GB792827A - Improvements in or relating to process for catalytic treatment of hydrocarbons - Google Patents
Improvements in or relating to process for catalytic treatment of hydrocarbonsInfo
- Publication number
- GB792827A GB792827A GB421855A GB421855A GB792827A GB 792827 A GB792827 A GB 792827A GB 421855 A GB421855 A GB 421855A GB 421855 A GB421855 A GB 421855A GB 792827 A GB792827 A GB 792827A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrocarbons
- reaction
- catalytic
- tube
- heated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000003197 catalytic effect Effects 0.000 title abstract 5
- 229930195733 hydrocarbon Natural products 0.000 title abstract 5
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 7
- 239000003054 catalyst Substances 0.000 abstract 5
- 238000010438 heat treatment Methods 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 229910000423 chromium oxide Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229910000431 copper oxide Inorganic materials 0.000 abstract 1
- 238000006356 dehydrogenation reaction Methods 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 abstract 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical class [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 abstract 1
- 229910001950 potassium oxide Inorganic materials 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- -1 zinc aluminate Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
- B01J8/0407—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds
- B01J8/0415—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds the beds being superimposed one above the other
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0207—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/386—Catalytic partial combustion
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/321—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Fluid Mechanics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Medicinal Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Catalysts (AREA)
Abstract
<PICT:0792827/III/1> In a process for catalytically treating fluid hydrocarbons, a heated reaction vessel contains a catalytic basket spaced from the walls so as to give a reaction space between the heating wall and the catalyst basket, which is continuously heated by radiation from the vessel. A refractory wall furnace 10 is employed to heat a thin walled metallic reaction tube 11, which passes completely through the furnace and is provided with inlets 12 and 13 and outlet 14. Concentrically disposed within the tube is a catalyst container 17 disposed in spaced relationship with the inner wall of the reaction tube to provide a narrow passageway 18 for reaction. A thin layer of particulate catalyst 19 is confined between the outer foraminous screen 20 and the fluid-impervious tubular member 21. Alternatively, as in Figures not shown, the reactor may be heated by an internal heating tube or the catalytic baskets may be placed on top of one another or may be coaxially disposed. Fluidized solids and heating gases may be also introduced into the reaction space. Reactions specified are the catalytic production of hydrogen from hydrocarbons the catalytic hydroforming of naphthenic hydrocarbons, polymerization of olefines and the hydrogenation of naphthenes and olefines, dehydrogenation of butylene and the oxiation of hydrocarbons. Catalysts specified are chromium or molybdenum oxides supported on zinc aluminate, chromium oxide on silica or alumina Fe203 supported on magnesium oxide together with promoters or accelerators such as copper or potassium oxide and catalysts described in Specification 640,368 and U.S.A. Specifications 2,571,953 and 2,575,324.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US1133808XA | 1954-02-19 | 1954-02-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB792827A true GB792827A (en) | 1958-04-02 |
Family
ID=22349067
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB421855A Expired GB792827A (en) | 1954-02-19 | 1955-02-11 | Improvements in or relating to process for catalytic treatment of hydrocarbons |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE1080981B (en) |
| FR (1) | FR1133808A (en) |
| GB (1) | GB792827A (en) |
| NL (1) | NL103240C (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2077347A1 (en) * | 1970-01-27 | 1971-10-22 | Selas Corp Of America | |
| US3751232A (en) * | 1971-01-14 | 1973-08-07 | Universal Oil Prod Co | Means for effecting a multiple stage contact of a reactant stream |
| EP0021736A3 (en) * | 1979-06-27 | 1981-06-10 | Imperial Chemical Industries Plc | Catalytic process involving carbon monoxide and hydrogen |
| EP0036268A1 (en) * | 1980-03-18 | 1981-09-23 | British Gas Corporation | Vaporisation and gasification of hydrocarbon feedstocks |
| RU2300493C2 (en) * | 2001-10-22 | 2007-06-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Method of production of gas containing hydrogen and carbon oxide |
| ITMI20131564A1 (en) * | 2013-09-23 | 2015-03-24 | Rivoira S P A | ENDOGAS GENERATION SYSTEM |
| CN113264502A (en) * | 2020-08-29 | 2021-08-17 | 江苏集萃分子工程研究院有限公司 | Hydrogen production device by hydrolysis of sodium borohydride of kilowatt-level fuel cell |
| CN113277468A (en) * | 2020-08-29 | 2021-08-20 | 江苏集萃分子工程研究院有限公司 | Integrated kilowatt-level fuel cell sodium borohydride hydrolysis hydrogen production device |
| CN113477027A (en) * | 2021-08-04 | 2021-10-08 | 中冶赛迪技术研究中心有限公司 | Integrated device and method for desulfurization, adsorption, regeneration, cooling and recovery of blast furnace gas |
| CN113845404A (en) * | 2021-09-30 | 2021-12-28 | 中国石油化工股份有限公司 | A kind of method for preparing hydrogenated bisphenol A by catalytic hydrogenation of bisphenol A |
| US11438976B2 (en) | 2020-02-04 | 2022-09-06 | Qwave Solutions, Inc. | Apparatuses, systems, and methods for heating with electromagnetic waves |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1180719B (en) * | 1961-04-18 | 1964-11-05 | Georg Schwaneck | Device for treating granules with gas |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE270062C (en) * | ||||
| DE386395C (en) * | 1922-10-27 | 1923-12-15 | Merck Chem Fab E | Device for carrying out contact reactions of gaseous substances |
| DE578824C (en) * | 1926-11-27 | 1933-06-17 | I G Farbenindustrie Akt Ges | Conversion of hydrocarbons or gas mixtures containing them |
| DE570026C (en) * | 1927-06-28 | 1933-02-10 | I G Farbenindustrie Akt Ges | Process for the catalytic conversion of hydrocarbons |
| DE542494C (en) * | 1928-12-16 | 1932-01-25 | I G Farbenindustrie Akt Ges | Device for carrying out endothermic catalytic gas reactions |
| USRE21521E (en) * | 1937-08-30 | 1940-07-30 | Process for catalytic reaction | |
| US2524840A (en) * | 1945-02-06 | 1950-10-10 | Hercules Powder Co Ltd | Hydrogen production |
| US2628890A (en) * | 1946-06-20 | 1953-02-17 | Hercules Powder Co Ltd | Process for the decomposition of hydrocarbons |
| DE807802C (en) * | 1949-09-03 | 1951-07-05 | Georg Vogelsang | Clamping device, especially for clamping items of clothing to be separated |
| US2665979A (en) * | 1949-10-31 | 1954-01-12 | United Gas Improvement Co | Method of reforming gaseous hydrocarbons |
| DE933087C (en) * | 1952-03-11 | 1955-09-15 | J F Mahler | Tube furnace with bent tubes for the catalytic mass to convert gaseous or vaporous substances |
-
1955
- 1955-02-11 GB GB421855A patent/GB792827A/en not_active Expired
- 1955-02-16 FR FR1133808D patent/FR1133808A/en not_active Expired
- 1955-02-18 DE DEH23035A patent/DE1080981B/en active Pending
- 1955-02-19 NL NL194978A patent/NL103240C/xx active
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2077347A1 (en) * | 1970-01-27 | 1971-10-22 | Selas Corp Of America | |
| US3751232A (en) * | 1971-01-14 | 1973-08-07 | Universal Oil Prod Co | Means for effecting a multiple stage contact of a reactant stream |
| EP0021736A3 (en) * | 1979-06-27 | 1981-06-10 | Imperial Chemical Industries Plc | Catalytic process involving carbon monoxide and hydrogen |
| EP0036268A1 (en) * | 1980-03-18 | 1981-09-23 | British Gas Corporation | Vaporisation and gasification of hydrocarbon feedstocks |
| RU2300493C2 (en) * | 2001-10-22 | 2007-06-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Method of production of gas containing hydrogen and carbon oxide |
| ITMI20131564A1 (en) * | 2013-09-23 | 2015-03-24 | Rivoira S P A | ENDOGAS GENERATION SYSTEM |
| EP2851339A1 (en) * | 2013-09-23 | 2015-03-25 | Rivoira S.p.A. | Modulable system for the generation of endogas |
| US11438976B2 (en) | 2020-02-04 | 2022-09-06 | Qwave Solutions, Inc. | Apparatuses, systems, and methods for heating with electromagnetic waves |
| CN113264502A (en) * | 2020-08-29 | 2021-08-17 | 江苏集萃分子工程研究院有限公司 | Hydrogen production device by hydrolysis of sodium borohydride of kilowatt-level fuel cell |
| CN113277468A (en) * | 2020-08-29 | 2021-08-20 | 江苏集萃分子工程研究院有限公司 | Integrated kilowatt-level fuel cell sodium borohydride hydrolysis hydrogen production device |
| CN113477027A (en) * | 2021-08-04 | 2021-10-08 | 中冶赛迪技术研究中心有限公司 | Integrated device and method for desulfurization, adsorption, regeneration, cooling and recovery of blast furnace gas |
| CN113845404A (en) * | 2021-09-30 | 2021-12-28 | 中国石油化工股份有限公司 | A kind of method for preparing hydrogenated bisphenol A by catalytic hydrogenation of bisphenol A |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1080981B (en) | 1960-05-05 |
| FR1133808A (en) | 1957-04-02 |
| NL103240C (en) | 1962-12-17 |
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