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RU2001125920A - Способ селективного окисления целлюлозы - Google Patents

Способ селективного окисления целлюлозы

Info

Publication number
RU2001125920A
RU2001125920A RU2001125920/04A RU2001125920A RU2001125920A RU 2001125920 A RU2001125920 A RU 2001125920A RU 2001125920/04 A RU2001125920/04 A RU 2001125920/04A RU 2001125920 A RU2001125920 A RU 2001125920A RU 2001125920 A RU2001125920 A RU 2001125920A
Authority
RU
Russia
Prior art keywords
group
cellulose
oxidation
carbaldehyde
nitroxyl compound
Prior art date
Application number
RU2001125920/04A
Other languages
English (en)
Inventor
Ян Маттхейс ЕТТЕН (NL)
Ян Маттхейс ЕТТЕН
ДЕН ДОЛ Роналд ВАН (NL)
ДЕН ДОЛ Роналд ВАН
ХАРТИНГСВЕЛДТ Вим ВАН (NL)
ХАРТИНГСВЕЛДТ Вим ВАН
Ари Корнелис БЕСЕМЕР (NL)
Ари Корнелис БЕСЕМЕР
Original Assignee
Ска Хайджин Продактс Зейст Б.В. (Nl)
Ска Хайджин Продактс Зейст Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ска Хайджин Продактс Зейст Б.В. (Nl), Ска Хайджин Продактс Зейст Б.В. filed Critical Ска Хайджин Продактс Зейст Б.В. (Nl)
Publication of RU2001125920A publication Critical patent/RU2001125920A/ru

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/16Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
    • D21H11/20Chemically or biochemically modified fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B15/00Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
    • C08B15/02Oxycellulose; Hydrocellulose; Cellulosehydrate, e.g. microcrystalline cellulose
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/001Modification of pulp properties
    • D21C9/002Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Materials For Medical Uses (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Multicomponent Fibers (AREA)

Claims (10)

1. Способ окисления целлюлозы, используя ионы нитрозония, полученные окислением нитроксильного соединения окисляющим агентом, отличающийся тем, что нитроксильное соединение окисляют в присутствии окисляющего фермента или комплекса переходного металла и комплексообразующего агента.
2. Способ по п.1, отличающийся тем, что нитроксильным соединением является ди-трет-нитроксильное соединение, особенно 2,2,6,6-тетраметилпиперидин-1-оксил (TEMPO).
3. Способ по п.1 или 2, отличающийся тем, что переходным металлом является марганец, железо, кобальт, никель, медь или ванадий.
4. Способ по одному из пп.1-3, отличающийся тем, что комплексообразующим агентом является азотсодержащее соединение.
5. Способ по п.4, отличающийся тем, что комплексообразующим агентом является бипиридил или триазонан или (поли)гистидин.
6. Способ по п.1, отличающийся тем, что окисляющим ферментом является пероксидаза, полифенолоксидаза или лакказа.
7. Способ по одному пп.1-6, отличающийся тем, что получают производное целлюлозы, содержащее по меньшей мере 1 циклическую моносахаридную цепную группу, несущую карбальдегидную группу на 25 моносахаридных звеньев и на среднюю молекулу.
8. Окисленная целлюлоза, содержащая по меньшей мере 1 циклическую моносахаридную цепную группу, несущую 6-карбальдегидную группу и по меньшей мере 1 циклическую моносахаридную цепную группу, несущую 6-карбоксильную группу на 100 моносахаридных звеньев и на среднюю молекулу, или ее химические производные.
9. Производное целлюлозы, в которой по меньшей мере часть 6-карбальдегидных групп, введенных окислением, превращена в производные окислением до групп формул -CH=N-R или CH2-NHR, где R означает водород, гидроксил, аминогруппу или группу R1, OR1 или NHR1, где R1 означает С120-алкил, С120-ацил, остаток углевода или группу, связанную или способную к связыванию с остатком углевода.
10. Производное целлюлозы, в котором по меньшей мере часть 6-карбальдегидных групп, введенных окислением, превращена в группу формулы -CH(OR3)-О-CH2-COOR2 или -CH(-О-CH2-COOR2)2, где R2 означает водород, катион металла или возможно замещенную аммониевую группу, и R3 означает водород или простую связь с атомом кислорода дегидрированной гидроксильной группы целлюлозы.
RU2001125920/04A 1999-02-24 2000-02-24 Способ селективного окисления целлюлозы RU2001125920A (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP99200537 1999-02-24
EP99200537.1 1999-02-24

Publications (1)

Publication Number Publication Date
RU2001125920A true RU2001125920A (ru) 2004-02-20

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU2001125920/04A RU2001125920A (ru) 1999-02-24 2000-02-24 Способ селективного окисления целлюлозы

Country Status (16)

Country Link
US (1) US6716976B1 (ru)
EP (1) EP1155039B1 (ru)
JP (1) JP2002537448A (ru)
CN (1) CN1341125A (ru)
AT (1) ATE271068T1 (ru)
AU (1) AU776991B2 (ru)
BR (1) BR0008475A (ru)
CZ (1) CZ20012873A3 (ru)
DE (1) DE60012148T2 (ru)
DK (1) DK1155039T3 (ru)
ES (1) ES2223462T3 (ru)
HU (1) HUP0105300A3 (ru)
PL (1) PL350423A1 (ru)
RU (1) RU2001125920A (ru)
WO (1) WO2000050463A1 (ru)
ZA (2) ZA200106416B (ru)

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Also Published As

Publication number Publication date
ATE271068T1 (de) 2004-07-15
ZA200106416B (en) 2002-11-04
PL350423A1 (en) 2002-12-16
HUP0105300A3 (en) 2004-04-28
CN1341125A (zh) 2002-03-20
DK1155039T3 (da) 2004-11-08
ZA200106740B (en) 2002-08-15
US6716976B1 (en) 2004-04-06
EP1155039B1 (en) 2004-07-14
WO2000050463A1 (en) 2000-08-31
DE60012148D1 (de) 2004-08-19
EP1155039A1 (en) 2001-11-21
CZ20012873A3 (cs) 2002-01-16
HUP0105300A2 (hu) 2002-04-29
BR0008475A (pt) 2002-02-05
AU2833000A (en) 2000-09-14
AU776991B2 (en) 2004-09-30
DE60012148T2 (de) 2005-07-21
ES2223462T3 (es) 2005-03-01
JP2002537448A (ja) 2002-11-05

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