JPH04502016A - マイクロカプセルに封入した農薬 - Google Patents

マイクロカプセルに封入した農薬

Info

Publication number: JPH04502016A
Authority: JP; Japan
Prior art keywords: pesticide; prepolymer; microcapsules; melamine; pesticides
Prior art date: 1989-09-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP2513127A

Other languages

English (en)

Japanese (ja)

Inventor

クリーチ、デイビッド・シー

カーティス、ラルストン

Original Assignee

サンド・リミテッド

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-09-28

Filing date

1990-09-24

Publication date

1992-04-09

1990-09-24 Application filed by サンド・リミテッド filed Critical サンド・リミテッド

1992-04-09 Publication of JPH04502016A publication Critical patent/JPH04502016A/ja

Status Pending legal-status Critical Current

Links

239000000575 pesticide Substances 0.000 title claims description 47
239000003094 microcapsule Substances 0.000 title claims description 46
239000000203 mixture Substances 0.000 claims description 48
238000000034 method Methods 0.000 claims description 32
239000007788 liquid Substances 0.000 claims description 22
150000003839 salts Chemical class 0.000 claims description 17
229920000877 Melamine resin Polymers 0.000 claims description 16
239000002245 particle Substances 0.000 claims description 15
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 13
XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 11
239000002775 capsule Substances 0.000 claims description 10
238000002386 leaching Methods 0.000 claims description 9
229920000642 polymer Polymers 0.000 claims description 9
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
229910052782 aluminium Inorganic materials 0.000 claims description 8
239000000725 suspension Substances 0.000 claims description 8
239000005574 MCPA Substances 0.000 claims description 7
WHKUVVPPKQRRBV-UHFFFAOYSA-N Trasan Chemical compound CC1=CC(Cl)=CC=C1OCC(O)=O WHKUVVPPKQRRBV-UHFFFAOYSA-N 0.000 claims description 7
241000607479 Yersinia pestis Species 0.000 claims description 7
239000003814 drug Substances 0.000 claims description 6
229910052742 iron Inorganic materials 0.000 claims description 6
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 5
VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 claims description 4
229920006037 cross link polymer Polymers 0.000 claims description 4
229940079593 drug Drugs 0.000 claims description 4
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 4
230000008635 plant growth Effects 0.000 claims description 4
WVQBLGZPHOPPFO-UHFFFAOYSA-N 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(C(C)COC)C(=O)CCl WVQBLGZPHOPPFO-UHFFFAOYSA-N 0.000 claims description 3
VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical class [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 3
XCSGPAVHZFQHGE-UHFFFAOYSA-N alachlor Chemical compound CCC1=CC=CC(CC)=C1N(COC)C(=O)CCl XCSGPAVHZFQHGE-UHFFFAOYSA-N 0.000 claims description 3
-1 or dicampa Chemical compound 0.000 claims description 3
DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims 4
239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 claims 2
239000003905 agrochemical Substances 0.000 claims 1
239000013043 chemical agent Substances 0.000 claims 1
125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 36
239000013543 active substance Substances 0.000 description 32
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
239000000126 substance Substances 0.000 description 15
239000005504 Dicamba Substances 0.000 description 14
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 13
238000003756 stirring Methods 0.000 description 13
IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 description 12
238000009472 formulation Methods 0.000 description 12
239000002002 slurry Substances 0.000 description 12
241000196324 Embryophyta Species 0.000 description 11
ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 11
229920001807 Urea-formaldehyde Polymers 0.000 description 10
IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 10
239000000243 solution Substances 0.000 description 10
238000004519 manufacturing process Methods 0.000 description 9
238000002156 mixing Methods 0.000 description 9
239000004009 herbicide Substances 0.000 description 8
239000002689 soil Substances 0.000 description 7
229920005989 resin Polymers 0.000 description 6
239000011347 resin Substances 0.000 description 6
239000004094 surface-active agent Substances 0.000 description 6
239000002253 acid Substances 0.000 description 5
238000007796 conventional method Methods 0.000 description 5
239000012467 final product Substances 0.000 description 5
239000000463 material Substances 0.000 description 5
239000000047 product Substances 0.000 description 5
239000003795 chemical substances by application Substances 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
238000001816 cooling Methods 0.000 description 4
230000000694 effects Effects 0.000 description 4
238000005538 encapsulation Methods 0.000 description 4
239000000843 powder Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
239000004202 carbamide Substances 0.000 description 3
238000004132 cross linking Methods 0.000 description 3
239000003085 diluting agent Substances 0.000 description 3
ZNNYSTVISUQHIF-UHFFFAOYSA-N formaldehyde;thiourea Chemical compound O=C.NC(N)=S ZNNYSTVISUQHIF-UHFFFAOYSA-N 0.000 description 3
230000000887 hydrating effect Effects 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
238000012360 testing method Methods 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
229920000858 Cyclodextrin Polymers 0.000 description 2
ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
ZUQAPLKKNAQJAU-UHFFFAOYSA-N acetylenediol Chemical compound OC#CO ZUQAPLKKNAQJAU-UHFFFAOYSA-N 0.000 description 2
239000011149 active material Substances 0.000 description 2
239000000654 additive Substances 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
235000013339 cereals Nutrition 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000012141 concentrate Substances 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
239000010949 copper Substances 0.000 description 2
239000013078 crystal Substances 0.000 description 2
238000007865 diluting Methods 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
239000012065 filter cake Substances 0.000 description 2
239000008187 granular material Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
239000005416 organic matter Substances 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
LUMVCLJFHCTMCV-UHFFFAOYSA-M potassium;hydroxide;hydrate Chemical compound O.[OH-].[K+] LUMVCLJFHCTMCV-UHFFFAOYSA-M 0.000 description 2
230000002028 premature Effects 0.000 description 2
238000010992 reflux Methods 0.000 description 2
HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 2
239000011734 sodium Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000002904 solvent Substances 0.000 description 2
UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
238000012546 transfer Methods 0.000 description 2
JZLWSRCQCPAUDP-UHFFFAOYSA-N 1,3,5-triazine-2,4,6-triamine;urea Chemical compound NC(N)=O.NC1=NC(N)=NC(N)=N1 JZLWSRCQCPAUDP-UHFFFAOYSA-N 0.000 description 1
AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 1
YPFNIPKMNMDDDB-UHFFFAOYSA-K 2-[2-[bis(carboxylatomethyl)amino]ethyl-(2-hydroxyethyl)amino]acetate;iron(3+) Chemical compound [Fe+3].OCCN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O YPFNIPKMNMDDDB-UHFFFAOYSA-K 0.000 description 1
UIKUBYKUYUSRSM-UHFFFAOYSA-N 3-morpholinopropylamine Chemical compound NCCCN1CCOCC1 UIKUBYKUYUSRSM-UHFFFAOYSA-N 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
241000270722 Crocodylidae Species 0.000 description 1
XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
229920003270 Cymel® Polymers 0.000 description 1
241000255925 Diptera Species 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
241000490229 Eucephalus Species 0.000 description 1
241000416536 Euproctis pseudoconspersa Species 0.000 description 1
239000005562 Glyphosate Substances 0.000 description 1
240000001549 Ipomoea eriocarpa Species 0.000 description 1
235000005146 Ipomoea eriocarpa Nutrition 0.000 description 1
229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
239000005909 Kieselgur Substances 0.000 description 1
241001465754 Metazoa Species 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
240000007594 Oryza sativa Species 0.000 description 1
235000007164 Oryza sativa Nutrition 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
102000006463 Talin Human genes 0.000 description 1
108010083809 Talin Proteins 0.000 description 1
240000000851 Vaccinium corymbosum Species 0.000 description 1
235000003095 Vaccinium corymbosum Nutrition 0.000 description 1
235000017537 Vaccinium myrtillus Nutrition 0.000 description 1
240000008042 Zea mays Species 0.000 description 1
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
235000002017 Zea mays subsp mays Nutrition 0.000 description 1
239000003377 acid catalyst Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000000443 aerosol Substances 0.000 description 1
239000002518 antifoaming agent Substances 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
235000021014 blueberries Nutrition 0.000 description 1
238000009395 breeding Methods 0.000 description 1
230000001488 breeding effect Effects 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
159000000007 calcium salts Chemical class 0.000 description 1
125000002843 carboxylic acid group Chemical group 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000013270 controlled release Methods 0.000 description 1
235000005822 corn Nutrition 0.000 description 1
244000038559 crop plants Species 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
239000013530 defoamer Substances 0.000 description 1
LNNWVNGFPYWNQE-GMIGKAJZSA-N desomorphine Chemical compound C1C2=CC=C(O)C3=C2[C@]24CCN(C)[C@H]1[C@@H]2CCC[C@@H]4O3 LNNWVNGFPYWNQE-GMIGKAJZSA-N 0.000 description 1
238000011161 development Methods 0.000 description 1
230000018109 developmental process Effects 0.000 description 1
239000002283 diesel fuel Substances 0.000 description 1
150000004656 dimethylamines Chemical class 0.000 description 1
VFFDVELHRCMPLY-UHFFFAOYSA-N dimethyldodecyl amine Natural products CC(C)CCCCCCCCCCCN VFFDVELHRCMPLY-UHFFFAOYSA-N 0.000 description 1
YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000000975 dye Substances 0.000 description 1
230000001804 emulsifying effect Effects 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
230000009969 flowable effect Effects 0.000 description 1
239000006260 foam Substances 0.000 description 1
238000005187 foaming Methods 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
239000000417 fungicide Substances 0.000 description 1
230000035784 germination Effects 0.000 description 1
XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 1
229940097068 glyphosate Drugs 0.000 description 1
238000000227 grinding Methods 0.000 description 1
230000012010 growth Effects 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
238000004128 high performance liquid chromatography Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
238000007654 immersion Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000002917 insecticide Substances 0.000 description 1
230000002452 interceptive effect Effects 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
159000000014 iron salts Chemical class 0.000 description 1
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
239000012633 leachable Substances 0.000 description 1
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
238000003801 milling Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
OOHAUGDGCWURIT-UHFFFAOYSA-N n,n-dipentylpentan-1-amine Chemical compound CCCCCN(CCCCC)CCCCC OOHAUGDGCWURIT-UHFFFAOYSA-N 0.000 description 1
PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
FIKAKWIAUPDISJ-UHFFFAOYSA-L paraquat dichloride Chemical compound [Cl-].[Cl-].C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 FIKAKWIAUPDISJ-UHFFFAOYSA-L 0.000 description 1
239000013618 particulate matter Substances 0.000 description 1
230000002688 persistence Effects 0.000 description 1
QIIPQYDSKRYMFG-UHFFFAOYSA-N phenyl hydrogen carbonate Chemical class OC(=O)OC1=CC=CC=C1 QIIPQYDSKRYMFG-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
235000009566 rice Nutrition 0.000 description 1
238000009666 routine test Methods 0.000 description 1
JWHOQZUREKYPBY-UHFFFAOYSA-N rubonic acid Natural products CC1(C)CCC2(CCC3(C)C(=CCC4C5(C)CCC(=O)C(C)(C)C5CC(=O)C34C)C2C1)C(=O)O JWHOQZUREKYPBY-UHFFFAOYSA-N 0.000 description 1
230000001568 sexual effect Effects 0.000 description 1
235000019333 sodium laurylsulphate Nutrition 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
ABVVEAHYODGCLZ-UHFFFAOYSA-N tridecan-1-amine Chemical compound CCCCCCCCCCCCCN ABVVEAHYODGCLZ-UHFFFAOYSA-N 0.000 description 1
239000000052 vinegar Substances 0.000 description 1
235000021419 vinegar Nutrition 0.000 description 1
238000010792 warming Methods 0.000 description 1
238000001238 wet grinding Methods 0.000 description 1
238000009736 wetting Methods 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/18—In situ polymerisation with all reactants being present in the same phase
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules

Landscapes

Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Chemical & Material Sciences (AREA)
Pest Control & Pesticides (AREA)
Environmental Sciences (AREA)
Toxicology (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Plant Pathology (AREA)
Agronomy & Crop Science (AREA)
Organic Chemistry (AREA)
Dispersion Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Manufacturing Of Micro-Capsules (AREA)

JP2513127A 1989-09-28 1990-09-24 マイクロカプセルに封入した農薬 Pending JPH04502016A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US41379589A	1989-09-28	1989-09-28
US413,795		1989-09-28

Publications (1)

Publication Number	Publication Date
JPH04502016A true JPH04502016A (ja)	1992-04-09

Family

ID=23638669

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP2513127A Pending JPH04502016A (ja)	1989-09-28	1990-09-24	マイクロカプセルに封入した農薬

Country Status (16)

Country	Link
EP (1)	EP0445266A1 (xx)
JP (1)	JPH04502016A (xx)
KR (1)	KR920700535A (xx)
CN (1)	CN1050483A (xx)
AU (1)	AU641694B2 (xx)
BR (1)	BR9006932A (xx)
CA (1)	CA2040418A1 (xx)
HU (1)	HUT56998A (xx)
IE (1)	IE903470A1 (xx)
IL (1)	IL95801A0 (xx)
MY (1)	MY106614A (xx)
PL (1)	PL287075A1 (xx)
PT (1)	PT95429A (xx)
WO (1)	WO1991004661A2 (xx)
YU (1)	YU182890A (xx)
ZA (1)	ZA907807B (xx)

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JP2000342956A (ja) *	1999-04-01	2000-12-12	Dai Ichi Kogyo Seiyaku Co Ltd	マイクロカプセルの製法およびそれによって得られたマイクロカプセル

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GB9306852D0 (en) *	1993-04-01	1993-05-26	Ciba Geigy Ag	Multiply-coated particles
GB9306808D0 (en) *	1993-04-01	1993-05-26	Ciba Geigy Ag	Coated microparticle agglomerates
AU756668B2 (en) *	1997-12-24	2003-01-23	Kiwitech Limited	Substantially water-insoluble matrix containing bioactive substances for slow release
DK1131152T3 (da) *	1998-11-12	2004-02-02	Fmc Corp	Fremgangsmåde til fremstilling af mikroindkapslede formuleringer
JP2000302606A (ja) *	1999-04-15	2000-10-31	Novartis Ag	固体農薬のマイクロカプセル、その製造方法及び施用方法
WO2002089578A1 (en) *	2001-05-09	2002-11-14	Toppan Forms Co., Ltd.	Microencapsulated antibacterial
CN100428886C (zh) *	2005-12-30	2008-10-29	山东农业大学	一种高效氯氰菊酯微囊悬浮剂
CN101965129B (zh) *	2007-12-13	2013-07-10	唐纳吉实业有限公司	草甘膦的二甲胺盐和钾盐的组合的除草制剂
EP2395843B1 (en)	2009-02-13	2017-08-09	Monsanto Technology LLC	Encapsulation of herbicides to reduce crop injury
EA023099B1 (ru) *	2009-09-30	2016-04-29	Басф Се	Низколетучие аминные соли анионных пестицидов
EP2605646B1 (en)	2010-08-18	2016-07-20	Monsanto Technology LLC	Early applications of encapsulated acetamides for reduced injury in crops
EP2460404A1 (en) *	2010-12-01	2012-06-06	Basf Se	Compositions containing identical polyamine salts of mixed anionic pesticides
UY34263A (es) *	2011-08-16	2013-02-28	Dow Agrosciences Llc	Complejos de ácidos carboxílicos herbicidas y polímeros que contienen amina u oligómeros
IN2014DN01626A (xx) *	2011-08-25	2015-05-15	Dow Agrosciences Llc
GB201115564D0 (en) *	2011-09-08	2011-10-26	Syngenta Ltd	Herbicidal composition
EP2978309B1 (en)	2013-03-26	2020-12-02	Basf Se	Microcapsules comprising anionic pesticides
BR102016019512B8 (pt)	2015-08-26	2022-10-11	Dow Agrosciences Llc	Composição compreendendo complexo protetor compreendendo cloquintocet e polímeros ou oligômeros contendo amina, seu método de preparação, e método para controle da vegetação indesejável
US11109591B2 (en)	2017-04-24	2021-09-07	Taminco Bvba	Single phase liquids of alkanolamine salts of dicamba
WO2025202977A1 (en) *	2024-03-28	2025-10-02	Upl Limited	A solid composition

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US3074845A (en) *	1959-10-14	1963-01-22	Plant Products Corp	Particulate pesticidal composition coated with an amido-aldehyde resin polymerized in situ
US3516941A (en) *	1966-07-25	1970-06-23	Minnesota Mining & Mfg	Microcapsules and process of making
GB1507739A (en) *	1975-11-26	1978-04-19	Wiggins Teape Ltd	Capsules
JPS58124705A (ja) *	1982-01-18	1983-07-25	Kureha Chem Ind Co Ltd	マイクロカプセル化農薬及びその製造方法
US4534783A (en) *	1984-01-03	1985-08-13	Monsanto Co.	High concentration encapsulation of water soluble-materials
EP0158449B1 (en) *	1984-03-30	1987-11-04	Stauffer Chemical Company	Microcapsules and microencapsulation process
DD240843A1 (de) *	1985-09-13	1986-11-19	Adw Ddr	Verfahren zur mikroverkapselung von pestiziden
JPS62149607A (ja) *	1985-12-25	1987-07-03	Kureha Chem Ind Co Ltd	エトプロホスのカプセル剤
IL83130A (en) *	1986-07-09	1990-11-29	Monsanto Co	Formulations of water-dispersible pesticidal or plant-growth regulating granules and process for preparation thereof
JPS63178840A (ja) *	1987-01-19	1988-07-22	Toppan Moore Co Ltd	徐放性マイクロカプセル

1990
- 1990-09-24 WO PCT/EP1990/001618 patent/WO1991004661A2/en not_active Ceased
- 1990-09-24 JP JP2513127A patent/JPH04502016A/ja active Pending
- 1990-09-24 HU HU911930A patent/HUT56998A/hu unknown
- 1990-09-24 EP EP90914385A patent/EP0445266A1/en not_active Withdrawn
- 1990-09-24 BR BR909006932A patent/BR9006932A/pt unknown
- 1990-09-24 CA CA002040418A patent/CA2040418A1/en not_active Abandoned
- 1990-09-24 AU AU64207/90A patent/AU641694B2/en not_active Ceased
- 1990-09-24 KR KR1019910700533A patent/KR920700535A/ko not_active Withdrawn
- 1990-09-26 MY MYPI90001660A patent/MY106614A/en unknown
- 1990-09-26 PT PT95429A patent/PT95429A/pt not_active Application Discontinuation
- 1990-09-26 IL IL95801A patent/IL95801A0/xx unknown
- 1990-09-27 IE IE347090A patent/IE903470A1/en unknown
- 1990-09-27 PL PL28707590A patent/PL287075A1/xx unknown
- 1990-09-27 YU YU182890A patent/YU182890A/sh unknown
- 1990-09-27 CN CN90108132A patent/CN1050483A/zh active Pending
- 1990-09-28 ZA ZA907807A patent/ZA907807B/xx unknown

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2000342956A (ja) *	1999-04-01	2000-12-12	Dai Ichi Kogyo Seiyaku Co Ltd	マイクロカプセルの製法およびそれによって得られたマイクロカプセル

Also Published As

Publication number	Publication date
AU6420790A (en)	1991-04-28
WO1991004661A2 (en)	1991-04-18
WO1991004661A3 (en)	1991-05-16
EP0445266A1 (en)	1991-09-11
PL287075A1 (en)	1991-09-09
AU641694B2 (en)	1993-09-30
PT95429A (pt)	1991-05-22
YU182890A (sh)	1993-10-20
CA2040418A1 (en)	1991-03-29
IE903470A1 (en)	1991-04-10
KR920700535A (ko)	1992-08-10
IL95801A0 (en)	1991-06-30
CN1050483A (zh)	1991-04-10
MY106614A (en)	1995-06-30
HUT56998A (en)	1991-11-28
ZA907807B (en)	1992-05-27
BR9006932A (pt)	1991-10-08

Publication	Publication Date	Title
JPH04502016A (ja)	1992-04-09	マイクロカプセルに封入した農薬
US5462915A (en)	1995-10-31	Process for producing microcapsules
EP1652433B1 (en)	2009-11-04	Herbicidal compositions
JPH0229642B2 (xx)	1990-07-02
CN102770023B (zh)	2014-10-15	改良的制剂
JP2003526687A (ja)	2003-09-09	マイクロカプセル懸濁液
EP2552212B1 (en)	2015-01-21	An improved formulation
CN103929958B (zh)	2016-08-03	改良的除草制剂
EP0380325A2 (en)	1990-08-01	Microencapsulated agriculturally active material
CS249110B2 (en)	1987-03-12	Method of water non-miscible substance encapsulation
HUP0100193A2 (hu)	2001-06-28	Könnyen állítható kibocsátást biztosító mikrokapszulák
HU215771B (hu)	2000-09-28	2-Klór-N-(etoxi-metil)-6'-etil-o-aceto-toluidid herbicidet tartalmazó kapszulák és eljárás előállításukra
JPH06107509A (ja)	1994-04-19	放出の遅い組成物
JPH0517882B2 (xx)	1993-03-10
TWI605758B (zh)	2017-11-21	包含可滅蹤（ｃｌｏｍａｚｏｎｅ）之除草組成物及其用途
US3031292A (en)	1962-04-24	Method for the control of weeds
CA1118222A (en)	1982-02-16	Microencapsulated trifluoralin
US3089765A (en)	1963-05-14	Herbicidal method
JPH0229289B2 (xx)	1990-06-28
JPS63225301A (ja)	1988-09-20	農薬製剤の製造方法
JPH0571608B2 (xx)	1993-10-07
NZ624217A (en)	2015-11-27	Stable pesticidal compositions

JPH04502016A - マイクロカプセルに封入した農薬 - Google Patents

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