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RU2016138363A - Сверхбыстро перезаряжаемая металл-ионная батарея - Google Patents

Сверхбыстро перезаряжаемая металл-ионная батарея Download PDF

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RU2016138363A
RU2016138363A RU2016138363A RU2016138363A RU2016138363A RU 2016138363 A RU2016138363 A RU 2016138363A RU 2016138363 A RU2016138363 A RU 2016138363A RU 2016138363 A RU2016138363 A RU 2016138363A RU 2016138363 A RU2016138363 A RU 2016138363A
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battery according
cathode
electrolyte
aluminum
ionic liquid
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RU2684622C2 (ru
RU2016138363A3 (ru
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Хунцзе ДАЙ
Мэн-Чан ЛИНЬ
Мин ГУН
Бинган ЛУ
Инпэн ВУ
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Те Борд Оф Трастиз Оф Те Лилэнд Стэнфорд Джуниор Юниверсити
Индастриэл Текнолоджи Рисеч Инститьют
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/46—Alloys based on magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
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    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
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    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
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    • H—ELECTRICITY
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    • H01M10/00—Secondary cells; Manufacture thereof
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    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
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    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
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    • H01M2300/0025—Organic electrolyte
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    • H01M4/36—Selection of substances as active materials, active masses, active liquids
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    • H01M4/386—Silicon or alloys based on silicon
    • H—ELECTRICITY
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    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
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    • Y10T29/49108—Electric battery cell making
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T29/49115—Electric battery cell making including coating or impregnating

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  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
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  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Cell Electrode Carriers And Collectors (AREA)

Claims (29)

1. Металл-ионная батарея содержащая:
анод, включающий алюминий;
катод, включающий слоистый активный материал; и
электролит, расположенный между анодом и катодом, для поддержания обратимого осаждения и растворения алюминия на аноде и обратимого интеркалирования и деинтеркалирования анионов на катоде.
2. Батарея по п. 1, в которой слоистым активным материалом является графит.
3. Батарея по п. 2, в которой графит является пиролитическим графитом.
4. Батарея по п. 1, в которой слоистый активный материал представляет собой слоистый двойной гидроксид, слоистый оксид или слоистый халькогенит.
5. Батарея по п. 1, в которой слоистый активный материал имеет пористость в диапазоне 0,05-0,95.
6. Батарея по п. 1, в которой электролит соответствует смеси галогенида алюминия и ионной жидкости, причем мольное отношение галогенида алюминия к ионной жидкости превышает 1,1.
7. Батарея по п. 6, в которой галогенидом алюминия является AlCl3, а ионной жидкостью является хлорид 1-этил-3-метилимидазолия.
8. Батарея по п. 7, в которой мольное отношение AlCl3 к 1-этил-3-метилимидазолий хлориду превышает 1,2.
9. Батарея по п. 1, в которой содержание воды в электролите составляет не более чем 1000 ppm.
10. Металл-ионная батарея содержащая:
алюминиевый анод;
катод из пористого графита; и
электролит на основе ионной жидкости, расположенный между алюминиевым анодом и катодом из пористого графита.
11. Батарея по п. 10, в которой катод из пористого графита имеет пористость в диапазоне 0,05-0,95.
12. Батарея по п. 11, в которой указанная пористость составляет 0,3-0,9.
13. Батарея по п. 10, в которой электролит на основе ионной жидкости соответствует смеси галогенида алюминия и ионной жидкости, причем мольное отношение галогенида алюминия к ионной жидкости превышает 1,1.
14. Батарея по п. 10, в которой содержание воды в электролите на основе ионной жидкости не превышает 1000 ppm.
15. Батарея по п. 14, в которой содержание воды не превышает 400 ppm.
16. Способ изготовления металл-ионной батареи включающий:
получение анода, содержащего алюминий;
получение катода, содержащего активный материал, способный к интеркаляции ионов во время заряда и к деинтеркаляции ионов во время разряда, при этом активный материал выбирают по меньшей мере из одного из следующих материалов: углеродсодержащий материал, кремнийсодержащий материал и германийсодержащий материал; и
получение электролита, способного поддерживать обратимое осаждение и растворение алюминия на аноде и обратимую интеркаляцию и деинтеркаляцию ионов на катоде.
17. Способ по п. 16, в котором получение катода включает в себя получение катода из пористого графитового материала.
18. Способ по п. 17, в котором получение пористого графитового материала включает в себя формирование графитовой пены посредством осаждения на пористую удаляемую подложку.
19. Способ по п. 17, в котором получение пористого графитового материала включает в себя расширение графитового материала посредством электрохимического выделения водорода.
20. Способ по п. 16, в котором получение электролита включает в себя электрохимическое высушивание электролита, так чтобы содержание воды в электролите не превышало 400 ppm.
RU2016138363A 2014-02-28 2015-02-27 Сверхбыстро перезаряжаемая металл-ионная батарея RU2684622C2 (ru)

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US201461946618P 2014-02-28 2014-02-28
US61/946,618 2014-02-28
US201462076420P 2014-11-06 2014-11-06
US62/076,420 2014-11-06
US14/622,692 2015-02-13
US14/622,692 US9843070B2 (en) 2014-02-28 2015-02-13 Ultra-fast rechargeable metal-ion battery
PCT/US2015/018154 WO2015131132A1 (en) 2014-02-28 2015-02-27 Ultra-fast rechargeable metal-ion battery

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US (1) US9843070B2 (ru)
EP (1) EP3111504B1 (ru)
JP (1) JP6713926B2 (ru)
KR (1) KR102506536B1 (ru)
CN (1) CN106471660B (ru)
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