit 1〇〇. The fuel supply device 5 is in the form of a wind and can store the mouse roll, for example, by using a fuel supply device 5 - a hydrogen storage material (not shown), such as a hydrogen storage alloy, nano carbon or boride. Carbon, to store hydrogen,. In one embodiment, the fuel supply device 5 is configured to receive a hydrogen storage alloy material for supplying hydrogen, and the hydrogen storage alloy material is an alloy material capable of storing hydrogen gas, which has a large hydrogen storage capacity and is easy to activate (Aetivati〇n). The nitrogen absorption/nitrification chemical reaction rate is fast, the service life is long, and the cost is low, so that the volume and weight of the fuel supply device 500 can be reduced, thereby reducing the overall volume and weight of the fuel cell, and improving the overall battery efficiency. 10 200816549 The fuel supply device 500 is provided with a supply port 51〇 and an injection port 52〇, and the supply port 510 of the fuel supply device 500 is opened corresponding to the overall area of the battery cells 1〇〇 to make the hydrogen uniform. These battery cells are sufficiently diffused to generate electricity, thereby ensuring the power generation-efficiency of the battery unit 100. The injection port 520 of the fuel supply device 500 is for injecting supplementary fuel to avoid a shortage of fuel to supply power. An adjustment membrane 7〇〇 may be optionally disposed between the battery unit 100 and the fuel supply device 500, and the adjustment membrane 7〇〇 may adjust the hydrogen supply pressure or flow rate of the fuel supply device 500 to avoid the hydrogen supply of the fuel f supply device 5 The pressure is too large to damage the structure of the battery unit. Referring to Figure 3, there is shown a cross-sectional view of a series battery unit in accordance with a first embodiment of the present invention. Since the single battery unit 1 has only a fixed power output, the fuel cell of the present invention electrically connects a plurality of battery cells 100 in series to increase the overall power output. As shown in Fig. 3, the battery sheets are arranged side by side on a plane, but each two adjacent battery cells 100a and lb have a gap a to separate each two. Battery cells I 1 (10)' and 1 〇 Gb. In the embodiment, the void a may be filled with, for example, an insulating material to isolate every two battery cells i 00 . When the electrical connection is made, the anode conductive sheet 120a of each battery unit 100a is electrically connected to the cathode conductive sheet 130b of the other battery unit i〇〇b on the adjacent side by the wiring 14〇. The battery cells 100a*1〇〇b are electrically connected in series, so that the fuel cell of the first embodiment can select the overall power output corresponding to the series number of battery cells.曰 It is worth noting that 'in Figure 3A, the two adjacent battery sheets 200816549 yuan 100a and 100b are used for detailed description, but the fuel cell of the present invention does not limit its battery unit. The number of series of turns is determined by the number of series connected to its battery cells 100 depending on the demand for electrical output. Referring to FIG. 1 and FIG. 3, when assembled, the battery cells 1 are first arranged on a plane and electrically connected to each other, and then the first platen 2 and the second platen 600 are tightly stabilized. The battery cells 1 are pressed together to the fuel supply device 500, and the battery cells are assembled by the cover plate 4 on the fuel supply device 500, thereby forming the fuel cell of the present invention. When the fuel cell is generating electricity, the fuel supply device 500 can uniformly supply hydrogen gas to the battery unit 1 , and the oxygen in the outside air can enter the battery unit 100 from the cover 4 , thus eliminating the need for a pump or fan system. The auxiliary cycle provides fuel. In addition, the battery cells (10) are arranged and electrically connected in series on the plane of the fuel supply device 500, so the fuel cell of the present invention can increase the overall output power' without significantly increasing the overall thickness and volume, and can meet the miniaturization of the fuel cell. Demand. Please refer to FIG. 4 to FIG. 6 , FIG. 4 is a schematic diagram showing the unfolded structure of the conductive sheet set according to the second embodiment of the present invention, and FIG. 5 is a schematic cross-sectional view showing the battery unit according to the second embodiment. Figure 6 is a perspective view showing a single battery unit according to the second embodiment of the present invention. Compared with the anode conductive sheets 12A and the cathodes of the battery cells (10) of the second embodiment, the lengths of the sheets (4) are shorter, and are connected and combined with the % pole conductive sheets 120 by using a connecting portion 15? And the cathode conductive sheet ^ ^ the power blocking sheet 130 to form a conductive sheet group 15 〇 4 ® such that the anode conductive sheets 12G are located on the side of the connecting portion - the cathode conductive sheets (10) are located at the connecting portion 15G - 12 200816549 = and the anode conductive sheets 12G and the cathode conductive sheets are electrically connected in series. The connecting portion 15G is made of an insulating material, and the combined position of the anode conductive sheet 120 and the cathode conductive sheet 130 corresponds to the set position of the battery unit (8). When the fuel cell of the embodiment of FIGS. 4 to 6 is roughly mounted, the plurality of membrane electrode groups 110 are first arranged on a plane, and then the two conductive sheet groups 16 〇 are used to correspond to the membrane electrode groups. 11〇, (as shown in FIGS. 5 and 6), and the anode conductive sheet i2Q and the cathode conductive sheet 130 of the conductive sheet group 16G are respectively sandwiched between the opposite surfaces of the membrane electrode groups 11 and thus formed. The battery cells 100' of each of the battery cells are electrically connected to the cathode conductive sheets of the battery cells i 与其 on the adjacent side thereof by the wires 140. Next, the assembled battery unit 1 is tightly pressed against the fuel supply device 500 by the first pressure plate 2 (8) and the second pressure plate 600 to form the fuel cell of the second embodiment. Therefore, by: the electric piece & 160 corresponding to the end of the membrane electrode assembly 11〇, so that the battery: the overall structure of the crucible 100 can be more encrypted 'to avoid the occurrence of structural combination The situation thus increases the power generation efficiency of the fuel cell. It can be seen from the above embodiments of the present invention that the fuel cell of the present invention can make the fuel supplied from the material supply device and the oxygen in the outside air uniform and enter the battery cells, thereby improving the overall power generation. effectiveness. Since the =^ milk system is directly supplied by the fuel supply device and the outside air, there is no "or fan to supply hydrogen and oxygen to the shield ring, thereby reducing the overall design of the components to reduce the volume and weight of the fuel cell. The structure of the fuel cell of the present invention is closely sealed and thus can further provide power generation efficiency. Although the present invention has been disclosed above by way of example, it is not intended to limit the present invention. It is expected that: meat, hibiscus a, without departing from the sleeves 4 of the present invention, shall be subject to the definition of the patent application scope and the scope of the patent application. According to the simple description of the drawing, the image of the fuel cell of the first embodiment is shown in Fig. 1. The explosion of the fuel cell of the embodiment of the present invention is shown by the fuel cell according to the first embodiment of the present invention. A schematic diagram of the structure of the fuel cell in the first embodiment of the present invention. Fig. 4 is a diagram showing the conductivity of the fuel cell according to the second embodiment of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 5 is a cross-sectional view showing a battery unit of a fuel cell according to a second embodiment of the present invention. Fig. 6 is a view showing a single battery of a fuel cell according to a second embodiment of the present invention. A schematic diagram of a main unit: a: gap 100, 100a, 100b: battery unit no, 100a, 100b: membrane electrode group 120, 120a, 120b: anode conductive sheet 130, 130a, 130b: cathode conductive sheet 14 200816549 140 : Wiring 160 : Conductive sheet set 200 : First platen 300 : Filter film 4 1 0 : Through hole 5 1 0 : Feed port 600 : Second platen 150 : Connection portion 210 : Through hole 400 : Cover plate 500 : Fuel supply device 520 ··Injection port 700 ··Adjustment membrane
1515