[go: up one dir, main page]

RU2009102602A - METHOD FOR SELECTIVE PRODUCTION OF N- [3- (1,3,5-Dithiazinan-5-yl) propyl] -N- [4- (1,3,5-dithiazinan-5-yl) butyl] amine and n1, n4- BIS [3- (1,3,5-Dithiazinan-5-yl) propyl] -1, 4-butanediamine - Google Patents

METHOD FOR SELECTIVE PRODUCTION OF N- [3- (1,3,5-Dithiazinan-5-yl) propyl] -N- [4- (1,3,5-dithiazinan-5-yl) butyl] amine and n1, n4- BIS [3- (1,3,5-Dithiazinan-5-yl) propyl] -1, 4-butanediamine Download PDF

Info

Publication number
RU2009102602A
RU2009102602A RU2009102602/04A RU2009102602A RU2009102602A RU 2009102602 A RU2009102602 A RU 2009102602A RU 2009102602/04 A RU2009102602/04 A RU 2009102602/04A RU 2009102602 A RU2009102602 A RU 2009102602A RU 2009102602 A RU2009102602 A RU 2009102602A
Authority
RU
Russia
Prior art keywords
dithiazinan
propyl
amine
butanediamine
bis
Prior art date
Application number
RU2009102602/04A
Other languages
Russian (ru)
Other versions
RU2409574C2 (en
Inventor
Внира Рахимовна Ахметова (RU)
Внира Рахимовна Ахметова
Елена Борисовна Рахимова (RU)
Елена Борисовна Рахимова
Райхана Валиулловна Кунакова (RU)
Райхана Валиулловна Кунакова
Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Original Assignee
Учреждение Российской академии наук ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА РАН (RU)
Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Учреждение Российской академии наук ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА РАН (RU), Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран filed Critical Учреждение Российской академии наук ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА РАН (RU)
Priority to RU2009102602/04A priority Critical patent/RU2409574C2/en
Publication of RU2009102602A publication Critical patent/RU2009102602A/en
Application granted granted Critical
Publication of RU2409574C2 publication Critical patent/RU2409574C2/en

Links

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Способ селективного получения N-[3-(1,3,5-дитиазинан-5-ил)пропил]-N-[4-(1,3,5-дитиазинан-5-ил)бутил]амина (1) и N1,N4-бис-[3-(1,3,5-дитиазинан-5-ил)пропил]-1,4-бутандиамина (2) ! ! включающий взаимодействие амина с насыщенным сероводородом водным раствором формальдегида, отличающийся тем, что в качестве амина используют полиметиленполиамин (спермидин или спермин) при мольном соотношении полиамин:формальдегид:сероводород равном 1:6:4 и реакцию проводят при температуре 20°С в течение 3 ч. Method for the selective preparation of N- [3- (1,3,5-dithiazinan-5-yl) propyl] -N- [4- (1,3,5-dithiazinan-5-yl) butyl] amine (1) and N1 , N4-bis- [3- (1,3,5-dithiazinan-5-yl) propyl] -1,4-butanediamine (2)! ! comprising the interaction of an amine with an aqueous solution of formaldehyde saturated with hydrogen sulfide, characterized in that polymethylene polyamine (spermidine or spermine) is used as an amine with a molar ratio of polyamine: formaldehyde: hydrogen sulfide equal to 1: 6: 4 and the reaction is carried out at a temperature of 20 ° C for 3 hours .

Claims (1)

Способ селективного получения N-[3-(1,3,5-дитиазинан-5-ил)пропил]-N-[4-(1,3,5-дитиазинан-5-ил)бутил]амина (1) и N1,N4-бис-[3-(1,3,5-дитиазинан-5-ил)пропил]-1,4-бутандиамина (2)Method for the selective preparation of N- [3- (1,3,5-dithiazinan-5-yl) propyl] -N- [4- (1,3,5-dithiazinan-5-yl) butyl] amine (1) and N 1 , N 4 -bis- [3- (1,3,5-dithiazinan-5-yl) propyl] -1,4-butanediamine (2)
Figure 00000001
Figure 00000002
Figure 00000001
Figure 00000002
 включающий взаимодействие амина с насыщенным сероводородом водным раствором формальдегида, отличающийся тем, что в качестве амина используют полиметиленполиамин (спермидин или спермин) при мольном соотношении полиамин:формальдегид:сероводород равном 1:6:4 и реакцию проводят при температуре 20°С в течение 3 ч. comprising the interaction of an amine with an aqueous solution of formaldehyde saturated with hydrogen sulfide, characterized in that polymethylene polyamine (spermidine or spermine) is used as an amine with a molar ratio of polyamine: formaldehyde: hydrogen sulfide equal to 1: 6: 4 and the reaction is carried out at a temperature of 20 ° C for 3 hours .
RU2009102602/04A 2009-01-26 2009-01-26 Method for selective production of n[3-(1,3,5-dithiazinan-5-yl)propyl]-n-[4-(1,3,5-dithiazinan-5-yl)butyl]amine and n1,n4-bis[3-(1,3,5-dithiazinan-5-yl)propyl]-1,4-butane diamine RU2409574C2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2009102602/04A RU2409574C2 (en) 2009-01-26 2009-01-26 Method for selective production of n[3-(1,3,5-dithiazinan-5-yl)propyl]-n-[4-(1,3,5-dithiazinan-5-yl)butyl]amine and n1,n4-bis[3-(1,3,5-dithiazinan-5-yl)propyl]-1,4-butane diamine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2009102602/04A RU2409574C2 (en) 2009-01-26 2009-01-26 Method for selective production of n[3-(1,3,5-dithiazinan-5-yl)propyl]-n-[4-(1,3,5-dithiazinan-5-yl)butyl]amine and n1,n4-bis[3-(1,3,5-dithiazinan-5-yl)propyl]-1,4-butane diamine

Publications (2)

Publication Number Publication Date
RU2009102602A true RU2009102602A (en) 2010-08-10
RU2409574C2 RU2409574C2 (en) 2011-01-20

Family

ID=42698473

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2009102602/04A RU2409574C2 (en) 2009-01-26 2009-01-26 Method for selective production of n[3-(1,3,5-dithiazinan-5-yl)propyl]-n-[4-(1,3,5-dithiazinan-5-yl)butyl]amine and n1,n4-bis[3-(1,3,5-dithiazinan-5-yl)propyl]-1,4-butane diamine

Country Status (1)

Country Link
RU (1) RU2409574C2 (en)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1341792A (en) * 1961-12-29 1963-11-02 Degussa Process for the preparation of dithiazine compounds
RU2323933C1 (en) * 2006-08-08 2008-05-10 Институт нефтехимии и катализа РАН "method for preparation of 3-thia-1,5-diazabicyclo[4,3,1]decane and 5-[4-(1,3,5-dithiazinane-5-yl)butyl] 1,3,5-dithiazinane mixture"
RU2333910C1 (en) * 2006-11-23 2008-09-20 Институт нефтехимии и катализа РАН Method for obtaining 5-{2-[5-{2-[1,3,5-ditiazinan-5-il]ethyl}-4-methyl-1,3,5-tiadiazinan-3-il]ethyl}-1,3,5,-ditiazinan

Also Published As

Publication number Publication date
RU2409574C2 (en) 2011-01-20

Similar Documents

Publication Publication Date Title
EA201590623A1 (en) STEAM REFORMING CATALYST AND METHOD FOR MANUFACTURING IT
PH12012502453A1 (en) Method of synthesis of ferroquine by convergent reductive amination
RU2008122310A (en) TWO-COMPONENT HYDROGEN HYDROGEN ABSORBENT AND METHOD FOR ITS PRODUCTION
RU2013122694A (en) METHOD FOR PRODUCING AMMONIUM SULPHATE-NITRATE
RU2005114653A (en) METHOD FOR PRODUCING 5- [ORTO- (STEAM -) - HYDROXYPHENYL] -1,3,5-Dithiazines
RU2010132919A (en) METHOD FOR SELECTIVE OBTAINING α, ω-BIS- (1,3,5-DITIAZINAN-5-IL) -3-OXOPENTANE And α, ω-BIS- (1,3,5-DITIAZINAN-5-IL) -3,6 -DIOXOACTANE
RU2010108950A (en) METHOD FOR PRODUCING 3,7-DIARIL-1,3,5,7-DITIADIAZAOCTANES
MX365072B (en) Process for preparing substituted biphenyls by c-h activation.
UY31681A1 (en) COMBRETASTATINE PREPARATION PROCEDURE
RU2009102602A (en) METHOD FOR SELECTIVE PRODUCTION OF N- [3- (1,3,5-Dithiazinan-5-yl) propyl] -N- [4- (1,3,5-dithiazinan-5-yl) butyl] amine and n1, n4- BIS [3- (1,3,5-Dithiazinan-5-yl) propyl] -1, 4-butanediamine
RU2005114640A (en) METHOD FOR PRODUCING N-METHYLENE-4H-1,3,5-Dithiazinyl-5 (6H) AMINE
RU2009102797A (en) METHOD FOR SELECTIVE OBTAINING 2-, 3-, AND 4- (1,3,5-DITIAZINAN-5-IL) THIOPHENOLS
RU2015147242A (en) METHOD FOR PRODUCING ARFORMOTHEROL OR ITS SALT
RU2012100111A (en) METHOD FOR PRODUCING 2- AND 2,3-SUBSTITUTED QUINOLINS
GEP20156350B (en) New process for synthesis of ivabradine and their additional salts with pharmaceutically acceptable acid
RU2007104626A (en) METHOD FOR PRODUCING 5-ACETYLSALICYLOYL-1,3,5-DITIAZINAN
BRPI0909752A2 (en) method for the production of sulfonylpyrrols as hdac inhibitors
RU2010122542A (en) METHOD FOR PRODUCING MONO- (DI-, TETRA-) METHYL-1,2-BIS- (1,3,5-DITIAZINAN-5-IL) ETHANES
RU2008136365A (en) METHOD FOR PRODUCING O-METHYL-N-NITROISOMIC UREA
RU2008138808A (en) METHOD FOR PRODUCING ORGANOPHILIC BENTONITE
RU2006128805A (en) METHOD FOR PRODUCING 3-TIA-1,5-DIAZABICYCLO [4,3,1] DECAN AND 5- [4- (1,3,5-DITIAZINAN-5-IL) BUTYL] 1,3,5-DITIAZINAN
RU2008132580A (en) METHOD FOR SELECTIVE PRODUCTION OF 6,7-DIHYDRO-1,3,5,7-BENZOTRITIAZONINE
RU2011124568A (en) METHOD FOR PRODUCING α, ω-BIS- (1,5,3-DITIAZEPINAN-3-IL) ALKANOV
RU2010108958A (en) METHOD FOR PRODUCING 3,5-DIARIL-1,3,5-THIADIAZINANES
RU2012101387A (en) METHOD FOR PRODUCING N- (1,5,3-DITIAZOCINAN-3-IL) AMIDES

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20110127