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KR20130090312A - 리튬 이차전지용 리튬 복합 전이금속 산화물의 전구체 입자들 및 이를 포함하는 양극 활물질 - Google Patents

리튬 이차전지용 리튬 복합 전이금속 산화물의 전구체 입자들 및 이를 포함하는 양극 활물질 Download PDF

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Publication number
KR20130090312A
KR20130090312A KR1020120097454A KR20120097454A KR20130090312A KR 20130090312 A KR20130090312 A KR 20130090312A KR 1020120097454 A KR1020120097454 A KR 1020120097454A KR 20120097454 A KR20120097454 A KR 20120097454A KR 20130090312 A KR20130090312 A KR 20130090312A
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KR
South Korea
Prior art keywords
transition metal
lithium
composite transition
precursor
particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
KR1020120097454A
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English (en)
Korean (ko)
Inventor
강성훈
박병천
신호석
박상민
박홍규
Original Assignee
주식회사 엘지화학
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 주식회사 엘지화학 filed Critical 주식회사 엘지화학
Priority to JP2014547125A priority Critical patent/JP6284484B2/ja
Priority to ES13743401T priority patent/ES2989624T3/es
Priority to HUE13743401A priority patent/HUE068507T2/hu
Priority to CN201380004172.XA priority patent/CN103975464B/zh
Priority to EP13743401.5A priority patent/EP2811555B1/fr
Priority to KR1020130010061A priority patent/KR101477497B1/ko
Priority to PL13743401.5T priority patent/PL2811555T3/pl
Priority to PCT/KR2013/000712 priority patent/WO2013115544A1/fr
Publication of KR20130090312A publication Critical patent/KR20130090312A/ko
Priority to US14/290,120 priority patent/US9590242B2/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/04—Oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Complex oxides containing cobalt and at least one other metal element
    • C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C01G51/44—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/04—Oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/60—Other road transportation technologies with climate change mitigation effect
    • Y02T10/70—Energy storage systems for electromobility, e.g. batteries

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
KR1020120097454A 2012-02-03 2012-09-04 리튬 이차전지용 리튬 복합 전이금속 산화물의 전구체 입자들 및 이를 포함하는 양극 활물질 Pending KR20130090312A (ko)

Priority Applications (9)

Application Number Priority Date Filing Date Title
JP2014547125A JP6284484B2 (ja) 2012-02-03 2013-01-29 リチウム二次電池用リチウム複合遷移金属酸化物の前駆体粒子及びそれを含む正極活物質
ES13743401T ES2989624T3 (es) 2012-02-03 2013-01-29 Método para preparar partículas precursoras de un óxido de metal de transición compuesto de litio al usar un reactor rotativo
HUE13743401A HUE068507T2 (hu) 2012-02-03 2013-01-29 Eljárás lítium kompozit átmeneti fém-oxid prekurzor részecskék elõállítására egy forgó reaktor használatával
CN201380004172.XA CN103975464B (zh) 2012-02-03 2013-01-29 锂二次电池用锂复合过渡金属氧化物的前体粒子及包含其的正极活性材料
EP13743401.5A EP2811555B1 (fr) 2012-02-03 2013-01-29 Méthode de préparation de particules de précurseurs d'oxydes de métals de transition de lithium au moyen d'un réacteur rotatif
KR1020130010061A KR101477497B1 (ko) 2012-02-03 2013-01-29 리튬 이차전지용 리튬 복합 전이금속 산화물의 전구체 입자들 및 이를 포함하는 양극 활물질
PL13743401.5T PL2811555T3 (pl) 2012-02-03 2013-01-29 Sposób wytwarzania cząstek prekursora tlenku litu złożonego metalu przejściowego przy użyciu reaktora obrotowego
PCT/KR2013/000712 WO2013115544A1 (fr) 2012-02-03 2013-01-29 Particules de précurseur d'oxyde composite de métal de transition de lithium pour batterie secondaire au lithium et matière active de cathode les contenant
US14/290,120 US9590242B2 (en) 2012-02-03 2014-05-29 Precursor particles of lithium composite transition metal oxide for lithium secondary battery and cathode active material comprising the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20120011113 2012-02-03
KR1020120011113 2012-02-03

Publications (1)

Publication Number Publication Date
KR20130090312A true KR20130090312A (ko) 2013-08-13

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KR1020120097454A Pending KR20130090312A (ko) 2012-02-03 2012-09-04 리튬 이차전지용 리튬 복합 전이금속 산화물의 전구체 입자들 및 이를 포함하는 양극 활물질
KR1020130010061A Active KR101477497B1 (ko) 2012-02-03 2013-01-29 리튬 이차전지용 리튬 복합 전이금속 산화물의 전구체 입자들 및 이를 포함하는 양극 활물질

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KR1020130010061A Active KR101477497B1 (ko) 2012-02-03 2013-01-29 리튬 이차전지용 리튬 복합 전이금속 산화물의 전구체 입자들 및 이를 포함하는 양극 활물질

Country Status (9)

Country Link
US (1) US9590242B2 (fr)
EP (1) EP2811555B1 (fr)
JP (1) JP6284484B2 (fr)
KR (2) KR20130090312A (fr)
CN (1) CN103975464B (fr)
ES (1) ES2989624T3 (fr)
HU (1) HUE068507T2 (fr)
PL (1) PL2811555T3 (fr)
WO (1) WO2013115544A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL2810706T3 (pl) * 2012-02-01 2024-12-02 Lg Energy Solution, Ltd. Reaktor do wytwarzania prekursora tlenku litu złożonego metalu przejściowego oraz sposób wytwarzania prekursora
KR101596272B1 (ko) * 2013-01-03 2016-02-22 주식회사 엘지화학 리튬 복합 전이금속 산화물 제조용 장치, 이를 이용하여 제조된 리튬 복합 전이금속 산화물, 및 그 제조방법
KR101608632B1 (ko) 2013-08-20 2016-04-05 주식회사 엘지화학 리튬 복합 전이금속 산화물 제조용 전구체, 그 제조방법 및 이를 이용한 리튬 복합 전이금속 산화물
WO2018047841A1 (fr) * 2016-09-07 2018-03-15 協和化学工業株式会社 Hydroxyde métallique composite microparticulaire, produit calciné de celui-ci, son procédé de production et composition de résine associée
KR20190075729A (ko) * 2017-12-21 2019-07-01 재단법인 포항산업과학연구원 리튬 이차 전지용 양극 활물질 및 이의 제조 방법, 상기 양극 활물질을 포함하는 리튬 이차 전지
CN110233259B (zh) 2018-12-29 2021-02-09 宁德时代新能源科技股份有限公司 正极活性材料、正极极片及电化学储能装置
JP6880086B2 (ja) 2019-01-21 2021-06-02 Ｊｘ金属株式会社 全固体リチウムイオン電池用酸化物系正極活物質、全固体リチウムイオン電池用酸化物系正極活物質の製造方法及び全固体リチウムイオン電池
CN112352333A (zh) 2019-03-29 2021-02-09 Ｊｘ金属株式会社 全固态锂离子电池用氧化物系正极活性物质、全固态锂离子电池用氧化物系正极活性物质的前体的制造方法、全固态锂离子电池用氧化物系正极活性物质的制造方法以及全固态锂离子电池

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CN1300869C (zh) 2002-05-20 2007-02-14 日亚化学工业株式会社 非水电解液二次电池用正极活性物质及其电池
KR100895225B1 (ko) * 2002-09-26 2009-05-04 에이지씨 세이미 케미칼 가부시키가이샤 리튬 2차 전지용 양극 활성 물질 및 그 제조방법
JP2004342548A (ja) * 2003-05-19 2004-12-02 Mitsubishi Chemicals Corp リチウム二次電池用正極活物質及びその製造方法、並びに、それを用いたリチウム二次電池用正極材料、リチウム二次電池用正極及びリチウム二次電池
WO2007094644A1 (fr) * 2006-02-17 2007-08-23 Lg Chem, Ltd. Procédé de préparation d'oxydes composites métal/lithium
KR100765970B1 (ko) * 2006-09-29 2007-10-10 대정화금주식회사 공침법을 이용한 망간 복합산화물 및 그 제조방법, 이를이용한 리튬이차전지용 스피넬형 양극활물질과 그 제조방법
JP4211865B2 (ja) * 2006-12-06 2009-01-21 戸田工業株式会社 非水電解質二次電池用Ｌｉ−Ｎｉ複合酸化物粒子粉末及びその製造方法、並びに非水電解質二次電池
JP5114998B2 (ja) * 2007-03-29 2013-01-09 住友金属鉱山株式会社 非水系電解質二次電池用正極活物質、その製造方法及びそれを用いた非水系電解質二次電池
JP5655218B2 (ja) 2008-04-03 2015-01-21 エルジー・ケム・リミテッド リチウム複合遷移金属酸化物製造用の新規な前駆物質、リチウム−遷移金属複合酸化物及びリチウム二次バッテリ−
JP5590283B2 (ja) * 2008-09-22 2014-09-17 住友金属鉱山株式会社 リチウム複合ニッケル酸化物およびその製造方法
DE102010053411B4 (de) * 2009-12-15 2023-07-06 Vat Holding Ag Vakuumventil
KR101345509B1 (ko) * 2011-03-31 2013-12-27 스미토모 긴조쿠 고잔 가부시키가이샤 니켈 복합 수산화물 입자 및 비수계 전해질 2차 전지
JP4894969B1 (ja) * 2011-06-07 2012-03-14 住友金属鉱山株式会社 ニッケルマンガン複合水酸化物粒子とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、ならびに、非水系電解質二次電池
PL2810706T3 (pl) * 2012-02-01 2024-12-02 Lg Energy Solution, Ltd. Reaktor do wytwarzania prekursora tlenku litu złożonego metalu przejściowego oraz sposób wytwarzania prekursora

Also Published As

Publication number Publication date
JP2015506075A (ja) 2015-02-26
WO2013115544A1 (fr) 2013-08-08
US20140272587A1 (en) 2014-09-18
US9590242B2 (en) 2017-03-07
CN103975464B (zh) 2017-05-17
PL2811555T3 (pl) 2024-12-16
EP2811555A4 (fr) 2015-10-21
HUE068507T2 (hu) 2024-12-28
CN103975464A (zh) 2014-08-06
EP2811555B1 (fr) 2024-08-21
JP6284484B2 (ja) 2018-02-28
KR20130090341A (ko) 2013-08-13
KR101477497B1 (ko) 2014-12-30
ES2989624T3 (es) 2024-11-27
EP2811555A1 (fr) 2014-12-10

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