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TW205576B - - Google Patents

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TW205576B
TW205576B TW081104382A TW81104382A TW205576B TW 205576 B TW205576 B TW 205576B TW 081104382 A TW081104382 A TW 081104382A TW 81104382 A TW81104382 A TW 81104382A TW 205576 B TW205576 B TW 205576B
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Taiwan
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fermentation
oil
item
ester
alkyl
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TW081104382A
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English (en)
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Hercules Inc
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
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    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282—Addition polymers
    • D04H1/4291—Olefin series
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D06M13/17—Polyoxyalkyleneglycol ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2243—Mono-, di-, or triglycerides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10—Methods of surface bonding and/or assembly therefor
    • Y10T156/1052—Methods of surface bonding and/or assembly therefor with cutting, punching, tearing or severing
    • Y10T156/1062—Prior to assembly

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

Β6β 經濟部中央標準局员工消費合作社印製 邮挪- 五、發明説明（1 ) 本發明供两於一種處理疏水性含聚丙烯鐵鎗之表面以 改良其潤滑性及抗靜霣性並且幫肋加工其成疏水性不雄 物货品。 常見之加工作業，如旋紡、伸拉、捲曲、橡理，從習 用之含聚烯原料it雒、未處理疏水性鐵品製造不鐵物料 子時很快地變成不可加工的，此係因為摩擦及靜霣荷聚 集所致。 已知，例如於美豳専利第3, 341,45 1號中，含磷酸_ »之抗靜霣劑會幫助習用鑛維之加工，但是該抗靜霣處 理亦使所製之纖維及不繊料子比未處理之紡絲雄維更具 親水性。 亦知，例如於美团専利第3,423,314狭中，二甲基聚 矽氧烷液為對於合成鐵維有效之潤滑劑，而即使以已知 之抗霣劑處理其亦不具抗靜霣性。 亦知，例如於美國專利第4,938,858號中，用B中和 之磷酸酯處理含聚烯雄雒之表面，之後用聚（二烷基矽 氣烷）處理（較宜為在任何錤縮步鼸後），以增加其潤滑 性及抗靜電性且幫助加工成疏水性不嫌物貨品，並保一 定程度的疏水性以便可接受於用作《人衡生方面（如月 經物品、可丢棄式尿布、失禁墊等等，其有流釀吸收核 心靥及隔離該已吸收於核心層之流釀的疏水性材料層。 玆有一種改良需要，即給予含聚烯疏水性鑛維或絲抗 靜電性及潤滑性，侔較少被其之疏水性或黏*性干擾而 -3- (請先閲讀背面之注意事項再填寫本頁) 裝· 訂- 線< 本紙張尺度遠用中釀家樣準(CNS) T4規格(210X297公 81. 5 . 20.000(H) 經濟部中央橾準局3工消費合作杜印製 2〇δ&7β ； Ί Α6 •· -7. ' ι Β 6 ' — —-—— Γί ^ · - j —-. — - 五、發明説明（2) 幫助加工。 本發明之方法俱用於*理疏水性含聚烯雄維之表面以 便改良其潤》性及抗靜霣性，該方法包括将掖狀癎滑油 劑塗於一擠製含聚烯繼绻或絲之表面t其特微在於該油 劑像苗自： (1) 多元酵，如下式： (R) m -c-(CH 2 OH) 或 4-m
CH 2 -OH
I (CH-OH)n
I
CH 2 -OH 其中R换C1-C4院基：僳0-3而n供0-4: (2) 水溶性酯或聚酯，僳得自該多元酵輿高至6鏑硪 原子的線型或分枝鐽脂肪酸反應者； (3) 二酵，你得自該多元酵輿璣氣乙烷之反應者： 然後機械加工該鑛錐或絲，該油麵不但提供加工 作業之趙滑性而且因缺少足夠之親油性取代基而 在雄維或絲上産生霣要之界面活性劑效果。 在油Μ處理後，加工步《可包括捲曲、選擇性之再整 理、切•剌（通常至3/4"-1 1/2”長）或Κ理（形成繼維布>, 然後依習用方式收集黏合以得到親水性不織物料子。 較佳，在機械加工步«中至少之一者後.用水洗該油 劑處理過之纖維或絲，以便至少除去某些油两。 較佳之上述（1)中的多元酵你丙三酵、乙二酵、丙二 (請先閲讀背面之注意事項再填窝本頁) -裝· 訂- 線· 本紙張尺度遑用中家樣準(CNS)甲4規格(210X297公麓) 81. 5. 20.000(H) A 6 B6 五、發明説明（3 ) 酵、新戊二酵、三羥甲基乙烷、三羥甲基丙烷及異戊四 酵〇 較佳之（2)中的水溶性酯或聚釀像得自（1)中之較佳 多元酵輿离至6鵪磺原子的嫌型或分枝鰱麻肪酸反鼴而 得到酯類如甘油三醮酸酯、異戊四酵四醋酸酸、丙二酵 二丙酸酯、及三羥甲基丙烷二丁酸酯。 較佳之（3)中的二酵可亦為被一离至6鏑硪原子之醣 基所包覆（capped)之二酵，係得自由該較佳之多元酵輿 環氣乙烷反應者。二酵之較佳例子你聚氣乙烯二酵（P〇E 二酵較佳為分子量400或2000)、POE二酵，較佳為10契 耳Ρ0Ε對1其耳甘油（稱為P〇E(10)甘油）、P0E(20)«萄 糖酵、P〇E(10)«萄糖酵二丙酸酯、及聚乙二酵（PEG)二 醣酸較佳為分子董6000更佳之二_傜得自由多元_ 舆琢《乙烷和离至約20X琛氣丙烷之組合物反應而得到 一種嵌段或無規型態聚《某烯二酵，例如丁基包覆EP/ P0聚合物（90/10比率，平均分子悬1〇〇〇)。 一般而言，該油_可用於本發明之方法中，不管是用 作初紡絲油則或再整理油_，都供為水溶性油_成分具 有低或有限之界面活性劑性質，在下式所得界定類別内 (請先閲讀背面之注意事項再填寫本頁) 裝· 訂- 線. 經濟部中央標準局貝工消費合作社印製 (R)rn -C-(CH 2 OR)Λ 4-m (1) CH 2 -OR a j (CH-OR 2 ) n (2) | CH 2 OR 2 -5 - 本紙張尺度遑用中困a家樣準(CNS) T4規格(210X297公*) 81. 5. 20,000(H) Μ 經濟部中央標準局员工消費合作社印製 五、發明説明u) R 2 -(OCH 2 CH 2 ) 〇 -OR a (3) CH a R 2 - [ (OCH 2 CH a ) p (OCH a CH) q ] -R 4 (4) 其中各R你氫或Ci -C4烷基•包括CH3 -及C4H9 R、R2、R3、及IU各僳為氫或一直鰱或分枝低分子M S 基或烷《基，包括 CH3C0-SCH3(CH2)4C0-、CH3-0-、CH3 (CH2)s-〇-; 傈 1-3 ; η 僳 0-4 ; 〇 僳 2-50; Ρ你2-50; <ι像1-10;而P/q樣至少4。 更佳之油薄為聚氣乙烯二酵（Ρ0Ε二酵）400、Ρ0Ε二酵 2000、P0E(10>甘油（；一種方便上的缩寫，通常當作10其 耳琛氣乙烷對1其耳甘油）、P0E(20)«萄糖酵、POE(IO) «萄糖酵二丙酸_、聚乙二酵（PEG>600二»酸酸、或丁 基包覆ED/P0聚合物（9 0/10fch率，平均分子量10 00)。 液狀油涮（若須要，加上一習用量的抗靜霣«)可用任 何習用之手續塗於«維或絲之表面，例如用沈漫、噴》 或輪印，然後乾錄。産品可能為純淨形式、水溶掖形式 (1-99重量X)、或水/油乳化液。較佳為在鱖冷步*後立 邸藉由滾筒將其水溶液帚至纖雄或銶上。較佳之塗用量 約0.02X-0.8X,更佳為0.1X-0.5X水溶液，基於结餓維 重量。 較佳之再整理步*可包括：於鑛維捲曲站中或下游畤 ，塗用0.05X-0.8X,且較佳為0.1X-0.5X(佔纖維重）之 再整理油劑組成物。該再整理油痢包括： 一 6 - (精先閲讀背面之注意事項再填寫本頁) 本紙張尺度逍用中«家揲毕(CNS)甲4規格(210x297公*) 81. 5. 20.000(H) 經濟部中央標準局员工消费合作社印製 2,055^^ 9W i；i B6 WTiTl 五、發明説明（5 ) (A>佔組成物重董約0X-65X的如下式之聚矽氣烷至少 之一者
I X-(S i-0)r-Y (4)
iIV 其中X及Y各傺疏水性化學衊基，如低级铳基； 各RIV偽各自為磁基•如甲基或辛基；且r你為約 10以上且較佳為离至約50之囿的正數； (B)佔再整理油劑組成物約35X-100X的中和《酸酯至 少之一者，當作抗靜電_，如下式： 0
II N (Alk-0-)s P-0 CRT)t (5) 其中Aik傜為低级烷基，包括Ci-C8烷基，較佳為 C4-C8烷基，例如丁基或辛基； 以傜胺基或«金屬； s及t各供不小於約1之正數，其和約3。 「含聚烯鐵維或絲j 一飼包括遽鑛及短鐵（切醑 > 熔紡 繼雒·可得自習用之同排聚丙烯及/或已知之其孩水硅 共聚物輿乙烯、卜丁烯、4-甲基戊烯-1等等之摻合而得 。産出之少紡絲熔釀的平均分子量約3X 10s至約5X10 ,分子董分佈約5.0-8.0,纺鐵熔*之流動速率約13.0 克/分至約40克/分•雄維之紡絲上油溫度約220t： -315t： (請先閲讀背面之注意事項再填窝本頁) 裝· -訂- 線· 本紙張尺度遑Λ中·國家«竿(CNS>甲4規格(210x297公 81. 5. 20.000(H) 經濟部中央標準局貝工消費合作社印製 五、發明説明（6 ) 含聚烯紡絲熔錶之定義中亦包含各種習用纖維添加用 ，包括pH安定劑如硬脂酸鈣、抗靜霣用、及顔料，如壜 白劑及着色劑，包括Ti02。大黼上，該添加繭之量為 佔紡絲熔讎重量的約0.05-3X。 以下更進一步用實例及表來銳明本發明，其中吸收度 拥試傜依照ASTM拥試方法D-1117-79,其中將5克乾燥 處理遇之短鑛維鬆散地裝於50cc之金屬纗藍内，秤霣然 後將其置入一桶水内。3 0秒後，除去藍子，漏滴（排水） 30秒，然後秤重以蘭得水吸收蛋及吸收度百分率（以重 量基準計算）。1LSLL 由習用安定聚丙烯批（batch)製得聚丙烯織雄試櫬S-1 、S-2及S-3。該聚丙烯批傜為Η狀，分子最分佈約5.0, 溶臁流動速率約13.0克/10分鏞。 然後将各樹脂試樣與0.5重置X之習用pH安定雨即硬 脂酸鈣及0.1重嫌X顔料卽二氣化鈦於揑合摻合機中混 合60分鐘。然後將此摻合漿於300 t：擠遇一 67 5圖孔之 紡絲板，並於周圃溫度用空氣將所得之擠製絲朦冷，之 後將甘油及嗶《中和磷酸酯之如表I的初紡狳油劑（A" 、B ”或C”）用滾简塗施檐局部地塗於各絲上，給予佔乾 鑛維重董約0.3X-0.5X之初油。 然後將所得塗過之絲拉伸成約2.0-2.4dpf(克/9 000公 尺）並用習用之蒸汽捲曲檐（100*C)捲曲，同畤使用” D或 -8- (請先閲讀背面之注意事項再填窝本頁) 裝. 訂· 線. 本紙張尺度遑用中爾家樣準(CNS)甲4規格(210x297公釐) 81. 5. 20,000(H) A 6 B6 五、發明説明（7 ) ”E”（油劑D傜單獨之囑啉中和磷酸醯，而油劑E你50X/ 50X比率之痗啉中和磷酸酯比聚二甲基矽氣烷，得自馨 合磺化物公司〈Union Carbide〉之LE-458 HS)，並使經 過摧曲埔塞箱之蒸汽噴射孔。對照例使用得自市場上之 George A. Goulston(在北卡羅來纳州之門鼸郡）公司的 Lurol PP-912當作標準親水性纺絲油_。 然後乾燥該«理遇之銶，切成1.5吋短纖•保留作吸 收度及疏水性拥試。结果報告於表I。•mm2 揑合相同批次之樹脂及相同之安定阐及顔料，量及方 式如實例1所述者，而製得聚丙烯雄維試樣S-4、S-5及 S-6。然後於295 t：将該摟合»擠遇一 782國孔之紡絲 板，並於周圍租度骤冷。之後用滾简塗施機及IX錚中和 磷酸酯之水溶液笛紡絲油黼而局部地處理所得之絲，因 而該絲得到佔乾纖維重Μ約0.1ΘΧ之初油M。 所得之絲然後如先前地拉伸成約2.0-2.4dPf,蒸汽捲 曲，及將再整理油劑送經捲曲缜塞箱之蒸汽嘖射以得到 約0.20X-0.50X百重比之最後油劑，然後使該織維乾嫌， 切成1.5吋長短纖，保甯用於拥試。結果報告於表I。 (請先閲讀背面之注意事項再填窝本頁) 裝. 訂· 線· 經濟部中央標準局貝工消費合作社印製 -9- 本紙張疋度遑用中飄·家樣毕(CNS)甲4規格(210 X297公*) 81. 5. 20.000(H) 205576
66 AB 五、發明説明（8) 試樣《 S-l S-2 S_3(對照） 劑油絲纺 (*
··· ABC 表I 3>程度再處理油两 0.33X D. 0.4ΘΧ E. 0.30X C. 播 度 欠X X X MV9 5 2 S5 7 8 5 3 總 1 MX X X &9 ο ο 和3 7 9 B · · ♦ Μκοι ο 烷 20氧 91矽pp聚 0 0 1* 油油Γ0¥ 甘甘LU二 及及如及 醣酸，_ 酸釀劑_ 磷磷油。转 和和性酯和 中中水酸中 啉啉親雄£ ««之和« 之之用中之 率率常啉率 比比烯一tth X X丙之X 5 3SIO 7 8S澜 5 x/x/定單x/ 2517鑼為50 A B c D E 00000 油油油油油 表I * 3 試樣紡絲油繭（· 6)程度再處理油總油麵總吸收度
6 4 5 6 -II · s s S
0.16X G. 0.21X 44.7X 0.16X H. 0.26X 109.6X 0.16X I. 0.49X 87.5X 油劑F係鉀中和磷酸酯。 油劑G像50X/50X比率之鉀中和磷酸酯及聚二甲基矽氣烷。 油WH你50X/50X比率之押中和磷酸醣及聚氣乙烯二酵（400)。 油劑I傜17X/83X比率之鉀中和羁酸酯及聚氧乙烯二_(400>。 (請先閲讀背面之注意事項再填寫本頁) 裝* 訂_ 線< 經濟部中央標準局員工消費合作社印製 -10- 本紙張尺度逍用中家«準(CNS)甲4規格(210x297公釐) 81. 5 . 20.000(H)

Claims (1)

  1. 六、申請專利範園 第81104382號「可梳理疏水聚丙烯織維」專利案（82年4月修正 1. 一種處理疏水性含聚丙嫌雄維之表面以便改良其潤滑性 及抗靜《性的方法，包括将液狀潤滑油劑塗於一擠裂 含聚丙嫌鑛維或絲之表面，其特徼在於該油劑你遘自： (1)多元酵，如下式： (R) m -C- (CH 2 0H)4_m 或 CH 2 -0H I (CH-OH) n I CH 2 -OH 其中R 烷基；係0-3而η供0-4; (請先閲讀背面之注意事項再填寫本頁) 經 濟 部 中 央 標 準 局 員 工 消 費 合 作 社 印 製 (2) 碩原子(3) 然後機 之潤滑 絲上産 .如申請 劑傺水 硪原子 .如申請 劑偽二 .如申諳 劑傺二 所包覆 水溶性酯 的線型或 二醇，傜 械加工該 性而且因 生重要之 專利範圍 溶性酯或 的線型或 專利範困 醇，得自 專利範豳 酵，得自 的（1)多 或聚酯， 分枝鰱脂 得自該多 鐵維或絲 缺少足夠 界面活性 第1項之 聚酯，係 分枝鏈脂 第1項之 (1)多元 第3項之 琛氣乙烷 元醇反應 换得自該 肪酸反應 元酵舆環 ,該油劑 之親油性 劑效果。 方法，其 得自（1) 肪酸反應 方法，其 酵輿琛氣 方法，其 與一高至 者。 多元酵輿高至6傾 者； 氣乙烷之反應者； 不但提供加工作業 取代基而在纖維或 進一步特擻在於油 多元酵與高至6鍺 者。 進一步特徽在於油 乙烷反應者。 進一步特锹在於油 6傾磺原子之酯基 本紙狀度顧㈣岐料(娜）T4_(21Qx297公垃） 81. 1. 5.000(H) A7 B7 C7 D7 六'申請專利範園 5. 如申請專利範鼷第1項之方法，其進一步特徽在於油 薄锿二酵、乙二酵、丙二酵、新戊二酵、三羥甲基乙 烷、三羥甲基丙烷、異戊四酵、或蕕萄糖酵。 6. 如申請専利範園第3或4項之方法，其進一步特徽在 於油薄你聚氧乙烯二酵（POE二酵\) 400、POE二酵2000 、P0E(10)二酵、p〇E(20)« 萄耱酵、聚乙二酵（PEG) 600二_酸酯、或P0E(10)«萄糖酵二丙酸酯。 7. 如申請専利範鼷第1項之方法，其進一步特擞在於油 薄f僳嵌段或無規型態聚氣烷烯多元醇，偽得自⑴多元醇 與環氣乙烷及高至約20X的琛氣丙烷之組合反應者。 8. 如申請専利範匾第7項之方法，其進一步特徼在於油 劑你丁基包覆E〇/P〇(90/10其耳比）聚合物，平均分t 子量1000 。 9. 如申請専利範圍第1項之方法，其進一步特徴在 於油劑包括水溶性化合物，具有低或有限之界面活性 劑性質，於下式界定類別内·♦ (R)m -c- (CH 2 OR)4-m ⑴ C Η 2 ^ 0 R 2 I (CH-OR 2 )„ (2) 經濟部中央標準局員工消費合作社印製 I CH 2 OR 2 R 2 - (〇CH 2 CH 2 ) 〇 -OR 3 (3) CH a I R 2 - [ (0CH 2 CH 2 )p (〇CH2 CH)q ] -R 4 (4) -12- 81. 1. 5.000(H) (請先閲讀背面之注意事項再填寫本頁) 本紙诋尺度適川，卜H3 w家標苹(CNS) Ψ4規格(210x297公釐） A7 ' B7 ^05^6_ . dt ' 碡 六、申請專利範園 其中各R俗氫或C i -C 4烷基，包括CH 3 -及C 4 Η 9 -; R、R2、R3、及R4各你為氫或一直鏈或分枝低分 子量醯基或烷«基，包括CH3C〇-至CH3 (CH2)4C0-、CH3-〇-、 CH a (CH 2 ) 5 -〇-； b 係 1-3 ； n % 0-4 ;0 僳 2 - 5 0 ; p 係 2 - 5 0 ; q 傜 1 - 1 0 ;而 p / q 傜至少 4。 10. 如申請專利範圍第1項之方法.其進一步特撤 在於將中和磷酸酯當作抗靜霣劑塗於纖維，該中和 磷酸酯之式為： 0 II (Alk-0-)s P-0- (Rv)t (5) 其中Aik傜為低鈒烷基，包括Ci-Cs烷基，較佳 為C4-C8烷基，例如丁基或辛基；\ Rv偽胺基或齡金屬； s及t各傺不小於約1之正數，其和約3 。 11. 如申請專利範圍第10項之方法，其進一步特擻在於 抗靜電劑偽嗎啉中和磷酸酯。 請先閲讀背面之注意事項再填寫本頁) .^- *打. 經濟部中央標準局員工消費合作杜印製 .線. -13- 本紙張尺度通;丨】t «闽家櫺半（CNS”(M规格(2丨0x297公81. 1. 5,000(H)
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US5403426A (en) 1995-04-04
KR920021796A (ko) 1992-12-18
CA2069269A1 (en) 1992-11-29
AU1720992A (en) 1992-12-03
EP0962583A3 (en) 2000-01-05
EP0516412A3 (en) 1993-09-08

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