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RU2017126724A - Пиколинамиды в качестве фунгицидов - Google Patents

Пиколинамиды в качестве фунгицидов Download PDF

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RU2017126724A
RU2017126724A RU2017126724A RU2017126724A RU2017126724A RU 2017126724 A RU2017126724 A RU 2017126724A RU 2017126724 A RU2017126724 A RU 2017126724A RU 2017126724 A RU2017126724 A RU 2017126724A RU 2017126724 A RU2017126724 A RU 2017126724A
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compound
hydrogen
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RU2686987C2 (ru
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Захари БАКЕН
Кайл А. ДЕКОРВЕР
Дэвид М. ДЖОУНС
Джессика ХЕРРИК
Джереми ВИЛМОТ
Джаред РИГОЛИ
Брайан ЛОЙ
Юй ЛУ
Кевин Дж. МЕЙЕР
Чэнлинь Яо
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ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/81—Amides; Imides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/18—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with sulfur as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10—Macromolecular compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links

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  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pyridine Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Ecology (AREA)
  • Forests & Forestry (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Thiazole And Isothizaole Compounds (AREA)
  • Botany (AREA)

Claims (44)

1. Соединение формулы I
Figure 00000001
где X представляет собой водород или C(O)R5;
Y представляет собой водород, C(O)R5, или Q;
Q представляет собой
Figure 00000002
;
R1 и R11 независимо выбраны из водорода или алкила, необязательно замещенных 0, 1 или несколькими R8; альтернативно, R1 и R11 можно брать вместе с формированием 3-6-членного насыщенного или частично насыщенного углеродного цикла или гетероцикла, необязательно замещенного 0, 1 или несколькими R8;
R2 и R12 независимо выбраны из водорода или метила;
R3 выбран из арила или гетероарила, каждый из которых необязательно замещен 0, 1 или несколькими R8;
R4 выбран из алкила, арила или ацила, каждый из которых необязательно замещен 0, 1 или несколькими R8;
R5 выбран из алкокси или бензилокси, каждый из которых необязательно замещен 0, 1 или несколькими R8;
R6 выбран из водорода, алкокси или галогена, каждый из которых необязательно замещен 0, 1 или несколькими R8;
R7 выбран из водорода, -C(O)R9 или -CH2OC(O)R9;
R8 выбран из водорода, алкила, арила, ацила, галогена, алкенила, алкокси или гетероциклила, каждый из которых необязательно замещен 0, 1 или несколькими R10;
R9 выбран из алкила, алкокси или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8;
R10 выбран из водорода, алкила, арила, ацила, галогена, алкенила, алкокси или гетероциклила.
2. Соединение по п. 1, где X и Y представляют собой водород.
3. Соединение по п. 2, где R1 и R11 независимо выбраны из водорода или алкила.
4. Соединение по п. 2, где R2 и R12 независимо выбраны из водорода или метила.
5. Соединение по п. 2, где R3 представляет собой арил, необязательно замещенный 0, 1 или несколькими R8.
6. Соединение по п. 2, где R4 выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
7. Соединение по п. 2, где R1 и R11 независимо выбраны из водорода или алкила, R2 и R12 независимо выбраны из водорода или метила, R3 представляет собой арил, необязательно замещенный 0, 1 или несколькими R8, и R4 выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
8. Соединение по п. 1, где X представляет собой C(O)R5, и Y представляет собой водород.
9. Соединение по п. 8, где R1 и R11 независимо выбраны из водорода или алкила.
10. Соединение по п. 8, где R2 и R12 независимо выбраны из водорода или метила.
11. Соединение по п. 8, где R3 представляет собой арил, необязательно замещенный 0, 1 или несколькими R8;
12. Соединение по п. 8, где R4 выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
13. Соединение по п. 8, где R1 и R11 независимо выбраны из водорода или алкила, R2 и R12 независимо выбраны из водорода или метила, R3 представляет собой арил, необязательно замещенный 0, 1 или несколькими R8, и R4 выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
14. Соединение по п. 1, где X представляет собой водород и Y представляет собой Q.
15. Соединение по п. 14, где R7 представляет собой водород.
16. Соединение по п. 15, где R6 представляет собой алкокси.
17. Соединение по п. 16, где R1 и R11 независимо выбраны из водорода или алкила.
18. Соединение по п. 16, где R2 и R12 независимо выбраны из водорода или метила.
19. Соединение по п. 16, где R3 представляет собой арил, необязательно замещенный 0, 1 или несколькими R8;
20. Соединение по п. 16, где R4 выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
21. Соединение по п. 16, где R1 и R11 независимо выбраны из водорода или алкила, R2 и R12 независимо выбраны из водорода или метила, R3 представляет собой арил, необязательно замещенный 0, 1 или несколькими R8; и R4 выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
22. Соединение по п. 15, где R7 выбран из -C(O)R9, или -CH2OC(O)R9.
23. Соединение по п. 22, где R9 представляет собой алкил, необязательно замещенный 0, 1 или несколькими R8.
24. Соединение по п. 23, где R1 и R11 независимо выбраны из водорода или алкила.
25. Соединение по п. 23, где R2 и R12 независимо выбраны из водорода или метила.
26. Соединение по п. 23, где R3 представляет собой арил, необязательно замещенный 0, 1 или несколькими R8;
27. Соединение по п. 23, где R4 выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
28. Соединение по п. 23, где R1 и R11 независимо выбраны из водорода или алкила, R2 и R12 независимо выбраны из водорода или метила, R3 представляет собой арил, необязательно замещенный 0, 1 или несколькими R8; и R4 выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
29. Соединение по п. 28, где R9 выбран из -CH3, -CH2OCH2CH3, -CH2CH2OCH3, -CH(CH3)2, -CH2CH2CH2CH3, -циклопропила.
RU2017126724A 2014-12-30 2015-12-21 Пиколинамиды в качестве фунгицидов RU2686987C2 (ru)

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US201462098097P 2014-12-30 2014-12-30
US201462098089P 2014-12-30 2014-12-30
US62/098,089 2014-12-30
US62/098,097 2014-12-30
US201562255163P 2015-11-13 2015-11-13
US201562255168P 2015-11-13 2015-11-13
US62/255,163 2015-11-13
US62/255,168 2015-11-13
PCT/US2015/067206 WO2016109304A1 (en) 2014-12-30 2015-12-21 Picolinamides as fungicides

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KR (2) KR20170100620A (ru)
CN (2) CN107205399B (ru)
AU (2) AU2015374379B2 (ru)
BR (2) BR112017013608B8 (ru)
CA (2) CA2972551A1 (ru)
CO (2) CO2017006960A2 (ru)
ES (1) ES2841906T3 (ru)
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BR102018000183B1 (pt) 2017-01-05 2023-04-25 Dow Agrosciences Llc Picolinamidas, composição para controle de um patógeno fúngico, e método para controle e prevenção de um ataque por fungos em uma planta
TW201902357A (zh) * 2017-05-02 2019-01-16 美商陶氏農業科學公司 用作種子處理之無環吡啶醯胺
KR102659552B1 (ko) 2017-05-02 2024-04-23 코르테바 애그리사이언스 엘엘씨 잔디풀 상의 진균 질환에 대한 살진균제로서의 비고리형 피콜린아미드 화합물의 용도
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