JP5649891B2 - Hair cosmetic used by filling non-gas former - Google Patents
Hair cosmetic used by filling non-gas former Download PDFInfo
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- JP5649891B2 JP5649891B2 JP2010212321A JP2010212321A JP5649891B2 JP 5649891 B2 JP5649891 B2 JP 5649891B2 JP 2010212321 A JP2010212321 A JP 2010212321A JP 2010212321 A JP2010212321 A JP 2010212321A JP 5649891 B2 JP5649891 B2 JP 5649891B2
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Landscapes
- Cosmetics (AREA)
Description
本発明は、ノンガスフォーマーにより泡沫状にして用いる毛髪化粧料に関する。より詳しくは、洗い流さないタイプの毛髪化粧料として好適に用いられる毛髪化粧料に関する。 The present invention relates to a hair cosmetic used in the form of foam by a non-gas former. More specifically, the present invention relates to a hair cosmetic suitably used as a type of hair cosmetic that does not wash away.
カラーやパーマまたは日常生活によりダメージを受けた毛髪には、指どおりの悪さ、パサつき、ごわつき、及びまとまり感の欠如といった問題が生じる。このような問題を、シリコーン等を毛髪補修成分として含有する毛髪化粧料により解決することが行われている。中でも、洗い流さないタイプの毛髪化粧料を毛髪に塗布して毛髪補修を行うと、毛髪補修成分が洗い流されることなく毛髪に吸着および浸透するため、高い補修効果が得られる。 Hair damaged by color, perm, or daily life has problems such as poor fingering, dryness, stiffness, and lack of cohesion. Such problems have been solved with hair cosmetics containing silicone or the like as a hair repair component. In particular, when a hair cosmetic of a type that does not wash away is applied to the hair and the hair is repaired, the hair repair component is adsorbed and permeated into the hair without being washed away, so that a high repair effect is obtained.
しかしながら、これらの洗い流さないタイプの毛髪化粧料の場合、毛髪に毛髪補修成分が均一に付着されないと、べたつきやごわつきが生じることがあった。また洗い流さないタイプの毛髪化粧料を乾いた毛髪に用いた場合と、タオルドライ（水で濡らした毛髪の水分を、完全に除去することなく、自然状態で垂れ落ちない程度にふき取ること）した毛髪に用いた場合とでは、毛髪化粧料の毛髪への浸透が異なるため、いずれにも使用した場合でも、毛髪へのなじみやすさと仕上がりの滑らかな感触とが得られる毛髪化粧料が望まれていた。 However, in the case of these types of hair cosmetics that do not wash away, if the hair repair component is not evenly attached to the hair, stickiness or wrinkle may occur. In addition, hair that has not been washed away is used for dry hair, and hair that has been towel-dried (whether it has been wiped off to the extent that it does not drip in the natural state without completely removing the moisture of the hair wet with water) Since the penetration of the hair cosmetic into the hair is different from that used for the hair, there has been a demand for a hair cosmetic that can be easily applied to the hair and have a smooth finish when used in any case. .
洗い流さないタイプの毛髪化粧料の剤型として、毛髪化粧料を霧状にする剤型があり、該剤型には噴射剤を封入するエアゾールタイプと噴射剤（ガス）を用いないノンエアゾールのミストタイプがある。これら霧状の毛髪化粧料は、乾いた毛髪およびタオルドライした毛髪のいずれに対しても、毛髪補修成分を均一に塗布して付着浸透させることが可能であることから、べたつきが生じない。しかしながら、毛髪補修成分を特定の箇所に集中させて塗布することが困難であるという問題点、一部の毛髪化粧料が毛髪に塗布されることなく床に飛び散ることにより床が滑りやすくなってしまうという問題点があった。一方、乳液状、ジェル状、ジェルクリーム状およびミルク状などの剤型は、上記霧状の剤型の問題点は生じないが、毛髪補修成分を均一に毛髪全体に塗布することができず、つけムラがおき、べたついた仕上がりになる。 There are two types of hair cosmetics that do not wash away. There are two types of hair cosmetics in the form of a mist. The aerosol type contains a propellant and the non-aerosol mist does not use a propellant (gas). There are types. These mist-like hair cosmetics do not cause stickiness because the hair repair component can be uniformly applied and adhered to both dry hair and towel-dried hair. However, the problem that it is difficult to concentrate and apply the hair repair component to a specific part, and the floor becomes easy to slip because some hair cosmetics are scattered on the floor without being applied to the hair. There was a problem. On the other hand, dosage forms such as emulsion, gel, gel cream and milk do not cause the problems of the above-mentioned mist-like dosage form, but the hair repair component cannot be uniformly applied to the entire hair, Unevenness occurs, resulting in a sticky finish.
床を汚すことなく毛髪に塗布可能な剤型の毛髪化粧料として、泡沫状の剤型の毛髪化粧料が提案されている（特許文献１および２参照）。泡沫状の剤型の毛髪化粧料は、毛髪に毛髪化粧料を均一に塗布するのに適しているため、つけムラやべたつきの問題がない。毛髪化粧料を泡沫状にする方法として、エアゾールタイプおよびノンガスタイプ（ノンエアゾールタイプ）があるが、コストや環境面からも噴射剤を用いないノンガスタイプのものが最近は好まれる傾向にある。 As a foam-type hair cosmetic that can be applied to hair without soiling the floor, a foam-type hair cosmetic has been proposed (see Patent Documents 1 and 2). Foam-like hair cosmetics are suitable for uniformly applying hair cosmetics to the hair, and thus do not have any problem of unevenness or stickiness. There are aerosol type and non-gas type (non-aerosol type) as methods for making hair cosmetics into a foam form, but non-gas type that does not use a propellant has recently been preferred from the viewpoint of cost and environment.
ノンガスタイプで毛髪化粧料を泡沫状にするためには、界面活性剤を添加した毛髪化粧料をノンガスフォーマー（泡吐出容器）を用いて泡沫状にする方法がある。しかし、界面活性剤を含有する毛髪化粧料を毛髪に塗布すると、一般に毛髪の指通り及びまとまりについて良好な効果が得られにくい。そのため、界面活性剤を添加してノンガスフォーマーにより泡沫状にする毛髪化粧料は寝ぐせ直し用途等に限られており、毛髪の感触を向上させるための毛髪補修用途に用いることは考えられていなかった。 In order to make the hair cosmetic foam in a non-gas type, there is a method in which the hair cosmetic to which a surfactant is added is foamed using a non-gas former (foam discharge container). However, when a hair cosmetic containing a surfactant is applied to the hair, it is generally difficult to obtain a good effect on the finger's fingering and unity. Therefore, hair cosmetics that are added with a surfactant and foamed with a non-gas former are limited to re-laying applications, etc., and are considered to be used for hair repair applications to improve the feel of hair. There wasn't.
界面活性剤を添加した組成物を毛髪用途に用いた例として、毛髪からの染毛剤の色落ちを防止するためにアシル化シルクペプチド型陰イオン界面活性剤を添加した染色毛髪用シャンプー組成物が知られている（特許文献３参照）。しかしながら、特許文献３は、洗い流して用いる用途（シャンプー用途）に関するものであり、洗い流さない用途に界面活性剤を用いた場合に、毛髪の感触に与える影響については検討されていなかった。 A shampoo composition for dyed hair to which an acylated silk peptide type anionic surfactant is added in order to prevent discoloration of the hair dye from the hair as an example of using the composition to which the surfactant is added for hair use Is known (see Patent Document 3). However, Patent Document 3 relates to an application used after washing (shampoo application), and the effect on the feel of hair when a surfactant is used for an application where washing is not performed has not been studied.
本発明は、毛髪にむらなく塗布可能な泡沫状とすることができ、乾いた毛髪およびタオルドライした毛髪のいずれに用いても毛髪に良好になじみ、毛髪の指通り及びまとまりといった感触を向上させる毛髪補修機能を有する環境負荷の少ない毛髪化粧料を提供することを目的とする。 The present invention can be made into a foam that can be applied evenly to hair, and can be used well for dry hair and towel-dried hair. An object of the present invention is to provide a hair cosmetic material having a hair repair function and a low environmental load.
本発明は、特定の毛髪補修成分を特定の界面活性剤とともに用いて泡沫状の剤型の毛髪化粧料とすることにより、毛髪化粧料が毛髪に均一に塗布可能となるとともに、毛髪の指通り及びまとまりが良好となることを見出し、本発明を完成するに至った。 The present invention uses a specific hair repair component together with a specific surfactant to form a foam-form hair cosmetic, whereby the hair cosmetic can be uniformly applied to the hair and The present inventors have found that the unity is good and have completed the present invention.
すなわち、本発明は以下の［１］〜［５］である。
［１］絹タンパク質の加水分解物をアシル化して得られ、下記一般式（１）で表わされる化合物（ａ１）を含む成分（Ａ）と、
下記一般式（２）で表わされるジメチコノール（ｂ１）、界面活性剤（ｂ２）および水（ｂ３）を含むジメチコノールエマルジョン（Ｂ）と
を含有する毛髪化粧料であって、
前記成分（Ａ）が、式（１）中のＲ2が異なる３種以上の化合物（ａ１）を含み、
前記毛髪化粧料全体を１００重量％とした場合、前記化合物（ａ１）の含有量が０．０５〜３．０重量％であり、前記ジメチコノール（ｂ１）の含有量が０．０５〜４．０重量％であり、
ノンガスフォーマーに充填させて用いることを特徴とする毛髪化粧料。
That is, the present invention includes the following [1] to [5].
[1] A component (A) obtained by acylating a hydrolyzate of silk protein and containing a compound (a1) represented by the following general formula (1):
A hair cosmetic containing dimethiconol (b1) represented by the following general formula (2), a surfactant (b2) and a dimethiconol emulsion (B) containing water (b3),
The component (A) includes three or more compounds (a1) having different R 2 in the formula (1),
When the total amount of the hair cosmetic is 100% by weight, the content of the compound (a1) is 0.05 to 3.0% by weight, and the content of the dimethiconol (b1) is 0.05 to 4.0. % By weight
A hair cosmetic characterized by being used by filling in a non-gas former.
（式１）：Ｒ1ＣＯＮＨＣＨ（Ｒ2）ＣＯＯＭ
［式（１）中、Ｒ1はヒドロキシル基を有していてもよい炭素数５〜２１の直鎖状または分岐鎖状のアルキル基もしくはアルケニル基を表し、Ｒ2は絹タンパク質を加水分解して得られたアミノ酸の側鎖を表わし、Ｍはアルカリ金属、水素原子またはトリエタノールアミンを表わす。］
（式２）：ＨＯ［（ＣＨ3）2ＳｉＯ］mＨ
［式（２）中、ｍは、２５℃におけるジメチコノール（ｂ１）の粘度を、０．０１〜５０００Ｐａ・ｓの範囲にする値である。］
［２］毛髪に塗布後、洗い流さないで用いることを特徴とする［１］に記載の毛髪化粧料。
(Formula 1): R 1 CONHCH (R 2 ) COOM
[In formula (1), R 1 represents a linear or branched alkyl group or alkenyl group having 5 to 21 carbon atoms which may have a hydroxyl group, and R 2 hydrolyzes silk protein. And M represents an alkali metal, a hydrogen atom or triethanolamine. ]
(Formula 2): HO [(CH 3 ) 2 SiO] m H
[In Formula (2), m is a value which makes the viscosity of dimethiconol (b1) in 25 degreeC the range of 0.01-5000 Pa.s. ]
[2] The hair cosmetic composition according to [1], wherein the hair cosmetic composition is used without being washed away after application to hair.
［３］前記界面活性剤（ｂ２）がアニオン性界面活性剤であることを特徴とする［１］または［２］に記載の毛髪化粧料。
［４］前記ジメチコノールエマルジョン（Ｂ）が、アニオン性界面活性剤の存在下で下記一般式（３）で表わされる化合物を乳化重合することにより得られたものであることを特徴とする［１］〜［３］のいずれか一項に記載の毛髪化粧料。
（式３）：ＨＯ［（ＣＨ3）2ＳｉＯ］nＨ
［式（３）中、ｎは、２５℃における式（３）で表わされる化合物の粘度を、１〜３０００ｍＰａ・ｓの範囲にする値である。］
［５］［１］〜［４］のいずれか一項に記載の毛髪化粧料をノンガスフォーマーにより起泡させ、毛髪に塗布することを特徴とする毛髪補修方法。
[3] The hair cosmetic composition according to [1] or [2], wherein the surfactant (b2) is an anionic surfactant.
[4] The dimethiconol emulsion (B) is obtained by emulsion polymerization of a compound represented by the following general formula (3) in the presence of an anionic surfactant [1] Hair cosmetics as described in any one of-[3].
(Formula 3): HO [(CH 3 ) 2 SiO] n H
[In Formula (3), n is a value which makes the viscosity of the compound represented by Formula (3) in 25 degreeC the range of 1-3000 mPa * s. ]
[5] A hair repairing method characterized by foaming the hair cosmetic composition according to any one of [1] to [4] with a non-gas former and applying it to the hair.
本発明の毛髪化粧料は、ノンガスフォーマーにより起泡させて泡沫状とすることが可能であり、形成された泡は、毛髪への塗布に適した持続性を有する。泡沫状の本発明の毛髪化粧料は、毛髪になじみやすく毛髪の所望の箇所にむらなく塗布可能であるとともに、毛髪に付着しなかった化粧料が床等を汚すという問題もない。さらには、本発明の毛髪化粧料は、乾いた毛髪およびタオルドライした毛髪のいずれに使用してもなじみが良く、毛髪の指通り及びまとまりといった感触を向上させる。 The hair cosmetic composition of the present invention can be foamed by a non-gas former to form a foam, and the formed foam has a durability suitable for application to hair. The foamed hair cosmetic composition of the present invention is easy to adjust to the hair and can be applied evenly to a desired portion of the hair, and there is no problem that the cosmetic composition that does not adhere to the hair stains the floor or the like. Furthermore, the hair cosmetic composition of the present invention is well-familiar with both dry hair and towel-dried hair, and improves the feel of hair passing through and uniting.
以下、本発明について具体的に説明する。
＜毛髪化粧料の組成＞
本発明の毛髪化粧料は、絹タンパク質の加水分解物をアシル化して得られ、下記一般式（１）で表わされる化合物（ａ１）を含む成分（Ａ）と、
下記一般式（２）で表わされるジメチコノール（ｂ１）、界面活性剤（ｂ２）および水（ｂ３）を含むジメチコノールエマルジョン（Ｂ）とを含有し、
前記成分（Ａ）が、式（１）中のＲ2が異なる３種以上の化合物（ａ１）を含み、
前記毛髪化粧料全体を１００重量％とした場合、前記化合物（ａ１）の含有量が０．０５〜３．０重量％であり、前記ジメチコノール（ｂ１）の含有量が０．０５〜４．０重量％であり、
ノンガスフォーマーに充填させて用いることを特徴とする。
Hereinafter, the present invention will be specifically described.
<Composition of hair cosmetics>
The hair cosmetic composition of the present invention is obtained by acylating a hydrolyzate of silk protein, and contains a component (A) containing a compound (a1) represented by the following general formula (1):
Dimethiconol emulsion (B) containing dimethiconol (b1) represented by the following general formula (2), surfactant (b2) and water (b3),
The component (A) includes three or more compounds (a1) having different R 2 in the formula (1),
When the total amount of the hair cosmetic is 100% by weight, the content of the compound (a1) is 0.05 to 3.0% by weight, and the content of the dimethiconol (b1) is 0.05 to 4.0. % By weight
It is characterized by being used by filling a non-gas former.
（式１）：Ｒ1ＣＯＮＨＣＨ（Ｒ2）ＣＯＯＭ
式（１）中、Ｒ1はヒドロキシル基を有していてもよい炭素数５〜２１の直鎖状または分岐鎖状のアルキル基もしくはアルケニル基を表し、Ｒ2は絹タンパク質を加水分解して得られたアミノ酸の側鎖を表わし、Ｍはアルカリ金属、水素原子又はトリエタノールアミンを表わす。
(Formula 1): R 1 CONHCH (R 2 ) COOM
In the formula (1), R 1 represents a linear or branched alkyl or alkenyl group having 5 to 21 carbon atoms which may have a hydroxyl group, and R 2 hydrolyzes silk protein. The side chain of the obtained amino acid is represented, and M represents an alkali metal, a hydrogen atom or triethanolamine.
（式２）：ＨＯ［（ＣＨ3）2ＳｉＯ］mＨ
式（２）中、ｍは、２５℃におけるジメチコノール（ｂ１）の粘度を、０．０１〜５０００Ｐａ・ｓの範囲にする値である。
(Formula 2): HO [(CH 3 ) 2 SiO] m H
In formula (2), m is a value which makes the viscosity of dimethiconol (b1) in 25 degreeC the range of 0.01-5000 Pa.s.
（ｉ）成分（Ａ）
本発明の毛髪化粧料は、絹タンパク質をアミノ酸単位に加水分解した化合物をアシル化して得られる、下記一般式（１）で表わされる化合物（ａ１）を含む成分（Ａ）を含有する。
(I) Component (A)
The hair cosmetic composition of the present invention contains a component (A) containing a compound (a1) represented by the following general formula (1) obtained by acylating a compound obtained by hydrolyzing silk protein into amino acid units.
（式１）：Ｒ1ＣＯＮＨＣＨ（Ｒ2）ＣＯＯＭ
前記成分（Ａ）は、絹タンパク質をアミノ酸単位まで加水分解したものを、アシル化（高級脂肪酸と縮合）させて得られる混合物である。絹タンパク質を加水分解して得られるアミノ酸としては、グリシン、アラニン、バリン、ロイシン、イソロイシン、フェニルアラニン、プロリン、スレオニン、セリン、チロシン、メチオニン、シスチン、アルギニン、ヒスチジン、リジン、アスパラギン酸、グルタミン酸およびトリプトファンが挙げられる。
(Formula 1): R 1 CONHCH (R 2 ) COOM
The component (A) is a mixture obtained by acylating (condensation with higher fatty acids) a silk protein hydrolyzed to amino acid units. Amino acids obtained by hydrolyzing silk protein include glycine, alanine, valine, leucine, isoleucine, phenylalanine, proline, threonine, serine, tyrosine, methionine, cystine, arginine, histidine, lysine, aspartic acid, glutamic acid and tryptophan. Can be mentioned.
式（１）中、Ｒ1はヒドロキシル基を有していてもよい炭素数５〜２１、好ましくは炭素数７〜１５、より好ましくは炭素数９〜１３の直鎖状または分岐鎖状のアルキル基もしくはアルケニル基を表す。炭素数が上記範囲にあると起泡性が優れるため好ましい。Ｒ1ＣＯの具体例としては、カプロイル基、ラウロイル基、ミリストイル基、ココイル基等が挙げられる。Ｒ2は絹タンパク質を加水分解して得られたアミノ酸の側鎖を表わす。Ｒ2の具体例としては、アラニンの側鎖であるメチル基、グルタミン酸の側鎖であるカルボキシエチル基が挙げられる。Ｍはアルカリ金属、水素原子またはトリエタノールアミンを表わし、乾燥後の毛髪の指通りの観点からナトリウムまたはカリウムが好ましい。 In the formula (1), R 1 is a linear or branched alkyl having 5 to 21 carbon atoms, preferably 7 to 15 carbon atoms, more preferably 9 to 13 carbon atoms, which may have a hydroxyl group. Represents a group or an alkenyl group. It is preferable that the number of carbon atoms is in the above range because foamability is excellent. Specific examples of R 1 CO include a caproyl group, a lauroyl group, a myristoyl group, a cocoyl group, and the like. R 2 represents an amino acid side chain obtained by hydrolyzing silk protein. Specific examples of R 2 include a methyl group that is a side chain of alanine and a carboxyethyl group that is a side chain of glutamic acid. M represents an alkali metal, a hydrogen atom or triethanolamine, and sodium or potassium is preferred from the viewpoint of fingering after drying.
成分（Ａ）は、Ｒ1が同一でも異なっていてもよいが、Ｒ2が異なる３種以上、好ましくは４種以上、より好ましくは１７種以上の化合物（ａ１）を含む。
成分（Ａ）の例としては、グリシンおよびアラニンのアシル化物がそれぞれ混合物全体の３分の１程度を占め、セリンのアシル化物が混合物の約１０分の１を占め、バリンその他のアミノ酸のアシル化物が残りを占める混合物が挙げられ、絹タンパク質のアミノ酸の組成比と同じである該アミノ酸のアシル化物混合物が好ましく挙げられる。
The component (A) may include the same or different R 1, but includes 3 or more, preferably 4 or more, more preferably 17 or more compounds (a1) having different R 2 .
Examples of component (A) include acylated products of glycine and alanine, each accounting for about one third of the total mixture, serine acylated products accounting for about one-tenth of the mixture, and valine and other amino acid acylated products. Is a mixture of the amino acids of the silk protein, and preferably an acylated mixture of the amino acids having the same composition ratio as the amino acids of the silk protein.
このような成分（Ａ）の例としては、日本化粧品工業の表示名称で、ラウロイルシルクアミノ酸Ｎａ、ラウロイルシルクアミノ酸Ｋが挙げられる。
前記成分（Ａ）は、本発明の毛髪化粧料をノンガスフォーマーに用いた場合に、毛髪化粧料を起泡させ持続させる効果を奏するとともに、本発明の毛髪化粧料を塗布した毛髪に良好な指通り及びまとまりやすさを与える。
As an example of such a component (A), lauroyl silk amino acid Na and lauroyl silk amino acid K are mentioned with the display name of Japan Cosmetic Industry.
When the hair cosmetic composition of the present invention is used in a non-gas former, the component (A) has an effect of foaming and sustaining the hair cosmetic composition and is good for hair coated with the hair cosmetic composition of the present invention. Gives fingering and ease of grouping.
本発明の毛髪化粧料１００重量％中、前記成分（Ａ）は、化合物（ａ１）の毛髪化粧料（１００重量％）中の濃度が、０．０５〜３．０重量％、好ましくは０．１〜２．０重量％、さらに好ましくは０．２〜１．０重量％の量で含まれる。毛髪化粧料中の化合物（ａ１）の含有量が上記範囲よりも少ないと泡の起泡性が悪くなり、上記範囲よりも多いと毛髪化粧料の毛髪へのなじみが悪くなったり、毛髪化粧料を塗布して乾燥させた毛髪の指通りが悪くなる。 In 100% by weight of the hair cosmetic of the present invention, the component (A) has a concentration of the compound (a1) in the hair cosmetic (100% by weight) of 0.05 to 3.0% by weight, preferably 0.8. It is contained in an amount of 1 to 2.0% by weight, more preferably 0.2 to 1.0% by weight. When the content of the compound (a1) in the hair cosmetic is less than the above range, the foaming properties are deteriorated. When the content is more than the above range, the hair cosmetic is not well adapted to the hair, or the hair cosmetic. The finger of the hair that has been applied and dried becomes poor.
（ｉｉ）成分（Ｂ）
本発明の毛髪化粧料は、下記一般式（２）で表わされるジメチコノール（ｂ１）、界面活性剤（ｂ２）および水（ｂ３）を含むジメチコノールエマルジョン（Ｂ）を含有する。
(Ii) Component (B)
The hair cosmetic composition of the present invention contains a dimethiconol emulsion (B) containing dimethiconol (b1) represented by the following general formula (2), a surfactant (b2) and water (b3).
（式２）：ＨＯ［（ＣＨ3）2ＳｉＯ］mＨ
式（２）中、ｍは、２５℃におけるジメチコノール（ｂ１）の粘度を、０．０１〜５０００Ｐａ・ｓ、好ましくは０．１〜３０００Ｐａ・ｓ、より好ましくは０．５〜１０００Ｐａ・ｓの範囲にする値である。
(Formula 2): HO [(CH 3 ) 2 SiO] m H
In the formula (2), m represents the viscosity of dimethiconol (b1) at 25 ° C. in the range of 0.01 to 5000 Pa · s, preferably 0.1 to 3000 Pa · s, more preferably 0.5 to 1000 Pa · s. Is the value to be
前記界面活性剤（ｂ２）としては、アニオン性界面活性剤、カチオン性界面活性剤およびノニオン性界面活性剤のいずれも使用することができるが、毛髪化粧料の起泡性および泡の持続性ならびに乾燥後の毛髪の指通りの観点からアニオン性界面活性剤が好ましい。アニオン性界面活性剤としては、アルキルベンゼンスルホン酸、ポリオキシエチレンアルキルエーテル硫酸、アルキル硫酸、およびそれらの塩が挙げられる。その中でも、アルキルベンゼンスルホン酸として、ドデシルベンゼンスルホン酸などが、ポリオキシエチレンアルキルエーテル硫酸として、ポリオキシエチレンラウリルエーテル硫酸などが、アルキル硫酸として、ラウリル硫酸、ミリスチル硫酸、セチル硫酸などおよびそれらの塩が好ましく挙げられる。 As the surfactant (b2), any of an anionic surfactant, a cationic surfactant and a nonionic surfactant can be used. An anionic surfactant is preferable from the viewpoint of fingering after drying. Examples of the anionic surfactant include alkylbenzene sulfonic acid, polyoxyethylene alkyl ether sulfuric acid, alkyl sulfuric acid, and salts thereof. Among them, as alkylbenzene sulfonic acid, dodecylbenzene sulfonic acid, etc., polyoxyethylene alkyl ether sulfuric acid, polyoxyethylene lauryl ether sulfuric acid, etc., as alkyl sulfuric acid, lauryl sulfuric acid, myristyl sulfuric acid, cetyl sulfuric acid etc. and their salts Preferably mentioned.
前記ジメチコノールエマルジョン（Ｂ）は、界面活性剤（ｂ２）を用いて水（ｂ３）にジメチコノール（ｂ１）を乳化させる方法の他、界面活性剤（ｂ２）の存在下で下記式（３）で表わされる化合物を乳化重合する方法によっても得ることができ、毛髪を乾かした後の毛先のまとまりの観点から、界面活性剤（ｂ２）の存在下で下記式（３）で表わされる化合物を乳化重合する方法により得ることが好ましく、アニオン性界面活性剤の存在下で下記式（３）で表わされる化合物を乳化重合する方法により得ることがより好ましい。 The dimethiconol emulsion (B) is represented by the following formula (3) in the presence of the surfactant (b2) in addition to the method of emulsifying the dimethiconol (b1) in the water (b3) using the surfactant (b2). The compound represented by the following formula (3) can be obtained by emulsion polymerization in the presence of the surfactant (b2) from the viewpoint of uniting the hair ends after drying the hair. It is preferable to obtain by a method of emulsion polymerization of a compound represented by the following formula (3) in the presence of an anionic surfactant.
（式３）：ＨＯ［（ＣＨ3）2ＳｉＯ］nＨ
式（３）中、ｎは、２５℃における式（３）で表わされる化合物の粘度を、１〜３０００ｍＰａ・ｓの範囲にする値である。
(Formula 3): HO [(CH 3 ) 2 SiO] n H
In Formula (3), n is a value which makes the viscosity of the compound represented by Formula (3) in 25 degreeC the range of 1-3000 mPa * s.
ジメチコノールエマルジョン（Ｂ）は、毛髪を補修し、毛髪の指通り及びまとまりを良好にする。また、エマルジョンの形態であるため、ジメチコノールが毛髪になじみやすい。 The dimethiconol emulsion (B) repairs the hair and improves the finger passage and unity of the hair. Moreover, since it is in the form of an emulsion, dimethiconol is easy to adjust to hair.
ジメチコノールエマルジョン（Ｂ）は、ジメチコノール（ｂ１）の毛髪化粧料（１００重量％）中の濃度が、０．０５〜４．０重量％、好ましくは０．１〜３．０重量％、より好ましくは０．３〜２．５重量％となる量で用いられる。本発明の毛髪化粧料中のジメチコール（ｂ１）の含有量が上記範囲よりも少ないと、毛髪化粧料を毛髪に塗布して乾燥させた後の毛髪の指通りやまとまり感がなくなり、上記範囲よりも多いと、毛髪化粧料を毛髪に塗布して乾燥させた後の毛髪の指通りが悪くなる。 In the dimethiconol emulsion (B), the concentration of dimethiconol (b1) in the hair cosmetic (100% by weight) is 0.05 to 4.0% by weight, preferably 0.1 to 3.0% by weight, more preferably It is used in an amount of 0.3 to 2.5% by weight. When the content of dimethicol (b1) in the hair cosmetic composition of the present invention is less than the above range, there is no sense of touching and clumping the hair after the hair cosmetic composition is applied to the hair and dried, from the above range. If the amount is too large, the fingering of the hair after the hair cosmetic is applied to the hair and dried is deteriorated.
ジメチコノールエマルジョンは、ジメチコノール、界面活性剤および水の他に、ジメチコノールおよびエマルジョンの性質を損なわない範囲で、防腐剤、殺菌剤等の成分を含んでいてもよい。 In addition to dimethiconol, surfactant and water, the dimethiconol emulsion may contain components such as preservatives and bactericides as long as the properties of dimethiconol and the emulsion are not impaired.
（ｉｉｉ）任意成分
本発明の毛髪化粧料は、本発明の目的を損なわない範囲で上記成分の他に成分（Ａ）以外のアニオン性界面活性剤、カチオン界面活性剤、両性界面活性剤、ノニオン性界面活性剤等の界面活性剤、エステル油、高級脂肪酸、高級アルコール、炭化水素、油脂類等の油剤、鎖状シリコーン、環状シリコーン、変性シリコーン、（Ｂ）以外のシリコーンエマルジョン等のシリコーン類、天然水溶性高分子、半合成水溶性高分子、合成水溶性高分子等の水溶性高分子、多価アルコール、糖類、低級アルコール、芳香族アルコール等の水性成分、アミノ酸、アミノ酸誘導体、ペプチド、ペプチド誘導体、植物エキス等の毛髪用美容成分、エデト酸塩等の金属キレート剤、クエン酸、乳酸、リン酸またはこれらの塩等のｐＨ調整剤、香料、防腐剤、殺菌剤、紫外線吸収剤、酸化防止剤、色素、顔料等、毛髪用化粧料あるいは化粧料一般において汎用される他の成分を配合することができる。
(Iii) Optional component The hair cosmetic composition of the present invention is an anionic surfactant other than the above component (A), a cationic surfactant, an amphoteric surfactant, and a nonion as long as the object of the present invention is not impaired. Surfactants such as surfactants, oil agents such as ester oils, higher fatty acids, higher alcohols, hydrocarbons, fats and oils, chain silicones, cyclic silicones, modified silicones, silicones such as silicone emulsions other than (B), Water-soluble polymers such as natural water-soluble polymers, semi-synthetic water-soluble polymers, synthetic water-soluble polymers, aqueous components such as polyhydric alcohols, sugars, lower alcohols, aromatic alcohols, amino acids, amino acid derivatives, peptides, peptides Derivatives, cosmetic ingredients for hair such as plant extracts, metal chelating agents such as edetate, pH adjusters such as citric acid, lactic acid, phosphoric acid or salts thereof, Other ingredients commonly used in hair cosmetics or cosmetics in general, such as fragrances, preservatives, bactericides, ultraviolet absorbers, antioxidants, dyes and pigments, can be blended.
＜毛髪化粧料の製造方法＞
本発明の毛髪化粧料は、上述した各成分を、公知の方法で、撹拌、混合、加熱、溶解、分散および乳化等を必要に応じて選択して行うことによって製造することができ、製造方法は特に限定されない。
<Method for producing hair cosmetics>
The hair cosmetic composition of the present invention can be produced by selecting each of the above-mentioned components by a known method, such as stirring, mixing, heating, dissolving, dispersing and emulsifying, as necessary. Is not particularly limited.
＜毛髪化粧料の使用態様＞
本発明の毛髪化粧料は、ノンガスフォーマーによって手に起泡させてから毛髪に塗布する方法で用いられる。このような剤型とすることにより、毛髪の所望の箇所に均一に毛髪化粧料を塗布でき、使用者の周りの床等を汚すことがない。
<Use mode of hair cosmetic>
The hair cosmetic composition of the present invention is used by a method in which the hair is foamed by a non-gas former and then applied to the hair. By setting it as such a dosage form, hair cosmetics can be apply | coated uniformly to the desired location of hair, and the floor etc. around a user are not soiled.
ノンガスフォーマーとしては、充填された毛髪化粧料を空気と混合して泡状に吐出できる機構を備えたものであれば特に限定はなく、ポンプ機構を備えた容器およびスクイズ容器等を用いることができる。また、これらノンガスフォーマー内部には、通常メッシュ等の多孔体が設けられているが、メッシュの場合、網目の大きさは特に限定されず、通常５０〜３００メッシュ、好ましくは１００〜２００メッシュ程度とすることが好ましい。上記ノンガスフォーマーの例としては、ポンプ機構とメッシュ等の多孔体を備えたポンプ容器であって、ポンプの頭部（押圧部）を押すことにより、毛髪化粧料が空気と混ざり発泡した状態で多孔体を通過して均質な泡状になる容器が挙げられる。 The non-gas former is not particularly limited as long as it has a mechanism capable of mixing the filled hair cosmetic with air and ejecting it in the form of foam, and a container having a pump mechanism, a squeeze container, or the like may be used. it can. Further, a porous body such as a mesh is usually provided inside these non-gas formers, but in the case of a mesh, the size of the mesh is not particularly limited, and is usually 50 to 300 mesh, preferably about 100 to 200 mesh. It is preferable that An example of the non-gas former is a pump container having a pump mechanism and a porous body such as a mesh, and the hair cosmetic is mixed with air and foamed by pressing the head (pressing portion) of the pump. Examples include a container that passes through a porous body and becomes a homogeneous foam.
本発明の毛髪化粧料は、乾いた毛髪またはタオルドライした毛髪に塗布し、洗い流すことなく乾燥させて用いる。乾燥は自然乾燥またはドライヤーによる乾燥のいずれでもよい。このような使用方法により、乾いた毛髪およびタオルドライした毛髪のいずれに対しても高い毛髪補修機能が得られる。また、このように使用しても、毛髪のごわつきや、べたつきが生じることがない。 The hair cosmetic composition of the present invention is applied to dry hair or towel-dried hair and dried without being washed away. Drying may be either natural drying or drying with a dryer. By such a method of use, a high hair repair function can be obtained for both dry hair and towel-dried hair. Moreover, even if used in this way, the hair does not become stiff or sticky.
以下、実施例に基づいて本発明をさらに具体的に説明するが、本発明はこれらの実施例に限定されるものではない。
実施例において、アニオン界面活性剤を用いて乳化したジメチコノールエマルジョンとしてはDM３１１２VP（旭化成ワッカーシリコーン（株）製）、ノニオン界面活性剤を用いて乳化したジメチコノールエマルジョンとしてはXS−６５C２１７３（モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社製）、ラウロイルシルクアミノ酸Ｋとしては、カワシルクS（川研ファインケミカル（株）製）を使用し、ラウロイル加水分解シルクＫとしては、カワシルク（川研ファインケミカル（株）製）を使用し、ココイルアラニンＮａとしては、アミライトACS−１２（味の素ヘルシーサプライ（株）製）を使用し、ココイルグリシンＮａとしては、アミライトGCS−１２K（味の素ヘルシーサプライ（株）製）を使用し、ジメチルシリコーンエマルジョンとしては、FZ−４１８８（東レ・ダウコーニング（株）製）を使用した。これら成分の表に記載された量は、純分の量である。
EXAMPLES Hereinafter, although this invention is demonstrated further more concretely based on an Example, this invention is not limited to these Examples.
In Examples, DM3112VP (manufactured by Asahi Kasei Wacker Silicone Co., Ltd.) is used as a dimethiconol emulsion emulsified using an anionic surfactant, and XS-65C2173 (momentive performance material is used as a dimethiconol emulsion emulsified using a nonionic surfactant. KAWA SILK S (manufactured by Kawaken Fine Chemical Co., Ltd.) is used as lauroyl silk amino acid K, and KAWA SILK (manufactured by Kawaken Fine Chemical Co., Ltd.) is used as lauroyl hydrolyzed silk K. As cocoylalanine Na, amylite ACS-12 (manufactured by Ajinomoto Healthy Supply Co., Ltd.) is used, and as cocoylglycine Na, amylite GCS-12K (manufactured by Ajinomoto Healthy Supply Co., Ltd.) is used, and dimethyl silicone D The Rujon, was used FZ-4188 (manufactured by Dow Corning Toray Co., Ltd.). The amounts listed in the table of these components are pure amounts.
［実施例１〜１６、比較例１〜９］
表１に示す組成の毛髪化粧料を調製した。得られた毛髪化粧料の各試料について、下記評価方法１にて、試料の（Ａ−１）起泡性および（Ａ−２）泡の持続性を評価した。また、下記評価方法２にて、（Ｂ−１）タオルドライした毛髪に試料を塗布する時の試料の毛髪に対するなじみやすさ、（Ｂ−２）タオルドライした毛髪に試料を塗布し、毛髪を乾かした後の毛髪の指通り、および（Ｂ−３）タオルドライした毛髪に試料を塗布し、毛髪を乾かした後の毛先のまとまりを評価し、また、評価方法３にて（Ｃ−１）乾燥した毛髪に試料を塗布する時の試料の毛髪に対するなじみやすさ、（Ｃ−２）乾燥した毛髪に試料を塗布し、毛髪を乾かした後の毛髪の指通り、および（Ｃ−３）乾燥した毛髪に試料を塗布し、毛髪を乾かした後の毛先のまとまりを評価した。その結果を表１に示す。
[Examples 1 to 16, Comparative Examples 1 to 9]
Hair cosmetics having the composition shown in Table 1 were prepared. About each sample of the obtained hair cosmetics, the following evaluation method 1 evaluated the (A-1) foamability and (A-2) foam sustainability of the sample. Moreover, in the following evaluation method 2, (B-1) Ease of familiarity of the sample with the hair when applying the sample to towel-dried hair, (B-2) Applying the sample to the towel-dried hair, The sample was applied to the hair after the hair was dried and (B-3) towel-dried hair, and the unit of the hair ends after the hair was dried was evaluated. ) Ease of familiarity of the sample with the hair when the sample is applied to the dried hair, (C-2) After applying the sample to the dried hair and drying the hair, and (C-3) A sample was applied to the dried hair, and the bundle of hair ends after the hair was dried was evaluated. The results are shown in Table 1.
＜評価方法１：起泡性、泡の持続性の評価＞
２００メッシュのネットを有するポンプ型泡吐出容器（商品名；Ｆ２ポンプフォーマー、大和製罐社製）に充填した実施例１〜１６および比較例１〜９の各試料をラップ（商品名；
サランラップ（登録商標）、旭化成ホームプロダクツ（株）製）上に２プッシュ吐出し、（Ａ−１）起泡性を目視にて下記評価基準により評価した。その後、そのまま１分間静置した試料の（Ａ−２）泡の持続性を目視にて下記評価基準により評価した。（Ａ−１）および（Ａ−２）のいずれも１０人の美容師のテスターにより評価した。評価は、各パネラー毎に評点を出し、１０人の評点の平均を評価基準に基づき判定した。
<Evaluation method 1: Evaluation of foamability and foam persistence>
Each sample of Examples 1 to 16 and Comparative Examples 1 to 9 filled in a pump-type foam discharge container (trade name; F2 pump former, manufactured by Daiwa Steel Corporation) having a 200 mesh net is wrapped (trade name;
Two push discharges were performed on Saran Wrap (registered trademark), manufactured by Asahi Kasei Home Products Co., Ltd., and (A-1) foamability was visually evaluated according to the following evaluation criteria. Then, the persistence of the (A-2) foam of the sample which was left still for 1 minute as it was was visually evaluated according to the following evaluation criteria. Both (A-1) and (A-2) were evaluated by 10 beautician testers. In the evaluation, a score was given for each paneler, and the average of 10 scores was determined based on the evaluation criteria.
（Ａ−１）起泡性
（評点）
４点：泡密度が高く、起泡性が非常に良好である。
３点：泡密度は普通であるが、起泡性が良好である。
２点：起泡性がやや悪い。
１点：起泡性が悪く泡立たない。
(A-1) Foamability (score)
4 points: Bubble density is high and foamability is very good.
3 points: The foam density is normal, but the foaming property is good.
2 points: Slightly poor foaming property.
1 point: Foaming property is poor and no foaming occurs.
（Ａ−２）泡の持続性
（評点）
４点：起泡時の泡を保っている。
３点：極僅かに破泡が確認されるが、起泡時の泡をほぼ保っている。
２点：破泡が多数確認される。
１点：ほとんど破泡してしまう。
(A-2) Sustainability of foam (score)
4 points: Maintaining foam when foaming.
3 points: Foam breakage is confirmed slightly, but the foam at the time of foaming is almost maintained.
2 points: Many bubbles are confirmed.
1 point: Bubbles are almost broken.
＜評価用毛束の作製＞
中国人毛髪（商品名；BS-B3A、（株）ビューラックス製）の１０ｇ、３０ｃｍをブリーチ処理（毛髪を６％過酸化水素水ｐＨ１１の水溶液４００ｍＬに３０分浸漬させ、その後、毛髪を水洗し、ドライヤーで乾燥させる処理）した。次いで、得られた毛髪にパーマ処理（毛髪にチオグリコール酸６．０％（ｐＨ９）の水溶液を塗布し、１５分放置した。毛髪を水洗後、１０％臭素酸ナトリウム水溶液を塗布し２０分放置し、水洗し、乾燥させる処理）を施した。さらに、得られた毛髪に上記ブリーチ処理をもう一度行い、評価用毛束を作成した。
<Production of evaluation hair bundle>
10g, 30cm of Chinese hair (trade name: BS-B3A, manufactured by Beaulux Co., Ltd.) was bleached (the hair was immersed in 400 mL of 6% hydrogen peroxide solution pH 11 for 30 minutes, and then the hair was washed with water. And drying with a dryer. Next, perm treatment was applied to the obtained hair (an aqueous solution of thioglycolic acid 6.0% (pH 9) was applied to the hair and left for 15 minutes. After washing the hair with water, a 10% sodium bromate aqueous solution was applied and left for 20 minutes. , Washed with water and dried). Furthermore, the above-mentioned bleaching treatment was performed once again on the obtained hair, and a hair bundle for evaluation was prepared.
＜評価方法２：タオルドライした毛髪に試料を使用したときの評価＞
評価用毛束を、シャンプー（商品名；ケアトリコシャンプータイプS、（株）アリミノ製）、トリートメント（商品名；ケアトリコトリートメントタイプS、（株）アリミノ製）を用いて前処理し、タオルドライした。２００メッシュのネットを有するポンプ型泡吐出容器（商品名；Ｆ２ポンプフォーマー、大和製罐（株）製）に充填した実施例１〜１６および比較例１〜９の各試料１プッシュ分を上記評価用毛束に塗布し、毛髪になじませ（Ｂ−１）の評価を行った後、毛髪をドライヤーで乾燥させ（Ｂ−２）および（Ｂ−３）の評価を行った。評価は１０人の専門テスター（美容師）により官能評価した。評価は、各パネラー毎に評点を出し、１０人の評点の平均を下記評価基準に基づき判定した。
<Evaluation method 2: Evaluation when a sample is used on towel-dried hair>
The hair bundle for evaluation is pretreated with a shampoo (trade name; Care Trico Shampoo Type S, manufactured by Arimino Co., Ltd.) and a treatment (trade name; Care Trico Treatment Type S, manufactured by Arimino Co., Ltd.), and then towel dried. did. Each sample 1 push for Examples 1-16 and Comparative Examples 1-9 filled in a pump-type foam discharge container (trade name; F2 pump former, manufactured by Daiwa Steel Co., Ltd.) having a 200 mesh net After applying to the evaluation hair bundle and applying to hair (B-1), the hair was dried with a drier and evaluated (B-2) and (B-3). Evaluation was sensory evaluated by 10 professional testers (beauticians). In the evaluation, a score was given for each paneler, and an average of 10 scores was determined based on the following evaluation criteria.
（Ｂ−１）タオルドライした毛髪に試料を塗布する時の試料の毛髪に対するなじみやすさ
（評点）
４点：毛髪化粧料の泡が塗布時に消え、毛髪化粧料が毛髪になじみやすく、毛髪全体に非常に均一に塗布できる。
３点：毛髪化粧料の泡が塗布時に消え、毛髪化粧料が毛髪になじみやすく、毛髪のほぼ全体に均一に塗布できる。
２点：毛髪化粧料の泡が塗布時に消えにくく、毛髪化粧料の毛髪へのなじみが悪い。
１点：毛髪化粧料の泡が塗布時に消えず、毛髪化粧料が毛髪になじまない。
(B-1) Familiarity of sample to hair when applying sample to towel-dried hair (score)
4 points: The foam of the hair cosmetic disappears upon application, the hair cosmetic easily adapts to the hair, and can be applied to the entire hair very uniformly.
3 points: The foam of the hair cosmetic disappears upon application, the hair cosmetic easily adapts to the hair, and can be applied uniformly to almost the entire hair.
2 points: The foam of the hair cosmetic is difficult to disappear at the time of application, and the hair cosmetic is not well adapted to the hair.
1 point: The foam of the hair cosmetic does not disappear at the time of application, and the hair cosmetic does not conform to the hair.
（Ｂ−２）タオルドライした毛髪に試料を塗布し、毛髪を乾かした後の毛髪の指通り
（評点）
４点：非常に滑らかである。
３点：滑らかである。
２点：やや滑らかである。
１点：滑らかさは無い。
(B-2) Applying a sample to towel-dried hair and drying the hair, following the finger of the hair (rating)
4 points: Very smooth.
3 points: Smooth.
2 points: Slightly smooth.
1 point: No smoothness.
（Ｂ−３）タオルドライした毛髪に試料を塗布し、毛髪を乾かした後の毛先のまとまり
（評点）
４点：非常にまとまる。
３点：まとまる。
２点：ややまとまりに欠ける。
１点：まとまらない。
(B-3) Coat of hair tips after applying a sample to towel-dried hair and drying the hair (rating)
4 points: Very well organized.
3 points: Collect.
2 points: Slightly unorganized.
1 point: Not settled.
＜評価方法３：乾燥した毛髪に試料を使用したときの評価＞
評価用毛束を、シャンプー（商品名；ケアトリコシャンプータイプS、 （株）アリミノ製）、トリートメント（商品名；ケアトリコトリートメントタイプS、 （株）アリミノ製）を用いて前処理し、タオルドライした後、乾燥させた。２００メッシュのネットを有するポンプ型泡吐出容器（商品名；Ｆ２ポンプフォーマー、大和製罐（株）製）に充填した実施例１〜１６および比較例１〜９の各試料１プッシュ分を上記評価用毛束に塗布し、毛髪になじませ（Ｃ−１）の評価を行った後、毛髪をドライヤーで乾燥させ（Ｃ−２）および（Ｃ−３）を評価した。評価は１０人の専門テスター（美容師）により官能評価した。評価は、各パネラー毎に評点を出し、１０人の評点の平均を下記評価基準に基づき判定した。
<Evaluation method 3: Evaluation when using sample on dry hair>
The hair bundle for evaluation is pretreated with a shampoo (trade name; Care Trico Shampoo Type S, manufactured by Arimino Co., Ltd.) and a treatment (trade name; Care Trico Treatment Type S, manufactured by Arimino Co., Ltd.), and then towel dried. And then dried. Each sample 1 push for Examples 1-16 and Comparative Examples 1-9 filled in a pump-type foam discharge container (trade name; F2 pump former, manufactured by Daiwa Steel Co., Ltd.) having a 200 mesh net After applying to the hair bundle for evaluation and adapting to the hair (C-1), the hair was dried with a dryer to evaluate (C-2) and (C-3). Evaluation was sensory evaluated by 10 professional testers (beauticians). In the evaluation, a score was given for each paneler, and an average of 10 scores was determined based on the following evaluation criteria.
（Ｃ−１）乾燥した毛髪に試料を塗布する時の試料の毛髪に対するなじみやすさ
（評点）
４点：毛髪化粧料の泡が塗布時に消え、毛髪化粧料が毛髪になじみやすく、毛髪全体に非常に均一に塗布できる。
３点：毛髪化粧料の泡が塗布時に消え、毛髪化粧料が毛髪になじみやすく、毛髪のほぼ全体に均一に塗布できる。
２点：毛髪化粧料の泡が塗布時に消えにくく、毛髪化粧料の毛髪へのなじみが悪い。
１点：毛髪化粧料の泡が塗布時に消えず、毛髪化粧料が毛髪になじまない。
(C-1) Familiarity of the sample to the hair when the sample is applied to dry hair (score)
4 points: The foam of the hair cosmetic disappears upon application, the hair cosmetic easily adapts to the hair, and can be applied to the entire hair very uniformly.
3 points: The foam of the hair cosmetic disappears upon application, the hair cosmetic easily adapts to the hair, and can be applied uniformly to almost the entire hair.
2 points: The foam of the hair cosmetic is difficult to disappear at the time of application, and the hair cosmetic is not well adapted to the hair.
1 point: The foam of the hair cosmetic does not disappear at the time of application, and the hair cosmetic does not conform to the hair.
（Ｃ−２）乾燥した毛髪に試料を塗布し、毛髪を乾かした後の毛髪の指通り
（評点）
４点：非常に滑らかである。
３点：滑らかである。
２点：やや滑らかである。
１点：滑らかさは無い。
(C-2) Applying a sample to the dried hair and passing the hair through the hair after drying (rating)
4 points: Very smooth.
3 points: Smooth.
2 points: Slightly smooth.
1 point: No smoothness.
（Ｃ−３）乾燥した毛髪に試料を塗布し、毛髪を乾かした後の毛先のまとまり
（評点）
４点：非常にまとまる。
３点：まとまる。
２点：ややまとまりに欠ける。
１点：まとまらない。
(C-3) Coat of hair tips after applying sample to dried hair and drying hair (rating)
4 points: Very well organized.
3 points: Collect.
2 points: Slightly unorganized.
1 point: Not settled.
（Ａ−１）〜（Ｃ−３）の評価基準
◎：評点の平均点が３．５点以上である。
○：評点の平均点が３点以上３．５点未満である。
△：評点の平均点が２点以上３点未満である。
×：評点の平均点が２点未満である。
Evaluation criteria (A-1) to (C-3) A: The average score is 3.5 or more.
A: The average score is 3 or more and less than 3.5.
Δ: The average score is 2 or more and less than 3 points.
X: The average score is less than 2 points.
Claims (4)
下記一般式（２）で表わされるジメチコノール（ｂ１）、界面活性剤（ｂ２）および水（ｂ３）を含むジメチコノールエマルジョン（Ｂ）と
を含有する毛髪化粧料であって、
前記成分（Ａ）が、式（１）中のＲ2が異なる３種以上の化合物（ａ１）を含み、
前記毛髪化粧料全体を１００重量％とした場合、前記化合物（ａ１）の含有量が０．０５〜３．０重量％であり、前記ジメチコノール（ｂ１）の含有量が０．０５〜４．０重量％であり、
ノンガスフォーマーに充填させて用い、かつ毛髪に塗布後、洗い流さないで用いることを特徴とする毛髪化粧料。
（式１）：Ｒ1ＣＯＮＨＣＨ（Ｒ2）ＣＯＯＭ
［式（１）中、Ｒ1はヒドロキシル基を有していてもよい炭素数５〜２１の直鎖状または分岐鎖状のアルキル基もしくはアルケニル基を表し、Ｒ2は絹タンパク質を加水分解して得られたアミノ酸の側鎖を表わし、Ｍはアルカリ金属、水素原子またはトリエタノールアミンを表わす。］
（式２）：ＨＯ［（ＣＨ3）2ＳｉＯ］mＨ
［式（２）中、ｍは、２５℃におけるジメチコノール（ｂ１）の粘度を、０．０１〜５０００Ｐａ・ｓの範囲にする値である。］ A component (A) obtained by acylating a hydrolyzate of silk protein and containing a compound (a1) represented by the following general formula (1);
A hair cosmetic containing dimethiconol (b1) represented by the following general formula (2), a surfactant (b2) and a dimethiconol emulsion (B) containing water (b3),
The component (A) includes three or more compounds (a1) having different R 2 in the formula (1),
When the total amount of the hair cosmetic is 100% by weight, the content of the compound (a1) is 0.05 to 3.0% by weight, and the content of the dimethiconol (b1) is 0.05 to 4.0. % By weight
A hair cosmetic characterized by being used by being filled in a non-gas former and applied to the hair without being washed away .
(Formula 1): R 1 CONHCH (R 2 ) COOM
[In formula (1), R 1 represents a linear or branched alkyl group or alkenyl group having 5 to 21 carbon atoms which may have a hydroxyl group, and R 2 hydrolyzes silk protein. And M represents an alkali metal, a hydrogen atom or triethanolamine. ]
(Formula 2): HO [(CH 3 ) 2 SiO] m H
[In Formula (2), m is a value which makes the viscosity of dimethiconol (b1) in 25 degreeC the range of 0.01-5000 Pa.s. ]
（式３）：ＨＯ［（ＣＨ3）2ＳｉＯ］nＨ
［式（３）中、ｎは、２５℃における式（３）で表わされる化合物の粘度を、１〜３０００ｍＰａ・ｓの範囲にする値である。］ The dimethiconol emulsion (B) is, in claim 1 or 2, characterized in that a compound represented by the following general formula in the presence of an anionic surfactant (3) obtained by emulsion polymerization The hair cosmetic composition described.
(Formula 3): HO [(CH 3 ) 2 SiO] n H
[In Formula (3), n is a value which makes the viscosity of the compound represented by Formula (3) in 25 degreeC the range of 1-3000 mPa * s. ]
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