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KR910009814A - 불소함유 공중합체 조성물 - Google Patents

불소함유 공중합체 조성물 Download PDF

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KR910009814A
KR910009814A KR1019900019235A KR900019235A KR910009814A KR 910009814 A KR910009814 A KR 910009814A KR 1019900019235 A KR1019900019235 A KR 1019900019235A KR 900019235 A KR900019235 A KR 900019235A KR 910009814 A KR910009814 A KR 910009814A
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요우이찌 히라꾸리
사까에 무라까미
하지메 이나가끼
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다께바야시 쇼오고
미쓰이세끼유 가가꾸고오교오 가부시끼가이샤
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Abstract

내용 없음.

Description

불소함유 공중합체 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. 플루오르 올레핀(a)과, 분자내에 올레핀성 불포화 결합과 가수분해성기를 갖는 유기 실리콘 화합물(b)로 된 불소함유 공중합체(A) 및 이소시아네이트기를 갖는 유기 실리콘 화합물(B)로 구성된 것이 특징인 불소함유 공중합체 조성물.
  2. 제1항에 있어서, 상기 유기 실리콘 화합물(B)의 사용량이 상기 불소함유 공중합체(A) 100중량부당 0.1∼60중량부인 것이 특징인 불소함유 공중합체 조성물.
  3. 제1항에 있어서, 상기 불소함유 공중합체(A)가 상기 플루오르 올레핀(a)을 25∼70몰% 함유하는 것이 특징인 불소함유 공중합체 조성물.
  4. 제1항에 있어서, 상기 불소함유 공중합체(A)가 상기 유기 실리콘 화합물(b)을 1∼50몰%을 함유하는 것이 특징인 불소함유 공중합체 조성물.
  5. 제1항에 있어서, 상기 플루오르 올레핀(a)의 탄소수가 2 또는 3인 것이 특징인 불소함유 공중합체조성물.
  6. 제1항에 있어서, 상기 유기 실리콘 화합물(b)이 하기 일반식(I),(II) 또는 (3)으로 표시되는 실란화합물인 것이 특징인 불소함유 공중합체 조성물:
    RlR2SiYlY2[I]
    RIXlSiYlY2[II]
    또는
    RlSiYlY2Y3[III]
    (상기 식에서, R1과 R2는 서로 같거나 다르며, 올레핀성 불포화 결합을 갖는 1가의 유기기를 나타내며, X1은 올레핀성 불포화 결합을 갖지 않는 1가의 유기기를 나타내며, Yl,Y2및 Y3는 서로 같거나 다르고, 가수분해성기를 나타낸다).
  7. 제6항에 있어서, 상기 R1이 비닐기이고, Yl,Y2및 Y3가 알콕시기 또는 알콕시 알콕시기인 것이 특징인 불소함유 공중합체 조성물.
  8. 제6항에 있어서, 상기 실란 화합물이, 비닐트리 메톡시실란, 비닐트리에톡시실란, 비닐트리스(메톡시에톡시)실란, 비닐옥시프로필트리메톡시실란, 비닐메틸디에톡시실란 및 비닐페닐디메톡시실란으로 구성된 그룹에서 선택된 화합물인 것이 특징인 불소함유 공중합체 조성물.
  9. 제1항에 있어서, 상기 불소함유 공중합체(A)가, 알킬비닐 에테르(c), 카르복시산 비닐에스테르(d)및 불포화 카르복시산 또는 그의 유도체(e)로 구성된 그룹에서 선택된 1이상의 공단량체를 더 포함하는 것이 특징인 불소함유 공중합체 조성물.
  10. 제1항에 있어서, 상기 유기 실리콘 화합물(B)이 1이상의 가수분해성기를 갖는 것이 특징인 불소함유 공중합체 조성물.
  11. 제10항에 있어서, 상기 유기 실리콘 화합물(B)이 하기 일반식(IV)으로 표시되는 것인 불소함유 공중합체 조성물:
    (이 식에서, R3은 가수분해성기이고, R4는 수소원자 또는 유기기를 나타내며, R5는 유기기를 나타내며, 복수의 R3,R4또는 R5가 존재하는 경우, 이들은 서로 같거나 다르고, m은 0∼3의 정수, n은 0∼3의 정수, p는 0∼4의 정수, q는 0∼4의 정수이며, 단, m+n+p+q=4이고 p+q≥1이다)
  12. 제10항에 있어서, 상기 유기 실리콘 화합물(B)이 하기 일반식(V)으로 표시되는 것인 불소함유 공중합체 조성물:
    (이 식에서, R6은 가수분해성기, R7은 수소원자 또는 유기기, R8은 탄소수 1∼10의 알킬렌, 옥시알킬렌 또는 알케닐렌기이며, m은 1∼3의 정수, n은 0∼2의 정수이고, 단, m+n=3이고, 복수의 R6또는 R7이 존재하는 경우, 서로 같거나 다를 수 있다).
  13. 제12항에 있어서, 상기 R5가 알콕시기, 아실옥시기, 페녹시기, 이미녹시기 또는 알케닐옥시기를 나타내며, R7이 알킬기, 아릴기 또는 아랄킬기를 나타내는 것이 특징인 불소함유 공중합체 조성물.
  14. 제10항에 있어서, 상기 유기 실리콘 화합물이 하기 일발식(VI)으로 표시되는 것인 불소함유 공중합체조성물:
    (식에서, R9는 가수분해성기, Rl0은 유기기를 나타내며, p는 1∼4의 정수, m과 n은 0∼3의 정수이며, 단,p+m+n=4이고, p가 1이면 m이 1∼3의 정수이고, n은 0∼2의 정수이고, p+m+n=4의 조건을 만족하며, 복수의 R9또는 Rl0이 존재하는 경우, 서로 같거나 다를 수 있다).
  15. 제14항에 있어서, 상기 R9가 알콕시기, 아실옥시기 또는 페녹시기를 나타내고, Rl0이 알킬기, 알케닐기, 시클로알킬기, 아릴기 또는 아릴알킬기를 나타내는 것이 특징인 불소함유 공중합체 조성물.
  16. 제1항의 불소함유 공중합체 조성물과 경화제(C)로 구성된 것이 특징인 불소함유 도포용 조성물.
  17. 제16항에 있어서, 상기 경화제(C)의 사용량이 상기 불소함유 공중합체(A) 100중량부당, 0.03∼50중량부인 것이 특징인 불소함유 도포용 조성물.
  18. 제16항의 불소함유 도포용 조성물을 경화시켜 얻는 경화물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900019235A 1989-11-27 1990-11-27 불소함유 공중합체 조성물 Expired - Fee Related KR940008034B1 (ko)

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JP1-307148 1989-11-27
JP1307148A JP3033105B2 (ja) 1989-11-27 1989-11-27 含フッ素共重合体組成物、フッ素系塗料用組成物およびその塗膜

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KR940008034B1 KR940008034B1 (ko) 1994-09-01

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US (1) US5106895A (ko)
EP (1) EP0430628B1 (ko)
JP (1) JP3033105B2 (ko)
KR (1) KR940008034B1 (ko)
CN (1) CN1025740C (ko)
AT (1) ATE124062T1 (ko)
CA (1) CA2030887C (ko)
DE (1) DE69020314T2 (ko)
HU (1) HU211432B (ko)
PL (2) PL168183B1 (ko)

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KR20220011008A (ko) * 2020-07-20 2022-01-27 울산과학기술원 유체 장치를 이용하여 혈액 내 감염성 물질 또는 혈전을 제거하는 혈액 투석 장치 및 혈액 투석 방법

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CN102782534A (zh) * 2010-03-03 2012-11-14 旭硝子株式会社 太阳能集热用反射板用的涂料组合物、以及太阳能集热用反射板及其制造方法
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TWI577763B (zh) * 2016-02-16 2017-04-11 廣科工業股份有限公司 烘烤型水性有機矽含氟聚合物塗料、塗層、與其形成方法
CN106336498B (zh) * 2016-08-31 2020-03-31 衢州氟硅技术研究院 一种氟硅改性聚氨酯人造革耐水解剂及其制备方法
CN114133516B (zh) * 2021-12-31 2023-05-26 广东美涂士建材股份有限公司 一种自清洁低表面能改性聚氨酯的制备方法

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KR20220117192A (ko) * 2020-06-04 2022-08-23 울산과학기술원 유체 장치 및 이를 이용한 혈액 내 물질을 제거하는 방법
KR20220011008A (ko) * 2020-07-20 2022-01-27 울산과학기술원 유체 장치를 이용하여 혈액 내 감염성 물질 또는 혈전을 제거하는 혈액 투석 장치 및 혈액 투석 방법

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DE69020314D1 (de) 1995-07-27
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EP0430628A1 (en) 1991-06-05
ATE124062T1 (de) 1995-07-15
PL169464B1 (pl) 1996-07-31
CA2030887C (en) 1995-08-01
HUT57817A (en) 1991-12-30
KR940008034B1 (ko) 1994-09-01
HU211432B (en) 1995-11-28
PL287960A1 (en) 1991-09-09
JP3033105B2 (ja) 2000-04-17
DE69020314T2 (de) 1995-11-23
CN1053249A (zh) 1991-07-24
JPH03167214A (ja) 1991-07-19
PL168183B1 (pl) 1996-01-31
US5106895A (en) 1992-04-21
CN1025740C (zh) 1994-08-24
HU907652D0 (en) 1991-06-28

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