SE8503850D0 - NEUTRAL CIRCUIT PROMOTERS FOR SULFIDE MINERALS AND METHODS FOR USING SAME - Google Patents
NEUTRAL CIRCUIT PROMOTERS FOR SULFIDE MINERALS AND METHODS FOR USING SAMEInfo
- Publication number
- SE8503850D0 SE8503850D0 SE8503850A SE8503850A SE8503850D0 SE 8503850 D0 SE8503850 D0 SE 8503850D0 SE 8503850 A SE8503850 A SE 8503850A SE 8503850 A SE8503850 A SE 8503850A SE 8503850 D0 SE8503850 D0 SE 8503850D0
- Authority
- SE
- Sweden
- Prior art keywords
- sulfide
- methods
- sulfide minerals
- processes
- collectors
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 5
- 229910052569 sulfide mineral Inorganic materials 0.000 title abstract 3
- 230000007935 neutral effect Effects 0.000 title 1
- 239000010953 base metal Substances 0.000 abstract 2
- 238000005188 flotation Methods 0.000 abstract 2
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 2
- 229910052976 metal sulfide Inorganic materials 0.000 abstract 2
- 239000011707 mineral Substances 0.000 abstract 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
- 235000011941 Tilia x europaea Nutrition 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- UMGDCJDMYOKAJW-UHFFFAOYSA-N aminothiocarboxamide Natural products NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 abstract 1
- 238000009291 froth flotation Methods 0.000 abstract 1
- 239000011133 lead Substances 0.000 abstract 1
- 239000004571 lime Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052683 pyrite Inorganic materials 0.000 abstract 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 abstract 1
- 239000011028 pyrite Substances 0.000 abstract 1
- 229910052952 pyrrhotite Inorganic materials 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- -1 thiourea compound Chemical class 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/008—Organic compounds containing oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/04—Frothers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Collector compositions for use in froth flotation processes for the beneficiation of mineral values from base metal sulfide ores comprise at least one hydrocarboxycarbonyl thionocarbamate or thiourea compound selected from compounds of the formulas: <IMAGE> R<1>, R<2> and R<3> being specified. The processes include the use of the collectors which at pH values below 10.0 exhibit unexpectedly high collector activity for base metal sulfide minerals such as copper, lead and zinc and selectively rejects gangue sulfide minerals, such as pyrite and pyrrhotite. The collectors and processes provide excellent metallurgical recoveries of copper sulfide mineral values of high grade at a substantial reduction in lime consumption and reagents costs associated with prior art flotation separation methods. Bulk sulfide flotation methods are also disclosed. <IMAGE>
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/641,660 US4556483A (en) | 1984-08-17 | 1984-08-17 | Neutral hydrocarboxycarbonyl thiourea sulfide collectors |
| US06/641,657 US4584097A (en) | 1984-08-17 | 1984-08-17 | Neutral hydrocarboxycarbonyl thionocarbamate sulfide collectors |
| US06/641,658 US4595493A (en) | 1984-08-17 | 1984-08-17 | Process for the flotation of base metal sulfide minerals in acid, neutral or mildly alkaline circuits |
| US06/641,659 US4556482A (en) | 1984-08-17 | 1984-08-17 | Process for the flotation of base metal sulfide minerals in acid, neutral or mildly alkaline circuits |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| SE8503850D0 true SE8503850D0 (en) | 1985-08-16 |
| SE8503850L SE8503850L (en) | 1986-02-18 |
| SE465359B SE465359B (en) | 1991-09-02 |
Family
ID=27505238
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE8503850A SE465359B (en) | 1984-08-17 | 1985-08-16 | PROCEDURAL AND COLLECTOR REAGENT COMPOSITION FOR FOAM FLOTATION OF SULPHID MINERAL |
| SE8902752A SE467293B (en) | 1984-08-17 | 1989-08-16 | COLLECTOR REAGENT COMPOSITION AND FOOT FLOT PROCEDURE FOR ENRICHMENT OF SULPHIDE ORE |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE8902752A SE467293B (en) | 1984-08-17 | 1989-08-16 | COLLECTOR REAGENT COMPOSITION AND FOOT FLOT PROCEDURE FOR ENRICHMENT OF SULPHIDE ORE |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS6157254A (en) |
| KR (1) | KR910003051B1 (en) |
| AU (2) | AU570131B2 (en) |
| BG (1) | BG60234B1 (en) |
| BR (1) | BR8503910A (en) |
| ES (2) | ES8701849A1 (en) |
| FI (1) | FI77169C (en) |
| GB (2) | GB2163068B (en) |
| SE (2) | SE465359B (en) |
| YU (1) | YU45737B (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8527214D0 (en) * | 1985-11-05 | 1985-12-11 | British Petroleum Co Plc | Separation process |
| GB2267852B (en) * | 1992-06-09 | 1995-12-06 | American Cyanamid Co | Improved metal recovery by flotation |
| RU2131303C1 (en) * | 1997-03-12 | 1999-06-10 | Институт химии и химико-металлургических процессов Сибирского отделения РАН | Copper-nickel sulfide flotation process |
| RU2133644C1 (en) * | 1997-11-03 | 1999-07-27 | Иркутский государственный технический университет | Method of concentrating persistent gold-containing sulfide ores |
| RU2235602C1 (en) * | 2002-12-26 | 2004-09-10 | Открытое акционерное общество "Иргиредмет" | Method of extraction of non-ferrous and noble metals |
| US7360656B2 (en) | 2005-12-16 | 2008-04-22 | Rohm And Haas Company | Method to improve the cleaner froth flotation process |
| CN101337206B (en) | 2008-08-13 | 2011-02-02 | 中南大学 | Sulphide ore floation collector and use method of diacyl bis-thiourea and preparation method thereof |
| CN101337205B (en) | 2008-08-13 | 2011-04-20 | 中南大学 | Use of diester isosulfocyanate in sulphide ore floation and preparation method thereof |
| RU2425720C1 (en) * | 2009-12-21 | 2011-08-10 | Общество с ограниченной ответственностью "ТВЭЛЛ" | Selective extraction method of copper minerals to concentrates at enrichment of copper-zinc pyrite-containing ores |
| CN101757985B (en) * | 2010-03-04 | 2013-04-10 | 中南大学 | Mineral flotation collectors |
| RU2434953C1 (en) * | 2010-06-21 | 2011-11-27 | Открытое акционерное общество "Иркутский научно-исследовательский институт благородных и редких металлов и алмазов" ОАО "Иргиредмет" | Method of processing gold-containing sulphide concentrates (versions) |
| CN102516144B (en) * | 2011-11-02 | 2014-11-05 | 中南大学 | Thiourea compound and preparation thereof and application thereof to metal ore floatation |
| JP7206150B2 (en) * | 2019-03-29 | 2023-01-17 | Jx金属株式会社 | Method for removing SiO2 from slurry containing silver and SiO2 and method for purifying silver |
| CN113751205A (en) * | 2021-09-10 | 2021-12-07 | 紫金矿业集团股份有限公司 | N-tert-butyl ester collecting agent and preparation method thereof |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1211041A (en) * | 1967-01-24 | 1970-11-04 | Egyt Gyogyszervegyeszeti Gyar | Thiocarbamide derivatives |
| US3590996A (en) * | 1969-02-03 | 1971-07-06 | Dow Chemical Co | Floatation of sulfide ores |
| US3590998A (en) * | 1969-02-03 | 1971-07-06 | Dow Chemical Co | Flotation of sulfide ores |
| US3655657A (en) * | 1970-02-24 | 1972-04-11 | Du Pont | 2 1 4-benzothiadiazine-3-carbamic acid esters |
| DE2301400C2 (en) * | 1973-01-12 | 1984-12-13 | Bayer Ag, 5090 Leverkusen | 0-Triazolyl-thionophosphorus (phosphonic) acid esters and ester amides, process for their preparation and their use as insecticides and acaricides |
| US3907854A (en) * | 1973-07-13 | 1975-09-23 | Minerec Corp | Dialkyl thionocarbamate method |
| FR2285397A1 (en) * | 1974-09-20 | 1976-04-16 | Roussel Uclaf | NEW THIAZOLIC ORGANOPHOSPHORUS DERIVATIVES, PROCESS FOR PREPARATION AND APPLICATION AS PESTICIDES |
| FR2308629A1 (en) * | 1975-04-24 | 1976-11-19 | Roussel Uclaf | NEW SUBSTITUTE DERIVATIVES OF THIADIAZOLE, THEIR PREPARATION PROCESS AND THEIR APPLICATION AS HERBICIDES |
| GB2106804A (en) * | 1981-10-08 | 1983-04-20 | American Cyanamid Co | Process for the beneficiation of metal sulfides and collector combinations therefor |
-
1985
- 1985-08-06 GB GB08519737A patent/GB2163068B/en not_active Expired
- 1985-08-14 ES ES546173A patent/ES8701849A1/en not_active Expired
- 1985-08-16 JP JP60179518A patent/JPS6157254A/en active Granted
- 1985-08-16 AU AU46262/85A patent/AU570131B2/en not_active Expired
- 1985-08-16 YU YU131485A patent/YU45737B/en unknown
- 1985-08-16 SE SE8503850A patent/SE465359B/en not_active IP Right Cessation
- 1985-08-16 BR BR8503910A patent/BR8503910A/en not_active IP Right Cessation
- 1985-08-16 BG BG071476A patent/BG60234B1/en unknown
- 1985-08-16 FI FI853162A patent/FI77169C/en not_active IP Right Cessation
- 1985-08-16 KR KR1019850005914A patent/KR910003051B1/en not_active Expired
-
1986
- 1986-03-14 ES ES553035A patent/ES8706842A1/en not_active Expired
-
1987
- 1987-08-03 GB GB08718337A patent/GB2193660B/en not_active Expired
- 1987-12-10 AU AU82435/87A patent/AU594845B2/en not_active Expired
-
1989
- 1989-08-16 SE SE8902752A patent/SE467293B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ES8706842A1 (en) | 1987-07-16 |
| BG60234B2 (en) | 1994-01-18 |
| GB8718337D0 (en) | 1987-09-09 |
| FI77169C (en) | 1989-02-10 |
| SE8503850L (en) | 1986-02-18 |
| ES546173A0 (en) | 1986-12-16 |
| ES8701849A1 (en) | 1986-12-16 |
| AU4626285A (en) | 1986-02-20 |
| SE467293B (en) | 1992-06-29 |
| AU570131B2 (en) | 1988-03-03 |
| BR8503910A (en) | 1986-05-27 |
| KR860001615A (en) | 1986-03-20 |
| YU45737B (en) | 1992-07-20 |
| ES553035A0 (en) | 1987-07-16 |
| AU594845B2 (en) | 1990-03-15 |
| AU8243587A (en) | 1988-03-31 |
| SE465359B (en) | 1991-09-02 |
| SE8902752D0 (en) | 1989-08-16 |
| GB8519737D0 (en) | 1985-09-11 |
| GB2193660B (en) | 1988-09-28 |
| FI77169B (en) | 1988-10-31 |
| FI853162A0 (en) | 1985-08-16 |
| YU131485A (en) | 1987-12-31 |
| KR910003051B1 (en) | 1991-05-17 |
| JPH0566182B2 (en) | 1993-09-21 |
| BG60234B1 (en) | 1994-01-24 |
| GB2163068A (en) | 1986-02-19 |
| GB2193660A (en) | 1988-02-17 |
| JPS6157254A (en) | 1986-03-24 |
| GB2163068B (en) | 1988-09-28 |
| FI853162L (en) | 1986-02-18 |
| SE8902752L (en) | 1989-08-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NAL | Patent in force |
Ref document number: 8503850-3 Format of ref document f/p: F |
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| NUG | Patent has lapsed |