RU2015144080A - Поперечно-сшитые продукты, полученные ионным сшиванием олигомера твердой марки и полимера с применением ионного сшивающего агента, и способы их получения - Google Patents
Поперечно-сшитые продукты, полученные ионным сшиванием олигомера твердой марки и полимера с применением ионного сшивающего агента, и способы их получения Download PDFInfo
- Publication number
- RU2015144080A RU2015144080A RU2015144080A RU2015144080A RU2015144080A RU 2015144080 A RU2015144080 A RU 2015144080A RU 2015144080 A RU2015144080 A RU 2015144080A RU 2015144080 A RU2015144080 A RU 2015144080A RU 2015144080 A RU2015144080 A RU 2015144080A
- Authority
- RU
- Russia
- Prior art keywords
- polymer
- oligomer
- asphalt
- crosslinked product
- composition according
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims 10
- 238000000034 method Methods 0.000 title claims 8
- 239000007787 solid Substances 0.000 title claims 7
- 238000004132 cross linking Methods 0.000 title claims 5
- 239000003431 cross linking reagent Substances 0.000 title claims 5
- 239000000203 mixture Substances 0.000 claims 17
- 239000010426 asphalt Substances 0.000 claims 12
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 3
- 239000000178 monomer Substances 0.000 claims 3
- 229910052717 sulfur Inorganic materials 0.000 claims 3
- 239000011593 sulfur Substances 0.000 claims 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 2
- 230000002209 hydrophobic effect Effects 0.000 claims 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- -1 ethylene, propylene, isobutylene Chemical group 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
- C08L95/005—Aqueous compositions, e.g. emulsions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/246—Intercrosslinking of at least two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
- C08L9/08—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2395/00—Bituminous materials, e.g. asphalt, tar or pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08J2423/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2425/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2425/02—Homopolymers or copolymers of hydrocarbons
- C08J2425/04—Homopolymers or copolymers of styrene
- C08J2425/08—Copolymers of styrene
- C08J2425/10—Copolymers of styrene with conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/10—Copolymers of styrene with conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2555/00—Characteristics of bituminous mixtures
- C08L2555/20—Mixtures of bitumen and aggregate defined by their production temperatures, e.g. production of asphalt for road or pavement applications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/30—Adapting or protecting infrastructure or their operation in transportation, e.g. on roads, waterways or railways
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
Claims (22)
1. Асфальтовая композиция, содержащая:
сшитый продукт, полученный ионным сшиванием олигомера твердой марки и полимера с применением ионного сшивающего агента.
2. Композиция по п. 1, в которой полимер является производным 4-80 мас.% стирола, 4-80 мас.% бутадиена и 8-25 мас.% олигомера твердой марки.
3. Композиция по п. 2, в которой полимер является производным 25-59 мас.% стирола, 25-59 мас.% бутадиена и 8-25 мас.% олигомера твердой марки.
4. Композиция по п. 1, в которой полимер является производным гидрофобного мономера, и гидрофобный мономер состоит из бутадиена.
5. Композиция по п. 1, в которой полимер является производным газофазного мономера, выбираемого из этилена, пропилена, изобутилена, винилхлорида, винилиденхлорида или их смеси.
6. Композиция по п. 5, в которой полимер является производным этилена и 81 мас.% или менее винилацетата.
7. Композиция по п. 6, в которой полимер является производным 16%-41 мас.% этилена, 41-67 мас.% винилацетата и 8-25 мас.% олигомера твердой марки.
8. Композиция по любому одному из пп. 1-7, в которой сшитый продукт не содержит серу.
9. Асфальтовая композиция по любому одному из пп. 1-7, в которой верхний температурный предел по SHRP (программе стратегических исследований в области автомобильных дорог) составляет 76°С или выше.
10. Асфальтовая композиция по п. 8, в которой верхний температурный предел по SHRP составляет 76°С или выше.
11. Способ получения асфальтовой композиции по любому из пп. 1-10, включающий:
обеспечение сшитого продукта;
смешение сшитого продукта с асфальтом при температуре, равной 160°С или менее.
12. Способ получения асфальтовой композиции, включающий:
сшивание олигомера твердой марки и полимера с применением ионного сшивающего агента с образованием сшитого продукта; и
смешение сшитого продукта с асфальтом при температуре, равной 160°С или менее, с получением асфальтовой композиции.
13. Способ по п. 12, дополнительно включающий в себя стадию взаимодействия олигомера твердой марки с полимером до стадии сшивания.
14. Способ по п. 12, в котором стадия сшивания протекает при температуре окружающей среды.
15. Способ по пп. 12-14, в котором стадия смешения включает в себя смешение сшитого продукта с асфальтом при температуре, равной 120°С или менее, с получением асфальтовой композиции.
16. Способ по любому одному из пп. 12-14, в котором асфальтовую композицию получают без применения сшивающих агентов на основе серы.
17. Способ по п. 15, в котором асфальтовую композицию получают без применения сшивающих агентов на основе серы.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361793686P | 2013-03-15 | 2013-03-15 | |
| US61/793686 | 2013-03-15 | ||
| PCT/EP2014/054680 WO2014139999A1 (en) | 2013-03-15 | 2014-03-11 | Crosslinked products prepared by ionically crosslinking a solid grade oligomer and a polymer using an ionic crosslinking agent and methods of making the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2015144080A true RU2015144080A (ru) | 2017-04-24 |
Family
ID=50289642
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2015144080A RU2015144080A (ru) | 2013-03-15 | 2014-03-11 | Поперечно-сшитые продукты, полученные ионным сшиванием олигомера твердой марки и полимера с применением ионного сшивающего агента, и способы их получения |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US10174201B2 (ru) |
| EP (1) | EP2970517B1 (ru) |
| KR (1) | KR20150129849A (ru) |
| CN (1) | CN105283469B (ru) |
| AU (1) | AU2014230892B2 (ru) |
| BR (1) | BR112015021904A2 (ru) |
| CA (1) | CA2899547A1 (ru) |
| MX (1) | MX2015010210A (ru) |
| RU (1) | RU2015144080A (ru) |
| WO (1) | WO2014139999A1 (ru) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10174201B2 (en) | 2013-03-15 | 2019-01-08 | Basf Se | Crosslinked products prepared by ionically crosslinking a solid grade oligomer and a polymer using an ionic crosslinking agent and methods of making the same |
| ES2666889T3 (es) | 2013-03-15 | 2018-05-08 | Basf Se | Composiciones que comprenden un copolímero de un oligómero de calidad sólida y un monómero hidrófobo y/o un monómero en fase gaseosa y procedimientos de fabricación de las mismas |
| WO2015091648A1 (en) * | 2013-12-20 | 2015-06-25 | Basf Se | Compositions prepared using an ionic crosslinking agent and methods of making the same |
| US9745480B2 (en) | 2014-06-12 | 2017-08-29 | Akzo Nobel Chemicals International B.V. | Method for producing bituminous coatings with reduced tackiness |
| US10323147B1 (en) | 2016-05-26 | 2019-06-18 | Marathon Petroleum Company Lp | Asphalt composition containing ester bottoms |
| EP3514213A1 (en) | 2018-01-18 | 2019-07-24 | Basf Se | Pressure-sensitive adhesive solution comprising polymers with cationic and anionic groups |
| KR102648697B1 (ko) * | 2018-12-17 | 2024-03-15 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 및 고흡수성 수지 |
| US11814506B2 (en) | 2019-07-02 | 2023-11-14 | Marathon Petroleum Company Lp | Modified asphalts with enhanced rheological properties and associated methods |
| CA3088894C (en) | 2020-05-21 | 2024-04-30 | Marathon Petroleum Company Lp | Systems and methods for venting asphalt transport tanks |
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| US3352808A (en) | 1963-09-09 | 1967-11-14 | Gen Aniline & Film Corp | Graft copolymers of styrene and butadiene onto polyvinyl lactam homopolymers |
| DE2126009A1 (de) * | 1971-05-26 | 1972-12-07 | Basf Ag | Ionisch vernetzte Stoffmischungen aus Äthylencopolymerisaten und bituminösen Substanzen |
| GB1529274A (en) * | 1976-07-28 | 1978-10-18 | British Petroleum Co | Polycyclic aromatic-polymer compositions |
| US4414370A (en) | 1981-01-09 | 1983-11-08 | S. C. Johnson & Son, Inc. | Process for continuous bulk copolymerization of vinyl monomers |
| JPS5840349A (ja) * | 1981-09-04 | 1983-03-09 | Asahi Chem Ind Co Ltd | 瀝青質を含む組成物 |
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| US4529787A (en) | 1982-06-15 | 1985-07-16 | S. C. Johnson & Son, Inc. | Bulk polymerization process for preparing high solids and uniform copolymers |
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| US4806207A (en) | 1987-02-15 | 1989-02-21 | The Dow Chemical Company | Structured latex particles having reinforcing and opacity characteristics |
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| GB9316221D0 (en) | 1993-08-05 | 1993-09-22 | Zeneca Ltd | Production of polymer emulsions |
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| US5770648A (en) | 1996-10-29 | 1998-06-23 | E. I. Du Pont De Nemours And Company | Pigment dispersions containing aqueous branched polymer dispersant |
| US7105587B2 (en) * | 2001-03-07 | 2006-09-12 | Innovative Construction And Building Materials | Method and composition for polymer-reinforced composite cementitious construction material |
| US6930150B2 (en) * | 2002-08-29 | 2005-08-16 | Taylor Made Golf Company, Inc. | Method for making polymer mixtures and compositions thereof |
| DE602004027038D1 (de) | 2003-06-20 | 2010-06-17 | Kaneka Corp | Härtende zusammensetzung |
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| NO20041205L (no) | 2004-03-22 | 2005-09-23 | Polymers Holding As | Lagringsstabile polymer-oligomer partikler og anvendelse av disse i seed polymerisasjon |
| GB0413338D0 (en) * | 2004-06-15 | 2004-07-21 | Ciba Spec Chem Water Treat Ltd | Polymeric particles |
| ATE455151T1 (de) | 2004-06-15 | 2010-01-15 | Basf Se | Polymerteilchen |
| JP2006052365A (ja) | 2004-08-16 | 2006-02-23 | Jsr Corp | 共重合体ラテックス、共重合体ラテックスの製造方法、紙塗工用組成物及び塗工紙 |
| US7470751B2 (en) * | 2004-09-21 | 2008-12-30 | Basf Corporation | Stabilized water-borne polymer compositions for use as water-based coatings |
| JP2006152484A (ja) | 2004-11-29 | 2006-06-15 | Jsr Corp | 艶消し塗工紙用組成物及び艶消し塗工紙 |
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| CN105732904B (zh) | 2009-06-10 | 2019-03-15 | 宣伟投资管理有限公司 | 低粘度、高固含量共聚物 |
| US9309351B2 (en) | 2010-12-16 | 2016-04-12 | Basf Se | Styrene-acrylic-based binders and methods of preparing and using same |
| EP2809692A1 (en) | 2012-02-03 | 2014-12-10 | DSM IP Assets B.V. | Polymeric beads, process and composition |
| TWI598411B (zh) | 2012-05-29 | 2017-09-11 | 巴斯夫歐洲公司 | 用於印刷墨水及塗層之水基聚合物組成物 |
| US8895658B2 (en) | 2012-12-18 | 2014-11-25 | Columbia Insurance Company | Grafted pigment dispersing polymeric additive and paint employing the same with improved hiding |
| ES2666889T3 (es) | 2013-03-15 | 2018-05-08 | Basf Se | Composiciones que comprenden un copolímero de un oligómero de calidad sólida y un monómero hidrófobo y/o un monómero en fase gaseosa y procedimientos de fabricación de las mismas |
| US10174201B2 (en) | 2013-03-15 | 2019-01-08 | Basf Se | Crosslinked products prepared by ionically crosslinking a solid grade oligomer and a polymer using an ionic crosslinking agent and methods of making the same |
-
2014
- 2014-03-11 US US14/777,365 patent/US10174201B2/en active Active
- 2014-03-11 EP EP14710839.3A patent/EP2970517B1/en active Active
- 2014-03-11 AU AU2014230892A patent/AU2014230892B2/en not_active Ceased
- 2014-03-11 KR KR1020157029350A patent/KR20150129849A/ko not_active Ceased
- 2014-03-11 CA CA2899547A patent/CA2899547A1/en not_active Abandoned
- 2014-03-11 MX MX2015010210A patent/MX2015010210A/es unknown
- 2014-03-11 BR BR112015021904A patent/BR112015021904A2/pt not_active Application Discontinuation
- 2014-03-11 RU RU2015144080A patent/RU2015144080A/ru not_active Application Discontinuation
- 2014-03-11 WO PCT/EP2014/054680 patent/WO2014139999A1/en not_active Ceased
- 2014-03-11 CN CN201480013437.7A patent/CN105283469B/zh not_active Expired - Fee Related
-
2019
- 2019-01-03 US US16/238,895 patent/US20190136061A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| US20190136061A1 (en) | 2019-05-09 |
| EP2970517B1 (en) | 2020-01-01 |
| CA2899547A1 (en) | 2014-09-18 |
| US10174201B2 (en) | 2019-01-08 |
| MX2015010210A (es) | 2015-11-25 |
| AU2014230892A1 (en) | 2015-09-17 |
| CN105283469A (zh) | 2016-01-27 |
| BR112015021904A2 (pt) | 2017-07-18 |
| CN105283469B (zh) | 2018-02-13 |
| WO2014139999A1 (en) | 2014-09-18 |
| EP2970517A1 (en) | 2016-01-20 |
| KR20150129849A (ko) | 2015-11-20 |
| AU2014230892B2 (en) | 2017-05-11 |
| US20160046810A1 (en) | 2016-02-18 |
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