RU2008135988A - Способ получения акролеина - Google Patents
Способ получения акролеина Download PDFInfo
- Publication number
- RU2008135988A RU2008135988A RU2008135988/04A RU2008135988A RU2008135988A RU 2008135988 A RU2008135988 A RU 2008135988A RU 2008135988/04 A RU2008135988/04 A RU 2008135988/04A RU 2008135988 A RU2008135988 A RU 2008135988A RU 2008135988 A RU2008135988 A RU 2008135988A
- Authority
- RU
- Russia
- Prior art keywords
- propylene
- oxidation
- acrolein
- dehydration
- gas containing
- Prior art date
Links
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 title claims abstract 12
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract 16
- 238000000034 method Methods 0.000 claims abstract 11
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract 10
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract 10
- 239000007789 gas Substances 0.000 claims abstract 6
- 238000006297 dehydration reaction Methods 0.000 claims abstract 5
- 230000003647 oxidation Effects 0.000 claims abstract 5
- 238000007254 oxidation reaction Methods 0.000 claims abstract 5
- 230000018044 dehydration Effects 0.000 claims abstract 4
- 239000012495 reaction gas Substances 0.000 claims abstract 2
- 235000011187 glycerol Nutrition 0.000 claims 5
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 239000002826 coolant Substances 0.000 claims 1
- 229910001882 dioxygen Inorganic materials 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
- B01J8/0453—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being superimposed one above the other
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0492—Feeding reactive fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0496—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00203—Coils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00805—Details of the particulate material
- B01J2208/00814—Details of the particulate material the particulate material being provides in prefilled containers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1. Способ получения акролеина путем окисления пропилена, отличающийся тем, что он включает стадию дегидратации глицерина в присутствии газа, содержащего пропилен. ! 2. Способ по п.1, отличающийся тем, что газ, содержащий пропилен, представляет собой реакционный газ, забираемый на стадии окисления пропилена в акролеин. ! 3. Способ по п.1, отличающийся тем, что газ, содержащий пропилен, представляет собой газовую смесь, которую загружают в реактор окисления пропилена. ! 4. Способ по одному из пп.1-3, отличающийся тем, что реакцию дегидратации осуществляют в газовой фазе в присутствии катализатора. ! 5. Способ по одному из пп.1-3, отличающийся тем, что добавляют молекулярный кислород на стадии дегидратации глицерина. ! 6. Способ по одному из пп.1-3, отличающийся тем, что глицерин вводят в жидком или в газообразном виде. ! 7. Способ по одному из пп.1-3, отличающийся тем, что используют глицерин в чистом виде или в виде концентрированного или разбавленного водного раствора. ! 8. Способ по одному из пп.1-3, отличающийся тем, что окисление пропилена осуществляют в присутствии избытка тепла. ! 9. Способ по одному из пп.1-3, отличающийся тем, что стадию дегидратации глицерина осуществляют частично в бойлере, который охлаждает теплоноситель, циркулирующий в трубопроводах 6 или 7.
Claims (9)
1. Способ получения акролеина путем окисления пропилена, отличающийся тем, что он включает стадию дегидратации глицерина в присутствии газа, содержащего пропилен.
2. Способ по п.1, отличающийся тем, что газ, содержащий пропилен, представляет собой реакционный газ, забираемый на стадии окисления пропилена в акролеин.
3. Способ по п.1, отличающийся тем, что газ, содержащий пропилен, представляет собой газовую смесь, которую загружают в реактор окисления пропилена.
4. Способ по одному из пп.1-3, отличающийся тем, что реакцию дегидратации осуществляют в газовой фазе в присутствии катализатора.
5. Способ по одному из пп.1-3, отличающийся тем, что добавляют молекулярный кислород на стадии дегидратации глицерина.
6. Способ по одному из пп.1-3, отличающийся тем, что глицерин вводят в жидком или в газообразном виде.
7. Способ по одному из пп.1-3, отличающийся тем, что используют глицерин в чистом виде или в виде концентрированного или разбавленного водного раствора.
8. Способ по одному из пп.1-3, отличающийся тем, что окисление пропилена осуществляют в присутствии избытка тепла.
9. Способ по одному из пп.1-3, отличающийся тем, что стадию дегидратации глицерина осуществляют частично в бойлере, который охлаждает теплоноситель, циркулирующий в трубопроводах 6 или 7.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0601059A FR2897058B1 (fr) | 2006-02-07 | 2006-02-07 | Procede de preparation d'acroleine |
| FR0601059 | 2006-02-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2008135988A true RU2008135988A (ru) | 2010-03-20 |
| RU2399609C2 RU2399609C2 (ru) | 2010-09-20 |
Family
ID=37038311
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2008135988/04A RU2399609C2 (ru) | 2006-02-07 | 2007-02-06 | Способ получения акролеина |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US7531699B2 (ru) |
| EP (1) | EP1981834B1 (ru) |
| JP (1) | JP5209499B2 (ru) |
| KR (1) | KR100995262B1 (ru) |
| CN (1) | CN101379017B (ru) |
| AT (1) | ATE531684T1 (ru) |
| BR (1) | BRPI0707501B1 (ru) |
| ES (1) | ES2376364T3 (ru) |
| FR (1) | FR2897058B1 (ru) |
| MY (1) | MY140962A (ru) |
| PL (1) | PL1981834T3 (ru) |
| RU (1) | RU2399609C2 (ru) |
| WO (1) | WO2007090990A2 (ru) |
| ZA (1) | ZA200806683B (ru) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008066082A1 (en) | 2006-12-01 | 2008-06-05 | Nippon Shokubai Co., Ltd. | Method for producing acrolein and glycerin-containing composition |
| JP5069977B2 (ja) * | 2007-08-30 | 2012-11-07 | 株式会社日本触媒 | グリセリンからのアクロレインの製造方法 |
| FR2913974A1 (fr) | 2007-03-19 | 2008-09-26 | Arkema France | Procede de vaporisation de glycerol |
| FR2920767B1 (fr) * | 2007-09-06 | 2009-12-18 | Arkema France | Procede de vaporisation reactive de glycerol |
| FR2921361B1 (fr) | 2007-09-20 | 2012-10-12 | Arkema France | Procede de fabrication d'acroleine a partir de glycerol |
| US8461391B2 (en) | 2008-05-13 | 2013-06-11 | Basf Se | Method for producing N,N-substituted-1,3-propandiamines |
| EP2179981A1 (en) | 2008-10-24 | 2010-04-28 | Arkema France | Process for manufacturing acrolein from glycerol |
| JP5490129B2 (ja) | 2008-11-05 | 2014-05-14 | ビーエーエスエフ ソシエタス・ヨーロピア | Ｎ，ｎ−置換−３−アミノプロパン−１−オールの製造方法 |
| DE102009027420A1 (de) | 2009-07-02 | 2011-01-05 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Acrolein |
| KR20130128478A (ko) | 2009-09-18 | 2013-11-26 | 닛뽄 가야쿠 가부시키가이샤 | 글리세린의 탈수 반응에 의한 아크롤레인 및/또는 아크릴산의 제조용 촉매 및 방법 |
| KR101478887B1 (ko) | 2009-12-18 | 2015-01-02 | 바텔리 메모리얼 인스티튜트 | 멀티하이드릭 화합물 탈수 시스템, 촉매 조성물, 및 방법 |
| WO2012010923A1 (en) | 2010-07-19 | 2012-01-26 | Arkema France | Process for manufacturing acrolein from glycerol |
| WO2013008279A1 (en) | 2011-07-14 | 2013-01-17 | Nippon Kayaku Kabushiki Kaisha | Process for preparing catalyst used in production of acrolein and/or acrylic acid and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin |
| WO2013017904A1 (en) | 2011-07-29 | 2013-02-07 | Arkema France | Improved process of dehydration reactions |
| US20130274520A1 (en) * | 2012-04-11 | 2013-10-17 | The Procter & Gamble Company | Purification Of Bio Based Acrylic Acid To Crude And Glacial Acrylic Acid |
| FR2989684B1 (fr) * | 2012-04-18 | 2014-10-31 | Arkema France | Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol |
| FR2997398B1 (fr) * | 2012-10-30 | 2014-11-21 | Adisseo France Sas | Procede de preparation de l’acroleine a partir de glycerol |
| FR3019545B1 (fr) * | 2014-04-04 | 2016-03-11 | Arkema France | Procede de synthese directe de (meth)acroleine a partir d'ethers et/ou acetals |
| CN106423236A (zh) * | 2016-06-20 | 2017-02-22 | 广西壮族自治区化工研究院 | 以丙烷为原料生产丙烯酸的催化剂及其制备方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR695931A (fr) | 1929-06-15 | 1930-12-23 | Schering Kahlbaum Ag | Procédé de fabrication d'acroléine |
| US2558520A (en) * | 1948-01-29 | 1951-06-26 | Us Ind Chemicals Inc | Production of acrolein from glycerol |
| SU131347A1 (ru) * | 1959-05-29 | 1959-11-30 | Ю.Д. Кернос | Способ получени акролеина |
| GB1152215A (en) * | 1965-10-12 | 1969-05-14 | Rohm & Haas | Preparation of Acrolein |
| JPS5835971B2 (ja) * | 1979-04-28 | 1983-08-05 | 宇部興産株式会社 | アクロレインの製造方法 |
| US5218146A (en) * | 1987-05-27 | 1993-06-08 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Process for production of acrylic acid |
| JP2794332B2 (ja) * | 1990-08-08 | 1998-09-03 | ダイセル化学工業株式会社 | アクロレインの製造方法 |
| JP3289303B2 (ja) * | 1992-03-06 | 2002-06-04 | 住友化学工業株式会社 | アクロレインの製造方法 |
| DE4238493C1 (de) * | 1992-11-14 | 1994-04-21 | Degussa | Verfahren zur Herstellung von Acrolein und dessen Verwendung |
| DE4238492C2 (de) * | 1992-11-14 | 1995-06-14 | Degussa | Verfahren zur Herstellung von 1,2- und 1,3-Propandiol |
| DE4431957A1 (de) * | 1994-09-08 | 1995-03-16 | Basf Ag | Verfahren zur katalytischen Gasphasenoxidation von Propen zu Acrolein |
| BR9810715A (pt) * | 1997-07-15 | 2000-08-08 | Du Pont | Processo para oxidação seletiva da fase de vapor de propileno em acroleìna |
| TW476746B (en) * | 1997-07-23 | 2002-02-21 | Shell Int Research | Hydrogenolysis of glycerol |
| DE19848208A1 (de) | 1998-10-20 | 2000-04-27 | Deg Engineering Gmbh | Reaktor für die katalytische Umsetzung von Reaktionsmedien, insbesondere von gasförmigen Reaktionsmedien |
| DE10019381B4 (de) | 2000-04-19 | 2006-05-18 | Daun, Klaus-Dieter, Dipl.-Ing. | Reaktor für die katalytische Umsetzung von Reaktionsmedien, insbesondere von gasförmigen Reaktionsmedien |
| US7294734B2 (en) * | 2003-05-02 | 2007-11-13 | Velocys, Inc. | Process for converting a hydrocarbon to an oxygenate or a nitrile |
| US7268254B2 (en) * | 2003-07-24 | 2007-09-11 | Basf Aktiengesellschaft | Preparation of (meth)acrolein and/or (meth)acrylic acid by heterogeneously catalyzed partial oxidation of C3 and/or C4 precursor compounds in a reactor having thermoplate modules |
-
2006
- 2006-02-07 FR FR0601059A patent/FR2897058B1/fr not_active Expired - Fee Related
-
2007
- 2007-02-06 WO PCT/FR2007/050757 patent/WO2007090990A2/fr not_active Ceased
- 2007-02-06 AT AT07731583T patent/ATE531684T1/de active
- 2007-02-06 MY MYPI20083002A patent/MY140962A/en unknown
- 2007-02-06 US US12/162,691 patent/US7531699B2/en active Active
- 2007-02-06 ES ES07731583T patent/ES2376364T3/es active Active
- 2007-02-06 CN CN2007800045886A patent/CN101379017B/zh not_active Expired - Fee Related
- 2007-02-06 RU RU2008135988/04A patent/RU2399609C2/ru active
- 2007-02-06 PL PL07731583T patent/PL1981834T3/pl unknown
- 2007-02-06 JP JP2008551844A patent/JP5209499B2/ja not_active Expired - Fee Related
- 2007-02-06 KR KR1020087019377A patent/KR100995262B1/ko not_active Expired - Fee Related
- 2007-02-06 BR BRPI0707501A patent/BRPI0707501B1/pt not_active IP Right Cessation
- 2007-02-06 EP EP07731583A patent/EP1981834B1/fr not_active Not-in-force
-
2008
- 2008-07-31 ZA ZA200806683A patent/ZA200806683B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES2376364T3 (es) | 2012-03-13 |
| ZA200806683B (en) | 2009-05-27 |
| CN101379017A (zh) | 2009-03-04 |
| WO2007090990A2 (fr) | 2007-08-16 |
| CN101379017B (zh) | 2013-01-02 |
| US20080319233A1 (en) | 2008-12-25 |
| MY140962A (en) | 2010-02-12 |
| JP5209499B2 (ja) | 2013-06-12 |
| US7531699B2 (en) | 2009-05-12 |
| RU2399609C2 (ru) | 2010-09-20 |
| BRPI0707501A2 (pt) | 2011-05-10 |
| FR2897058A1 (fr) | 2007-08-10 |
| KR20080085088A (ko) | 2008-09-22 |
| JP2009524629A (ja) | 2009-07-02 |
| WO2007090990A3 (fr) | 2007-12-06 |
| EP1981834B1 (fr) | 2011-11-02 |
| ATE531684T1 (de) | 2011-11-15 |
| EP1981834A2 (fr) | 2008-10-22 |
| FR2897058B1 (fr) | 2008-04-18 |
| KR100995262B1 (ko) | 2010-11-19 |
| BRPI0707501B1 (pt) | 2016-04-26 |
| PL1981834T3 (pl) | 2012-03-30 |
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