TW200814928A - Fungicidal active compound combinations - Google Patents

Abstract

The novel active compound combinations comprising a carboxamide of the general formula (I) (group 1) in which R, R1 and R2 are as defined in the description, And the active compound groups (2) to (26) listed in the description have very good fungicidal properties.

Description

200814928 IX. OBJECTS OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to novel active compound compositions comprising a known sulphamine and a second known class of active compounds having a bactericidal activity, such active compounds. The material is extremely suitable for controlling unwanted plant pathogenic fungi. > [Prior Art] It is known that certain carboguanamines have fungicidal properties: for example, a team of 10 known from W〇2005/123689 (3,4,-difluorolinked stupid base_2_ W+methyl-3-(trifluoromethyl)-1Η-pyrazole carboxamide and N-(3,4,-dichlorobiphenyl-2·yl) from ^2005/123690 _3_(difluorodecyl η· decyl-1 Η-pyrazole-4-carboxyguanamine, these compounds have good activity, but are sometimes not satisfactory at low application rates; in addition, countless bismuths are known. 15 Azoline derivatives, aniline derivatives, dicarboxyboximides and other heterocyclics can be used to control fungi (Reference: Ep_ a 〇〇4〇345, DE-A 22 01 063, DE -A 23 24 010,Pesticide al面al,9th

Edition (1991), pages 249 and 827, EP_A 382 382 375 and Ep_A 〇 515 901), however, the effects of these compounds are often similarly low at low application rates. SUMMARY OF THE INVENTION We have found novel active compound compositions having excellent fungicidal properties, and which comprise a carboxamide of formula i (1) 200814928

Wherein R represents hydrogen or fluorine, R1 represents dentate, Ci-C^alkyl, CVC6-haloalkyl, cyano, nitro, CrCy alkoxy, having from 1 to 7 fluorine, chlorine and/or bromine atoms CrC3-halo-alkoxy or represent _c(R4)=N-OR5, R2 represents hydrogen, halogen, CrCV alkyl, Q-CV haloalkyl, cyano, schishyl, alkoxy' or a C1-C3-halo alkoxy group having 1 to 7 fluorine, gas and/or a desert atom, R4 representing hydrogen or methyl 'R5 representing a crc5-alkyl group, a CrC5-alkenyl group or a CrC5-alkynyl group, and at least An active compound selected from categories (2) to (26) below: ^£7}jL History of formula (II)

Where A1 represents one of the following bases: 200814928

A2 represents NH or 0, A3 represents N or CH, and 5 L represents one of the following groups: R12 *Production *8^0丫" *Bagua, N^N CH3 CH3 Among them, the bond marked with an asterisk (*) Attached to the phenyl ring, I0 Ru represents a stupid group, a benzylidene group, a phenoxy group or an acridinyl group, each of which is optionally one or two identical or different, selected from the group consisting of a gas, a cyano group, Substituted by a substituent of a fluorenyl group and a trifluoromethyl group, or represents 1-(4-phenylphenyl)oxazol-3-yl or represents 1,2-propanedi-bis(0-fluorenyl)-1- The base 'R12 stands for hydrogen or fluorine; 15 the third class (III) triazoles of formula (III)

Fish R14 20 wherein Q represents hydrogen or SH, m represents 0 or 1, R13 represents hydrogen, fluorine, gas, phenyl or 4-chlorophenoxy, R14 represents hydrogen or gas, and 200814928 A represents a direct bond...CH2.... (CH2)2· or _〇_, behalf of *-ch2-chr丨' or 'where the number marked with * is attached to the benzene ring, 5 where R15 and R17- represent -CH2-CH2-CH[CH(CH3) 2;H ° -CH2-CH2-C(CH3)2·, ' A5 stands for C or Si(矽), A also stands for -N(R17)- and A5 also together with Rb and R!6 stands for ON-R18 Base, which together represent the following base:

Vs port, where the key chain marked with * is attached to rI7,

Rl5 represents hydrogen, hydroxy or cyano,

Rl6 stands for 1-cyclopropylethyl, κ gas cyclopropyl, CrQ•alkyl, Ci_c 『Zhaojiaki' CrCr alkyl group, CVC2·dentate alkoxy-CVCV b alkyl, trimethyl矽alkyl_Cl_c2-alkyl, monofluorophenyl or phenyl, R 5 and R16 together represent _〇-CH2_CH(Ri8)-〇_,_〇Ch2_ CH(R18)-〇V,-0-CH( 0CH2CF3HCH2)2- or -0-CH-(2·gasphenyl)-, A, A5 and R15 are also represented together, CH=C>, wherein the bond marked with an * is attached to the stupid base ring, ^ 18 represents hydrogen, CrC4-alkyl or bromine; - Sulphenamides of formula (IV) 20 (IV) 200814928 fci2c,

Ch3 wherein R19 represents hydrogen or methyl; Valinamides from the lower jaw: (5-1) Iprovalicarb (5, 2) 妒-〇 (4- {[3 -(4-Phenylphenyl)-2-propynyl]oxy}methoxyphenyl)ethyl]-7V2-(indolylsulfonyl)-D-decylamine (5'3)benzene σ 塞 val ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben ben

χ/^Ν, Z wherein 15 X represents 2_chloro-3-cyanodinyl, which represents 2,4-dichloro-3-pyridinyl, which represents methyl, monofluoromethyl or tri-gas at the position of Xin 3 a 1-methylpyrazole-4-yl group substituted with a methyl group at the position of hydrogen or chlorine, representing a 4-ethyl-2-ethylamino-1,3-thiazole _5- group, representing 2_ Methyl 4-1,4-trifluoromethyl 丨, 3 thia thiol I represents 'h methylcyclohexyl, which stands for 2,2-dichloroethylidene 2〇T-cyclopropyl, representing 2_fluoro_ 2_propyl, 3,4-dichloroisoindolyl 5-yl, 5_,6 didihydro-2-methyl+4-oxathiohetero-3-yl, 4,4-dioxo 5,6_ Dihydro-1,4-oxothioheterocyclyl-3-yl, 4-methylammonium 2,3•thiadiazole_5_yl', 4'5-mercapto-2_dimethylstone shallow group叹 各 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' a phenyl group substituted with a substituent of 'methyl and difluoromethyl, or a methyl indol-3-yl group, Y representing a direct bond, optionally substituted with a chloro, cyano or oxo group Substituted CrC6-alkyldiyl (alkylene), Represents 仏<6-enediyl(alkenylene) or thiophenyldiyl, and Z represents a murine 'Ci-Cg-alkyl group or a group below:

A6 represents CH, CBr or N, 2 0 R represents hydrogen, gas, bromine, cyano or crcv alkyl, optionally selected from one or two identical or different selected from the group consisting of chlorine and bis(rcc3-alkyl)amine a phenyl group substituted with a substituent of a carbonyl group, or a cyclopropyl-cyclopropyl group which may be substituted by a methyl group, r21 represents hydrogen, chlorine or isopropoxy group, and R represents hydrogen, chlorine, bromine, hydroxy group, methyl group, Trifluorodecyl, trifluoromethoxy, or di(crc3-alkyl)aminocarbonyl, R20 and R21 together represent *-CH(CH3)-CH2-C(CH3)2- or *_CH(CH3) _0-C(CH3)2·, where the bond indicated by the * is attached to R20; the imaginary IZ) class is selected from the following dithiocarbamates: (7-1) Zinc Meng Nai Pu (mancozeb) (7-2) I Mengnai (maneb) -11 - 200814928 (7-3) ruin (metiram) (7-4) 曱基锌奈浦 (propineb) (7-5) thiram (7) -6) Zinb (Zineb) (7 knives) ziram (Acylalanines) (8)

10

* represents a carbon atom with R- or S-configuration, preferably for the s configurator, 23 R for the stupid methyl, furyl or decyl fluorenyl; 15 dior (YJI) of the amine-based bite class (Aflilinopyrimidiiies)

20 wherein R represents fluorenyl, cyclopropyl or 1-propynyl; ^^&丄: has the formula (vim of 1 imidazoles -12- 200814928 t27

Wherein R and R each represent hydrogen or together represent _〇_Cf2_〇_, R represents hydrogen, alkylamino group or represents 3,5-dimethylisox-4-yl continued g blue, R Represents chlorine, methoxylamino, chlorophenyl, fluorenyl or sinyl; M11M_ has a formula (DO urethane turns)

Η wherein R29 represents n- or isopropyl, R represents —(Ci-C)-alkyl)amino-C2-C4-alkyl or diethoxyphenyl, and 15 includes salts of these compounds; Poor (12) - selected from the following Dicarboximides · (12-1) tetramdan (captafol) (12_2) eptan (12. 3)培(f〇ipet) 20 (H4) 依普同 (ipr〇di〇ne) (12-5) 灭宁宁(proCymid〇ne) (12-6) 免克宁(vincl〇z〇lin) 盖ill class Selected from the following Guanidines: dodine -13· 200814928 (13-2) guazatine (13-3) diinoctyl triacetate (im3-4) ) 克热净 (burning benzoate) [iminoctadine tris (albesilate)] (13-5) donin (dodine) 5 (13-6) gram heat (immoctadine) (free test) (14) Classes are selected from the following mouths (Imidazoles) · (14-1) Cytofamid | (14-2) (14-3) Triazoxide ίο (14- 4) pefurazoate cover (15) morpholine (or its salt) of formula (X)

Wherein R31 and R32 independently of each other represent hydrogen or methyl, R33 represents CrC14-alkyl (preferably C12-C14-alkyl), c5_C12-cycloalkyl (preferably ClQ-Cirb). a radical -C1-C4-alkyl group which may be substituted at the phenyl moiety with a halogen or CrCV alkyl group or a propylene group which may be substituted with a chlorophenyl group and a dimethoxyphenyl group; XI) of all kinds of mouth (Pyrroles;, -14-20 200814928 -35 τ

Wherein 5 R34 represents chlorine or cyano, R35 represents gas or determinate, R36 represents chlorine, | R35 and R36 together represent -0-CF2-0·; and Π7) are selected from the following (thio)phosphonic acid Ester: ίο (17-1) Forsythia-aluminum (fosetyl·A1) (17-2) phosphonic acid (17-3) sulphate sulphate (toldophos-methyl) Π8) genus (XII) Phenylethylamine

(ΧΠ) wherein R37 represents unsubstituted or substituted by fluorine-, chloro, bromo-, decyl- or ethyl-substituted 20 phenyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl Or 茚满基; Π9) is selected from the following fungicides (19-1) acibenzolar-S-methy 1 (19-2) chlorothalonil (19) -3) cymoxanil -15- 200814928 (19-4) granules (edifenplios) (19-5) where fascinated (famoxadone) (19-6) volts south (fluazinam) (19-7) Copper oxychloride 5

10 15

(19-8) Copper hydroxide (19-9) oxadixyl (19-10) spiroxamine (19-11) disulfide S dkhianon (19-12) benzene Metrafenone (19-13) fenamidone (19-14) 2,3-dibutyl-6-chlorothieno[2,3-d]pyrimidin-4(3H)- Ketone (19-15) probenazole (19-16) isofothiolane (19-17) kasugamycin (19.18) phthalide (19-19) Fermizone (19-20) tricyclazole (19-21) N-({4-[(cyclopropylamino)carbonyl)phenyl}sulfonyl)-2-methyl Oxybenzamide (19-22) 2-(4-chlorophenyl)-N-{2-[3-f-oxy-4-(prop-2-yn-1-yloxy)phenyl] Ethyl}propan-2-fast-1 -yloxy)ethinamide (19-23) quinoxyfen (20) selected from the following sulfur (urea) derivative (20-1) clone (pencycuron) -16- 20 200814928 (20-2) 曱 _ thiophanate-methyl (20-3) ethyl-polyphanate-ethyl (21) class (XIII) Amidoxime

CI

among them

10 A7 represents a direct bond or -〇-, A8 represents -C(=0)NH· or -NHC(=0)-, R38 represents hydrogen or CrC4-alkyl, R39 represents CrC6-alkyl; ΆίΖΖΙΜ XIV) Triazoles (Triazolopvrimidines) 15

Wherein r4Q represents CVCV alkyl or CVCV alkenyl, R41 represents CrC6-alkyl, and R4G and R41 together represent C4-Cr alkanediyl (alkylene) substituted with 1 or 2 CrC6-alkyl substituents. , R42 represents bromine or gas, R and R independently represent nitrogen, and gas 'chloro or methyl' R and R independently of each other represent nitrogen or gas, -17-20 200814928 R represents hydrogen, fluorine or methyl, (23) The break of the type (XV) j^WIodochromones) 〇

Wherein R represents CrC6-alkyl, R49 represents CrC6.alkyl, C2-C6-alkenyl or CVC6-alkynyl; ΜΙΖ^ύΜ has the formula iXVI) of Biphenylcarboxamides

Wherein 15 R represents hydrogen or fluorine, _ R51 represents fluorine, chlorine, bromine, methyl, trifluoromethyl, trifluoromethoxy, -CH=N-OMe or -C(Me)=N-OMe, 52 R Represents hydrogen, fluorine, chlorine, bromine, methyl or tri-anthracene,

Het represents one of the following Hetl to Het7 bases:

53 R represents iodine, methyl, difluorodecyl or trifluoromethyl, -18- 200814928 R54 represents hydrogen, fluorine, chlorine or sulfhydryl, R55 represents methyl, difluoromethyl or trifluoromethyl, R56 represents Chlorine, bromine, iodine, methyl, difluoromethyl or trifluoromethyl, R57 represents methyl or trifluoromethyl; 5 wherein the biphenyl carbamide of formula (XVI) and the carboxy hydrazine of formula (1) The amines are different; the alkyl carboxamides of formula (25) having the formula (XVII)

10

among them

Het is defined as before, R58 stands for hydrogen or fluorine, 15

R59 represents hydrogen, halogen, CrC3-alkyl or CrC3-haloalkyl having 1 to 7 fluorine, chlorine and/or bromine atoms, and alkylcarboxamide having the formula (XVIII) of (26)

Wherein r6() represents hydrogen or fluorine, and -19-20 200814928 R represents hydrogen, halogen, Ci-C3-alkyl or cvc3-haloalkyl having 1 to 7 fluorine, chlorine and/or bromine atoms. A' represents one of the following A'l to A, 8 bases

R62 represents crc3-alkyl, R represents hydrogen, halogen, C1-C3-alkyl or has 1 to 7 fluorine, gas and/or bromine atom crc3-haloalkyl, r64 represents hydrogen, halogen or CrC3- Alkyl, 15 R 5 represents halogen, CrCy alkyl or C1-C3-haloalkyl having 1 to 7 fluorine, chlorine and/or bromine atoms, R represents argon, halogen or CrCy alkyl, amine group , mono- or di(crC3-alkyl)amine, R represents hydrogen, halogen, Ci_C3-alkyl or a 1 to 7 fluoro, chloro and 20/ or bromo atomic crc3-haloalkyl, R 8 Represents halogen, CrCV alkyl or C1-C3-haloalkyl having 1 to 7 fluorine, chlorine and/or odor atoms, r69 representing halogen, CrC3_alkyl or having 1 to 7 fluorine, chlorine And/or C1-C3--based alkyl group of the atom, -20- 200814928 R7〇 represents hydrazine, halogen, CrC3-alkyl or crc3-halo having 1 to 7 fluorine, chlorine and/or bromine atoms alkyl. 5

10 15

Surprisingly, the fungicidal effect of the active compound compositions according to the invention is much greater than the sum of the activities of the individual active compounds, so that unanticipated synergistic effects exist and are not merely phases The compound added as the class (1) represents the general definition by the formula (I). Preferred derivatives of the formula (I) are those wherein R represents hydrogen or fluorine, and R1 represents fluorine, chlorine, bromine, iodine, decyl, ethyl, n-propyl, isopropyl, trifluoromethyl. , trichloromethyl, cyano, methoxy, ethoxy, n-propoxy, isopropoxy, trifluoromethoxy, trichloromethoxy or -c(r4)=n-or5, R2 represents hydrogen, fluorine, chlorine, bromine, iodine, decyl, ethyl, n-propyl, isopropyl, trifluoromethyl, trichloroindolyl, cyano, methoxy, ethoxy, n-propyl Oxy, isopropoxy, trifluoromethoxy or represents trichloromethoxy, R4 represents hydrogen or methyl, and R5 represents CrC5-alkyl. Particularly preferred carboxyguanamines of the formula (1) are those wherein R represents hydrogen or fluorine, and R1 represents fluorine, chloro, decyl, trifluoromethyl, cyano, decyloxy, trifluoromethoxy, trichlorophosphonium Or represents -CH=N-OCH3, R2 represents hydrogen, fluoro, chloro, decyl, trifluoromethyl, cyano, decyloxy, trifluoromethoxy or trichloromethoxy, -21 - 20 According to another embodiment of the present invention, preferred amines of formula (1) are those in which the R 2 group is located at the 2,_ position of the distal phenyl ring of the biphenyl group (nearly adjacent) Phenyl ring). The formula (I) comprises, in particular, the preferred carboxamides of the following class (1) (Ref. 5: WO 2005/123689 and WO 2005/123690): (1-1) N-(3,4 - Monochlorobiphenyl-2-yl)-1-methyl-3-(trifluoromethyl)-1Η" than 4-sulfenylamine, (ι·2)Ν-(3, chlorobenzo fluoride biphenyl Base; _ methyl-3-(trifluoromethyl)-1Η-pyrazole carboxamide, (1-3) N-(2,4,-dichlorobiphenyl-2-yl)-1 -methyl-3-(trifluoromethyl)·1Η_pyrazole-4_carboxamide, (1_4) Ν伐 4'·difluorobiphenyl-2-yl) small methyl each (three said A Base)_m"pyrazole carboxamide, (1-5) N-(2,5,2-dichlorobiphenyl 1 yl) small methyl each (trimethylmethylHH4 嗤 ice carboxamide, ( 1_6) post ^ two said biphenyl winter base) * methyl-3-(difluoroindolyl) · 1Η" than salivary amine, (Bai N_ (4, · chlorine 1 said joint stupid base 4 base) -1-methyl|(trifluoromethyl HH•吼嗤* oxime, (Bu 0 15 team (heart 2,-methyl phenyl), small methyl winter (Santun 曱基)_1H 』••Sal+(tetra)amine, (1·9) phenylbiphenyl-2.yl)]-methyl=(trimethyl)-1Η-(tetra)-4 amide, (1)〇) N book , Methyl phenyl phenyl-2-yl) sulfhydryl-3-(trifluoromethyl)嗤* 绫 胺 , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , Methylbiphenylmethane)+methyl-3-(difluoroindolyl)-ih』h4·Dangan, 〇(3)Νκ二气联基基-2-yl)小methyl each (trifluoromethyl) Base) m4-Weiamine, (1-14) N-(2'-gas methoxy-linked phenyl 2) benzyl-3-yl _(trifluoromethyl MH-mouth than winter 4- Carboxylamamine, (17) team (2,6,-difluorobiphenylmethylene) small-22 - 200814928 methyl (trifluoromethyl)-lH-pyrazole winter carboxamide, (1 -16) Ν-(3,,5,-dimethylbiphenyl-2-yl) benzhydryl (trifluoromethyl)_1H-pyrazole-4-carboxamide, 〇17) N-( 4'-Chloro-3'-nitrobiphenyl-2-yl)-1-methyl-3-(3-trifluoromethyl)-1Η-indazole 4-carboxamide, (Μ8)Ν-[3 \5,-bis(trifluoromethyl)biphenyl 5 meryl l·1, methyl each (trifluoromethyl)-lH-pyrazole-4-carboxamide, (1-19) Ν-( 3,4-Methylbiphenyl-2-yl)-1-methyl-3-(trifluoromethyl-s-carboxycarboxamide, (1-20) 1-methylnitro-3, -(trifluoromethyl)biphenyl |-2-yl](trifluoromethyl)-1Η^bazole-4-treazone, (1-21) Ν-(4,-Methoxy-3'-methylbiphenyl-2-yl)_1-methyl-3-(tri-f-methyl hydrazide), dimethoxybiphenyl-2- ))-1-methyl-3-(trifluoromethyl)-1 Η-carbazole 'carboxycarboxamide' (1·23) Ν-(3,-fluoro-4,-methoxybiphenyl-2 -yl) benzhydryl-3 -(trifluoromethyl)-1 oxime-4-carboxychiral amine, (1-24) Ν-(4,_chloro-3'-methoxybiphenyl winter base ) small methyl 3-(3-trifluoromethyl)·1Η^biazole benzalamine, (1-25) Ν·[4'_chloro-3'-(trifluoromethyl)biphenyl·2 _ base] small methyl 15 -3_(trifluoromethyl)-1 Η ^ 峻 醯 carboxy carbamide, (1-26) Ν-(3,,5,-dichlorobiphenyl _ -2- -1-methyl-3-(trifluoromethyl babi-4-reamine, (1-27) > Η4,-methoxy-2, _methylbiphenyl-2-yl )_1_Methyl·3_(trifluoromethyl)-1Η-pyrazole 4-carboxamide, (1-28) Ν-(3,4^ dichlorobiphenyl-2-yl) fluorenyl -3-(difluoroindolyl sit _4·Wei-enamine, (1_29) N-(3,-gas-4,·20 fluorobiphenylmethanol)-1•methyl-3-(two gas Kibiw-4-sulfonamide, (1_30) N-(2f,4'-dichlorobiphenyl-2-yl)small methyl_3_(difluoromethyl)·ΐΗ_pyrazole ice carboamide , (1-31) N- (3,4,4-difluorobiphenylyl)methylene-M difluoromethyl)-1Η-°Bizozol-4-carboxyguanamine, (1·32) N-(2,,5 ,-dichlorobiphenyl mercapto) small methyl-3-(difluoromethyl)-111-% azole _4-carboxycarnitine, (Bu 33) -23- 200814928 N-(2f,5'- Difluorobiphenyl-2-yl)-1-methyl-3-(difluoromethyl)_1Η-indopazole carboxamide, (I-34) Ν·(4,-chloro-2,·1 Biphenyl 1 yl) + methyl each (difluoromethyl hydrazine - azole azole carboxy carbamide, (l-35) N-(4, - gas_2, _methylbiphenyl_2_ -l-mercapto-3-(difluoromethyl)-lH-pyrazole-4-decylamine, (1_36) N-(4f_ 5 chloro-3-methylbiphenyl-2-yl) -1-methyl-3-(difluoromethyl-sodium carbofuramide, (1·37) team (4,-fluoro-2,-methylbiphenylj-yl) fluorenyl (difluorocarbamate) Base)-1Η^biazole ice carbofuramide, (1-38) sense (4,-fluoro-3,-mercaptobiphenyl-2-yl)-1-methyl winter (difluoromethyl)- 1Η-ϋ比嗤-4--test amine, (1_39) Ν-(4,_chloro-3'-fluoro-2'-methylbiphenyl-2-yl)-1-indenyl (difluoro Methyl)_道_吼吼ίο -4-carboxyl-amine '(1-40) N-(2',4'-difluorobiphenyl-2-yl)-1_methyl_3_(二气^ Methyl)-1Η-pyrazole ice carboxy Amine, (1-41) N-(2,-fluoro-4'-methoxybiphenyl-2-yl)-1-methyl-3-(difluoromethylcarboxylate, (1-42) ) Ν-ΡΆ1-fluorobiphenyl-2-yl)-1-methyl-3-(di-Imethyl-s--4-carboxycarboxamide, (1-43) N-(3f,5,-two Methylbiphenyl-2-yl) benzhydrin-3-(two isis methyl)-1Η-pyrazole-4-carboxamide, (1·44) N-(4,-chloro-3' · Nitrobiphenyl-2- yl) small methyl each (difluoromethyl)-1 Η-pyrazole-4-carboxamide, (1-45) N-[3,,5,- bis ( Difluoromethyl)biphenyl-2-yl]-1-indolyl-3-(dimethylsulfate-4-carboxamide, (1-46) Ν-(3',4'-dimethyl Base phenyl-2-yl)-1-methyl-3-(difluoromethyl)-1 Η-pyrazole-4-carboxamide, (1-47) 1-mercapto-N-[4, -nitro-3H tris(2)fluoromethyl)biphenyl-2-yl]-3-(difluoroindolyl)-1Η^bazole-4-carboxamide, (1-48) N-(4 '-Methoxy-3'-methylbiphenyl-2-yl)-1-methyl-3-(difluoromethyl)-1Η-pyrazole-4-carboxyguanamine, (1·49) N-(3',4'-Dimethoxybiphenyl-2-yl)-1-methyl-3-(difluoromethyl)-1Η·carbazole-4-carboxamide, (1- 50) N-(3'-fluoromethoxybiphenyl-2-yl) benzhydrin-3-(difluoromethylhydrazine-hydrazine -4- -24- 200814928 Carboxylamidine, (1_51) N-(4,-chloro-3, methoxybiphenyl-2-yl) small methyl (difluoromethyl)-1Η Carbazole|Carboxylamidine, (1-52) N-[4f-chloro-3,-(trifluoromethyl)biphenylmungyl]methylenemethyl(difluoromethyl)-1Η^bazole-4 - Carboxylamamine '(1-53) Ν-(3',5,-Dichlorobiphenyl-2-yl)beryl (difluoromethyl)-1Η-pyrazole-4-carboxyguanamine ,(1-54) Ν-(4,·methoxy-2,-methylbiphenyl-2-yl)beryl mercapto (difluoroindolyl)_ΐΗ-π-pyrazole_4_carboxamide ,(1-55) 3-(Difluoromethyl[(6)-(methoxyimino)methyl]-u,-biphenyl-2-yl}smallmethyl-1pyrazole carboxamide ,(1-56) 3H-trifluoromethyl[(5)-(decyloxyimino)indolyl]-;[,;[,-biphenyl-2-yl}-1-methyl-1 //-pyrazole-4-carboxyguanamine, [(5)-(methoxyimino)methyl]-biphenyl-2-yl} beryllyl winter (trifluoromethyl)-1/ /-pyrazole 4-carboxyguanamine, (1_58) > (difluoromethyl) good "4, _[(6) oximeimido) methyl] biphenyl-2-yl} fluorenyl -1 music. Butyrazole carbamazepine, (1-59) [(quinone-n-butoxyimino)methyl]biphenyl-2-yl}-1-methyl-3-(trifluoromethyl) Biazole-4-carboxydecylamine, (1-60) Ν-{4,-[(1Ζ)-Ν-ethoxyethyl quinone imino]biphenyl meryl} small methyl winter (trifluoromethane -1//-pyridin 4-carboxydecylamine, (1-61) 1-methyl-exhaustion of {4,-[(1Ζ)-fluorenyl-propoxyacetamido]biphenyl- 2-yl}3·(trifluoromethyl ϋ -4--4--4-oxo-amine, (1-62) 1{44(6)-(isopropoxyimino)indolyl]biphenyl-glycolyl}-] -methyl-3-(trifluoromethyl)-1/^biazole_4_carboxamide, (1_63)#-{4,-(£>(ethoxyimino)indolyl} Benyl-2-yl]-1-mercapto-3-(trimethylsulfonyl)-1//-u than sal-4-carboxylic acid amine '(1-64) 1-mercapto-cui {4, -[(£>(propoxyimino)indolyl]biphenyl-2-ylbu-3-(trifluoromethylpyrazole-4-4carboxamide, (1-65) A^{44 (1Z)-N-isopropoxyacetammine]biphenyl-2-yl-2-methyl-25- 200814928 Winter (trifluoromethyl)-1 and pyrazole-4-carboxyindole Amine, (1-66) 7V-{4,_[(1Z)-N-butoxyacetamido]biphenyl-2-ylbu 1-indolyl-3-(trifluoromethyl) -1 Dan _ oxazol-4-carboxyguanamine, (1-67 ),{3,-chloro-4,-[(5)-(decyloxy-imino)methyl] hydrazino-2-yl}-1-methyl-3-(trimethylmethyl) -1//-° than 嗤-4-decanoate, 5 (1-68) decyloxyimido)methyl]biphenyl-2-yl}small methyl winter (trifluoromethyl)- 1 private pyrazole-4-carboxyguanamine, (1-69) to the end of {4,-[(1Ε)-Ν-methoxyethylidene imino]biphenyl-2-yl}-1-fluorenyl -3-(trifluoromethyl)-1 pirin | azole ice carboxamide, (1-70) 7V-{3L fluoro-4'-[(£>(methoxyimino)methyl] Biphenyl-2-yl}-1-methyl-3-(trifluoromethyl)-1 ugly-pyrazole-4-carboxamide, ίο U-71) Μdifluoromethylfluoro-4'- [(5)-(Methoxyimino)indenyl]biphenyl-2-yl}-1-methyl-1//-pyrazole winter carboxamide, (1-72) cyclopropyl Oxy)imido]methylidene-2-yl)methylmethyl(trifluoromethyl)-m-pyrazole-4-carboxamide, (1-73) ?H4,-[ (5Η Butoxyimino)methyl]biphenyl-2-yl}-3-(difluoromethyl)-1-indolyl-1-le-15-oxazole-carbocarboxamide, (1- 74) 3-(Difluoroindenyl) U4,-[(1E)-N-methoxy-ethylideneimido]biphenyl-2-yl}-1_methyl-1//-pyrazole _4_Carboxyamine, (1-75) '{3' Fluor-4'-[(five )-(propoxyimino)methyl]biphenyl-2-yl}small methyl-3-(trifluoromethyl)-1/^pyrazolecarboxamide, (1_76) 3-( Difluoromethylfluoro-44 (£>(propoxyimino)methyl]biphenyl-2-yl}small 20 fluorenyl-1#•pyrazole 1 carboxamide, (1-77) ,{2,-chloro-4,-[(5)-(methoxyimino)methyl]biphenyl-2-ylbu-1-indolyl_3·(trifluoromethyl)-1 -. Biazole-4-carboxycyanamine, (1-78) I{3'H[(1E)-N-propoxyethylideneimido]biphenyl-2-yl}small methyl-3-( Trifluoromethyl)·ιπ. Biazole-4-carboxyguanamine, (1-79) 3-(difluoromethyl)-good {3,-fluoro-4,-[(1Ε)-fluorenyl-propoxyacetamido]biphenyl -26 - 200814928 benzyl-2-yl}small methyl-1//-吼w-4--4-carbylamine, (1-80) 3-(difluoroindolyl)-exhaustive {3'-fluoro·4' -[(1Ε)-Ν-methoxyethinium imino]biphenyl-2-yl}small methyl-1--pyrazole-4-carboxamide, (1-81) Λ^{ 3, _1-4,-[(1Ε)-Ν-methoxyethyl quinone imino]biphenyl-2-yl} hydrazinoyl (trifluoromethyl)-1 pyrazole-4-carboxylate Indoleamine, (1-82), {3,-chloro-4,-[(^)-:^-methoxyacetamido]biphenyl-2-yl}-3-(difluoromethyl) Base)-1 - mercaptopyrene-4-carboxyl: tyrosine, (1-83) chloro-44(1Ε)-Ν-methoxyethoxylated imino]biphenyl-2-yl}-1 _Methyl-3-(tri-Imethyl)-1//-° than 嗤-4-sodium amide, (1-84) 3-(difluoromethyl hydrazine-methyl-ΑΜ4'-[(6)- (propoxyimino)indenyl]biphenyl-2-yl}-1 ugly-oxazole-4-carboxyguanamine, (1-85) ΛΓ-{4,-[(5)-(A Oxyimido)methyl]-31-methylbiphenyl-2-yl}-1-methyl winter (trifluoromethyl)-1-carbazole carbamide, (1-86) 3-(Difluoromethyl)small methyl U4,-[(lE)-isl·propoxyacetamidine Imino]biphenyl-2-yl}-1//-pyrazole-4-carboxamide, (1-87) 3-(difluoroindolyl)-indole-{44(1 E)-N -isopropoxyacetammine]biphenyl-2-yl}-1-indolyl ΐπpyrazole-4-carboxyguanamine, (1·88) Ν-(4,-{(Ζ) -[(allyloxy)imino]indenyl}bibenyl-2-yl)-3-(difluoro(methyl)-1 -methyl-1 oxazole-4-carboxamide, ( 1-89) Ν-(4,-{(ΖΗ(allyloxy)imino]methyl}biphenyl-2-yl)-1·methyl-3-(trifluoromethyl)-1 //-carbazole-4-carboxamide, (1-90) 3-(difluoromethyl[(penta)-(methoxyimino)indolyl]·3'-methylbenzidine- 2-yl}-1-indolyl-1//- ϋ比嗤-4-Rebel amine '(1-91) I{4'-{(1Z)-N-(allyloxy)ethene Amino}biphenyl-2-yl}small methyl-3-(trifluoromethyl)_ι//·π-pyrazole_4·carboxamide, (1-92)ΛΜ4,·[(1Ε)- Ν-(allyloxy)acetammine]biphenyl-2-yl}-3-(difluoroindolyl)-1-methyl-1//-pyrazole-4-carboxamide (1-93) Λ^{4,-[(1Ε)-Ν-(but-2-yne_1_yloxy) -27- 200814928 Ethylene imine]biphenyl-, phenyl-methyl _3_(trifluoromethyl-isopyrazole_4_carboxamide, (1-94)1-mercapto #(4,-{(1Ε)-Ν-[( 1-methylprop-2-enyl small group) oxy] acetamido]}biphenyl-2-yl)-3-(trifluoromethyl)-1 private pyrazole _4_carboxamide, ( 1-95) 1-decyl-Λ44'-{(ιε)-Ν·[(2-methylprop-2-en-1-yl)oxy] 5 acetamido]}biphenyl)- 3-(trifluoromethyl)-1//-lazolyl 4-mercaptoamine, (1-96) 1-indenyl-iV-{4'-[(lE)-N-(prop-2- Alkyn-1-yloxy)-acetamidomino]biphenyl-2-ylbu 3-(trifluoromethyl-pyr-4-rebel, (1-97) | fluorenyl-fluoromethyl)- 1-methyl-specific {4'-[(lE)-N-(propyl H)-yloxy]ethinyl}}biphenyl-2-yl}-1/^ ratio α sitting_4_slow acid Amine, (1-98) #-{2,-gas 10 this [(6)_(methoxyimino)methyl] phenylidene carbazyl 3-(difluoromethyl)small methyl-1 Oxazole-4-carboxyguanamine, (1-99) nonyloxyimido) fluorenyl]-2'-methylbiphenyl-2-yl}-1-methyl}-3-(trifluoromethyl) ) -17 -17 -17 -4- 醯 醯 醯 醯, (1-100) #_{4,-[(1Ζ)-Ν-butoxyacetamido]] phenyl-2-yl} (Difluoromethyl) small methyl group is 0 _4_carboxamide, (i-ioi) 15 3_(difluoroindolyl [(penta-isopropoxyimino)methyl]biphenyl- 2- _ yl} small methyl-1/ί- 0 than 嗤-4-treazone, (1-1 02) 3-(Difluoromethyl)-exhaustive {4'-[(5)-(methoxyimino)indolyl]-2,-methylbiphenyl-2-yl}-1-indole Kibi sal-4-carboxamide, (1_1〇3)豕{3,_chloro-44(penta)-(methoxyimino)indolyl]biphenyl-2-yl}-3-( Difluoromethyl)-1-methyl-1//-2-pyrazole-4-carboxamide, (1-104) 3-(difluoroindolyl)-indole-{2,-fluoro-4, -[(5)-(decyloxyimino)methyl]biphenyl-2-yl}_1_mercapto-17/-σ ratio tr aruin, (1·105) M{2' -Fluoro-4'-[(phantom-(methoxyimino)methyl]biphenyl-2-yl}-1 -methyl-3-(tripdenyl thioglycolamine). The compound of formula (II) comprises the following preferred blend of pair (2): -28- 200814928 (2-1) azoxystrobin (obtained from: EP-A 0382 375), with The chemical formula is: 〇

M CN

YV

(2-2) Fluoxastrobin (known from: DE_A 196 02 095), with the chemical formula:

(2-3) (2 Magic-2-(2-{[6-(3-Chloro-2-indolylphenoxy)-5-fluoro-4-pyrimidinyl] 15

Oxygen}phenyl)-2-(methoxyimino)-oxime/"methylacetic acid amine (obtained from: DE_A 196 46 407, ΕΡ-Β 0 712 396), with the chemical formula:

(2-4) Trifloxystrobin (available from: EP-A 0 460 575) with a chemical formula of 20 200814928 〇

(2-5) (2 5)-2-(oximeoxyiminomethyl-2-(2-{[({(l 5)·Η3- 5 (trifluoromethyl)phenyl]) }}-amino)oxy]methyl}phenyl)acetamide (known from: ΕΡ-Α0 569 384), with the chemical formula:

10 〇

(2-6) (2£>2-(decyloxyiminomethyl-2-{2-[(5)-({1-[3-(trifluoromethyl)phenyl]ethoxy) (imino)-methyl]phenyl}acetamide (known from: ΕΡ-Α0 596 254), with the chemical formula: 15

〇

(2-7) Adiscalin (orsastrobin X is known from: DE-A 195 39 324), with the chemical formula: 〇

(2-8) 5-Methoxy-2·indolyl-4-(2-{[({(1) singular [3_(trifluoromethyl)phenyl) -30- 20 200814928 ethylenediyl)amine Oxy]-methyl}phenyl)_2,4-dihydro-3F-1,2,4-triazol-3-one (obtained from: WO 98/23155), having the chemical formula:

(2-9) Kresoxim-methyl (know from EP-A 0 253 213) with the chemical formula:

15

(2-10) dimoxystrobin (known from: ΕΡ-Α0 398 692), with the chemical formula:

(2-11) picoxystrobin (known from: ΕΡ-Α0 278 595), with the chemical formula: -31- .200814928 ο

(2-12) Pyraclostrobin (known from: DE_A44 23 612), with the chemical formula:

10 〇

(2-13) Metominostrobin (available from: EP-A 0 398 692) with the chemical formula: 15

(2-14) enestrobin (known as EP-A 0 936 213) with the chemical formula:

The compound of formula (III) comprises the following preferred mixture of the class (3) - 32- 200814928 (3-1) azaconazole (known from: DE_A 25 51 560), having the chemical formula for:

5 (3-2) Itaconazole (known from: DE-A25 51 560), with the chemical formula:

10

(3-3) propiconazole (known from: DE-A 25 51 560), with the chemical formula:

15 (3-4) Waiting for difanoconazole (available from: EP-A 0 112 284), with the chemical formula:

(3-5) Bromoclazole (bromuconazoleX is known from: EP-A 0 258 161), -33- 20 200814928

CH—(CH2)2CH3 CH0 has the chemical formula:

(3-6) cyproconazole (known from: DE-A 34 06 993), with the chemical formula:

(3-7) hexaconazole (known from: DE-A30 42 303), with the chemical formula: • (ch2) 3ch3 ch2 (3-8) penconazole (recognized from: DE -A 27 35 872), with the chemical formula: C! (3-9) myclobutanil (known from: ΕΡ-Α 0 145 294), -34- 200814928 with the chemical formula:

Cl

(ch2)3ch3

10

15

(3-10) tetraconazole (available from: EP-AO 234 242) with the chemical formula:

CI

CH-CHr〇~CF2CF2H (3-11) Fucaifu (fhitriafblX is known from: EP-A0 015 756), with the chemical formula:

F

(3-12) epoxiconazole (known from: ΕΡ-Α0 196 038), with the chemical formula:

(3-13) Flusilazole (obtained from: EP-A 0 068 813), with the formula -35- 20 200814928

(3-14) simeconazole (available from: EP-A 0 537 957) with the chemical formula: ΟΗ F—y--CH—Si(CH3)3 CH2 (3-15) Prothioconazole (available from: WO 96/16048) with the chemical formula: 15

(3_16) Fenbu Kang. Sitting (fenbuconazole) (learned from DE-A37 21 786) with the chemical formula: -36- 20 200814928

5 (3-17) tebuconazole (available from: EP-AO 040 345) with the chemical formula:

10 (3-18)

Ipconazole (known from: ΕΡ-Α0 329 397) with the chemical formula:

15

(3-19) metconazole (available from: EP-A 0 329 397) having the chemical formula:

(3-20) Triticonazole (available from: EP-A 0 378 953) with the chemical formula: -37- 20 200814928

(3-21) Bitertanol (known from: DE-A 23 24 010), with a chemical formula:

OH Ο - 〒H-CH-C(CH3)3 10 (3-22) triadimenol (known from: DE-A23 24 010), with chemical formula:

(3-23) Triadimefon (learned from: DE-A22 01 063), with a chemical formula.

(3-24) Fluconconazole X (fluquinconazoleX is known from: EP-A 0 183 458), with the chemical formula: -38- 20 200814928

(3-25) quinconazole (known from: EP-AO 183 458), with the chemical formula:

Ίο (3-26) Diclobutrazole (known from: DE-A 27 37 489), having the chemical formula:

15 (3-27) Deconazole (diniconazoleX is known from: DE-A30 10 560), with the chemical formula:

(3-28) Nikon 嗤-M (diniconazole-M) with the chemical formula: -39- 200814928

5 (3-29) Furconazole (available from: EP-AO 230 844), with a chemical formula:

10

(3-30) Uniconazole (known from: ££-eight 30 10 560), with the chemical formula:

15

(3-31) Uniconazole P, with the chemical formula:

The compound of formula (IV) comprises the following preferred complex of class (4): (4-1) dichloroflunisi (dichlofluanid X is known from: DE-A 11 93 498), -40- 20 200814928 With the chemical formula:

(4-2) Tolylfhianid (known as: DE-A 11 93 498),

10

DE_A 40 26 966), the preferred mixed counterpart of class (5) is: (5-1) Iprovalicarb (known from: 15 chemical formula:

2〇 (5-3) Benzoguanamine (ben1; hiavalicarb) (known to have the chemical formula: :WO 96/04252), -41 - 200814928

The compound of formula (V) comprises the following preferred complex of class (6): 5 (6-1) 2-Gas-N-(l,1,3-dimethylin-4-yl) In the acid test amine (known from: ΕΡ-Α0 256 503), the chemical formula is:

10

(6-2) Boscalid (known from: DE-A 195 31 813), with a chemical formula:

(6-3) Furametpyr (available from: EP-A 0315 502), with a chemical formula:

(6-4) Ν·(3-p-Tolylthiophen-2-yl)-1·indolyl-3-trifluorodecyl-1H-pyrazole-4-carboxamide (available from: ΕΡ- Α0 737 682), with the chemical formula -42- 200814928

C (6-5) ethaboxam (obtained from: EP-A 0 639 574) with the chemical formula:

〇 CN

(6-6) fenhexamid (known from: EP-A0 339 418), having the chemical formula:

(6-7) carpropamid (from ΕΡ·Α 0 341 475), with the chemical formula: 20

(6-8) 2-Gas-4-(2-Ga-2-mercaptopropylamino)-indole, fluorene-dimercaptobenzoic brewing>43- 200814928 Amine (Know from: EP- A0 600 629), with the chemical formula: 5

10 (6-9) fluopicolide (known from: WO 99/42447), with the chemical formula:

(6-10) Salicin (zoxamide) (obtained from: EP-A 0 604 019), with a chemical formula:

(6-11) 3,4-Dichloro-N-(2-cyanophenyl)isothiazol-5-carboxamide (available from: WO 99/24413), having the chemical formula:

(6-13⁄4 carb〇xin (obtained from: US 3,249,499), with the chemical formula -44· 200814928 as...

5 (6-13) tiadinil (obtained from: US 6,616,054) with the chemical formula:

10

15

(6-14 penthiopyrad (known from: EP-A 0 737 682), with the chemical formula:

(6-15) silthiofam (obtained from: WO 96/18631), with a chemical formula:

CH, (6-16) N-[2-(l,3-dimethylbutyl)phenyl]-1-methyl-4-(trifluoromethyl)- -45- 20 200814928 1H-pyrrole- 3-carboxyguanamine (known from: WO 02/38542) with the chemical formula:

(Heart 1?) Fortune (flutolanil X learned from: DE-A 27 31 522), with a chemical formula:

(6_18) Fenfuram (known from: 0£-eight 20 06471), with a chemical formula of two

(649) oxycarboxin (available from: US 3,399,214) with a chemical formula of:

(6-20) thifluzamide (known from: EP-A 0 371 950), with the chemical formula: -46- 200814928

(6-21) N-{2-[3-Chloro-5-(trifluoromethyl)acridin-2-yl]ethyl-2-(trifluoro-5methyl)benzamide, chemical formula :

10 (6-22) N-(2-Dicyclopropyl-2-ylphenyl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide (available from: WO 2006/015865), with chemical formula.

(6-23) N-(2-Dicyclopropyl-2-ylphenyl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide (available from: WO 2006 /015865), with the chemical formula:

(6-24) N-[2-(l'-Methylbicyclopropyl-2-yl)phenyl]-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxyguanamine (Knowed from: WO 2006/015865), -47- 200814928 has the chemical formula:

5

10 (6-25) Ν-[2-(Γ-Methylbicyclopropyl-2-yl)phenyl]-1-methyl-3-difluoromethyl-1Η-pyrazole carboxamide (known From: WO 2006/015865), with the chemical formula:

15

(6-26) Ν·[1 -(5- >odor-3-chloropyrene-pyridyl-2-yl)ethyl]-2,4-dialdehyde final amine amine, with the chemical formula:

(6-27) Bichuan>2-yl)methyl-2,4-dichloro acid in acid test, having the chemical formula:

The preferred blending partner of class (7) is: -48- 20 200814928 (7-1) (7-2) 5 (7-3) ίο (7-4) 15 (7-5) Zinc Manganese Mancozeb (known from: DE-A 12 34 704), having the IUPAC name: manganese ethylene bis(dithiocarbamate) (polymerizable) and zinc salt complex manganese (maneb) (from (US 2,504,404), with the chemical formula:

Free of metiram (known from: DE-A 1076434), having the IUPAC name: zinc amide ethylene bis(dithiocarbamate)-poly(ethylene thiuram disulfide) Methyl zinc is a propineb (known from: GB 935 981), with the chemical formula:

Thiram (available from: US 1,972,961) with the chemical formula:

(7-6) Zinna (Zineb) (known as DE-A 10 81 446), with chemical formula • 49-20.200814928

(7-7) Zirma (known from: US 2,588,428) with the chemical formula:

10

Ch3 ch3 The compound of the formula (VI) comprises the following preferred mixed complex of the (8) class (8-1) Bendal (benalaxyl X is known from: DE_A 29 03 612), and has a chemical formula:

15

(8-2) Furalaxyl (known from: DE-A 25 13 732), with the chemical formula:

(8-3) Metalaxyl (available from: DE-A 25 15 091), with a chemical formula: -50 - 20 200814928

5 (8-4) 灭达乐-Μ (known from: WO 96/01559), with the chemical formula:

Ίο (8-5) Bunda-M, with the chemical formula:

The compound of formula (VII) comprises the following preferred mixed partner of class (9): (9-1) cyprodinil (known from: EP-A 0 310 550) having the chemical formula .

Ch3 (9-2) mepanipyrim (known from: ΕΡ·Α 0 270 111), with the chemical formula: -51 - 200814928

5 (9-3) pyrimethanil (from DD 151 404), with chemical formula,

The compound of formula (VIII) comprises the following preferred blend of class (10):

(10-1) 6-Gas- 5-[(3,5-Dimercaptopurine-4-yl)-retinyl]-2,2-digas^ is -5H-[1,3 Dioxin and [4,5-f> benzimidazole (obtained from: WO _ 97/06171), with the chemical formula:

(10-2) benomyl (available from: US 3,631, 176), with the chemical formula -52 - 200814928

(10-3) carbendazim (available from: US 3,010,968) with a chemical formula:

(10-4) Chlorfenazole, which has the chemical formula:

(10-5) Mai Sui Ning (fuberidazoleX is known from: DE-A 12 09 799), with the chemical formula:

(10-6) thiabendazole (obtained from: US 3,206,468) with the chemical formula:

The compound of formula (IX) comprises the following preferred blend of pair (11) - 53-20 200814928: (1M) dithiofenac (didhofencarb X is known from: EP-A 0 078 663) :

EtO CH,

(11-2) propam〇carb (obtained from: US 3,513,241), with the chemical formula: .CH., Ν Η ! CH. (11-3) Propyl hydrochloride (pr0pam〇carl>liydrochloride ) (Know from: US 3,513,241), with the chemical formula: 15 Η CH,

HCI (11-4), fosetyi, with a chemical formula of 20 η^Λ h^ch3 f| VN - P -〇 CH,

H Preferred mixed partner of class (12) is: (12-1) tetramdanium (captaf〇i) (known from: us 3,178,447) ' has the chemical formula: -54- 200814928

(12-2) Captan (available from: US 2,553,770) with the chemical formula:

5 (12-3) Folpet (known from: US2, 553, 770) with the chemical formula:

10 (12-4) Iprodione (available from: DE-A 21 49 923), with a chemical formula: 15

(12-5) Procymidone (known from: DE-A 20 12 656), with the chemical formula:

CI

CI (12-6) vinclozolin (known from: DE-A 22 07 576), with a chemical formula: -55- 20 200814928

5 The preferred mixed counterpart of class (13) is: (13-1) dodine (known from: GB 11 03 989), with the chemical formula:

(13-2) Suazatine (available from: GB 11 14 155) (13-3) Gminoctadine triacetate (known from: EP-A 0 155 509), with chemical formula for:

Hr nh2 15 ) gram heat (burning benzoate) [iminoctadine tris (albesilate)] (derived from: ΕΡ-Α0 155 509), with the chemical formula:

S〇3H 2〇 5) Doning (dodine) (1 η ~ ml (13-6) gram heat (imm〇ctadine) (free test), with the chemical formula: -56- 200814928

Preferred mixed partners of class (14) are: (14-1) cyazofamid (available from: EP-A 0 298 196) having the chemical formula:

10

CN CI^^/N, s〇2MMe2 Φ ch3 (14-2) Prochloraz (learned from: DE-A 24 29 523), with a chemical formula: 15

CI

(14-3) Triazoxide (known from: DE_A 28 02 488), with 20 formulas:

(14-4) Pefurazoate (known from: ΕΡ·Α 0 248 086), with -57- 200814928

10 15

The compound of formula (X) comprises the following preferred mixed partner of class (15): (15-1) Adelmo (&1 out 111〇卬11) (from 00 140 041) , with the chemical formula:

CH CH, (15-2) tridemorph (known from: GB 988 630), with the chemical formula:

Ch3 (15-3) dodemorph (known from: DE-A 25 432 79), with a chemical formula: -58 - 200814928

Or diclofenac 5 (15-4) fenpropimorph (known from: DE-A 26 56 747), with the chemical formula:

(15-5) Dafenfen (dimethomorphX is known from: EP-A 0219 756), with the chemical formula:

The compound of formula (XI) comprises the following preferred mixed pair 20 of class (16): (16-1) fenbikini (fbnpiclonil K is known from: EP-A 0236 272), having the chemical formula: - 59- 200814928

NC

NH

Cl Cl EP-A 0 206 999), with :JP 65-25876), with (16-2) fludioxonil (known from the chemical formula: Η

(16-3) σ pyrrolnitrin (known as self-learning:

CI

CI NO. The preferred hybrid partner of class (17) is: 15 (17-1) fosetyl-Al (known from: DE-A 24 56 627), having the chemical formula: Π A1H, ΌΗ 20 (17-2) phosphonic acid (known chemical) with chemical formula f?

Hoi

OH (17-3) tolclophos-methyl (known from: DE-A25 01 • 60- 200814928 040) with the chemical formula: h3c

Cl

s 0 令 0, Cl 〜CH, CH. The compound of formula (XII) comprises the preferred mixed partner of class (18) below, which is known from WO 96/23793 and each may be E or Z The isomer is present, therefore, the compound of formula (XII) may be a mixture of different ratios of isomers, or a single isomer form, preferably a compound of formula (XII) E isomer: (18-1) compound 2-(2,3-dihydro-1H-indol-5-yl)-N-[2-(3,4-dimethoxyphenyl)ethyl] -2-(methoxyimino)acetamide with the chemical formula: 15

(18-2) Compound N-[2-(3,4-Dimethoxyphenyl)ethyl]-2-(methoxyimino)-2-(5,6,7,8-tetra Nitrogen-Cai-2-yl)Ethylamine has the chemical formula:

(18·3) Compound 2-(4-chlorophenyl)-N-[2-(3,4-dimethoxyphenyl)ethyl]methoxyimino)-ethonamide For ·· -61 - 20 200814928

5 (18-4) Compound 2-(4-Bromophenyl)-N-[2-(3,4-dimethoxyphenyl)ethyl]-2-(methoxyimino)-B Indoleamine, with the chemical formula:

10

(18-5) Compound 2-(4-methylphenyl)-N-[2-(3,4-dimethoxyphenyl)ethyl]-2-(decyloxyimino)-B Indoleamine, with the chemical formula:

15

(18-6) Compound 2-(4-ethylphenyl)-N-[2-(3,4-dimethoxyphenyl)ethyl]-2-(decyloxyimino)-B Indoleamine, with the chemical formula:

A preferred mixed partner of the (19) class is: -62- 200814928 (19-1) acibenzolar-S_methyl (known from: ΕΡ-Α0 313 512), having the chemical formula :

10 (19-2) chlorothalonil (available from: US3, 290, 353) with a chemical formula:

CN

(19-3) cymoxanil (available from: DE-A 23 12 956) with the chemical formula: 15

(19-4) edifenphos (known as DE-A 14 93 736), with a chemical formula:

(19_5) Where is the famoxadone (available from: EP-A 0 393 911), with -63- 20 200814928 The chemical formula is:

10 (19-6) volts to the south (fluazinam) (obtained from: EP-A 0 031 257), with a chemical formula:

15

(19-7) Copper oxychloride (19-9) oxadixyl (obtained from: 0£-eight 30 30 026), with the chemical formula:

(19-10) Spiroxamine (known from: DE-A 37 35 555), having the chemical formula:

H3c (19-11) dithianon (available from: JP-A 44-29464), with chemistry -64-20 201414928: 〇

ο (19_12) metrafenone (known from: ΕΡ-Α 0 897 904), with the chemical formula:

(19-13) fenamidone (known from: ΕΡ-Α 0 629 616), with the chemical formula:

(19-14) 2,3-Dibutyl-6-oxothieno[2,3-d]pyrimidin-4 (3H> ketone (obtained from: WO 99/14202) having the chemical formula:

(19-15) Probenazole (available from: US 3,629,428) with a chemical formula: -65- 200814928

10 > 〇 , (19-16) Isoprothiolane (obtained from: US 3,856,814), with a chemical formula:

(19-17) Carbachol (1<^1^3111>^11) (from 〇3 1 094 567), with the chemical formula:

15

(19-18) phthalide (known from: JP-A 57-55844), with the chemical formula:

CI (19-19) Ferimzone (available from: EP-A 0 019 450) with the chemical formula: -66- 200814928

(19-20) Tricyclazole (known as DE-A 22 50 077) with the chemical formula:

10 (19-21) N-({4-[(cyclopropylamino)carbonyl]phenyl}sulfonyl)-2-methoxybenzenecarbamamine, with the chemical formula...

15

(19-22) 2-(4-Chlorophenyl)-N-{2-[3-methoxy-4-(prop-2-yn-1-yloxy)phenyl]ethylpropan-2- Fast-1-yloxy)ethylamine (known from: WO 01/87822), with the chemical formula:

(19_23) quinoxyfen (known from: EP-A 0326 330), with a chemical formula: -67- 20 200814928 C!

F. Preferred mixed partner of class (20) is: (20-1) pencycuron (known as DE-A 27 32 257) with a chemical formula of:

(20-2) thiophanate-methyl (obtained from: DE-A 18 06 123), with the chemical formula:

Η Η (20-3) ethyl-polyphanate-ethyl (known from: DE-A 18 06 123), with the chemical formula:

Η 较佳 Preferred mixed partner of class (21) is: -68- 200814928 (21-1) fenoxanil (known from: EP-A 0 262 393), having the chemical formula:

5 (21-2) Diclocymet (known from: JP-A 7-206608), with the chemical formula: The preferred blend of the (22) class is: (22-1) 5-Chloro-N-[(lS)-2,2,2-trifluoro-1-methylethyl]-6-(2,4,6-trifluorophenyl)[1,2,4] Zoledolo[l,5-a]pyrimidin-7-amine (obtained from: US is 5,986,135) with the chemical formula:

2〇(22-2) 5-Gas-N-[(1R)-1,2-Dimercaptopropyl]-6-(2,4,6-trisylphenyl)[1,2,4] Triazolo[l,5-a]pyrimidin-7-amine (known from: WO 02/38565) with the chemical formula: -69- 200814928

(22-3) 5-Chloro-6-(2-aero-6-phenylphenyl)-7-(4-mercaptohexanitropyridinium-1-yl) 5 [1,2,4]triazole And [l,5-a]-pyrimidine (known from: US 5,593,996), with the chemical formula:

10

(22-4) 5-Chloro-6·(2,4,6-trifluorophenyl)-7-(4-mercaptohexahydroacridin-1-yl)[1,2,4]triazole [l,5-a]pyrimidine (known from: DE-A 101 24 208) with the chemical formula: 15

A preferred mixed partner of the (23) class is: (23_ 1) 2-butoxy-6-bromo-3-propylbenzoquinone σ-pyran-4-嗣 (known from WO 03/014103 ), with the chemical formula: -70- 20 200814928 Ο

(23-2) 2-Ethoxy-6-iodo-3-propylbenzopyran-4-one (obtained from: WO 03/014103), having the chemical formula:

^ ^ ch3 ch3

10 (23-3) 6-iodo-2-propoxy-3-propylbenzopyran-4-one (obtained from: WO 03/014103), having the chemical formula:

(23-4) 2-but-2-Quinyloxy-6-bromo-3-propylphenylpyrenepyran-4-pyrene (obtained from: WO 03/014103), with the chemical formula: 15

〇

(23-5) 6-Moth-2-(1-decylbutyryl)-3-propylbenzoquinone 1^pyran-4-嗣 (obtained from: WO 03/014103), with the chemical formula:

(23-6) 2-but-3-enyloxy-6-iodobenzopyran-4-one (obtained from: WO 03/014103) with the chemical formula: -71 ~ 20 200814928

(23-7) 3-butyl-6-iodo-2-isopropoxybenzopyran-4-one (obtained from: WO 03/014103) having the chemical formula:

10 〇

Preferred mixed partners of class (24) are: (24-1) N-(3',4'-dichloro-5-fluorobiphenyl-2-yl)-3-(difluoromethyl) )-1 -Methyl-1H-pyrazole-4-carboxyguanamine (known from: WO 03/070705), with the chemical formula: 15

(24-2) 4-(Difluoromethyl)-2-methyl-N-[4f•(trifluoromethylbiphenyl-2-yl)-1,3-thiazole-5-carboxamide ( Learned from: WO 03/066610), with the chemical formula: -72- 20 200814928

5 (24-3) N-(3'-Gas-4'-chlorobiphenyl-2-yl)-4·(dioxamethyl)-2-methyl-1,3-thiazole-5-carboxylate Guanamine (available from: WO 03/066610) with the chemical formula:

(24-4) N-(3',4'-Dichloro-1, fluorene-biphenyl-2-yl> 5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxylate Indoleamine (known from: WO 00/14701), with chemical formula.

2〇(24-5) N-(4'-gas-3'-random-l,r_biphenyl-2-yl)-2-mercapto-4-(trimethylmethyl)-1,3 -thiazole-5-carboxamide (available from: W0 03/066609) with the chemical formula: -73- 200814928

5 (24-6) N-(4'-chlorobiphenyl-2-yl)-4-(difluoromethyl)-2-mercapto-1,3-thiazole-5-carboxyguanamine (known From: WO 03/066610), with chemical formula

(24-7) ΛΚ4'·bromo-1,Γ-biphenyl-2-yl)-4-(difluoroindolyl)-2-indolyl gastric 1,3-thiazole-5-carboxyguanamine Known from: WO 03/066610), with 15 learning styles:

Preferred mixed partners of class (25) are: (25-1) Λ42-(1,3-dimercaptobutyl)phenyl]-1,3-dimethyl-lif-mouthbazole- 4-carboxyguanamine with the chemical formula: -74- 20 200814928

(25-2) Falling {2-(l,3-dimethylbutyl)phenylfluoro-1,3-dimethyl-5 pyrazole-4-carboxamide (available from: WO 03/010149) With chemical formula

(25-3) Λ42-(1,3-dimethylbutyl)phenyl]_5-chloro-1,3-dimethyl-1phenazineazole-4-carboxamide (available from: JP- A 10-251240), with the chemical formula:

15 (25-4) 3-(Difluoromethyl)-7\^[2-(1,3-dimethylbutyl)phenyl]_ι·methyl-1//-pyrazole-4-carboxylate Indoleamine, with the chemical formula:

(25-5) 3-(Trifluoromethyl)-[2-(1,3-dimethylbutyl)phenyl]oxofluoromethyl-177-pyrazole-4-carboxamide (known From: DE-A 103 03 589), -75« 200814928 The chemical formula is:

(25-6) 3-(Trifluoromethyl)_#_[2_(1,3-dimethylbutyl)phenyl]_5_qimethyl than salivation-4_tetamine (known from: jp_A 仙), • has the chemical formula:

(25-7) 1,3-Dimethyl#[2,3,3-trimethyl)phenyl^ is more than a salicylamine (known as JP-A 10-251240), with a chemical formula for:

(25-8) 5-Fluoro-1,3-dimethylso[2(1,3,3·trimethylbutyl) stupid base]• Heart ratio n entrained amine (known from: WO 03 /010149), with chemical formula

(25-9) 3-(disodium methyl) small methyl good [2_(1,3,3_tridecylbutyl) stupid-76- 200814928 base]4 pyrazole-4-carboxyguanamine, With the chemical formula:

(25-10) 3-(Trifluoromethyl)-1-methyltrimethylbutyl)phenyl]-1//-pyrazole-4-carboxyguanamine, having the chemical formula··

(25-11) 3-(dimethylmethyl)-5 far-1_indolyl tridecylbutyl) phenyl hydrazine hydrazine carbaryl amide (known from: dE-A 103 〇 3 589 ), with the chemical formula:

(25_12)t(trifluoromethyl)·5-chloro-1-methyl good [2-(1,3,3-trimethylbutyl)phenyl]-1 dan·^ than sal-4-carboxyl Guanamine (known from: jp A 1〇_25124〇), with the chemical formula: 200814928

5(25-13)#-[2-(1,3-(dimethylbutyl)phenyl)-2-iodobenridamide (known from: DE-A 102 29 595), with chemical formula :

(25-14) 2-iodo, 3,3-trimethylbutyl)phenyl]benzamide (found from: DE-A 102 29 595), having the chemical formula:

(25-15) 豕[2-(1,3-Dimethylbutyl)phenyl]-2-(trifluoromethyl)benzamide (available from: DE-A 102 29 595), with The chemical formula is:

(25-16) 2-(Trifluoromethyl)-7V-[2-(l,3,3-tridecylbutyl)phenyl]benzamide-78- 20 200814928 Amine (Know from: DE -A 102 29 595), with the chemical formula:

5 The compound of the formula (XVIII) comprises the following preferred compound of the above (26) class | Pair: (26-1) 5-fluoro-1,3-didecyl-N-[2-(3-曱 butyl phenyl) phenyl; HH-carbazole ίο -4-carboxamide, with the chemical formula:

15

(26-2) 3-(Difluoroindolyl)-N-[2-(3,3-dimercaptobutyl)-4-fluorophenyl]-1-indenyl-1//*pyrazole 4 - Carboxylamamine, with the chemical formula:

(26-3) 3-(Difluoromethyl)-indole-[2-(3,3·didecylbutyl)phenyl]-1-methyl-1Η-pyrazole-4-carboxamide, With the chemical formula: -79- 200814928

(26-4) N-[2-(3,3-dimethylbutyl)phenyl]-2-(trifluoromethyl)benzamide, having the chemical formula:

(26-5) N-[2-(3,3-dimethylbutyl)-4-fluorophenyl]-2-methyl ice (trifluoromethyl)-1,3-thiazole-5- Carboxyamine, with the chemical formula:

15

(26-6) N-[2-(3,3-Dimethylbutyl)-3-methylthiophene-2-carboxamide, with chemical formula:

(All are known from WO 2005/042494). The compound (6-7), caipropamid, has three asymmetric substituted carbon atoms, and therefore, the compound (6-7) may be a mixture formed of different isomers or a separate component. The type, particularly excellent compound 20 200814928 is (^3i〇-2,2-dichlorophenyl)ethyl]-1-ethyl-3-methylcyclopropanecarboxamide, which has the chemical formula:

And (/iU*S>2,2-dioxane (1 〇 small (4-chlorophenyl)ethyl) small ethyl _3_methylcyclopropanecarboxamide, having the chemical formula:

15 Particularly preferred active compounds of the above categories (2) to (26) are the following activated compounds: (2-1) azoxy Str〇bin, (2-2) fluoxastrobin ( Fluoxastrobin),(2_3) (2£>2-(2- {[6-(3-chloro-2-methylphenoxy)_5_fluoro-4-pyrimidinyl]oxy yphenyl)-2- (methoxyanilide)-oxime-methylacetamide, (2_4) trifloxystrobin, (2-5) (2£>2-(methoxyimino)# Methyl 2-(2_{[({(1))-1-[3_(difluoromethyl)phenyl]ethanediylamino)oxy]methyl}phenyl)acetamidamine' (2· 6) (2 phantom (methoxyimino)·|^^ -2-{2-[(5)-({1-[3-(trifluoromethyl)phenyl]ethoxy oxime) Aminomethyl]phenyl}acetamidamine, (2-8) 5-methoxy-2-methyl ice (2-{[({(1) is a small [3_(three gas-81 - 200814928 methyl) Phenyl]ethylenediyl}amino)oxy]-methyl}phenyl)-2,4-dihydro-3F-1,2,4-triazol-3-one' (2-9) Kresoxim-methyl, (2-10) dimoxystrobin, (2-11) picoxystrobin, (2-12) pyracostrobin, 2 -13 ) 5 phenoxystrobin (metominostrobin), (2-14) Enestrobin, (3-3) propiconazole, (3-4) difenoconazole, (3-6) cyproconazole, (3-7) ) hexaconazole, (3-8) penconazole, (3-9) myclobutanil, (3·10) tetraconazole, (3-12) 10 epoxiconazole, (3-13) flusilazole, (3-15) prothioconazole, (3-16) fenbuconazole, (3- 17) tebuconazole, (3-19) metconazole, (3-21) than bitertanol, (3-22) triadimenol, 〇23) tritopine (triadimefon), (3-24) fluquinconazole, (3-26) diclobutrazole, _ (3-27) diniconazole, (4-1) Dichlofluanid '(4-2) 曱基益发灵 (tolylfhianid), (5-1) isopropyl carbamide (iprovalicarb), (5-3) benzothiazol (benAiavalicarb), (6_2) Boscalid, (6-5) ethaboxam, (6-6) guanidine 20 fenhexamid ), (6-7) carpropamid, (6-8) 2-gas-4-(2-fluoro-2-methylpropanylamino)_condition #-dimethylbenzamide , (6-9) bactericide (picobenzamid), (6_10) zoxamide, (6-11) 3,4-dichloro-N-(2-cyanophenyl) iso-salt- 5-treazone, (6-14) σs-subtilamine (penthiopyrad), (6-16) Λ42-(1,3-didecylbutyl)phenyl]-1-methyl-82- 200814928 ice (trifluoromethyl)_1 ugly 吼 吼 -3--3-carboxamide, (6-17) flutolanil, (6·21) N-{2-〇chloro·5-(trifluoromethyl Π-pyridinyl]ethyl}-2-(trifluoromethyl)benzamide, (6-22) Ν-(2-bicyclopropyl-2-ylphenyl)-diphenyl-3- Fluoromethyl-lji-u is more than salivary _4_ apoein, (6-23) Ν-(2-bis 5 propyl propyl-2-ylphenyl)-1-methyl-3- dioxin methyl -111-° than saliva-4-rebel, (6-24) Ν-[2-(Γ-methylbicyclopropyl-2-yl)phenyl]-1-methyl-3-trifluoromethyl Base-1-pyrazole-4-carboxyguanamine, (6-25) Ν-[2-(indolyl-bicyclopropyl-2-yl), phenyl]-1-methyl-3-difluoro曱基-1Η· σ比峻-4- slowly brewing amine, (6-26) N-[l-(5-bromo-3-gas 0-bit-2-yl)ethyl]-2,4-di chlorine In the test of amine, (6,27) ίο Ν·(5-bromo-3-chloropyridin-2-yl)methyl-2,4-di-nicotinamide, (7-1) zinc snail (mancozeb), (7-2) Manna, (7-4) methyl zinc (propineb), (7-5) thiram, (7-6) zinc napu ( Zineb), (8-l) Benalaxyl, (8-2) furalaxyl, (8-3) metalaxyl, (8, 4) vandal-M ( metalaxyl-M), (8:5) Bendais is -M (benalaxyl-M), (9,1) cyprodinil, (9-2) mepanipyrim, (9 -3) Pyrimen (pyrimethanil), (10-1) 6-

W chloro-5-[(3,5-dimethylisoxazol-4-yl)sulfonyl]-2,2-difluoro-5H-[1,3]di-sigma oxo[4,5 -f]-benzopyrene, (10-3) carbendazim, (11-1) diefhofencarb, (11-2) propamocarb, 2〇 (11 -3) propamocarb_hydrochloride, (11-4), fosetyl, (12-2), Gapdan (^?丨 & 11), (12-3) Folpet, (12-4) iprodione, (12-5) procymidone, (13-1) dodine, (13-2) gram heat (guazatine) ), (13-3) bis-octylamine triacetate (iminoctadine • 83- 200814928 triacetate) '(14-1) Cyazofainid, (14-2) prochloraz, (14-3) Triazoxide, (15-4) fenpropimorph, (15-5) dimethomorph, (16-2) fludioxonil, (17-1)赛得-aluminium (fbsetyl-Al), (17-2) 5 phosphonic acid '(17·3) sulphate (toldophos-methyl), (19-1) benzothiazolidine (acibenzolar-S) -methyl) , (19-2) chlorothalonil, (19-3) Cymoxanil, (19-5) famoxadone, (19-6) fluazinam, (19-7) copper oxychloride, (19_9) octopus (oxadixyl), (19-10) snail ί spiroxamine, (19-13) fenamidone, (19-22) 2-(4-chlorophenyl)-N-{2- [3-methoxy-4-(prop-2-ynyloxy)phenyl]ethyl}-2-(prop-2-yn-1-yloxy)acetamidamine, (19-23) Quinoxyfen, (20-1) pencycuron, (2〇-2) thiophenate- thiophenate-methyl, (22-1) 5-chloro-Λ4 (/5>2, 2,2_Trifluoro-l is methylethyl] each (2,4,6-trifluorophenyl)[1,2,4]tri. Sit and [l,5-a], dentate amine, (22-2) 5-chlorodimercaptopropyl]-6-(2,4,6-trifluorobenzene-yl)[1,2,4 Triazolo[l,5_a]pyrimidin-7-amine, (22-4) 5-chloro(2,4,6-triphenyl)-7-(4-mercaptohexahydroacridine-1 -yl)[1,2,4]triazolo[l,5-a]pyrimidine, (23-1) 2-butoxy-6-bromo-3-propylbenzopyran-4·one ,(23-2) 2-ethoxy-2-mercapto-6-iodo-3-propylbenzopyran-', (23-3) 6-iodo-2-propoxy-3-propylbenzene And ketone-4·one, (24-1) 沁(3,,4,-dichloro-5-fluoro·1,1'-biphenyl-2-yl)-3·(di-It methyl)- 1-methyl-p-indene-4-carboxylamine, (24-7) Λ^(4,_bromo-1, fluoren-biphenyl-2-yl)-4-(difluoroindolyl)-2- Methyl-1,3H5-decylamine, (25-1) 1[2-(1,3-didecylbutyl)phenyl]-indole, 3·dimethyl-1//•pyrrole- 84- 200814928 领醯amine, (25_2) ^{2_(1,3_dimethylbutyl)phenyl b-5_气妙二Y base-1 heart than saliva-continued _, (25_8) methyl good [ 2(1,3,3-dimethylbutyl)phenylhydrazine//" than saliva_4_rebellion_, (25·13^_[2 (ι,3 (dimethyl)phenyl))- 2-iodobenzoguanamine, (25_15) as far as {2_〇,3-dimethylbutanyl)phenyltrifluoro Methyl) benzoic acid amine. The excellent active compounds of the above categories (2) to (26) are the following active compounds: | (2-2) Fluorine. _ _ flu (fluoxastrobin), (2-3) (2 5)-2-(2-{[6-(3-chloro-2-methylphenoxy)_5-fluoropyridinyl]oxy}phenyl ) winter (nonoxyimino) good 10 mercaptoamine, (2.4), trifloxystrobin, (3-15) prothioconazole, (3,17) Tebuconazole, (3-21) bitertanol, (3-22) triadimenol, (3-24) fluquinconazole, (4-1) dichlorofluoride (dichlofluanid), (4-2) methyl phenylephrine (tolylfluanid), (5-1) isopropyl amide 15 (iprovalicarb), (6-6) fenhexamid, (6-7) Caipropamid, (6-9) picobenzamid, (6-14) penthiopyrad, (6-17) fhitolanil, (6-21) Ν-{ 2-[3-Chloro-5-(trifluoromethyl)pyridin-2-yl]ethyl 2-(trifluoromethyl)benzamide, (6-22) N-(2-bicyclopropyl -2-ylphenyl)-1-indolyl-3-trifluoromethyl-1H-port ratio 20 azole-4-carboxyguanamine, (6-23) Ν-(2-bicyclopropyl-2-yl Phenyl)-1-mercapto-3-difluoromethyl-1H-pyrazole-4-carboxamide, (6-24) Ν-[2-(Γ-methylbicyclopropyl-2-yl) benzene 1-methyl-3-trifluoromethyl-lH-u-pyrazole·4·carboxamide, (6-25) Ν-〇(Γ-methylbicyclopropyl-2-yl)phenyl ··1-Mercapto-3-difluoromethyl-1Η-pyrazole-4-carboxamide, (6-26)Ν-[1-(5-bromo-3-pyridin-2-yl)B Base]-2,4- -85- 200814928 Dichloronicotinium amide, (6-27) 1^-(5-bromo-3-chloropyridin-2-yl)indolyl-2,4-dichloro醯 醯 ''(7_4) 曱 锌 乃 ( (pr〇pineb), (8_4) 达达乐-M (metalaxyl-M), (8-5) 达达乐_M (benalaxyl-M), (9 No. 3) Pyrimethanil, (10-3) Befendazim, (11-4) Pu 5 Buck-Fusie Fu (f〇setyl) '(12-4) Yi Putong Iprocji〇ne), (14-2) prochloraz, (14-3) triazoxide, (16-2) fludioxonil, (17-3) methyl chlorpyrifos (toidophos-methyl), except (19-10) spiroxamine, (19-22) 2-(4-phenylphenyl)-N-{2-[3-methoxy-4-( Prop-2-yne-1-yloxy)phenyl]ethyl}-2-(propyl-2-ίο alkynyloxy)ethinamide, (19-23) quinoxyfen, (22-4 ) 5-Chloro-6-(2,4,6-triIphenyl)-7-(4-methylhexahydroindole. Ding-1-yl)[1,2,4]triazino[l,5-a]pyrimidine, (24-1) A^(3f,4,-dichloro-5-fluoro·1, Γ-linked Phenyl-2-yl)-3-(difluoromethyl)succinymethyl-lif-pyrazole-4-carboxamide, (25-2) Λ^2-(1,3-dimercaptobutyl Phenyl}·5-fluoro-1,3-dimethyl-1-pyrazole-4-15 carboxamide, (25-13) ΛΓ-[2-(1,3-(dimethyl) Base) phenyl) winter iodobenzamide, amine. Preferred active compound compositions comprise two classes of active compounds and in each case: at least one carboxamide compound of formula (I) (category (1)) and at least one class (2) as described below To the compound of the class (26), these Group 2 conjugates are active compound compositions of hydrazine to W. A preferred active compound composition wherein the indoleamine compound of the formula (I) of the formula (I) is selected from the compounds listed in Table A below. - 86 - 200814928 Table A: Chemical Name of the Number Carboxamide (1-1) N-(3V^Dichlorobiphenyl-2-yl)小methyl-3-(trifluoromethyl)-1Η^Bizozol-4-carboxyguanamine (1-2) N_( 3'-Chloro-4'-fluorobiphenyl-2-yl) small methyl-3-(trifluoromethylpyrazole-4-carboxyguanamine (1-3) N-(2f, 4L dichlorinated Phenyl-2-yl)small methyl(trifluoromethyl)-1Η"pyrazole-4-carboxamide (1-4) N-(3f,4'-difluorobiphenyl-2-yl Small methyl each (trifluoromethyl)-1 Η-pyrazole-4-carboxamide (1-5) N-(2',5f-dichlorobiphenylmethylene) small methyl each (trifluoro Methyl)-1Η-pyrazol carboxamide (1-6) Ν-(2*,5*-di-biphenyl-2-yl)-1-methyl-3-(di Dunmethylmethyl) Indoleamine (1-7) N-(4'-gas-2'-fluorobiphenylmethanol) small methyl (trifluoromethyl)-1pyridazole ice carboguanamine (1-8) N- (4T-Gas-2'-Methylbiphenyl-2-yl)-1-methyl-3-(dimethylmethylguanamine (1-9) N-(4'-chloro-3'- Methyl biphenyl-2-yl) small methyl each (trifluoromethyl)-1 Η-carbazole winter carboxamide (1-10) N-(4L mouse - 2'-Methylbiphenyl-2-yl)-1-methyl-3-(dimethylmethyl)-1Η-σΛσ sit-4-decylamine (1-11) Ν-(4'-qi -3^·•Methylbiphenyl-2-yl)-1-methyl-3-(dimethyl-methyl-pyridin-4-indoleamine (1-12) N-(4f-gas-3' -gas methylbiphenyl-2-yl)-1-methyl-3-(dimethylmethyl)-1Η·α than 嗤-4-carboxyguanamine (1-13) Ν-(2',4 '-Difluorobiphenyl-2-yl) small methyl each (trifluoromethyl)-1 Η 比 azole carbamide (1-14) NW-fluoro U oxybiphenyl-2-yl) Small methyl-3-(trifluoromethyl)-1H"pyrazole carboxamide (1-15) di-biphenyl-2-yl)-1-methyl-3-(dimethyl) -1Η-ϋΐ^Sit-4-Weiamine-87- 200814928 No. Chemical name of carboxamide (1-16) N-(3',5f-dimethylbiphenyl-2-yl)methyl -3-(Trifluoromethyl)-1Η ^Bymazole Ice Carboxamide (1-17) N-(4'-Chloro U-Schothylbiphenyl-2-yl) Small Methyl-3-(Trifluoro Methyl)-1Η^Bizozol-4-carboxamide (1-18) N-[3\5f-bis(dimethylmethyl)biphenyl-2-yl]-1-methyl-3-( Dimethyl carbaryl carbamide (1-19) N-(3',4'-dimethylbiphenyl-2-yl) small methyl-3-(trifluoromethyl)·1Η·carbazole -4-carboxyguanamine (1-20) 1-methyl-N-[4W -3'-(trifluoromethyl)biphenyl-2-yl](trifluoromethyl)-1Η-α-pyrazole-4-carboxamide (1-21) N-(4f-methoxy -3^methylbiphenyl-2-yl)methylmethyl(trifluoromethyl)-1Η-indazole-4-carboxamide (1-22) N-(3*,4'-di Methoxybiphenyl-2-yl)-1-methyl-3-(dimethylmethyl)-1Η-ϋΛσ sit-4-decylamine (1-23) N-(3'-gas-4 '-Methyllacylbiphenyl-2-yl)-1-methyl-3-(dimethylcarbamoylamine (1-24) N-(4'-chloro-3'-methoxybiphenyl Benzyl-2-yl)methylmethyl(trifluoromethyl)-1Η-indazole-4-carboxamide (1-25) N-[4'-chloro-3H-trifluoromethyl)biphenyl- 2-yl]small methyl-3-(trifluoromethyl)-1Η^bazole-4-carboxamide (1-26) N-(3\5L di-biphenyl-2*•yl)- 1-methyl-3-(dimethylmethyl)-111-lasyl-4-indole amine (1-27) N-(4'-methoxy-2'-methylbiphenyl-2- 1-methyl-3-(trifluoromethyl)-1Η·carbazole-4-carboxamide (1-28) N-(3f,4L dichlorobiphenyl-2-yl)-1 -methyl each (difluoromethyl)-1 Η-carbazole-4-carboxamide (1-29) Ν-(3, chlorofluorobiphenyl-2-yl) small methyl-3-(difluoro Methyl)-1Η-indazole-4-carboxamide (1-30) N-(2',4f-dichlorobiphenyl-2-yl)-1 Di(difluorodecyl)-1H-pyrazole-4-carboxamide (1-31) N-(3', lenodifluorobiphenyl-2-yl) small methyl-3-(difluoro Methyl)-1Η-oxazole-4-carboxyguanamine-88- 200814928 No. Chemical name of carboxamide (1-32) ST-(2*,5*-di-biphenyl-2-yl)- 1-methyl-3-(dimethylmethyl^^.峻 - 斗 - weiwei amine (1-33) Ν-(2',5^difluorobiphenyl-2-yl) small methyl-3-(difluoromethylbiazole carbamoylamine (1 -34) N-(4'-Chloro-2匕fluorobiphenyl-2-yl)methylmethyl(difluoromethyl)-1Η-indazole carbamide (1-35) N-(4 *-Gas-2匕Methyl-benzino-2-yl)-1-methyl-3-(dimethylmethyl)-1Η-σ ratio -4-meramide (1-36) Ν-( 4'-Chloro-3' draw methylbiphenyl-2-yl)-1 ore methyl-3-(difluoromethyl) 111-0 than oral -4-nonanoic acid amine (1-37) N-(4L-gas-2f-methylbiphenyl-2-yl)-1-methyl-3-(di-methylmethylpropionamide (1-38) N-(4f-rat-3'-A Benzyl-2-yl)-1-methyl-3-(di-methyl)-111-° ratio 坐-4-decylamine (1-39) N-(4'-chloro-3f -Fluoro-2'-methylbiphenyl-2-yl)methanol (difluoromethyl)-111-3⁄4 oxazole-4-carboxamide (140) N-(2',4'- Difluorobiphenyl-2-yl) small methyl each (difluoroindolyl)-1Η-carbazole-4-carboxamide (1-41) Ν-(2. gas-4'-methoxy linkage Phenyl-2-yl)-1-methyl-3-(dioxamethylcarboxamide (1-42) N-(2f,6f-disorder biphenyl-2-yl)-1-methyl -3-(dimethyl fluorenyl)-1 Η-ϋ ratio 17 sitting -4- 竣 胺 (1-43) Ν-(3',5'-dimethyl Benzyl-2-yl)-1-methyl-3-(dimethylmethyl)-1Η-σ 嗤-4-竣 with amine (1-44) N-(4f-rat-3*-肖 肖 基 biphenyl-2-yl)-1-methyl-3-(disorder decyl decylamine (1-45) N-[3',5f-bis(trifluoromethyl)biphenyl-2 -yl]-1-methyl-3-(difluoromethyl)-1Η^biazole carbamide (1-46) N-(3',4'-dimethylbiphenyl-2-yl ) bismuthyl (difluoromethyl)-1 Η-carbazole-4·carboxycarboxamide (1-47) I-methyl "N-[4'-Shishouji-3f-(di-gas methyl) Phenyl-2-yl]-3-(dimethylmethyl)-1Η-σΛ azole-4-carboxyguanamine-89- 200814928 No. Chemical Name of Carboxylamamine (1-48) Ν·(4'-A Oxy-3'-mercaptobiphenyl-2-yl)methanol (difluoromethyl)_1H-indazole-4-carboxamide (1-49) N-(3',4'- Dimethoxybiphenylbiyl)small methyl(difluoromethyl)-1Η·carbazole carboxylamine (1-50) Ν-(3,-gas-4,-methoxybiphenyl Benzyl-2-yl)-1·methyl-3-(di-methyl)-1Η-oral ratio -4-carboxamide (1-51) N-(4f-chloro-3f-methoxy Biphenyl-2-yl)·1-methyl-3-(dimethylmethyl)-1Η-σ 嗤-4_ Carboxamide (1-52) Ν-[4'-chloro-3'-( Trifluoromethyl)biphenyl-2·yl]-1- Methyl (difluoromethyl)-1 Η·-Bizozol-4-carboxamide (1-53) N-dS'-di-r-phenylphenyl)-1-methyl-3-(two mouse Base)-1Η-ϋΛσ:^-4-decanoic acid amine (1-54) Ν-(4'-methoxy-2'-methylbiphenyl-2-yl)-1-methyl-3- (dimethyl)-lH-atb嗤-4-carboxamide (1-55) 3-(difluoromethyl)#{3'-fluoro-44((6)-(methoxyimino) A Base, Γ-biphenyl-2-ylmethylpyrazole 4-carboxydecylamine (1-56) 3-(trifluoromethyl)-indole 31-fluoro-44 (£>(methoxyiamine) Methyl]-1, fluorenyl-biphenyl-2-yl b-methylpyrazole-4-propanolamine (1-57) Ν_{4'·[(6)-(methoxyimino group )methyl]-biphenyl-2-yl}small methyl (trifluoromethyl)-1//-pyrazole-4-carboxamide (1-58) 3-(difluoromethyl)[ (6)-(Methoxyimino)methyl]biphenylmungyl}small methyl ratio -4--4-weisamine (1-59) (n-butoxyimino)methyl]biphenyl Benzyl-2-yl}-1-methyl-3-(dimethylmethyl)-1//-pyrazole 4-carboxamide (1-60) N-{44(1Z)-N-ethoxy Ethylene imido]biphenyl-2-yl}small methyl-3-(trifluoromethyl)-1//·carbazole 4-carboxamide (1-61) 1_mercapto-AL{ 44(1Z)-N-propoxyacetammine]biphenyl-2-yl}3-(three Methyl)-1//-carbazole-4-propanolamine (1-62) by {4'-[(6)-(isopropoxyimino)methyl]biphenyl-2-yl] - mercapto-3-(trifluoromethyl)-1 from ° 嗤-4-treazone (1-63) ΛΜ4'-(8)·(ethoxyimino)methyl}biphenyl-2 -yl}small methyl each (trifluoromethyl)-1//-°bazole-4·carboxamide-90- 200814928 No. Chemical name of carboxamide (1-64) 1 -methyl-^H4L [C£K propoxyimino)methyl]biphenyl-2-yl}-3-(3-mercaptomethyl)-1//-pyrazole-4-carboxamide (1-65) iV -{4'-[(lZ)-N-isopropoxyacetammine]biphenyl-2-yl}small methyl each (trifluoromethyl ratio σ sit-4-cartoamine (1 -66) ΛΓ-{44(1Ζ)-Ν-butoxyacetammine]biphenyl-2-ylbu-methyl-3-3(trifluoromethyl-pyria-4-hydrazide ( 1-67) iV~{3L Chlorine 44 (£>(decyloxy-imino)methyl]biphenyl-2-diylmethyl(trifluoromethyl)-1 from pyrazole-4-carboxyl Indoleamine (1-68) #-{34(幻·(methoxyimino)methyl]biphenyl-2-yl}-1-methyl each (trifluoromethyl)-1//- Pyrazole-4-carboxyguanamine (1-69) 7V»{44(1E)-N-methoxyethyl quinone imino]biphenylmethylene}methylmethyl(trifluoromethyl)-li /j ratio -4-Rebelamine (1-70) Private {3'-say _44(6)·(methoxyimino)methyl] phenylidene-2-yl}small methyl each (trifluoromethyl)- 1 Lepyrazol-4-carboxyguanamine (1-71) 3-(Difluoromethyl)-exhaustive {3'-fluoro 44 (£>(decyloxyimino)methyl]biphenyl- 2-yl}small methyl-1-leprazole-4-carboxamide (1-72) {(ZH(cyclopropylmethoxy)imido)methyl bphenyl-2-yl) small Methyl-3-(trifluoromethyl)-li^biazole carbamide (1-73) AM44 (£>(butoxyimino)methyl]biphenyl-2·kib 3 -(difluoromethyl)small methyl-1//-° ratio -4--4- Wei Si amine (1-74) 3-(difluoromethyl)# {44( 1 E)-N-methoxy Ethylene imido]biphenyl-2-yl}sodiummethyl-1/ί-pyrazole-4-carboxamide (1-75) iV_{3f-fluoro-4'-[(£)-( Propoxyimido)methyl]biphenyl-2-yl}-1-methyl-3-(3-trifluoromethyl)-li/·pyrazole-4-carboxyguanamine (1-76) 3 -(difluoromethyl)good {3'H[(£>(propoxyimino)methyl]biphenylyl-H-methyl-1-"pyrazole-4-carboxamide" 1-77) {Γ-Chloropi P>(methoxyimino)methyl]biphenyl-2-yl}-1 -methyl-3-(trifluoromethylcarbazole-4-carboxyindole Amine (1-78) ΛΜ3'-fluoro-44(1E)-N- Ethoxyacetimido]biphenylmungyl}]-methyl; (tri-1methyl)-1 private ratio salivary-4~tretachlor (1-79) 3-(difluoromethyl) #{,Fluorine 44(ie)-n-propoxyacetammine]biphenyl Z-based}small methyl-1 from pyrazole-carbocarboxamide-91 - 200814928 No. Chemical name of carboxamide 1-80) 3-(Difluoromethylfluoro-4'-[(1Ε)-fluorenyl-methoxyethylidene imino]biphenyl-2-yl}methylmethylpyrene-4-carboxyindole Amine (1-81) (1-82) M{3'-Fluoro-^[(ΙΕ^Ν·methoxyethyl quinone imino)biphenyl-2-yl}small methyl-3-(three Fluoromethyl)-1//-° ratio. -4-Si with amine chloro-4'-[(1Ε)-Ν-methoxyethyl hydrazide]biphenyl fluorenyl} each (difluoromethyl)_1_methyl-1 private ratio Oral -4-oxoamine (1-83) chloro-4'-[(1Ε)-Ν-methoxyethinylidene]biphenyl-2-yl}small methyl-3-(three Fluoromethyl) 4 cups pyrazole-4-carboxamide (1-84) 3-(difluoromethyl) small methyl #{44(6)-(propoxyimino)methyl]biphenyl-2 -yl}-1//^ is more than 嗤-4-weisamine (1-85) iH44 (£>(decyl imino)methyl]methylbiphenyl-2-yl} small methyl Each (tri-1methyl)-1//-° than wow-4-propanolamine (1 -86) Η difluoromethyl hydrazine-methyl #{4,-[(1Ε)-Ν-propoxy Ethyl imino]biphenyl-2-yl b l/ί-pyrazole-4-carboxamide (1-87) Η difluoromethyl ΗΗ 44 (ιε) good isopropoxyacetammine Biphenyl-2-yl b 1·methyl-1//^ than 嗤-4-carboxychiral amine (1-88) N-(4I-{(ZH(allyloxy)imido)] }}biphenyl-2-yl) winter (difluoromethyl) small methyl-1-leprazole carbaryl amide (1-89) Ν·(4Η(Ζ)-[(allyloxy) Amino]methyl}biphenyl-2-yl)small methyl each (trifluoromethyl-wow-4-weizamine (1-90) 3-(difluoromethyl HV-{44(£&gt) (methoxy imino group Methyl]-3,-fluorenylbiphenyl-2-yl}-1-methyl-1//-° than 嗤-4-treazone (1-91) iV-{4t-{(lZ) -N-(allyloxy)ethylidene imino}biphenylyl bromide; (trifluoromethyl)·17ϊ^bazole-4-carboxyguanamine (1-92) Μ{44( 1 Ε)-Ν-(allyloxy)ethylideneimine;|biphenyl-2_ylbu3·(difluoromethyl)small methyl-1//-° than 嗤-4- Indoleamine (1-93) is as far as {4'-[(1Ε)-Ν-(丁·2·alkyn-1-yloxy)ethylidene imino]biphenyl-2-yl}small methyl-3 -(Trifluoromethylbiwow-4-carboamine (1-94) 1-methyl#(4'-{(1Ε)-Ν-[(1-methylpropion!-enyl)oxy]B醯iminophosphonium biphenyl-2-yl)-3-(trifluoromethyl)-1loindole 嗤 ice carboxamide (1-95) 1-methyl#(4f-{(lE)-N -[(2_methylpropionene small)oxy]ethinylidene}biphenylyl)(trifluoromethyl)-1//-cafe-4-weizamide•92- 200814928 The chemical name of the number of carboxamide (1-96) 1 -methyl 1 EHSl · (prop-2-yne small oxygen) - acetamido] biphenyl-2-yl}-3- (-' Gas methyl ratio _4- succinimide (1-97) 3-f fluoro-methylmethyl #{44(1Ε)·Ν_(propionyloxy) etiminoimine} biphenyl Ke-2-yl}-1//^ ratio n rebel amine (1-98) Dedicated to the chlorine [[6)·(methoxyimino)methyl]biphenyl-mungyl} each (difluoromethyl)-1 ·methyl-1 ugly than the saliva "4_ recorded S-amine (1 -99) 曱oxyimino)methyl]_2L methylbiphenyl fluorenylmethyl} each (tri-II methyl Viz/Lir than 嗤_4_carboxamide (1-100) TV»{4L [(1Z) succinyloxyethylidene imino]biphenyl·2·kib 3-(difluoromethyl) fluorenyl-1//-° than 嗤 winter winding amine (1-101) 3-(Difluoroindolyl HV^{44(£>(isopropylideneimino)methyl]biphenylyl)methyl-1/ί-吼嗤-4-sulfanylamine (1 -102) ΗDifluoromethyl)#{44(£>(methoxyimino)methyl]-2,-methylbiphenyl mercaptopurine-methyl-1 carbazole-4- Carboxylamidine (1-103) M{3L chloro 4'-[(pentamethoxyanilide)methyl]biphenyl-2-ylbu 3-(difluoromethyl)smallmethyl-li /" 嗤 嗤 嗤 缓 ( 1-10 (1-104) 3-(Difluoromethyl> gt-{2^Fluoro-4f-[(£)-(methoxyimino)methyl]biphenyl _2_基}小methyl-Li/-σ ratio 吐-4-魏醯amine 〇105) Π{Π44(6)-(methoxyimino)methyl]biphenylmethylene}methyl; Fluorinyl Hif-pyrazole-4·carboxamide. In addition to the acid amine of the formula (1) of the formula (I), the active compound composition A also comprises the strobilurin of the formula (II) of the class (2).

Among them, A1, L and R11 are as defined above. Preferred active compound composition A, wherein the history of formula (2) (η)-93-200814928 Strobilurin is selected from the following compounds: 〇1) azoxystrobin, (2) -2) Fluoxastrobin, (2-3) (2£>2-(2-{[6-(3-chloro-2-indolylphenoxy)-5-fluoro-4- Pyrimidinyl]oxy}phenyl)-2-(methoxyiminomercaptoacetamide, (2-4) trifloxystrobin, (2-5) (2-5)-2-( Methoxyiminomethyl-2-(2-{[({(1£>1-[3-(trifluoromethyl)phenyl]ethanediyl}amino)oxy)methyl}benzene Ethylamine, (2-6) (2£>2-(methoxyiminomethyl, _2-{2-[(5)-({1-[3-(trifluoromethyl)) Phenyl]ethoxy}imine>methyl]phenyl}ethyl 1 leucine, (2-7) willsostazone, (2-8) 5-methoxy_2_10 Methyl ice (2-{[({(1)5)[[((((((((()))]]]]]] -37^-l,2,4-three sigma sitting -3-嗣, (2-9) 克 辛 辛 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克 克2-11) picoxystrobin, (2-12) pyraclostrobin (pyr Aclostrobin) '(2-13) methotrexate (metominostrobin), (2-14) 15 enestrobin. _ Particularly good active compound composition A, of which type (2) (Π) The Strobilurin line was selected from the following compounds: (2-1) Azoxystrobin, Acupoint 2-2) Fluorobacteria bait (10) Cubs!!), ^.) (2£ >2-(2-{[6_(3-Chloro-2-methylphenoxy)·5-fluoro-4-, octyl]oxy}benzene 20-yl)_2-(methoxyimino)- As far as methyl acetamide, (2-4) trifloxystrobin' (2-9) kexin-methyl (kres〇xim-methyl), (2-10) dimoxystrobin (2-11) picoXyStrobin, (2-12) pyracostrobin '(2-13) phenoxynibine (met〇niinostrobin).

The active compound composition A to be particularly emphasized, comprising the guanamine of the formula (I) selected from the group (1) in Table A-94-200814928, and (iv) the azotoxin (az xy s plus (4) ^ The active compound composition A is emphasized, comprising a carboguanamine of the formula (1) selected from the group (1) of Table A, and (2_2) fluoxastrobin.

10 15

The active compound composition A to be particularly emphasized, comprising the carboxamide of the formula (I) selected from the reference class (1), and (2-3) (2£>2-(2-{[ 6. (3 chloromethylphenoxy)_5_fluoro-4-pyrimidinyl]oxy}phenyl)_2_(methylidylmethylacetamide. "^ In particular, the active compound composition A to be emphasized, Included is a carboguanamine of the formula (I) selected from the group (1) of the reference A, and (2-4) a trifloxystrobin. The active compound composition A' to be emphasized is selected from | The carboxamide of the formula (I) of the class (1), and the active compound composition A of (2-9) kresoxim-methyl oxime, which is particularly emphasized, The carboxamide of the formula (I) of the class (1) in Table a, and the active compound composition of the (2-10) dimoxystrobin, especially emphasized, are included in Table A. Carboxylamidines of the formula (I), and (2-11) picoxystrobin 活性 The active compound composition A to be particularly emphasized, comprising the formula (1) selected from the class (1) in Table A Carboxyamine, and (2_2)azole Pyramidin (pyraclostrobin).

The active compound composition A to be particularly emphasized, comprising the carboxamide of the formula (1) selected from the group (1) in Table A-95-20 200814928, and (2-13) metominostrobin in addition to In addition to the carboguanamine of the formula (1) (the compound of the formula (1)), the active compound composition B also contains the triazole compound of the formula (III) (the compound of the (3) class)

10

(10) where Q, m, R14, R15, A4, A5, R16 and R17 are as defined above. Preferred active compound composition B, wherein the triazole of the formula (III) of the class (3) is selected from the compounds listed below: 15 (3-1) azaconazole, ( 3-2) Itaconazole, (3-3) propiconazole, 〇4) difanoconazole, (3-5) bromuconazole, (3- 6) cyproconazole, (3-7) hexaconazole, (3-8) penconazole, (3-9) myclobutanil, (3-10) ) tetraconazole, (3-11) flutriafol, (3-12) epoxiconazole, (3-13) fhisilazole, (3-14) xin Simeconazole, (3-15) prothioconazole, (3-16) fenbuconazole, (3-17) tebuconazole, (3-18) Ai Ipconazole, (3-19) metconazole, (3-20) triticonazole, (3-21) than bitertanol, (3-22) Triadimenol, (3-23) three tedin-96- 20 200814928 (triadimefon), (3-24) fluquinconazole ), (3-25) quinconazole, (3-26) diclobutrazole, (3-27) diniconazole, (3-28) Nikon 嗤-Μ (diniconazole-M), (3,29) furconazole, (3_30) uniconazole (uniconazole), (3-31) uniconazole P (uniconazole P). Particularly preferred active compound composition B, wherein the triazole of formula (III) of formula (3) is selected from the compounds listed below: | (3·3) propiconazole, (3-4) ) to dofonconazole, (3-6) cyproconazole, (3-7) hexaconazole, (3-15) prothioconazole, ( 3-17) tebuconazole, (3-19) metconazole, (3-21) than bitertanol, (3-22) triadimenol, (3-24) ) fluquinconazole, (3-27) diniconazole.

15 The active compound composition B to be particularly emphasized, comprising the carboxamide of the formula (I) selected from the group (1) in Table A, and (3-3) propiconazole 〇 The active compound composition B to be emphasized, including the carboguanamine of the formula (I) selected from the class (1) in Table A, and (3-4) the difenoconazole oxime (difenoconazole) are particularly emphasized Active Compound Composition B, comprising carboxamide attached to formula (I) of Table (1), and (3-6) cyproconazole.

The active compound composition B to be particularly emphasized, comprising the carboguanamine of the formula (1) selected from the class (1) in Table A-97-200814928, and (3-7) hexaconazole 〇 The active compound composition B, which is emphasized, comprises the carboxamide which is selected from the class (1) of the class (1) in Table A, and the activity of (3-15) prothioconazole 5 which is particularly emphasized. Compound composition B, comprising a carboguanamine of formula (I) selected from the group (1) in Table A, and (3-17) an active compound composition particularly emphasized by tebuconazole B, comprising the carboxamide of the formula (I) selected from the group (1) in Table A10, and (3-19) the active compound composition B of the conconazole, especially emphasized, comprising Carboxylidene of formula (I) of class (1) selected from Table A, and (3-21) than bitertanol °

15 The active compound composition B to be particularly emphasized, comprising the carboguanamine of the formula (1) selected from the group (1) in Table A |, and (3-22) triadimenol, especially to be The active compound composition B is emphasized, comprising the carboxamide which is selected from the formula (1) of the class (1) in Table A, and the activity of (3-24) fluoroquinconazole 2 (fhiquinconazole) which is particularly emphasized. Compound Composition B, comprising carboxamide attached to formula (I) of Table (1), and (3-27) diniconazole, in addition to carboxamide having formula (1) (1) Compounds), active compound group-98-

I 200814928 Compound C also contains Sulphenamide of the formula (iv) (Group (4) compound)

Wherein R19 is as defined above. A preferred active compound composition C wherein the sulfenic acid amine of the formula (IV) of the formula (4) is selected from the group consisting of: ίο (4-1) dichlofluanid, ( 4-2) Tolylfluanid. The active compound composition C to be particularly emphasized, comprising a carboguanamine of the formula (I) selected from the group (1) in Table a, and (4-1) dichlofluanid 〇 are particularly The active compound composition C is emphasized, comprising a carboxamide selected from the group (I) of the class (1) in Table a 15 and (4-2) tolylfluanid. In addition to the carboguanamine of the formula (I) (the compound of the formula (1)), the active compound composition D also comprises a valinamide selected from the following (category (5)): 2〇(5) -1) Iprovalicarb, (5-2) chlorophenyl)-2-propynyl]oxy}-3-methoxyphenyl)ethyl]-7V2-(methylsulfonyl) )-;^ Fibrin amine, (5-3) benthiavalicarb. Preferred active compound composition D, wherein the amidoxime amine of the group (5) is selected from the following compounds: -99-200814928 (5-1) iprovalicarb, (5- 3) Streptomycin (benthiavw^^

The active compound composition D to be particularly emphasized, comprising the slow-acting amine of the formula (1) selected from the group (1) in Table A, and (5) the active compound particularly emphasized by iprovalicarb 〇5 Composition D, comprising a rebel amine of formula (I) selected from class (1) of Table a, and (5-3) benthiavalicarb. 10 In addition to the carboxamide (formula (1) compound) of the formula (1), the active compound composition E also contains a carboxamide selected from the following formula (v) (v).

Among them, the definitions of X, Y and Z are as defined above. A preferred active compound composition, wherein the carboxy 15 guanamine of the formula (6) is selected from the group consisting of: _(6-1) 2-gas-]^-(1,1,3 - dimethylindol-4-yl) in the test amide, (6_2) benzoic (boscalid) ' (6-3) blessing ratio (furametpyr), (6-4) Ν-(3-p-tolyl吩 · · · 小 小 小 小 · · — — — — — — — — — 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- 4- (fenhexamid), (6 stomach 7) 20 carpropamid, (6-8) 2-chloro 4-(2-fluoro-2-mercaptopropylaminol, -N,N-methylmethyl Amine, (6-9) bactericide (picobenzamid), (6-10) zoxamide, (6-11) 3,4-digas-N-(2-cyanophenyl) α stopper-5-treazone, (6-12) carboxin, (6-13) σ xidinium '(6_14) cuminamide (penthiopyrad), (6_15) Shi Xi Triamcinol-100 - 200814928 (silthiofam), (6-16) ΛΚ2-(1,3-dimercaptobutyl)phenyl]p-methyl-4-(trifluoromethylpyrrol-3-carboxyindole Amine, (6-17) flutolanil, (6-18) fenfuram, (6] 9) jiacarin (oxycarbox) In), (6-20) thifluzamide, (6-21) 5 N-{2_[3_Chlorine, 5_(trifluoromethyl-to-bit-2-yl)ethyl}-2_ (di-gas methyl) benzepidine, (6-22) N-(2-bicyclopropyl-2-ylphenyl) small methyl each trifluoromethyl-1H-indazole-4-carboxamide ,(6-23) Ν-(2-biscyclopropyl-2-ylphenyl)-1-methyl,yl-3-difluoromethyl-1H-pyrazole-4-carboxyguanamine, (6-24 ) Ν-|>(Γ-fluorenylbicyclopropyl-2-yl) stupyl] small methyl-3-trifluoromethyl-1Η-11 is more than salivary-4, 7 (6-25) Ν-[2-(Γ-Mercaptobiscyclopropyl-2-yl)phenyl]-1-methyldifluorof-yl-1H-pyrazole·4-carboxamide, (6-26) N- [l-(5-Bromo-3-chloropyridin-2-yl)ethyl]-2,4-chloro-purine acid amine '(6-27) N-(5-bromo-3-chloro-° ratio bite -2-yl)methyl-2,4-dione nicotinamide. Particularly preferred active compound composition E, wherein the carboxamide of the formula (v) of formula (v) is selected from the following Compounds: • (6-2) boscalid, (6-5) ethab〇xam, (6_6) fenhexamid, (6-7) carp 〇pamid),(6_8) 2_ chloro-4-(2-fluoro-2-methylpropanylamino) Benzobenzamide, (6_9) fungicide (picobenzamid), (6-10) oxazolamide (z〇xamide), (6 u) 20 3, dehydrogenated 2 cyanophenyl)isothiazole-5 - Carboxylamamine, (6-14) penthiopyrad, (6-16) 〇 (1,3-dimethylbutyl)phenyl]methyl-4-(trifluoromethyl)- 1//-吼咯-3·Carboxyguanidamine, (heart 17) Futonin (flutolanil) '(6-21) N-{2-[3' gas (trifluoromethyl) acridine_2 Ethyl 2-(trifluoromethyl)benzamide, (6Q2) N-(2-bicyclopropyl-2-yl-101-200814928)-1-methyl-3-trifluoroanthracene _lHl·pyrazole-4-carboxamide, (6-23) N-(2-bicyclopropyl-2-ylphenyl)-1-methyl-3-difluoroindolyl-1H-pyrazole -4-carboxyguanamine, (6-24) Ν-[2-(Γ-methylbicyclopropyl-2-yl)phenyl]-1-methyl-3-trifluoromethyl-indoleazole- 4-carboxyguanamine, (6-25) Ν-[2-(Γ-methylbicyclopropyl-2-yl) 5 phenyl] small methyl dimethyl difluoroindolyl-1 Η-pyrazole-4-carboxylate Indoleamine, (6-26) 1^-[1-(5->Smelly-3-athracepin-2-yl)ethyl]-2,4-dichloro in the amine ('-27 Ν-(5-Bromo-3-chloropyridin-2-yl)indolyl-2,4-dichloronicotinium amide. An excellent active compound composition, wherein the carboxamide of the formula (V) of the formula (V) is selected from the following compounds: ίο (6-2) boscalid, (6-6) Cyclosporin (£€111^\311^〇1), (6-7) carpropamid, (6-9) bactericide (picobenzamid), (6-14) guanidinamide (pentiiiopyrad), (6-17) Flutolanil, (6-21) N-{2-[3-chloro-5-(trifluoromethyl)acridin-2-yl]ethyl}-2-(three Fluoromethyl)benzamide,(6-22) N-(2-bicyclopropyl-2-ylphenyl)-1-methyl-3-trifluoromethyl is-1H-pyrazole-4- Carboxylamidine, (6-23) Ν-(2-bicyclopropyl-2-ylphenyl)-1-methyl-3-yl-3-difluoromethyl-1H-pyrazole-4-carboxamide, ( 6-24) Ν-[2-(Γ-Methylbicyclopropyl-2-yl)phenyl]-1-methyl-3-trifluoromethyl-1Η-pyrazole-4_carboxamide, ( 6-25) Ν-[2-(Γ_Methylbicyclopropyl-2-yl)phenyl]-1-mercapto-3-difluoromethyl-1Η-pyrazole-4-carboxyguanamine, ( 6-26) N-[l-(5-Bromo-3-chloropyridin-2-yl)ethyl 2indolyl]-2,4-dichloronicotinium amide, (6-27) Ν-(5- Bromo-3-chloroacridin-2-yl)methyl-2,4-dichloronicotinium amide. The active compound composition, particularly emphasized, comprises carboxamide selected from the group (I) of Table (1), and (6-2) boscalid.

The active compound composition E to be particularly emphasized, comprising the carboxamide of the formula (1) selected from the group (1) in Table A-102 - 200814928, and (6-6) fenhexamid 〇 The active compound composition E to be emphasized, including the carboguanamine of the formula (I) selected from the class (1) in Table A, and (6-7) carpropamid 〇 are particularly emphasized. The active compound composition E, comprising the carboxamide which is selected from the formula (1) of the class (1) in Table A, and (6-9) the active compound composition which is particularly emphasized by the picobenzamid E, comprising a carboxamide which is selected from the group (I) of the class (1) in Table A ίο, and (6-14) penthiopyrad 活性 an active compound composition E which is particularly emphasized, including The carboxamides of the formula (1) of the class (1) in Table A, and (6-17) flutolanil were selected.

The active compound composition E to be particularly emphasized, comprising the carboxamide of the formula (I) selected from the group (1) in Table A, and (6-21) N-{2-[3-chloro 5-5-(Trifluoromethyl)pyridin-2-yl]ethyl}-2-(trifluoromethyl)benzamide. The active compound composition E to be particularly emphasized, comprising the carboguanamine of the formula (I) selected from the group (1) in Table A, and (6_22) N-(2-bicyclopropyl-2-2? The basic group)-1-mercapto-3-^ gas methyl-1Η-σ ratio ° sit-4-anthracene amine. The active compound composition 特别 particularly emphasized, comprising the carboguanamine of the formula (I) selected from the group (1) in Table A, and (6-23) N-(2-bicyclopropyl-2- Phenyl)-1-methyl-3-difluoroindolyl-1H-pyrazole-4-carboxamide.

The active compound composition E, which is particularly emphasized, comprises the selected from the group A-103-200814928, helium methyl-1H-pyrazole ice carboguanamine.

The active compound composition E, which is selected from the group A (group), the base, the dimethyl group, the methyl group, the quinone 4-minamine, and the class (1) of the active compound composition ε to be emphasized. Carboxamide of formula (I), and hydrazine

10 15 基基)ethyl] from dichloromethane and (6, 备 3 3 3 3 ΖΪΓ ΖΪΓ ΖΪΓ 触 触 Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε 甲基 甲基 甲基 甲基 甲基 甲基 甲基amine. ( person=1 = 1) of the (tetra)amine (the compound of the (1) type), the active compound grade (=1 Γ from the dithiocarbamate containing the following (class (7)): (-1) zinc manganese Naipo (mancozeb), (7_2) Manganese-eb), (5) Bad (meti_, (7_4) methyl zinc napo (pr〇pineb) (75) Dean _ram) '(7_6) Zinc Napo (zineb), (7 7) Fumei Zinc (2) called. The active compound composition F of the parent company, wherein the dithiocarbamate of the (7) class is selected from the following compounds: (7-1) Manganese (mancozeb), (7-2) manganese Naipu (maneb), (7_4) methyl zinc is the propineb, (7-5) Dean (also as 1!1), (7_6) zinc napu (zineb) 〇 particularly good active compound composition F, wherein the dithiocarbamate of the (7) class is selected from the following compounds: 〇 1) Zn Mn 浦 (mancozeb), (7-4) methyl Zn pu pu (pr〇pineb ). -104· 20 200814928 The active compound composition F to be particularly emphasized, comprising the carboguanamine of the formula (I) selected from the group (1) in Table a, and (7-1) the zinc manganese (mancozeb) 〇 The active compound composition F to be particularly emphasized, comprising the carboxamide of the formula (I) selected from the class (1) in Table a, and (74) the propineb of the formula (1) in addition to the formula (1) In addition to the carboxamide (the compound of the formula (1)), the active compound composition G also contains the mercaptoalanine selected from the formula (VI) which is described below (category (8)).

Among them, the definitions of * and R23 are as defined above. A preferred active compound composition G, wherein the hydrazine-based propylamine of the formula (8) is selected from the group consisting of: (8-1) benalaxyl, (8) -2) fUralaxyl, (8-3) metalaxyl '(8-4) tadal-M (metalaxyl-M), (8-5) borda-M (benalaxyl -M) ° 20 Particularly preferred active compound composition G, wherein the mercaptoalanine of the formula (8) is selected from the following compounds: (8-3) metalaxyl (8-4) Metalaxyl-M, (8-5) Benalaxyl-M.

The active compound composition G to be particularly emphasized, comprising the carboguanamine of the formula (i) selected from the group (1) in Table A-105-200814928, and (8-3) metalaxyl oxime The emphasized active compound composition G comprises carboxamide which is selected from the group (I) of the class (1) in Table A, and (8-4) metalaxyl-M. The active compound composition G to be particularly emphasized, comprising the carboguanamine of the formula (I) selected from the class (1) in Table A, and (8-5) Benalaxyl-M (benalaxyl-M) In addition to the carboguanamine of the formula (I) (the compound of the formula (1)), the active compound group Η Η Η also contains an anilinopyrimidine selected from the following (category (9)): (9-1 ) cyprodinil, (9-2) annihilation (|1160&1^}^1111), (9-3) pyrimethanil. The active compound composition H to be particularly emphasized includes carboxyguanamine of the formula (I) selected from the group (1) in Table A, and (9-1) cyprodinil.

The active compound composition 特别 particularly emphasized, comprising carboxamides of formula (I) selected from class (1) in Table A, and (9-2) mepanipyrim 〇 The emphasized active compound composition H comprises carboxamide which is selected from the formula (1) of the class (1) in Table A 20, and (9-3) pyrimethanil. In addition to the carboxamide (Formula (1) compound) of formula (I), active compound composition I also comprises benzimidazole-106 selected from formula (VIII) below (category (1)) - >27200814928 (vm) where r25 ' r26 ' r27 and R28 are as defined above. 5 Preferred active compound compositions, wherein the formula (10) (the benzimidazoles of Vii are selected from the following compounds:

10 (HM) 6-Chloro-5-[(3,5-dimethylisoxazolyl)sulfonyl]_2, indole difluoro-5H-[1,3]dioxole||f]- Benzimidazole, (ι〇_2)-free (benomyl) '(10-3) baccen (carbencJazim), (10-4) chlorfenazole, (10-5) Mai Suining (fuberidazole), (10-6) thiabendazole 〇 Particularly preferred active compound composition I, wherein the formula (1〇) is (benzazole of V1 is: (10-3) befenfen (carbendazim). 15

R R

The active compound composition I to be particularly emphasized, comprising the carboguanamine of the formula (I) selected from the class (1) in Table A, and (10-3) the carbendazim in addition to the formula ( In addition to the carboxamide (class (1) compound) of I), the active compound % J also contains the amine bismuth acid of formula (IX) selected from the following (category (11)).

Among them, the definition of R29 and R30 is as defined above. Preferred active compound composition J, wherein the amine group of the (11) class of decanoic acid-107-20 200814928 is selected from the following compounds: (11-1) diefhofencarb (11) -2) propamocarb, (11-3) propamocarb-hydrochloride '(11-4), fosetyl.

5 The active compound composition J to be particularly emphasized, comprising the carboguanamine of the formula (I) selected from the group (1) in Table A, and (11-1) diethofencarb (diethofencarb)

& In particular, the active compound composition J, which contains the carboxamide of the formula (I) selected from the class (1) in Table A, and the activity to be particularly emphasized by Propacarb (propamocarb) Compound composition J, comprising a carboguanamine of formula (I) selected from the group (1) in Table A, and (11-3) an active compound to be particularly emphasized by propamocarb-hydrochloride Composition J' comprises carboxamide which is selected from the group (I) of the class (1) in Table A 15 and (Π-4), fosetyl. In addition to the carboxychiral amine of the formula (I) (the compound of the formula (1)), the active compound composition K also contains dicarboxyboximide selected from the following (category (12)): 2〇 (12-1) tetramdan (captafol), (12-2) captan (captan), (12-3) folfet, (12-4) iprodione, (12 -5) Procymidone, (12-6) vinclozolin. A preferred active compound composition κ' wherein the dicarboxy carbamide of the group (12) is selected from the group consisting of: -108 - 200814928 (12_2) captan, (12_3) fore (f〇ipet), (12_4) Iprodione.

The active compound composition K to be particularly emphasized includes carboxyguanamine of the formula (I) selected from the group (1) in Table A, and (12-2) captan.

5 The active compound composition K to be particularly emphasized, comprising the carboguanamine of the formula (I) selected from the group (1) in Table A, and (12-3) folpet.

The active compound composition K to be particularly emphasized, comprising the carboxamide of the formula (I) selected from the group (1) in Table A | and (12-4) iprodi〇ne 〇10 In addition to the carboguanamine of the formula (I) (the compound of the formula (1)), the active compound composition L also contains guanidine selected from the following (category (13)): (13-1) tannin ( D〇dine), (13-2) guazatine, (13-3) iminoctadine triacetate, (13-4) gram heat (burning shale) [ Iminoctadine tris (albesilate)], (13-5) donin (dodine 15 (free test)) '(13-6) gram hot (immoctadine) (free test). p Preferred active compound composition L, wherein the lanthanide of class (13) is selected from the group consisting of: (13-1) dodine, (13-2) guazatine. The active compound composition L to be particularly emphasized includes carboxyguanamine of the formula (I) selected from the group (1) in Table A 20, and (13-1) dodine. The active compound composition L to be particularly emphasized, comprising the rebel amine of formula (1) selected from the class (1) in Table A, and (13-2) guazatine 〇 in addition to the carboxy group of formula (I) In addition to the indoleamine (the compound of the (1) class), the active compound group -109-200814928 compound also contains the imidazole selected from the following (category (14)): (14-1) (cyazofamid), (14-2) poker pull (prochloraz), (14-3) two sitting 嘻 (triazoxide) '(14_4) rice dish vinegar ^ \ ^ 2 € ^ 6) 0 5

A preferred active compound composition M, wherein the imidazole of the (14) class is selected from the group consisting of: (14-2) prochloraz, (14-3) triazoxide. In particular, the active compound composition Μ, including the carboxamides of formula (I) selected from class (1) in Table A, and (14-2) prochloraz 〇 are particularly emphasized The active compound composition M comprises a carboguanamine of the formula (I) selected from the group (1) in Table A, and (14_3) triazoxide, in addition to the carboguanamine having the formula (I) ( In addition to the compound of the above formula (1), the active compound composition N also contains morpholine 15 of the formula (X) selected from the following (category (15))

(morpholine)

(X) wherein R31, R32 and R33 are as defined above. Preferred active compound composition N, wherein the morpholine group of the formula (15) is selected from the following compounds: (15-1) aldimorph, (15-2) ) tridemorph, (15-3) dodemorph, (15-4) fenpropimorph, (15-5) dimethomorph 〇-110-20 2014 Particularly preferred active compound composition N, wherein the morpholine of the formula (15) of the formula (X) is selected from the following compounds: (15-4) fenpropimorph, (15-5) ) dimethomorph 〇

5 The active compound composition N to be particularly emphasized, comprising the carboguanamine of the formula (I) selected from the group (1) in Table A, and (15-4) fenpropimorph 〇

The active compound composition N to be particularly emphasized, comprising the carboguanamine of the formula (I) selected from the class (1) in Table A, and (15-5) dimethomorph ° In addition to the carboguanamine of the formula (I) (the compound of the formula (1)), the active compound composition Ο also contains pyrrole of the formula (XI) selected from the following (class (16)).

Among them, R34, R35 and R36 are as defined above. Preferred active compound compositions 吡' wherein the pyrrole of the group (16) of the formula (XI) is selected from the following compounds: 2〇(16-1)fenpiclonil, (16- 2) Fludioxonil, (16,3) ° pyrrolnitrin. A particularly preferred active compound composition, wherein the pyrrole of the formula (16) of the formula 1) is selected from the group consisting of: (16-2) fludioxonil. -111- 200814928

In particular, the active compound composition 〇 contains carboxyguanamines of the formula (1) selected from the group (1) in Table A, and (16_2) fludioxonil 〇 in addition to the ruthenium amine of the formula (I) In addition to the (第) compound, the active compound group P also contains a phosphonate selected from the following (diterone): (Π-1) Forsythia-aluminum (f0Setyi_A1), (17_2 Phosphonic acid, (17·3) tolclophos-methyl.

In particular, the active compound composition P to be emphasized, comprising the carboxamide of the formula (I) selected from the class (1) in Table A, and (17_丨) Forsyth_aluminum ίο (fosetyl-Al) 〇

The active compound composition p to be particularly emphasized, comprising the carboguanamine of the formula (1) selected from the class (1) in Table A, and (17-3) tolclophos-methyl oxime In addition to the carboxychiral (terpenoid) compound of formula (1), the active compound group 15 compound Q also contains a fungicide selected from the following (category (19)): (19-1) Acibenzolar-S-methyl, (19-2) chlorothalonil, (19-3) yemoxanil, (19·4) edifenphos, (19-5)杀 同 (fam〇xadone), (19-6) volt nan (fluazinam), (19-7) copper OXyChl〇ride, (19-8) 2 〇 copper hydroxide (copper hydroxide), (19-9) oxadixyl, (19-10) spiroxamine, (19-11) dithianon, (19-12) meperfenone , (19-13) fenamidone, (19-14) 2,3-dibutyl-6-azepine [2,3-(1], 密^_4(3H)-one (19-15) probenazole, (19-16) rice thin 112 200814928 spirit (isoprothiolane) '(19-17) kasugamycin (kasugamycin), (19- 18) phthalide, (19-19) ferimzone, (19-20) tricyclazole, (19-21) Ν·({4-[(cyclopropyl) Amino)diyl]phenyl}sulfonyl)-2-decyloxybenzamine, (19-22) 2-(4-chlorophenyl-5-yl; decyloxy ice (propan-2-yne small) Phenoxy)phenyl]ethyl}-2-(propan-2-yl-1-yloxy)acetamide, (19-23) quinoxyfen. Preferred active compound composition Q, wherein 19) fungicides | are selected from the following compounds: (19-1) benzothiazolidine (acibenzolar-S-methyl), (19-2) chlorhexidine ίο (chlorothalonil), ( 19-3) cymoxanil, (19-5) famoxadone, (19-6) fluazinam, (19-7) copper oxychloride, (19_9) Oxadixyl, (19-10) spiroxamine, (19-13) fenamidone, (19-21) N-({4-[(cyclopropylamine) (carbonyl)phenyl]sulfonyl)-2-methoxyl benzoguanamine, (19-22) 2-(4-chlorophenyl)-:^{2-[3-methoxy- 4-(prop-2-yne p. -1·yloxy)phenyl]ethylprop-2-yn-1-yloxy)diethylamine (19-23) quinoxyfen 〇 a particularly preferred active compound composition Q, wherein the fungicide of class (19) is selected from the following compounds: 2〇(19-2) chlorseni (chlorothalonil), (19-7) COpper oxychloride, (19-10) spiroxamine, (19_21) N-({4-[(cyclopropylamino)carbonyl)benzene (sulfonyl)-2-decyloxybenzamide, (19-22) 2-(4-chlorophenylmethoxy-4-(prop-2-yne small oxy) phenyl] }}-2-(prop-2-yn-1-yloxy)acetamide, (19-23) vebufen-113- 200814928 (quinoxyfen) 〇

The active compound composition Q to be particularly emphasized includes carboxamide which is selected from the group (I) of the class (1) in Table A, and (19-2) chlorothalonil.

5 The active compound composition Q to be particularly emphasized, comprising the carboxamide of the formula (I) selected from the group (1) in Table A, and (19-7) copper oxychloride.

• The active compound composition Q to be particularly emphasized, comprising the carboguanamine of the formula (1) selected from the class (1) in Table A, and (19-10) spiroxamine 10, especially The active compound composition Q is emphasized, comprising the carboxamide of formula (I) selected from the class (1) in Table A, and (19-21) N-({4-[(cyclopropylamino)) Carbonyl]phenyl}sulfonyl)_2_decyloxybenzamide. The active compound composition Q to be particularly emphasized, comprising the carboxamide of the formula (I) selected from the class (1) in Table A 15 and (19-22) 2-(4-chlorophenyl)-N -{2-[3-Methoxy phenyl (prop-2-ynyloxy)phenyl]ethyl 2-(propyn-7-yloxy)acetamide. The active compound composition Q to be particularly emphasized, comprising the carboguanamine of the formula (I) selected from the class (1) in Table A, and (19_23) quinoxyfen in addition to the formula (I) In addition to the carboxamide (the compound of the class (1)), the active compound composition R also comprises a (thio)urea derivative selected from the following (category (20)): (20-1) penmone (pencycuron) ), (20-2) thiophanate-methyl, (20-3) ethyl-polyphanate_ethyl. -114- 200814928 A preferred active compound composition R wherein the (thio)urea derivative of the (2) class is selected from the group consisting of: (20-1) penmone (pencycur〇n), ( 2〇2) thiophanate-methyl 〇

5 In particular, the active compound R, which is to be emphasized, comprises carboxamide which is selected from the formula (1) of the class (1) in Table A, and (20-1) pencycuron 〇_ except for the formula (1) In addition to the carboxamide (the compound of the formula (1)), the active compound composition S also contains the triazole pyrimidine 10 of the formula (XIV) selected from the following (category (22)).

15 where R40, R41, R42, R43, R44, R45, R46 and R47 are as defined above. A preferred active compound composition S, wherein the triamed pyrimidine of the formula (XIV) is selected from the group consisting of: (22-1) 5m -2,2,2-trifluoropyrimidine Ethylethyl]-6·(2,4,6-trifluorobenzene-2-indenyl)indole, 2,4]triazolo[1,5-a]pyrimidin-7-amine, (22-2) 5- Chlorine-exhaustion [(77^1,2-dihydroxypropyl]-6-(2,4,6-trifluorophenyl)[1,2,4]triterpene [l,5-a> dense Ding-7-amine '(22-3) 5-chloro-6-(2-chlorofluorophenyl)-7-(4-mercaptohexahydrogen 唆 "4_ base" [1,2,4] Triazolo[i,5-a]-pyrimidine, (22-4) 5-chloro(2,4,6-trifluorophenyl)-7-(4-methylhexahydropyridinyl)[ Yj]Triazolo[l,5_a]pyrimidine. -115- 200814928 A particularly preferred active compound composition S, wherein the trihalopyrimidine of the formula (22) is selected from the following compounds: (22 -1) 5•Chlorotrifluoromethylethyl]_6_(2,4,6-trifluorophenyl)[1,2,4]triazolo[15_a]pyrimidine-7-amine, (22 2) 5 Monomethylpropyl P6_(2,4,6-trifluorophenyl)[1,2,4]triazolo[l,5-a]pyrimidin-7-amine, (22-4) 5-chloro- 6-(2,4,6-trifluorophenyl)_7_(4-methylhexahydro 0-pyridyl)indole, 2,4]triazolo p,^], pyridine. The active compound composition s, comprising the guanamine of formula (1) selected from the group (1) in Table A, and (22_1) 5-chloro 〇Ψ &]^6»(2Λ6-^ ^ ^^)[1?2,4] Disporin [l,5-a], indole-7-amine. The active compound composition s, which is particularly emphasized, contains the first (1) selected from Table A. Carboxylamidines of the formula (I), and (22-2) 5-chloro-7(^^^7^_1,2-monodecylpropyl]_6-(2,4,6-trifluorophenyl ) pj, 4] triazolo[L^a]pyrimidine_7_15 amine.

_ The active compound composition S to be emphasized, including the lysine of the formula (1) selected from the class (1) of Table A, and (22_4) 5' gas·6_(2,4,6, trifluorophenyl) >7_(4-Methylhexahydro-l-yl)[U,4]Sanjun[1»-pyridine. In addition to the carboxamide (Formula (1)) of formula (I), The active compound group 2 chelate T also contains an iodochromone of the formula (XV) selected from the following (category (23))

Among them, R48 and R49 are as defined above. • 116- 200814928 Che’s active compound composition T, wherein the moth ketone of the formula (23) (χν) was selected from the following compounds: (23-1) 2-butoxy moth winter Propyl benzopyrene, (23-2) 2-ethoxybutyrozin-3-propylbenzopyran-4-one, (23-3) 6-iodo-2-propoxy _3-propyl benzopyran + ketone, (23_4) 2 - butyrynyloxytoluene iodo-propyl benzopyrane, (23-5) 6-iodo-2-(1-methylbutyl Oxypropyl benzopyranone, (23-6) 2-but-3-enyloxy-6-branched benzopyrano-4-one, (23-7) 3-butyl-6 - Indole-2-isopropoxybenzopyrenepyrene, a particularly preferred active compound composition, wherein the iodochromone of the formula (23) is selected from the following compounds: (23-1) 2-butoxy-6-angyl benzopyrano-pyranone, (23-2) 2-ethoxy-6-bromo-3-propylbenzopyran-4 - ketone. The active compound composition 特别 particularly emphasized, comprising carboxyguanamine of formula (1) selected from the group (1) in Table A, and (23-1) 2-butoxy-6-iodo-3- Propyl benzo-pyran-4-one. Active compound composition to be particularly emphasized τ, which comprises the carboxamide of formula (I) selected from the class (1) in Table A, and (23_2)2-ethoxy-3-6-iodo-3-propylbenzopyran-4-one. In addition to the slow-acting amine of the formula (1) (the compound of the formula (1)), the active compound composition U also contains a biphenylcarbendazim of the formula (XVI) selected from the following (category (24)), 117 , 200814928

10 15 Preferred active compound composition U, wherein the biphenylcarboxylamine of the formula (24) is selected from the following compounds: (24-1) Λ4Ί·dichloro-5. Γ-biphenyl-2-yl)|(difluoromethyl)small methyl-1-propionazole carboxamide, (24_2) 4_(difluoromethyl)·2_methyl good [4 _( Difluoromethylbiphenyl·2_yl]pyrene-5-carboxyguanamine, (24-4), (3',4'-dichloro-1,1,biphenyl-1-yl) Shiqishan 3 · dimethyl _. pyrazole-4-carboxamide, (24-5) ΛΚ4,-chloro-3, fluoro-U,-biphenyl-2-yl)-2-methyl-4-( Trifluoromethyl)-1,3-thiox-5-treazone, (24-6)1(4,-chloro-1, fluorene-biphenyl-2-yl)-4-(difluoromethyl) ))-2-mercapto-1,3-thiazole-5-carboxyguanamine, (24-7) ΛΚ4'-di-1, Γ-biphenyl-2-yl)-4-(difluoromethyl )-2-methyl-1,3-thiazole-5-carboxamide. A particularly preferred active compound composition U wherein the biphenylcarbendazim of the formula (24) is selected from the group consisting of: (24-1) ΛΚ3',4'-dichloro-5- Fluorin-1, fluorene-biphenyl-2-yl) each (difluoromethyl) small methyl-1//-pyrazole-4-carboxamide, (24-3) 3-(trifluoromethyl) :Fluorum 44 (5)-(methoxyimino)methyl]-U'-biphenyl-2-yl}-1-methyl•l/fj than 嗤-4-Rebel, (24 -7) 豕(4'->Smelly-1,1/-biphenyl-2-yl)-4-(difluoroindolyl)-2-methyl-1,3-thiazole-5-carboxyindole -118- 20 200814928 t The active compound composition U to be emphasized, including the tickamines of formula (I) selected from Table A (1), and (24-1) AK3', 4 '-Digas-5-fluoro I1 · phenyl group), 3_(difluoromethyl)-1_methyl-l/fj-pyrazole-4-carboxamide.

5 The active compound composition U to be particularly emphasized, comprising the carboguanamine of the formula (I) selected from the group (1) in Table A, and (24-7)7\K4U,r-biphenylyl group) Ice (difluoromethyl)> 2-mercapto-1,3-thiazole-5-carboxamide. | In addition to the slow-acting amine of the formula (I) (the compound of the formula (1)), the active compound composition V is also Contains a burnt-rebel ο ο ο amine selected from the following (Class (25))

15 Among them, Het, R50 and R58 are as defined above. A preferred active compound composition V, wherein the alkylcarboxyguanamine of the formula (25) is selected from the group consisting of: (25-1), 1,3-mercaptobutyl) ] _ 1,3-dimercapto-1 tablet j-wow-4-carboxamide, (25-2) ΛΜ2-(1,3-dimethylbutyl)phenyl}-5-fluoro-1, 3-dimethyl 2-mercapto-1 ugly-oxazole-4-carboxamide, (25-3) Aq2-(1,3-dimethylbutyl)phenyl]-5-chloro-^methyl- 1//-0 to 17 -4- an amine, (25-4) 3-(dimethyl)-[2-(1,3-didecylbutyl)phenyl H.methyl -1//^Bizozol-4-carboxamide, (25-5) 3-(trifluoromethyl)-indole 42-(1,3-didecylbutyl)phenyl]-5-fluoro-1 -Methyl-1//-0 ratio ° 竣-4- 竣 胺 ' '(25-6) 3 · (three gas methyl) " Ί · [2-(1,3- -119- 200814928 dimethyl Benzyl)phenyl]·5-chloro-1-indenylpyrimidine-4-indoleamine, (25-7) 1,3-dimethyl-'[2-(1,3,3-tri Methyl)phenyl]-177-indole 嗤 嗤 缓 gf amine, (25-8) 5-fluoro-1,3-dimethyl good [2 (1,3,3-tridecylbutyl)benzene Kebizozol-4-carboxyguanamine, (25-9) 3-(difluoromethyl)-1-methyltrimethylpentyl)phenyl]-1-pyrazol-4-carboxamide 25-10) 3-(Trifluoromethyl)-1_indolyl-7Η2-(1,3,3-tridecylbutyl)phenylpyrazinium, (25-11) 3-(difluoro Methyl)-5-ani-1-indolyl-|[2-(1,3,3-tridecylbutyl) _phenylpyrazole-4.carboxamide, (25-12) 3-( Trifluoroindolyl)_5-chlorosuccinyl-indenyl-[2·(1,3,3-dimercaptobutyl)phenyl] is more than 0-position of 4-decanoic acid amine, (25-13) ίο 2-(1,3-(-decylbutyl)phenyl)-2-benzophenentamine, (25·14) 2-iodo-A^[2-(l,3,3-dimethyl Butyl)benzyl]benzamide, (25]5)jV-[2-(l,3-dimercaptobutyl)phenyl]-2-(trifluoromethyl) cumamine, 25_16) 2_(Trifluoromethyl)-[2-(1,3,3·trimethylbutyl)phenyl]benzamide. Particularly preferred active compound composition V, wherein the alkylidene amine of formula (25) of formula 15 (xvii) is selected from the following compounds: • (25-1) WK1,3-dimethylbutyl) Stupid H,3-dimethyl-1//-pyrazole 4-carboguanamine, (25-2) 7V-{2-(l,3-dimethylbutyl)phenyl bromide ^^ Di-diyl-1A pyrazole-4-carboxamide, (25-8) 5-fluoro], 3-dimethylindole (1,3,3-dimethylbenzyl)phenyl]-lii-pyrazole -4-carboxamide, (25_13) (di-20 decylbutyl) phenyl)-2_iodobenzamide, (25-15) Λ42-(1,3-didecylbutyl) group ]-2-(Trifluoromethyl)benzamide. Knowing the fineness of the formula (1) of the (1) class and the (tetra)butyl)phenyl]-1,3-dimethyl-l/ί-pyrazole_4_carboxylate in the active compound composition to be emphasized Guanamine. 120- 200814928 The active compound composition V to be particularly emphasized, comprising the carboxamide of the formula (I) selected from the class (1) in Table A, and (25-2) Ι {2-(1,3) - dimethylbutyl) phenyl fluoride-1,3-dimethyl-l/ί-pyrazole-4-carboxamide. The active compound composition V to be particularly emphasized, comprising the carboguanamine of the formula (I) selected from the group (1) in Table A5, and (25-8) 5-fluoro-1,3-dimethyl base

Good [2(1,3,3-trimethylbutyl)phenyl]pyrazole 4 Carboxamide Q The active compound composition V, which is particularly emphasized, contains the first (1) selected from Table A | Carboxylamidines of the formula (I), and (25-13) chloro[2-(1,3-(dimethylbenzyl)phenyl)-2-bromoformamide.

10 The active compound composition V to be particularly emphasized, comprising the carboxamide of the formula (I) selected from the group (1) in Table A, and (25·15) Λ42-(1,3-dimethyl Butyl) phenyl]-2-(trifluoromethyl) benzoate. In addition to the carboguanamine of the formula (I) (the compound of the formula (1)), the active compound composition w also contains an alkylcarboxyl decylamine of the formula (xvm) selected from the following (class (26))

Among them, A, R60 and R70 are as defined above. A preferred active compound composition W, wherein the alkylcarboxamide of the formula (26) is selected from the group consisting of: (26-1) 5-fluoro-1,3-dimethyl- Λ42-(3·methylbutyl)phenylcarbazole-4-121-200814928 Carboxylamidine, (26-2)3-(difluoromethyl)-#-[2-(3,3-di Mercaptobutyl)-4-fluorophenyl]-1-methyl-1//- π ΰ 竣-4-竣 胺 ''(26-3) 3-(dimethyl)-Ί-[ 2·(3,3-dimercaptobutyl)phenyl]-1 -methyl-1//- ^ ratio σ sit-4-anthracene, (26-4), [2-(3,3 -dimercaptobutyl)phenyl]-2-(trifluoromethyl)benzamide 5 amine, (26-5)iV-[2-(3,3-dimethylbutyl)-4-fluoro Phenyl]-2-mercapto-4-(trifluoromethyl)-1>thiazole-5-carboxamide, (26-6) Λ42-(3,3-dimethylbutyl)-3-methyl Thiophene-2-carboxamide. The active compound composition W to be particularly emphasized, comprising the carboxamide of the formula (I) selected from the group (1) in Table A, and (26-1) 5-fluoro-1,3-dimethyl The base ίο -iV-[2-(3-methylbutyl)phenyl]-177-° is -4-anthracene than 0. The active compound composition W to be particularly emphasized, comprising the carboguanamine of the formula (I) selected from the group (1) in Table A, and (26-2) 3-(difluoroindolyl)-fluorene- [2-(3,3-Dimethylbutyl)-4-fluorophenyl]-1-indolyl-1//-carbazole-4-carboxamide. 15 The active compound composition W to be particularly emphasized, comprising the carboxamide of the formula (I) selected from the group (1) in Table A, and (26-3) 3-(difluoromethyl)- 7\^[2-(3,3-Dimethylbutyl)phenyl]-1-mercaptosin-4-tetamine. The active compound composition W to be particularly emphasized, comprising the carboguanamine of the formula (1) selected from the class (1) in Table A, and (26-4)7\42-(3,3-dimethyl 20 butyl phenyl)-2-(trifluoromethyl)benzamide. The active compound composition W to be particularly emphasized, comprising the carboguanamine of the formula (I) selected from the group (1) in Table A, and (26-5) Λ42-(3,3-dimethylbutyl) 4-)Phenyl]-2-mercapto-4-(trifluoromethyl)-1,3-indole sitting--5-rebel amine 0-122- 200814928 Active compound to be emphasized Composition W, comprising a carboxylic acid amine of formula (I) selected from the group (1), and (26_6) dimethyl butyl V3-methyl porphin-2-carboguanamine. In addition to an active compound of formula (I), the activating & composition according to the invention comprises at least one compound selected from classes (2) to (26), and furthermore, we may also comprise additional A fungicidal active additive.

10 15

The effect of synergy is particularly pronounced in the presence of a certain weight I ratio, however, the weight ratio of active compound in the/tongue compound composition can vary over a relatively wide range, typically, the activity according to the invention The compound of the formula (1) and the mixed partner from the group (2) to (26) contained in the compound composition are mixed in the following Table B. If the active compound mixing ratio in the active compound composition according to the invention is based on the weight ratio, i.e. the active compound of the formula (1): the weight ratio of the externally conjugated counterpart. : Mixed proportions of mixed counterparts. Preferred mixing ratios are particularly good. Mixing ratios (2): Strobilurins 50 : 1 to 1 · · 50 10 : 1 to 1: 20 : (3- 15) Other triazoles 50 : 1 to 1: 50 20 : 1 to 1: 20 Prothioconazole 50 : 1 to 1: 50 10 : 1 to 1: 20 Category (4): Sulfenamides 1 : 1 to 1: 150 1 : 1 to 1: 100 -123- 200814928 Mixing ratios preferred mixing ratios particularly preferred mixing ratios Category (5): amidoxime 50 : 1 to 1: 50 10 : 1 to 1 ·· 20 Category (6): Carboxylamamines 50 : 1 to 1: 50 20 : 1 to 1: 20 Category (7): Dithiocarbamate 1 : 1 to 1: 150 1 : 1 to 1: 100 Class (8): Mercapto Alanine 10 : 1 to 1: 150 5 : 1 to 1: 100 Category (9): Anilinopyrimidines 5 : 1 to 1 : 50 1 : 1 to 1: 20 Category (10): Benzimidazoles 10 : 1 to 1: 50 5 : 1 to 1: 20 Category (11): Amino formates other than (1H) 1 : 1 to 1: 150 1 : 1 to 1: 100 (11-1): diethofencarb 50 : 1 to 1: 50 10 : 1 to 1: 20 Class (12): (12-1) / (12-2) / (12-3) 1 : 1 to 1: 150 1 : 5 to 1: 100 Class (12): (12 -4)/(12-5)/(12-6) 5 : 1 to 1: 50 1 : 1 to 1: 20 Class (13): 胍100 : 1 to 1: 150 20 : 1 to 1: 100 Class (14) · · Imidazole 50 ·· 1 to 1 ·· 50 10 : 1 to 1: 20 Class (15): Morpholine 50 : 1 to 1: 50 10 : 1 to 1: 20 (16) Class··pyrrole 50 : 1 to 1: 50 10 : 1 to 1: 20 Class (17): (Sulfur) phosphonates other than (17-3) 10 : 1 to 1 ·· 150 1 : 1 to 1 : 100 (17-3) tolclophos-methyl 50 : 1 to 1: 50 10 : 1 to 1: 20 Category (18): phenylacetamide 50 : 1 to 1: 50 10 : 1 to 1: 20 -124- 200814928

A preferred mixing ratio of the mixed counterpart is particularly good (19-1): acibenzolar-S-methyl 50 : 1 to 1: 50 20 : 1 to 1: 20 (19-2 ): chlorothalonil 1 : 1 to 1: 150 1 : 1 to 1: 100 (19-3) · · cymoxanil 10 : 1 to 1: 50 5 : 1 to 1: 20 (19 -4): edifenphos 10 : 1 to 1: 50 5 : 1 to 1: 20 (19-5): famoxadone 50 : 1 to 1: 50 10 : 1 to 1: 20 (19-6): fluazinam 50 ·· 1 to 1: 50 10 : 1 to 1: 20 (19-7): copper oxychloride 1 : 1 to 1: 150 1 : 5 to 1: 100 (19-8): Copper hydroxide 1 : 1 to 1: 150 1 : 5 to 1: 100 (19-9) · Oxdixyl 10 : 1 to 1 ·· 150 5 ·· 1 to 1: 100 (19-10): spiroxamine 50 : 1 to 1: 50 10 : 1 to 1: 20 (19-11) ··二石荒酉昆 (dithianon 50 : 1 to 1: 50 10 : 1 to 1: 20 (19-12): metrafenone 50 : 1 to 1: 50 10 : 1 to 1: 20 (19-13): taste σ Fenamidone 50 : 1 to 1: 50 10 : 1 to 1: 20 (19-14) ·· 2,3-Butyl-6-chlorothieno[2,3-d]pyrimidin-4(3H)one 50 : 1 to 1: 50 10 : 1 to 1: 20 (19- 15) ················································ 100 -125- 200814928 Mixing ratios are preferred. Mixing ratios are particularly good (19-17) ··Kasugamycin 50 : 1 to 1: 50 10 : 1 to 1: 20 (19-18 ························· : 20 (19-20): Tricyclazole 50 : 1 to 1: 50 10 : 1 to 1: 20 (19-21) : N-({4-[(cyclopropylamino)-carbonyl) Phenyl}sulfonyl)-2-methoxybenzamide 10 : 1 to 1: 150 5 : 1 to 1: 100 (19-22) : 2-(4-chlorophenylmethoxy bucket (prop-2-ynyl-4-yloxy)phenyl]ethyl}-2-(propan-2-free-1-yloxy)ethinamide 50 : 1 to 1: 50 10 : 1 to 1: 20 ( 19-23): quinoxyfen 10 : 1 to 1: 150 5 : 1 to 1: 100 Category (20): (thio)urea derivative 50 : 1 to 1 : 50 10 : 1 to 1: 20 Category (21): decylamines 50 : 1 to 1: 50 10 : 1 to 1: 20 Category (22): Triazolopyrimidines 50 : 1 to 1: 50 10 : 1 to 1: 20 Class (23): Iodochromones 50 : 1 to 1: 50 10 : 1 to 1: 20 Category (24): Biphenylcarboxylamine 50 : 1 to 1 : 50 10 ·· 1 to 1: 20 Class (25): Alkylcarboxamides 50 : 1 to 1: 50 10 : 1 to 1: 20 Class (26): Alkylcarboxamides 50 : 1 to 1: 50 10 : 1 to 1: 20

In each case, the mixing ratio is selected from a mixture which can achieve synergy, and the ratio between the compound of the formula (I) and the compound of one of the formulas (2) to (26) may vary depending on the individual compound. The active compound compositions according to the invention have a strong microbicidal action and can be used for crop protection and material protection for controlling undesirable microorganisms such as fungi and bacteria. For crop protection, when used as a fungicide, it can be used for controlling Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and incomplete fungi ίο (Deuteromycetes) fungi. In the case of crop protection, when used as a bactericide, it can be used for controlling Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae, and Streptomycetaceae, 15 genus 0 p Listed under the generic name above, some of the pathogens causing fungal and bacterial diseases can be exemplified as follows, but not limited to these: causing powdery mildew (powdery mildew) Pathogens, for example, Blumeria species, for example, Blumeria graminis of the barley powdery fungus pathogen, Podosphaera species, such as powdery mildew (Podosphaera leucotricha) \ monofilament Sphaerotheca species, for example, Sphaerotheca fuliginea; -127- 200814928 Uncinula species, for example, necator, causing rust pathogens, for example, rust Gymnosporangium species, for example, Gymnosporangium sabinae, coffee Hemileia species, for example, Phyllostachys pubescens (Kvastatrix) \ , Phakopsora species, for example, soybean rust (external (7) pachyrhizi A Phakopsora meibomiae) \ i rust fungus ( Puccinia secies), for example, wheat rust pathreta), Uromyces species, for example, Uromyces appendiculatus; Oomycetes pathogen causing disease, for example, 15 Bremia species, for example, Phytophrenia (7) ^ lactucae), Peronospora species, for example, pea downy mildew/> plus or downy mildew (household; Phytophthora) Species), for example, Phytophthora infestation, Plasmopara species, for example, Grape bacterium viticola; Pseudoperonospora species, for example, Pseudomonas sinensis ( Pseudopewnospora humUliHMtMPseud〇per_sp〇ra -128- 200814928 cubensis); Pythium species, for example, Pythium ultimum (such as ultimum); causing leaf spot disease and leaf blight a pathogen of wilting, for example, an Alternaria species, for example, Alternaria solani;

10 15

Cercospora species, for example, Cercospora beticola; Cladiosporum species, for example, Cladiosporium cucumerinum, Cochliobolus species, for example Helminthosporium (conidial type: Drechslera, syn: Helminthosporium); Colletotrichum species, for example, Anthrax (Colletotrichum lindemuthaniuni)

Cycloconium species, for example, Cje/oco/iiwm oleaginum \Diaporthe species, for example, Diaporthe citri l Elsinoe species, for example , Elsinoe fawcettii \ Gloeosporium species, for example, Gloeosporium laeticolor \ Glomerella species, for example, grape late rot fungi (G/omere//a -129- 20 200814928 cingulata); Guignardia sPecies, for example, Guignardia bidwelli ·, 5

10 15

Leptosphaeria species, for example, Leptosphaeria maculans \ Magnaporthe species, for example, Magnaporthe grisea \ Mycosphaerella species, For example, graminicola ·, Phaeosphaeria species, for example, Phaeosphaeria nodorum, Pyrenophora species, for example, Pyrenophora teres \ Leaf spot genus (Ranmlaria species) 'For example, collo-cygni, Rhyndosporium species, for example, Rhynchosporium secalis, Septoriaspecies, such as 'Saccharomyces cerevisiae · 〇; Typhula species, for example, wheat rot fungus (housekeeper "in incarnata"), genus Ventura species (for example, apple black spot disease as inaequalis) \ causing roots a pathogen of a disease of the stem, for example, a Corticium species, for example, c〇rtidum, a round body; -130- 20 200814928 Fusarium species, for example, FMsar/wm oxysporum \ Gaeumannomyces species, for example, wheat whole pathogen; 5

10 15

Rhizoctonia species, for example, Rhizoctonia solani,

Tapesia species, for example, Tapesia acuformis; Thielaviopsis species, for example, Thielaviopsis basicola; pathogens causing ear and panicle diseases, including corn and cob, For example, Alternaria species, for example, Alternaria spp.; Aspergillus species, for example, Flavobacterium flavus; Cladiosporium species, for example, Cladicporium spp. ·, Claviceps species, for example, ergot fungus purpurea; Fusarium species, such as culmorum; Gibberella species ), for example, Zeaeus zeae) \Monographella species, for example, wheat snow rot - 131 - 20 200814928 (Monographella nivalis) \ A fungus that causes smuts, for example, A. sphaeroides Sphacelotheca species, for example, Sphacelotheca reiliana \ Tilletia species, such as wheat net Black powder fungus (heart is like caries) \ rye stem smut (Urocystis species), for example

10 15

{Urocystis occulta); Ustilago species 'eg 'S. serrata nuda' \ A pathogen causing fruit rot, for example, Aspergillus species 'eg , Astragalus flavous; Botititis species, for example, Botrytis cinerea (7) to lose cinerea); 'Expanding Penicillium oil 囷 病 ' 'Penicilium species, for example, Penicillium species, for example {Penicillium expansum) \Sclerotinia species, for example, (Sclerotinia sclerotiorum); Verticilium species, such as {Verticilium alboatrum) \ Seed-and soil-borne causing decay and blight, and Pathogens causing seedling diseases, for example, Fusarium species, for example, Fusarium oxysporum 20 200814928 culmorum) Phytophthora species, for example, Phytophthora (Ρ/Ρ 叩; cactorum); Pythium (Pythium species), for example, Pythium ultimum (ultimate); Rhizoctonia species, for example, Rhizoctonia solani (Rhi) Zoctonia solani);

10 15 Sclerotium species, for example, chalk pathogens (&/"〇(~所rolfsii); pathogens causing cancer, galls and witches'broom For example, Nectria species, for example, TVecir/a galligena; a pathogen causing blight, for example, Monilinia species, for example, Trichophyton laxa) Pathogenic bacteria causing deformation of leaves, flowers and fruits, for example, Taphrina species, for example, rop/zWwfl deformans; pathogens causing degenerative diseases of woody plants, for example,

Esca species, for example, Phaemoniella; pathogens causing diseases of flowers and seeds, for example, Botrytis species, for example, Botrytis cinerea; >133-20 200814928 Pathogen causing disease of plant bulbs For example, Rhizoctonia species, for example, & Rhizoctonia solani; bacterial pathogen causing disease, for example, Xanthomonas species For example, Xanthomonas campestris pv. oryzae; Pseudomonas species, for example,

10 15

8 {Pseudomonas syringae pv. Lachrymans); Erwinia species, for example, apple heat-treating bacteria (^^仏amylovora) \ Preferred for use in controlling the following soybean diseases: causing leaves, stems Pathogens of fungal diseases such as pods and seeds, for example, alternaria leaf spot, temiissima, anthracnose {Colletotrichum gloeosporoides dematium var. truncatum)^ M (brown spot) Ugly shell needle, *' cercospora leaf spot and blight (large ugly pathogen, moxibustion wcAzz), wet and rot (ehomephora) leaf wilting (Choanephora infundibuiifera trispora (syn)), Dactuliophora leaf iii disease (Dactuliophora gfyches) 'downy mildew (d. edema, corpse mfl / iwrfcfl), drechslera blight, frogeye leaf spot (soybean gray spot, soli · ηα ), Leptosphaerulina (Isolation), phyllostica leaf spot (Soybean leaf spot) -134-20 200814928 5

10 15 bacteria, powdery mildew (powdery mildew) (Anopheles sinensis, ¢/3⁄4^^), Pyrreochaeta leaf spot disease CPy (9) oc / m to fl g / jc / « es), Rhizoctonia Ball, leaf, and rhizoctonia aerial (foliage, and web blight) (Rhizoctonia solani), money disease {Phakopsora pachyrhizi), saab (Sabceloma glycines), black, rot Disease (stemphylium leaf blight), sorghum leaf spot (P. oleracea); a pathogen causing fungal diseases at the base of roots and stems, for example, black root rot (L. erythraea, Charcoal rot (Macrophomina /?/ζαχβ〇/ζ> 2β), Fusarium blight or wilt, root rot, and pod and root rot [ Soybean root rot is called oxyworwm), Fusarium oxysporum (F(10)ar/wm oribcer-like), Fusarium semitectum, Fusarium equiseti, mycoleptodiscus root rot , terrestris), Neocapmospora (Neocosmopspora) voszTz/ecifl), pod and stem blight (Diaporthe phaseolorum), i stem disease (stem canker) (Dalporthe phaseolorum var· caulivora) ), Phytophthora megasperma, brown stem rot (gum stem rot, gregfl/iz), Pythium aphanidermatum, Pythium irregulare, Pythium debaryanum , Pythium myriotylum, Pythium -135- 20 200814928 w/Umi/m), rhizoctonia root rot, stem rot, and damping-off (Rhizobacter serrata, Zn'zoc(6)z/fl/ (10)/), sclerotinia stem decay (Sclerotium sclerotiorum, Sc/eroOWa sc/eroi/orwm), sclerotinia southern blight (Cretaceous, Sc/er plus /ma ro/ /hz·), thielaviopsis root rot (Telecaopsis, Thielaviopsis basicola). The active compound composition according to the present invention allows plants which are treated with the whole plant (plants on the surface part and roots) to be propagated under the fact that they can be tolerated by plants at a concentration required for controlling plant diseases. The active compound compositions according to the invention can be used for foliar application or as seed dressings for the materials and seeds used, as well as for the treatment of soil. The active compound according to the invention is allowed to be treated by the plant under the fact that it can be used to control the disease of the plant, and the active compound according to the invention can be used as Seeds of the pathogenic A fungi cause most of the damage to crop plants, possibly 3 during sub-storage and when the seeds are introduced into the soil, when the plants are germinated and within 20, which is particularly critical. The roots and seedlings of plants with == are sensitive to special duties, and even the objects are _^= ,, with (4) appropriate group interest. The plants in the scorpion and the hair are therefore particularly pleasing to the soil and on the surface of the plant. Due to the consideration of the environment and the health of humans and animals, the active compounds are called The amount administered. The scales are still treated by treating the seeds of the plants to prevent the pathogens from being long-lasting. The goal of continuous improvement is _ _ has been known to encounter a distant ambition |,, wooden site people ... and 'the seed's Necessary development for the protection of seeds and germination of plants in the planting, plant protection immediately after plant germination to = = outside the external is also necessary to optimize the application of 2 2 = ' Μ provide seed and germinated plants The best #的保== ^ to the pathogen Zhenzhen attack, but will not let the ==; special, the method for processing the seed should also = the nature of the fungus inside the funeral, consider the seed and the sprout Medium plants can use the lowest amount of crop protection agent to achieve the most appropriate protection. Still 15 20 The invention thus relates in particular to a method for protecting seed and germinated plants from attack by pathogens by treating the seed with the composition according to the invention. The invention also relates to the use of a composition according to the invention for treating seeds to protect plants from germinating plants from pathogenic fungi. Furthermore, the invention also relates to seeds which have been treated according to the invention and which are protected from pathogenic fungi. One of the advantages of the present invention is that, according to the particular systemic nature of the compositions of the present invention, the treatment of seeds with these compositions not only protects the seed body, but also allows the post-emergence plant to behave this way. y is the processing performed. ~ The initial protection is protected from the attack of pathogenic fungi, and it is possible to dispense with the need to be considered as an advantage when crops are planted and shortly thereafter. The mixture according to the invention can also be applied, in particular, the transgenic gene. Plant seeds. Any of the plants described in the field of forestry or horticulture (see, wheat, barley) The composition according to the invention is suitable for protection in agriculture, warm

: from the use of cockroaches to separate plants from the cob, shell, stem, coat (pod), j hair or pulp, so, for example, it is possible that the treatment has been harvested, cleaned and the moisture has been dried to 15% Seeds below the weight, or, possibly, treated with water, dried and then dried. μ When handling seeds, the amount of the composition according to the invention applied to the seed and/or the amount of other additives must be chosen with great care to avoid damage to the germination of the seed, for example, in particular, An active compound that may cause a plant toxic effect at a rate of 200814928. The composition according to the invention can be applied directly, that is to say without the need to contain additional components or used without dilution; it is customary to apply the composition to the seed in a suitable formulation form; for treating the seed Suitable formulations and methods are known to the expert and are disclosed by, for example, the following

10 15 20 In the document ... US 4,272,417 A, US 4,245,432 A,us 4,8〇M30 A, US 5,876,739 A, US 2003/0176428 A, WO 2002/080675 A1, WO 2002/028186 A2 活性Activity according to the invention Compound compositions are also suitable for increasing crop yields 'in addition' they exhibit reduced toxicity and better tolerance to plants. At certain concentrations and application rates, the active compound compositions according to the invention also have the potential to reinforce plants within plants, which are therefore suitable for the defense of fixed plants for attack against unwanted microorganisms. Plant-enhanced (resistance-induced) substance, understandably, in this context, a substance that has the ability to provoke a plant's defense system, when the plant is subsequently inoculated with unwanted microorganisms, the treated silver substance The ability to fight this creature. In the case of the present invention, it is understood that the undesired microorganism refers to the pathogens mentioned above, the fine «and the virus, and thus, after treating the plant with the compound according to the present invention 9 can be The plants are protected against the above-mentioned original bacteria for a period of time, and the effective protection period is usually 1 to 10 days after the treatment of the plants with the live = compound, preferably from 7 to 10 days. The fact that the active compound can be well tolerated by the plant at -139-200814928 at the concentration required to control plant diseases allows for the treatment of plant parts in the air, tree stems and seeds for propagation, and soil. Herein, the active compound according to the present invention is used for controlling diseases which are particularly good. · Diseases in cereals, for example, for diseases caused by the genus Puccinia specips, and in grapes. Diseases and diseases in the cultivation of fruit trees and vegetables, for example, bacteria against Botrytis species, Venturia species, or Alternaria species. The active compounds according to the invention are also suitable for increasing the yield, in addition they exhibit a lower degree of toxicity to plants and are well tolerated by plants. Appropriately, the active compounds according to the invention can also be used as herbicides at certain concentrations and application rates, for regulating plant growth and for controlling animal pests, suitably they can also serve as intermediates and Precursor' is used to synthesize other active compounds. According to the present invention, it is possible to treat plants and plants of the whole plant, and it is understood herein that the term "plant" refers to all plants and plant communities, for example, desired and unwanted wild plants or crops. Plants (including naturally occurring crop plants); crop plants can be grown, obtained by traditional breeding and optimization methods or by biotechnology and genetic engineering, or by using these methods, including transgenic genes The more plants include the unprotected plant species that are certified by the plant breeder; the plant parts are understood to refer to all plant plaques on the surface and in the underground part of the plant, such as 'sprouts, leaves' An example of a flower and root can be mentioned as a leaf? -140- 200814928 Needles, stems, tree stems, flowers, fruit bodies, fruits and seeds, and roots, bulbs and stolons; parts of plants also include harvested materials and growing parts and propagation materials, for example, seedlings , bulbs, stolons, seeds and seeds. 5 According to the invention, the plant and plant parts are treated with the active compound, in a conventional manner, directly treating the plant itself or acting on its surroundings, in the living space or in the storage, for example by dripping, sprinkling, evapotranspiration, fog =, sprinkling • cloth, brush, and, for propagation material, especially seeds, by means of application- or multi-Jan coating; here, the active compound combination can be used to treat individual active compounds before treatment. Prepared by mixing, or treated in such a manner that the carboxamide in the class (1) is applied successively, followed by the application to the active compound of the class 5, however, it is also possible to use the active compound of the class (7) to (10) The site of the plant or plant is treated, followed by treatment with a carboxamide of the G) class. 15, as already mentioned, according to the invention, all plants and parts can be treated, in a preferred embodiment, for the treatment of two species of wild plants and plant cultivars, or those by conventional organisms Breeding methods for obtaining plants, such as those obtained by hybridization or protoplast fusion, and their various parts; in another preferred embodiment, for processing by gene two-way 20 & and appropriate combination of traditions Methods The transgenic plants and plant cultivars (genetically modified organisms) obtained by the method, and various parts thereof; so-called "sites", "plant parts" or "plant parts", whose meanings are as explained above. Particularly suitably, the plants for treatment according to the invention are those which can be mentioned or used in plant cultivars. -141 - 200814928 Depending on the plant variety or plant cultivar, its distribution and growth conditions (soil, climate, growth period, nutritional status), the treatment according to the invention may also lead to super-addition ("co-multiplied,") The effect, therefore, for example, a reduced application rate and/or an augmented activity profile and/or an increase in the activity of the substance 5 and the composition which can be used according to the invention, preferably plant growth, more economical or low temperature, More resistant to drought or water or soil salt, increased flowering, easier harvesting, accelerated ripening, higher yield, better quality and / or • Harvest with more nutritious value, harvest Better storage stability and/or processability of the product may exceed the actual expected effect. 10 Plants or plant cultivation of preferred transgenic genes to be treated according to the invention (ie those by genetic engineering) Method acquirer) includes all those plants genetically engineered to obtain beneficial useful properties ("features") of genetic material, examples of which are: better plant growth, more High temperature or low temperature resistance, more resistant to drought or salt content in water or soil, increased flowering period, 15^ easy harvesting, accelerated ripening, higher yield, better harvested products • shellfish and/or higher nutrition Value, better storage stability and/or processability of harvested products. An example of such a characteristic that deserves special emphasis is that plants are resistant to pests such as animals and microorganisms (eg, insects, mites, phytopathogenic fungi, bacteria). And/or virus) has better defensiveness and also increases plant tolerance to certain herbicidal compounds. Plants that can be mentioned as transgenic genes are important crop plants, such as grains (wheat, rice). ), corn, soybeans, horses, potatoes, cotton, canola and fruit trees (apple, pear, citrus and Portuguese, vine) and especially emphasize corn, soybean, horse yam, cotton and rapeseed The emphasis is on the ability to increase the resistance of plants to - insects by the toxins formed in plants, especially those from the genetic material from S. faecalis (10,000) For example, by gene CrylA (a), CrylA (b), CrylA (c), CryllA, CrylllA,

CryIIIB2, Cry9c, Cry2Ab, Cry3Bb and CrylF and also include 5

10 15 Composition) (hereinafter referred to as "Bt plant"); other features that are particularly emphasized are that plants have certain herbicidal compounds (eg, misoprostone, scutellaria, An increase in glyphosate or phosphinotricin (such as the "PAT" gene); the genes involved in the desired characteristics can be undoubtedly mixed with other genes. Among the plants of the transgenic gene, an example of a "Bt plant" that can be mentioned is a corn variety, a cotton variety, a soybean variety, and a potato variety sold under the trade name: YIELD GARD8 (for example, corn). , cotton 'soybean', KnockOut8 (eg corn), StarLink® (eg corn), Bollgard (cotton), Nucotn® (cotton) and NewLeaf® (potato); the herbicide-tolerant plant species Corn varieties, cotton varieties and soybean varieties are sold under the following trade names: Roundup Ready8 (resistant to the most stone bases such as corn, cotton, soybeans), Liberty Link 8 (Finyl Phosphate Trisin' such as oil Dish), IMI8 (imidazole-resistant ketone) and STS8 (sulfonyl-resistant urea, such as corn), which can be mentioned as a herbicide-weaking plant (a herbicide-tolerant plant bred in a conventional manner) including the name of Clearfielf8 Vendors (such as corn), of course, these statements also apply to plant cultivars that have these genetic characteristics or that will be developed and/or sold in the future with the genetic characteristics to be developed. Depending on its individual physical and/or chemical nature, the active compound composition can be converted into conventional formulations, for example, solutions, emulsions, suspensions, powders, dusts, foams, pastes, Soluble powders, granules, gas solutions, suspension-emulsion concentrates, natural and synthetic materials infiltrated with active compounds, microcapsules coated in polymeric materials, and coating compositions for seed use, and ULV Cold and warm misty formulation. These formulations are produced in a known manner, for example, by mixing the active compound with a spreading agent, which is a liquid solvent, a liquefied gas under pressure, and/or a solid carrier, optionally using an interface. Active agents, ie, emulsifiers and/or dispersants, and/or foam formers. If the extender used is water, it is also possible to use, for example, an organic/treat agent as an auxiliary solvent. Primarily, suitable liquid solvents are: aromatics such as xylene, toluene or alkylnaphthalenes; Chlorinated aromatic or chlorinated aliphatic hydrocarbons, for example, chlorobenzenes, vinyl chlorides or methylene chloride; aliphatic hydrocarbons such as cyclohexane or paraffin, such as petroleum repellents; minerals and Vegetable oils; alcohols, for example, butanol or glycol and their ethers and esters, ketones, such as acetone, methyl ethyl, methyl isobutyl ketone or cyclohexanone, strong polar solvents For example, dimethylformamide and dimethylhydrazine; or water. By liquefied gas extender or carrier, it is understood to mean a liquid which is a gas at standard temperature and pressure, for example, a gaseous solution propellant such as butane, propane, nitrogen and carbon dioxide. Suitable solid carriers are, for example, money salts and ground natural minerals such as kaolin, clay, talc, chalk, quartz, American activated clay, montmorillonite or diatomaceous earth, and fine synthetic Materials, ^ -144 - 200814928 5

10 15 If the south is dispersed, the oxidizing is not fine; the appropriate solid state of the granule is: for example, natural rock crushed and divided, for example, calcite, marble, pumice, sepiolite And dolomite "go is a synthetic particle of inorganic and organic scrap, and particles of organic material, for example, mineral chips, coconut shell, jade shaft and stem; suitable emulsifier and / or foam forming agent is : for example, nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid i, polyoxyethylene aliphatic alcohol ethers, for example, alkyl aryl polyglycol ethers, alkyl sulfonates, alkanes a base sulfate, an aryl sulfonate, or an egg-derived hydrolysate; suitable dispersants are, for example, lignin sulfurous acid waste liquid and methyl cellulose. Drying agents 'for example, 竣 methyl fiber And natural and synthetic polymers in powder, granule or latex form, for example, gum arabic, polyvinyl alcohol and polyvinyl acetate, and natural phospholipids, for example, cephalin and egg ly, Synthetic phospholipids can be added to the formulation Other possible additives are mineral oils and vegetable oils. It is also possible to use coloring agents, for example, inorganic pigments such as iron oxide, monomethicone and Jinluslan, and organic dyes such as alizarin. Dyes, azo dyes and metal phthalocyanine dyes, and trace nutrients such as salts of iron, manganese, butterfly, copper, cobalt, molybdenum and zinc, etc. used in the formulation of commercially available formulations. The active compound content can vary over a wide range, and the concentration of active compound used to control the use of animal pests (eg, insects and spider mites) can be comprised from 〇.1 and 95% by weight. The active compound in between and preferably comprises from 0.0001 to 1% by weight, administered in a conventional manner suitable for the use of the variant -145-20 200814928. Used in a formulation for controlling unwanted pathogenic fungi The active compound is usually comprised between 0.1 and 95% by weight, preferably between 0.5 and 90%. 5 The active compound composition according to the invention can be present as a commercially available formulation and Formulations prepared using the formulations are used, for example, ready-to-use solutions, emulsifiable concentrates, emulsions, suspensions, wettables|powders, soluble powders, dusting agents, and granules, which are conventionally used. Use, for example, by washing (soaking), irrigating, sneezing, atomizing, spreading, dusting, foaming, laying, and treating the seeds with dry powder, treating the seeds with solution, and being water soluble Powder treatment of seeds, treatment of seeds with water-soluble slips, or by formation in the outer shell, etc. The active compound compositions according to the invention may be presented as commercially available formulations and from these formulations The prepared form and other active compounds (eg, insecticides, attractants, infertile agents, fungicides, acaricides, nematicides, fungicides, growth regulators or The herbicide) is used as a mixture. When the active compound composition according to the invention is used, the application rate can vary within a substantially relatively broad range depending on the type of application, and when used for 20 treatment of plant parts, the application rate of the active compound composition is usually between 0.1. Between 10 000 g / ha, preferably between 10 and 1000 g / ha, when used to treat seeds, the application rate of the active compound composition is usually between 0. 001 and 50 g / kg of seed, preferably Between 0. 01 and 10 g / kg of seed, when used to treat soil, the application rate of active compound is usually -146 - 200814928 between 0 · 1 and 10 gram / hectare, should be The active compound composition may be in the form of a concentrate or, usually, formulated as a formulation, for example, as a powder, a granule, a solution, a suspension gas, an emulsion or a paste.

10 20 The above formulation may be formulated in a known manner, for example, by mixing the active compound with at least one solvent or diluent, emulsifier, dispersion, and/or dry or fixative, water repellent, If necessary, add a desiccant and a UV stabilizer, and if necessary, add a coloring agent and a pigment and other processing aids. The good fungicidal action of the active compound compositions according to the invention can be exemplified by the following examples, although the individual activations exhibit a weak fungicidal effect, and the compositions exhibit far more effects than their individual The sum of the effects of the ingredients. When the active compound composition often exceeds the sum of the effects of its individual active compounds in the fungicidal action, it has a synergistic effect. For a desired gas enthalpy effect of a fraction comprising the two active compounds given, according to the formula of S.R. Colby, ^1(ϊιιΜη§ Synergistic and Antagonistic Responses Herbicide

Combinations", Weeds 1967. U, 20-22), calculated as follows: If X represents the exertion of active compound A at the application rate of gram/m^^, -147-200814928 γ represents no; The rate of application of the active compound Β, Ε represents the application rate of the active compound at the application rate of m and ηg / νν礞, 5 • τ XX γ 1 1J Ε-Χ +Υ --- 100 Secrets here, the efficacy is expressed in %, 〇% represents the equivalent of the untreated control, and 100% of the efficacy represents no infection was found. If the real bactericidal effect is more than calculated The value of the composition is superadditive, that is, a synergistic effect occurs. In this case, the effectiveness of the actual sacrifice is greater than the expected effect of 15 using the above formula (Ε). The present invention is illustrated by the following examples, but the present invention is not limited to these embodiments. [Examples] 5 examples of straight cases Α · Α 丝 核 ( ( and / ^ z 〇 c such as test (in the camp) / name This micro-test is attached to a microtiter plate using a horse yam dextrose gravy (Potat) o-Dextrose Broth, PDB) was carried out as a liquid test medium, and the active compound was inoculated into Rhizoctonia solani using a technical grade (active material) dissolved in acetone (Li (7) (10) 菌 菌 悬 -148 - 200814928 After floating for 5 days in a dark room and shaking (10 Hz), the light transmittance of each filled cavity of the microtiter plate was measured by a photoelectric colorimeter. 0% represents the efficacy of growth in the control group. The 100% potency represents no growth of the fungus. Tables A1 and A2 below clearly show that the active compound composition according to the invention is more active than the calculated activity, i.e., exhibits a synergistic effect. Table A1 : Rhizoctonia solani test (in test tube) / microtiter plate active compound active compound application rate (ppm) potency (%) (1-1) 0.01 83 (1-28) 0.1 28 (1-31) 0.1 53 ( 1-31) 0.03 36 (1-31) 0.003 63 (1-39) 1 46 (1-39) 03 37 (GBO 827) 0.3 46 meperfenone 1 46 meperfenone 0.1 1 metconazole 0.003 12 epoxyconazole 0.1 25 epoxyconazole 0.03 14 .-149 - 200814928 Epoxyconazole 0.01 73 According to the invention: (1-1) + epoxy conjugate (1: 1) 0.01+0.01 Calculated 97 Calculated 95 (1-28)+ Epoxyconazole (1 : 1) 0.1+0.1 52 46 (1-31) + thiconazole (1 : 1) 0.1+0.1 63 53 (1-31) + benzophenone (1 : 1) 0.003 + 0.003 82 67 (1-31) + Cycloconazole (1 : 1) 0.03 + 0.03 62 45 (1-39) + benzophenone (1 : 1) 1 + 1 92 71 (1-39) + GBO 827(1 : 1) 03 + 03 98 66 measured = actual found efficacy; calculated = effectiveness calculated using the Colby formula Table A2: Rhizoctonia solani test (in vitro) / microtiter active compound active compound Application rate (ppm) Efficacy (%) (1-39) 0·1 43 Epoxyconazole 0.1 42 According to the invention: (1-39) + epoxyconazole (1 : 1) 0.1+0.1 Calculated 91 67 measured = the actual found effectiveness; calculated = the effectiveness calculated using the Colby formula -150- 200814928 Example one: - Φ f photo 茧 (Pg / | / ei7 / | ·!! Gy/m(10)/g) test (test tube ίι/microtiter plate) This micro-test is applied to microtiter plates using potato dextrose gravy (Potato-Dextrose Broth, PDB) was carried out as a liquid test medium, and 5 active compounds were used as the 'technical-grade' dissolved in acetone to become 'inoculated into the sputum-like bacteria Z> reWcanw/e) The sub-suspension was inoculated for 4 days in a dark room and shaking (1 Hz), and the light transmittance of each filled cavity of the microtiter plate was measured by a photoelectric ratio meter. 〇% represents the equivalent of the growth in the control group, while 1〇〇. /0 effectiveness representative ίο did not see the growth of fungi. Table B below clearly shows that the active compound composition according to the present invention is more active than the calculated activity, i.e., exhibits a synergistic effect. Table B: Ophiopogon fungus test (in test tube) / microtiter plate active compound active compound application rate (ppm) potency (%) - (1-39) 03 65 metconazole 0.3 3 according to the invention: 1-39) + diconazole (1: 1) 0.3 + 0.3 The calculated 73 66 L·'--L-———— 15 measured = the actual found effect; calculated = calculated using the Colby formula Efficacy - 151 - 200814928 Example C: Fusarium oxysporum (eg, along the test (in vitro) / microtiter _ This micro-test is on a microtiter plate using Potato-Dextrose Broth (PDB) The reaction is carried out as a liquid test medium, and the active compound is inoculated into a gray grape hug using a technical-grade active ingredient dissolved in acetone (approximately 0 ^; along the stalk suspension, in a dark room and shaken (10) After 4 days of inoculation at Hz), the light transmittance of each filled cavity of the microtiter plate was measured by a photoelectric colorimeter. 〇% represents the efficacy equivalent to growth in the control group, and 1% of the efficacy represents no Growth of fungi. Tables C1 and C2 below clearly show the active compound group according to the invention The activity of the substance is greater than the calculated activity, that is, it exhibits a synergistic effect. Table C1: Botrytis cinerea (in vitro) / microtiter plate Active compound active compound application rate (Ppm) Efficacy (%) (1- 1) 〇·01 18 (1-29) 1 54 (1-39) 〇J 51 pyrachlostrobin 0.1 42 pyrachlostrofoin 1 27 metconazole 0.01 5 According to the invention: (1 1)+ 灭康口圭 (1 : 1) —---- 0.01+0.01 Measured 31 Calculated 22 -152- 200814928 (1-29)+ Bai Kemin (1 : 1) 1 + 1 93 66 (1 -39)+100gmin (1:1) 0.1+0.1 94 72 measured = actual found efficacy; calculated = potency calculated using the Colby formula C2: Botrytis cinerea (in vitro) / microtiter active compound Active compound application rate (ppm) Efficacy (%) (1-1) 03 31 (1-4) 1 29 (1-31) 0·1 39 100 gram (pyrachlostiObm) 0.3 20 pyrachlostrobin 1 16 克克敏(pyradilostrobin) 0.1 42 According to the invention: (1-4) + baikemin (1 : 1) 1 + 1 measured 78 calculated 40 (1_1) + 100 gram (1 : 1) 0.3 + 0.3 90 45 (1- 31) + Bai Kemin (1 : 1) 0.1 +0.1 86 65 measured = actual found efficacy; calculated using the Colby formula calculated 153-200814928 Example D: rice fatigue (PyriVrt </ar/a orvza) test (in trial camp) / micro Titration plate This microtest was performed on a microtiter plate using Potato-Dextrose Broth (PDB) as a liquid test medium, and the active compound was used in a technical-grade 5 dissolved in acetone. The active ingredient was inoculated into a spore suspension of rice blast fungus (jPyr/cw/flr/fl orj; za), and after inoculation for 4 days in a dark room and shaking (10 Hz), the microtiter plate was determined by photoelectric colorimeter. Transparency of each filled cavity. The 〇% potency represents the growth of the control group, and the 100% potency represents > no fungal growth was observed. Ίο The following Tables D1, D2 and D3 clearly show that the activity of the active compound composition according to the present invention is greater than the calculated activity, i.e., it exhibits an existing synergistic effect. Table D1: Rice blast test (in test tube) / microtiter plate active compound active compound application rate (ppm) potency (%) (1-29) 3 55 (1-29) 0.03 18 (1-4) 1 9 ( 1-31) 0.1 16 (M) 0.03 6 GBO 827 0.03 76 GBO 827 0.1 87 GBO 827 3 80 Metrafenone 3 60 -154- 200814928 Metaconazole 1 74 Meconazole ^ (metconazole) 0.03 66 epoxyconazole 3 81 According to the invention: (1-29) + epoxyconazole (1 : 1) (1-29) + diconazole (1 : 1) 3 + 3 0.03 + 0.03 Measured 98 85 Calculated 91 72 (1-29) + benzophenone (1 : 1) 3 + 3 90 82 (1-4) + thiconazole (1 : 1) 1 + 1 97 76 (1 -31)+ GBO 827(1 : 1) 0.1 +0.1 99 89 (1-1)+ GBO 827(1 : 1) 0.03 + 0.03 87 77 Measured = actual found effect; calculated = calculated using Colby formula Table of potency D2 #· rice blast fungus (Pjr/cw^r/fl) test (in test tube) / microtiter plate active compound active compound application rate (ppm) potency (%) (1-4) 3 33 (1- 28) 0.03 19 灭康^(metconazole) 0.03 10 苯苯菌_(metrafeiKme) 3 80 phenoxylinone (metrafenone) 0.03 45 according to this hair : (1-4)+ GBO 827(1 : 1) 3 + 3 Measured 99 Calculated 87 (1-28) + benzophenone (1 : 1) 0.03 + 0.03 95 55 -155 - 200814928 (1- 28) + Deconazole (1 : 1) 0.03 + 〇.〇3 58 27 Measured = actual found efficacy; calculated = potency table D3 calculated using Colby formula: rice blast fungus (Pjr/c«/ariVi Test (in test tube) / microtiter plate active compound active compound application rate (ppm) potency (%) (1-4) 3 33 mettrafenone 3 55 according to the invention: (1·4) + benzene The ketone (1: 1) 3 + 3 was calculated to be 75 70 measured = the actual found efficacy; calculated = the effect calculated using the Colby formula _ real _ case E: maize red emblem (10) g) test (in test tube v檄Trip handle This type test was applied to a microtiter plate using Pot-Dextrose Broth (PDB) as a liquid test medium, and the active compound was used in an industrial grade dissolved in acetone ( Technical_grade) Active ingredient, inoculated into a spore suspension of Gibberella zeae, inoculated in a dark room and shaken (10 Hz) for 3 days, the microtiter plate was determined by photoelectric colorimeter Transparency of each filled cavity. The 0% potency represents the growth of the control group, 1〇〇0/. The efficacy representative did not see the growth of fungi. Table E below clearly shows that the active compound composition according to the present invention is more active than the calculated activity, i.e., exhibits a synergistic effect. -156- 200814928 Table E: Gibberella rubrum test (in test tube) / microtiter plate active compound active compound application rate (ppm) potency (%) (1-4) 1 —---—___ — (1-28) 0·1 (1-29) 0.3 —_ —_ 59 Epoxyconazole 1 65 GBO 827 0.1 ] GBO 827 03 --- 24 According to the invention: 0.1+0.1 Calculated, (1-29 ) + GBO 827 (1 : 1) 78 69 (1-28) + GBO 827 (1 : 1) 0.3 + 0.3 43 37 (1-4) + Epoxyconazole (1 : 1) 1 + 1 --- - 84 73 Measured = actual found efficacy; calculated = effectiveness calculated using the Colby formula Example F: Pseudomonas pallidum test (in test tube) / derivative; ji 5 This micro-test is applied to a microtiter plate Potato-Dextrose Broth (PDB) was carried out as a liquid test medium, and the active compound was inoculated into Alternaria alternata using a technical grade (active) formulated in acetone. (7) The suspension was suspended with W(3//), and after inoculation for 3 days in the dark room and shaking (10 Hz), the light transmittance of each filled cavity of the microtiter plate was measured by photoelectric colorimeter. Sex. -157- 2008 14928 〇% potency represents the growth of the control group, 100% efficacy means no growth of the fungus. Table F below clearly shows that the activity of the active compound composition according to the invention is greater than the calculated activity, ie , which exhibits a synergistic effect table F · Alternaria alternata (in vitro) / microtiter plate active compound active compound application rate (ppm) potency (° / 〇) (1_1) 0.03 66 phenacridone (metrafenone 0.03 14 According to the invention: (1-1) + benzophenone (1 : 1) 03 + 03 Calculated by calculation *) 72 71 Measured = actual found efficacy; calculated = calculated using the Colby formula Efficacy of the case G: _I nuclear cavity (Pyrg / i or / Wgized rgs) test (Daily V 徭 让 让 让 让 溶剂 溶剂 溶剂 : : : : : : : : : : : : τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ The heavy alkylaryl polyglycol ether is a suitable active compound formulation, 1 part by weight of the active compound or active compound composition, mixed with the amount of solvent and emulsifier, 15 and this concentrate in water Dilute to the desired concentration. To measure the activity of the formula 5, at the stated application rate. The active compound preparation is sprayed on the young plant, and after the spray layer is dried, the plant is sprayed with a suspension of the genus of the genus of the genus, and the plant is left at 158·200814928 20° C. and 100% relative The humidity in the incubator was carried out for 48 hours. The plants were then transferred to a greenhouse of about 2 (TC and about 80% relative humidity. Evaluation was performed 10 days after inoculation, 0% represents the efficacy equivalent to the control group, and 100% of the efficacy represents no infection. Table G · · Bougainvillea test (barley) / protective active compound active compound application rate (g / ha) potency (%) (1-2) 3L25 22 (1-12) 31.25 --------- 56 Pycrostobin 31.25 78 Epirubicone _ (metrafenone) 31.25 0 Epoxyconazole 31.25 0 metconazole 31.25 0 tebuconazole 31.25 0 GBO 827 31.25 0 white (boscalid) 31.25 22 According to the invention: (1_2) + 100 gram dorbin 31.25 + 31.25 Measured - 94 78 Calculated 83 22 (1-2) + benzophenone 31.25 + 31.25 (1-2) + epoxy Kang α Sit 31.25 + 31.25 89 22 (1-2) + 灭康0 sit 31.25 + 31.25 89 22 (1-2) + HWG1608 3L25 + 3L25 100 22 -159- 200814928 (1-2) + GB0827 31,25+ 31.25 78 22 (l-2) + RK02273 31.25 + 31.25 100 39 (1-12) + 克克司多宾31.25 + 31.25 100 92 (1-12) + Epirubicin _ 31.25 + 31.25 89 56 (1_12) + Epoxy Oxazole 31.25+ 31 .25 89 56 (1-12) + 消康嗤31.25 + 31.25 94 56 (1-2) + 克力力31.25 + 31.25 89 56 (1-2) + GB0827 3L25 + 3L25 94 56 (1-2)+白克力31.25+ 3L25 89 66 Measured = actual found efficacy; calculated = effectiveness calculated using the Colby formula Example H: Phytophthora (P/IV plus /? / | recognized still 71) test (tomato V protective solvent: 24.5 parts by weight of acetone 5 24.5 parts by weight of dimethylacetamide I emulsifier: 1 part by weight of aryl aryl polyglycol ether to give a suitable active compound formulation, 1 part by weight of active compound or active The compound composition is mixed with the amount of solvent and emulsifier, and the concentrate is diluted with water to the desired concentration. In order to test the protective activity, the active compound preparation is sprayed onto the juvenile plant at the stated application rate, and after the spray layer is dried, the plant is sprayed with the aqueous suspension of the disease-causing bacteria/«/(2) plus) Liquid, the plants are placed in 2 (TC and 100% relative humidity incubator. -160- 200814928 and:: two into two: represents the equivalent of the control group

Table H· Phytophthora (P-engineer/|from_) test (fanlin)/protective compound active compound application rate (g/ha) —----- effectiveness (%) (1-2) 20 — -~—---- 8 Cyazofamid, Example 14-1 2 ——-- 24 According to the invention: (1-2)+ Saibo (lO^JL 20 + 2 46 calculated ^ Λα Measured == the actual found effectiveness, δ ten different = the use of Colby formula calculated drinking power -161-

Claims (1)

200814928 X. Patent application scope / / fungicidal active compound composition, carboxamide of formula (I) comprising class (1) Wherein R represents hydrogen or fluorine, R1 represents _'s 'Ci-CV alkyl' group, and nitro, 'CrC3_alkoxy' has from 1. to 7 fluorine, chlorine and/or > CrC3_halo-alkoxy or represent -C(R4)=N-OR5, and R2 represents a murine 'halogen' crcv alkyl, crcv haloalkyl, nitrogen, nitro, CrCr alkoxy, or a C1-C3-halo alkoxy group having from i to 7 hydrogen and/or a bromine atom, R4 representing hydrogen or a fluorenyl group, R5 representing a CVCV alkyl group, a CVCV alkenyl group or a crc5-alkynyl group, and at least one selected Active compounds from categories (2) to (25) below: JlilllL_ County (Strobihidns (ID) -162- 200814928 of ID) where A1 represents one of the following groups 10 A2 represents NH or Ο, A3 represents N or CH, and L represents one of the following groups The bond marked with an asterisk (*) is attached to the phenyl ring, 15 R11 represents phenyl, benzylidene, phenoxy or acridinyl, each of which is optionally substituted by one or two identical or different, selected from the group consisting of chlorine, cyano, decyl and trifluoromethyl Substituted, or represents 1-(4-phenylphenyl)oxazol-3-yl or represents 1,2-propanedione-bis(0-fluorenyl)-1-yl, R12 represents hydrogen or fluorine; 3) Triazoles of formula (III) m -163 - 20 ^00814928 wherein Q represents hydrogen or SH, m represents 0 or 1, ^ represents hydrogen, gas, chlorine, phenyl or 4, gas phenoxy, represents hydrogen or chlorine, A4 represents a direct bond, seven Out -, _(CH2)2_4_〇·, represents 10 -CH2-CHR - or *-CH=CR17-, the label of the towel marked with * is attached to the benzene ring, /, where R and R together represent · CH2 CH2 CH[CH(CH3) ± or - CH2-CH2-C(CH3)2-, A5 represents C or Si (Shixi), A also represents -N(R)- and a5 also together with r15 and r16 represent the group of ON-R18, in which Rn&Ru Represents the following base: The bond indicated by the * symbol is attached to R17, R15 represents hydrogen, hydroxy or cyano R represents cyclopropylethyl, 1-chlorocyclopropyl, CrC4-alkyl, CrC6-hydroxyalkyl, crC4- Alkylcarbonyl, CrC2-haloalkoxy-CrC2.alkyl, tridecylsulfanyl-crC2-alkyl, monofluorophenyl or phenyl, R15 and R16 together represent -〇-CH2-CH (R18 )-〇-, _o-ch2_ch(r丨8)-ch2-,-0-CH(OCH2CF3)_(CH2)2- or -0-CH-(2-chlorophenyl)-, -164- 20 200814928 A4, A5 and rU 尚键_接Μ ί CH=C_, where the singularity marked with * is attached to the base ring, Aicrc4 Goki or desert; 5 ~ ~" Sulphenamides ( IV) 10 Wherein R represents hydrogen or methyl; Charge (5) Pain--Iktin is self-priming of Valinamides: (5-1) IprovaHcarb (5-2) Λ^[ 2-(4-{|>(4-chlorophenyl)-2-propynyl]oxy}-3-decyloxyphenyl)ethyl]-indole 2-(methylsulfonyl)>D- Amidoxime (5-3) benthiavalicarb 15 Carboxamides of type (6) with formula (V) Η (V) wherein X represents chloro-3-indenyl group, representing 2,4-dichloroindazinyl, which represents a methyl, difluoromethyl or trifluoromethyl group at the 3-position and substituted at 5 - 1-methyloxazol-4-yl substituted by hydrogen or chlorine, representing 4-ethyl-2-ethylamino-1,3-thiazol-5-yl, representing 2-methyl-4- Trifluoromethyl-1,3-thiazol-5-yl, representing 1-methylcyclohexyl, substituted-165- 20 200814928 5 10 Table 2, 2-dichloro-1-ethyl-3-indenyl-propylpropyl, representing 2-air-2-propyl, 3,4-dioxaisothiazol-5-yl, 5,6·2 Hydrogen-2-mercapto-1,4-oxothio (杂环xathiin)-3-yl, 4,4-dioxo-5,6-dihydro-1,4-oxothiazepine-3- '4-indolyl·1,2,3-σ-cetyl-5-yl' 4,5-dimercapto-2-diindenyl ketone-based thiophene-3-yl' 1-methyl σ Pilo-3-yl, which is substituted at the 4-position with a fluorenyl or trifluoromethyl group and substituted at the 5-position with hydrogen or gas, or represents one to three identical or different selected from the group consisting of chloro, fluorenyl And a phenyl group substituted with a substituent of a trifluoromethyl group, or a 2-methylfuran-3-yl group, Υ represents a direct bond, and is optionally substituted with a substituent of a chlorine, a cyano group or an oxo group. Dibasic (alkylene), representing c2-cv enediyl (alkenylene) or thiophenyldiyl, Z represents hydrogen, crc6-alkyl or the group below: A6 represents CH, CBr or N, and r2() represents hydrogen, chlorine, bromine, cyano or crc6-alkyl, optionally selected from one or two identical or different selected gases and bis(CrCr alkyl)amines. a phenyl group substituted with a substituent of a carbonyl group, or a cyclopropyl-cyclopropyl group which may be substituted by a methyl group, R21 represents hydrogen, a gas or an isopropoxy group, and R22 represents a hydrogen, a gas, a bromine, a hydroxyl group, a thiol group, Trifluoromethyl, trifluoromethoxy or bis(CrC3-alkyl)aminocarbonyl, -166- 20 200814928 10 15 R2G and R21 also together represent *-CH(CH3)-CH2-C(CH3)2- or *-ch(ch3)-oc(ch3)2-, wherein the bond marked with an * is attached to R20; From the following dithiocarbamates: 1) Zinc Imanoze (mancozeb) Meng Naipu (maneb) to avoid ruin (metiram) (7-4) methyl zinc napo (propineb) (7_5) Dean ( Thiram) (7-6) Zinna (zineb) (7, 7) ziram zirconia __ with formula (VD alkaline (Acylalanines) Wherein it represents a carbon atom having an R- or S-configuration, preferably an s-configurator, 20 f3 represents a stupid methyl group, a furyl group or a decyloxymethyl group; Amine, anilinopyrimidines Ch3 -167- 200814928 where R24 represents methyl, cyclopropyl or 1-propynyl; group (10) has the formula (VIID of stupid imidazoles 5 among them 10 R25 and R26 each represent hydrogen or together represent -0-CF2-0-, R27 represents hydrogen, CrC4-alkylaminocarbonyl or represents 3,5-dimethyliso-sigma-4-yl fluorenyl, R28 represents chloro, decyloxycarbonylamino, chlorophenyl, furyl or thioxyl; Π1) is a formula (DO urethane 15 R2, cA〆. Wherein R29 represents n- or isopropyl, R3G represents bis(crc2-alkyl)amino-c2-c4-alkyl or diethoxyphenyl, and also includes salts of these compounds; (12) The class was selected from the following Dicarboxyboximides: (12-1) tetramdan (captafol) (12-2) captan (168-2) 200814928 (12-3) Folpet (12-4) iprodione (12-5) procymidone (12-6) vinclozolin 5 (13) selected from the following mites ( Guanidines) · (13-1) dodine (13-2) guazatine 10 (13-3) bisinoctylamine triacetate (13-4) gram heat net (burning benzoate) [iminoctadine tris (albesilate)] (13-5) donin (dodine (free test) )) (13-6) Imgoctadine (free test) Item (14) is selected from the following Imidazoles (14-1) Cyazofamid 15 (14-2) ) poker (prochioraz) (14-3) triazoxide (14-4) rice thin g (pefurazoate) (13th class < OQ morpholine (or its salt)·· among them (X) R31 and R32 independently of each other represent hydrogen or a fluorenyl group, R33 represents a CrC14-alkyl group (preferably a C12-CH-alkyl group), and C5-C〗 r-169- 20 200814928 Is a Ci(R)-Ci2-(alkyl)-phenyl-Ci-Cr alkyl group which may be substituted at the phenyl moiety by halogen or CrC4-alkyl or represents a propylene group which may be chlorophenyl and dimethoxy Phenyl substitution; Π 6) Pyrroles of formula (XI) 5 ID 15 wherein R34 represents chlorine or cyano, R35 represents gas or nitrate A, R36 represents chlorine, R35 and R36 together represent -0-CF2-0-; and group 7) is selected from the following (thio)phosphine Acid esters: (17-1) Fossex-aluminum (fosety 1-A1) (17-2) Phosphonic acid (17-3) tolclophos-methyl Π8) genus (XII) Stupid base acetamide Wherein R37 represents unsubstituted or fluoro-, chloro-, bromo-, decyl- or ethyl-substituted phenyl^2-caiyl^ 1,2,3,4-tetrazinyl or indanyl -170- 20 200814928 Class (19) is selected from the group of fungicides described below (19-1) benzoxanthene (acibenzolar-S-met; hyl) (19-2) chloroseni ( Chlorothalonil) (19-3) cymoxanil 5 (19-4) edifenphos (19-5) fascinated (famoxadone) (19-6) volts south (fluazinam) • (19- 7) Copper oxychloride (19-8) Copper hydroxide 10 (19-9) Oxadixyl (19-10) Spiroxamine (19-11) Disulfide ( Dithianon) (19-12) metrafenone (19-13) fenamidone 15 (19-14) 2,3-dibutyl-6-chlorothieno[2,3 -d]pyrimidin-4(3H)-one (19-15) prague fever (19-16) rice saponin (isoprothiolane) (19-17) kasugamycin (19-18) heat Phthalate 20 (19-19) Fermizone (19-20) Tricyclazole (19-21) N-({4-[(cyclopropylamino)carbonyl) Phenyl}sulfonate 2-methoxybenzoguanamine (19-22) 2-(4-chlorophenyl)-N-{2-[3-decyloxy-4-(propan-2-alkyn-1- Base -171 - 200814928 Milk)Phenyl]ethyl}-2_(propan-2-free-1-yloxy)ethinamide (19-23) quinoxyfen (20) is selected from the following (thio)urea derivative (20-1) pencycuron (20-2) thiophanate-methyl (20-3) ethyl-polyphanate-ethyl ( 2 hydrazines of the formula (XIII) (xm) wherein A7 represents a direct bond or -0-, A8 represents _C(=0)NH- or -NHC(=0)-, R38 represents hydrogen or CrC4-alkyl, and R39 represents a Ci-Cf alkyl group; Class (22) has the same formula (XIV). Triazolopyrimidines R4G represents crc6-alkyl or c2-c6-alkenyl, R41 represents CrC6-alkyl, and R40 and R41 together represent C4-C5-alkanediyl (alkylene), which is -172- 20 200814928 or Two of the crc6-alkyl groups, R42 represents bromine or chlorine, R43 and R44 independently of each other represent hydrogen, fluorine, chlorine or methyl, R44 and R46 independently of each other represent hydrogen or fluorine, and 5 R45 represents hydrogen, fluorine or Base, Idochromones of type (23) with formula (XV) 10 'Xx!jC0S wherein R48 represents CrC6-alkyl, R49 represents C"C6-alkyl, C2-C6-alkenyl or C2-C6-alkynyl; and (24) has the formula (XVI) Biphenvlcarboxamides 15 (XVI) wherein R5() represents hydrogen or fluorine, and R51 represents fluorine, chlorine, bromine, methyl, trifluoromethyl, trifluoromethoxy, -CH=N-OMe or -C(Me) di N-OMe , R52 represents hydrogen, fluorine, chlorine, bromine, decyl or trifluoromethyl, -173-20 200814928 Het represents one of the following Hetl to Het7 groups: 5 R53 represents iodine, fluorenyl, difluoromethyl or trifluoromethyl, | R54 represents hydrogen, fluorine, chlorine or methyl, R55 represents methyl, difluoroindenyl or trifluoromethyl, ίο R56 represents chlorine, Bromine, iodine, methyl, difluoromethyl or trifluoromethyl, R57 represents methyl or trifluoromethyl; (25) has the formula (XVID alkyl carbamide) 15 Wherein Het is as defined above, R58 represents hydrogen or fluorine, and R59 represents hydrogen, halogen, CrC3-alkyl or CrC3-haloalkyl having 1 to 7 fluorine, chlorine and/or bromine atoms. 2. A fungicidal active compound composition comprising the rebel amine of formula (1) of formula (1) -174-20 Wherein R represents argon or fluorine, and R represents halogen 'Ci-Cg-alkyl' Ci-Cg-i-based alkyl group, nitro group, CrC3-alkoxy group, having 1 to 7 fluorine, chlorine and/or > C1-C3-halo-alkoxy of the odor atom or represents -C(R4)di-N-OR5, R2 represents hydrogen, i, crc6-alkyl, crc6-haloalkyl, cyano'颂The base 'C1-C3-alkoxy' or a crc3-haloalkoxy group having 1 to 7 fluorine and/or bromine atoms, R4 represents hydrogen or a fluorenyl group, and R5 represents a CrC5-alkyl group, CrC5 An alkenyl group or a CrC5-alkynyl group, and at least one active compound selected from the following class (26): Group (26) of the formula (XVIID alkyl carboxy guanamine) -175- R represents hydrogen or fluorine, and r61 represents hydrogen, halogen, CrC3.alkyl or a C1-C3- yl group having 1 to 7 fluorine, gas and/or a desert atom. A' represents one of the following A'l to A, 8 bases 200814928 R represents Ci_C3~alkyl, 63 R represents hydrogen, halogen, crc3-alkyl or has 1 to 7 fluorine, chlorine and/or bromine atom crcr haloalkyl, R64 represents hydrogen, halogen orcrcr alkyl , R6 represents halogen, CrC3-alkyl or has 1 to 7 fluorine, chlorine and/or a Ci-CV haloalkyl group, R66 represents hydrogen, halogen or crc3-alkyl, amine, mono- or Di(cr(V alkyl)amino group, 67 R represents hydrogen 'halogen, CrCV, or a crcr haloalkyl group having 1 to 7 fluorine, chlorine and/or bromine atoms, R represents halogen, Ci-Cr An alkyl group or a crc3-haloalkyl group having 1 to 7 fluorine, chlorine and/or bromine atoms, R represents a halogen, a Ci-C^alkyl group or a fluorine, chlorine and/or bromine atom having 1 to 7 Crc3-haloalkyl, -176- 200814928 3. 10 15 guanamine 'wherein R represents hydrogen or fluorine r7 〇 > vv . ^ represents gas, self-priming, crc3-alkyl or CrC" group having i chlorine and/or a desert atom. The composition of the active compound of the first or the second of the seventh or the second of the formula (1) of the formula (1) of the winding R represents fluorine, chlorine 'bromine, iodine 'fluorenyl' Ethyl, n-propyl, isopropyl, trifluoromethyl, trimethyl decyl, cyano, methoxy, /ethoxy, n-propenyl, isopropoxy, trifluoromethoxy; i methoxy or represents -C(R4)=N-OR5, R represents hydrogen, fluorine, chlorine, bromine, iodine, decyl, ethyl, n-propyl, isopropyl, trifluoromethyl, tri Chloromethyl, cyano, methoxyethoxy, n-propoxy, isopropoxy, trifluoromethoxy or trichloromethoxy, r4 represents hydrogen or methyl, R represents Ci-C5-burn base. 4. The active compound composition according to claim 1, wherein the active compounds of the (2) to (25) are selected from the group consisting of: (2-1) azoxystrobin, (2- 2) Fluoxastrobin, 〇3) (2-5)-2·(2-{[6-(3-Vinylmethylphenoxy)-5·fluoro-4-pyrimidinyl]oxy} Phenyl)-2-(methoxyimino)-#-methylacetamide, (2-4) trifloxystrobin, (2-5) (25)-2-(oxygen) Amidino-based fluorenyl 2-(2-{[({(1)>1-[3_(trifluoromethyl)phenyl]ethylenediyl}amino)oxy)indolyl}phenyl) Indoleamine, (2·6) -177- 20 (2£>2-(methoxyimino) U-based_2_{2-[(£>({1-[3-(trifluoromethyl) (phenyl)ethoxy}imido)-methyl]phenyl}acetamidamine, (2-7) willsostazone, (2-8) 5-decyloxy-2- Methyl-4-(2-{[({(1)5)][3-(trifluoromethyl)phenyl]ethylenediyl}amino)oxy]-methyl}phenyl)-2,4- Dinitro-3//-l,2,4-dioxin-3·嗣, (2-9) kesoxim-methyl, (2-10) dimoxystrobin, (2-11) picoxystrobin, (2-12) σ galactosamine (pyraclostrobin) ' (2-13) metominostrobin, (2-14) enestrobin, (3-1) azaconazole, (3-2) itacon (aconaconazole), (3-3) propiconazole, (3-4) difenoconazole, (3-5) bromuconazole, (3-6) Cyproconazole, (3-7) hexaconazole, (3-8) penconazole, (3-9) myclobutanil, (3-10) tetraconne ( Tetraconazole), (3-11) flutriafol, (3-12) epoxiconazole, (3-13) flusilazole, (3-14) simeconazole ), (3-15) prothioconazole, (3-16) fenbuconazole, (3-17) tebuconazole, (3-18) ipuna ( Ipconazole), (3-19) metconazole, (3-20) triticonazole, (3-21) than bitertanol, (3-22) triadimenol (3_23) triadimefon, (3-24) fluquinconazole, (3-25) quinconazole, (3-26) Dichlorobuconazole-178- 200814928 (diclobutrazole), (3-27) Nikonazole (diniconazole), (3-28) Nikon Jun-m (diniconazole-m), (3-29 ) furconazole, 〇30) uniconazole, (3-M) uniconazole p, (4-1) dichlofluanid '(4-2) ) tolylfluanid, (5-1) iprovalicarb, (5-3) benthiavalicarb, (6-1) 2' gas-N-(l,l , 3-trimethylindan+yl) _ in the test of guanamine, (6-2) 克克力〇 (^&1丨(!), (6-3) blessing ratio (furametpyr), (6-4 N-(3-p-tolylthiophen-2-yl)-1-methyl10-winter trifluoromethyl °° wow _4_ rebel amine, (6-5) ethaboxam, (6-6) fenhexamid, (6-7) carpropamid, (6-8) 2-chloro-4-(2-fluoro-2-methylpropanylamino) -N,N-dimethylbenzamide, (6_9) fliopicolide, (6-10) zoxainide, (6-11) 3,4- 15 dichloride Cyanophenyl)isoxime, (6-12) card insurance (carboxin) (6-13) thiadinil, (6-14) penthiopyrad, (6-15) thiathicillin (siithi〇fam), (6-16) 1[2-( 1,3-Dimethylbutyl)phenyl]indenyl_4-(trifluoromethyl)-1仏0 to slightly 3-carboxychiral amine '(6-17) fordone (flut〇ianii) ), (6-18) Fenfu 20 South (fenfuram) '(6-19) OXyCarb〇xin, (6-20) thifluzamide, (6-21) Ν·{2 -[3-chloro-5-(trifluoromethyl) 0-bito]ethyl}-2_(trifluoromethyl)benzamide, (6-22) Ν·(2-bicyclopropyl-2- Phenyl) small methyl winter trifluoromethyl 1 Η pyrazole _4 carboxy carbamide, (6-23) Ν-(2-bicyclopropyl -2-phenylene) small methyl difluoro- 179 - 200814928 Mercapto-1H-pyrazole-4-carboxamide, (6-24) Ν-[2-(Γ-methylbicyclopropyl-2-yl)phenyl]indolyl·3·3 Fluoromethyl -4-meramine, (6-25) Ν-[2-(Γ-methylbicyclopropyl-2-yl)phenyl]-1-methyl-3-difluoromethyl- 1Η-pyrazole carbaryl amide, (6-26) Ν-[1·(5-bromo-3-chloropyridine 5 -2-yl)ethyl]-2,4-dichloronicotinium amide, ( 6-27) Ν-(5-bromochloroacridin-2-yl)methyl-2,4-di-nicotinamide (7-1) Yan Mannapu (mancozeb), (7-2) Manganese (maneb), (7-3) free of _ (metiram), (7-4) methyl zinc ispo (propineb) (7-5) thiram ' (7-6) 乃奈浦 (zineb), (7-7) ziram, 10 (8-1) benalaxyl'8 -2) Fura (furalaxyl), (8·3) Ganda (11^&1&\>4), (8-4) Gendari-]\4, (8-5) Dale-]\4, (9-1) cyprodinil, (9-2) mepanipyrim, (9-3) pyrimethanil, (10-1) 6-Gapent-5-[(3,5-dimethylisoxan-4-yl) sulphate]-2,2-difluorois -5H-[1,3] dioxin and [4,5 -f>benzimidazole, (10-2) free (benomyl), (10-3) carbendazim, (10-4) chlorfenazole, ( 10-5) Fuberidazole, (10-6) thiabendazole, (11-1) dithiofene (diethofencarb), (11-2) propamocarb, (11·3) HCl Propamocarb-hydrochloride, (11-4) propamocarb-fosetyl, (12-1) tetrahydropalm (captafol), (12 -2) Captan, (12-3) Folpet, (12-4) iprodione, (12_5) procymidone, (12-6) Ning (vinclozolin), (13-1) dodine, (13-2) gram heat net-180 - 200814928 (guazatine) '(13-3) bisinoctyl triacetate (iminoctadine triacetate) '( 13-4) gram heat net (burning phenoflavin) [iminoctadine tris (albesilate)], (13·5) linine (dodine (free base)), (13-6) gram heat (immoctadine) ( Free base), (14·1) cyazofamid, (14-2) prochloraz, (14-3) triazoxide, (14_4) rice mark g (pefurazoate) , (15,1) adimorph, (15-2) tridemorph, (15-3) dodemorph, (15-4) fenpropimorph _ (fenpropimorph ) '(15-5) dimethomorph, (16,1) ίο fenpiclonil, (16-2) fludioxonil, (16-3) 吼洛尼精(pyrrolnitrin), (17-1) foss-aluminum (fosetyl-Al), (17-2) phosphonic acid, (17-3) fluorenylphosphorus (tolclophos-m Ethyl),(18-1) 2-(2,3-dihydro-1H-indol-5-yl)-N-[2-(3,4-dimethoxyphenyl)ethyl]-2-( Methoxyimino) is acetamide, (18-2) Ν-[2-(3,4-dimethoxyphenyl)ethyl]-2-(decyloxyimido)-2 -(5,6,7,8-tetrazole-n-2-yl)ethinamide, (18-3)2-(4· ® gas phenyl)-Ν·[2-(3,4-di曱oxyphenyl)ethyl]-2-(methoxyimino)-acetamide, (18-4) 2-(4-bromophenyl)-:^[2-(3,4- Dimethoxyphenyl)ethyl]-2-(methoxyimino)-acetamide, (18-5) 2-(4-methylphenyl 2 fluorenyl)-N-[2-( 3,4-Dimethoxyphenyl)ethyl]-2-(decyloxyimino)-acetamide, (18-6) 2-(4·ethylphenyl)-indole-[2 -(3,4·didecyloxy)ethyl]-2-(decyloxyimido)-acetamide, (19-1) benzothiazolidine (acibenzolar-S-methyl) , (19-2) chlorothalonil, (19-3) cymoxanil, (19-4) edifenphos, (19-5) 凡-181- 200814928 杀同 (famoxadone ), (19_6) voltazinam, (19·7) copper oxychloride, (19-9) oxadixyl, (19-10) spirocycline (spirox Amine), (19-11) dithianon, (19_12) metrafenone, 5 (19-13) fenamidone, (19-14) 2,3- Dibutyl-6-oxythieno[2,3-d]pyrimidin-4(3H)-one, (19-15) probenazole, (19-16) isofoliioliane, (19 -17), kasugamycin, (19-18) phthalide, (19-19) ferimzone, (19-20) three races ίο (tricyclazole) '(19-21) Ν-({4-[(cyclopropylamino)carbonyl)phenyl}sulfonyl)-2-decyloxybenzamine, (19-22) 2-(4- Chlorophenyl)-N- {2-[3-decyloxy-4-(prop-2-yn-1-yloxy)phenyl]ethyl 2-(prop-2-yn-1-yloxy) Ethylamine, (19-23) quinoxyfen '(20-1) pencycuron, (20-2) methyl is-thiophanate-methyl, (20-3) Ethyl-polyphanate-ethyl, (21-1) fenoxanil, (21-2) ® diclocymet, (22-1) 5-chloro-ΛΗΓ7Θ· 2,2,2-trifluoro-1-methylethyl>6-(2,4,6-trifluorophenyl)[1,2,4]triazolo[l,5-a]pyrimidine- 7-amine (22-2) 5-Chloro-D-dimethylpropan-2-yl]-6-(2,4,6-trifluorophenyl)[1,2,4]triazolo[l,5-a] Pyrimidine-7-amine, (22-3) 5-chloro-6-(2-chloro-6.fluorophenyl)-7-(4-mercaptohexanitrogen-pyridin-1-yl)[1, 2,4]triazolo[l,5-a]-pyrimidine, (22-4) 5-chloro-6-(2,4,6-trifluorophenyl)-7-(4-methylhexahydro Acridine small group) [1,2,4]triazolo[l,5-a]pyrimidine '(23-1) 2-butoxy-6-moth-3-propylbenzo-1 -4--4-S, (23-2) -182- 200814928 Ethoxy-6-iodo-3-propylbenzopyran-4-one, (23_3) 6-iodo-2-propoxy- 3-propylbenzopyran-4-one, (23-4) 2-but-2-ynyloxy-6-iodo-3-propylbenzopyrone, (23-5) 6-iodine -2-(1-methylbutoxy)-3-propylbenzopyran-4-one, (23-6) 2·but-3-enyloxy-6-iodobenzopyranone ,(23-7) 3-butyl-6-iodo-2-isopropoxybenzopyrone, (24_1)% (3',4'-dichloro_5-fluoro-1,1,- Biphenyl group; each) (difluoromethyl) small methyl-lif-11 than saliva-4-carboxylic acid amine, (24-2) #-(4,-bromo-1, fluorene-biphenyl- 2-yl)-4-(difluoromethyl)-2-methyl-1,3-indolyl-5-sulfanylamine, (24-3) 4-(difluorofluorenyl) Winter methyl-[4,-(trifluoromethyl)-1, fluorenyl-biphenyl-2-yl]-1,3-aluminum-5-carboxamide, (24-4) dichloride Phenylmethylene)-5-fluoro-1,3-dimethyl-lif"pyrazole Icarboxamide, (24-5) ΛΚ4,-chloro-3,-fluoro-1,1,-biphenyl -2-yl)-2-mercapto-4-(trifluoromethyl)-1,3-thiazole-5-carboxamide, (24_6) (4,-chloro•l,lf-biphenyl- 2-yl)-4-(difluoromethyl)-2-methyl-1,3-σ stopper -5-hydrazide, (25-1) #-[2-(1,3-dimethyl Butyl)phenyl]-1,3-dimethyl-1//-pyrazole-4-carboxamide, (25-2) 7V-{2-(l,3-didecylbutyl) Phenyl}-5-fluoro-1,3-dimethyl-1/f-pyrazole-4-carboxamide, (25-3) 1[2-(1,3-didecylbutyl)benzene 5-[Chloro-1,3-dimethylbizozol-4-reactive amine '(25-4)3-(difluoromethyl)-7V~[2-(l,3-dimethyl Butyl) phenyl]-1_methyl-1-leprazole-4-carboxamide, (25-5) 3-(trifluoromethyl)-indole 42-(1,3-dimethylbutyl) Phenyl]-5-fluoro-1-methylpyrazole-4-carboxamide, (25-6)3-(trifluoromethyl)-indole 42-(1,3-dimethylbutyl)phenyl ]-5-chloro-1-methyl-1 ugidazole carbamide, (25-7) 1,3-dimethyl-Λ42-(1,3,3-three Phenyl]-1 仏 比 比 -4- -4- 醯 醯 醯 ,, (25-8) -183- 200814928 5-fluoro-1,3-indolyl-iV-[2 (1,3,3- Trimethyl butyl)phenyl]-1 π pi-salt-4-carboxamide, (25-9) 3-(difluoromethyl)small methyl- Λ42·(1,3,3-trimethyl Butyl)phenyl]-17^bazole-4-carboxamide, (25-10) 3-(trifluorof-decyl-methyl 1-[2-(1,3,3-trimethyl) Butyl)phenyl]-1//-, azole _4_ 5 carboxamide, (25-11) 3-(trifluoromethyl) fluoro-1-methyl j-[2-(l,3 , 3, tridecyl butyl) phenyl] oxazole-4-carboxy decylamine, (25-12) 3-(trifluoromethyl)-5 qi-1-methyl good [2-(1, 3,3-trimethylbutyl)phenyl>1//, pyrazole-4-carboxamide, (25-13) 7V-[2-(l,3-(didecylbutyl)) Stupid)-2-iodobenzamine, (25-14) 2-硖-Λ/42-(1,3,3-trimethylbutanyl)phenyl]benzamide, (25- 15) Ν-{2-(1,3-dimethylbutyl) phenyl}-2-(trifluoromethyl)benzamide, (25-16) 2-(trifluoromethyl)-indole 42 -(1,3,3-tridecylbutyl)phenyl]benzamide. 5. The active compound composition according to claim 2, wherein the active compound of the (26) class is selected from the group consisting of: 15 (26-1) 5-fluoro-1,3-dimethyl-anthracene Butyl)phenyl]pyrazole-4-carboxamide, (26·2) 3-(difluoromethyl)-indole 42-(3,3-dimethylbutanyl)·4-fluorophenyl ]-1-methyl-ΐπ. Biazole-4-carboxyguanamine, (26-3) 3-(difluoroindolyl)-indole 42-(3,3-dimethylbutyl)phenyl]-1-methylpyrazole-4-carboxylate Indoleamine, (26-4) 豕[2-(3> Dimercaptobutyl)phenyl]-2-(trifluoro-2-indenyl)benzamide, (26-5) iV-[2- (3,3-Dimethylbutyl)-4-fluorophenyl]-2-methyl-4-(trifluoromethyl)-1,3-thiazole-5-carboxamide, (26-6) iV-[2-(3,3-Dimercaptobutyl)-3-indolyl porphin-2-propanolamine. The active compound composition according to any one of claims 1 to 5, wherein the biphenylcarboxamide of the formula (XVI) is different from the carboxamide of the formula (I)-184-200814928. Compound. The active compound of the invention in the scope of claims i to 6 includes a carboxamide of the formula (1) wherein the R2 group is located at the 2,-position of the distal phenyl ring of the group. One is based on the scope of the patent application! Use of the activated mouth composition of any of the seven items for controlling unwanted phytopathogenic fungi. 10 10- 11 12· 15 13. 20 14· The use of the active compound composition of any of the items in item 7 of the above-mentioned item 7 for the treatment of seeds. A use of an active compound composition according to any one of the claims of claim 1 17 for the treatment of a transgenic plant. The use of the active compound composition of any of the patents, item m, for the treatment of seeds of a transgenic plant. A seed treated with an active compound composition according to item (4) (4) to item 7. : A method for controlling unwanted phytopathogenic fungi, characterized by activity according to any one of items 1 to 7 of the patent application scope ==: unwanted pathogenic fungi and or oysters thereof The method for preparing the smear of the smear 8 is characterized in that the root of the active compound group of any one of the first to seventh aspects of the patent of the invention is mixed with a stretching agent and/or a surfactant. The active compound composition according to any one of the claims 185- 15.200814928 is applied to the seed in the form of an active compound against any of the phytopathogenic fungi which is not desired. 4 200814928 VII. Designation of representative representatives: (1) The representative representative of the case is: (No). (2) A brief description of the symbol of the representative figure: 8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: (I)