TW200535229A - Systems and methods of producing a crude product - Google Patents

Abstract

Contact of a crude feed with one or more catalysts produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The crude product is a liquid mixture at 25 DEG C and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed. In some embodiments, gas is produced during contact with one or more catalysts and the crude feed.

Description

200535229 IX. Description of the invention: [Technical field to which the invention belongs] The present invention generally relates to a system and a method for processing a crude oil feed, and a composition prepared by, for example, a feedstock system and method. In more detail, the specific examples described herein relate to the conversion of a crude oil feed with a residual content of at least 0-2 grams of residue per gram of crude oil to 25%. . The system below is a liquid mixture and has one or more systems and methods of crude oil products that have improved properties compared to the same properties of the crude oil feed. [Prior art] The inability to transport crude oil economically 'is often referred to as, crude oil with one or more inappropriate properties or processed crude oil (disadvantaged crudes) using traditional facilities. Inferior crude oil often contains relatively high levels of residue. Such crude oils are often difficult and expensive to transport and / or process using traditional facilities. High-residue crude oil can be converted to coke after high temperature treatment. Alternatively, high-residue crude oils are typically treated with water at high temperatures to produce less viscous crude oils and / or crude oil mixtures. During processing, it may be difficult to remove water from the less viscous crude oil and / or crude oil mixture using conventional means. Inferior crude oil may contain hydrogen-depleted hydrocarbons (hydrogen deficient hydrobacarbs). When processing depleted hydrocarbons, it is often necessary to add a consistent amount of hydrogen, especially if there are unsaturated fragments due to the cracking process. Hydrogenation during processing usually involves the use of active hydrogenation catalysts, and it may be necessary to suppress the formation of coke from unsaturated fragments. The production and / or transportation of hydrogen to processing facilities is expensive. 200535229 Anxiety ~ τ is formed and / or deposited on the catalyst surface at a rapid rate during the processing of inferior crude oil. The catalyst activity to regenerate catalysts contaminated with coke can be expensive. The high temperatures used during regeneration may also weaken the catalyst's activity and / or degrade the catalyst. Inferior crude oil may contain acidic components that contribute to the total acid number ("TAN") of the crude feed. Inferior crude oils with relatively high TAN can cause corrosion of metal components during transportation and / or processing of inferior crude oils. Removal of acidic components from inferior crude oil may include chemically neutralizing acidic components with various bases. Alternatively, anticorrosive button metal can be used in transportation equipment and / or processing equipment. The use of anticorrosive surname metals usually involves considerable costs, and for this reason, the use of anticorrosive metals in existing equipment may not be desirable. Another method of inhibiting rot may involve adding corrosion inhibitors to inferior crudes prior to transportation and / or processing of inferior crudes. The use of rotting preparations may negatively affect the quality of the equipment and / or products made from the crude oil. w Inferior crude oils can contain relatively high amounts of metal contaminants such as nickel, vanadium and / or iron. During the processing of such crude oil, metal contaminants and old compounds may be deposited on the surface of the catalyst or the void volume of the catalyst. Such deposits can cause low catalyst activity. Inferior crude oils often contain organically bonded heteroatoms (eg sulfur, milk). Organic-bonded heteroatoms may be counterproductive to the catalyst in some cases ^ metal salts and / or soil metal salts have been used in the desulfurization of residues. These procedures can easily lead to bad delithicity, produce insoluble oil, poor metal removal efficiency, formation of salts, oils, theta compounds that are essentially inseparable, use of large amounts of gas and / or Quite high chlorine pressure. ^ 200535229 Some methods to improve the quality of crude oil include adding diluents to inferior crude oils to reduce the weight percentage of ingredients that cause inferior properties. However, adding diluents often increases the cost of processing inferior crudes because of the cost of diluents and / or the cost of managing inferior crudes. Adding diluents to inferior crudes can in some cases reduce the stability of such crudes. The following US patent cases: 3,136,714 to Gibson et al; 3,558,747 to Gleim et al; 3,847,797 to pasternak et al; 3,948,759 to King et al; 3,957,620 to pukui et al; and McCollum et al 3,960,706 for people; 3,960,708 for McCollum and others; 4,1 19,5 28 for Baird, Jr. and others; 4,127,470 to Baird, Jr. and others; 4,224, for Fujimori and others, 140; 4,437,980 to Heredy et al .; to

4,591,426 to Krasuk et al .; 4,665,261 to Mazurek; 5,064,523 to Kretschmar et al .; 5,166,118 to Kretschmar et al .; 5,288,681 to Gatsis; 6,547,957 to sudhakar et al .; and US Patent application publication number: 20030000867 to Reynoids and 20030149317 to Rendina, describing various methods and systems for processing crude oil. However, the methods, systems, and contacts summarized in these patent cases have limited applicability due to the many technical issues mentioned above. In short, inferior crude oils generally have undesired properties (for example: considerable residues, tendency to corrode equipment, and / or tendency to consume a significant amount of hydrogen during processing). Other undesirable properties include a relatively high amount of unwanted knives (for example, a relatively high amount of TAN, organic-bonded heteroatoms, and / or gold 200535229). This type of property is problematic, including increased hydrogen use during the period of specialized transportation and / or processing. Therefore, the H catalyst has a longer life and / or has a more rational-property in processing ...: It has obvious experience in improving systems, methods, and / or catalysts used to convert inferior crude oils into well-known L:,:. Technical needs. [Summary of the invention;] The invention described in this article plus multi-box bunks ... This month is generally about contacting the crude oil feed with one or more catalysts to produce a crude oil product containing 1-3 crude oil products and in some specific examples Zhonghuan 0〇_ 0 system, charge and method 0 The hair month described in this article is also generalized about the composition in which the ancients can be combined with the ingredients. Such groups are obtained by using the systems and methods described herein. The invention provides a method for preparing a crude oil product by contacting a lacquer feed with a chlorine source in the presence of-$ multi H Λ, which includes contacting crude oil with a catalyst, to produce a crude product, in which one or more of the catalysts are packaged. Shi Yuxi dagger 3 3 has K3Fei〇SM catalyst. This month also provides a method for making crude oil products. Crude oil feed, Qi, original buckets, and eight daggers are contacted in the presence of one or more catalysts. To produce a finished product containing a crude oil product, the crude product in the eighth middle contains at least one of 25 ° c and 〇1〇1 ::::: mixture 'catalyst including-or multiple transitions, and The shai crude oil feed has a content of at least 0.2 grams per gram of crude oil feed. Check the contact conditions as measured by ASTM method 05307, so that the crude oil product contains at most _ coke per gram of crude oil product, A crude oil product contains at least 100,000 grams of light oil per gram of crude oil product, and the light oil has an octane number of at least 70. The present invention also provides a method for preparing a crude oil product, comprising: making a 200535229 crude oil feed and The hydrogen source is contacted in the presence of-or multiple catalysts. The whole product is straight ^^ ^ 3 MPa is the liquid feedstock g crude oil product at 25 ° C with 0 · 硫化 metal sulfide, and the V includes one or more transition households, 杳 feed has per gram of crude oil feed The content of residues at least 02 grams should be checked, as determined by the method of contacting M ™ method D5307; and the control of the crude oil product contains kerosene, which is 2 per gram of kerosene ::: = Compounds, ... Method 1) Freezing point at 23 ° C, 0 ° C, as measured by As ™, and the crude product is 1 gram of crude oil up to 0.05 gram of coke. 物 3 有 、 The present invention also provides a manufacturing A method of a crude product comprising contacting a crude feed with a hydrogen source in the presence of one or more catalysts 'to produce a complete product comprising a crude product, wherein the crude product is a liquid mixture at 25 ° C and 0 T' At least one of the catalysts contains one or more transition metal sulfides, and the crude oil feed has a residue content of at least 0.2 grams of residue per gram of crude oil feed; and controlling the contact conditions such that the crude oil product contains Up to 0.05 g of coke, of which crude oil product The weight ratio of atomic chlorine to atomic carbon is at most i.75, as measured by ASTM method D6730. The present invention also provides a method for manufacturing a crude oil product, comprising: making a crude oil feed and a hydrogen source at one or more catalysts Contacting in the presence to produce a complete product comprising a crude product, wherein the crude product is a liquid mixture at 25 and 0.11 Mpa, at least one of the catalysts contains one or more transition metal sulfides, and the crude oil is The feed has a residual content of at least 0.2 g 200535229 per gram of crude oil feed, as determined by ASTM method D5307, and the original weight ratio of atomic hydrogen to atomic carbon (H / C) in the feed is at least! 5 and controlling the contact conditions so that the crude oil product has an atomic H / c ratio of 80-12% of the atomic H / C ratio of the crude oil feed, and the crude oil product has a content of at most 30% of the residue content of the crude oil feed Residue content, as determined by the AStm method DUO®, crude oil products contain at least 0.001 grams of light oil 'per gram of crude oil product, and the light oil has an octane number of at least 70. The present invention also provides a method for manufacturing a crude oil product, comprising: contacting a crude oil feed with a hydrogen source in the presence of one or more catalysts to produce a complete product comprising a crude oil product, wherein the crude oil product is present.匸 and ^ ⑴ _a are liquid mixtures, at least one of the catalysts contains one or more transition metal sulfides, and the crude oil feed has a residual content of at least 0.2 grams per gram of crude oil feed, such as U ASTM & D530.7 household weight tester; and control the contact conditions so that the crude oil product per gram of crude oil product contains: at least Shek's light oil 'the light oil has a smoldering value of at least 7G; at least Guker's kerosene' Far kerosene contains aromatic compounds' The kerosene system contains at least 0.2 grams of aromatic compounds per gram of kerosene, as determined by the ASTM method, and the kerosene has at most · 30. . The freezing point of temperature, as measured by "Asm method D2386; at least 0.001 g of vacuum gas oil (0)", the VG0 series contains at least 0.3 grams of aromatic compounds per gram of VG0, as in IP method 368 / 90 Measured · π Μ

′ And the residue of 0.05 g, as measured by ASTM method D5307. This month also provides a method for manufacturing crude oil products, which includes: contacting a raw feed "a hydrogen source in the presence of one or more catalysts containing transition metal sulfide catalysts 10 200535229" to produce a complete product containing crude oil products Wherein, the crude oil product is a liquid mixture at 25 C and 〇1 (} 1 Mpa, and the transition catalyst compound contains a total of gram or gram of transition metal sulfide per gram of total transition metal sulfide catalyst. The crude oil is fed with a residual content of 0.2 grams of residue per gram of crude oil, as measured by the 卩 astm method D5307; and the contact conditions are controlled so that the crude oil product has at most G (3) per product. 5 grams of coke, and the crude product has a residual content of at most 30% of the residual content of the crude feed as determined by MM method D5307. The present invention also provides a method for manufacturing a crude product, including : The crude oil feed is contacted with a hydrogen source in the presence of a catalyst containing a transition metal sulfide catalyst to produce a complete product containing a crude oil product. The crude product in 1 is at 25 ° C and 0.11. Liquid under Mpa The transition metal sulfide catalyst contains at least 0.4 grams of one or more transition metal sulfides per gram of total transition metal sulfide catalyst, and the crude oil is fed with at least 0.001 per gram of crude oil feed. Nitrogen content of grams of nitrogen, and the crude oil is fed with: gram crude oil: the residual content of at least 0.2 domain slag; and control of contact elements so that the crude oil product has at most the nitrogen content of the crude oil feed Nitrogen content, and the crude product has a residue content of at most 30% of the crude feed feed residue content, where the nitrogen content is as measured in M, & d times and the residue content is as measured by ASTM method DM. The tester. The present invention also provides a method for manufacturing a crude oil product, comprising contacting a crude oil feed with a hydrogen source in the presence of-or a plurality of catalysts including a transition metal sulfide catalyst to produce a crude oil product. Complete product, in which the 11 200535229 crude oil product is a liquid mixture at 25 C and 010 MPa, and the transition metal catalyst system contains a total of ^ g or xg of the total transition metal sulfide catalyst per gram. Transition metal The crude oil feed has a total content of Ni / V / Fe per gram of crude oil feed to 10,000 grams, and the crude oil feed has at least Q_ amount per gram of crude oil feed; and controlling the contact conditions such that The crude oil product contains up to 0.05 grams of coke per gram of crude oil. The crude oil product has a total Ni / v / Fe content of at most 90% of the crude feed / V / Fe content, and the crude product has at most Residue content of 30% of the crude oil feed residue content, where the = i / v / Fe content is as measured by ASTM method 05863, and the residual content is as measured by ASTM method D5307. The present invention is also Provide a method for manufacturing a crude oil product, comprising: contacting a crude oil feed with a chlorine source in the presence of—or a plurality of catalysts including a transition metal sulfide catalyst—to shear & The complete product, wherein the original: the product is a liquid mixture at 25 C and 0 · 101 Mpa, the transition metal sulfide catalyst contains a total of at least 0.4 grams per gram of total transition metal sulfide catalyst-or more Transition metal sulfide, the crude oil feed has 〇〇〇1 coupon six K heart containing ϊ, and the crude feed has at least 0.2 grams of residue of the parent gram of crude feed, 杳 person said, containing $, and control of the contact ', so that the crude oil product has at most The sulfur content of the sulfur content of the crude oil feed, and the crude oil product has a residue content of at most 5% of the residual content of the crude oil feed, wherein the sulfur content is as measured by ASTM method D4294. 'The residue content is as measured by the AS ™ method d53G7. The invention also provides a 200535229 method for manufacturing a transition metal sulfide catalyst composition, which includes: mixing a transition metal oxide with a metal salt to form a transition metal oxide / metal salt mixture; and making the transition metal oxide / The metal salt mixture reacts with hydrogen to form an intermediate; and the intermediate is reacted with sulfur in the presence of one or more smoke to produce a transition metal sulfide catalyst. The present invention also provides a method for manufacturing a crude oil product, comprising: contacting a crude oil feed with a chlorine source in the presence of one or more catalysts including a transition metal sulfide catalyst to produce a complete product including a crude oil product, wherein the The crude oil product is a liquid mixture at 25 QC and 〇ιιι Mpa, the transition metal sulfide catalyst contains transition metal sulfide, the crude oil feed has a residue content of at least 0.2 grams of residue per gram of crude oil feed, As determined by the astm method D5307; control the contact conditions so that the crude oil product has a residue content of at most 30% of the content of the crude oil feed residue; and wherein the transition metal sulfide catalyst system is obtained as follows: the transition metal oxide With metal salts this. To form a transition metal oxide / metal salt mixture; reacting the transition metal oxide / metal salt mixture with hydrogen to form an intermediate; and reacting the intermediate with sulfur in the presence of one or more hydrocarbons to produce a transition Metal sulfide catalyst. The present invention also provides a method for manufacturing a crude oil product, comprising: contacting a crude oil feed with a hydrogen source in the presence of one or more catalysts to produce a complete product comprising the crude oil product, wherein the crude oil product is at 25 and 0.1 〇1 Mpa is a liquid mixture, and the crude oil feed contains at least 0.2 grams of residue per gram of crude oil feed, as determined by ASTM method D5307; at least the complete product of the trowel is made into a vapor; 25 and 〇01〇1 Mpa cooled 13 200535229 condensed at least a part of this vapor; and forming a crude oil product, wherein the crude oil product is per gram of crude oil product containing: at least 0.001 grams of light oil ;; light oil has at least A scorch value of 70; at least 0.001 grams of VG0, which vg〇 contains at least 0.3 grams of aromatic compounds per gram of VGO, as determined by ιρ * 368/90; and up to 0.05 grams of residue, As determined by Dinghe method D53〇7. The invention also provides a method for manufacturing a crude oil product, which comprises contacting a crude oil feed with a source of radon in the presence of an inorganic salt catalyst to produce a complete product comprising a crude oil product, wherein the crude oil feed has at least one gram of crude oil feed 0.2 g of residue content, as determined by ASTM method D5307, the crude product is a liquid mixture at 25 ° C and 0. 101 Mpa, and the crude product contains at least 0 per gram of crude product. 〇〇 丨 gram of light oil, this light oil is at least 0.001 grams of monocyclic ring aromatic compounds per gram of light oil, as determined by ASTM method D6730; at least 0.001 grams of distillate ; And up to 0.05 g of residue, as determined by ASTM method d5307. The present invention also provides a method for manufacturing a crude oil product, comprising: contacting a crude oil feed with a hydrogen source in the presence of an inorganic salt catalyst to produce a complete product comprising a crude oil product, wherein the crude oil feed has a crude oil feed per gram of crude oil feed The residue content of at least 0.2 grams of residue, as determined by ASTM method D5307, is 25% for this crude product. (: It is a liquid mixture with 0 · ΐ〇ΐ Mpa, and the crude oil product contains at least 0.001 grams of diesel oil per gram of crude oil product, and the diesel oil contains at least 0.3 grams of aromatic compounds per gram of diesel oil, such as Measured by the method 368/90; at least 0.001 g of vg0, and the VG0 line 14 200535229 mother gram VGO contains at least 0.3 g of aromatic compound; and up to 0.05 g of residue, As determined by two: Qing. To D5307 The present invention also provides a method for manufacturing crude oil products. The crude oil feed and hydrogen source are present in an inorganic salt catalyst: including: making the complete product of the oil product, wherein the crude oil product is in 25 .: Shangcong contains the original: is a liquid mixture, the crude oil feed has a residue content of two Mpa grams of residue per gram of crude oil, such as a single crude oil feed of at least as much as 07 in ASTM method ... The content of the aromatic compounds in the formula ring; and the control of the content of the formula compounds in the formula; and the control during the contact period of up to 0.02 grams per gram of crude oil feed in 25 dishes.

Mpa & non-condensable hydrocarbon formation, such as mass balance ㈣ at least 5 feed single ring ::: aromatic ::. The content of the early-ring cyclic aromatic compound of 3 $, in which the content of the single compound is determined by ASTM method D6730. " Yili The present invention also provides a method for manufacturing a crude oil product, which includes the following: contacting a gas source in the absence of a catalyst, and including the original: complete product, wherein the crude product is in M The crude oil feed has a residual content of at least M grams of residual edge per gram of crude oil feed, as determined by AS ™ method D5307, and the: oil feed has grams of olefins per gram of crude oil feed The olefin content indicated and the contact strip # are controlled so that the crude oil product has an olefin content that is greater than: the olefin content of the oil feed, wherein the olefin content is as determined by AS, method D6730. 15 200535229 The present invention also provides- A method for manufacturing a crude oil product, comprising: contacting a crude oil feed with a hydrogen source in the presence of an inorganic salt catalyst to produce a complete product containing the crude oil product, and the middle section of the crude oil product is produced at a temperature of 25 ° C. It is a liquid mixture with O.ioi Mpa. The crude oil feed has a residue content of at least 0.2 grams of residue per gram of crude oil feed, and the inorganic salt catalyst exhibits an exhaust gas in a temperature range between 1C disk · 0C Exhaust gas Breakpoints, as determined by product temporal analysis (Temporal __ 〇f pr0ducts, τΑρ); and controlling the contact conditions so that the crude product has a residual content of at most 30% of the residual content of the crude feed, It is expressed as the number of residues per gram of crude oil product> the number of Chucks, in which the recording, the Xingrendan Mojiahan / Chacong is as measured by ASTM method D5307. The present invention also provides a method for producing a crude oil product, which comprises: contacting a crude oil feed with a lice source in the presence of an inorganic salt catalyst to produce a το king product comprising the original product, wherein the crude oil product is at 25. . It is a liquid mixture at 〇1 Mpa. The crude oil feed has at least 0.2 H 3 in each gram of crude oil feed. The '4 inorganic salt catalyst contains at least two inorganic metal salts' and the inorganic salt catalyst exhibits a temperature The exhaust gas turning point of the exhaust gas in the range, as measured by the instantaneous product fraction # (τΑρ), has a small gas month and the turning point / degree range is between the DSC temperature of the two inorganic metal salts and ⑻The inorganic salt catalyst㈣ and the contact conditions, so that the crude oil product has a residual content of at most 30% of the crude oil feed: slag content t 30%, which is indicated by the residual residue per gram of crude oil product, medium residual The water content is as measured by ASTM method D5307. The present invention also provides a method for manufacturing a crude oil product, which comprises: making a complete product of 16 200535229 crude oil feed and a hydrogen source in an inorganic salt catalyst to store the oil product, ... [two: contacting 'to manufacture a raw material containing tantan The crude oil product, the right M, and the human 1 cut at 25 c and 0.101 Mpa are liquid materials. The crude oil feed is., ^, And the mother gram crude oil feed is at least 0 2 grams of residue. Content, such as ASTM method ~ inorganic salt catalyst exhibited at 50% fish determination, and the exhaust gas inflection point, the scheduler in the temperature range between… and the production of Γ instantaneous score (TAP ) The tester, as well as the crude oil product, made the eagle eagle. The volume of the crude oil product obtained from the measurement of 0 ° C and 0-101 MPa was used to measure the volume of the crude oil product. The present invention also provides a method for making a crude oil product, which is a complete product of a crude oil feed and a hydrogen source in an inorganic salt oil product, wherein :: = contact: / Product at 25 ° C and 0.101 Mpa / The crude oil feed has a residue content of at least 0.2 grams of residue per gram of crude oil feed, and the exhaust gas in the temperature range between the helmet γ shows at 50 ° c and 500 Instantaneous eight ... ΛP, the turning point of the exhaust gas, as measured by the product in Mid-Autumn, China, Japan, Japan, and Japan, and the control of the contact conditions, so that each gram of crude oil feed during the contact & 0.2 g at 25. (: Formed with 0.101 Mpa non-condensable hydrocarbons, as measured by mass balance. = Meming also provides a method for manufacturing crude oil products, which includes: making materials; f source in the presence of inorganic salt catalyst Contact to make the original: King product 'where the crude product is mixed with 0 · 101 Mpa at 25 ° C. The crude feed has at least 0.2 per gram of crude feed. And 4 inorganic salt catalysts have The thermal transitions around 200 ° and 500 fox degrees in the reservoir, as determined by differential scanning calorimetry 17 200535229 (DSC) at a rate of 1G% per minute, and controlling the contact conditions so that crude oil Residual content with a cut% of at most the residue content of the crude feed is expressed in grams of residuals per gram of crude product, where the residual content is as determined by ASTM method D5307. &Quot;

This month, a method for manufacturing a crude oil product is also provided, which comprises: contacting a crude oil feed with a hydrogen source in the presence of an inorganic salt catalyst to produce a complete product comprising a crude oil product, wherein the crude oil product is at 25 ° α. .ι〇 下 ΜΜ is a liquid mixture 'the crude oil feed has a residue content of at least 0.2 grams of residue per gram of crude oil feed, and the ionic conductivity of the inorganic salt catalyst to at least one of the inorganic salt in the inorganic salt catalyst Or ionic conductivity at 3,000Ci500c; and controlling the contact conditions so that crude oil production has a residue content of at most 30% of the residue content of the crude oil feed, which is based on Residual gram number of grams of crude oil product, where the residue content is as determined by ASTM method D5307. The present invention also provides a method of making ##, Αβ, " Yiyi crude oil product, which includes ...

The crude feed is contacted with a hydrogen source in the presence of an inorganic salt catalyst to produce

The complete product of the oil product, where the crude oil product is a liquid mixture at 25Υ and G.1 () 1Mpa, and the raw material is at least 0.2 grams per gram of crude feed. Residual> Check the cleanliness of the present day-the inorganic salt catalyst contains an alkali metal salt, at least the alkali metal salt in the bean-dehydration, or an alkali metal carbonate, and the alkali metal has a > , The atomic order of 11, and is & /, and at least one of an alkali metal having an atomic order of at least 11 to a metal having an atomic order greater than 11, the atomic ratio 疋 is in the range of 〇! To 10; And control the contact strain so that the crude oil product has a content of up to 30% of the crude feed residue 66 I, Tairen 0

And 歹 slag, where the residue content is determined by aSTM 18 200535229 method D 5 3 0 7. The present invention also provides a method for manufacturing a crude oil product, which comprises contacting a crude oil feed with a hydrogen source in the presence of an inorganic salt :, 'its: the crude oil feed has per gram of crude oil feed ... 2 grams = Chahanli, The inorganic salt catalyst contains alkali gold, which is small and medium, and which is a metal hydroxide in the metal salt. The alkali metal has an atomic order of at least η and an atomic order of at least 11 At least one atom of an alkali metal with an atomic order greater than u is within the dry range of a king 1 υ; at least: a part of the complete product is made into a vapor; cool at 25 ° C with 〇〇〇〇〇 The radon gas adjacent to the knife; and the formation of the crude oil product, in which the crude oil product has a residue content of 30% of the crude oil feed residue content. The present invention also provides a method for manufacturing a crude oil product, It includes: contacting a crude oil feed with a hydrogen source in the presence of an inorganic salt catalyst to produce a complete product: the crude oil feed has a feed of > 0.2 g of residue, 3 miles " meta inorganic The salt catalyst comprises an alkali metal salt, wherein at least one of the alkali metal salts Is an alkali metal hydride, and the alkali metal has at least 11 = subsequence, and the alkali metal having an atomic order of at least 11 and the alkali atomic number greater than 11 is >> an atomic ratio is between 〇 · 丨 ～ 丨 〇 Within the range of at least a portion of the complete product of T; vapour condensing 4 knives of steam at 25 cC and 0 · 101 Mpa; and forming the crude oil product, wherein the crude product ", at most, is the crude oil A residue content of 30% of the feed residue content. The present invention also provides a method for manufacturing a crude oil product, comprising: contacting a crude oil feed with a hydrogen source in the presence of an inorganic salt catalyst to produce a complete product containing the crude oil product, Wherein the crude oil product is a liquid mixture at 25 ° C and 0.101 Mpa 19 200535229, the crude oil feed has a residue content of at least gram of residue per gram of crude oil feed, and the inorganic salt catalyst contains _ or more metal test salts, one or A variety of alkaline earth metal salts or mixtures thereof, wherein one of the alkali metal salts is an alkali metal carbonate, wherein the alkali metal has an atomic order of at least 1 and control of contact conditions so that the crude oil product has at most Residue content of crude oil feed t 30%, wherein the residue content is as determined by the astm method D5307. The present invention also provides a method for manufacturing a crude oil product, comprising: contacting a crude oil feed with a hydrogen source in an inorganic salt. Contact in the presence of a medium to produce a complete product containing a crude oil product, wherein the crude oil product is a liquid mixture at 25. ^ q.⑻ ¥, and the crude oil feed has at least ⑴2 per gram of crude oil feed. 'The inorganic salt catalyst contains one or more metal test hydrides:-or multiple alkaline earth metal salts or mixtures thereof, wherein the alkali metal has an atomic order of at least Π' and the control of the contact conditions so that crude oil production does not have a hometown The residue content is 30% of the residue content of the crude oil feed, wherein the residue content is as determined by ASTM method D5307. This month, a method for manufacturing a crude oil product is also provided, which comprises: contacting a crude oil feed with a hydrogen source in the presence of an inorganic salt catalyst to produce several whole products including the original product ', wherein the crude oil product is at M. . &Quot; ΟΙ ¥ is a liquid compound. The crude oil feed has a residual content of at least 002 2 gram per gram of crude oil feed. The inorganic salt catalyst contains one or more metal test hydrogens. Having an alkaline earth metal salt or a mixture thereof, and wherein the alkali metal has an atomic sequence of at least 1 1; and controlling the contact conditions such that the crude oil production is a residue content of 30% of the crude feed residue content, which is 20 200535229 The content of the residue is, for example, based on the original gram: the residue of the product; the Chuck number means the one measured by ASTM method D5 3 07. The present invention also provides a method for producing hydrogen, which includes the following steps: bringing crude oil into contact with one or more hydrocarbons in an inorganic salt phase, and in the presence of 1 × * Chenghe water; Song has a feed in the range of 1 to 6 and a < > 忒 crude oil feed has a residue of + 0.2 gram of residue per gram of crude oil feed in a residue of 50. 〇: and 5 () ()% ”and the money machine salt catalyst exhibits the exhaust gas turning point of the exhaust gas in the revolution, such as the instantaneous analysis of the product (gas. A method for manufacturing a crude oil product, which comprises: flowing a crude oil feed with an inorganic salt catalyst in an &steam; the gas stream containing hydrogen; The feed has a residual content of at least 0.2 grams of residue per gram of first crude oil. A, ^. 1] owed / set 3 miles, such as using the ASTM method D5307 2 = inorganic salt catalyst exhibited at 50. ° Between 500% and 50%: the turning point of the exhaust gas of the dish "Θ", such as the instantaneous analysis of the product

Analysis ™); the second crude oil feed is contacted with a second catalyst H-part of the generated gas stream to produce a crude oil containing product

Complete product of 'wherein the crude oil product is between 25 Y and 0.10ϊ M liquid: a compound; and controlling the contact conditions such that the-or 2 properties of the crude oil product are compared to each of one or more of the second crude oil feed Nature,;: at least 10%. The present invention also provides a method of generating at least one gas stream per gram of crude oil feed with a feedstock and an inorganic salt catalyst, which includes contacting crude oil with steam in the presence of 0.2 g of crude oil feedstock. The residue content of the residue, as determined by Astm 200535229 method D5370; and the generation of a gas stream containing gas, carbon and carbon dioxide, and wherein -carbon oxide to carbon dioxide; the ear ratio is at least 0.3. The present invention also provides a method for manufacturing a crude oil product, which includes: organic salt catalyst; contacting a crude oil feed with a hydrogen source under the adjusted inorganic salt catalyst to produce a complete product containing crude oil products :: product ... versus. A liquid mixture at one pa, the crude oil: 枓 "at least 0.2 grams of residual content per gram of crude oil feed; and, under conditions, such that the crude oil product has at most 3 The residue content of 0% is expressed in terms of the number of grams of broken crude per gram of crude oil product. The residue content is as determined by the method of let-through method D5307. The present invention also provides a crude oil composition comprising: In the range of 0.ΗΗ MPa ^ Futten range of smoke between ⑽ 乂 and 538 Qc0, Gang. F), ❹ group contains iso-chain hydrocarbons and normal-chain hydrocarbons. The weight ratio is at most i.4 'as measured by ASTM method D673q. + The present invention also provides a crude oil composition, which contains per gram of composition: V 0.001 g at G1G1 MPa-Teng range distribution is at most 20%. Hydrocarbons at 4 ° C (400 ° F), at least 0.001 g of hydrocarbons with boiling range under MPa between 4,000 ° C and 300 ° C, at least 0.001 g · Η) The hydrocarbons with a boiling range at 1⑽a are distributed between 3c.c and · c, and at least grams are distributed throughout the boiling range (MW MPaT). Hydrocarbons between [and (1, 000F), and the boiling range of which is distributed to at most states JC Fe contains hetero-chain burned hydrocarbons and normal-chain fluorene, in which the weight of the hetero-bonded smoke to the normal chain The purchase ratio is at most 14, as determined by the astm method plus 7 children. 22 200535229 The present invention also provides a crude oil composition 5-〇〇〇1 ^--six mother brother composition contains: _ 'Emu oil' the light oil It has a maximum of 0 and 0, and the oil contains at most 0.15 grams of olefin, as measured by the AS ™ method ΓΓΓ; at least, 0.001 grams of kerosene, which is 2 to 1 per gram of coal). .2 grams of aromatic compounds, as described in ASTM method 05186, and the kerosene has a freezing point at a temperature of at most .c, as described in the first method; and difficulties in most, such as by the ASTM method Tested by D5307.

The present invention also provides a crude oil composition containing per gram of composition: up to 0.15 grams of non-condensable hydrocarbon gas at 25% and 0.1101 Mpa, and the non-condensable flue gas system contains up to 0.3 grams per W gas Carbon number to Sichuan: 3) Masonry class' at least 0.001 grams of light; therefore, the light oil has a scorch value of at least 70; at least 0.00 grams of kerosene, the kerosene has at most _300. c The freezing point of temperature, as measured by ASTM & D2386, and the kerosene-based kerosene contains at least 0.2 grams of aromatic compounds, such as by the ASTM method

6 'and a residue of at most 0.05 g, as measured by ASTM method D5307. The present invention also provides a crude oil composition containing per gram of composition: 0.05 grams of residue, as measured by ASTM method D5307, at least 0.001 grams of boiling range distribution at 0.101 MPa of at most 2 4 ° C (400 ° F) smoke; at least 0, (g) hydrocarbons with a boiling range between 204 C and 300 ° C at 0 (1) Mpa; at least 0.001 g in Hydrocarbons with a boiling range between 300 ° C and 400 cC at 10 MPa; at least 0.001 g of boiling ranges between 538 ° C (0.100 235 200535229 ° F) at 0.101 MPa Hydrocarbons in between; and in which the boiling range is between 20 and 40 ° c, the hydrocarbons in the distribution include olefins with terminal double bonds and olefins with intramolecular double bonds, of which The molar ratio of olefins to olefins with intramolecular double bonds is at least 0.4, as determined by ASTM method D673. The present invention also provides a crude oil composition, each gram of which contains: at most 0.05 grams of residue, as measured by ASTM method D5307, and at least 0.001 grams of boiling range distributed between 2000c and 53800C (1, 00. Hydrocarbon mixtures between, as determined by ASTM method D5307, and hydrocarbon mixtures contain at least 0.001 grams of paraffin hydrocarbons per gram of hydrocarbon mixture , As measured by ASTM method D6730; at least 0.001 grams of olefin, as measured by ASTM "D6730, and the olefins contain at least 0.ool grams of terminal olefin per gram of olefin, as measured by ASTM method 〇673〇 measured; at least 1 gram of light oil; at least gram of kerosene, this kerosene gram of kerosene contains at least 0.2 grams of aromatic compounds, as determined by eight lamps by DU%, to / 〇 〇 !! grams of diesel oil, which contains at least 0.3 grams of aromatic compounds per gram of diesel, as determined by the lp method 368/90; and at least 0 grams of vacuum gas oil (VG) The VG0 is at least 0.3 grams of aromatic compounds per gram of VG0, as measured by the lp method 368/90. The present invention also provides a crude oil composition, each of which contains a maximum of 0.05 g of residue, as determined by ASTM method D5307; at least 0.0000 g of boiling range distribution at 0.101 MPa For hydrocarbons of at most 004c (4 ° F), at least 0.001 g of hydrocarbons having a boiling range between 20CC and 300 ° C at 0.001 Mpa; at least 〇_g at 〇 〇〇iMpa 24 200535229 Lower Futen range hydrocarbons between 300 ° C and 400 ° C; and at least

0.001 g of hydrocarbons with a boiling range between 400 ° C and 53.8 ° C (1,000 ° F) at 0.101 MPa, as determined by ASTM method D2887; hydrocarbons with a boiling range of up to 204 CC The smoke with a boiling range of up to 204 ° C per gram contains: at least 0.001 g of fluorene, as determined by α§τμ method D6730; and at least 0.001 g of paraffin, the chain Alkanes include isoparaffins and normal paraffins, where the weight ratio of isoparaffins to normal paraffins is at most 1.4, as determined by ASTM method D6730. The present invention also provides a crude oil composition which contains, at most 0.05 mg of residue per gram of composition, as measured by ASTM method D5307; and 0.001 g at 0.11 MPa Warp range with a boiling range of up to 204 ° C (400 F), with a boiling range of 204 at least 0.001 g. (: Hydrocarbons between 300 and γ; at least 0.001 g of hydrocarbons with a boiling range distributed between 3000 c and 4000 c at 00 MPa; and up to 0.001 Grams of hydrocarbons with a boiling range in OlOi Mpa ranging from 4 ° C to 538 C (1,000 ° C), as determined by the astm method d⑽7; and wherein the boiling range is distributed at -10 ° c The hydrocarbons between 2 and 40. fluorene contain a carbon number 4 (c4) compound, and the & compound system contains at least 0.001 g of butadiene per gram of q compound. The present invention also provides a crude oil composition, which Each gram of composition contains · grams of dross, at least grams of hydrocarbons with a boiling range distribution of at most 2400C (400cF) at 0.101 MPa, and at least 100,000 grams at 0.10 gram. The boiling range distribution at ι MPa is less than 0.001 grams of hydrocarbons between 0.1 (H MPa 204 ° C and 3000 ° C, and the lower boiling range is distributed between 300 ° c and 400 25 200535229. And at least 0.001 g of hydrocarbons with a boiling range between 400 ° C and 53.8 at 001 MPa; and one or more catalysts greater than 0 g but less than 0.001 g The catalyst contains at least one or more alkali metals. In some specific examples, the present invention also provides a crude oil feed in combination with one or more of the methods or compositions according to the present invention, which "..." Treatment, distillation and / or fractionation in a refinery; ⑻ contains components with a carbon number of 4 or more, and the crude oil feed contains at least 0.5 grams per gram of crude oil feed, which contains hydrocarbons, of which Some have ... under the 〇i〇i milk, low side; the boiling range distribution of 100 C, the boiling range distribution between 0 and 100 MPa. C and 200 boiling range distribution between 001 and 001 Boiling range distribution between 2⑻.c and 300. (: between 3 分布% and 400 at 100 MPa, and boiling range distribution between 0〇 and 4⑽ and 7 〇iMpa. (). (: Boiling range distribution between: ⑷ / g crude oil feed contains: at least 0.0001 g of hydrocarbons with boiling range distribution below 0.10 MPa at 0.11 MPa 'at least The boiling range of 〇01. Gram at 010 MPa is distributed at just. C = 200. (: Hydrocarbons between, at least 0.001 gram in 〇ι〇ι Lower boiling · Capricorns are distributed between 200 ° C and 300 hydrocarbons, at least 0.001 g of boiling range between 0.001 and 400% at 0.1 MPa , And at least 0.001 grams of hydrocarbons with a boiling range distributed between · C and 700 ... at 0.001 Mpa; ⑷ has ―TAN; ⑺ 0.2-0.99 grams per gram of crude oil feed. -3-0.8 g or 0.4-0.7 g of residues-⑻ contains nickel, vanadium, iron or mixtures thereof; ⑻ contains sulfur; and / or ⑴ nitrogen-containing hydrocarbons. In some specific examples, the present invention also provides a hydrogen source in combination with one or more of the aspects of the invention according to the invention 26 200535229 :: '(a) is gaseous; ㈨ contains molecular wind; ⑷ contains light weight Hydrocarbons; rhenium contains methane, ethane, propane or mixtures thereof; (e) contains water; and / or (f) mixtures thereof. In some specific examples, the present invention also provides a method in combination with root = composition-or-multiples, which includes adjusting the unintentional medium, wherein adjusting the inorganic catalyst includes: ⑷ catalyzing an inorganic salt Heat to at least 300+ degrees, and / or (b) heat the inorganic salt catalyst to degrees. In the specific examples of the temperature and temperature of the white salt catalyst and the temperature method of cooling the inorganic salt catalyst to at most 500 γ, the present invention also provides one or more groups of knife materials and-or multiple contacts with the solution or composition according to the present invention. Media contact and _ 妾 touch the stop ... °. 2 grams' at most. 15 grams, at most ㈠ grams, such as mass denier * 50 and non-condensable hydrocarbons in the range of 0.10lMpa: the tester; ㈨ so that the contact temperature is within the range of 2-750 kJ or between 26 Within the range of 55% ^; ⑷ so that n ⑷ force is between 0.1-20 MPa meters crude oil feed to crude oil feed ratio is per cubic meter to inhibit households from producing 0 or 5-320 standard cubic meters Within the range of hydrogen source; (e) crude oil feed, Γ /) in order to suppress coke during contact or complete product or at most 0.05% formation; (g) make this crude oil product per gram of crude oil product. Coke; (h) _ evening 0.03 grams, at most 0.01 grams or at most 0.003 grams of semi-liquid t | ° 卩 inorganic salt catalyst in this type of contact conditions ... of =; ⑴ makes crude oil products Has at most for this crude oil. TAN′ω makes the crude oil product have a total / V / Fe content of at most 90%, at most 50% or at most 1% of the V / Fe content for the crude oil; (k) at the crude oil product; Have a sulfur content of 90 /, at most 60% or at most 30% of the sulfur content of the crude oil feed; ⑴ so that the original product has at most 90%, at most 70%, at most 50 of the nitrogen content of the crude oil feed % Or up to 1G% nitrogen content; (i) making the crude oil product have a residue content of up to 30%, up to 10% or up to 5% of the crude feed residue content; (ii) co-production of ammonia and crude oil products; ⑷ make the oil product contain methanol, and the method further "reduces methanol from the crude product; combines the recovered methanol with an additional crude feed to form an additional crude feed / methanol mixture; and heats the additional Emu oil feed / methanol mixture 'reduces the tan of the additional crude oil feed to below! (—P): One or more properties of the obtained crude oil product are changed compared to the individual or multiple properties of the crude oil feed. Up to 90%, (q) the contact area The consumption of the media is 100 grams of crude oil per 100 grams of crude catalyst, and the total catalyst is only 160 grams; and / or the lice source is added to the crude oil feed before or during contact. In some specific examples, Ben Yuming's α Dongtuming also provides the contact conditions with the method according to the present invention or one or more combinations ° C mw], including: 包括 at a temperature of 500 c or less The inorganic salt catalyst is combined with the contact material of the field, where the inorganic :: something ... is insoluble in the crude oil feed or the crude oil feed and the inorganic salt catalyst are produced t = catalyst In order to make a complete product containing a piece of Ququ house which is a liquid mixture under the sacrifice. In some specific examples, the method of the present invention is also used for formulas or compositions according to the present invention. One or more methods of grouping the months, which include bringing crude oil into contact with the inorganic salt catalyst, and further including: (i) contacting the contact area before or during the contact; (ii) bringing the crude oil into contact. Feed and inorganic :: before contact, an emulsion of crude oil feed and water is formed; the original two ::: contact zone "; and 'Or, the steam is brought into contact with the inorganic salt catalyst in order to at least partially remove coke from the surface of the natural organic salt catalyst. In some specific examples, the present invention also provides a combination with one or more of the two or two substances according to the present invention. A method includes contacting crude oil, organic salt catalysts to produce a complete product, wherein at least part of the complete product is made with steam, and the method further includes the following steps: Condensation of at least a portion of the vapor at 1 Mpa to form the crude oil is achieved by: (i) the crude oil product further comprises a component having a selected boiling range distribution; and / or (b) the crude oil product comprises a component having a selected boiling range; Composition of API gravity. In some specific examples, the present invention also provides a method in combination with a party or composition according to the present invention, or a combination thereof, which includes bringing crude oil into contact with one or more catalysts and the one or more The catalyst is non-acidic. 2. In some specific examples, the present invention also provides a K3Fei〇Si4 catalyst or a transition metal sulfide catalyst in combination with one or more of the methods or compositions according to the present invention, which: ⑷ per gram of the K3Fei () S " catalyst or transition metal sulfide catalyst contains a total of at least 0.4 grams, at least 0.6 grams or at least 0.8 grams of at least one transition metal sulfide; ⑻ in K3Fei0s "catalyst or transition metal sulfide catalyst The atomic ratio of transition metal to sulfur is in the range of 02 to 20: (0 further-comprises-or more alkali metals, one or more compounds of an alkali metal or a mixture thereof; ⑷ further comprises a Or more than one soil test 29 200535229 metal, one or more compounds of alkaline earth metal or one or more mixtures thereof further comprising one or more metal test, one or more metal test,), or more compounds or mixtures thereof, wherein in the KJcqS The atomic ratio of the transition metal to sulfur in the 4 catalyst or the transition metal sulfide catalyst is in the range of υ.5 · 2 · 5, and the atomic ratio of the alkali metal to the transition metal is in the range of 0 to h • Main 1 Within the range of (f) One or more compounds or mixtures thereof containing one or more earth test metals, one or more earth test metals, among the 3 ei〇 ^ 4 catalysts or transition metal sulfide catalysts The atomic ratio of transition metal to sulfur is

Within the range; and the atomic ratio of the alkaline earth metal to the transition metal is in the range from Q to above; (g) further includes zinc; (h) further includes (/) further includes KFeS2; and / or rhenium is non-acidic. 3 1 In some specific examples, the present invention also provides combinations with one or more of the methods or compositions according to the present invention, where K3F ~ s "catalyst formation. In some specific examples, the present invention also Provide one or more transition metal sulfides in combination with one or more of the formula = composition according to the present invention, two or more of which (a) contains one or more transition queens selected from columns 6-10 of the periodic table or A plurality of one or more compounds selected from transition metals from 6 to 10; or, the compound contains one or more iron sulfides; (c) contains FeS; ⑷ contains Fes :; (e) a mixture containing iron sulfides Wherein the iron sulfide is represented by the chemical formula Fe (] _ 0) S, where 6 is within a range of Γ from 0 to 0 · 17 '(f) further comprising K3FeiOM after contact with the crude oil feed; ( g) the transition metal of the one or more transition metal sulfides is iron, and / or (h) is deposited on a carrier, and the transition metal 30 200535229嫖 contains up to 0.25 g of total carrier. In some specific cases Φ, 〒 The present invention also provides A formula for forming a transition metal sulfide catalyst composition in combination with one or more of the methods or compositions according to the present invention, _ ti A t, θ VIII, / Μ 万, including the transition metal Oxides and metal salts: X forms a transition metal oxide / metal salt mixture; reacts the transition metal oxide / monsen salt mixture with hydrogen to form an intermediate; and the: intermediate and sulfur are in one or more hydrocarbons React in the presence of a compound to produce a transition metal catalyst. (A) the metal salt contains an alkali metal carbonate; further comprising dispersing the intermediate in a liquid hydrocarbon, and simultaneously It reacts with (c) where one or more of the hydrocarbons have a boiling point of at least R. C. ⑷ where one or more of the hydrocarbons are VG0, benzene, or a mixture thereof, where the transition metal oxide and Metal salt mixing includes: mixing a transition metal oxide with a metal salt in the presence of deionized water to form a thirsty paste & drying the wet paste at a temperature ranging from 150.250; and burning at a temperature ranging from 3, _ The dry paste; The reaction includes the intermediate force in the presence of at least one of the hydrocarbons to a temperature ranging from 2.35 "; and / or it further comprises contacting the catalyst composition with a crude oil feed comprising a source of sulfur and hydrogen. In certain embodiments, the present invention also provides an inorganic salt catalyst in combination with one or more of the methods or compositions according to the present invention, comprising: (㈡ or more alkali metal carbonates, one or more alkaline earth metal carbonates Salt or its thinking) eight things; (b) —or alkali metal hydroxides, one or more alkaline earth metal compounds or mixtures thereof; (C) one or more alkali metal hydrides, species test soil Metal hydrides or mixtures thereof; (d) —an old and new species of alkali metals 31 200535229 sulfides, one or more sulfides or mixtures of one or more alkaline earth metals; (e) —one or more of alkali metals One or more amines, one or more feamines or mixtures thereof; (f) one or more metals selected from columns 6-10 of the periodic table, one or more selected from columns 6_1 of the periodic table One or more compounds of metals (G) one or more inorganic metal salts, and wherein at least one of the inorganic metal salts produces Z hydrides during the use of the catalyst; osmium sodium, potassium, noodles, cesium, or mixtures thereof; osmium and / or ^) A mixture of sodium and potassium salts, and the potassium salt contains potassium carbonate, potassium hydroxide, hydrogen

Potassium or a mixture thereof, and the sodium salt comprises sodium carbonate, sodium hydroxide, sodium hydride or a mixture thereof; and / or (k) a mixture thereof. Mind, according to the present invention: The combination of one or more combinations of inorganic salts containing alkali metals, the contact order of at least the test sequence of the metal to the atomic order greater than the genus is 0. 5 d A々々- · within the target range; (b) at least · of the alkali metal is sodium and unloaded, and the atomic ratio of 崎 is at least / in the alkali metal] within the dry range,

Kobe Kobe = ^, potassium, and noodles, and at least three of sodium, potassium, and sodium ^ are within the dry range of 5, the alkali metal neutron ratios are each in 0 "'and sodium pairs Potassium, sodium versus planer and potassium versus planer are in the range of U, and ^; 至少 at least three of the metal test towels are in the range of 0.1 to 5. ... and the atomic ratios of absolute and absolute planes are in the range of For a certain 4b ship — ~ one of the conventional methods of φ method or composition, the description also provides contact with the medium according to the present invention, and: (a) the combination of two or more inorganic salts containing a carrier material is contacted -Materials include Oxidation, Oxidation, Oxidation, Oxidation 32 200535229 Titanium Water / Moonstone, Oxide Shao, Germanium Oxide, Iron Oxide, Oxide Record, Zinc Oxide, Oxide Bromide, Antimony Oxide or mixtures thereof; The carrier material is incorporated with:-or one or more compounds selected from metals in columns 6-10 of the periodic table, one or more compounds selected from columns 6-10 of the periodic table;-or more metal carbonates , One or more metal hydroxides,-or more metal hydrides,-or more alkaline earth metal carbonates,-or more alkaline earth gold It is a hydroxide, one or more earth test metal hydrides, and / or mixtures thereof. In certain embodiments, the present invention also provides a method in combination with one or more of the methods or compositions according to the present invention, which Including contacting the crude oil feedstock with a thermomechanical salt catalyst, where: ⑷ the catalyst activity of the inorganic salt catalyst is substantially unchanged in the presence of sulfur; and / or 添加 the inorganic salt catalyst is continuously added Into the crude oil feed. In some specific examples, the present invention also provides an inorganic salt catalyst in combination with one or more of the methods or compositions according to the present invention, which exhibits · G)

The turning point of the exhaust gas in the temperature range of TAP, and the exhaust gas contains water vapor and / or carbon dioxide; (b) thermal transition in the temperature range between 200-500, 250.45000 or 300-400 ^ , As measured by differential scanning calorimetry φ at a heating rate of ο per minute; (c) a DSC temperature in the range of 2000-500% or 250-450 ° C; (d) at At least ι〇〇. . The X-ray diffraction pattern, which is broader than the x-ray diffraction pattern of the inorganic salt catalyst below 1000 ° C at a temperature of 3 ° C; and / or 3 ° after adjustment. The ionic conductivity at C is less than the ionic conductivity of the inorganic salt catalyst before adjustment. In some specific embodiments, the present invention also provides an inorganic salt catalyst combined with the method according to the method 33 200535229 of the present invention or-and formed-or more, which exhibits-discharge within the degree of dryness The inflection point is as measured by TAp and the contact conditions are such that the contact temperature is: 以上 above Ti, 1 in τj, the TAP temperature of the inorganic salt catalyst is below 300c, 2000c, or 10. ^ =

Formula I produces at or above the temperature; and / or (at least) the TAP of the inorganic salt catalyst. In some specific examples, the present invention also provides a combination with the product of Formula 3 and the product according to the present invention. Inorganic salt catalyst, 1 or where = liquid or semi-liquid at the TAP temperature of the inorganic salt catalyst, two

… Organic salt catalyst is at least A Μ at least at the TAP temperature. The mixture of phase and solid phase, and the temperature of Yiyi ZC is liquid ~, at least one of Han / Yu (C), Haiyi inorganic salt has a Dsc temperature of more than 500 ℃. 'In some specific examples, the present invention is also provided for combination with one or more of the methods or compositions according to the present invention innn / JijL Na Dian male media, which is tested in the form of particles that can pass through the filter At the time, AA, w — x the field is heated to at least 300 to κ / will be under gravity and / or under the force of at least 0 tear feet a and: 2 makes the inorganic salt catalyst from the first form to the first Two forms': The evil is cooling the inorganic salt catalyst to 20%. . Back to the brother a form. In some specific examples, the present invention is also a combination of one or more methods or compositions: two roots: the 10,000 catalysts of the present invention, the ancient ... 裇 salt catalysts, and each gram of inorganic salt catalysts 3 There are: ⑷ bells or bell compounds of up to 0.01 g, which is calculated by the weight of ri 34 200535229; (b) halides of up to 0.001 g, which is calculated by the weight of halogen ^, and / or (C) Up to 0.001 g of a glassy oxide compound. In certain embodiments, the present invention also provides a complete product # in combination with one or more of the methods or compositions according to the present invention, which contains at least 0.8 grams of crude oil product per gram of complete product.

In some specific examples, the present invention also provides a crude oil product in combination with one or more of the methods or compositions according to the present invention. #: ⑷ Each gram of the original reading product contains at most 0.003 g, at most 002 g, Up to 0.001 g up to 0.05 g, up to 0.001 g, 0-00 g, 0 g, or 0.0001-0.03 g of residue; (b) & g per crude oil product. G to 0.05 g, 0.01.0.03 g or 0.00 g of coke; ⑷ has an olefin content of at least 10% greater than the olefin content of the crude oil feed; ⑷ per gram of raw product 3 is generous 0 g but less than 100 g of total inorganic salt catalyst, such as those in the mass balance; (e) each gram of crude oil product contains at least 0 g,

0 side W grams, (UMI 9 grams, G · ⑷ grams of v⑻; ⑺ contains VGO and the touch per gram VG0 contains at least 0. 3 grams of aromatic compounds; ⑷ contains 0.001 grams or O.KO.U of Germany ; ⑻ up to 14 々 H / C '⑴ has 9 (M 1 0% atomic H / c of the crude oil feed: ⑴ has a monocyclic ring aromatic compound content of at least ⑽ greater than the crude oil feed ^ Single «cyclic aromatics content; (k) containing xylenes, ethylbenzene and up to grams of benzene, di: compounds; (I) per gram of crude oil product containing ϋ · 05 · 〇」 5 See toluene, 03_0 Toluene, ... grams of o-xylene and 0.2 grams of diesel oil containing at least 0.0001 grams or 0 Λ < ± 0.0i_0 · 5 grams of diesel oil; ⑷ contains diesel oil, 35 200535229, and the diesel system contains less Even at least 0.001 g of aromatic compound, at least 0.001 g, from 0 to (0) 3 up to 0.7 g, or 0.000-1 to 0.5 g of (P) contains kerosene, and the kerosene is Grams ..., _5 grams of aromatic compounds, and: in grams "contains at least ... 2 grams or at least and / or at most -30. (:, At most _4 0. freezing point at a temperature of -50 ° C, ( q) contains at least 〇〇〇〇ιι or at least 0. 5 grams of light oil; ⑴ contains light oil, and the light oil is per gram light ·

Grams, at most. -Grams or at most. .〇. 2 grams of benzene, at least heart: :: or at least 90 octane and / or isoparaffin and n-paraffin, the weight ratio of iso-chain burned hydrocarbon to normal-chain burned hydrocarbon in double light oil is at most M; and At least 10% of the volume is greater than the crude feed volume.

In certain specific examples, the present invention also provides a method in combination with one or more of the methods or compositions according to the present invention, including: contacting crude oil with a catalyst to form a complete product comprising a crude oil product, the Methodological advances include: (i) combining crude oil products with a crude oil that is the same or different from the crude oil feed to form a transportable pusher; (ii) crude oil products I that are the same or different from the crude oil feed Merge to form a blend suitable for processing; ⑷ divide the crude oil product; 分 fractionate the crude oil product into-or multiple sites' and manufacture transportation fuel from at least one of the sites; and / or () When the ® catalyst is a transition metal sulfide catalyst, the transition metal sulfide catalyst is processed to recover metals from the transition metal sulfide catalyst. In some specific examples, the present invention also provides a crude oil product in combination with the method or according to the present invention, and one or more of the products, each gram of crude oil product contains: (a) at least 0.001 grams of VGO, And the VG0 series contains at least 0.3 grams of aromatic compounds per gram of VG0; (b) at least o.ooi grams of diesel oil, 36 200535229, and the diesel series contains at least 0.33 grams per gram of diesel oil; Light oil, and the compound m \ is a compound; benzene to benzene, to ". Each gram of light oil contains at most .5 grams, y 6 'octane number, and / or isoparaffin and the positive bond K j- The fumes of the n-hydrocarbons are mostly 1.4% more; (d) Manchu hill

The distribution of the boiling range to gt., 〇._g is a mixture of 2 to 4 Qc (T.f) ::, and the mixture contains at most 015 grams of olefin per gram of the mixture. The weight ratio of atomic hydrogen to atomic carbon is at most "5 or at most G gram of kerosene, and the kerosene contains at least 0.5 grams of aromatic compounds per gram of kerosene and / or has a freezing point at a temperature of at most 30% (G) From 009 to 013 grams of atomic hydrogen, non-condensable hydrocarbon gas and light oil per gram of composition, when combined with Risi, the combined non-condensable hydrocarbon gas and light oil per gram contains at most G · 15 grams of diene; non-condensable hydrocarbon gas and light oil, when combined, they contain iso-fluorene and normal-chain fluorene, where isoparaffin vs. normal paraffin in the combined light oil and non-condensable flue gas A weight ratio of up to 14; hydrocarbons having up to 3 carbons, including: olefins and paraffins having carbon numbers 2 (C2) and 3 (c.), And the combined q and q olefins to the combined dagger and q chain The weight ratio of alkanes is at most 0.3; the olefins and paraffins of carbon number 2 (C2), wherein the weight ratio of I-olefins to q-paraffins is at most 0.2; and / or carbon number 3 (C3) Olefins and paraffins, wherein the weight ratio of Cs olefins to q-paraffins is at most 0.3; (k) has a butadiene content of at least 0 005 grams; ⑴ has an API specific gravity in the range of 15 to 30 at 15.50 ° C; (M) has a total Ni / V / Fe of at most 0.00001 grams per gram of composition; (... boiling range distribution is at most 204. (: the paraffin content of the hydrocarbons is in the range of 0 · 7_0 · 98 g; (0 ) Fotan range hydrocarbons up to 204 ° C, boiling range per gram 37 200535229 distribution up to 204 cc Yigong 4 contains 0.001-0.5 grams of olefins 4 boiling range distribution containing olefins per gram dilute The hydrocarbon contains at least 0.01 g: hydrocarbons that are too c ', and the olefins have a di-terminal dilute hydrocarbon with a distribution range of at most one; (a warp type, and the olefin has at least 0 ": = the molecule is called a hydrocarbon. & Lt The hydrocarbons in the 'Fortten dry distribution' range from " 1 to 0.5 grams of olefins, in some specific embodiments. The invention also provides one or more of the products according to the method of the invention or A combination of crude oil products containing at least one of the catalysts of one or more alkali metal catalysts, Where ... U) the alkali metal T main / one is potassium, thorium or sw, turquoise, this a substance; and / or (b) one to ^ of the catalysts further includes iron ore unloading (ba_e ). In the specific examples of transition metal sulfides and / or lignin, the features from the specific examples of the present invention: the features from other specific examples of the present invention are combined. For example, the characteristics from a specific example may be The characteristics of the bidders are merged .... "From any of the other specific examples, the crude oil product is obtained via any of the methods and systems described in the specific and further specific examples that can be described herein in the further specific examples. Added extra features to the example. [Embodiment] Detailed description of the invention 1 Here, some specific examples of the present day and month will be described in more detail. The terms used in this article 38 200535229 are defined as follows. The genus means one or more metals selected from the first group of the periodic table, one or more compounds selected from the first group of the periodic table, or a mixture thereof. "Earth test metal" means one or more metals selected from column 2 of the periodic table, one or more compounds or mixtures thereof selected from column 2 of the periodic table. "AMU" means atomic mass units. ASTM Means American standard tests and materials

Testing and Materials). "C5 Worcite, means pentane insoluble asphaltenes. Asphaltene content is as determined by ASTM method D2007. Crude oil feed, crude oil products, light oil, kerosene, diesel and VGO atomic hydrogen percentage and Atomic carbon percentage is determined by ASTM method D529l.

"API specific gravity" means the API specific gravity at 15.5 ° C. The Ap? Specific gravity was measured by ASTM method D6 822. "4" bitumen refers to a raw material produced and / or retorted from a hydrocarbon product: otherwise, otherwise the crude oil feed and / or complete product is as measured by the AS ™ method By. Hydrocarbon components such as: smoke, hetero-bonded, dilute, ring-burned, and aromatic compounds I :: As measured by the AS ™ method. Aromatic compound: The content of wood oil and VGO is as determined by 1? Fang 39 200535229 The content of the compound in kerosene is determined by the astm method D5 1 86. Br011 sted-Lory acid ' refers to a molecular body that has the ability to donate protons to another molecular body. ‘’ Brunister-Rory base, refers to a molecular body that can accept protons from another molecular body. Examples of Brewster-Rory base include hydroxide (OH), water (h2O), carboxylate (rC〇21), halide (Br—, C1, F, 1), hydrogen sulfate (HS04 —) And sulfate (S042—). "Carbon number '" means the total number of carbon atoms in the molecule. Coke "means a solid containing a carbonaceous solid that does not vaporize under process conditions. Coke content is as determined by mass balance. Coke weight is the total weight of solids minus the total weight of the input catalyst. Daytime refers to the weight of an ingredient in a substrate (such as crude oil feed, complete product, or origin / derived product) and is expressed as a weight fraction or weight percentage of the total weight of the substrate. "Wtppm" means parts per million expressed by weight. Diesel oil "means a boiling range of 26 ° at 0.101 MPa. € and 343 ° C (500-650 ° F) As determined by method D2887. ° F) hydrocarbons. The diesel content is as follows

ASTM distillate ’’ means that the boiling range is distributed at 204 at 0.101 MPa.

Assayed by ASTM method D2887. The distillate may include kerosene and diesel. "DSC55 refers to differential scanning calorimetry." Freezing point "and" freezing point temperature. Freezing point is determined by ASTM D2386, which means that crystalline particles are formed in the liquid. 40 200535229 "GC / MS" refers to gas chromatography combined with mass spectrometry. "Hard base" refers to, for example, Pearson in j⑽r, 7 ^ ^ i ^ J0uinal 〇 American Chemical 1963, 85, ρ · 35 Anion as described in 33. "H / C" refers to atomic hydrogen cutting; ^ 1 Θ r Ding by weight ratio of 耵 atom slave. H / c is measured as a value measured by the AS T M method D 5 2 91 on the hydrogen weight percentage t. "Heteroatom" refers to the oxygen, nitrogen, and / or sulfur contained in the structure of hydrocarbons + J. Thousands. The heteroatom content is, for example, ASTM method mp M 沄 1 = 1385 for oxygen, D5762 For nitrogen and D4294 for sulfur. "Hydrogen source" means hydrogen and / or a compound or compounds and / or compounds that react in the presence of a crude oil feed and catalyst to provide hydrogen to the crude oil feed and / or Or compound group. The source of hydrogen may include, but is not limited to, H, a I, 10,000, hydrocarbons (such as Cl to C6 hydrocarbons, such as tritium, ethyl, and propylene; J: Wan, Ding Song 4, P, 70 Ding , Pentane, light oil), water or mixtures thereof. Mass balance is used to evaluate the net amount of hydrogen in one or more compounds in a crude oil feed. "Inorganic salt" refers to a compound consisting of + genus accompany M ~ Litian to gen% ions and anions. "" Refers to the Petroleum Association (the —te Of petroleum), the current Central State Energy Association (the Energy ⑽ her. F [. ⑽, United Kingdom) 〇 "heterochain burning fe" means branched saturated hydrocarbons class. The boiling range of the kerosene system at 0 · 丨 〇 i Mpa is distributed in the other four. Warp classes between 匸 and 260oC (400-500 d η, Yang Niu § Bugan, 丄 人 Θ r). Kerosene content is as determined by the astm method D2887. 41 200535229 "Lewis acid" refers to a compound or substance that has the ability to accept one or more electrons from another compound. "Lewis test" refers to the ability to give one or more electrons to another. A compound and / or substance. `` Light hydrocarbons '' means hydrocarbons with a carbon number in the range of 1 to 6. Liquid mixtures '' means those containing one or more kinds at standard temperature and pressure (2 5 ° c, 0 · 101 Mpa, hereinafter (Referred to as "STP") a composition that is a liquid compound, or a composition that contains one or more compounds that are liquid under STP and one or more compounds that are solid under STP. ("MCR") refers to the amount of carbon residues remaining after the substance is evaporated and pyrolyzed. The MCR content is as measured by ASTM method 05453. "Light oil" refers to 0.11. Hydrocarbon components with boiling ranges between 38 and 204 C (100-400 ° F) at MPa. Light oil content is as determined by method D2887.

"Ni / V / Fe" means nickel, vanadium, iron, or a combination thereof.

The N] / V / Fe content refers to the content of Ni / V / Fe in a matrix. The Nl / V / Fe content is determined by the ASTM method or 863. ‘: Nm3 / m3’ ’refers to standard cubic meters of gas per cubic meter of crude oil feed. 'Non-acidic' means Lewis base and / or Brewster 'Rory alkaline. &Quot; " Non-condensable gas, means at standard temperature and plant strength (2 "c, 〇i〇im later said Under "STP") under Alp "under the ingredients and / or mixture of ingredients of the milk. "N-paraffin" means a normal (straight-chain) saturated hydrocarbon. "Burning value" refers to the expression of internal combustion engine fuel compared to the standard reference fuel. The calculated scorch value of light oil is determined by 卩 aStm method D6730. An olefin refers to a compound having a non-aromatic carbon-carbon double bond. The types of olefins include, but are not limited to, formulas, trans, terminal, intramolecular, branched, and linear. The table "k" refers to the periodic table stipulated by the International Union of Pure and Applied Chemistry (IUpac) in November 2003. Xifangzhi compound '' refers to a compound containing two or more aromatic rings. Examples of Xifang compounds include, but are not limited to, indene, naphthalene, anthracene, phenanthrene, benzothiophene and dibenzothiophene. "Residual" refers to a component whose boiling range is distributed above 538 (1000 ° F) at 0.1 Mpa, as measured by the astm method D5307. A semi-liquid system is a substance phase that has the substance liquid phase Examples of solid phase shell-liquid-lime inorganic salt catalysts include pulp and / or phases with a consistency such as toffee, pudding, or toothpaste. "SCFB" means standard cubic feet of gas per barrel of crude oil feed. '' Superbase '' refers to a substance that can deprotonate hydrocarbons such as paraffins and olefins under reaction conditions. 'TAN' refers to the [OH] per gram ("g ,,]) The number of milligrams ("mg ,,) represents the total number of acids. Tan is determined as AST] VU ^ D664. "TAP" means transient analysis of the product. "TMS" means transition metal sulfide. VGO means that the boiling range is distributed at 343 at 0.00 MPa. (:versus

Composition between 538 (65 (M000 π). Vg0 content is determined by ASTM 43 200535229 method D 2 8 8 7. In the context of this application, it is necessary to understand The values obtained for the properties of the composition fall outside the test% and the limit values of the Wanwan method, then the test method can be recalibrated to test the property, 1 Wang Bei. It should be understood that other values that are considered equivalent to References to standardized test methods for testing mummy goZero

Crude oil can be produced and / or obtained from hydrocarbon-containing products, and then colored. Crude oil is usually solid, semi-solid and / or liquid. Crude oil can contain crude $ petroleum. Stabilization may include, but is not limited to, removing non-condensables, water, salt, or a combination thereof from the crude oil to form a stable crude oil. This stabilizing mediation can take place at or near the manufacturing and / or f Watt distillation site.

Stable crudes have often not been steamed and / or divided in processing facilities to produce multiple components with a specific boiling range distribution (eg, light oil, distillate, VGO, and / or lubricating oil). Distillation includes, but is not limited to, atmospheric distillation and / or vacuum distillation. Undistilled and / or unfractionated stable primary II; contains components with a carbon number of 4 or more in an amount of at least 0.05 g per gram of crude oil. Examples of stable crude oil include whole crude oil, topped crude oil, desalted crude oil, desalted crude oil, or a combination thereof. "Topping, refers to a crude oil that has been processed so that at least some of its constituents with a boiling point of 35 D at 0.11 MPa have been removed. Typically, topping crudes contain up to 0.1 per gram of topping crude. G, up to 0.05 g or up to 002 g of such ingredients. Some stable crudes have properties that allow stable crudes to be transported to traditional processing facilities by means of transportation, such as pipelines, trucks or ships. Other 44 200535229 Crude oil has one or more inappropriate properties that make them worse. Inferior, / For transportation vehicles and / or processing facilities Moon Dagger is not acceptable, so y ... oil has very low economic value. The economic value may lie in the receptacles that hold the inferior crude oil that is too expensive in terms of transportation, shipping and / or processing. The properties of the inferior crude oil may include, but are not limited to: a) at least 0,5 mb) at least 0.2 Pa.s viscosity; c) at least 19 Aρm specific gravity of at least 0.00005 grams per gram of crude oil or at least 0.00001 grams of Ni / V / Fe total content; e) at least 0.005 grams of heteroatoms per gram of crude oil Total heteroatom content; f) a residue content of at least 0.01 grams of residue per gram of crude oil; g) an asphaltene content of at least 0.004 grams of asphaltene per gram of crude oil; h) an MCR content of at least 0.02 grams of MCR per gram of crude oil; Or i) their combination. In some specific examples, the inferior crude oil series may include at least 0.2 g of residue, at least 0.3 g of residue, at least 0-5 g of residue, or at least 0.9 g of residue per gram of inferior crude oil. In some specific examples, the 'inferior crude oil' contains 0.2 to 0.99 grams, 0.3 to 0.9 grams, or 0.4 to 0.7 grams of residue per gram of inferior crude oil. In certain specific examples, the low grade crude oil may have a sulfur content of at least 0.001 grams, at least 0.0005 grams, at least 0.001 grams, or at least 0.02 grams per gram of low grade crude oil. Inferior crude oil may comprise a mixture of hydrocarbons having a range of boiling points. Inferior crude oil may include: at least 0.001 grams, at least 0.005 grams, or at least 0.01 grams of hydrocarbons having a boiling range between 200 and 300 ° C at 0.11 MPa; at least 0.0 0.001 g, at least 0.005 g, or

0.01 g less boiling range is distributed at 300 at 0.101 MPa. (: Hydrocarbons between 400 ° C; and at least 0.001 g, at least 0.005 g, or at least o.oi 45 200535229 g at a boiling range of 0.101 MPa distributed between 4000 (: and 7⑻.c. Hydrocarbons or a combination thereof. In some specific examples, in addition to higher boiling components, inferior crude oil may include at least 0.001 g, at least 0.05 g per gram of inferior crude oil, or At least 0.01 g of hydrocarbons with a boiling range of at most 200 C at 0.101 MPa. Typically, this inferior crude oil has at most 0.2 g or at most 0.1 g of such hydrocarbons per gram of inferior crude oil. In some specific examples, the low-grade crude oil may contain up to 0.9 grams or up to 0.99 grams of hydrocarbons with a boiling range distribution of at least 3000c per gram of low-grade crude oil. ^ In some specific examples, Crude oil can also include δ smoke of at least 0. 001 grams per gram of crude oil with a boiling range distribution of at least 65.0 ° C. In some specific examples, 'inferior crude oil can be produced per gram of lower grade crude oil. Contains up to 0.9 g or Nanda 0-99 g. Forten range is distributed between 3000c and 1000.00. Hydrocarbons. Examples of inferior crudes that can be processed using the methods described herein include, but are not limited to, crudes obtained from the following countries and regions: Canadian Alberta, Venezielan Orinoco, Venezuela , US California and North Slope Alaska, Mexico Bay of Campeche, Argentina San Jorge basin, Santos and Kan, Brazil Persian Basin (Brazilian Santos and Campos basins), China

Bohai Gulf) ’China Karamay, Iraq Zagros, Kazakhstan 46 200535229

Caspian), Nigeria 〇ffsh〇re, Umted Kmgdom North Sea, Madagascar northwest, Oman (0man) and Hungarian Baker (Netherlands)

Schoonebek) 〇 The treatment of inferior crude oil can enhance the properties of inferior crude oil,

Acceptable for transportation and / or premises. The crude oil and / or inferior crude oil to be processed may be referred to as a "crude oil feed." This crude oil feed may be topped as described herein. Using the methods described herein, the crude oil obtained from the crude oil feed is processed The product is suitable for transportation and / or refining. The properties of the crude oil product are closer to the counterpart of West Texas Intermediate crude oil than the crude oil feed = or closer to Brent than the crude oil feed. Correspondence of crude oil has an economic value that is improved compared to the economic value of the crude oil feed. Tritium crude oil products can be refined with less or no pretreatment, which improves refining efficiency. Pretreatment can include Desulfurization, demetallization, and / or normal dust distillation to remove impurities from crude oil products.

A method for contacting a crude oil feed according to the present invention is described here. In addition, specific examples of production of products with various concentrations of light oil, coal>, gasoline, diesel, and / or VGO are generally not available. They can not be produced by traditional methods. Crude oil feed can be derived from hydrogen or multiple catalysts. Contact in the presence of a contact area and / or in a combination of two or more contact areas. In some specific examples, the ' hydrogen source is generated on the spot. On-site production of hydrogen sources " Bring crude oil feed to the hydrazone part with inorganic salt catalysts ranging from 200-500 ° C or 300-400. . The sound of y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, y, and y, and then react to form hydrogen and / or light hydrocarbons. The on-site reaction of 4 may include at least a portion of an inorganic salt catalyst including, for example, an alkali metal phosphonate. The complete product typically contains gases, vapors, liquids, or mixtures thereof produced during the contact. The complete product Vulcanis iguana 3 is a crude product of liquid mixtures under S 1 P'and ', and in some specific examples, contains non-condensable hydrocarbons at sTp. In some specific examples, complete products and / or crude oil products may include solids (e.g., inorganic solids and / or coke). In some specific examples, solids may be entrained in the liquid and / or vapor produced during contact. The contact zone typically includes a reactor, a portion of the reactor, multiple portions of the reactor, or multiple reactors. Examples of reactors that can be used to contact a crude oil feed with a hydrogen source in the presence of a catalyst include: stacked bed reactors, fixed bed reactors, continuous stirred tank reactors (CSTR), spray reactors, plug flow reactors, And liquid / liquid contactors. Examples of CSTRs include fluidized bed reactors and futeng bed reactors. Contact conditions typically include temperature, pressure, crude oil feed flow, complete product flow, residence time, hydrogen source flow, or a combination thereof. Contact conditions can be controlled to produce crude products with specific properties. The contact temperature range can be 200-800 ° C, 300-700 ° C, or 400 · 600 ° C. In specific examples where the hydrogen source is supplied as a gas (such as hydrogen, methane, or ethane), the ratio of gas to crude oil feed typically ranges from 1 _ 丨 6,] 〇〇

Nm3 / m3, 2-8000 Nm3 / m3, 3-4000 Nm3 / m3 or 5-300 Nm3 / m3. Contacting is usually performed within an I force range of 0.1-20 Mpa, 1-16 Mpa, 2-10 Mpa, or 4-8 MPa. In some specific examples in which steam is added, the ratio of two to eight crude oil feeds is in the range of seven to two kilograms per kilogram of crude oil feed, or 0.1 to one kilogram of steam. The flow rate of the crude oil feed may be sufficient to maintain the crude oil feed volume in the contact zone to at least 10%, at least 50%, or at least 90% of the volume of the contact zone. Typically, the crude oil feed volume in the zone is 4G%, 6G%, or 80j of the total volume of the contact zone. In some specific examples, the contact may be under additional gas such as argon, nitrogen, methane, ethane, Propane, butane, propylene, butene, or a combination thereof = complete below.子 隹 ―Fig. 1 (1) is used to make the contact system of the complete product as vapor. The crude feed leaves the crude feed supply source 101 and enters 1G2 via 2 104. The amount of catalyst used in the contact zone ranges from 1-100 grams, 2-80 grams, ㈣grams, or 4-60 grams per 1GG grams of crude oil feed in the contact zone. In some specific examples, a diluent may be added to the feed to reduce the viscosity of the crude feed. In some specific examples, crude oil 2 enters the bottom of adapter 102 via conduit 104.纟 In some specific cases, 49 1: Original: The feed can be heated to a temperature of at least 100 ° C or at least 300 π before and / or during the feeding of the crude oil feed to the contact zone 1G2. The standard can be used to heat the crude feed to a temperature in the range of 100% or more. In some embodiments, the catalyst is combined with the crude oil feed and transferred to the contact zone 1G2. The crude oil feed / catalyst mixture may be heated to at least ⑽ before sending it to the zone 102. C or at least ... C temperature. :: type and 1, can heat the crude oil feed to 200-500. . Or a temperature in the range of 30 " 00〇c. In this case and in each case, nr = 2 limbs, the crude oil feed / catalyst mixture 200535229 is a slurry. Left * In some specific examples, the TAN can be reduced by feeding crude oil into TΛ \ τ and feeding crude oil into the contact zone. Toshiki ^ 200-300 qc r R, —] For example, heating crude oil at a temperature of 100-400 or within the range, ^ ^ can be formed when the crude oil enters the sister ... ^ field material / catalyst mixture, The formation of the alkali metal of the sex ingredient can be from the tan oil and the TAN of some alkali metal salts. A _ knife to reduce the crude oil feed zone !: some t: in the example, the crude oil feed is continuously added

Mixing of material / touch two = zone ΓΗ can be sufficient to suppress the catalyst from cutting away from the original target. In some specific examples, at least a portion of the catalyst can be removed from the contact area ι0, and in some specific cases, such catalysts are regenerated and re-catalyzed. In certain embodiments, ' fresh catalyst may be added to the contact zone 102 during the reaction procedure.

In some embodiments, the crude oil feed and / or a mixture of the crude oil feed and the inorganic salt catalyst is delivered to the contact zone as an emulsion. The emulsion can be 'added in some specific examples by combining a natural salt catalyst / water mixture with a crude oil feed / surfactant mixture by adding a stabilizer to the emulsion. The emulsion can remain stable for at least 2 days, at least 4 days, or at least 7 days. Typically, the 'emulsion is stable for 30 days, 10 days, 5 days, or 3 days. Surfactants include, but are not limited to: organic polyweilic acid (Tenax 2101);

MeadWestvaco Specialty Product Group; Charleston, South Carolina, U.S.A.), C21 dicarboxylic fatty acid (DIACID 1550;

MeadWestvaco Specialty Product Group), Petroleum Luteinate (Hostapur SAS 30; Clarient Corporation, Charlotte, North

Carolina, U.S.A.), Tergital NP-40 Surfactant (Union 50 200535229

CarMde; DanbmT 'Comiectlcut, υ · δ · Α.) Or a mixture thereof. Stabilizers include, but are not limited to, diethylene glycol (Aldrich Chemica: [c .; Milwaukee, W1SCOnsin, u.s.a.) and / or monoethanolamine (j • butyl

Baker; Phillipstmi ^ g, New Jersey, U.S.A.). The circulation catheter 106 can connect the catheter 108 to the catheter 104. In some specific examples, the circulation catheter 106 may directly enter and / or leave the contact area 102. The circulation conduit 106 may include a flow control valve 110. The flow control valve ιιο may allow at least a portion of the material to circulate from the conduit 108 to the conduit ι04 and / or the contact area 102. In some specific examples,

The condensing unit can be placed in the duct 108 so that a part of the material from σ to J is condensed and recycled to the contact zone 1. In some specific examples, the circulation catheter 1G6 may be a gas loop. : The volume control port U " port 110 can be used to control the flow in and out of the contact zone 102 so that a fixed volume of liquid is maintained in the contact zone. In some specific cases, 5 is at the contact area 10 2 Φ: 4 ^ ^ 2 towels can maintain the volume of the selected volume range.

liquid. The feed volume in the contact zone 102 can be monitored using standard equipment. The bulk inlet 112 can be used to allow a hydrogen source and / or additional gas to be added to the crude feed while the crude feed is fed into the contact zone 102. In some In a specific example, the steam inlet 114 can be used to add steam to the contact area 102. In a specific example, the water-containing steam system is sent to the contact area ^ via the steam population m... The at least part of the complete product is produced as a vapor, in the contact zone W2. In some specific examples, the complete product is produced as steamed milk and / or a vapor containing small amounts of liquids and solids from the top of the contact 102. The vapor is transported to the separation zone through the duct 108. The ratio of hydrogen source to crude oil in the contact zone 102 can be changed in 51 200535229 and / or the rhino force in the contact zone can be changed from L to the contact zone. 〖〇2 Top soil-4 θ μ — generated radon gas and / or liquid phase. In the January / August case, from the contact area} 廇 山, mountain, bucket bucket 1 a eight-pound steam The amount of crude oil per gram contains at least 0.5 grams, up to ^ grams, and at least 0.9 grams. To a small square · 97 grams of crude product. In a certain discrimination ", consistent accustomed embodiment, the steam generated from the Department of contact regions 102 per gram of crude mound ^ ^ ^ ^ ^, g of crude product. ~ 〇 · " .99g or 0.9_0.98 can remain in the contact zone 102 as the contact process catalyst can contain residual crude oil feed

Used catalysts and / or solid order by-products. Solid and / or used and / or coke. Eight ★ In the separation sheet & 116 towels, the steam is cooled using standard separation techniques:

Knife 1, $ into crude oil products and gases. The crude product leaves the separation unit 1 1 6 and then enters the crude product receiver ΐ 9 via a conduit 118. The resulting raw & product can be transported and / or processed palatably. The crude product receiver may include one or more pipelines,-or multiple storage units,-or multiple transport containers. In some specific examples, the separated gas is transported to other Canadian dollars (such as for use in fuel cells or sulfur recovery equipment) and / or via '& amp 1 20 cycles to the contact area 102. In some specific examples, 'quasi-physical separation methods (such as filtration, centrifugation, or membrane separation) can be used to remove the solids and / or liquids entrained in the crude product. Figure 2 "% Contact system 122 for processing crude oil feed with one or more catalysts to make a complete product, which can be a liquid or a liquid mixed with a gas or solid. Crude oil feed can enter contact zone 102 52 200535229 via conduit 104. In some specific examples, the crude feed is received from a crude feed supply. The conduit may include a gas inlet " 2. In some specific examples, the body π Π2 can directly enter the contact 1 102. In some specific examples, the Luo steam inlet 114 can be used to add steam to the contact ^ 1 () 2. The crude feed can be contacted with the catalyst in contact 1 102 to make the complete product. In some specific examples, the catheter 106 allows at least one Qiba to circulate from the complete product of αT ^^ to the contact zone 102. Contains complete product and / or solid and / or unreacted crude

The feed mixture leaves the contact zone 102 and enters the separation zone 124 via a conduit. In some specific examples, "the female cold weight is placed early (for example, placed in ¥ 106) so that the mixture of at least one V trowel in the catheter can be condensed and recycled to the contact area 102 for further addition. Plus. In some specific examples, the circulation duct 106 may be a gas circulation tube. In some embodiments, the duct 108 may include a filter to remove particles from the complete product's throne. In separation zone 124. $ 小 ^, the main / part of the crude oil product can be separated from the finished product and / or the catalyst. In specific examples where the 70 product contains solids, standard solid separation techniques can be used, such as centrifugation, filtration, decantation,

溽 fe / knife off) to remove solids from fully produced -j m knife off. For example, solids include catalysts, used catalysts, and / or ",, annoying, and 5. In some specific examples, a part of the gas system is cut off from the full production of eight products. In addition, In the example, at least a part of the product of the & female-eight body Befan and / or the solid may be circulated to the catheter 104 ′ and / or in a body sound 1-1 /, which is circulated through the catheter 120 to Contact area 10 2. For example, #, Shi Yao ^ _ can be combined with crude oil feed, after which it enters the contact area 1 02 for further processing ... Crude oil products can be separated from the pipeline 128. Zone 124. In some specific examples, the crude product can be transported to the receiver of crude oil products in certain specific examples.… In some specific examples, the complete product and / or crude product may contain up to- Media. The central zone of the complete product and / or crude oil can be separated using standard gas / liquid separation techniques such as spraying, membrane separation, and lowering: here and there; Separated gas carrier / plus: unit (for example for combustion Batteries, sulfur recovery equipment, other processing equipment, or combinations thereof) and / or recycled to the contact zone. In some specific examples, at least a portion of the separation of the crude oil feed is carried out in the feed area. Figure 3 is the specific combination of branching and relaying system (schematic I contact system), which can be relaying system 100.

And / or contact system 122 (shown in Figures 1 and 2). The crude oil feed enters the separation zone 132 via the HM HM. At the separation zone 132, at least a portion of the crude feed is separated using standard separation techniques to produce the separated crude feed and hydrocarbons. The separated crude oil feed, in some specific examples, includes a boiling range distribution of at least 100. . Or a mixture of ingredients of at least 1 200c 'or, in some embodiments, those having a boiling range distribution of at least 200 Y. Typically, the separated crude feed comprises a mixture of ingredients with a boiling range distributed between 100-_Y, 120-900 ° C, or 200-800 ° C. Hydrocarbons separated from the crude oil feed leave the separation zone via conduit 134 and are transported to other processing units, processing facilities, storage facilities, or combinations thereof. At least a portion of the separated crude oil feed leaves the separation zone 132 and enters the contact system 130 via a conduit 136 for further processing to form a crude product, which leaves the contact system 13 via a conduit 138. 54 200535229 In some specific examples, the crude oil product produced by the feed described herein is blended with a crude oil carrier < For example, ^ 4 i Μ times are different-and, this material can be a blended product with a crude oil with a different viscosity between the viscosity of the crude oil product and the original degree. The hunted crude oil-3 4 The second product of A may be suitable for transportation and / or processing. Specific examples of the combination of μ, 〃 contact system 130 are shown: Figure. In some specific examples, at least-part of the original hydrazone system 13 and enter the blending zone 14 ... in the blending zone: 〇

Divide into a "seed" or a processing stream (such as a flue gas stream or light oil made from two feedstocks), crude oil, raw materials, etc. to combine to make a blended product. Processing streams, crude oil feeds, crude oil or mixtures thereof are depicted as ', and the system is transported directly into the blending zone 140 or via,' ② to the upstream of the quadrilateral zone. The mixing system may be located near the blending zone 140 :::. Blends can meet specific product specifications. Specific product specifications: We: Γ: ApI specific gravity, ταν, viscosity or a combination of daggers in a dry range or limit. The blended product leaves blended region 140 via conduction f 144

Be transported and / or processed. in. In the illustrated example, methanol was used as a catalyst during the contact procedure. For example, hydrogen and -carbon oxide can react to form formazan. The recovered methanol may contain dissolved salts, such as potassium hydroxide. Methanol can be combined with additional crude feed to form a crude feed / methanol mixture. Combining methanol with the 2 feed tends to reduce the viscosity of the crude feed. Heating the crude feed / mouth to a maximum of 500 can reduce the TAN of the crude feed to less than one. I 55 200535229 Figure 5 is a specific example W diagram of a combination of a separation zone, a contact system, and a blending zone. Crude oil feed enters separation zone 132 through conduit 104. The crude oil feed core is separated as previously described to form a separate crude oil feed. The separated crude feed enters the contact system 130 via a conduit 136. The crude product leaves contact system 130 and enters blending zone 14 via conduit 138. In blending 40, the other processing streams that are fed by M < 142 > and / or crude oil / crude oil products are combined to form the blended product. The blended product exits the blended region 140 via a conduit 144.

Schematic diagram of κ °,. ,,, and the heavy contact system 146. Contact system 100 (

θ) can be placed before the ash contact system 148. In an alternative embodiment :: the position of the contact system is interchanged. The contact system may include an inorganic salt catalyst system, and the charger 148 may include one or more catalysts. Additional inorganic salt catalyst, transition metal sulfide catalyst, commercially available Z, mixture in contact system 1 48. The crude oil feed enters the contact system via a conduit 104, and then comes into contact with a hydrogen source in the presence of an inorganic salt catalyst. The entire product contains chlorine. In some specific examples, it also contains the original ::. The edge product can exit the contact system 100 via the guide 108. The inorganic salt catalyst is connected to the hydrogen source of the crude oil feed. At least a portion of the hydrogen generated is transmitted to the contact system 148 by the contact system 100. B 150 二 二 = Entity M ′ can separate and / or, for example, the generated hydrogen; St; transfer to the contact system ⑷. In some parts of the system where the hydrogen produced touches 10 °, the contact system 100 flows to the contact system 148. In some specific examples of '56 200535229 ', do you carelessly ^ The vapor stream produced by the contact system 100 is directly mixed with the crude oil feed into the contact system 1 48. The primary / by feed system enters the contact system i 48 via conduit 152. In the contact system 148, contact of the Xidun, Shan, and Teng crude oil feed with at least a portion of the catalyst produced produces a product. This product is in some specific examples the KING product σ HAI product leaves the contact system via the conduit j 54 n in some specific examples' a system including a contact system, a contact zone, a separation zone and / or a blending zone, such as As shown in Figure 1-6, it can be located at or near the manufacturing site that manufactures inferior crude oil feeds. After processing through the catalyst system 'the crude oil feed may be considered suitable for transportation and / or use in a refining process. In some embodiments ' is the transport of crude oil products and / or blended products to a refining and / or processing facility. Crude products and / or blended products can be processed to make commercially available products, such as transportation fuels, heating fuels, lubricants, or chemicals. Processing may include leaving crude oil products and / or blended products to Germany and / or fractions I for manufacturing-or multiple locations. In some specific examples, crude oil products, blended products, and / or one or more fractions may be hydrotreated. … In some specific examples, the complete product is coke containing at most 0.05 g, at most 0.03 g, or at most 0.01 g per gram of the complete product. In some instances, the complete product is substantially free of coke (i.e., less coke-based). In some specific examples, the ' crude oil product may include up to 0.05 grams, up to 0.03 grams, up to 0.001 grams, or up to 0. ' grams of coke per gram of crude oil product. In certain specific examples, the crude oil product has from above 0 to 0.05 per gram of crude oil product, 0.0001-0.03 grams, 〇〇〇 (η-ο · (η gram or 〇 Gu-〇 The coke content in the range of 0.05 g, or 57 200535229 is not detectable. In some specific examples, the crude oil product has up to 90%, up to 80%, and up to 50% of the MCr content of the crude feed. %, Up to 30% or up to 10% MCR content. In some specific examples, the crude product has a negligible amount of MCR | In some specific examples, the crude product contains at most 0.05 grams per gram of crude product, MCR of at most 3.0 g, at most 0.001 g, or at most 0.001 g. Crude oil products typically contain from 0 g to 0.04 g, 0.000001 to 03 g, or 0.0001 g per gram of crude oil product. 〇1 grams of MCR. · In some specific examples, the complete product contains non-condensable gases. Non-condensable gases usually include but are not limited to: carbon dioxide, ammonia, chlorine sulfide, hydrogen, carbon monoxide, methylbenzene, other non-condensable under STP Hydrocarbons or mixtures thereof. In some specific examples, Gas, carbon dioxide, carbon monoxide, or a combination thereof can be formed on the spot by contacting steam and light hydrocarbons with inorganic salt catalysts. Typically, under thermodynamic conditions, the molar ratio of carbon monoxide to carbon dioxide is 0.07. In- In some specific examples, the molar ratio of the carbon monoxide produced to the carbon dioxide produced is at least 0, 0, 5 or at least 0. In some specific examples, the molar ratio of the carbon monoxide produced to the carbon dioxide produced is In the range of om 04_09 or 〇5_〇 · 8. When the% production-the ability of carbon oxides to take precedence over carbon dioxide can be beneficial to other processes located near or upstream of the process. For example, the carbon monoxide produced can The product is used as a reducing agent 'or in other processes such as the synthesis gas process. 58 200535229 In some specific examples, as prepared herein, the boiling range is distributed between 0 Wc: the inclusion compound can be Contains smoke with a carbon number within the range. The mixed two: master gram This mixture may contain l__Ql 2 0.005-0.0〗 grams of c4 hydrocarbons. The c4 hydrocarbons or. —G — ^ or ㈣, g In the case of two specific t, the isofluorene hydrocarbons are prepared with a denier ratio of at most 1.5, at most 1,4, at most U, at most 0.8, at most 0.3, or at most 0.1 relative to the normal chain hydrocarbons. In certain specific examples, 'heterochain hydrocarbons are prepared with weights in the range of 0.000H.5, 0.00H.0, or 0.0001 "relative to the positive bond: paraffins. Paraffins may contain heterochains Alkanes and / or n-paraffins.

In some specific examples, the complete product and / or crude oil product may contain proportions or amounts that are not normally found in the raw, olefins, and / or paraffins produced and / or retorted from the product. The olefin contains a mixture of an olefin (, dilute) having a terminal double bond and an olefin having an intramolecular double bond. In some specific examples, the olefin content of the crude product is greater than the olefin content of the crude feed by 2 W , 50, 100, or at least 200. In some specific examples, the olefin content of the crude product is a factor that is at most L000, at most 500, at most 300, or at most 250,000 greater than the olefin content of the crude feed. In some specific examples, the boiling range is in the range of 20-400. Rhenium hydrocarbons have a boiling range in the range of 20-40 ° C per gram of hydrocarbons in the range of 0.0001- 0 1 g, 0.0001 Olefin content in the range of 0.05 grams or 0.04 grams. In some specific examples, at least 0.0000 grams, at least 0.005 grams, or at least 0.00 grams of alpha olefins can be produced per gram of crude oil product. In some specific examples, 59 200535229, the crude oil product contains 0.001-0.2 grams or HCM grams of alpha dilute hydrocarbons per gram of crude oil products. In some specific examples, the boiling range distribution is 纟 20 Shoulder hydrocarbons have a boiling range of 20 grams per gram. Alpha-olefin content of hydrocarbons between -400 γ in the range of 0.0000 g, 0.000 g, or 0.01-0.04 g. In some specific examples, the boiling range is distributed in 2〇_2〇4. 匸 smoke has at least 0.7, at least 0.8, at least 009, at least 10, ^ 1.4 or at least 1.5 weight ratio of alpha olefins to intramolecular double-bonded olefins. The transition range is distributed at 20 ° C. The soot from 〇.7-1〇, 0.8-5, 0.9_3, or W ranges from double-bonded dilute hydrocarbons + m ^ ^ ^ ^ ^ Inner μ ratio. The weight ratio of α-olefins in crude oil and commercially available products to intramolecular pseudobond fine hydrocarbons is usually at most 0.5. Manufacturing pairs and intramolecular: In addition, there is an increase in the amount of alpha fluorene in dilute smoke. Capacity, which can help double bond formation into commercially available products. 7 helps to transfer crude oil products to the next ;;: in the example 'crude oil feed and hydrogen source in the inorganic salt catalyst storage ° C between 2 o Side chain double side bond μ μ cis and trans double bond. The ratio by weight of trans-0.4, at most Guangjing to cis double bond straight chain alkanes is at most linear olefin: or Zhixiang丨 · 4. In some In the examples, the weight ratio of trans olefins with trans double 0.001-14, 0 to cis double bonds is in the range of 1-1.0 or 0.1-0 · 4. In the range = body shot ,, the boiling range of smoke distributed in the range between 2G-2G4 ° C_ to have a mother gram full range range of 20-400 ℃ range, at least U grams, at least 0.15 grams, at least please grams or A normal paraffin content of at least 60 200535229 0.30 g. The normal paraffin content of such hydrocarbons may be in the range of 0.001-0.9 g, 0.0.8 g or 0.2-5 g per gram of hydrocarbon. In some specific examples, such hydrocarbons have a weight ratio of isoparaffins to normal paraffins of at most 1-5, at most 1.4, at most 1.0, at most 0.8, or at most 0.3. From the normal chain burned hydrocarbon content in this type of hydrocarbons, it can be estimated that the normal bond burned hydrocarbon content of crude oil production is between 0.001 · 09 g, 0.001-0.5 g per gram of crude oil product. In the range. /

In some specific examples, the crude oil product has a total Ni / V / Fe content of up to 90%, at most 50%, at most 10%, at most 5%, or at most 3% of the Ni / v / Fe content of the crude feed. . In some specific examples, the crude oil product comprises at most 0.0001 g, at most i x 10.5 g, or at most 1 x 100.6 g of Ni / V / Fe per gram of crude product. In some specific examples, the crude oil product has χ 10.7 to 5 x 10-5 g, 3 x 107 g to 2 x 105 g, or 1 x 10-6 g per gram of crude product. The total Qin content in the range from i χ 10 to 5 grams. In some specific examples, the crude product has a TAN of at most 90%, at most 50%, or at most 10% of the crude feed tan. In certain specific examples, the crude oil product may have a TAN of at most 丨, at most 5, at most 〇, or at most 0.05. In some specific examples, ταν of the crude product may be in a range of 0.001 to 0.5, 0.01 to 02, or 0.05 to 0.001. In some specific examples, the API specific gravity of the crude product is at least 10%, at least 50%, or at least 90% greater than the ApI specific gravity of the crude feed. In some specific examples, the API gravity of crude oil products is between 3-50, 1 5-30, or 16-20. 61 200535229 In some specific examples, the content of the child is at most 70% and at most. In some specific examples, the content is at least 10%, at least the amount. Crude oil products have a total heteroatom content of 50% or up to 30% of the total heteroatom crude oil feed. Crude oil products have a total heteroatom content of 40% or at least 60% of the total heteroatom crude oil feed. The sulfur content of crude oil feeds is up to 9q%, up to 70% or up to 60%. Shield Zhanke from ^ 『Claw 3. The sulfur content of the crude oil product may be up to 0.02 apricot, 5 mg, at most 008 g, at most 0.05 g, at most 0.05 g per gram of crude product, and at most 3 per gram of crude product. Grams or at most ㈣i grams. In some specific examples, the crude oil product has a sulfur content in the range of 0.005 gram or 0.005 to 0.01 gram per gram of crude oil product. In some specific examples, the crude product may have a nitrogen content of up to 90% or up to 80% of the crude feed gas content. The nitrogen content of the crude product may be at most g, at most gq () 3 g, or at most 0 · g, based on one gram of crude product. In some specific examples, the crude oil product has a nitrogen content in the range of 0.0001 to 0.005 grams or 0.0001 grams per gram of crude oil products. In some specific examples, the crude product contains 0.05-0.2 grams or 0.09-0.15 grams of hydrogen per gram of crude product. The H / c of the crude product may be at most 1.8, at most 1.7, at most L6, at most 1.5 or at most 14. In some specific examples, the H / C of the crude product is 8 (M20% or 90-110% of the crude feed H / c. In other specific examples, the H / c of the crude product is the crude feed H / C 100-120% of the crude oil product H / C within 20% of the crude oil feed H / c means that the absorption and / or consumption of hydrogen in this procedure is a minimum of 62 200535229. Crude oil products contain a range of boiling points In some specific examples, the crude oil product contains: at least 0.001 grams or from 0.0001 to 0.5 grams at a boiling range distribution of at most 200 at 0-101 MPa. (: Or at least 204 fe, at least 0.001 grams or from 0.001 to 0.5 grams of hydrocarbons with a boiling range between 200 ° C and 300 ° C at 001 MPa; at least 0.001 g or from 0.001 to 0.5 g The boiling range at o.ioi MPa is distributed between 300 ° C and 400. (: hydrocarbons between: and at least 0.001 g or from 100,000 to

The boiling range of 0.5 g at 400 MPa was distributed at 400 c and 538. Hydrocarbons between plutonium.

In some specific examples, the crude oil product has a light oil content of 0.00001-0.2 grams, 0.0001-cm grams, or 0.0001 · 0.05 grams per gram of crude oil products. In some specific examples, the crude oil products contain 〇〇1_〇2 grams or 〇 丨 4 'grams of light oil. In some specific examples, the light oil system contains at most 0.15 g, at most (M g or at most 0.05 g of olefins per gram of light oil.) In some specific examples, the crude oil product contains 0 per gram of crude oil product. 〇〇〇ι_〇ΐ 5 grams 0. 0001-0.1 grams <0. 001_0 05 grams of dilute hydrocarbons. In some specific examples, the light oil system has at most G.G 1 gram per gram of light oil, at most 5 grams or 0 Content of benzene. In some specific examples, light oil has the ability to detect 5 1 χ 10 7 grams to 1 χ 10 · 2 grams, 1 x valence 6 grams to 1 X 10-5 grams: χ 1〇 &quot; grams Benzene content in the range of 1 × 10 ′ gram. Composition containing benzene ”: It is considered to be a hazardous person in processing, so crude oil with a relatively low benzene content may not require special treatment.“ &Gt; In some specific examples The light oil may contain aromatic compounds. Aromatic &gt; 63 200535229: The compounds may include early cyclic compounds and / or polycyclic cyclic compounds. The bad compounds may include, but are not limited to, stupid, toluene, ortho-benzene. , P-xylene, ethylbenzene, i-ethylmbenzene, m-xylylene, &quot;, such as 1 τ basic, ethyl ethyl heptylbenzyl; 1 its trimethylbenzene; 1, 3, 5 -Trimethylbenzene; 1-methyl_3_propylbenzyl; propyl Ipropylbenzene; 2 · ethyl], 4-dimethylbenzene on ethyl_2, xin ·, 2, μ_ Tetramethylbenzene; Ethyl, Pentylmethylbenzene; U3: Ethylbis-tetramethylbenzene; Triisopropyl-o-xylene; Benzene, toluene, o-dione, Yada, Komoto, Makamoto , Substituted homologues of p-phenylene or mixtures thereof.

Private compounds are used in a variety of commercially available products and / or sold separately. Crude products made as described herein typically have an increased monoaromatic content. Clothing

In some specific examples, the crude oil product has a methylbenzyl content of 0.001 to 0.2 g, 0.05 to 0.15 g, or 0.01 to 0.01 g per gram of crude product. The original product product has a content of m-xylene at 0.05-0.08 g per gram of crude oil product; 0.005 g, 0.05-0.09 g. Crude oil products are 0.001-0.2 grams, 0.005-0 "grams or 〇_〇1_〇 05 grams of o-xylene per gram of crude product:!. The crude oil product has a content of 0.005-0.08 g or 0.001-0.06 g per gram of crude oil product per gram of crude oil product. ~ Light>, the increase in the content of aromatic compounds tends to increase the octane number of the light oil. Crude oil can be evaluated based on an estimate of the crude's gasoline potential. Gasoline potential may include, but is not limited to, the calculated octane number two crude oil for the light oil portion of crude oil, which typically has a calculated octane number in the range of 35-60. The octane number of gasoline tends to decrease the additive 嶋 for increasing the scorch value of gasoline. In certain specific examples, the crude product comprises light oil having a scorch value of at least 60, at least 70, at least 80 64 200535229, and at least 90. Typically at 6. "," Or, within the range of 95. t⑨ In the specific example, 'total light oil and kerosene ::: aromatics compared to crude oil feed. The content of group compounds' crude oil products are distributed in the boiling range of 204. Hydrocarbons (total "light oil and kerosene,") have a higher content; Ge :, compound content, and higher than at least 5%, at least 10%, at least 50. Typically, the total light oil in crude oil products Total with kerosene

Into: The content of It is lower than the total aromatics of total light oil and kerosene in crude oil feed. 3: Outflow 8%, 20%, 75% or exhaust. Within ", ..GGG1_G.2 grams" Please HI grams range

ο.οοι ^ ί system has a quantity of 0.0001-0.9 g per gram of crude oil product. In the specific example, the weight ratio of kerosene to diesel in the distillate is between-so far 4: 1, 1: 3 to 3: In the range of 1 or 2: 5 to 5 ... 2. Less than 0.001: In the specific example, the 'crude oil product' contains gram of kerosene per gram of crude oil product to G · 7 grams or more, which is 1-. ^ G or. .. 1-〇_1 or 0.H. In certain embodiments, the 'crude oil product contains 0.00 g of oil having an paleokerosene of at least 02. In some specific examples, the kerosene content is per gram of coal. In ".1, at least 0.3 grams or at least 0.4 grams of aromatic compounds, or from. = You Guangzhong, kerosene has an aromatic compound per gram of kerosene in the range of from 5 · 2-0.4 grams Content. In some specific examples, the freezing point of kerosene can be below -30% ... 65 200535229 below 40 ° C or below -50. Increasing the content of the material tends to increase the low freezing point. The kerosene part can be refined. In order to produce the desired high-density machine fuel. The aromatic compound of the crude oil product kerosene part has the density of the kerosene part of the crude oil product, and the high-density and low-freezing point crude oil yield and low-freezing point properties of the aviation turbine are shielded in some specific examples. : ^ JT crude oil product is 0.001-0.8 grams per gram of crude oil product

.υΐ_〇.4 grams of diesel content within the target range. In a 4b S-body example, diesel oil is one for every year ... 丨 Dinggan Xiongmu oil has at least 0 ″ g, at least 0 ″

Or to the compound content of v 0.5 {. In some specific examples, the oil system has a square compound content per gram of diesel oil within 0.3 g, 0.3-U g, or 0.2-0.5 g.

In some specific examples, the crude oil product has a VGO content ranging from 0.0001 to 0.99 grams, from 0.001 to 0.8 grams, or from 0.01 to 0.3 grams per gram of crude product. In some specific examples, the vg0 content in the crude product is in the range of 0.4-0.9 g or 0.6-0.8 g per gram of crude product. In some specific examples, the VGO line has an aromatic compound content per gram of VG0 in the range of 0-1-99 g, 0.3-0.8 g, or 0.5-0.6 g. In some specific examples, the crude oil product has a residue content of up to 70/6, up to 50%, up to 30%, up to 10%, or up to 70% of the crude feed.纟 In some specific examples, the crude oil product is per gram of crude oil product and has at most (Mg, at most 0.05g, at most 0.003g, at most 002g, at most 0.01g, at most 0.005g or at most Residue content of 0 001 grams. In some specific examples, the crude oil product has between 0.000001-0.1 grams, _01_0 〇5 grams, 0.00001 grams, or 〇-66 200535229 per gram crude oil products. Residue content in the range of 0 g. In some specific examples, the crude oil product may contain at least a part of the heterogeneous media. In a contact 7 j, such as a mountain, the crude oil product contains greater than 0 per gram of crude oil product. Grams but less than 0 Π 1 ± Λ 3 large, · 000001-0 · 001 grams or 0.00001-0 00 (η grams of the catalyst. The catalyst can be used during the continuous delivery of the wheel and / or during processing in the processing facility Stable crude oil products. The catalyst π 彡 helps some to inhibit corrosion, friction and / or increase the water separation ability of the product. The crude oil product containing at least a portion of the catalyst can be further processed by τ to produce lubricants and / Or other commercially available products.

The catalyst used to process the crude oil feed in the presence of a hydrogen source to make the finished product can be a single catalyst, Gordon Chain &gt; + We are a second-line catalyst. The catalyst used in this application may be a catalyst precursor ′ which is converted into a catalyst in a contact zone when hydrogen and / or sulfur-containing crude oil is fed to the catalyst precursor 4 ′. The contact used to contact the crude feed with a hydrogen source to make a complete product helps reduce the molecular weight of the crude feed. Without wishing to be bound by theory, the combination of the catalyst and the chlorine source can be reduced in the crude oil feed through alkaline components (Louis base or Brewster's Rory's base ;, or: Molecule

alas. Examples of catalysts that may have a Lewis base and / or a Bronister-Rory basic include the catalysts described herein. In some specific examples, the catalyst is a TMS catalyst. The TMs catalyst contains a compound containing a transition metal sulfide. For this application, the weight of the 'transition metal sulfide in the TMS catalyst is determined by adding the total weight of the metal to the total sulfur in the catalyst. The atomic ratio of the transition metal to sulfur is usually in the range of 0.2-20, 0.5-10, or 1-5. Examples of transitions to sulfides can be found in "Inorganic Sulfur chemistry" edited by G. Nickless; "Inorganic Sulfur chemistry"; Elsevier Publishing

Company? Amsterdam — London — New York * Copyright 1 968) Chapter 19. In some specific examples, the TMS catalyst system may include a total of at least 0.4 g, at least 0.5 g, at least 0.8 g, or at least 0.99 g of one or more transition metal sulfides per gram of catalyst. In some specific examples, the TMS catalyst has one or more transitions per gram of catalyst in the range of 0.4_0.0999 g, 0.5_0.9 g, or 0.6_0.8 g. Total metal sulfide content.

TMS catalysts contain one or more transition metal sulfides. Examples of transition metal sulfides include: nickel pyrite (Fe45Ni45S8), pyrite (^ 6 75 commits 2.25811), galvanite (with ..7 state 0.2 (: 0〇.182), Sifang melon Tieguang (Fe〇75N10.25S0.9), silver nickel pyrite (AgFe6Ni2S8), isometric Cuban shiguang (CuFe2S3), isometric chalcopyrite, scintillation (Zn0.95Fe〇05S), brown Pyrite, Canthite, Pyrite (Cu6FeSn2S8), Pyrite (Yatani), Chalcopyrite (,

P member pyrite), yellow _ (sound), pyrrhotite (Fe (1.x) S (x = 0 to θ · 1 7)), Hethionite Office ("Guangdong (Ni3S2) or square sulfur Nickel ore (NiS2). In some specific examples, the TMS catalyst comprises one or more transition metal stone melon compounds that are combined with alkali metals, earth test metals, chains, forces &amp; In this example, the TMS catalyst is represented by the general chemical formula Ac [MflS 丄, where the force in the formula is also given by ## I. Deng Zi, "Represents alkali metals, Alkaline earth metal or zinc; M table is not selected from Zhou Peng table. The atomic ratio of 6.10W is in the range of .5 to two genera: ... is sulfur. 1 ^ θ • or to 2. Atoms of c to β The ratio is in the range of 0.0001 to i, • 1 to 0.8, or 0.3 to 0.5. 68 200535229 In some specific examples, the transition metal is iron. In some specific examples, the ™ s catalyst may Contains commonly known metal test and / or alkaline earth metal / transition metal sulfides (such as limonite (K3FelcS14), potassium pyrite (K3FelcS14), iron pyrite (K6NaFe19Cu4NiS26Cl), chloro brown pyrite (K6.iFe24Cu. 2S26 / 1.7) and / or ferrite (NaFe3S5. (H2O) 2). In some specific examples, the 'TMS' contains a limonite bellsite. The limonite potassium ore prepared on the spot It can be referred to as a manganese brown iron ore. Natural and / or artificial limonite can be used as a TMS catalyst in the methods described herein. In some specific examples, the TMS media is per gallium. 8 Catalysts can contain up to 25 grams, up to 15 grams, or at most 1 gram of carrier material. Typical 1L and 5 'TMS catalysts contain 0 to grams, 0.00' to 20 grams per 100 grams of TMS catalyst, 0.0001 to 10 grams of carrier material. Examples of carrier materials that can be used with TMS catalysts include refractory oxides, porous carbons, or mixtures thereof. In some specific examples, the catalysts It is essentially free of or without a carrier material.% Earth metals, zinc, zinc compounds, or mixtures thereof. MS catalysts may contain &amp; evening transition metal sulfides, bimetal bases, transition metal sulfides, black # 、 M 、 Luo Bayuan would like to use transition metal sulfide, transition metal oxygen, or their mixtures, such as γ plus. # 纯 4 丄 1 more X-ray diffraction Measured by TMS-part of alkali metal component, soil metal component, zinc component and / or a transition metal sulfide component, in some specific examples, it is detected by X-ray diffraction technology The measured amorphous group exists. 69 200535229 In some specific examples, the grains of the TMS catalyst and / or the tms catalyst, the mixture of grains has at most 1 A, at most 103 A, at most 、 A, or at most 40 The particle size of A. In general practice, the particle size of TMS catalyst grains is usually at least 10 people. TMS catalysts containing alkali metals, alkaline earth metals, zinc, zinc compounds, or mixtures thereof can be obtained by passing a sufficient amount of deionized water, a required amount of transition metal oxide, and a required amount of 1-2th metal carbonate, Columns 1-2 are prepared by mixing metal grass salt, 1-2 metal acetate, zinc carbonate, zinc acetate, and oxalic acid to form a wet paste. The wet paste can be dried at a temperature of 100-300 ° C or 150-250 ° C to form a transition metal oxide / salt mixture. The transition metal oxide / salt mixture can be calcined at a temperature ranging from 300 ° C, 500-800 ° C, or 600-700 ° C to form a transition metal oxide metal salt mixture. The transition metal oxide metal salt mixture can react with hydrogen to form a reduced intermediate solid. The hydrogen can be added at a flow rate sufficient to provide excess hydrogen to the transition metal oxide metal salt mixture. Hydrogen can be added to the transition metal oxide metal salt mixture over a period of 10-50 hours or 20-40 hours to produce a reduced intermediate solid that contains the elemental transition metal. Hydrogen addition can be performed at a temperature of 35-500 0C, 50-400 ° C, or 100-3300 ° C and a total pressure of 10-15 MPa, 11-14 MPa, or 12-13 MPa. It should be understood that the reduction time, reaction temperature, selection of the reducing gas, the pressure of the reducing gas, and / or the flow rate of the reducing gas used to prepare the intermediate solid are usually changed relative to the absolute mass of the transition metal oxide selected . In some embodiments, the reduced intermediate solids can be passed through a 40-mesh screen with minimal force. 70 200535229 Rate = Γ Interstitial solids can control heat release and gas production 22: Add to hot (example 1C) diluent / elemental sulfur and / 8; ... compound mixture. The diluent may include any suitable diluent provided. The diluent may include a boiling range of c to 150 ° C, less than 2000 c, or at least then. . Solvent. Generally, the diluent has a boiling range distribution between 100-50 "c, 15 (m00c or Γ 200 v :. In some specific examples, the diluent 疋 GO and / or xylene. Sulfur compounds include but Not limited to: vulcanization

Such as pentane, heptane or hexane) to obtain TMS catalyst. This TMS catalyst can be powdered using standard technology. In some cases, the catalyst is an inorganic salt catalyst. The anion of the inorganic salt catalyst includes an inorganic compound, an organic compound, or a mixture thereof. Inorganic lice and / or thiols. The amount of sulfur and / or sulfur compounds is based on the mole number of the metal or zinc in column i-2 of the &quot; metal salt or zinc salt, and it can range from 1-100 mole%, 2, mole %, 5500 mole% L mole%: After adding the reduced intermediate solids to the diluent / elemental sulfur mixture, the resulting mixture can be heated to 2000-500C, 2 cuts incrementally _45 () π or 300-400. (: Final temperature, and maintained at this final temperature for at least 1 hour, to 2 hours or at least 10 hours. Typically, the final temperature is maintained for 15 hours, 10 hours, 5 hours or 15 hours. After heating to liters After a high vulcanization reaction temperature, the diluent / catalyst mixture can be cooled to a temperature in the range of (MOO C, 30-90 ° c or 50-80 0c) to help recover the catalyst from the mixture. An oxygen-free atmosphere towel separates the sulfur catalyst from the diluent, and then uses at least a portion of a low boiling point solvent (Example 71 200535229). Salt catalysts include metal carbonate, metal hydroxide, metal hydride, and alkali metal acid. Amine, metal sulfide, metal acetate, alkali metal oxalate, alkali metal formate, alkali metal pyruvate, alkaline earth metal carbonate, earth metal hydroxide, earth metal hydride, earth test Metal amines, alkaline earth metal sulfides, alkaline earth metal acetates, alkaline earth metal oxalates, alkaline earth metal phosphonates, earth test metal pyruvates, or mixtures thereof. Inorganic salt catalysts include, but are not limited to, the following Compounds: NaOH / RbOH / CsOH; KOH / RbOH / CsOH; NaOH / KOH / RbOH; NaOH / KOH / CsOH; K2C03 / Rb2C03 / Cs2C03; Na20 / K20 / K2C03; NaHC03 / KHC03 / Rb2C03; LiHC03 / KR ; Mix with K2C03 / Rb2C03 / Cs2C03 KOH / RbOH / CsOH; K2C03 / CaC03; K2C03 / MgC03; Cs2C03 / CaC〇3; Cs2C03 / Ca0; Na2C03 / Ca (0H) 2; KH / CsCCH0; KOCHO / CaC03; CsOCHO / Ca (OCHO) 2; NaNH2 / K2C03 / Rb20; K2C03 / CaC03 / Rb2C03; K2C03 / CaC03 / Cs2C03; K2C03 / MgC03 / Rb2C03; K2C03 / MgC03 / Cs2C03 or a mixture with K2C03 / MgC03 / Cs2C03; Ca (OH) 2. In some specific examples, the inorganic salt catalyst contains at most 0.00001 grams, at most 0.001 grams, or at most 0.001 grams of lithium per gram of inorganic salt catalyst, which is calculated based on the weight of lithium. In some In a specific example, the inorganic salt catalyst contains lithium from 0 g but less than 0.01 g, · 0000001-0_001 g, or 0.00001-0.0001 g per gram of inorganic salt catalyst, which is calculated based on the weight of lithium. In some specific In an example, the inorganic salt catalyst includes one or more metal test salts that contain at least u of the original 200535229 subsequence. In some specific examples, when the inorganic salt catalyst contains two or more alkali metals, the atomic ratio of the alkali metal having an atomic order of at least ii to the alkali metal having an atomic order greater than 11 is between 0 and 10 and between 0.2 and 2 6 or 0 .... For example, inorganic salt catalysts can include sodium, potassium, and gamma salts, where the ratio of sodium to bell is in the range of 01_6; the ratio of sodium to europium is in the range of 0.1-6; and the ratio of potassium to europium Is in the range of (M-6. In another embodiment, the inorganic salt catalyst includes sodium salt and potassium salt, wherein the atomic ratio of sodium to unloading is in the range of 0 to 4. In some specific examples In addition, the inorganic salt catalyst also includes a metal selected from the eighth to tenth periodic table, a compound selected from the eighth to tenth periodic table, a metal selected from the sixth column of the periodic table, and a sixth selected from the sixth table of the periodic table. Metal compounds or mixtures thereof. Metals selected from the 8th to 10th include but are not limited to: iron, nails, nickel or nickel. Metals selected from the 6th include but are not limited to: metal, turn or crane. In- In some specific examples, the inorganic salt catalyst contains 0.1-0.5 g or 0.2-0.4 g of Raney nickel per gram of inorganic salt catalyst. In some specific examples, the inorganic salt catalyst Also included are metal oxides selected from Blocks 1-2 and / or 13 of the Periodic Table. Metals selected from Block 13 include but are not limited to: Shi Peng or Shao. Metal Oxidation Non-limiting examples include bell oxide (L12), potassium oxide (K2), and oxidized aluminum (Al2O3). In some specific examples, the inorganic salt catalyst is a Lewis acid (for example, tons, ㈣ and S03), cloth tolerance two (such as H30, h2s〇4, Ηα and hn〇3), gas-forming compositions such as borate and oxalate, and osmium. Inorganic salts are inorganic salt catalysts per gram 73 200535229 May contain: from 0 g to (M g, 0.001-001.00 g or 0.0000 g): a) a chemical compound; b) at least 35,000 c or at most A composition that forms a gas at a temperature of 0.000C; c) a Lewis acid; or e) a mixture thereof. Osmic acid; inorganic salt catalysts can be prepared using standard techniques. For example, standard mixing techniques (such as grinding and / or comminution) combine the required quantities of contact material. In other specific examples, the composition is dissolved in a solvent (such as water or a suitable organic solvent) to form an inorganic composition / solvent mixture. Solvents can be removed using standard separation techniques to produce inorganic salt catalysts. . In the example of r Γ Γ, the inorganic salt of the inorganic salt catalyst can be incorporated into the carrier and the center is formed on the carrier. The examples of the solitary catalyst carrier include, but not limited to, chemical errors and oxygen peaks. Magnesium oxide, titanium oxide, hydrotalcite, oxidized oxide, oxidized oxide, zinc oxide, zinc oxide, oxidized oxide, oxidized oxide and the like. In some specific examples, —and / or the 6th-10th of the genus of the genus ”, the brother 6_10 櫊 metal 1 genus compounds are immersed in the carrier. Alternatively, the inorganic salt can be dazzled or taught with heat # * Body ... / "metal carrier or metal oxide on 5 to form an inorganic salt catalyst on the carrier. ^ The structure of the catalyst will usually become uneven, permeable and / or susceptible to temperature within the preset temperature or the temperature range where the contact is lost. Inorganic salt catalysts can become surplus (for example, there is no tangible ^^ substantive change in contact, and she 1 does not want to be bound by theory, Xianxin Inorganic salt snails in the inorganic salt contact welding said. Preface ( Can be sidelined) a, said. Yu (when the distance increases, it becomes useless ...) § Increased ionic distance 'crude oil feed and / or hydrogen source can pass / permeate rather than across the surface of the inorganic salt catalyst. Crude oil feed 74 200535229 Infiltration of raw materials and / or nitrogen sources through inorganic salts often results in an increase in the contact area between the inorganic salt catalyst and the crude oil feed and / or hydrogen source. The contact area and / or active area of the inorganic salt catalyst Increasing can generally increase the yield of crude oil products, the production of positive scum and / or coke, and / or promote changes in properties of crude oil products compared to the same properties of crude oil feeds. Disorders of inorganic salt catalysts (such as unevenness) (Sentence, permeability, and / or migration) can be measured using DSC method, ion conductivity measurement method, TAP 丨, visual, line diffraction method, or a combination thereof.

The method of using TAP to determine catalyst properties is described in the following US patents: 4,626,412 to Eb⑽ et al .; 5,039,489 to Luzhou et al .; and 5,264,183 to Ebner et al. The ΤΑρ system is available from Mlthra Technology (Foley, Missun, u s a b,

W analysis is available at 25-850. 〇, 50-500. It was performed at a temperature of 60-400 ° C: within a temperature range of 1G-5G ° C or 2G. 4G ° C and a vacuum in the range of 1 × 3 to i × 3 Torr. The temperature can be maintained and / or increased as a function of time. As the temperature of the inorganic salt catalyst increases, the gas emitted by the inorganic salt catalyst is measured. The gas emitted by the inorganic salt catalyst # Examples include carbon monoxide, carbon dioxide, A , Water, or a mixture thereof. Debt: to the turning point (a sharp increase) in the release of inorganic salt catalyst gas @ temperature is considered to be the temperature at which the inorganic salt catalyst becomes disordered. In a specific example, the inorganic salt catalyst is discharged. ..... ~ Solitary ... J Cup 仞 布 山 月 豆 in the range of temperature Nebo ,, head 丨 丨, 丄 · ~~ 11 shells /, as measured by TAP. The temperature in this temperature range is called It is "TAP ,, 谇 ,, from the buckle .... r, the degree of dish. The starting temperature of the temperature production measured using TAP is called the" minimum TAP temperature ". Another 75 200535229 is the inorganic contact with the crude oil feed. The turning point of the exhaust gas displayed by the salt catalyst is 100-600, 200 π I ι

”0 0 0 00 or 300-400 ° C within the TAP / dish degree. Typically, the TAP temperature is in the range of 300-500 X. In some specific examples, different compositions of suitable inorganic salt catalysts also exhibit gas turning points, but at different tap temperatures. 2 The size of the ionization turning point related to the exhaust gas can be an indicator of the order of the particles in the crystal structure. In the highly ordered θ carving at P + a, in the ordered solar-solar structure, the ionic particles are tightly associated with each other, so they are separated; 8: 7 1 release of a child, a knife, a gas, or a combination thereof The stage t θ γ that needs f capacity, that is, more heat). In the disordered ions, the ions are not associated with ions as low as those in the highly ordered crystal structure, so the release of ions, molecules and / or air flyholes from the disordered crystal structure is required. Less energy, and therefore, at the selected temperature, the ions and / or gases released from the beneficial bed s dan #, #, 肢, 构, 肢, 构 and 肢 are greater than the height of the shore. Sequences of ions and / or gases released by the sundial structure ° In some specific examples,

aa,, Τ field uses differential scanning calorimetry at a heating rate or cooling rate of 100 ° C — the scallops can be sacrificed to the range of 50 to 500 π, and can be sacrificed to the inorganic salt catalyst. — 、、 ”/ _. In Efa, the sample can be added to: 丄: cooled to room temperature, and then heated again-times. The transformation observed in the first time…, ^ ^ ^ Ai and Dang represent the water and / or solvent entrained, and may not represent dissociation or waterman's exposing. ',,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 4, κ, σ, σ, σ When the reading is between Λ and 以下, below 250 ° C, the typical transformation is reported to the machine σ "p% and the observed heating during the second heating period, and Qitian dissipates the heat of the sample. 76 200535229 "Thermal transition" refers to the process of orderly molecules and / or filaments in a t-structure when the temperature increases during the DSC analysis of a thin door, and when the temperature increases, ^^ &gt; . "Cold = shore means that during the analysis of a

If and / or atoms become more homogeneous. In the case of political and ugly cases, τ, the inorganic salt catalyst appears within the heat / -range temperature. The temperature or temperature range of the heat transfer detected in Dsc using Dsc is called “E,” and the lowest Dsc temperature in the D :: ㈣ temperature range is called “Max.”. Inorganic salt catalysts can exhibit thermal transitions within a depletion range between 2000-5 () () Cp ... 50 or 300-400 ° C. In the inorganic salt containing the benefits of a fairly homogeneous mixture # / 11 ^ A…, 钺 1 particles, "the absorption is narrow during the second: human heating cycle. In Hegukou, this is relatively narrow. When the mixture is uneven, In the catalyst of inorganic salt particles, it is possible that the sharp bee with the heat absorbed during the 1 Lu thermal cycle of the salt salt contactor 1 of the Ming Sheng-ALI Ding J. See the DSC chart. There is a sharp peak range. No heat is absorbed or released inside. No heat :: &gt; The dish will not change when heated.… Indicates the sample structure ® uniformity of particles in the inorganic salt mixture, said period ## jg _ S 17, the mixture in The ability to heat f, select solids and / or semi-liquids is uniform under the &amp; &amp;, Japanese ^ g unbranched mixture of moon daggers and cation ions in the compound halves of small ions ^ As far as the% ions are concerned, the cation and electron dense skin ^ ^ ions share XW. This force increases, so the corresponding anion column is similar to the two / MM 7 W ^ increase. For a Li Xi h member like electricity What kind of ions are t, if the anion ions are produced by the quasi Hard bases are smaller than 1000 k — causing gravitational attraction between deionized and anionic ions 77 200535229. Higher inter-ionic attraction tends to lead to higher temperature of the salt and / or More homogeneous particle mixture (sharper: increased area under the DSC curve). Mixtures containing small ions separated by two degrees ° tend to be more acidic than cations with large ionic radius, = acidity of inorganic salt mixtures with cations The radius decreases and increases. For example, the contact between the crude oil feed and the hydrogen source in an inorganic mixture containing a bell cation is more important than the contact between the crude feed and the hydrogen source in a cation that contains half an ion larger than lithium. Contacts in the presence of inorganic salt catalysts tend to produce increased amounts

Gas and / or coke. Ability to inhibit gas and / or coke production; plus: total liquid product yield of the program. θ ^

In some specific examples, the inorganic salt catalyst may include two or more organic salts. The minimum DSC temperature of each inorganic salt can be extracted. The small DSC temperature of the inorganic salt ㈣ can be below the minimum DSC temperature of at least one of the inorganic metal salts in the inorganic salt catalyst. For example, the inorganic salt catalyst may include potassium carbonate and cesium carbonate. Potassium carbonate and carbonate shavings exhibit temperatures greater than 500 Y. The K2C03 / Rb2C03 / Cs2C03 catalyst exhibited a DSC temperature in the range of 29-30%. In some specific examples, the 'TAP temperature may be between the DSC temperature of at least one of the inorganic salts and the DS (: temperature of the inorganic salt catalyst. For example, the TAP temperature of the inorganic salt catalyst may be 35 ° _ The DSC temperature of the same inorganic salt catalyst can be in the range of 300,000, and the DSC temperature of individual salts can be at least 50000c or at most 500,000. In many In a specific example, it has a TAP and / or DSC temperature of 150.50 or between and will not be separated from i at the temperature of 78 200535229. The ",", organic salt catalyst can be used to catalyze High molecular weight and / or

The effect of converting still-viscosity components (such as Jiu X ^ ^ crude oil feed) into liquid products. In some specific cases with residual temperature of 350-450 γ, the inorganic salt catalyst 1 exhibited during heating of the inorganic salt catalyst at 2000-600 ° C, 300 · 500% or IX. Compared with copper, the electrical conductivity is increased by 1 Δ θ ..., and the organic salt is increased electrical conductivity. Inorganic salt catalysts and Wei Wei are caused by particles in the inorganic salt catalyst. The temperature at which the ionic conductivity of the seven-catalyst changes is higher than that of the inorganic salt in contact welding.的 The temperature at which the ionic conductivity of a component changes in the early morning. The ionic conductivity of an inorganic salt of ICna can be determined by Ohm's law, where F is the voltage, 7 7 疋 current, and 7 是 is the resistance. To measure the ion conductivity, the machine M ^ ^ M ^ ^ was placed in a quartz container equipped with two metal wires (such as copper wires or name wires) separated from each other but immersed in the non-catalyst. Figure 7 shows a system that can be used to measure ionic conductivity. The quartz of sample 158 is shown in Figure 156. . 56 placed in a heating device and gradually increase the temperature to: the desired temperature. During the heating period, a voltage from the power source 16 was applied: the entire current passed through the metal wire 162 # 164 and in the meter 166. The meter 166 may be (but is not limited to) a multimeter or (Wheatstone bndpe, advanced waste, bndge) § The sample 158 becomes more non-uniform (more transferable) without decomposition, and the resistance of the sample should be reduced. The observed current should be increase. Meter In some specific examples, ‘at a desired temperature, the inorganic salt catalyst may have different ionic conductivity after adding 卞 / 7 and then heating’. The difference in ionic conductivity can indicate that the crystal structure of the inorganic salt catalyst has changed from its original shape (the first state) during heating. After heating, if the two "become different shapes (second form * fruit inorganic salt contact; report energy / chemical, it is expected that the ionic conductivity is similar or the same ^ ,. σ ... has not changed in some specific examples during the month , Helmet machine _ claws 500 microns or 50 · 100 microns H, there are] 〇 _] _ microns, organic salt catalyst particle size measured through a net or sieve 'if the inorganic salt-free The medium may be softened when it is heated to 50 °. When inorganic or more than 500 ° C is used, inorganic or inorganic catalyst particles can be used in the inorganic salt catalyst matrix or at least please At the temperature, under the pressure of 0 · 101 MPa, = make money salt _ from the first material to the second ^ = cooling to 2 &quot;, the second form of inorganic salt catalyst cannot = = The first form. The temperature at which the inorganic salt changes from the first form to the second form is called "deformation, temperature. The deformation temperature can be a temperature range or a temperature earlier. In some specific examples, the inorganic salt catalyst particles are Deformation temperature added below the deformation temperature of any inorganic metal salt Self-deformation under pressure. In some specific examples, the inorganic salt catalyst includes two or more inorganic salts with different deformation temperatures. In some specific examples, the deformation temperature of the inorganic salt catalyst and individual inorganic metal salts The deformation temperature is different. ^ In some specific examples, the inorganic salt catalyst is liquid and / or semi-liquid at TAp and / or DSC temperature or above. In some specific examples, the inorganic salt catalyst is at the minimum TAP and / Liquid or semi-liquid at DSC temperature. At 80 200535229 the minimum TAP and / or DSC temperature is above κ ^ above, in some specific examples, liquid or semi-liquid mixed with crude oil feeds> dry plate inorganic salt The catalyst will form a phase separated from the crude oil feed. In this case, in the case of bulk sound, the liquid or semi-liquid inorganic salt catalyst is used in crude oil at the minimum TAp temperature. Low solubility in feed (for example, mother gram crude feed from 0 g to 05 years old, q see 〇__1 · 〇 · 2 gram or 〇 · _Κ 〇1 gram of inorganic salt catalyst) or Liu Fei 疋Not compatible with crude oil feed (for example from 0 grams to 0 per gram of house oil feed. 05 grams, 〇〇〇〇〇〇〇,

0,01 grams or 0.00001-0 00J grams of inorganic salt catalyst). In some specific examples, it is reported that the distance between atoms in the organic salt catalyst is determined by the method of tertiary terminal diffraction. In J, the shape of the DOG1 peak in the χ-ray spectrum can be used to estimate the phase of the inorganic salt particles. The spikes in X-ray diffraction represent different compounds of inorganic salt catalysts. In X-ray diffraction at the end of the week, the DGG] peak can be monitored and the atomic interval can be estimated. In a highly ordered ... L-shaped inorganic salt catalyst towel &apos; D. "The shape is quite narrow. In inorganic salt catalysts (such as ^ VRb2C03 / Cs2C03 catalysts) containing inorganic salt atoms in random order, the shape of u may be equivalent, and the peaks of '~ 1 may not exist. In order to determine whether the disorder of the M inorganic salt atom changes during heating, Α τ takes the X-ray diffraction pattern of the inorganic salt catalyst before heating, and obtains the X-ray diffraction pattern at 5 ° C or higher after heating. In the obtained 1-line diffraction pattern, the D_ front C corresponds to the inorganic salt atom) may not exist 001, 7 卞 ″ ”, or it is more than the χ_ray diffraction pattern obtained below 50γ / degrees, which is- ~ Σί ^ η said r 峄 wide. In addition, the X-ray diffraction pattern of individual ... organic salts exhibits a relatively narrow DG (n peak at similar temperatures at the same temperature. 81 200535229 = In addition to limiting and / or inhibiting the generation of by-products, the contact can be controlled The article allows the whole product composition (ie, the crude product) to be changed for a given crude oil feed. The complete product composition includes, but is not limited to, paraffins, dilute hydrocarbons: aromatic compounds, or mixtures thereof. These compounds constitute crude oil: And non-condensable flue gas composition.-Controlled contact conditions combined with the catalysts described herein can produce complete products with lower coke content than expected. Comparing the MCR content of various crude oils allows crude oils to form coke based on them. For example ,: = 0.1 g of crude oil with an MCRi MCR content per gram of crude oil is expected to be more annoying than crude oil with an oil content of 0.001 g MCR ^ MCR content. Inferior grade Crude oil generally has an MCR content of at least 0_05 grams of MCR per gram of inferior crude oil. In some specific examples, the residue content and / or coke content deposited on the catalyst during the reaction may be up to 0.1 g, up to 0 per gram of catalyst. 05 grams or up to 0.03 grams of residue and / or coke. In some specific examples, the weight of the residue and / or coke deposited on the catalyst is between 0.001 ... gram, 0.001-0.05 Gram or 0.003 gram. In some specific examples, the used catalyst is substantially free of residues and / or coke. In some specific examples, the contact conditions are controlled such that each gram of crude oil The product has a coke formation of up to 0.015 g, up to 0.01 g, up to 0.005 g or up to 0.003 g. Contacting the crude feed with the catalyst under controlled conditions, as opposed to refining the catalyst by using the same contact conditions The amount of coke and / or residue produced by heating crude oil feed in the presence or absence of catalyst is to produce a reduced amount of coke and / or residue> 82 200535229 In some specific examples, the contact conditions can be controlled such that Crude oil feeds of at least 0.5 grams, at least G.7 grams, at least G8 grams, or at least ㈣ grams per gram of crude oil feed are converted to crude oil products. Typically, each gram of crude oil feed # 0.5- Crude oil production between 0.99 g, "M g" or 0.7 g Production. With minimal residue and / or coke production (if any) in the crude oil product, the crude oil feed is converted into the crude oil product, so that the crude oil product can be converted into the Xiaoye product in the refinery with minimal pretreatment. &amp;. In some specific examples, there is at most 0.2 g, at most 0.01 g per gram of crude oil feed: "

A crude oil feed of at most 0.05 g and at most 0.003 nm a aa a sibling is converted into non-condensable hydrocarbons. In some specific examples, there is a non-condensing furnace with 0 to g per gram of crude oil feed, 0.0000 g to CM, 0.001 to 0.05 g, or 0 to 01 g.

The class is generated. I Controlling the temperature of the contact zone, the flow rate of the crude oil feed, the flow rate of the complete product, the flow rate and / or amount of the catalyst feed, or a combination thereof, can be performed to maintain the desired reaction temperature. In some embodiments, controlling the temperature in the contact zone can be performed by changing the flow of a gaseous hydrogen source and / or an inert gas through the contact zone to dilute the amount of hydrogen and / or remove excess heat from the contact zone. In some specific examples, the temperature in the contact zone may be controlled such that the temperature in the contact zone is the desired temperature "T], or above or below it. In some specific examples, the contact temperature is controlled such that the contact The zone temperature is below the maximum = TAP temperature and / or the minimum DSC temperature. In some specific examples, Ding I may be below the minimum TAP temperature and / or the minimum DSC temperature by 30%, below ^ C or below 1 〇 Qc. For example, in a specific example, when the minimum TAP temperature and / or the minimum DSC temperature is 400, the contact temperature can be controlled to 370 ° C, 380 during the reaction period. (: Or wo 〇 c. In other specific examples, 'the contact temperature is controlled such that the temperature is the TAP temperature and / or the catalyst DSC temperature or ±. For example, the minimum TAP temperature and / or the minimum DSC temperature is Tian π c 捋In the reaction, the contact temperature can be changed to 4500C, 500c '

And 550 c. Controlling the contact temperature according to the temperature of the catalyst AP and / or the temperature of the catalyst DSC can be obtained

Crude product properties. For example, this control can reduce coke formation, less non-condensable gas generation, or a combination thereof. A In some specific examples, the inorganic salt catalyst can be adjusted before the crude oil feed is added. In some specific examples, this adjustment may be performed in the crude feed stock. Adjusting the inorganic salt catalyst may include heating the inorganic salt catalyst to at least ° C; at least the class. 0, at least 4⑻. The first temperature of C or at least 500 dC, and then the inorganic salt catalyst is cooled to at most 250. Candidates can be operated at a temperature of at least 200 ° C or 100 ° C. Here, in the specific example, the inorganic salt catalyst is heated to a temperature in the range of 150-700 0C, 200 Ann bucket, 1 ^ C, or 3000-50000c, and then Cool to a temperature of 25 ° -24 °, L, or 50-90 ° C. The adjustment temperature can be determined by measuring the ion conductivity at different temperatures. In some specific examples, the adjustment temperature may be determined from the DSC temperature of the thermal / cold transition obtained by heating and cooling the inorganic salt catalyst multiple times in DSC. The adjustment of the inorganic salt catalyst allows the contact of the crude oil feed at a reaction temperature lower than the pulse rate used in conventional hydroprocessing catalysts. The content in the complete product in some specific examples, light oil , Distillate, VGO, or a mixture thereof can be changed by changing the rate at which complete product 84 200535229 is removed from the contact zone. For example, reducing the rate of contact with the catalyst after increasing the contact time between the crude oil feed and the catalyst tends to increase the contact time, which can increase the strength of the crude oil feed or ammonia source at a given mass flow rate. = f :, 'Blend into crude oil product, or can be changed = "Increase contact time between feed and catalyst, compared with short contact time In terms of the amount of Γ # 二, ^ and VG〇 produced, an increased amount of Bi :, kerosene or light oil, and a reduced amount can be obtained. Increasing the complete product in two: Two = can also change the crude oil product. Average carbon number. Increase ==: lower carbon number than the weight percentage of south (so there are higher trips, in some specific examples, the contact conditions can change with time. For example, the contact pressure and / or The contact temperature is increased: the amount of chlorine used to make crude oil products. Change the gas absorption of crude oil feed: = ability to feed other properties of good crude oil, increase the types of mr crude oil products that can be fed from a single crude oil. Feed from a single crude oil Manufacture of multiple crude oil products, moon force can allow different transportation / Or treatment specifications are met. H / 彳 absorption can be estimated by comparing the H / C of the crude feed with the crude product's ...: The increase in crude product H / C relative to the crude feed H / C indicates that The hydrogen source is incorporated into the crude oil product. The H / c in crude oil production is relatively low (plus 20% when compared to the crude oil feed), indicating that there is a relatively low hydrogen consumption during processing. Crude oil obtained with minimal hydrogen consumption The significant improvement in product properties relative to crude oil feedstock is ideal. The ratio of hydrogen source to crude oil feed can also be changed to change the properties of crude oil products. 85 200535229. For example, increase the gas source ..,. ^ Pair The ratio of crude oil feed can be used to obtain crude oil products with an increased VG0 content per gram of crude oil product. In some specific examples, BEI, 丄 w, 4cg. ,, Beijing oil feed and inorganic salt catalysts pass through light hydrocarbons. / Or 太太 车 车 # in the presence of radon steam, compared to the crude oil feed with inorganic salt catalyst lice and the contact body hydrocarbons in the presence of radon steam and less coke m are more produced in crude oil products Contact with methane in the presence of inorganic salt catalysts The specific example can include the atomic carbon and hydrogen that have been incorporated into the component molecule. The atomic carbon and hydrogen in the U, U structure (from a milk ..., 1 ^ K), from the presence of a hydrogen source in the presence of an inorganic salt catalyst. The volume of the crude oil product obtained from the crude oil feed from Shu is at least 5% larger than the volume of the heat from STP = 5 = the volume of the oil product, at least ⑽ or to the produced 3, to the evening M0 /. The contact table between the feed and the inorganic salt catalyst was used to find the crude oil product. U accumulated the volume of the crude oil feed under STP, and U0% by volume. The increase in volume is believed to be the density Lower users: The lower density is usually caused at least in part by the ammoniation of crude oil feeds. In some specific examples, each gram of crude oil feed contains at least 0.02 grams, = 0.05 grams or at least 0.1 grams Sulfur and / or at least 1 gram and V / Fe medium: the feed is in contact with a hydrogen source in the presence of an inorganic salt catalyst without reducing its activity. In some specific examples, the inorganic salt catalyst can be at least partially regenerated by removing one or more components of the catalyst. Contaminants include, but are not limited to, metals, sulfides, nitrogen, coke, or mixtures thereof. Sulfide contaminants 86 200535229 Can be removed from used inorganic salt catalysts by contacting steam and carbon dioxide with used catalysts to produce sulfur gases. Nitrogen contamination can be removed by contacting the used inorganic salt catalyst with steam to produce ammonia. Coke contaminants can be removed from used inorganic salt catalysts by contacting the used inorganic salt catalyst with steam and / or sintering to generate hydrogen and carbon oxides. In some specific examples, one or more gas systems are produced from a mixture of an inorganic salt catalyst and a residual crude oil feed. In some specific examples, used inorganic salts (such as K2C03 / Rb2C03 / Cs2C03; KOH / A1203; Cs2C03 / CaC03);

Na⑽KOH / LiOH / ZrO2), a mixture of unreacted crude oil feed and / or residue and / or coke is heated to 700-1000 in the presence of steam, hydrogen, carbon dioxide and / or light hydrocarbons.匚 or a temperature in the range of 800-900 ° c until the generation of gas and / or liquid is minimized 'to produce a liquid phase and old gas. The gas may include an increased amount of hydrogen and / or carbon dioxide relative to the reaction gas. For example, the gas may include hydrogen and / or carbon dioxide ranging from 01 to 99 moles or moles per mole of reactive gas. The gas may contain relatively low amounts of light hydrocarbons and / or carbon monoxide. For example, light hydrocarbons of less than 0.05 g per gram of gas and -CHg oxide carbon per gram of gas. The liquid phase may contain water, for example, greater than 0.5-0.99 grams or greater than 0.9-0.9 grams of water per gram of liquid. In some specific examples, 1 handles the catalyst and / or solids in the incoming material so as to remove the used catalyst and / or solids from the metal (eg, hungry and / or nickel). It can often use known metal separation techniques such as heating, chemical treatment and / or gasification to treat used catalysts and / or solids. 87 200535229 Non-limiting examples of catalyst preparation, catalyst testing, and systems with controlled contact conditions are described below. Preparation of a hydrated compound · A K-Fe sulfide catalyst system was prepared as follows: · 10 g of iron oxide (Fe203) and 580 g of carbohydrate were combined with 4 12 g of deionized water to form a wet paste. The wet paste was dried at 200 ° C to form an iron oxide / potassium carbonate mixture. Mix the iron oxide / potassium oxalate at 500. (: Calcined to form an iron oxide / potassium carbonate mixture. The iron oxide / potassium carbonate mixture is reacted with hydrogen to form a reduced intermediate solid containing iron metal. The addition of hydrogen is at 4500c and 15- 12.2 Mpa

(1665-1765 PS1) for 48 hours. The intermediate solid was passed through a 40-mesh screen with minimal force. The intermediate solid was added incrementally at a controlled exothermic rate to generate a gas at 100 ° C to the VGO / m-xylene / elemental sulfur mixture. After the addition of the intermediate solids, the resulting mixture was gradually heated to 3000 and maintained at 300 ° C for 1 hour. The solvent / catalyst mixture is cooled below 100%, and the sulfurized catalyst is separated from the mixture. The sulfurized catalyst was isolated by filtration in a dry box under an argon atmosphere, and then washed with m-xylene to obtain 544.7 g of a K-Fe sulfide catalyst. The K-Fe sulfide catalyst was pulverized by passing it through a 40-mesh screen. The resulting sulfide catalyst was analyzed using X-ray diffraction technology. From the analysis of the X-ray diffraction pattern, it was determined that the catalyst contains p-membered iron (FeS), K-Fe sulfide (KFeS2), pyrrhotite, and iron oxides (for example, magnetite 'Fes〇4) ° No peaks associated with iron disulfide (eg, pyrite, FeS2) are observed in this X-ray diffraction pattern. Example 2: The original fishery A and nitrogen source were in Kashi 88 200535229. A 600-ml continuous stirred tank reactor (composed of 316 stainless steel) was equipped with a bottom inlet, a single steam outlet, and three inside the reactor. Thermocouple and shaft-moving 125-inch diameter six-blade Rushton turbine. A K_Fe sulfide catalyst (110.3 g) prepared as described in Example 1 was filled into the reaction. Nitrogen was mixed with the asphalt (Lloydminster region, Canada) at 8,000 Nm3 / m3 (50,000 SCFB) to the inside of the reaction system. Asphalt is fed into the reaction chamber through the bottom inlet feed to form a hydrogen / crude feed mixture. During the reaction period of 85 hours, hydrogen and crude oil were continuously fed into the reactor, and the product was continuously taken out through the outflow steam port of the tritium reactor. The crude feed was fed at a rate of 67.0 grams / hour to maintain the crude feed level at 60% of the reactor volume. A 50 microcubic 37Cs gamma-ray source and a sodium iodide scintillation detector were used to measure the liquid level in the reactor. The hydrogen / crude feed was contacted with the catalyst at an average internal reactor temperature of 430 QC. Contact of the hydrogen / crude feed with the catalyst produces a complete product in the form of reactor effluent gas. The reactor exit steam exits the vessel through the single upper outlet. The top of the reactor was electrically heated to 430. (: To avoid the condensation of the reactor effluent vapor on the inside of the reactor top. After leaving the reactor, the reactor effluent vapor is cooled and separated in a high pressure gas / liquid separator and a low pressure gas / liquid separator to obtain a liquid Stream and gas stream. The gas stream was sent to a countercurrent alkaline scrubber to remove acid gases, and then quantified using t-quasi-chromatographic techniques. The complete product is 0.9 grams per gram of crude product and 0.089 grams of non-condensing Hydrocarbon gas. In the reactor, there are 0.027 grams of solid residue per gram of 89 200535229 crude oil feed. The properties and composition of the desert, product and non-condensable hydrocarbon gas produced by this method are summarized in Figure 8 Table 1, Table 2 in Figure 9, and Table 3 in Figure 10. ° This example demonstrates a method of making a crude oil feed in contact with hydrogen in the presence of a transition metal sulfide catalyst with minimal coke pollutant production. Method for complete product. This complete product contains a crude product that is a liquid mixture at STp and contains up to 0 ·] grams of non-condensable hydrocarbon gas per gram of complete product. By comparing the MCR content of the crude feed in Table 1 (13 · 7% by weight) during the process The solids formed (2.7% by weight) can be observed. The combination of controlled conditions and catalysts produces lower amounts of coke than those shown by ASTM method D453. Non-condensable hydrocarbons include C2, q And C4 hydrocarbons. From the sum of the weight percentages of q furnaces listed in Table 2 (20.5 grams), the ethylene content per gram of total C2 hydrocarbons can be calculated. The q hydrocarbons of hydrocarbon gas per gram of total c2 Hydrocarbons contain grams of ethylene. From the sum of the weight percentages of q hydrocarbons listed in Table 2 (23 9 grams), the propylene content per gram of total hydrocarbons can be significantly different. C hydrocarbons of non-condensable hydrocarbons per gram The total C3 hydrocarbons contain 0.21 g of propylene. The non-condensable hydrocarbons have a weight ratio of isobutane to n-butane of 0.2. This example demonstrates a method for preparing a crude product containing the following: · At least o.ool grams of hydrocarbons with a boiling range distribution of at most 2 ° C (400 ° F) at 0.1 MPa, and at least 0.001 grams of boiling range distribution at 0.001 Mpq. And 300. €: hydrocarbons between, at least 0.001 g of hydrocarbons with a boiling range distributed between 300 and 4000 c at 0.101 MPa and at least 0.001 g at 0101 MP Hydrocarbons with boiling ranges below 400 and 90 200535229 538 0C (10,000) under a, including heterochain diboiling ranges ranging from 204. The ratio of normal paraffins is at most 14. For crude oil products Includes the distribution of monuments related to light oil, kerosene, diesel, and vG0. The light oil portion of the crude oil product related to the crude oil product has up to 1 g of light oil, and the light oil portion has a per-Hg Calorific value. The crude oil product has a benzene content of up to 0.01 grams of benzene in the mother gram of light oil. The light oil part of the product is a product of Beigu, and the oil product has at most gram of olefin. The light oil portion of the product is per aromatic compound. Two main ^ 0.1 g early nuclear rings :: crude product contains at least. ·, Grams of kerosene. The = has a freezing point lower than -3 ". The kerosene of the crude product: = Compound 'and the kerosene portion of the crude product has each; Aromatic content of the crude oil. The crude kerosene contains at least 0.2 grams of monocyclic ring aromatic hi crude oil products containing at least 0.001 grams of diesel oil. The originals are ancient and modern, and the diesel oil of the crude oil product has an aromatic content of at least 0.4 grams of aromatic compounds in wood oil. Eight of the crude oil products have at least 0.001 grams. The part contains aromatic compounds, and the amount of aromatic compounds per gram: less than 0.5 5 ancient 芏 # renren eight 'mother grams of VGO to grams of private compounds. A certain clothing is as follows: · 1000 grams of iron oxide and 173 91 200535229 g of potassium carbonate and 423 g of deionized lip to form an edge paste. Treat the wet paste as described in "..." "Also Example 1 The intermediate solids pass through the sieve. "Take a small force to make this the opposite of Example 2. Mix the solid and the elemental sulfur with the elemental sulfur in the absence of the agent. In a dry box of ^ 隹 / manufactured dilute milk neon, neutralize The powdery elemental sulfur is mixed, and the 7 mouth body is placed in a tightly sealed carbon steel cylinder, ° C, and at 400. (: Xia ,, α Shidao ... ㈡400 Qiao 庑 ~ Sulfurized catalyst is solid from Carbon steel

: Should :: Use two grinding spiders and pestle to pulverize the unloading-iron sulfide catalyst into powder, so that the catalyst powder paid by the service station can pass through a sieve with a size of 40 °. The obtained potassium iron sulfide catalyst was analyzed using X-ray diffraction technology. From the analysis of the X-ray diffraction pattern, it was determined that the catalyst contains pyrite (ton), iron sulfide, (FeS), and pyrrhotite (FU). No mixed potassium-iron sulfide or iron oxide species were detected using X-ray diffraction. The sulphide contact device, crude oil feed and reaction steps are the same as in Example 2, but the ratio of hydrogen to crude oil feed is

16,000 NmVm3 (100,000 SCFB). A K-Fe sulfide catalyst (75.0 g) prepared as described in Example 3 was charged into the reactor. The properties of the crude oil product produced by this method are summarized in Table Workers in Fig. 8 and Table 3 in Fig. 10. The weight percentage of VG0 produced in Example 4 is greater than the weight percentage of VG0 produced in Example 2. The weight percentage of the distillate obtained in Example 4 was less than the weight percentage of the distillate obtained in Example 2. The API specific gravity of the crude oil product prepared in Example 4 is lower than the API specific gravity of the crude oil product prepared in Example 2. A higher 92 200535229 API specific gravity indicates that a cigarette with a higher carbon number is produced. After contact with the crude feed. The paper analyzes the TMS catalyst in the reaction state. From this analysis, it can be seen that the transition metal and the metal catalysts contain iFeiQS after being in the presence of crude oil feed and chlorine. F T A P test of other inorganic salts.

^ AP4 test towel, take the pure product in the reactor of the TAP system at a rate of 50 rfy per minute; Sword carp at a rate of 50 C from room temperature (27. 0 to 500 0 C. The discharged water is $ 1 each> ;

^…, Milk and carbon dioxide gas systems were monitored using a mass spectrometer of this TAP system. K, c0 / Rh m ^ -2 U3 / Rb2C (VCs2C03 catalyst supported on alumina shows 360 ◦C from the inorganic salt catalyst-an emulsified carbon identified with a current turning point greater than 0.2 volts And the drained water has a current turning point of 100 001 watts. The minimum TAP temperature is 360 ° C, as measured by log 1 of Li Zao Di, Gu Gu 7 Zi / Claw. FIG. 11 is a log 10 (“10 2 nvM branch, w free / 〇 g⑴) of the ionic current of the gas discharged from the K2C〇 / Rb Γ〇2 〇3 / CS2C〇3 catalyst versus temperature (" ding ,,) The graphs 168 and 170 are the log 1 values of the ionic currents of water and co2 discharged from the 1 μ 鴎, 4 斗, 4 甘, 攸 ... salt catalysts. From this machine商 ... russia | The sharp turning point of the water and C02 discharged by the catalyst appeared at 360. (: In contrast to the K2C〇3 / Rb2C〇3 / Cs2C〇3 catalyst, the bell carbonate and cesium carbonate at 360% for the discharge Both water and carbon dioxide have incumbent current turning points.… For the K2c〇3 / Rb2C〇3 / Cs2C〇3 catalyst's substantial increase in exhaust gas is confirmed by two or more different Organic salt catalysts composed of organic salts can be more disordered than individual pure carbonates. 93 200535229 fAJLj · No sign ^ dsc test of catalysts and individual inorganic salts. In all DSC tests, 10 mg Heated at a rate of 1 0 qC to 5 2 0 C in minutes 'Cooled from 5 2 0 ◦C to 0 · 0 ° C at a rate of 1 0 C' and then used a differential scanning calorimeter (DSC) DSC- Type 7 (manufactured by PerKin-Elmer (Norwalk, Connecticut, USA)) was heated from 0 ° C to 600 ° C at a rate of 10.0 ° C per minute. K2C03 / Rb2C03 during the second heating of the sample / Cs2C03 Catalyst DSC analysis selection: The salt mixture exhibits a wide thermal transition between 2 j 9.c and 2 60 ° C. The midpoint of this temperature range is 25 °. The area under the variation curve was calculated as β1 · 75 Joules / gram. The start of crystal disorder was determined to start at 219. (: The minimum DSC temperature. 相反 These results are contrary. No clear thermal transition was observed for cesium carbonate. 〇

DSC &amp; analysis of this complex of Ll2C03, Na2C ... and K2C0q during the second heating cycle showed that the Ll2C03 / Na2C03 / K2C03 mixture exhibited: between 390 ° C and 400 ° C Sharp heat transition. The midpoint of this temperature range is 385 ° C. The area under the thermal transition curve was calculated to be 82 J / g. The onset of migration was determined at 390. (: The minimum DSC warm production begins. A sharp thermal transition indicates a salt mixture that is substantially homogeneous.-~ Medium or individually without respect. Relative to: All experiments were performed as follows: 3 81 cm opening) Medium or individual inorganic salts are placed in a muffle furnace (mfU) in a quartz container equipped with turning wires separated from each other but immersed in the sample. These metal wires are connected to a 9.55 volt 94 200535229 cell and a 220,000 ohm current-limiting resistor. The muffle furnace was heated to 600 ° C. and the current was measured using a microampere meter. Figure 12 shows the sample resistance versus potassium carbonate resistance ("10 g (r K2c〇3), ()) The graph of the log of temperature and temperature ("ding"). Curves 1 72, 1 74, 1 76, 1 78, and 1 80 are K2C03 resistance, CaO resistance, K2C03 / Rb2C03 / Cs2C03 catalyst resistance, respectively. , Li2C〇3 / K2C03 / Rb2C03 / Cs2C03 catalyst resistance and Na2C03 / K2C03 / Rb2C03 / Cs2C03 catalyst resistance log plot.

CaO (curve 174) exhibits a relatively large stable resistance relative to κ / Ο3 (curve 172) at a temperature in the range between 380-500 ° C. Stable resistance indicates an ordered structure and / or ions that do not tend to move away from one another during heating. K2C〇3 / Rb2C〇3 / Cs2C〇3 catalyst,

Li2C03 / K2C03 / Rb2C03 / Cs2C03 catalysts and Na2C03 / K2C〇3 / Rb2C03 / Cs2C03 catalysts (see curves 176, 178, and 180) show a sharp decrease in resistivity at temperatures in the range of 350-500 ° C . A decrease in resistivity usually indicates that a current is detected during the application of a voltage to a metal wire embedded in an inorganic salt catalyst. The data in Figure 12 confirm that inorganic salt catalysts are generally more mobile than pure inorganic salts at temperatures in the 350-600 range. Figure 13 is a graphical representation of i2g of Na2C〇3 / K2C03 / Rb2C03 / Cs2C〇3 catalyst resistance vs. k2co3 resistance ("log (r K2C〇3),") versus temperature ("τ ,,) . Curve 182 is the ratio of the Na2C03 / K2C03 / Rb2c03 / Cs2C03 catalyst resistance to the K / 〇3 resistance (curve 172) during the heating of the Na2C03 / JC2C03 / Rb2C03 / CS2C〇3 catalyst. Plotting temperature. After adding 95 200535229 heat, the Na2C03 / K2C03 / Rb2C03 / Cs2C03 catalyst was cooled to room temperature 'and then heated in a conductivity device. The curve 84 is cooled from 600 to 25. (: Later, during the Na2C03 / K2C03 / Rb2C03 / Cs2C03 catalyst heating, the inorganic salt catalyst resistance was plotted against the K2C03 resistance versus temperature 10 g. Reheated Na2c 〇3 / K2C〇3 / Rb2C〇3 / Cs2C〇3 The ionic conductivity of the catalyst is increased compared to the ionic conductivity of the original catalyst. From the inorganic salt catalyst ionic conductivity during the first heating and the second heating The difference in time can be inferred that the inorganic salt catalyst forms a different form (second form) when cooling, which is different from the form before any heating (first form). Test · Put a powdered KfCVRhCh / Cs / O3 catalyst in a battalion in a stone = pan. Place the pan in a furnace and heat it to 500 0C for 1 hour. To measure the flow properties of the contact 'on heating Later, the tray was tilted manually in an oven to flow the K2C03 / Rb2CQ3 / Cs2C () 3 catalyst shirt. The catalyst had a toffee consistency when pressed with a spatula. In contrast, the individual carbonic acid The salt is free under the same conditions.

The ancient Haizhong Zhongzeng j803 / Cs2C03 catalyst became liquid and flowed easily (for example, similar to water). co / Rb ΓΓ. ^ and steam in the presence of ~ 1 ----In the examples, 27 equipment and general procedures, except that the use of the meaning of double-synthesis in j 7 is said. 96 200535229 = Reactor: 25.0 liters of helium CParr factory heater (Wd and 50000C, rated at 35MPa operating pressure (5000 psi), equipped with a mechanical stirrer and located to enable pressure The heater is maintained at an ambient temperature of 625 ° C ± 5 ° C. The E-controller's _Watt Gaumer-type heater, gas inlet, steam inlet, an outlet and a thermocouple come to the internal temperature. Before heating ' The top of the autoclave is separated by glass cloth. 0—Adding device · Adding container (250ml, 316 stainless steel hoke container) is equipped with a controlled heating system, appropriate gas control, and pressure. The release device, thermocouple, pressure gauge, and high temperature control valve (—k Valve # SS-4UW) can adjust hot, viscous and / or compressed crude oil feed at a flow rate of 0-500 g / min. After the crude oil feed has been filled into this addition vessel, an outlet side of the high temperature control valve is connected to the first inlet of the reactor. Before use, the line of the addition vessel is isolated. Product collection: vapor from the reactor from the reactor Exit left while being taken into a A row of decreasing temperature cold traps (impregnation tubes connected to a series of 150 ml, 3 i 6 stainless steel Hawker vessels). The liquid from this vapor is in the cold trap _ cold politics to form a gas stream and a liquid condensate stream. As required Use a back pressure regulating valve to adjust the flow rate of the vapor from the reactor and the cold trap. The flow rate and total gas volume of the air stream leaving the cold trap are measured using a wet flow meter (wet test meter (Rittei · Model # TG 05 Wet Test Meter) )) Measurement. After leaving the wet flow meter, collect the gas stream in an air bag (a Tedlar gas sampling bag) for analysis. Use GC / MS (Hewlett-Packard Model 5890, now Agilent Model 5890; Agilent Technologies, Zion 97 200535229 111 i ois, U · S · A · manufactured) Analyze 5H gas. Remove the liquid condensate stream from the cold trap and weigh it. Separate the crude product and water from the liquid condensate stream. Weigh the crude product And analysis. Step: Fill Cerro Negro (137.5g) to the addition container. The crude oil feed has an API specific gravity of 6.7. The crude oil feed has 0.042 grams per gram of crude feed Sulfur content, nitrogen content of 0.011 g, and total Ni / V content of 009 g. The crude feed was heated to 150. K2C03 / Rb2C03 / Cs2C03 catalyst (31.39 g) was charged into the reactor. K2C03 The / Rb2C03 / Cs2C03 catalyst system was prepared as follows: · 44 g of K2co3, 19.44 g of Rb2co3 and 24.49 g of Cs2C03 were combined. The K2C03 / Rb2C03 / Cs2C03 catalyst has a minimum TAP temperature of 360 ° C. The K2C03 / Rb2C03 / Cs2C03 catalyst has a DSC temperature of 250. Individual salts (K2C03, Rb2C03 and Cs2C03) did not exhibit DSC temperatures in the range of 50-50 ° C. The TAP temperature is higher than the DSC temperature of the inorganic salt catalyst and lower than the dsc temperature of individual metal carbonates. The catalyst was rapidly heated to 450 at a normal pressure flow of 250 cm V of pentane. After reaching the desired reaction temperature, steam was metered into the reactor at a rate of 0.4 ml / min and methane at a rate of 250 cmVmin. The steam and methane were continuously metered during the 2.6 hours while the crude feed was being fed to the reactor. 1 &gt; 5 Mpa (229 psi) of Ch4 was used to pressurize the crude oil feed into the reaction for 6 minutes. After the addition of the crude feed was completed, the remaining crude feed (0.56 g) remained in the addition vessel. It was observed that the temperature decreased to 370 ° C during the addition of feedstock. The catalyst / crude feed mixture was heated to 45 °. The reaction temperature of C was maintained at this temperature for 2 hours. : After hours, the reactor was cooled and the resulting residue / catalyst mixture was weighed to determine the percentage of coke produced and / or not consumed in the reaction. From the difference between the weight of the starting catalyst and the weight of the coke / catalyst mixture, it is known that ::. 046 g of coke left in the crude oil feed remains in the reactor. Complete product 2b 0.87 g of crude oil product and gas with an average API specific gravity of 13. The gas: unreacted CH4, hydrogen, Q and CfC6 hydrocarbons and co2 (0.08 g of co2 per gram of gas).

° The crude oil product contains 0.01 g of sulfur and 0.005 g of culprit and V per gram of crude oil product. The crude product was not analyzed further. [In Example 10, the reaction steps, conditions, crude oil feed, and catalyst system were the same as in Example 9. The crude product of Example 1G was analyzed to determine the boiling range distribution of the crude product. The crude oil product contained 0.14 g of light oil, 019 g of distillate, and 0.4 g per gram of crude oil product. On the side, the residue content is less than the amount of coke.

Example 9 and the following examples: Demonstration of contact between a crude oil feed and a hydrogen source per 100 g of crude oil feed: more than 3 g of catalyst in the presence of a catalyst to produce a crude oil product containing a liquid mixture at ττρ The complete product. The crude oil product has a residue content of up to 30% of the residue content of the crude oil feed. The crude oil product has a sulfur content Ni / V content of up to 90% of the crude feed sulfur content # Nl / V content. The crude oil product contains at least grams of hydrocarbons of up to 200 OC at Fortune Fan Knife at G1 (n Mpa), and at least 0.001 grams of Fenton I at around 0.003 MPa at 0.003 MPa. Intermediate hydrocarbons, at least 0.001 g 99 200535229 Boiling hydrocarbons with a boiling range between 400-538 0c (1000 ° F) at 0.101 MPa. Heavy U_mi · Secondary materials and hydrogen source at K2CC ^ / RbH / catalyst and Contact of steam, storage, and work examples and reaction steps and conditions in 12 and K2C03 / Rb2C03 / CS2C03 catalyst system is the same as in Example 9 'but used, 130 grams Crude oil feed (cerroNegr) and 60 g of K ^ CC ^ / Rl ^ CC ^ / CszCO3 catalyst. In Example η, methylbenzene was used as the hydrogen source. In Example 12, hydrogen was used as the hydrogen source. The source of hydrogen. The diagram of the non-condensable gas, crude oil products, and the amount of coke is depicted in Figure 14. The bars i 8 6 and 丨 8 8 φ represent the weight% of the coke produced, and the bars 1 90 and 1 92 represent the The weight% of liquid hydrocarbons was produced, and the bars 194 and 196 represent the weight% of the produced gas, which is based on the weight of the crude oil feed. In Example 11, 93% by weight of crude oil was produced. (Strip 1 92), 3% by weight of gas (Strip 196), and 4% by weight of coke (Strip 188), based on the weight of Cerro Negro. In Example 12, 84 was obtained. Crude oil product (strip i 90), 7% by weight of gas (strip 194) and 9% by weight of coke (strip 186), based on the weight of Cerro Negro. Examples 11 and 12 Provides a comparison between the use of methane as a hydrogen source and the use of hydrogen as a hydrogen source. Methane is usually cheaper than hydrogen in terms of manufacturing and / or shipping, so the method of using methane is ideal. As proven, in making crude oil feeds inorganic When contacted in the presence of a salt catalyst to produce a complete product, methane can be at least as effective as a hydrogen source as hydrogen. The API specific gravity is wide. 100 200535229 The device, reaction steps, and inorganic salt catalyst system are the same as those described in Example 9, but The reactor pressure was changed. In Example 13, the reactor pressure during the contact was 0.1 MPa (14 7 PS1). 15.5 was obtained. (: Nichiji API crude oil product with a specific gravity of 25. The complete product has a carbon number distribution of 5 Hydrocarbons in the range 32 to 32 (see curve 19 in Figure b) 8). In Example 14, the reactor pressure during the contact was 3.4 MPa (514.7 psi). A crude oil product with an Aρ specific gravity of 516 at 15 5c was prepared. The complete product has a carbon number distribution of 5 to 丨Hydrocarbons in the 5 range are shown in curve 200 of Figure 15). In some examples, a method of contacting a crude oil feed with hydrogen in the presence of an inorganic salt catalyst under different pressures to produce a crude product having a selected specific gravity of # Αρι. By changing the dust power, a crude oil product having a higher or lower Aρι specific gravity is obtained.装置 In Examples 15 and 16, the equipment, crude oil feed, and reaction steps are the same as in Example 9 ', but the crude oil feed and contact (or carbonization seconds) are directly charged into the reaction benefits simultaneously. Use carbon dioxide (CO2) as the carrier gas. In Example 15, 138 grams of Cerro Negr. Combined with 604 g of K2C03 / Rb2c03 / CS2C03 catalyst (the same catalyst as in Example 9). In Example 16, 132 g of cerr0 Negro and 83 μg of silicon carbide (40 mesh,

Matenals; Alis Vlejo, CA). It is believed that such carbides have low (if any) catalyst properties under the method conditions described herein. 200535229 In each sample, the compound was heated to a reaction temperature of 500 ° C over a two-hour period with n monitor and θ person u. C02 was metered into the reactor at a rate of 100 cm 3 / eight knives / knife. The vapor generated from the reactor was collected in a cold trap and an air bag using 3.2 MPa (479 7 Osi, back pressure from Menguang. The white f was consolidated into the cold drunk crude product and analyzed. In Example 15 'From the contact between the crude oil feed and the inorganic salt catalyst in a dioxic, carbon atmosphere, 36.82 "(26.68% by weight, based on the weight of the raw material) of a colorless hydrocarbon liquid having an API specific gravity of at least 5g was prepared.

Weight basis) Yellow hydrocarbon liquid with API specific gravity of 12. Although the yield in Example 15 is very low, the on-site generation of hydrogen source in the presence of an inorganic salt catalyst is greater than the on-site generation of hydrogen in the absence of a catalyst. In Example 16, 15.78 1 (11.95 wt%) was obtained from the contact between the crude oil feed and carbon cutting under a carbon dioxide table atmosphere. % ^ 丨 Half of the crude oil product yield in Example 15 of Example 15. Example 15 also confirms that Jian Wubian, Dong, and Yehuo, crude oil feeds in inorganic oil Produced during contact in the presence of salt and in the absence of a gaseous hydrogen source.

f EXAMPLE— · —It is the contact between the feed and-Huang Nong / Rb2C〇3 / Shangmeng-XjL atmospheric conditions. The device, reaction steps, crude oil feed and inorganic salt catalyst system are the same as in Example Instead of adding Ceiro Negro i to the reactor instead of adding power through the addition vessel, and using hydrogen as the hydrogen source. The reactor pressure during the contact was 0.101 MPa (14.7 psi). The hydrogen flow was captured at 25 cm 3 / min. The series of reaction temperatures, steam flow rates, and percentages of crude product, gas, and coke produced are shown in Table 4 in Figure 16. 102 200535229 In Examples 17 and 18, the K2C03 / Rb2C03 / Cs2C03 catalyst was used. In Example 17, the contact temperature was 375 ° C. In Example 18, the contact temperature was within a temperature range of 500-600 ° C.

As shown in Table 4 (Fig. 16), for Examples 1 to 18, when the temperature was increased from j75 ° C to 500, the gas production was increased from 0.02 g to 0.05 g of gas per gram of complete product. However, coke production decreased at higher temperatures from 0.17 grams per gram of crude feed to 0.99 grams of coke. The sulfur content of the crude product also decreased from 0.01 g per gram of crude product to 0.008 g of sulfur at higher temperatures. The two crude oil products all have] · 8.

In Example 19, the crude oil feed was contacted with the CaC03 system under conditions similar to those described in Example 18. The percentages of crude oil product, gas, and coke production are: Tables shown in Figure 16 ". Gas production is in the compilation," 9 is squared, and gas production in H Example 18 is increased. Crude oil feed The claw-releasing effect is not as effective as in the κ yoke example 8. Compared with the sulfur content per gram of crude oil produced in Example U of the crude oil product produced in Example U, 4 produced in Example 19 4 The crude oil products of 丄, 丄 + w ^ are parent gram crude oil products containing 0.01 g

Of sulfur. The yoke example 20 疋 is a comparative example of the embodiment i 8. In Example I, 83.13 grams of carbonized fossil powder was charged into the reactor in Example 20 instead of the inorganic salt catalyst, and the yield of coke and coke was relative to the gas production and coke production of Example 18 θ ^, Li Jiaqi. Under these catalyst-free conditions, 222 g of burnt per gram of crude oil product, 0.25 grams of non-condensable gas, and 0 grams of crude oil product were obtained. Phase ---: 0.18 gram of sulfur per gram of crude oil produced in Example 18, naming #, 焉 also the crude oil product produced in Example 20 was 103.00235229 gram of oil product per gram of crude oil. 0.036 grams of sulfur. The examples demonstrate that the catalysts used in Examples 17 and 18 provided improved results over catalyst-free conditions and conventional metal salts. At a hydrogen flow rate of ㈣. 匸 and 250 。//, coke and The amount of non-condensable gas is significantly lower than the amount of coke and non-condensable gas produced under no-catalyst conditions.-In the embodiment using inorganic salt catalyst (see Example 17 in Table 4 of Figure 丨 6) -1 8), relative to the gas formed during the control experiment (such as the real yoke example 2 in the table * in Figure 6), A reduction in the weight percentage of the produced gas was observed. From the amount of hydrocarbons in the produced gas, the crude oil feed was estimated to be at most 2G% by weight, at most 15% by weight, at most 10% by weight, at most 5% by weight, or None, based on the total amount of crude oil feed in contact with the hydrogen source. ~ ^ ~~~ Raw fish feed and gaseous phase i. Pile in the presence of source Wei Wei or silicon carbide ^^], and the device in 22 and It is the same as in Example 9 but using the countersink as the gas source. In Example 21, 10.4 g of Ceiro Negro and 3 k = 8 g of K2C03 / Rb2C03 / Cs2C03 catalyst were combined to A crude oil feed is formed. In Example 22, 139.6 grams of CerroNegro is combined with 80.14 grams of reversed silicon to form a crude oil feed mixture. The raw mixture is charged directly into the reactor from the feed mixture. During heating and dwell time, the gas range u 1 c Λ \, 2 • ”2 5 0 scoop / min was metered into the reactor. At 1.5 hours, the gate was heated from the feed mixture to 300. And maintained at 300. (: 1, 1, 1), increase the reaction temperature to 400 during the day guard. (: And maintain at 400 C for 1 hour. After the reaction temperature reaches 400 ° C, send water at a rate of 0.4 g / 104 200535229 minutes Combined with hydrogen into the reactor. Water and hydrogen were metered into the reactor to maintain heating and residence time. After the reaction mixture was maintained at 400. (: After, the reaction temperature was increased to 5000c and Maintained at 5⑻. 2 t under c. The reaction of 彳 was collected in the cold trap and air bag. The liquid product from the cold trap was consolidated and analyzed. In Example 21, 86.17 g (66.} % By weight, based on the weight of the crude oil feed) The dark reddish brown hydrocarbon liquid (crude oil product) and water (97 5 g) are generated by contact between the crude oil feed and the catalyst under a hydrogen atmosphere as steam. Φ In the examples In 22, water vapor and a small amount of gas are generated from the reactor. Check the reactor and remove the dark brown viscous hydrocarbon liquid. The contact between the crude oil feed and silicon carbide under a hydrogen atmosphere produces less than 5 ()% by weight Dark brown viscous hydrocarbon liquid. Compared to Example 22 The yield of the crude product produced was observed to increase by 25% in the crude product yield in the example 21. The example 21 confirms that the sex of the crude product produced using the method described herein is relative to that of the hot water. Improvement in the production of crude oil products. Specifically, the crude oil product in Example 21 is lower than the crude oil product obtained from Example 22_ &gt; Produced as verified. Compared to the crude oil product produced in Example 22, the crude oil product produced in Example 21 has enhanced flow properties, as determined by visual inspection. H system 23 2 crude oil feed and "Hydrogen-based cover" — — — —'_ 一 £ ^ £ 0 ^ — · —catalyst contact ^^^ contact ^ to manufacture compared to under catalyst-free conditions. Volume has increased volume and oil product set, 105 200535229 Crude oil feed 'inorganic catalyst and reaction steps are the same as in Example 9 ___' but the crude oil feed is directly charged to the reactor and gas is used as the source The crude oil feed (Cerro Negro) has an API specific gravity of 6.7, The density is 1.02 g / ml. E In Example 23, 1.02 g of crude oil feed (100 ml of crude oil feed) and 3 g of KfOs / Rbfh / Cs / O3 catalyst were charged. Into the reactor. A crude oil product (87. 6 g) with an API specific gravity of 50 and a density of 15.75 oz. (7 12 g) was prepared. In Example 24, 102 g of Crude oil feed (100 ml of original oil feed) and 80 g of silicon carbide were charged into the reactor. An Aρι specific gravity of 12 and a density of 15.50 oc was 0.9986 g / ml (7 0 ml) of crude product (70 g). Under these conditions, the volume of the crude product produced from Example 23 was approximately 10% greater than the volume of the crude feed. The volume of the crude oil product produced in Example 24 was significantly smaller (40% less) than the volume of the crude oil product produced in Example 23. The significant increase in product volume increases the ability of the producer to produce more volume of crude oil product per volume of crude oil input. _ 宜 油 进 料 鲁 _ Complex ^ In co, a device and reaction steps are the same as those described in Example 9, but the steam is measured at 3⑽cm 3 / min into the reactor K2C〇3 / Rb2C03 / Cs2C03 contact The media was prepared by combining 27.2 grams of K2C03, 32_2 grams of RhCO3 and 40.6 grams of CS2C03. Crude oil feed (130.35 g) and K2C03 / Rb2C03 / Cs2C03 catalyst (^ 1.6g) were filled into the reactor. Cer⑺⑺ crude oil series per gram of original 2005 200535229 oil feed contains 0.04 grams of total aromatics content in the boiling range distributed between 149_260000c (300_50000), 0.00064 grams of combined Nickel and vanadium, 0 · (2 g of L and 0.56 g of residue. The crude gravity of the crude feed is 6.7. The crude feed and methane are in the presence of K2C03 / Rb2C03 / Cs2C03 catalyst. The contact, per gram of crude oil feed, produced 0.95 grams of complete product and 0.041 grams of coke.

The whole product of Wuling contains 0.028 grams of hydrocarbon gas per gram of crude product. The total gas system collected contains mol of hydrogen, 0.045 mol of carbon dioxide, and mol of q and ^ C6 hydrocarbons per mol, as determined by GC / MS. The remainder of the gas is methane, air, carbon dioxide, and traces (0.4 mol) of evaporated crude oil products.

The crude product was analyzed using a combination of gas chromatography and mass spectrometry. The crude oil product contains a hydrocarbon mixture with a boiling range between i-538%. The total liquid product mixture contains Q. g of ethylbenzene per gram of mixture (a monocyclic cyclic compound with a boiling point of 136 · 2 γ at 0.101 MPa). It was not detected in the crude feed. Remove the used catalyst-used catalyst "from the reactor, weigh, and analyze. The weight of the used catalyst increased from 3L6g to a total weight of 37 · 38g (based on the original K2CCVRb2C〇3 / Cs2C〇3 catalyst weight as a benchmark 'increased by 18% by weight). The first-used catalyst system per gram of used catalyst contains 0.15 grams of additional coke, 〇03535 grams of Sulfur, 0 g of Nl / V, and G.845 g of K2C03 / Rb2C03 / Cs2C03. Feed additional crude oil (152.71 g) with the used catalyst 107 200535229 (36.63 g ) Contact to produce 150 grams of recovered complete product after loss. The complete product is 0.92 grams of liquid crude product, 0.058 grams of additional coke and 0.017 grams of gas per gram of complete product. This gas system per mole The gas contains 0.18 moles of hydrogen, 0.07 grams of carbon dioxide and 0.035 moles of CrQ hydrocarbons. The remainder of the gas is methane, nitrogen, some air and traces of evaporated petroleum products (&lt; 1% mole ). The crude oil product contains a hydrocarbon mixture with a boiling range of 100-538 ° C. The boiling range is distributed over 49 Part of the mixture below QC is 0.018 mol% ethylbenzene, 0.04 mol% toluene, 0.03 mol% m-xylene, and 0.060 mol% per mole of total liquid hydrocarbons. Xylene (monocyclic ring compound with a boiling point below 149 at 0.101 MPa). These products are not detectable in this crude oil feed. The used catalyst ("Second Used Catalyst, ,) Remove from the reactor, weigh, and analyze. The weight of the second used catalyst increased from 36.63 grams to 45.44 grams of total weight (based on the original [2 (: 〇3 / 灿 2 (: 〇3 / (^ 2 (: 〇3 catalyst weight as the basis, An increase of 43% by weight). The second used catalyst contains 0.32 g of coke, 0.01 g of sulfur, and 0 67 g per gram of the second used catalyst. Feed additional crude oil (丨(04 g) was contacted with the second used catalyst (44 84 g) 'on a per gram crude oil feed, 104 g of the complete product was obtained and 0.114 g of coke was collected.丨 104.1 grams of 33 grams of crude oil feed is crude oil, part of the coke is attributed to coke formation caused by excessive heating of the addition container in the addition container. The complete product is 0.86 grams per gram of complete product. Crude oil products and 108 200535229 0.025 grams of hydrocarbon gas. The total gas system contains 0.018 moles of ammonia, 0.052 moles of carbon dioxide and 0.03 moles of CrQ hydrocarbons per mole. The rest of the gas is methane, Air, carbon monoxide, hydrogen sulfide, and a small amount of evaporated petroleum. The crude oil product contains a boiling range of 100-538. (: Hydrocarbon mixtures with a boiling range of less than 149 ° C. Part of the mixture consists of 0.0021 g of ethylbenzene, 0.027 g of toluene, 0.0042 g of m-toluene and 〇〇〇20 grams of paraxylene, as previously measured. _ Remove the used catalyst ("third used catalyst,") from the reactor, weigh, and then analyze. The third The weight of the used catalyst was increased from 44.84 grams to 56.59 grams of total weight (based on the original K2C03 / Rb2C03 / Cs2c ... the catalyst weight was based on the 'strength σ 79% by weight). This third Detailed elemental analysis of the used catalyst. This third used catalyst system contains 0.90 g of carbon, 0.028 g of hydrogen, 0.025 g of oxygen, and 0 per gram of additional material. 0.046 grams of sulfur, 0.007 grams of nitrogen, 0.00 grams of vanadium, 0.0007 grams of nickel, 0.0015 grams of iron, and 0.00025 grams of chloride ions, the rest being other transition metals In this example, the coke, sulfur and / or metal deposited on the inorganic salt catalyst and / or on the surface of the inorganic salt catalyst are not The total yield of the crude oil product produced by the contact with the crude feed and the nitrogen source in the presence of the inorganic salt catalyst (at least 80% per test). Xi; §, a + μ μ The product has a monocyclic f in the boiling range distribution below 149. The content of the monocyclic aromatic compound is at least 100 times the content of the square compound in the Ding inch early-dressing%. 109 200535229

For these three tests, the average crude product yield (based on the weight of the crude feed) was 89.7% by weight 'standard deviation was 26%; the average coke yield was 7.5% by weight (based on the weight of the crude feed) As a benchmark), the standard: the difference is 2.7% 'and the average weight yield of gaseous cracked hydrocarbons is η% by weight (based on the weight of the crude oil feed), with a standard deviation of 0 °. The relatively large standard deviation of both liquid and coke was caused by the failure of the temperature controller of the feed vessel in the third test, 'overheating and adding crude oil feed in the vessel. Even if it is necessary, even a large amount of coke, tested here, has no significant significant adverse effect on the activity of the catalyst system. The ratio of C2 thin smoke to total C2 is 0 · 19. ^ The ratio of olefins to total c3 is 0.4. The ratio of alpha olefins of C4 hydrocarbons to intramolecular olefins is 0.6 m. The cis / trans olefin ratio is 6.34. This ratio is considerably higher than the predicted thermodynamic & cis / trans-olefin ratio of 068. The Cs hydrocarbons have an olefin to intramolecular olefin ratio of 0.92. This ratio is greater than the predicted thermodynamic C5 to ene smoke to I intramolecular olefin ratio. The C5 cis / trans-olefin ratio was 1.25. This ratio is greater than the predicted thermodynamic c5 cis / transolefin ratio of 0.9. Should be poured down—26_ · _ Contact with a considerable amount of sulfur in the shoulder oil feed and hydrogen source contact in the presence of a catalyst. The setup and reaction steps are the same as those described in Example 9, but the crude oil feed, Burning and steam are continuously fed into the reactor. The amount of feed in the reactor was monitored using changes in the weight of the reactor. Methane gas was continuously metered into the reactor at 500 cm V. Steam was continuously metered into the reactor at 6 g / min. The inorganic salt catalyst was prepared by combining 27.2 grams of K: 2C03, 32.2 grams of Rb2C03, and 40.6 grams of Cs2C03. The k2C03 / 110 200535229

Rb2C03 / CS2C03 catalyst (59.88 g) was charged into the reactor. That is, a crude oil feed having an Api specific gravity of 9.4, a sulfur content of 0.02 g sulfur, and a residue content of 0.40 g per gram of crude oil feed (green, Canada, Rammings = zone) is heated in an addition container to 15〇c. This heat transfer was continuously metered into the reactor at 10.5 g / min from Tianligu in an attempt to maintain the crude oil feed level at 50% of the reactor volume. However, this rate was not sufficient Maintain this level. The oxane / steam / crude feed was contacted with the catalyst at an average internal reverse C tamping degree of 456 μ. The contact of the pinane / steam / crude oil feed with the catalyst yields a complete product (in this example, it is in the form of steam flowing out of the reactor). A total of 1640 grams of crude feed was processed over a 6 hour period. From the difference between the initial catalyst weight $ and the weight of the residue / catalyst mixture, it is known that 0.085 grams of coke per gram of crude oil remains in the reactor. From the contact between the crude oil feed and methane in the presence of ^ VRhcovcs / O3 catalyst, the crude product per gram of crude oil feed was at a value of 0.931. The complete product is a gas containing 0.03 t per gram of complete product and 0.97 grams of crude oil product, excluding the amount of scorch and water used in the reaction. The gas system contains 0.014 g of hydrogen per gram of gas, 0.018 g of carbon dioxide, 0.13 g of nitrogen sulfide, and 68 g of non-condensing type f. From the amount of hydrogen sulfide produced, it can be estimated that the sulfur content of the crude feed was reduced by 18% by weight. As shown in this example, hydrogen, hafnium oxide, and -carbon oxide are generated. The molar ratio of carbon monoxide to carbon dioxide is 0. #. The q-c: 5 hydrocarbon system contains 0.30 g of a dagger compound, 0.32 2005200535229 g of a C3 compound, 0.26 g of a C4 compound, and 0.1 g of a c5 compound per gram of hydrocarbons. The weight ratio of isoprene to n-prene in non-condensable fes was 0.3. The weight ratio of isobutane to n-butane in the non-condensing cigarettes was 0.189. The c4 compound has a butadiene content of gram per gram of the C4 compound. The weight ratio of α (: 4 olefin to intramolecular c: 4 olefin is 0.75. The weight ratio of α (5 olefin to intramolecular olefin is 1.08. The data in Example 25 confirms: a relatively high sulfur crude oil feed Continuous processing with the same catalyst in the presence of coke has not weakened the activity of the inorganic salt catalyst and produced a crude oil product suitable for transportation. It is advisable to feed and cover the oil at j £ 2g ^ i / RbiCCK / Cs, c0_ 3 Contact · —The equipment and reaction steps were performed using the conditions as described in Example 26. The K2C03 / Rb2C03 / Cs2C03 catalyst (5 6 · 5 g) was packed into the reactor. A total of 6 hours of processing were performed 2 5 5 Θ grams of crude oil feed. From the difference between the weight of the initial catalyst and the weight of the residue / catalyst mixture, it can be known that, based on the weight of the crude oil feed, there are 0 · 丨 14 grams of crude oil per gram ... I hate it in the reactor. Each gram of crude oil feed produces a total of 0.89 grams of meta products. The Haiyuan full product system contains 0.04 grams of gas and 0.96 grams of crude products per gram of complete product, excluding The amount of oxane and water used in the reaction. The gas system contains 0.021 grams of tritium per gram of gas and 0.018 grams of Oxidized 2 grams of carbon monoxide, 0.18 grams of hydrogen sulfide, and 0.65 grams of non-condensable hydrocarbons. From the amount of hydrogen sulfide produced, it can be estimated that the sulfur content of crude oil feed contains burdock 1 4 weight 1 %, Which is based on the weight of the crude oil feed. As shown in this example, hydrogen, carbon monoxide, and carbon dioxide are produced. The oxygen molar ratio of carbon dioxide to carbon dioxide 200535229 is 0.6. C ^ C: 6 hydrocarbons Each gram of C2-C6 hydrocarbons contains 0.44 grams of C2 compounds, 0.3 grams of C3 compounds, 0.19 grams of C4 compounds, and 0.068 grams of C5 compounds. Isopentane versus n-pentane in non-condensable hydrocarbons The weight ratio is 0.25. The weight ratio of isobutane to n-butane in non-condensing cigarettes is 0.15. The compound system has a butadiene content of 0.003 grams per gram of the compound. This example demonstrates: equivalent High-sulfur crude oil feed (2550 g crude oil feed) repeated processing of the same catalyst (56 · 5 g) in the presence of coke did not impair the activity of the inorganic salt catalyst, and a crude oil product suitable for transportation was prepared. In this description, various modifications and substitutions of the present invention are specific to the invention. It will be obvious to those with ordinary knowledge in the art. Therefore, this description should be construed as an example only and is intended to teach the general way for those with ordinary knowledge in the technical field to which the present invention pertains to implement the present invention. The form of the invention described and illustrated is an example of a version of the present invention. Elements and materials can replace those exemplified and described herein, the number of injuries and procedures can be reversed, and certain features of the invention can be independently used. After benefiting from the description of the present invention, all of them will be understood by those with ordinary knowledge in the 7 members of the present invention. Variations can be made in the cattle described herein without departing from the spirit and scope of the invention as described in the scope of the following patent applications. Also [Schematic explanation] / 本 &amp; 日月 # The advantages will be more clearly understood by those with ordinary knowledge in the technical field to which the present invention pertains with reference to the above detailed description. A schematic illustration of a specific example of a contact system in which a crude oil feed is contacted with a chlorine source in the presence of one or more catalysts to produce a complete product. FIG. 2 is a diagram showing another specific example of a contact system for contacting a crude oil feed tray _ dike and lice source in the presence of one or more catalysts to produce a complete product. ^ Figure The figure is a schematic diagram of a specific example of a separation zone combined with a contact system. Figure 4 is a diagram of a specific example of a blending zone combined with a contact system. 5 is a diagram of a specific example of a separation zone, contact zone and blending zone. Schematic diagram of a specific example of a heavy contact system. Figure 7 is a schematic diagram of a specific example of an ionic conductivity measurement system. The properties of crude oil and crude oil obtained by contacting a crude oil feed with a transition metal sulfide catalyst are shown in FIG. 7. List of product properties. 〃 Figure 9 is a list of crude oil feed composition and non-condensable hydrocarbon composition obtained from &quot; contacting a crude oil feed with a transition metal sulfide catalyst. A list of the properties and composition of crude oil products that are in contact with the transition metal body examples obtained from the genus ... Figure e. Current vs. Wenlu: The measurement of the log 10 of ’exhaust gas ions measured by AP measured on AP. Resistance pair: A graph of the log 10 of the ratio of the inorganic salt catalyst and the inorganic salt's electricity to 2: 1 resistance to carbopotassium. Figure 13 is a graphical representation of the log resistance of temperature versus logl0 for NW / K2c03 / Rb2C03 114 200535229 versus potassium carbonate resistance. Trays: Μ βΓ, anti-night body warp and gas for various different crude oil feeds. Weight percentages of hydrogen sources produced by specific examples of media contact Figure 15 shows the weight percentages of crude oil products from the specific examples of contacting crude oil feed with the production shield, Graphic illustration of carbon number. List of ingredients made by specific examples of contact with oil feeds in contact with inorganic salt catalysts, metal salts or dishes. Even though the present invention is susceptible to various modifications and alternative forms, specific examples are shown in the drawings as examples, and will be specifically described in this section. The drawings may not be drawn to scale. It should be understood that the detailed description of the review ^ drawings and developments ^ indicates that it is not intended to limit the present invention to the disclosed special forms. The invention is intended to cover the spirit of the present invention, which is contrary to Fan Li 1. All variants and alternatives can be made. ^ [Description of main component symbols] 100 Contact system 101 Crude oil supply source 102 Contact area 104 Conduit 106 Circulating conduit 108 Conduit 110 Flow control valve 110 'Flow control valve 112 Gas inlet 115 200535229 i 14 Steam inlet 116 Separation zone 1 18 Conduit 119 Crude Product Receiver 120 Conduit 122 Contact System 124 Separation Zone 126 Conduit 128 Conduit 130 Contact System 132 Separation Zone 134 Conduit 136 Conduit 138 Conduit 140 Blend Zone 142 Conduit 144 Conduit 146 Multiple Contact System 148 Contact System 150 Conduit 152 Conduit 154 Catheter 156 Quartz Container 158 Sample

116 200535229 160 162 164 166 168-170 172-180 182-184 186-188 190-192 194-196 198-200 Power metal wire metal wire meter ion current vs. temperature plot resistance curve vs. temperature plot relative resistance curve Plotting temperature vs.% coke produced% wt. Liquid hydrocarbons wt% gas produced% carbon number distribution

117

Claims (1)

200535229 10. Scope of patent application ... 1. A method for manufacturing crude oil products, including: ... The following are liquid, crude, and crude products at 25 X and 0.11. , 2 grams of residual residue V ",, Γ feed has at least metal per gram of crude oil feed m 3 li ... organic salt catalyst contains at least two kinds of inorganic = out =: salt catalyst shows in-temperature range The exhaust gas is exhausted; = pound point, as measured by the instantaneous analysis (TAP), at least one of: the temperature range of the pound point is between the two inorganic metal salts; and% temperature and 温度The residual salt of the inorganic salt catalyst $ DSC temperature T3: Γ makes the crude oil product have a residual content of at most the dry weight of the crude oil in grams. The content is based on the residual content per gram of crude oil product. It is measured by ASTM method D5307. The method of item 1 in the salt =,! :: = 'wherein the two kinds of inorganic gold' has a DSC temperature above 500 ° C. Catalyst 1 = The method of claiming item No. of the patent scope, wherein the inorganic salt catalyst is within the range of D s C, w j ^ p e ^. The temperature is between 45 ° C or 300-400 ° C. The method of claiming any one of the patent scope 帛 i_3 J, 1 嗲 exhaust gas contains water vapor and / or carbon dioxide. J. A method of manufacturing crude oil products 5 comprising: contacting eight crude oil feeds with a hydrogen source in the presence of an inorganic salt catalyst to produce a complete product of the "oil product, wherein the crude product is at 25 ... and 118 200535229 MPa is a liquid mixture, the crude oil feed has a residue content of at least 0.2 grams of residue per gram of crude oil feed, the inorganic salt catalyst contains at least two inorganic metal salts, and the ionic conductivity of the inorganic salt catalyst The ionic conductivity of at least one of the inorganic salts of the inorganic salt catalyst at a temperature in the range of 3000c to 5000c; and The conditions of contact with work 1 make the crude oil product have a residue content of at most 30% of the crude oil into the slag 3, which is expressed in grams of crude product per gram of crude oil product, where the residue content is as measured by ASTM method D5307. Tester 6. A method for producing a crude oil product, comprising: adjusting an inorganic salt catalyst; contacting a crude oil feed with hydrogen from the presence of the adjusted inorganic salt catalyst to produce a complete product of a crude oil product, wherein the Crude products are at 25. It is a liquid mixture at 0.101 MPa, and the crude oil feed has a residue content of at least 0.2 g of residue per gram of feed; and 杳 = contact conditions so that the crude oil product has at most feedstock for the crude oil. ::: Residual content in% of Li, which is expressed in grams of residual a per gram of crude oil product, where the amount of residual is as measured by astmw-::: Send: Method of Patent Scope Item 6 Where the material exhibits electrical conductivity before the ionic conductivity node exhibited immediately after withering. Money salt catalysts are adjusted 8. The method such as item m in the patent application range, wherein the catalysts exhibit the ionic conductivity of the two ', ^ inorganic salt catalysts before adjustment at 3, c. ㈣ Below the 9 · Method of applying for any of the patents㈣ · 8 of the methods, wherein the 1] 9 200535229 inorganic salt catalyst contains one or more alkali metal carbonates, one or more soil-deficient octagen carbonates , One or more alkali metal hydroxides, one or more alkaline earth metal hydroxides, one or more alkali metal hydrides, one or more alkaline earth metal vapors, one or more alkali metal one or more sulfides, one or One or more sulfides of one or more alkali 2 metals, one or more alkali metals, one or more alkali metals, one or more amidoamines, or a mixture thereof. 10. The method according to item 9 of the scope of patent application, wherein the metal is sodium, potassium, rubidium, cesium or a mixture thereof, and / or the one or more metals are metal, magnesium or a mixture thereof. η. The method according to any one of claims 1 to 10, wherein the hydrogen source includes hydrogen, light hydrocarbons, water, or a mixture thereof. 12 · The method according to any of claims 1 to 11 of the scope of patent application, where contact between the crude oil feed and the hydrogen source in the presence of an inorganic salt catalyst occurs in it 'and the method further includes before the contact Or the method of $ = neutral term, and further part of the vapor of the method is shaped 13. The complete product of at least a part of any of claims 12 to 12 of the scope of the patent application is made by steam, including condensing at least one crude product at 25 ° C and 0.11 MPa. : Control the contact conditions so that: two:; ::: 15 g, at most 0 g, or at most 0.05, and L with non-condensable hydrocarbons at 0.101 MPa. As determined by Bailey's dry balance 120 200535229 1 5 · The method according to any one of claims 1-4 in the scope of patent application, wherein the crude oil feed contains 0.2-0.99 grams per gram of crude oil 0.3 g-0.8 g of residue. 16. The method according to any one of claims 1 to 15 of the scope of application for a patent, wherein the crude oil product contains 0000 1-0. 03 g or 0.0001 g of coke per gram of crude oil product. 17. The method according to any one of claims 1 to 16 of the scope of the patent application, wherein the crude oil feed also has a TAN, a total expressed in grams of Ni / V / Fe or grams of heteroatoms per gram of crude oil feed. Ni / V / Fe content and total heteroatom content, and also control the contact conditions so that the crude oil product also has at most 90% of the TAN, total Ni / V / Fe content, and / or total heteroatom content of the crude oil feed. TAN, total Ni / V / Fe content and / or total heteroatom content. 18. The method according to any one of item 17 of the scope of patent application, wherein the crude oil product is a distillate mixture of 0-0001-0.9 g per gram of original. The oil product also contains 0.00001-0.2 grams of light oil, liquid, 0.0001-0.99 grams of vacuum gas oil or the method in any one of the scope of the • D application patent, straight = = one step includes combining the crude oil product with -A crude oil that is the same as or different from the crude feed is combined to form a blend. 20 · —A kind of crude oil product. ^ ^ Any of the items 1 to 19 of the… mouth is obtained by the method of applying for the scope of patent application. 21 · —A method for manufacturing a fuel for a shipping vessel, which includes processing such as lubricants, chemicals, or blends. ^ Patent 20th; crude oil shame in the staff 121 200535229 22. Such as The method of claim 21, wherein the processing includes distilling the crude product or the blend into one or more German cents. 23. The method of claim 21 or 22, wherein the processing includes adding Hydrogen treatment XI. Schematic: See next page 122