[go: up one dir, main page]

RU2004115603A - METHOD FOR REDUCING THE GAS TEMPERATURE CONTAINING HYDROGEN AND CARBON MONOXIDE, AND THE HEAT EXCHANGER FOR REDUCING THE HOT GAS TEMPERATURE - Google Patents

METHOD FOR REDUCING THE GAS TEMPERATURE CONTAINING HYDROGEN AND CARBON MONOXIDE, AND THE HEAT EXCHANGER FOR REDUCING THE HOT GAS TEMPERATURE Download PDF

Info

Publication number
RU2004115603A
RU2004115603A RU2004115603/06A RU2004115603A RU2004115603A RU 2004115603 A RU2004115603 A RU 2004115603A RU 2004115603/06 A RU2004115603/06 A RU 2004115603/06A RU 2004115603 A RU2004115603 A RU 2004115603A RU 2004115603 A RU2004115603 A RU 2004115603A
Authority
RU
Russia
Prior art keywords
metal alloy
gas
heat exchanger
temperature
layer formed
Prior art date
Application number
RU2004115603/06A
Other languages
Russian (ru)
Other versions
RU2293912C2 (en
Inventor
ДОНГЕН Францискус Герардус ВАН (NL)
Донген Францискус Герардус ван
ГРААФ Уиннифред ДЕ (NL)
ГРААФ Уиннифред ДЕ
Тхиан Хой ТИО (NL)
Тхиан Хой ТИО
Антоний ВОЛЬФЕРТ (NL)
Антоний ВОЛЬФЕРТ
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL)
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL), Шелл Интернэшнл Рисерч Маатсхаппий Б.В. filed Critical Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL)
Publication of RU2004115603A publication Critical patent/RU2004115603A/en
Application granted granted Critical
Publication of RU2293912C2 publication Critical patent/RU2293912C2/en

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
    • F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
    • F28F21/081—Heat exchange elements made from metals or metal alloys
    • F28F21/087—Heat exchange elements made from metals or metal alloys from nickel or nickel alloys
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/02—Apparatus characterised by being constructed of material selected for its chemically-resistant properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/013—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C27/00—Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
    • C22C27/06—Alloys based on chromium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C30/00—Alloys containing less than 50% by weight of each constituent
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22—STEAM GENERATION
    • F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B37/00—Component parts or details of steam boilers
    • F22B37/02—Component parts or details of steam boilers applicable to more than one kind or type of steam boiler
    • F22B37/04—Component parts or details of steam boilers applicable to more than one kind or type of steam boiler and characterised by material, e.g. use of special steel alloy
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F19/00—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
    • B01J2219/0277—Metal based
    • B01J2219/029—Non-ferrous metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00—Arc welding or cutting
    • B23K9/04—Welding for other purposes than joining, e.g. built-up welding
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0238—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0255—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0883—Methods of cooling by indirect heat exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Metallurgy (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Industrial Gases (AREA)
  • Fuel Cell (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Chemically Coating (AREA)

Claims (19)

1. Способ уменьшения температуры газа, содержащего водород и монооксид углерода, характеризующийся тем, что вводят газ в контакт с образуемой металлическим сплавом поверхностью, имеющей более низкую температуру по сравнению с температурой газа, причем на образуемой металлическим сплавом поверхности содержится от 0 до 20% (мас.) железа, от 0 до 5% (мас.) алюминия, от 0 до 5% (мас.) кремния, от 20 до 50% (мас.) хрома и, по меньшей мере, 35% (мас.) никеля, при этом образуемую металлическим сплавом поверхность выдерживают при своей более низкой температуре по сравнению с температурой газа в результате использования охлаждающей воды.1. A method of reducing the temperature of a gas containing hydrogen and carbon monoxide, characterized in that the gas is brought into contact with a surface formed by a metal alloy having a lower temperature compared to the temperature of the gas, wherein the surface formed by the metal alloy contains from 0 to 20% ( wt.) iron, from 0 to 5% (wt.) aluminum, from 0 to 5% (wt.) of silicon, from 20 to 50% (wt.) of chromium and at least 35% (wt.) of nickel while the surface formed by the metal alloy is maintained at its lower temperature in cf Gas temperature as a result of using cooling water. 2. Способ по п.1, характеризующийся тем, что на образуемой металлическим сплавом поверхности содержится от 1 до 5% (мас.) кремния.2. The method according to claim 1, characterized in that on the surface formed by the metal alloy contains from 1 to 5% (wt.) Silicon. 3. Способ по п.1 или 2, характеризующийся тем, что содержание хрома превышает 30% (мас.).3. The method according to claim 1 or 2, characterized in that the chromium content exceeds 30% (wt.). 4. Способ по любому из пп.1 и 2, характеризующийся тем, что на образуемой металлическим сплавом поверхности содержится от 1 до 5% (мас.) алюминия.4. The method according to any one of claims 1 and 2, characterized in that the surface formed by the metal alloy contains from 1 to 5% (wt.) Aluminum. 5. Способ по любому из п.1 или 2, характеризующийся тем, что на образуемой металлическим сплавом поверхности содержится от 0 до 2% (мас.) титана и/или REM.5. The method according to any one of claim 1 or 2, characterized in that the surface formed by the metal alloy contains from 0 to 2% (wt.) Titanium and / or REM. 6. Способ по любому из п.1 или 2, характеризующийся тем, что образуемая металлическим сплавом поверхность опирается на образуемый металлическим сплавом несущий слой, обладающий лучшими механическими свойствами по сравнению с поверхностным слоем.6. The method according to any one of claims 1 or 2, characterized in that the surface formed by the metal alloy is supported by the carrier layer formed by the metal alloy having better mechanical properties compared to the surface layer. 7. Способ по п.6, характеризующийся тем, что образуемый металлическим сплавом несущий слой содержит от 7 до 98% (мас.) железа.7. The method according to claim 6, characterized in that the supporting layer formed by the metal alloy contains from 7 to 98% (wt.) Iron. 8. Способ по любому из п.1 или 2, характеризующийся тем, что образуемый металлическим сплавом поверхностный слой наносят на образуемый металлическим сплавом несущий слой, используя способ наплавки.8. The method according to any one of claims 1 or 2, characterized in that the surface layer formed by the metal alloy is applied to the support layer formed by the metal alloy using a surfacing method. 9. Способ по любому из п.1 или 2, характеризующийся тем, что температуру газа, содержащего водород, уменьшают от температуры в диапазоне от 1000 до 1500°С до температуры в диапазоне от 300 до 750°С.9. The method according to any one of claims 1 or 2, characterized in that the temperature of the gas containing hydrogen is reduced from a temperature in the range from 1000 to 1500 ° C. to a temperature in the range from 300 to 750 ° C. 10. Способ по любому из п.1 или 2, характеризующийся тем, что газ, содержащий водород, также содержит монооксид углерода при мольном соотношении водорода и СО в диапазоне от 1,6 до 2,5.10. The method according to any one of claims 1 or 2, characterized in that the gas containing hydrogen also contains carbon monoxide in a molar ratio of hydrogen to CO in the range from 1.6 to 2.5. 11. Способ по любому из п.1 или 2, характеризующийся тем, что газ содержит менее 15% (об.) водяного пара.11. The method according to any one of claim 1 or 2, characterized in that the gas contains less than 15% (vol.) Water vapor. 12. Способ по любому одному из п.1 или 2, характеризующийся тем, что способ неполного окисления приводит к получению газа, содержащего водород и монооксид углерода.12. The method according to any one of claim 1 or 2, characterized in that the method of partial oxidation leads to the production of a gas containing hydrogen and carbon monoxide. 13. Способ по любому из п.1 или 2, характеризующийся тем, что газ охлаждают в результате пропускания газа через одну либо несколько труб, которые погружают в охлаждающую воду, содержащуюся в емкости, в которой образуется водяной пар, который выпускают из емкости, причем на внутренней поверхности труб содержится образуемый металлическим сплавом поверхностный слой, а на внешней поверхности труб содержится образуемый металлическим сплавом несущий слой.13. The method according to any one of claim 1 or 2, characterized in that the gas is cooled by passing gas through one or more pipes, which are immersed in cooling water contained in the tank, in which water vapor is formed, which is released from the tank, a surface layer formed by the metal alloy is contained on the inner surface of the pipes, and a carrier layer formed by the metal alloy is contained on the outer surface of the pipes. 14. Теплообменник для понижения температуры горячего газа, характеризующийся тем, что содержит емкость, имеющую отделение для охлаждающей воды, впускное отверстие для охлаждаемого газа, выпускное отверстие для охлажденного газа, выпускное отверстие для нагретого водяного пара и пространство коллектора для вмещения образованного водяного пара и, по меньшей мере, одну трубу первичного испарителя, размещенную в отделении для охлаждающей воды и соединенную через текучую среду с впускным отверстием для охлаждаемого газа, и, по меньшей мере, одну пароотводящую трубу для отбора образованного водяного пара из пространства коллектора для вмещения образованного водяного пара и впускное отверстие для свежей воды, причем внутренняя поверхность материала трубы первичного испарителя сформирована образуемой металлическим сплавом поверхностью, на которой содержится от 0 до 20% (мас.) железа, от 0 до 5% (мас.) алюминия, от 0 до 5% (мас.) кремния, от 20 до 50% (мас.) хрома и, по меньшей мере, 35% (мас.), при этом данная поверхность опирается на образуемый металлическим сплавом несущий слой, обладающий лучшими механическими свойствами по сравнению с поверхностным слоем.14. A heat exchanger for lowering the temperature of the hot gas, characterized in that it comprises a container having a compartment for cooling water, an inlet for a cooled gas, an outlet for cooled gas, an outlet for heated water vapor and a manifold space for receiving the generated water vapor and, at least one primary evaporator tube located in the cooling water compartment and connected through the fluid to the inlet for the cooled gas, and at least the bottom of the steam exhaust pipe for collecting the generated water vapor from the space of the collector to contain the formed water vapor and an inlet for fresh water, the inner surface of the material of the primary evaporator pipe being formed by a metal alloy formed surface containing from 0 to 20% (wt.) iron, from 0 to 5% (wt.) aluminum, from 0 to 5% (wt.) of silicon, from 20 to 50% (wt.) of chromium and at least 35% (wt.), while this surface is supported onto a carrier layer formed by a metal alloy having better mechanical properties compared to the surface layer. 15. Теплообменник по п.14, характеризующийся тем, что на образуемой металлическим сплавом поверхности содержится от 1 до 5% (мас.) алюминия.15. The heat exchanger according to 14, characterized in that on the surface formed by the metal alloy contains from 1 to 5% (wt.) Aluminum. 16. Теплообменник по любому из п.14 или 15, характеризующийся тем, что на образуемой металлическим сплавом поверхности содержится от 1 до 5% (мас.) кремния.16. The heat exchanger according to any one of p. 14 or 15, characterized in that on the surface formed by the metal alloy contains from 1 to 5% (wt.) Silicon. 17. Теплообменник по п.14, характеризующийся тем, что содержание хрома на образуемой металлическим сплавом поверхности превышает 25% (мас.).17. The heat exchanger according to 14, characterized in that the chromium content on the surface formed by the metal alloy exceeds 25% (wt.). 18. Теплообменник по любому из п.14 или 15, характеризующийся тем, что на образуемой металлическим сплавом поверхности содержится от 0 до 2% (мас.) титана и/или REM.18. The heat exchanger according to any one of paragraph 14 or 15, characterized in that on the surface formed by the metal alloy contains from 0 to 2% (wt.) Titanium and / or REM. 19. Теплообменник по любому одному из п.14 или 15, характеризующийся тем, что образуемый металлическим сплавом поверхностный слой наносят на образуемый металлическим сплавом несущий слой используя способ наплавки.19. The heat exchanger according to any one of p. 14 or 15, characterized in that the surface layer formed by the metal alloy is applied to the carrier layer formed by the metal alloy using a deposition method.
RU2004115603/06A 2001-10-22 2002-10-22 Method and device for reducing gas temperature RU2293912C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP01204009.3 2001-10-22
EP01204009 2001-10-22

Publications (2)

Publication Number Publication Date
RU2004115603A true RU2004115603A (en) 2005-05-20
RU2293912C2 RU2293912C2 (en) 2007-02-20

Family

ID=8181114

Family Applications (2)

Application Number Title Priority Date Filing Date
RU2004115633/15A RU2300493C2 (en) 2001-10-22 2002-10-22 Method of production of gas containing hydrogen and carbon oxide
RU2004115603/06A RU2293912C2 (en) 2001-10-22 2002-10-22 Method and device for reducing gas temperature

Family Applications Before (1)

Application Number Title Priority Date Filing Date
RU2004115633/15A RU2300493C2 (en) 2001-10-22 2002-10-22 Method of production of gas containing hydrogen and carbon oxide

Country Status (10)

Country Link
US (3) US7422706B2 (en)
EP (2) EP1438259A2 (en)
JP (2) JP2005515140A (en)
AU (2) AU2002350598B2 (en)
GC (2) GC0000404A (en)
MY (2) MY136087A (en)
NO (2) NO20042086L (en)
RU (2) RU2300493C2 (en)
WO (2) WO2003036166A2 (en)
ZA (2) ZA200402448B (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8603430B2 (en) * 2002-02-05 2013-12-10 The Regents Of The University Of California Controlling the synthesis gas composition of a steam methane reformer
US7125913B2 (en) * 2003-03-14 2006-10-24 Conocophillips Company Partial oxidation reactors and syngas coolers using nickel-containing components
EP1613552A1 (en) * 2003-04-15 2006-01-11 Shell Internationale Researchmaatschappij B.V. Process to prepare synthesis gas
JP4527426B2 (en) * 2004-03-25 2010-08-18 アイシン精機株式会社 Fuel reformer
EP1610081A1 (en) * 2004-06-25 2005-12-28 Haldor Topsoe A/S Heat exchange process and heat exchanger
US7642294B2 (en) 2004-10-08 2010-01-05 Shell Oil Company Process to prepare lower olefins from a carbon containing feedstock
CA2587289C (en) * 2004-11-18 2010-07-06 Praxair Technology, Inc. Steam methane reforming method
US7037485B1 (en) * 2004-11-18 2006-05-02 Praxair Technology, Inc. Steam methane reforming method
US7354660B2 (en) 2005-05-10 2008-04-08 Exxonmobil Research And Engineering Company High performance alloys with improved metal dusting corrosion resistance
US7485767B2 (en) 2005-06-29 2009-02-03 Exxonmobil Chemical Patents Inc. Production of synthesis gas blends for conversion to methanol or Fischer-Tropsch liquids
US20070237710A1 (en) * 2006-04-05 2007-10-11 Genkin Eugene S Reforming apparatus and method for syngas generation
WO2007142739A2 (en) 2006-05-31 2007-12-13 Exxonmobil Chemical Patents Inc. Synthesis gas production and use
EP1995543A1 (en) 2007-05-10 2008-11-26 AGC Flat Glass Europe SA Heat exchanger for oxygen
US8168687B2 (en) * 2009-11-30 2012-05-01 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process for decreasing or eliminating unwanted hydrocarbon and oxygenate products caused by Fisher Tropsch synthesis reactions in a syngas treatment unit
US8163809B2 (en) * 2009-11-30 2012-04-24 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process for decreasing or eliminating unwanted hydrocarbon and oxygenate products caused by Fisher Tropsch Synthesis reactions in a syngas treatment unit
US8202914B2 (en) * 2010-02-22 2012-06-19 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process for decreasing or eliminating unwanted hydrocarbon and oxygenate products caused by Fisher Tropsch Synthesis reactions in a syngas treatment unit
GB201115929D0 (en) 2011-09-15 2011-10-26 Johnson Matthey Plc Improved hydrocarbon production process
WO2018093604A1 (en) * 2016-11-17 2018-05-24 Exxonmobil Research And Engineering Company Method for converting natural gas to dimethyl ether

Family Cites Families (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US488513A (en) 1892-12-20 Joiin anderson
US2647041A (en) * 1946-04-15 1953-07-28 Phillips Petroleum Co Production of hydrogen from hydrocarbons
US2587530A (en) * 1948-03-13 1952-02-26 Rossi Giovanni Water and fire tube for steam boilers
FR1081773A (en) 1952-11-24 1954-12-22 exchanger-vaporizer
GB792827A (en) * 1954-02-19 1958-04-02 Hercules Powder Co Ltd Improvements in or relating to process for catalytic treatment of hydrocarbons
FR2302004A5 (en) * 1973-08-31 1976-09-17 Thomson Csf AUTOMATIC TARGET TRACKING SYSTEM, PROCESSED BY VIDEO CONTRAST ANALYSIS
US3918410A (en) * 1974-06-19 1975-11-11 Handelsbolaget Broderna Backma Boiler for heating of water and generating of steam
SU670325A1 (en) * 1975-11-18 1979-06-30 Среднеазиатский Научно-Исследовательский Институт Нефтеперерабатывающей Промышленности Catalyst for vapour conversion of gaseous hydrocarbon
US4132065A (en) 1977-03-28 1979-01-02 Texaco Inc. Production of H2 and co-containing gas stream and power
US4433644A (en) * 1981-11-06 1984-02-28 Fitzpatrick James J Steam boilers
DE3272205D1 (en) * 1981-12-21 1986-08-28 Ici Plc Process for steam reforming a hydrocarbon feedstock and catalyst therefor
JPS5919792A (en) * 1982-07-26 1984-02-01 日揮株式会社 Carbon deposition preventive centrifugal force casting double pipe
US4487744A (en) * 1982-07-28 1984-12-11 Carpenter Technology Corporation Corrosion resistant austenitic alloy
JPS59176501A (en) * 1983-03-28 1984-10-05 株式会社日立製作所 boiler tube
US4488513A (en) * 1983-08-29 1984-12-18 Texaco Development Corp. Gas cooler for production of superheated steam
GB2163449B (en) * 1984-07-18 1988-06-02 Shell Int Research Production of gas mixtures containing hydrogen and carbon monoxide
US4919844A (en) * 1984-08-16 1990-04-24 Air Products And Chemicals, Inc. Enhanced heat transfer reformer and method
DE3663652D1 (en) * 1985-03-05 1989-07-06 Ici Plc Steam reforming hydrocarbons
CA1309907C (en) * 1986-08-26 1992-11-10 Herman Johannes Lameris Process and apparatus for heating steam formed from cooling water
US4685427A (en) 1986-12-08 1987-08-11 Inco Alloys International, Inc. Alloy for composite tubing in fluidized-bed coal combustor
GB8711156D0 (en) 1987-05-12 1987-06-17 Shell Int Research Partial oxidation of hydrocarbon-containing fuel
DE3716665A1 (en) * 1987-05-19 1988-12-08 Vdm Nickel Tech CORROSION RESISTANT ALLOY
DE3803082A1 (en) 1988-02-03 1989-08-17 Uhde Gmbh MULTI-STAGE PROCESS FOR GENERATING H (DOWN ARROW) 2 (DOWN ARROW) AND CO-CONTAINING SYNTHESIS GAS
US4827074A (en) * 1988-04-08 1989-05-02 Idemitsu Petrochemical Co., Ltd. Method of thermally decomposing hydrocarbon and thermal decomposition tube
SE9102410L (en) * 1991-08-21 1992-11-23 Sandvik Ab APPLICATION OF AN AUSTENITIC CHROME-NICKEL-MOLYBDEN-YEAR ALloy FOR MANUFACTURING COMPODO DRAWERS FOR APPLICATION AS BOTH TUBES IN SODA HOUSES
US6274113B1 (en) * 1994-01-04 2001-08-14 Chevron Phillips Chemical Company Lp Increasing production in hydrocarbon conversion processes
SE513552C2 (en) * 1994-05-18 2000-10-02 Sandvik Ab Use of a Cr-Ni-Mo alloy with good workability and structural stability as a component in waste incineration plants
DK173540B1 (en) * 1994-06-29 2001-02-05 Topsoe Haldor As Waste heat boiler
MY115440A (en) 1994-07-22 2003-06-30 Shell Int Research A process for the manufacture of synthesis gas by partial oxidation of a gaseous hydrocarbon-containing fuel using a multi-orifice (co-annular)burner
CN1104625C (en) 1995-01-20 2003-04-02 国际壳牌研究有限公司 Apparatus for cooling solids laden hot gases
WO1996033454A1 (en) 1995-04-21 1996-10-24 Hitoshi Takekasa Input device through which all characters and symbols are inputted using only numeric keys, and film drawing device using the input device
EG20966A (en) 1995-06-06 2000-07-30 Shell Int Research A method for flame stabilization in a process for preparing synthesis gas
US5931978A (en) * 1995-12-18 1999-08-03 Shell Oil Company Process for preparing synthesis gas
RU2149202C1 (en) * 1996-04-16 2000-05-20 Сименс Акциенгезелльшафт Article for direction of hot oxidizing gas
US5873950A (en) * 1996-06-13 1999-02-23 Inco Alloys International, Inc. Strengthenable ethylene pyrolysis alloy
JP3104622B2 (en) 1996-07-15 2000-10-30 住友金属工業株式会社 Nickel-based alloy with excellent corrosion resistance and workability
SE509043C2 (en) 1996-09-05 1998-11-30 Sandvik Ab Use of a compound tube with an outer layer of a Ni alloy for superheaters and waste boilers
US6247113B1 (en) * 1998-05-27 2001-06-12 Arm Limited Coprocessor opcode division by data type
RU2141383C1 (en) * 1998-07-20 1999-11-20 Институт катализа им.Г.К.Борескова СО РАН Method of preparation of hydrocarbon conversion catalyst
RU2136366C1 (en) * 1998-07-20 1999-09-10 Институт катализа им.Г.К.Борескова СО РАН Method of preparing fischer-tropsch catalyst
DK173742B1 (en) 1998-09-01 2001-08-27 Topsoe Haldor As Process and reactor system for producing synthesis gas
US5945067A (en) * 1998-10-23 1999-08-31 Inco Alloys International, Inc. High strength corrosion resistant alloy
US6162267A (en) * 1998-12-11 2000-12-19 Uop Llc Process for the generation of pure hydrogen for use with fuel cells
CA2303732C (en) * 1999-04-09 2010-05-25 Daido Tokushuko Kabushiki Kaisha Multi-layered anti-coking heat resisting metal tube and the method for manufacturing thereof
DE19926402C1 (en) 1999-06-10 2000-11-02 Steinmueller Gmbh L & C Generating steam from gases produced by non-catalytic cracking of hydrocarbons comprises passing them through one tube of double-walled heat exchanger in water-filled container, with different fluid being passed through other tube
AU4090600A (en) * 1999-06-30 2001-01-04 Rohm And Haas Company High performance heat exchangers
US6329079B1 (en) * 1999-10-27 2001-12-11 Nooter Corporation Lined alloy tubing and process for manufacturing the same
DE10028824A1 (en) 2000-06-10 2001-12-13 Linde Ag Synthetic gas cooling process involves input of fresh water at least partly by topping up cooling water flow in circuit

Also Published As

Publication number Publication date
EP1438259A2 (en) 2004-07-21
NO20042088L (en) 2004-05-21
MY136087A (en) 2008-08-29
ZA200402448B (en) 2006-05-31
WO2003036166A3 (en) 2003-10-23
NO20042086L (en) 2004-05-21
US7422706B2 (en) 2008-09-09
JP4436675B2 (en) 2010-03-24
AU2002350595B2 (en) 2008-01-31
RU2293912C2 (en) 2007-02-20
US7597067B2 (en) 2009-10-06
GC0000326A (en) 2006-11-01
US20090294103A1 (en) 2009-12-03
WO2003036166A2 (en) 2003-05-01
EP1438534B1 (en) 2012-11-14
EP1438534A2 (en) 2004-07-21
MY138154A (en) 2009-04-30
JP2005506443A (en) 2005-03-03
ZA200402707B (en) 2005-02-23
US20040262579A1 (en) 2004-12-30
GC0000404A (en) 2007-03-31
JP2005515140A (en) 2005-05-26
US20040241086A1 (en) 2004-12-02
RU2300493C2 (en) 2007-06-10
RU2004115633A (en) 2005-05-27
AU2002350598B2 (en) 2007-04-26
WO2003036165A3 (en) 2003-10-23
WO2003036165A2 (en) 2003-05-01

Similar Documents

Publication Publication Date Title
RU2004115603A (en) METHOD FOR REDUCING THE GAS TEMPERATURE CONTAINING HYDROGEN AND CARBON MONOXIDE, AND THE HEAT EXCHANGER FOR REDUCING THE HOT GAS TEMPERATURE
RU2008150586A (en) DEVICE FOR COOLING GASES (SHARP COOLING) WITH FORMATION OF CORROSION CONDENSATE
JP2005506443A5 (en) Method for lowering temperature of hydrogen and carbon monoxide-containing gas, and heat exchanger used in the method
JP2003532789A (en) Heat resistant pressure vessel
EP0687870B1 (en) Heat exchanger
CA2484143C (en) An absorption air conditioner body
RU2541489C2 (en) Method and device for evaporation of cryogenic media
EP0478112B1 (en) Vacuum boiler type evaporator
CA2262265A1 (en) Apparatus for concentrating and purifying sulfuric acid
JP2004012050A (en) Latent heat recovery device and water heater equipped with the same
FR2840542A1 (en) Distillation plant recovering and concentrating aqueous or organic liquids, comprises boiler, condenser, vacuum ejector, separator and heat pump circuit
EP0200782A1 (en) Solution heat pump apparatus and method
JP2011242023A (en) Liquid fuel water heater
CN216205353U (en) Cooling water vapor collecting device in aluminum alloy ingot production process
CN209923278U (en) Purification water outlet device for waste lubricating oil
RU2278333C2 (en) Steam-water boiler
RU2131104C1 (en) Air-condensing plant
CN220989718U (en) A crude benzene distillation and emission reduction system without water vapor
JPH09209933A (en) Condensation trap
CN2309551Y (en) Heat pipe cooler for cooling high-viscosity fluid
CN222684583U (en) Wine distiller with circular heat exchange function
CN213220969U (en) Liquid ammonia unloads automobile-used steam engine
JPH11173781A (en) Heat storage device
TWI299778B (en)
CN207963527U (en) A condensing device for recovering reaction tail gas of galvanizing solution

Legal Events

Date Code Title Description
QB4A Licence on use of patent

Effective date: 20081209

MM4A The patent is invalid due to non-payment of fees

Effective date: 20091023