RU2016122094A - Замещенные бензамиды для борьбы с членистоногими - Google Patents
Замещенные бензамиды для борьбы с членистоногими Download PDFInfo
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- 229940054066 benzamide antipsychotics Drugs 0.000 title 1
- 150000003936 benzamides Chemical class 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims 27
- 229910052757 nitrogen Inorganic materials 0.000 claims 13
- -1 cyano, nitro, amino Chemical group 0.000 claims 7
- 229910052736 halogen Inorganic materials 0.000 claims 5
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 claims 4
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims 4
- 229910052799 carbon Inorganic materials 0.000 claims 4
- 150000002367 halogens Chemical class 0.000 claims 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims 3
- 125000005842 heteroatom Chemical group 0.000 claims 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 3
- 125000004738 (C1-C6) alkyl sulfinyl group Chemical group 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 125000004429 atom Chemical group 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims 2
- 229910052731 fluorine Inorganic materials 0.000 claims 2
- 239000011737 fluorine Substances 0.000 claims 2
- 125000001153 fluoro group Chemical group F* 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 2
- 125000004916 (C1-C6) alkylcarbonyl group Chemical group 0.000 claims 1
- 125000004214 1-pyrrolidinyl group Chemical group [H]C1([H])N(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 claims 1
- 125000004070 6 membered heterocyclic group Chemical group 0.000 claims 1
- 125000004399 C1-C4 alkenyl group Chemical group 0.000 claims 1
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims 1
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 claims 1
- 150000001204 N-oxides Chemical class 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 239000002917 insecticide Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 125000006300 thietan-3-yl group Chemical group [H]C1([H])SC([H])([H])C1([H])* 0.000 claims 1
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
- C07D207/33—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals, directly attached to ring carbon atoms
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Claims (57)
1. Соединения формулы (Iaʺ)
в которой D1 представляет собой C-R11 или гетероатом, выбранный из N или О;
D2 представляет собой C-R11 или гетероатом, выбранный из N или О;
D3 представляет собой С или N;
D4 представляет собой С или N;
D5 представляет собой C-R11 или N;
причем, самое большее, одна (1) или две группы, выбранные из D1, D2, D3, D4 и D5, представляют собой гетероатом;
R1 представляет собой необязательно замещенный C1-C6-алкил;
группы
A1 представляет собой CR2 или N,
А2 представляет собой CR3 или N,
A3 представляет собой CR4 или N,
А4 представляет собой CR5 или N,
B1 представляет собой CR6 или N,
B2 представляет собой CR7 или N,
B4 представляет собой CR9 или N, и
B5 представляет собой CR10 или N,
причем не более трех из групп A1-A4 представляют собой N, и не более трех из групп B1-B5 представляют собой N;
R2, R3, R4, R5, R6, R7, R9 и R10 независимо друг от друга представляет собой Н, галоген, циано, нитро, в каждом случае необязательно замещенный C1-C6-алкил, C3-C6-циклоалкил, C1-C6-алкокси, N-C1-C6-алкокси-имино-С1-С3-алкил, C1-C6-алкилсульфанил, C1-C6-алкилсульфинил, C1-C6-алкилсульфонил, N-C1-C6-алкиламино, N,N-ди-C1-C6-алкиламино или N-C1-C3-алкокси-С1-С4-алкиламино или 1-пирролидинил;
когда ни одна из групп А2 и A3 не представляет собой N, R3 и R4 могут образовывать вместе с атомом углерода, с которым они связаны, 5- или 6-членное кольцо, содержащее 0, 1 или 2 атома N, и/или 0 или 1 атом О, и/или 0 или 1 атом S, или
когда ни одна из групп A1 и А2 не представляет собой N, R2 и R3 могут образовывать вместе с атомом углерода, с которым они связаны, 6-членное кольцо, содержащее 0,1 или 2 атома N;
R8 представляет собой галоген, циано, нитро, в каждом случае необязательно замещенный C1-C6-алкил, C3-C6-циклоалкил, C1-C6-алкокси, N-C1-C6-алкокси-имино-С1-С3-алкил, C1-C6-алкилсульфанил, C1-C6-алкилсульфинил, C1-C6-алкилсульфонил, N-C1-C6-алкиламино или N,N-ди-C1-C6-алкиламино;
R11 независимо друг от друга представляет собой Н, галоген, циано, нитро, амино или необязательно замещенный C1-C6-алкил, C1-C6-алкилокси, C1-C6-алкилкарбонил, C1-C6-алкилсульфанил, C1-C6-алкилсульфинил, C1-C6-алкилсульфонил, предпочтительно представляет собой Н;
W представляет собой О или S;
Q представляет собой Н, формил, гидрокси, амино или в каждом случае необязательно замещенный C1-C6-алкил, С2-С6-алкенил, С2-С6-алкинил, C3-C6-циклоалкил, С1-С5-гетероциклоалкил, С1-С4-алкокси, C1-C6-алкил-C3-C6-циклоалкил, C3-C6-циклоалкил-C1-C6-алкил, С6-,С10-,С14-арил, C1-C5-гетероарил, С6-,С10-,С14-арил-(С1-С3)-алкил, С1-С5-гетероарил-(С1-С3)-алкил, N-C1-C4-алкиламино, N-С1-С4-алкилкарбониламино или N,N-ди-С1-С4-алкиламино; или
представляет собой необязательно многократно замещенный заместителями V ненасыщенный 6-членный карбоцикл; или
представляет собой необязательно многократно замещенное заместителями V ненасыщенное 4-, 5- или 6-членное гетероциклическое кольцо, причем
V независимо друг от друга представляет собой галоген, циано, нитро, в каждом случае необязательно замещенный C1-C6-алкил, С1-С4-алкенил, С1-С4-алкинил, C3-C6-циклоалкил, C1-C6-алкокси, N-C1-C6-алкокси-имино-С1-С3-алкил, С1-С6-алкилсульфанил, C1-C6-алкилсульфинил, C1-C6-алкилсульфонил или N,N-ди-(C1-C6-алкил)амино.
а также соли, N-оксиды и таутомерные формы соединений формулы (Iaʺ).
2. Соединения по п. 1, причем соединения формулы (Iaʺ) представляют собой соединения формулы (I-T3)
в которой R1, A1, А2, A3, А4, R11, B1, В2, В4, В5, R8, Q и W имеют значения, как определено в пункте 1, причем, самое большее, одна группа, выбранная из А1, А2, A3, А4, представляет собой N, и, самое большее, одна группа, выбранная из B1, В2, В4 и В5, представляет собой N.
3. Соединения по п. 1, причем соединения формулы (Iaʺ) представляют собой соединения формулы (I-T2)
в которой R1, А1, А2, A3, А4, R11, B1, В2, В4, В5, R8, Q и W имеют значения, как определено в пункте 1, причем, самое большее, одна группа, выбранная из А1, А2, A3, А4, представляет собой N, и, самое большее, одна группа, выбранная из B1, В2, В4 и В5, представляет собой N.
4. Соединения по п. 1, причем соединения формулы (Iaʺ) представляют собой соединения формулы (I-T4)
в которой R1, А1, А2, A3, А4, R11, В1, В2, В4, В5, R8, Q и W имеют значения, как определено в пункте 1, причем, самое большее, одна группа, выбранная из А1, А2, A3, А4, представляет собой N, и, самое большее, одна группа, выбранная из B1, В2, В4 и В5, представляет собой N.
5. Соединения по п. 1, причем соединения формулы (Iaʺ) представляют собой соединения формулы (I-T22)
в которой R1, А1, А2, А3, A4, R11, В1, В2, В4, В5, R8, Q и W имеют значения, как определено в пункте 1, причем, самое большее, одна группа, выбранная из А1, А2, А3, А4, представляет собой N, и, самое большее, одна группа, выбранная из В1, В2, В4 и В5, представляет собой N.
6. Соединения по п. 1, причем соединения формулы (Iaʺ) представляют собой соединения формулы (I-T23)
в которой R1, А1, А2, A3, A4, R11, B1, В2, В4, В5, R8, Q и W имеют значения, как определено в пункте 1, причем, самое большее, одна группа, выбранная из А1, А2, A3, А4, представляет собой N, и, самое большее, одна группа, выбранная из В1, В2, В4 и В5, представляет собой N.
7. Соединения по п. 1, причем соединения формулы (Iaʺ) представляют собой соединения формулы (I-T46)
в которой R1, А1, А2, A3, А4, R11, В1, В2, В4, В5, R8, Q и W имеют значения, как определено в пункте 1, причем, самое большее, одна группа, выбранная из А1, А2, A3, А4, представляет собой N, и, самое большее, одна группа, выбранная из В1, В2, В4 и В5, представляет собой N.
8. Соединения по п. 1, причем R11 независимо друг от друга представляет собой Н, и W представляет собой О.
9. Соединения по п. 1, причем R11 независимо друг от друга представляет собой Н, и W представляет собой О, и R8 представляет собой замещенный галогеном С1-С3-алкил или замещенный галогеном C1-С3-алкокси.
10. Соединение по п. 1, причем группы A1-A4 и B1, В2, В4 и В5 представляют собой
11. Соединения по п. 1, причем R1 представляет собой метил.
12. Соединения по п. 1, причем Q представляет собой C1-С3-алкил, циклопропил, 1-(циано)-циклопропил, 1-(перфторированный C1-С3-алкил)-циклопропил, 1-(С1-С4-алкил)-циклопропил, 1-(тиокарбамоил)-циклопропил, замещенный галогеном C1-С3-алкил, тиетан-3-ил, N-метил-пиразол-3-ил или 2-оксо-2(2,2,2-трифторэтиламино)этил.
13. Соединения по любому из пп. 1-12, причем R8 представляет собой замещенный фтором С1-С4-алкокси или замещенный фтором С1-С4-алкил.
14. Инсектицидное средство, отличающееся тем, что оно содержит по меньшей мере одно соединение формулы (I) по любому из пп. 1-13 и наполнитель и/или поверхностно-активное вещество.
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