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RU2008128865A - SPRING STEEL, METHOD FOR PRODUCING A SPRING FROM SUCH STEEL AND A SPRING FROM THIS STEEL - Google Patents

SPRING STEEL, METHOD FOR PRODUCING A SPRING FROM SUCH STEEL AND A SPRING FROM THIS STEEL Download PDF

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RU2008128865A
RU2008128865A RU2008128865/02A RU2008128865A RU2008128865A RU 2008128865 A RU2008128865 A RU 2008128865A RU 2008128865/02 A RU2008128865/02 A RU 2008128865/02A RU 2008128865 A RU2008128865 A RU 2008128865A RU 2008128865 A RU2008128865 A RU 2008128865A
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steel
spring
smelting
spring steel
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RU2397270C2 (en
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Нао ЕСИХАРА (JP)
Нао ЕСИХАРА
Казухиса КАВАТА (JP)
Казухиса КАВАТА
Жюли МУГЕН (FR)
Жюли МУГЕН
Жак ЛАНГИЙОМ (FR)
Жак ЛАНГИЙОМ
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/02Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for springs
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/34Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/004Dispersions; Precipitations

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Heat Treatment Of Articles (AREA)
  • Heat Treatment Of Steel (AREA)
  • Wire Processing (AREA)
  • Springs (AREA)

Abstract

1. Пружинная сталь с повышенной усталостной прочностью на воздухе и в коррозионной среде и с высокой стойкостью против циклического разупрочнения, следующего состава, вес.%: ! С0,45-0,70Si1,65-2,50Mn0,20-0,75Cr0,60-2,0Ni0,15-1,0Моследы-1,0V0,003-0,8Cu0,10-1,0Ti0,020-0,2Nbследы-0,2Al0,002-0,050Рследы-0,015Sследы-0,015Оследы-0,0020N0,0020-0,0110 ! остальное - железо и сопутствующие при выплавке примеси, при этом содержание эквивалентного углерода Ceq в стали, рассчитанное по формуле: ! Ceq%=[С%]+0,12[Si%]+0,17[Mn%]-0,1[Ni%]+0,13[Cr5]-0,24[V%], ! составляет от 0,80 до 1,00%, твердость стали после закалки и отпуска превышает или равна 55 HRC. ! 2. Пружинная сталь по п.1, отличающаяся тем, что максимальный размер нитридов или карбонитридов титана на глубине 1,5 мм±0,5 мм от поверхности прутка, катанки или заготовки или пружины сечением с площадью 100 мм2 составляет 20 мкм или менее, причем упомянутый размер является величиной квадратного корня величины площади включений, форму которых принимают за квадрат. ! 3. Пружинная сталь по п.1 или 2, отличающаяся тем, что она имеет следующий состав, вес.%: ! С0,45-0,65Si1,65-2,20Mn0,20-0,65Cr0,80-1,7Ni0,15-0,80Моследы-0,80V0,003-0,5Сu0,10-0,90Ti0,020-0,15Nbследы-0,15Al0,002-0,050Рследы-0,010Sследы-0,010Oследы-0,0020N0,0020-0,0110 ! остальное - железо и сопутствующие при выплавке примеси. ! 4. Способ получения пружинной стали с повышенной усталостной прочностью на воздухе и в коррозионной среде и с высокой стойкостью против циклического разупрочнения, включающий выплавку жидкой стали в конвертере или электропечи, корректировку ее состава, разливку с получением блюмов или сутунок способом непрерывной разливки или слитков, охлаждение до температуры окружающей среды, прокатку с получением прутков, катанки или заготовок и изготовление пружин, отличающи�1. Spring steel with increased fatigue resistance in air and in a corrosive environment and with high resistance to cyclic softening, of the following composition, wt.%:! C0.45-0.70 Si1.65-2.50Mn0.20-0.75Cr0.60-2.0 Ni0.15-1.0 Sequences-1.0V0.003-0.8Cu0.10-1.0 Ti0.020- 0.2Nb-traces-0.2Al0.002-0.050-traces-0.015S-traces-0.015Traces-0.0020N0.0020-0.0110! the rest is iron and impurities associated with the smelting, while the content of Ceq equivalent carbon in steel, calculated by the formula:! Ceq% = [C%] + 0.12 [Si%] + 0.17 [Mn%] - 0.1 [Ni%] + 0.13 [Cr5] -0.24 [V%],! ranges from 0.80 to 1.00%, the hardness of steel after quenching and tempering is greater than or equal to 55 HRC. ! 2. Spring steel according to claim 1, characterized in that the maximum size of titanium nitrides or carbonitrides at a depth of 1.5 mm ± 0.5 mm from the surface of a rod, wire rod or billet or spring with a cross-section with an area of 100 mm2 is 20 μm or less, wherein said size is the square root value of the area of inclusions, the shape of which is taken as square. ! 3. Spring steel according to claim 1 or 2, characterized in that it has the following composition, wt.%:! С0.45-0.65Si1.65-2.20Mn0.20-0.65Cr0.80-1.7Ni0.15-0.80 Sequences-0.80V0.003-0.5Cu0.10-0.90Ti0.020- 0.15 Nb traces-0.15 Al0.002-0.050 Traces-0.010 S traces-0.010 O traces-0.0020N0.0020-0.0110! the rest is iron and the impurities associated with the smelting. ! 4. A method of producing spring steel with increased fatigue strength in air and in a corrosive environment and with high resistance against cyclic softening, including smelting of liquid steel in a converter or electric furnace, adjusting its composition, casting to produce blooms or sutures by continuous casting or ingots, cooling to ambient temperature, rolling to produce rods, wire rods or billets and manufacturing springs that distinguish

Claims (6)

1. Пружинная сталь с повышенной усталостной прочностью на воздухе и в коррозионной среде и с высокой стойкостью против циклического разупрочнения, следующего состава, вес.%:1. Spring steel with increased fatigue strength in air and in a corrosive environment and with high resistance against cyclic softening, of the following composition, wt.%: СFROM 0,45-0,700.45-0.70 SiSi 1,65-2,501.65-2.50 MnMn 0,20-0,750.20-0.75 CrCr 0,60-2,00.60-2.0 NiNi 0,15-1,00.15-1.0 МоMo следы-1,0traces-1.0 VV 0,003-0,80.003-0.8 CuCu 0,10-1,00.10-1.0 TiTi 0,020-0,20,020-0,2 NbNb следы-0,2traces-0.2 AlAl 0,002-0,0500.002-0.050 РR следы-0,015footprints-0.015 SS следы-0,015footprints-0.015 ОABOUT следы-0,0020traces-0.0020 NN 0,0020-0,01100.0020-0.0110
остальное - железо и сопутствующие при выплавке примеси, при этом содержание эквивалентного углерода Ceq в стали, рассчитанное по формуле:the rest is iron and impurities associated with the smelting, while the content of Ceq equivalent carbon in steel, calculated by the formula: Ceq%=[С%]+0,12[Si%]+0,17[Mn%]-0,1[Ni%]+0,13[Cr5]-0,24[V%],Ceq% = [C%] + 0.12 [Si%] + 0.17 [Mn%] - 0.1 [Ni%] + 0.13 [Cr5] -0.24 [V%], составляет от 0,80 до 1,00%, твердость стали после закалки и отпуска превышает или равна 55 HRC.ranges from 0.80 to 1.00%, the hardness of steel after quenching and tempering is greater than or equal to 55 HRC.
2. Пружинная сталь по п.1, отличающаяся тем, что максимальный размер нитридов или карбонитридов титана на глубине 1,5 мм±0,5 мм от поверхности прутка, катанки или заготовки или пружины сечением с площадью 100 мм2 составляет 20 мкм или менее, причем упомянутый размер является величиной квадратного корня величины площади включений, форму которых принимают за квадрат.2. Spring steel according to claim 1, characterized in that the maximum size of titanium nitrides or carbonitrides at a depth of 1.5 mm ± 0.5 mm from the surface of a rod, wire rod or billet or spring with a cross section of 100 mm 2 is 20 μm or less wherein said size is the square root value of the area of inclusions whose shape is taken as square. 3. Пружинная сталь по п.1 или 2, отличающаяся тем, что она имеет следующий состав, вес.%:3. Spring steel according to claim 1 or 2, characterized in that it has the following composition, wt.%: СFROM 0,45-0,650.45-0.65 SiSi 1,65-2,201.65-2.20 MnMn 0,20-0,650.20-0.65 CrCr 0,80-1,70.80-1.7 NiNi 0,15-0,800.15-0.80 МоMo следы-0,80traces-0.80 VV 0,003-0,50.003-0.5 СuCu 0,10-0,900.10-0.90 TiTi 0,020-0,150,020-0,15 NbNb следы-0,15traces-0.15 AlAl 0,002-0,0500.002-0.050 РR следы-0,010traces-0.010 SS следы-0,010traces-0.010 OO следы-0,0020traces-0.0020 NN 0,0020-0,01100.0020-0.0110
остальное - железо и сопутствующие при выплавке примеси.the rest is iron and the impurities associated with the smelting.
4. Способ получения пружинной стали с повышенной усталостной прочностью на воздухе и в коррозионной среде и с высокой стойкостью против циклического разупрочнения, включающий выплавку жидкой стали в конвертере или электропечи, корректировку ее состава, разливку с получением блюмов или сутунок способом непрерывной разливки или слитков, охлаждение до температуры окружающей среды, прокатку с получением прутков, катанки или заготовок и изготовление пружин, отличающийся тем, что:4. A method of producing spring steel with increased fatigue strength in air and in a corrosive environment and with high resistance against cyclic softening, including the smelting of liquid steel in a converter or electric furnace, the adjustment of its composition, casting to produce blooms or sutures by continuous casting or ingots, cooling to ambient temperature, rolling to obtain rods, wire rods or billets and the manufacture of springs, characterized in that: сталь представляет собой тип стали по любому из пп.1-3,steel is a type of steel according to any one of claims 1 to 3, блюмы, сутунки или слитки во время их затвердевания или после него подвергают охлаждению со средней скоростью 0,3°С/с в диапазоне 1450-1300°С,blooms, stoops or ingots during their solidification or after it is subjected to cooling at an average rate of 0.3 ° C / s in the range of 1450-1300 ° C, указанные блюмы, сутунки или слитки прокатывают при температуре 1200-800°С за один или два цикла нагрева и прокатки,these blooms, stoops or ingots are rolled at a temperature of 1200-800 ° C for one or two heating and rolling cycles, подвергают блюмы, катанку или заготовки или изготовленные из них пружины аустенизации в диапазоне температур 850-1000°С с последующей закалкой в воду, полимер или масло и отпуску при 300-550°С для придания стали твердости 55 HRC или более.subjected to blooms, wire rod or billets or austenitization springs made from them in the temperature range 850-1000 ° C followed by quenching in water, polymer or oil and tempering at 300-550 ° C to give steel hardness of 55 HRC or more. 5. Пружина, отличающаяся тем, что ее изготавливают из стали по любому из пп.1-3.5. A spring, characterized in that it is made of steel according to any one of claims 1 to 3. 6. Пружина по п.5, отличающаяся тем, что ее изготавливают из стали, полученной способом по п.4. 6. The spring according to claim 5, characterized in that it is made of steel obtained by the method according to claim 4.
RU2008128865/02A 2005-12-15 2006-12-11 Spring steel, procedure for fabrication of spring out of this steel ans spring out of this steel RU2397270C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0512775 2005-12-15
FR0512775A FR2894987B1 (en) 2005-12-15 2005-12-15 SPRING STEEL, AND METHOD OF MANUFACTURING A SPRING USING THE SAME, AND SPRING REALIZED IN SUCH A STEEL

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RU2008128865A true RU2008128865A (en) 2010-01-20
RU2397270C2 RU2397270C2 (en) 2010-08-20

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US (1) US20080308195A1 (en)
EP (1) EP1966407B1 (en)
JP (1) JP4869051B2 (en)
KR (1) KR101048946B1 (en)
CN (1) CN101400818B (en)
AT (1) ATE445026T1 (en)
BR (1) BRPI0619892B1 (en)
CA (1) CA2633153C (en)
DE (1) DE602006009705D1 (en)
ES (1) ES2331539T3 (en)
FR (1) FR2894987B1 (en)
ME (1) ME01062B (en)
NO (1) NO341748B1 (en)
PL (1) PL1966407T3 (en)
RS (1) RS51070B (en)
RU (1) RU2397270C2 (en)
SI (1) SI1966407T1 (en)
WO (1) WO2007080256A1 (en)

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