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PE20140735A1 - Proceso para preparar un catalizador fischer tropsch que contiene cobalto - Google Patents

Proceso para preparar un catalizador fischer tropsch que contiene cobalto

Info

Publication number
PE20140735A1
PE20140735A1 PE2013002912A PE2013002912A PE20140735A1 PE 20140735 A1 PE20140735 A1 PE 20140735A1 PE 2013002912 A PE2013002912 A PE 2013002912A PE 2013002912 A PE2013002912 A PE 2013002912A PE 20140735 A1 PE20140735 A1 PE 20140735A1
Authority
PE
Peru
Prior art keywords
cobalt
catalyst
compound
catalyst precursor
initial
Prior art date
Application number
PE2013002912A
Other languages
English (en)
Inventor
Rensburg Hendrik Van
Original Assignee
Sasol Tech Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Tech Pty Ltd filed Critical Sasol Tech Pty Ltd
Publication of PE20140735A1 publication Critical patent/PE20140735A1/es

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913Cobalt and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/75Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0205Impregnation in several steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/082Decomposition and pyrolysis
    • B01J37/088Decomposition of a metal salt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12Oxidising
    • B01J37/14Oxidising with gases containing free oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16Reducing
    • B01J37/18Reducing with gases containing free hydrogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425Catalysts; their physical properties
    • C07C1/043Catalysts; their physical properties characterised by the composition
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12Silica and alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0213Preparation of the impregnating solution
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

SE REFIERE A UN PROCESO PARA PREPARAR UN CATALIZADOR DE SINTESIS DE HIDROCARBUROS QUE CONTIENE COBALTO QUE COMPRENDE: A) CALCINAR UN PRECURSOR DE CATALIZADOR INICIAL QUE COMPRENDE UN SOPORTE DE CATALIZADOR QUE SOPORTA UN COMPUESTO DE COBALTO TAL COMO Co(NO3)2.6H2O TRATANDO CON CALOR EL PRECURSOR DE CATALIZADOR INICIAL EN CONDICIONES NO REDUCTORAS A FIN DE DESCOMPONER EL COMPUESTO DE COBALTO Y/O HACER QUE EL COMPUESTO DE COBALTO REACCIONE CON OXIGENO A UNA TEMPERATURA DE 95�C A 400�C CON LO CUAL SE OBTIENE UN PRECURSOR DE CATALIZADOR INICIAL CALCINADO; B) INTRODUCIR UN COMPUESTO DE COBALTO SOBRE Y/O DENTRO DEL PRECURSOR DE CATALIZADOR INICIAL CALCINADO DE MODO QUE EL PRECURSOR DE CATALIZADOR INICIAL CALCINADO SOPORTE ESTE COMPUESTO DE COBALTO, CON LO CUAL SE OBTIENE UN PRECURSOR DE CATALIZADOR SUBSIGUIENTE; C) SOMETER DIRECTAMENTE EL PRECURSOR DE CATALIZADOR SUBSIGUIENTE A CONDICIONES DE REDUCCION SIN UN PRIMER SOMETIMIENTO AL TRATAMIENTO CON CALOR A CONDICIONES DE OXIDACION QUE CAUSAN OXIDACION DEL COMPUESTO DE COBALTO SOPORTADO O DESCOMPOSICION DEL COMPUESTO DE COBALTO PARA ACTIVAR EL PRECURSOR DE CATALIZADOR SUBSIGUIENTE, CON LO CUAL SE OBTIENE UN CATALIZADOR DE SINTESIS DE HIDROCARBUROS QUE CONTIENE COBALTO
PE2013002912A 2011-09-21 2012-08-31 Proceso para preparar un catalizador fischer tropsch que contiene cobalto PE20140735A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ZA201106909 2011-09-21

Publications (1)

Publication Number Publication Date
PE20140735A1 true PE20140735A1 (es) 2014-06-30

Family

ID=47018331

Family Applications (1)

Application Number Title Priority Date Filing Date
PE2013002912A PE20140735A1 (es) 2011-09-21 2012-08-31 Proceso para preparar un catalizador fischer tropsch que contiene cobalto

Country Status (14)

Country Link
US (1) US9248435B2 (es)
EP (1) EP2758170B1 (es)
JP (1) JP5961694B2 (es)
CN (1) CN103635256B (es)
AP (1) AP2013007293A0 (es)
AR (1) AR087975A1 (es)
AU (1) AU2012311175B2 (es)
BR (1) BR112013032165B8 (es)
CA (1) CA2838233C (es)
MY (1) MY164214A (es)
PE (1) PE20140735A1 (es)
RU (1) RU2602803C2 (es)
WO (1) WO2013041997A1 (es)
ZA (1) ZA201309045B (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2838233C (en) 2011-09-21 2019-08-06 Sasol Technology (Proprietary) Limited Process for preparing a cobalt - containing fischer tropsch catalyst
EP3233277B1 (en) * 2014-12-19 2019-07-03 Bp P.L.C. Process for preparation of a supported cobalt-containing fischer-tropsch synthesis catalyst
DK3393659T3 (da) * 2015-12-21 2022-02-21 Shell Int Research Fremgangsmåde til fremstilling af en hydrogeneringskatalysator
JP6916219B2 (ja) 2016-08-11 2021-08-11 サソル サウス アフリカ リミティド コバルト含有触媒組成物

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4413064A (en) * 1981-10-13 1983-11-01 Gulf Research & Development Company Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel
DE3839580C1 (es) 1988-11-24 1990-07-05 Condea Chemie Gmbh, 2212 Brunsbuettel, De
DZ2013A1 (fr) 1995-04-07 2002-10-23 Sastech Ltd Catalyseurs.
DE69909112T2 (de) 1998-10-05 2003-12-24 Sasol Technology (Proprietary) Ltd., Johannesburg Tränkungsverfahren für katalysatoren
CA2500646C (en) * 2002-10-16 2010-12-14 Conocophillips Company Fischer-tropsch processes and catalysts using stabilized supports
US7012104B2 (en) * 2002-10-16 2006-03-14 Conocophillips Company Fischer-Tropsch processes and catalysts made from a material comprising boehmite
CN100479917C (zh) * 2003-04-07 2009-04-22 新日本制铁株式会社 由合成气制造烃的催化剂及催化剂的制造方法
JP4914840B2 (ja) * 2005-01-11 2012-04-11 サソール テクノロジー(プロプライエタリー)リミテッド フィッシャー・トロプシュ合成用の担持コバルト触媒の製造
US7524787B2 (en) 2005-01-11 2009-04-28 Sasol Technology (Proprietary Limited) Producing supported cobalt catalysts for the Fisher-Tropsch synthesis
EP1947073A1 (de) 2007-01-22 2008-07-23 Phillip Mertens Zubreitungsform mit verzögerter Freisetzungsrate für wasserlösliche und/oder wasserunlösliche Stoffe
US20100160464A1 (en) * 2008-12-24 2010-06-24 Chevron U.S.A. Inc. Zeolite Supported Cobalt Hybrid Fischer-Tropsch Catalyst
SG173637A1 (en) * 2009-02-26 2011-09-29 Sasol Tech Pty Ltd Process for the preparation of fischer - tropsch catalysts and their use
US7943674B1 (en) * 2009-11-20 2011-05-17 Chevron U.S.A. Inc. Zeolite supported cobalt hybrid fischer-tropsch catalyst
CA2838233C (en) 2011-09-21 2019-08-06 Sasol Technology (Proprietary) Limited Process for preparing a cobalt - containing fischer tropsch catalyst

Also Published As

Publication number Publication date
US9248435B2 (en) 2016-02-02
ZA201309045B (en) 2014-08-27
CN103635256B (zh) 2016-08-17
BR112013032165A2 (pt) 2016-12-13
JP2014527908A (ja) 2014-10-23
AU2012311175A1 (en) 2014-01-09
EP2758170A1 (en) 2014-07-30
US20140155501A1 (en) 2014-06-05
NZ618839A (en) 2015-10-30
BR112013032165B1 (pt) 2019-09-03
CN103635256A (zh) 2014-03-12
WO2013041997A1 (en) 2013-03-28
EP2758170B1 (en) 2015-10-07
CA2838233C (en) 2019-08-06
AU2012311175B2 (en) 2016-09-01
BR112013032165B8 (pt) 2019-11-05
RU2013154968A (ru) 2015-10-27
JP5961694B2 (ja) 2016-08-02
MY164214A (en) 2017-11-30
CA2838233A1 (en) 2013-03-28
RU2602803C2 (ru) 2016-11-20
AP2013007293A0 (en) 2013-12-31
AR087975A1 (es) 2014-04-30

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