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RU2019102474A - Способ увеличения объемной вместимости в системах хранения и высвобождения газа - Google Patents

Способ увеличения объемной вместимости в системах хранения и высвобождения газа Download PDF

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RU2019102474A
RU2019102474A RU2019102474A RU2019102474A RU2019102474A RU 2019102474 A RU2019102474 A RU 2019102474A RU 2019102474 A RU2019102474 A RU 2019102474A RU 2019102474 A RU2019102474 A RU 2019102474A RU 2019102474 A RU2019102474 A RU 2019102474A
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monolith
combination
gas
copolymer
aqueous binder
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RU2019102474A
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RU2019102474A3 (ru
RU2745599C2 (ru
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Билли-Пол М. ХОЛБРУК
Лоренс Х. ХИЛЦИК
Роберт В. МИМС
Рей П. БОНГАЛОНТА
Кенечукву ОНУБОГУ
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Индживити Саут Каролина, Ллк
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F17C11/00—Use of gas-solvents or gas-sorbents in vessels
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Claims (37)

1. Способ хранения газа, причем способ предусматривает:
введение газа в контакт с системой хранения газа, содержащей по меньшей мере один пористый газосорбирующий монолит, имеющий рабочую весовую вместимость не более 40 фунт/ЭГБ (эквивалент галлона бензина) и/или объемную вместимость не более 35 л/ЭГБ.
2. Способ по п. 1, в котором пористый газосорбирующий монолит имеет по меньшей мере одну из следующих характеристик:
менее чем приблизительно 100 куб. см/л-м (кубических сантиметров на литр монолита) объема в порах с размерами, составляющими менее чем приблизительно 9
Figure 00000001
;
более чем приблизительно 200 куб. см/л-м объема в порах с размерами, составляющими приблизительно от 9 до 27
Figure 00000001
;
более чем приблизительно 50 куб. см/л-м объема в порах с размерами, составляющими приблизительно от 27 до 490
Figure 00000002
;
плотность изделия, составляющая по меньшей мере 0,4 г/куб. см; или
их комбинацию.
3. Способ по п. 1 или 2, в котором рабочая весовая вместимость составляет не более чем 40 фунт/ЭГБ.
4. Способ по п. 1, в котором объемная вместимость равняется или составляет или менее чем 30 л/ЭГБ.
5. Способ по п. 1, в котором пористый газосорбирующий монолит содержит газоадсорбирующий материал и неводное связующее вещество.
6. Способ по п. 5, в котором неводное связующее вещество представляет собой по меньшей мере одно из следующих веществ: фторполимер, полиамид, полиимид, фибриллированная целлюлоза, высокоэффективный пластик, сополимер с фторполимером, сополимер с полиамидом, сополимер с полиимидом, сополимер с высокоэффективным пластиком, и их комбинацию.
7. Способ по п. 6, в котором фторполимер представляет собой по меньшей мере одно из следующих веществ: поли(винилидендифторид), политетрафторэтилен, фторированный этилен-пропилен, перфторалкоксиалкан, или их комбинацию.
8. Способ по п. 6, в котором полиамид представляет собой по меньшей мере одно из следующих веществ: нейлон-6,6', нейлон-6, нейлон 6, 12, или их комбинацию.
9. Способ по любому из пп. 5-8, который имеет по меньшей мере одну из следующих характеристик:
неводное связующее вещество присутствует в количестве, составляющем не более чем 10 мас. %;
газоадсорбирующий материал присутствует в количестве, составляющем по меньшей мере 90 мас. %;
неводное связующее вещество представляет собой дисперсию, содержащую от приблизительно 50 мас. % до приблизительно 70 мас. % связующего вещества;
или их комбинацию.
10. Способ по любому из пп. 5-8, который имеет по меньшей мере одну из следующих характеристик:
неводное связующее вещество присутствует в количестве, составляющем приблизительно 2,5 мас. % до приблизительно 7 мас. %
газоадсорбирующий материал присутствует в количестве, составляющем по меньшей мере 93 мас. %;
неводное связующее вещество представляет собой дисперсию, содержащую от приблизительно 55 мас. % до приблизительно 65 мас. % связующего вещества; или
их комбинацию.
11. Способ по любому из пп. 5-8, в котором газоадсорбирующий материал представляет собой по меньшей мере один из следующих материалов: активированный уголь, цеолит, диоксид кремния, металлоорганический каркас, ковалентный органический каркас, или их комбинацию.
12. Способ по п. 11, в котором источники активированного угля представляют собой древесина, торфяной мох, скорлупа кокосового ореха, уголь, скорлупа грецкого ореха, синтетические полимеры и/или природные полимеры.
13. Способ по п. 11, в котором активированный уголь получают, осуществляя термическую активацию, химическую активацию или их комбинацию.
14. Пористый газосорбирующий монолит, содержащий:
газоадсорбирующий материал,
причем пористый газосорбирующий монолит имеет рабочую весовую вместимость, составляющую не более чем 40 фунт/ЭГБ, и/или объемную вместимость, составляющую менее чем 35 л/ЭГБ.
15. Монолит по п. 14, дополнительно содержащий неводное связующее вещество.
16. Монолит по п. 15, в котором неводное связующее вещество представляет собой по меньшей мере одно из следующих веществ: фторполимер, полиамид, полиимид, фибриллированная целлюлоза, высокоэффективный пластик, сополимер с фторполимером, сополимер с полиамидом, сополимер с полиимидом, сополимер с высокоэффективным пластиком, или их комбинацию.
17. Монолит по п. 16, в котором фторполимер представляет собой по меньшей мере один фторполимер, выбранный из группы, которую составляют поли(винилидендифторид), фторированный этилен-пропилен, перфторалкоксиалкан, и политетрафторэтилен.
18. Монолит по п. 16, в котором полиамид представляет собой по меньшей мере один полиамид выбирают из группы, которую составляют нейлон-6,6', нейлон-6 и нейлон 6, 12.
19. Монолит по любому из пп. 15-18, в котором неводное связующее вещество присутствует в количестве, составляющем не более чем 10 мас. %, и/или газоадсорбирующий материал присутствует в количестве, составляющем по меньшей мере 90 мас. %.
20. Монолит по любому из пп. 14-18, в котором газоадсорбирующий материал представляет собой по меньшей мере один из следующих материалов: активированный уголь, цеолит, диоксид кремния, металлоорганический каркас, ковалентный органический каркас, или их комбинацию.
21. Монолит по п. 20, в котором источники активированного угля представляют собой древесину, торфяной мох, скорлупу кокосового ореха, уголь, скорлупу грецкого ореха, синтетические полимеры и/или природные полимеры, и/или активированный уголь является термически активированным, химически активированным или их комбинацией.
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