SK16995A3 - Method of vibration-pressing and apparatus for realization of this method - Google Patents
Method of vibration-pressing and apparatus for realization of this method Download PDFInfo
- Publication number
- SK16995A3 SK16995A3 SK169-95A SK16995A SK16995A3 SK 16995 A3 SK16995 A3 SK 16995A3 SK 16995 A SK16995 A SK 16995A SK 16995 A3 SK16995 A3 SK 16995A3
- Authority
- SK
- Slovakia
- Prior art keywords
- pressing
- press
- vibrations
- cavity
- approached
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 26
- 238000003825 pressing Methods 0.000 title claims description 36
- 239000000463 material Substances 0.000 claims abstract description 31
- 229920001187 thermosetting polymer Polymers 0.000 claims description 12
- 230000006835 compression Effects 0.000 claims description 7
- 238000007906 compression Methods 0.000 claims description 7
- 239000004033 plastic Substances 0.000 claims description 7
- 229920003023 plastic Polymers 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 239000010454 slate Substances 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 3
- 239000003999 initiator Substances 0.000 claims description 3
- 230000002787 reinforcement Effects 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims 1
- 239000004634 thermosetting polymer Substances 0.000 claims 1
- 238000000465 moulding Methods 0.000 abstract description 16
- 238000000748 compression moulding Methods 0.000 abstract 1
- 239000000654 additive Substances 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B11/00—Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses
- B30B11/02—Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses using a ram exerting pressure on the material in a moulding space
- B30B11/022—Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses using a ram exerting pressure on the material in a moulding space whereby the material is subjected to vibrations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/56—Compression moulding under special conditions, e.g. vacuum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2791/00—Shaping characteristics in general
- B29C2791/004—Shaping under special conditions
- B29C2791/008—Using vibrations during moulding
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
Description
Spôsob vibračného lisovania a zariadenie pre uskutočňovanie tohoto spôsobu.Method of vibratory pressing and apparatus for carrying out this method.
Oblasť technikyTechnical field
Vynález sa týka tvárnenia a predovšetkým sa týka lisovacej techniky, ktorá podporuje vyplnenie lisovacej dutiny lisovaným materiálom.The invention relates to molding and more particularly relates to a molding technique which promotes the filling of the mold cavity with molded material.
Stav technikyState of the art
Požiadavkom je, aby v priebehu lisovacej operácie bol lisovaný materiál privedený do všetkých krajov lisovacej dutiny tak, aby vznikol vylisovaný výrobok, ktorý presne kopíruje tvary a detaily tejto dutiny. Dosiahnutie tohoto požiadavku býva obtiažne, predovšetkým ak viskózny teplom vytvrditelný materiál začína vytvrdzovať už pri privádzanie do lisovacej dutiny. Teraz bol vyvinutý spôsob lisovania a zariadenia pre uskutočnenie tohoto spôsobu, ktoré pomáhajú zmenšiť uvedený problém.The requirement is that during the molding operation, the molded material is fed to all edges of the mold cavity to produce a molded product that accurately copies the shapes and details of the mold cavity. Achieving this requirement is difficult, especially if the viscous thermosetting material begins to cure when it is introduced into the press cavity. We have now developed a molding method and apparatuses for carrying out this method which help to reduce the problem.
Podstata vynálezuSUMMARY OF THE INVENTION
Spôsob lisovania vytvorený pódia tohoto vynálezu zahŕňa:The method of compression formed according to the invention comprises:
a) vytvorenie lisovacieho zariadenia, zahŕňajúceho aspoň prvú a druhú tvárniacu plochu vytvárajúcu lisovaciu dutinu, aspoň jednu lisovaciu plochu pohyblivú tak, že uvedené plochy sú umiestnitelné do vzájomne oddialenej a priblíženej polohy;a) providing a pressing device comprising at least first and second forming surfaces forming a pressing cavity, at least one pressing surface movable such that said surfaces are positioned in a mutually spaced and approached position;
b) umiestnenie vytvrditelného materiálu, ktorý má byť lisovaný, v uvedenej lisovacej dutine; ab) placing the curable material to be molded in said mold cavity; and
c) približovanie uvedenej aspoň jednej pohyblivej plochy z uvedenej oddialenej polohy do uvedenej priblíženej polohy a súčasné vystavenie vibráciám jednej alebo viacerých z uve2 dených lisovacích plôch tak, aby bol nevytvrdený materiál uvedený do kontaktu s v podstate celými uvedenými lisovacími plochami.c) bringing said at least one movable surface from said distal position to said approached position and simultaneously subjecting the vibrations of one or more of said press surfaces to contact the uncured material with substantially all of said press surfaces.
Naviac je pre zlepšenie vyplňovania lisovacej dutiny tepelne vytvrditeľným materiálom výhodné vystaviť tvárniacu plochu alebo plochy, tak ako boli vyššie opísané, vibráciám, čím dôjde k zmenšeniu sily nutnej pre zovretie lisovacej dutiny.In addition, in order to improve the filling of the molding cavity with the thermosetting material, it is advantageous to subject the molding surface or surfaces as described above to vibrations, thereby reducing the force required to clamp the molding cavity.
Výhodné je, ked je lisovacia dutina vytvorená prvou a protiľahlou druhou plochou a kedf tieto plochy sú vystavené vibráciám v opačných smeroch. Vibrácie sú potom výhodne také, ktoré spôsobia úplné vyplnenie dutiny lisovaným materiálom.Advantageously, the pressing cavity is formed by a first and opposed second surface and when these surfaces are subjected to vibrations in opposite directions. The vibrations are then preferably those which cause the cavity to be completely filled with the molded material.
Tieto vibrácie môžu zahŕňať priečne vibrácie aspoň jednej tvárniacej plochy, aby došlo v podstate k vyplneniu lisovacej dutiny tepelne vytvrditeľným materiálom. Vibrácie môžu dfalej zahŕňať vibrácie protiľahlých plôch medzi ich vzájomným oddialeným a priblíženým umiestnením, čím sa podporí zlisovanie materiálu medzi týmito plochami.These vibrations may include transverse vibrations of the at least one forming surface to substantially fill the press cavity with a thermosetting material. The vibrations may hopefully include vibrations of the opposing surfaces between their spaced and approached locations relative to each other, thereby promoting material compression between these surfaces.
Priečne vibrácie lisovacej plochy môžu zahŕňať priečny pohyb vo viac než jednom smere. Príkladne môžu priečne vibrácie zahŕňať v podstate ortogonálny vibračný pohyb aspoň jednej lisovacej plochy.The transverse vibrations of the press surface may include transverse movement in more than one direction. For example, the transverse vibrations may comprise a substantially orthogonal vibration movement of the at least one pressing surface.
Výhodné je tiež, ak lisovaný materiál obsahuje teplom vytvrditeľnú živicu alebo plast.It is also preferred that the molded material comprises a thermosetting resin or plastic.
Živica alebo plast môže byť prípadne zmiešaná s plnivami a s vláknitou výstužou. Teplom vytvrditeľná živica alebo plast môžu byť výhodne zmiešané tiež s iniciátorom alebo s katalyzátorom vytvrdzovania, čím sa dosiahne zlepšené vytvrdzovanie materiálu.The resin or plastic may optionally be mixed with fillers and fibrous reinforcement. Advantageously, the thermosetting resin or plastic may also be mixed with the initiator or curing catalyst to achieve improved curing of the material.
Výhodne obsahuje teplom vytvrdíteľný materiál polyesterovú živicu zmiešanú s bridlicovým práškom a sklenenými vlákna3 mi ako s výstužou a s iniciátorom vytvrdzovania. Materiál môže tiež obsahovať ďalšie prísady ako je drvený vápenec a mazivo, napríklad stearan.Preferably, the thermosetting material comprises a polyester resin mixed with slate powder and glass fibers as reinforcement and curing initiator. The material may also contain other additives such as crushed limestone and a lubricant, for example stearate.
Spôsob lisovania príkladne zahŕňa krok miešania, kde do teplom vytvrdítelnej živice alebo plastu sú primiešané vyššie uvedené výhodné prísady, a to pred jeho umiestnením v lisovacej dutine.The compression method includes, for example, a mixing step wherein the above-mentioned preferred additives are admixed into the thermosetting resin or plastic prior to being placed in the compression cavity.
Uvedený spôsob lisovania môže byť časťou systému v podstate plynulého lisovacieho pochodu, kde je uskutočňované množstvo takých spôsobov formou výrobnej linky. U výhodného uskutočnenia je jedna alebo viac lisovacích dutín vhodných pre uskutočnenie spôsobu podlá tohoto vynálezu umiestnená na dopravníkovom páse alebo podobne tak, že súčasne môže byť uskutočňované množstvo lisovacích krokov.Said pressing process may be part of a system of a substantially continuous pressing process where a plurality of such processes are carried out in the form of a production line. In a preferred embodiment, one or more pressing cavities suitable for carrying out the method of the present invention are disposed on a conveyor belt or the like such that a plurality of pressing steps can be performed simultaneously.
Ďalej je podlá vynálezu vytvorené zariadenie pre uskutočňovanie spôsobu lisovania tak, ako bolo vyššie opísané. Toto zariadenie zahŕňa:Furthermore, according to the invention, there is provided an apparatus for carrying out the compression method as described above. This equipment includes:
a) jednu alebo viac lisovacích dutín, kde každá táto dutina je vytvorená prvou a druhou lisovacou plochou;a) one or more press cavities, each cavity formed by first and second press surfaces;
b) prostriedky pre pohyb aspoň jednej lisovacej plochy tak, že uvedené plochy sú umiestnené do vzájomne oddialenej a priblíženej polohy; ab) means for moving at least one pressing surface such that said surfaces are positioned in a mutually spaced and approached position; and
c) prostriedky pre vytvorenie vibrácií jednej alebo viac uvedených plôch v priebehu postupu uvedenej aspoň jednej pohyblivej plochy z uvedenej oddialenej polohy do uvedenej priblíženej polohy, čím je v lisovacej dutine prítomný vytvrditelný materiál privedený do kontaktu s v podstate celými uvedenými lisovacími plochami pred tým, než je celkom vytvrdený.c) means for generating vibrations of one or more of said surfaces during the process of said at least one movable surface from said distal position to said approached position, whereby the curable material present in the pressing cavity is brought into contact with substantially all of said pressing surfaces before being completely cured.
Zariadenie podlá výhodného uskutočnenia vynálezu zahŕňa množstvo lisovacích dutín tak, že je vhodné pre použitie pri v podstate plynulom lisovaní, ako bolo vyššie uvedené. Prík4 ladne sú lisovacej dutiny umiestnené na dopravnom páse alebo podobnej dopravnej ploche. Vibračné prostriedky výhodne umožňujú vibrácie lisovacej plochy vyššie opísaným v podstate riadeným spôsobom.The apparatus according to a preferred embodiment of the invention comprises a plurality of press cavities such that it is suitable for use in a substantially continuous press as described above. For example, the press cavities are positioned gracefully on a conveyor belt or similar conveying surface. The vibration means preferably allows the pressing surface to be vibrated in a substantially controlled manner as described above.
U zvlášť výhodného uskutočnenia vynálezu zahŕňa lisovaný predmet krytinovú strešnú škridlu. V prípade, keď teplom vytvrditelný materiál obsahuje bridlicové plnivo, môže lisovaný výrobok zahŕňať krytinovú strešnú škridlu so vzhľadom prírodnej bridlice, predovšetkým ak lisovací povrch má reliéf povrchu zodpovedajúceho prírodnej bridlici.In a particularly preferred embodiment of the invention, the molded article comprises a roofing tile. In the case where the thermosetting material comprises slate filler, the molded article may comprise a roofing tile with the appearance of a natural slate, especially if the pressing surface has a relief surface corresponding to the natural slate.
U výhodného uskutočnenia vynálezu potom aspoň jedna lisovacia plocha vyššie opísaného lisovacieho zariadenia nesie doplnkový otlačok prírodnej bridlice.In a preferred embodiment of the invention, the at least one pressing surface of the above described pressing device carries a supplementary impression of the natural slate.
Prehľad obrázkov na výkresochBRIEF DESCRIPTION OF THE DRAWINGS
Vynález bude ďalej vysvetlený na príklade, zobrazenom na pripojených výkresoch, ktorý v žiadnom ohľade neobmedzuje rozsah tohoto vynálezu. Výkresy predstavujú schematický pohľad na zariadenie podľa vynálezu, ktoré je vhodné pre lisovanie a zobrazujú rôzne stavy v priebehu lisovacieho pochodu.The invention will be further elucidated by way of example, shown in the accompanying drawings, which in no way limits the scope of the invention. The drawings represent a schematic view of a device according to the invention which is suitable for pressing and shows various states during the pressing process.
Na výkrese je zobrazená forma, označená všeobecne vzťahovou značkou 1, ktorá pozostáva z dvoch polovíc 2, 3 formy. Zobrazené sú postupne polohy A, B, c formy 1 v priebehu lisovania.In the drawing there is shown a mold, generally designated 1, which consists of two mold halves 2, 3. The positions A, B, c of the mold 1 during the molding process are shown sequentially.
Príklady konkrétneho uskutočnenia vynálezuExamples of a particular embodiment of the invention
Teplom vytvrditeľný materiál 4 je umiestnený v lisovacej dutine 5 medzi čelnými plochami 2a, 3a polovíc 2, 3 formy 1. Lisovacie plochy 2a, 3a sú udržiavané na teplote okolo 120 ’C, pri ktorej dochádza k vytvrdzovaniu materiálu 4.The thermosetting material 4 is disposed in the press cavity 5 between the end faces 2a, 3a of the mold halves 2, 3. The press faces 2a, 3a are maintained at a temperature of about 120 ° C at which the material 4 cures.
Teplom vytvrditelný materiál 4 je pred umiestnením do lisovacej dutiny 5 namiešaný a odvážený, ako zobrazuje stav A. Polovice 2, 2 formy sú pre lahké vkladanie lisovaného materiálu 4 do dutiny 5 umiestnené v oddialenej polohe.The thermosetting material 4 is mixed and weighed prior to being placed in the mold cavity 5 as shown by state A. Mold halves 2, 2 are placed in a spaced position for easy insertion of the molded material 4 into the cavity 5.
Plochy 2a, resp. 3a zahŕňajú doplnkovo profilované vypuklé a zapustené útvary. Bočné steny 3b sú vybavené pružným povrchom 3c, ktorý znižuje poškodenie polovice 2 formy 1 pri spojovaní lisovacích plôch.Surfaces 2a, respectively. 3a include complementary profiled convex and recessed formations. The side walls 3b are provided with a resilient surface 3c which reduces damage to the mold half 2 when joining the pressing surfaces.
Ako zobrazuje stav B, polovica 2 formy postupuje smerom k polovici 2 formy, aby došlo k stlačeniu materiálu 4 medzi uvedenými plochami 2a a 2a. V priebehu postupu tejto polovice 2 formy je druhá polovica vystavená vibráciám v podstate horizontálneho smeru, čo na výkrese predstavuje šípka D. Tieto vibrácie napomáhajú vyplneniu dutiny 5 materiálom 4. Pružný povrch 3c je taktiež výhodný pre absorpciu vyššie uvedených vibrácií polovice 2 formy.As shown in state B, the mold half 2 proceeds towards the mold half 2 to compress the material 4 between said faces 2a and 2a. During the process of this mold half 2, the other half is subjected to vibrations in a substantially horizontal direction, which is an arrow D in the drawing. These vibrations help fill the cavity 5 with material 4. The resilient surface 3c is also advantageous for absorbing the above vibrations of mold half 2.
V posledných fázach uzavierania formy 1, ako zobrazuje na výkrese stav C, je polovica 2 formy vystavená taktiež vibráciám vo vertikálnom smere, ako ukazuje šípka E. Tieto vibrácie podporujú zlisovania materiálu 4 medzi plochami 2a a 3a.In the last closing stages of the mold 1, as shown in the drawing, state C, the mold half 2 is also subjected to vibrations in the vertical direction, as shown by the arrow E. These vibrations promote the pressing of the material 4 between surfaces 2a and 3a.
Forma 1 je potom zovretá a lisovacie plochy 2a a 3a sú vyhrievané dokial nie je dokončené vytvrdenie teplom vytvrditeiného materiálu 4 a dokial nie je vylisovaný výrobok dostatočne tuhý, aby mohol byť vybratý z lisovacej dutiny 5.The mold 1 is then clamped and the pressing surfaces 2a and 3a are heated until the curing of the thermosetting material 4 is complete and the molded article is sufficiently rigid to be removed from the pressing cavity 5.
Claims (10)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB929216968A GB9216968D0 (en) | 1992-08-11 | 1992-08-11 | Method of and apparatus for moulding |
| GB9306324A GB2272856A (en) | 1992-08-11 | 1993-03-26 | Vibrating mould surface while charging mouldable material to mould |
| PCT/GB1993/001684 WO1994004335A1 (en) | 1992-08-11 | 1993-08-09 | Method of vibration-moulding and an apparatus for carrying out the moulding |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SK16995A3 true SK16995A3 (en) | 1995-07-11 |
Family
ID=26301411
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK169-95A SK16995A3 (en) | 1992-08-11 | 1993-08-09 | Method of vibration-pressing and apparatus for realization of this method |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0655967A1 (en) |
| JP (1) | JPH07509672A (en) |
| AU (1) | AU4723593A (en) |
| CA (1) | CA2142108A1 (en) |
| CZ (1) | CZ33695A3 (en) |
| GB (1) | GB2272856A (en) |
| RU (1) | RU95101847A (en) |
| SK (1) | SK16995A3 (en) |
| WO (1) | WO1994004335A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5476617A (en) * | 1993-02-19 | 1995-12-19 | The Board Of Regents Of The University Of Wisconsin | Rotational and vibrational process for molding cellulosic fibers |
| US6149844A (en) * | 1994-09-09 | 2000-11-21 | Decta Holdings Pty Ltd. | Method of manufacturing composites |
| WO1998017457A1 (en) * | 1996-10-21 | 1998-04-30 | Erwin Ronald D | Molded lumber substitute and manufacturing method therefor |
| GB9821274D0 (en) * | 1998-10-01 | 1998-11-25 | Gribole Meirion | A plastics moulding press |
| DE10214626B4 (en) * | 2002-04-02 | 2004-06-03 | Buchwald, Schneider & Matten Gmbh | Press tool for the production of molded parts with resin mat or the like |
| DE102023115817A1 (en) * | 2023-06-16 | 2024-12-19 | Kiefel Gmbh | Process for producing three-dimensional products from a fibrous material using at least one molding tool and molding tool |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3123857A (en) * | 1964-03-10 | Plastic molding apparatus and method | ||
| GB627406A (en) * | 1946-10-02 | 1949-08-09 | Sidney Arthur Leader | Improvements in or relating to the manufacture of artificial teeth |
| CH477966A (en) * | 1967-07-14 | 1969-09-15 | Kabel Metallwerke Ghh | Process for producing molded articles from polyamides |
| FR2263051B1 (en) * | 1974-03-08 | 1976-12-10 | Fives Cail Babcock | |
| DE2558827A1 (en) * | 1975-12-27 | 1977-07-14 | Demag Kunststofftech | METHOD OF INJECTION MOLDING OF MOLDED PARTS FROM CERAMIC COMPOSITION AND INJECTION MOLDING MACHINE THEREFORE |
| GB2008023A (en) * | 1977-08-24 | 1979-05-31 | Daniels Stroud Ltd | Vibrating moulding material during injection or extrusion |
| GB2222547A (en) * | 1988-09-07 | 1990-03-14 | Distraker Limited | Apparatus and method for moulding articles from concrete or similar settable material |
| GB2224283B (en) * | 1988-10-28 | 1992-06-24 | Valle Roberto Dalla | Process for obtaining artificial stones for flooring and stone facing |
| US5182061A (en) * | 1990-07-20 | 1993-01-26 | Nisshinbo Industries, Inc. | Method of vibration-molding friction member |
-
1993
- 1993-03-26 GB GB9306324A patent/GB2272856A/en not_active Withdrawn
- 1993-08-09 CA CA002142108A patent/CA2142108A1/en not_active Abandoned
- 1993-08-09 AU AU47235/93A patent/AU4723593A/en not_active Abandoned
- 1993-08-09 CZ CZ95336A patent/CZ33695A3/en unknown
- 1993-08-09 JP JP6505991A patent/JPH07509672A/en active Pending
- 1993-08-09 WO PCT/GB1993/001684 patent/WO1994004335A1/en not_active Ceased
- 1993-08-09 EP EP94908059A patent/EP0655967A1/en not_active Withdrawn
- 1993-08-09 SK SK169-95A patent/SK16995A3/en unknown
-
1995
- 1995-02-10 RU RU95101847/25A patent/RU95101847A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB9306324D0 (en) | 1993-05-19 |
| CZ33695A3 (en) | 1995-09-13 |
| JPH07509672A (en) | 1995-10-26 |
| CA2142108A1 (en) | 1994-03-03 |
| GB2272856A (en) | 1994-06-01 |
| RU95101847A (en) | 1997-01-27 |
| AU4723593A (en) | 1994-03-15 |
| EP0655967A1 (en) | 1995-06-07 |
| WO1994004335A1 (en) | 1994-03-03 |
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