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JP2019034325A - Manufacturing method of ferritic stainless steel cold-rolled steel strip - Google Patents

Manufacturing method of ferritic stainless steel cold-rolled steel strip Download PDF

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Publication number
JP2019034325A
JP2019034325A JP2017158416A JP2017158416A JP2019034325A JP 2019034325 A JP2019034325 A JP 2019034325A JP 2017158416 A JP2017158416 A JP 2017158416A JP 2017158416 A JP2017158416 A JP 2017158416A JP 2019034325 A JP2019034325 A JP 2019034325A
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roll
rolling
cold
gloss
steel strip
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Inventor
彩子 田
Ayako Den
彩子 田
松原 行宏
Yukihiro Matsubara
行宏 松原
木村 幸雄
Yukio Kimura
幸雄 木村
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JFE Steel Corp
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JFE Steel Corp
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Priority to JP2017158416A priority Critical patent/JP2019034325A/en
Priority to CN201821343548.6U priority patent/CN209334439U/en
Priority to CN201810946840.5A priority patent/CN109420679B/en
Publication of JP2019034325A publication Critical patent/JP2019034325A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/22Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
    • B21B1/30Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a non-continuous process
    • B21B1/32Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a non-continuous process in reversing single stand mills, e.g. with intermediate storage reels for accumulating work
    • B21B1/36Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a non-continuous process in reversing single stand mills, e.g. with intermediate storage reels for accumulating work by cold-rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B3/00Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
    • B21B3/02Rolling special iron alloys, e.g. stainless steel
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236Cold rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0278Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular surface treatment
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Metal Rolling (AREA)
  • Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)

Abstract

【課題】表面光沢に優れ、かつ、光沢ムラが抑制されたフェライト系ステンレス冷延鋼帯の製造方法を提供すること。【解決手段】酸洗後のフェライト系ステンレス熱延鋼帯に対して、最終パス以外のパスでは、ロール径が40mm以上150mm以下、表面の算術平均粗さRaが0.20μm以上0.45μmRa以下のワークロールを用いて圧延し、最終パスでは、ロール径が40mm以上150mm以下、表面の算術平均粗さRaが0.03μm以上0.15μm以下のワークロールを用いて圧延する冷間圧延を施し、焼鈍を施した後、伸び率0.3〜2.0%の調質圧延を施すことを特徴とするフェライト系ステンレス冷延鋼帯の製造方法。【選択図】なしThe present invention provides a method for producing a ferritic stainless steel cold-rolled steel strip having excellent surface gloss and suppressing uneven gloss. SOLUTION: For ferritic stainless hot rolled steel strip after pickling, in a pass other than the final pass, the roll diameter is 40 mm or more and 150 mm or less, and the arithmetic average roughness Ra of the surface is 0.20 μm or more and 0.45 μm Ra or less. In the final pass, the roll is rolled using a work roll having a roll diameter of 40 mm or more and 150 mm or less and a surface arithmetic average roughness Ra of 0.03 μm or more and 0.15 μm or less. A method for producing a ferritic stainless steel cold-rolled steel strip, characterized by performing temper rolling with an elongation of 0.3 to 2.0% after annealing. [Selection figure] None

Description

本発明は、フェライト系ステンレス冷延鋼帯の製造方法に関するものである。   The present invention relates to a method for producing a ferritic stainless steel cold-rolled steel strip.

フェライト系ステンレス冷延鋼帯は、家電製品、厨房製品、洋食器などに使用される場合が多く、表面光沢は重要な特性である。特に、表面の光沢度を高めた高光沢の冷延鋼帯にすると、冷延鋼帯の幅方向に光沢ムラ(表面光沢の差)が目立ちやすくなるため、表面光沢に優れ、かつ、光沢ムラが抑制された冷延鋼帯を得ることは重要な課題である。   Ferritic stainless steel cold-rolled steel strip is often used for home appliances, kitchen products, Western dishes, etc., and surface gloss is an important characteristic. In particular, when a high-gloss cold-rolled steel strip with a high surface glossiness is used, gloss unevenness (difference in surface gloss) is more noticeable in the width direction of the cold-rolled steel strip, so that surface gloss is excellent and gloss unevenness It is an important subject to obtain a cold-rolled steel strip in which the above is suppressed.

フェライト系ステンレス冷延鋼帯は、通常、連続鋳造により製造されたスラブを熱間圧延して熱延鋼帯を製造し、焼鈍(場合によって省略される)、酸洗した後、冷間圧延し、これを焼鈍、酸洗(場合によって省略される)、調質圧延することにより製造される。このうち、光沢ムラは、冷間圧延の工程で発生する欠陥である。   Ferritic stainless steel cold-rolled steel strips are usually hot-rolled slabs produced by continuous casting to produce hot-rolled steel strips, annealed (may be omitted in some cases), pickled, and then cold-rolled. It is manufactured by annealing, pickling (may be omitted in some cases), and temper rolling. Among these, gloss unevenness is a defect generated in the cold rolling process.

上記のような表面光沢(高光沢)が要求されるステンレス冷延鋼帯は、20段式ゼンジミアミル、12段式クラスターミルといった、ロール径が小さいワークロールを有する冷間圧延機で冷間圧延して製造されるのが一般的である。これは、ロール径の小さいワークロールは圧延油の引き込みが少なく優れた表面光沢を得るのに好ましいことと、変形抵抗の大きいステンレス鋼を圧延するには、ロール径の小さいワークロールを用いる方が有利であることによる。   Stainless cold-rolled steel strips that require surface gloss (high gloss) as described above are cold-rolled with a cold rolling mill having a work roll with a small roll diameter, such as a 20-stage Zenzimir mill or a 12-stage cluster mill. Generally, it is manufactured. This is because a work roll with a small roll diameter is preferable for obtaining excellent surface gloss with less drawing of rolling oil, and for rolling stainless steel with a large deformation resistance, it is better to use a work roll with a small roll diameter. By being advantageous.

従来、フェライト系ステンレス冷延鋼帯の表面光沢を向上する技術については、多くの技術が開示されている。冷間圧延では、各パス毎、あるいは、2〜3パス毎に、表面粗さの大きいロールから表面粗さの小さいロールに順次ワークロールを交換して圧延を行い、表面光沢に優れた冷延鋼帯を造り込む方法が実施されている。しかし、この場合、ワークロールを交換する回数が増える、パス毎に表面粗さの異なる数種のワークロールを用意する必要がある、といった課題がある。   Conventionally, many techniques for improving the surface gloss of a ferritic stainless steel cold-rolled steel strip have been disclosed. In cold rolling, every roll or every 2 or 3 passes, the roll is rolled from a roll with a large surface roughness to a roll with a small surface roughness in order, and the roll is cold rolled with excellent surface gloss. A method of building steel strip has been implemented. However, in this case, there are problems that the number of times of exchanging the work rolls increases and it is necessary to prepare several kinds of work rolls having different surface roughness for each pass.

例えば、特許文献1には、冷間圧延に際し、1パス目はRa=0.4〜1.6μmのワークロールを用いて圧延し、2パス目以降はRa=0.01〜0.06μmのワークロールを用いて圧延する高光沢ステンレス冷延鋼板の製造方法が開示されている。   For example, in Patent Document 1, in cold rolling, the first pass is rolled using a work roll of Ra = 0.4 to 1.6 μm, and the second and subsequent passes are Ra = 0.01 to 0.06 μm. A method for producing a high-gloss stainless steel cold-rolled steel sheet that is rolled using a work roll is disclosed.

特許文献2には、表面粗さRaが0.5μm以上3.0μm以下のワークロールを使用して圧延した後、表面粗さRaが0.18μm以下のワークロールを使用して圧下率20%以上の圧延をし、さらに表面粗さRaが0.18μm以下のワークロールを用いて圧下率8%以上20%未満の圧延を行う、表面性状の優れた冷間圧延ステンレス鋼板の製造方法が開示されている。   In Patent Document 2, after rolling using a work roll having a surface roughness Ra of 0.5 μm or more and 3.0 μm or less, using a work roll having a surface roughness Ra of 0.18 μm or less, the rolling reduction is 20%. Disclosed is a method for producing a cold-rolled stainless steel sheet having excellent surface properties, which is rolled as described above and further rolled at a reduction rate of 8% to less than 20% using a work roll having a surface roughness Ra of 0.18 μm or less. Has been.

また、特許文献3には、光輝焼鈍を行って仕上げるフェライト系ステンレス鋼板の製造方法において、最終前パスにおいて平均表面粗度が0.030μm以下の圧延ロールを使用して15%以上の圧下率で圧延した後、さらに最終パスで平均表面粗度が0.020μm以下の圧延ロールを使用して10%以上の圧下率で仕上げ、光輝焼鈍後の調質圧延においても平均表面粗度が0.010μm以下の圧延ロールを使用する、光沢に優れたフェライト系ステンレス鋼板の製造方法が開示されている。   Further, in Patent Document 3, in a method for producing a ferritic stainless steel plate that is finished by performing bright annealing, a rolling roll having an average surface roughness of 0.030 μm or less is used at a rolling reduction of 15% or more in the final pass. After rolling, finish with a rolling roll having an average surface roughness of 0.020 μm or less in the final pass at a reduction rate of 10% or more, and even in temper rolling after bright annealing, the average surface roughness is 0.010 μm. The manufacturing method of the ferritic stainless steel plate excellent in the glossiness which uses the following rolling rolls is disclosed.

また、特許文献4には、調質圧延時に、調質圧延ロール表面にCrめっきを施した後、ロール幅方向の平均粗さRaが0.003μm以上0.010μm以下に研磨したロールを用いる表面光沢に優れたフェライト系ステンレス冷延鋼帯の製造方法が開示されている。特許文献5には、熱延鋼帯をグラインダーで表面研削することにより熱延鋼帯の表面粗さを規定し、帯状の光沢ムラを低減するステンレス冷延鋼板の製造方法が開示されている。   Patent Document 4 discloses a surface that uses a roll that is subjected to Cr plating on the surface of the temper rolling roll during temper rolling and then polished to an average roughness Ra in the roll width direction of 0.003 μm or more and 0.010 μm or less. A method for producing a ferritic stainless steel cold-rolled steel strip excellent in gloss is disclosed. Patent Document 5 discloses a method for producing a stainless cold-rolled steel sheet that regulates the surface roughness of a hot-rolled steel strip by grinding the surface of the hot-rolled steel strip with a grinder to reduce uneven glossiness of the strip.

特許第2642571号公報Japanese Patent No. 2642571 特公昭64−3561号公報Japanese Patent Publication No. 64-3561 特許第3241495号公報Japanese Patent No. 3241495 特開2011−110594号公報JP 2011-110594 A 特開2002−239604号公報JP 2002-239604 A

特許文献1に開示された方法では、高光沢の表面が得られるものの、鋼帯の幅方向に帯状の光沢ムラが生じる場合があり、歩留りが低下する場合があった。特許文献2に開示された方法は、ヒートストリークを予め発生させた鋼帯を後で平滑化する技術に関するものであるが、ヒートストリークは光沢ムラの原因となり、帯状の光沢ムラが発生する上、製造された鋼帯表面は光沢度には優れるが白濁欠陥が散在する場合があった。特許文献3および4に開示された方法は、表面粗さが非常に小さいロールを用いて表面光沢を造り込む技術であるが、通常の円筒研磨では0.030μmRa未満のロール粗度を造り込むことは不可能であり、特殊な研磨技術やCrめっきを必要とし、コストが高く、工業的な運用が困難である。特許文献5に開示された方法は、冷延鋼板の製造コストが高くなることとグラインダー設備を用いるため冷延鋼板の生産性が低く処理能力に限界があるという問題があった。   In the method disclosed in Patent Document 1, although a highly glossy surface is obtained, band-like gloss unevenness may occur in the width direction of the steel band, and the yield may be reduced. The method disclosed in Patent Document 2 relates to a technique for smoothing a steel strip in which heat streaks have been generated in advance, but heat streaks cause gloss unevenness, and strip-shaped gloss unevenness occurs. The surface of the manufactured steel strip was excellent in glossiness but sometimes had cloudy defects. The methods disclosed in Patent Documents 3 and 4 are techniques for creating surface gloss using a roll having a very small surface roughness. However, in general cylindrical polishing, a roll roughness of less than 0.030 μmRa is created. Is impossible, requires special polishing technology and Cr plating, is expensive, and is difficult to industrially operate. The method disclosed in Patent Document 5 has a problem that the manufacturing cost of the cold-rolled steel sheet is high and the productivity of the cold-rolled steel sheet is low because of using a grinder equipment, and the processing capacity is limited.

従来は、表面光沢を造り込むためには、表面粗さの小さいロール表面を鋼帯表面に転写させることが有利であり、その思想に基づいた様々な技術が提示されてきたが、一方で、光沢を向上させるほどより顕著になる光沢ムラとの両立が困難だった。また、光沢ムラを抑制するにはコストをかけて鋼帯の全長・全幅を均一に研削するなど、製造上の負荷が高い方法しか提示されてこなかった。   Conventionally, in order to build surface gloss, it is advantageous to transfer a roll surface having a small surface roughness to the surface of the steel strip, and various techniques based on the idea have been presented. It was difficult to achieve a balance with gloss unevenness that became more noticeable as the gloss was improved. In addition, in order to suppress uneven glossiness, only methods with high manufacturing load have been presented, such as grinding the entire length and width of the steel strip uniformly at a high cost.

本発明は、上記のような課題を解決するものであり、表面光沢に優れ、かつ、光沢ムラが抑制されたフェライト系ステンレス冷延鋼帯の製造方法を提供することを目的とする。   This invention solves the above subjects, and it aims at providing the manufacturing method of the ferritic stainless steel cold-rolled steel strip excellent in surface glossiness, and the gloss nonuniformity being suppressed.

本発明は、以下の構成を備える。
[1]酸洗後のフェライト系ステンレス熱延鋼帯に対して、最終パス以外のパスでは、ロール径が40mm以上150mm以下、表面の算術平均粗さRaが0.20μm以上0.45μm以下のワークロールを用いて圧延し、最終パスでは、ロール径が40mm以上150mm以下、表面の算術平均粗さRaが0.03μm以上0.15μm以下のワークロールを用いて圧延する冷間圧延を施し、焼鈍を施した後、伸び率0.3〜2.0%の調質圧延を施すことを特徴とするフェライト系ステンレス冷延鋼帯の製造方法。
The present invention has the following configuration.
[1] For ferritic stainless hot rolled steel strip after pickling, in a pass other than the final pass, the roll diameter is 40 mm or more and 150 mm or less, and the arithmetic average roughness Ra of the surface is 0.20 μm or more and 0.45 μm or less. Rolled using a work roll, and in the final pass, the roll diameter is 40 mm or more and 150 mm or less, and the surface arithmetic average roughness Ra is cold rolled using a work roll of 0.03 μm or more and 0.15 μm or less, A method for producing a ferritic stainless steel cold-rolled steel strip, characterized by performing temper rolling with an elongation of 0.3 to 2.0% after annealing.

本発明によれば、表面光沢に優れ、かつ、光沢ムラが抑制されたフェライト系ステンレス冷延鋼帯を製造することができる。   According to the present invention, it is possible to manufacture a ferritic stainless steel cold-rolled steel strip that is excellent in surface gloss and that suppresses uneven gloss.

本発明によれば、例えば酸洗前にショットブラスト処理が施され、深い凹みを有するような熱延鋼帯を被圧延材として冷間圧延した場合であっても、表面光沢に優れ、かつ、光沢ムラが抑制されたフェライト系ステンレス冷延鋼帯を製造しやすくなる。そのため、本発明によれば、より生産性高く、より低コストで、表面光沢に優れ、かつ、光沢ムラが抑制されたフェライト系ステンレス冷延鋼帯を製造することができる。   According to the present invention, for example, shot blasting is performed before pickling, and even when a hot-rolled steel strip having a deep dent is cold-rolled as a material to be rolled, the surface gloss is excellent, and It becomes easy to manufacture a ferritic stainless steel cold-rolled steel strip in which uneven gloss is suppressed. Therefore, according to the present invention, it is possible to produce a ferritic stainless steel cold-rolled steel strip with higher productivity, lower cost, excellent surface gloss, and suppressed gloss unevenness.

以下に、本発明の詳細について説明する。   Details of the present invention will be described below.

本発明者らは、光沢不良の発生状況を調査し、その発生メカニズムを考察し、改善方法を鋭意検討した結果、本発明を完成させるに至った。   As a result of investigating the occurrence of gloss failure, considering the generation mechanism, and intensively studying the improvement method, the present inventors have completed the present invention.

まず、光沢ムラの発生状況を調査した結果、光沢ムラは、
(i)冷間圧延工程の前半の圧延パスで発生する割合が高い、
(ii)冷間圧延工程での圧延速度が高速の場合に発生しやすい、
ことを見出した。
First, as a result of investigating the occurrence of uneven gloss,
(I) A high ratio is generated in the first rolling pass of the cold rolling process.
(Ii) likely to occur when the rolling speed in the cold rolling process is high;
I found out.

さらに、本発明者らは、光沢ムラが発生した冷延鋼帯を詳細に観察し、光沢ムラが生じる原因を調査した。その結果、光沢ムラが生じた部分では、他の部分(正常部)と比較して、オイルピット量(オイルピット数)に差があることがわかった。ここで、オイルピットとは、冷間圧延の際に被圧延材である熱延鋼帯の表面の凹みに圧延油が封入され、冷間圧延工程後においても、鋼帯表面の凹みに圧延油が封入された状態のまま残存する凹みである。フェライト系ステンレス熱延鋼帯は、脱スケールが難しいため、酸洗前に、鋼帯表面に対してショットブラストを実施することが常法であり、冷間圧延前の鋼帯表面にはショットブラスト痕である深さ1μmを超える凹みが存在する。これが起点となり、冷間圧延中にオイルピットが生成する。   Furthermore, the present inventors have observed in detail the cold-rolled steel strip in which the uneven gloss has occurred, and investigated the cause of the uneven gloss. As a result, it was found that there was a difference in the amount of oil pits (number of oil pits) in the portion where the uneven gloss occurred compared to the other portion (normal portion). Here, the oil pit means that rolling oil is enclosed in a dent on the surface of a hot-rolled steel strip that is a material to be rolled during cold rolling, and the rolling oil remains in the dent on the surface of the steel strip even after the cold rolling process. Is a dent remaining in the sealed state. Ferritic stainless steel hot-rolled steel strips are difficult to descal, so it is common practice to perform shot blasting on the steel strip surface before pickling, and shot blasting is applied to the steel strip surface before cold rolling. There is a dent exceeding a depth of 1 μm which is a mark. This is the starting point, and oil pits are generated during cold rolling.

次に、冷間圧延の前半パス、および、高速圧延時に光沢ムラが発生するメカニズムを考察した。すなわち、冷間圧延工程の初期段階である前半パスでは、熱延鋼帯(被圧延材)表面の凹みが多く、また、鋼帯の幅方向に表面性状(凹凸)のバラツキもあるため、冷間圧延後に残存するオイルピット量が多くなり、光沢ムラが発生しやすくなると考えた。一方、圧延速度については、高速圧延になるほど、ロールバイトへの圧延油の引き込み量が増すために、熱延鋼帯表面の凹みに圧延油が封入されやすく、オイルピットが生成しやすい。そして、生成したオイルピットに圧延を施しても表面の凹みは低減されにくい。このため、冷間圧延後に残存するオイルピットが多くなり、光沢ムラとして顕在化しやすいと考えた。つまり、冷間圧延時に発生するオイルピットを低減できれば、光沢ムラが生じ難くなると考えた。   Next, the first half pass of cold rolling and the mechanism of occurrence of gloss unevenness during high speed rolling were considered. That is, in the first half pass, which is the initial stage of the cold rolling process, there are many dents on the surface of the hot-rolled steel strip (rolled material), and there are also variations in surface properties (unevenness) in the width direction of the steel strip. The amount of oil pits remaining after hot rolling increased and gloss unevenness was likely to occur. On the other hand, as the rolling speed is increased, the amount of rolling oil drawn into the roll bite increases as the rolling speed increases, so that the rolling oil is easily enclosed in the recesses on the surface of the hot-rolled steel strip, and oil pits are easily generated. And even if it rolls to the produced | generated oil pit, the dent of a surface is hard to be reduced. For this reason, oil pits remaining after cold rolling increased, and it was considered that gloss unevenness was likely to be manifested. That is, if the oil pit generated during cold rolling can be reduced, it is considered that gloss unevenness is less likely to occur.

オイルピットの低減方法として、従来はロールバイトへの圧延油の引き込み油量を低減する対策が講じられるのが一般的だった。そして、そのためには、例えば、圧延速度を下げたり、圧延油の粘度をより低粘度にしたりすることが有効とされてきた。しかし、本発明では、例えばショットブラスト痕に起因するような、深さ1μmを超えるオイルピットをより効果的に除去(消去)する方法について検討した結果、以下の知見を得た。   As a method for reducing the oil pit, conventionally, a measure for reducing the amount of rolling oil drawn into the roll bite has been generally taken. For this purpose, for example, it has been effective to reduce the rolling speed or to lower the viscosity of the rolling oil. However, in the present invention, as a result of examining a method for more effectively removing (erasing) an oil pit exceeding a depth of 1 μm, for example, caused by shot blast marks, the following knowledge was obtained.

すなわち、オイルピットは、鋼帯表面の凹み部に圧延油が封入されることによって生じる。そこで、圧延油が封入されたまま残存しないよう、凹み部から圧延油が流出するための流出口となる疵をつけ、この疵から圧延油を流出させることで少ない圧延回数でも効果的に深いオイルピットを除去することを検討した。その結果、その疵をつける方法として圧延ロールの研磨目の転写痕を利用することが有効であることを見出した。   That is, the oil pit is generated when the rolling oil is sealed in the recess on the surface of the steel strip. Therefore, in order to prevent the rolling oil from remaining encapsulated, a ridge is provided as an outlet for the rolling oil to flow out of the recess, and the rolling oil is allowed to flow out of this ridge to effectively deepen the oil even with a small number of rolling operations. We considered removing the pits. As a result, it has been found that it is effective to use the transfer marks on the rolling rolls as a method for forming the wrinkles.

従来の考えでは、高光沢の冷延鋼帯を製造するためには表面粗さの小さいワークロールで冷間圧延することが有効とされてきた。しかし、本発明によれば、冷間圧延後に残存するオイルピットを低減し、高光沢で、かつ、光沢ムラが抑制された冷延鋼帯を製造するために、あえて表面粗さの大きいワークロールを用い、これと表面粗さの小さいワークロールを組み合わせて用いることが有効であることが明らかとなった。   Conventionally, cold rolling with a work roll having a small surface roughness has been effective for producing a high-gloss cold-rolled steel strip. However, according to the present invention, a work roll having a large surface roughness is intentionally produced in order to reduce the oil pits remaining after cold rolling, and to produce a cold rolled steel strip having high gloss and suppressed gloss unevenness. It was revealed that it was effective to use this in combination with a work roll having a small surface roughness.

さらに冷間圧延工程における各圧延パスでのワークロールのロール径と表面粗さについて鋭意検討し、最適な範囲を以下のように決定した。   Furthermore, the roll diameter and surface roughness of the work roll in each rolling pass in the cold rolling process were intensively studied, and the optimum range was determined as follows.

まず、ワークロールのロール径の限定理由を述べる。高光沢の製品を得るためには、ワークロールのロール径は小さいほど望ましい。しかし、ロール径が小さくなりすぎると、ロールの耐久性が悪くなる。そのため、ロール径の範囲(直径)は、40〜150mmの範囲とした。40mm未満のロール径では耐久性が低く、ロール表面の脱落(スポーリング)などのトラブルが起きやすい上、転動回数が多くなりロールの摩耗が顕著となる。ロール径が150mmを超えると、ロールバイトへの圧延油の引き込み量の増加を招いて光沢が劣化する。なお、圧延方法は、ゼンジミアミルまたはクラスターミルのようなリバース式の圧延でもタンデムミルに代表される一方向への圧延でも構わない。   First, the reason for limiting the roll diameter of the work roll will be described. In order to obtain a product with high gloss, the roll diameter of the work roll is preferably as small as possible. However, when the roll diameter is too small, the durability of the roll is deteriorated. Therefore, the range (diameter) of the roll diameter was set to a range of 40 to 150 mm. When the roll diameter is less than 40 mm, the durability is low, and troubles such as falling off of the roll surface (spoling) are likely to occur, and the number of rolling is increased and the wear of the roll becomes remarkable. When the roll diameter exceeds 150 mm, the amount of rolling oil drawn into the roll bite increases and the gloss deteriorates. The rolling method may be reverse rolling such as Sendzimir mill or cluster mill or unidirectional rolling represented by tandem mill.

つぎに、各圧延パスにおけるワークロールの表面粗さの限定理由について述べる。本発明では、表面粗さの大きいワークロールと、表面粗さの小さいワークロールを組み合わせて用いる。さらに各圧延パスにおける上記2種の表面粗さのワークロールの運用に関しては以下のように行う。   Next, the reason for limiting the surface roughness of the work roll in each rolling pass will be described. In the present invention, a work roll having a large surface roughness and a work roll having a small surface roughness are used in combination. Further, the operation of the two types of surface roughness work rolls in each rolling pass is performed as follows.

まず、表面粗さの大きいワークロール(以後、高粗度ロールと称する場合がある)を、光沢ムラ防止のために冷間圧延の1パス目で用いる。高粗度ロールを冷間圧延の1パス目で用いることによって、光沢ムラの発生率が顕著に下がる。一方、冷間圧延の1パス目を、表面粗さの小さいロールで圧延してしまうと、光沢ムラが発生してしまい、後のパスで光沢ムラを除去することが困難となる。   First, a work roll having a large surface roughness (hereinafter sometimes referred to as a high roughness roll) is used in the first pass of cold rolling to prevent uneven gloss. By using a high roughness roll in the first pass of cold rolling, the occurrence rate of uneven glossiness is significantly reduced. On the other hand, if the first pass of the cold rolling is rolled with a roll having a small surface roughness, gloss unevenness occurs, and it becomes difficult to remove the gloss unevenness in a later pass.

上記高粗度ロールの表面粗さ(算術平均粗さRa)は、0.20μmRa以上0.45μmRa以下とする。高粗度ロールの表面粗さが前記範囲であることでオイルピットを効果的に除去することができる。高粗度ロールの表面粗さが0.20μmRa未満であると、研磨目の転写痕は浅く、塑性変形によって油を凹み部から押し出す前に転写痕が消えてしまう。この結果、光沢ムラの改善ができない。また、高粗度ロールの表面粗さが0.45μmRaより大きいと、十分な転写痕はつくが、転写痕が強すぎて鋼帯表面の凹凸を後の圧延パスで消すことができず、光沢が悪化する。高粗度ロールの表面粗さは、より好ましくは0.25μmRa以上0.35μmRa以下である。   The surface roughness (arithmetic average roughness Ra) of the high roughness roll is 0.20 μmRa or more and 0.45 μmRa or less. Oil pits can be effectively removed when the surface roughness of the high roughness roll is within the above range. If the surface roughness of the high-roughness roll is less than 0.20 μmRa, the transfer marks on the polishing marks are shallow, and the transfer marks disappear before the oil is pushed out of the recess due to plastic deformation. As a result, gloss unevenness cannot be improved. Also, if the surface roughness of the high roughness roll is larger than 0.45 μmRa, a sufficient transfer mark is formed, but the transfer mark is too strong and the unevenness on the surface of the steel strip cannot be erased by a subsequent rolling pass, resulting in gloss. Gets worse. The surface roughness of the high roughness roll is more preferably 0.25 μmRa or more and 0.35 μmRa or less.

次に、表面粗さの小さいロール(以後、低粗度ロールと称する場合がある)を、光沢向上のため冷間圧延の最終パスで用いる。低粗度ロールを冷間圧延の最終パスで用いることにより、高粗度ロールの転写痕が消えて光沢が向上する。最終パス手前で低粗度ロールを用いても、最終パスで低粗度ロールよりも表面粗さの大きいロールを用いてしまうと、ロールの転写痕が残存して光沢が悪化する。   Next, a roll having a small surface roughness (hereinafter sometimes referred to as a low roughness roll) is used in the final pass of cold rolling to improve gloss. By using the low roughness roll in the final pass of the cold rolling, the transfer marks of the high roughness roll disappear and the gloss is improved. Even if a low roughness roll is used before the final pass, if a roll having a surface roughness larger than that of the low roughness roll is used in the final pass, the transfer marks of the roll remain and the gloss deteriorates.

上記低粗度ロールの表面粗さ(算術平均粗さRa)は、0.03μmRa以上0.15μmRa以下とする。低粗度ロールの表面粗さを0.03μmRaより小さく仕上げるには、表面にめっき加工を施したり、特殊な研磨技術を要したりするため、冷間圧延ロールに用いることは工業的に生産するラインでは非現実的である。また、低粗度ロールの表面粗さが0.15μmRaを超えると、冷間圧延工程の前半パスで表面粗さの粗いワークロールで付与した転写痕と同等レベルの転写痕を付与してしまい、光沢向上が見込めない。研磨負荷や最終製品の光沢の観点から、低粗度ロールの表面粗さは、より好ましくは0.05μmRa以上0.12μmRa以下である。   The surface roughness (arithmetic average roughness Ra) of the low roughness roll is 0.03 μmRa or more and 0.15 μmRa or less. In order to finish the surface roughness of the low-roughness roll to be smaller than 0.03 μmRa, the surface is plated or requires a special polishing technique, so that it is industrially produced for use in a cold rolling roll. It is unrealistic on the line. Further, if the surface roughness of the low roughness roll exceeds 0.15 μmRa, it gives a transfer mark of the same level as the transfer mark given by the work roll having a rough surface roughness in the first half pass of the cold rolling process, I cannot expect the gloss improvement. From the viewpoint of polishing load and gloss of the final product, the surface roughness of the low roughness roll is more preferably 0.05 μmRa or more and 0.12 μmRa or less.

さらに、3パス以上の圧延を行う場合には、最終パス以外のパスは高粗度ロールで圧延する。高粗度ロールで最初のパスを圧延した後、2パス目以降最終手前パスで低粗度ロールを用いると、平滑化した板面をさらに圧延することになり、鋼帯表面へ圧延油が偶発的に封入される新たなオイルピットの生成が助長される。そのため、低粗度ロールは最終1パスのみの使用にとどめ、それより前のパスは高粗度ロールで圧延する。   Furthermore, when rolling 3 passes or more, passes other than the final pass are rolled with a high roughness roll. After rolling the first pass with a high roughness roll, if the low roughness roll is used in the second and subsequent passes, the smoothened plate surface will be further rolled, and rolling oil will accidentally occur on the surface of the steel strip. The creation of a new oil pit to be sealed is encouraged. Therefore, the low-roughness roll is used only for the final pass, and the previous passes are rolled with a high-roughness roll.

なお、冷間圧延の1パス目から最終手前パスに使用する高粗度ロールの表面粗さは0.20μmRa以上0.45μmRa以下であればよい。すなわち、前記表面粗さの範囲を満たす高粗度ロールを用いる限り、1パス目から最終手前パスまでの間で、前後のパスに使用する高粗度ロールの表面粗さの大小を考慮する必要はない。   The surface roughness of the high-roughness roll used from the first pass of cold rolling to the final front pass may be 0.20 μmRa or more and 0.45 μmRa or less. That is, as long as a high-roughness roll satisfying the surface roughness range is used, it is necessary to consider the surface roughness of the high-roughness roll used for the front and rear passes between the first pass and the final pass. There is no.

また、本発明において、表面粗さは、JIS B 0601−2001に規定される算術平均粗さ(Ra)を意味する。また、本発明においてロールの表面粗さは、ロール軸方向の表面粗さを意味する。   Moreover, in this invention, surface roughness means the arithmetic mean roughness (Ra) prescribed | regulated to JISB0601-2001. In the present invention, the surface roughness of the roll means the surface roughness in the roll axial direction.

なお、高粗度ロールおよび低粗度ロールの表面粗さを造り込む上では、研磨方向、加工法は、特に限定しない。例えば周方向研磨、ダルロールであっても同様の効果が得られるものである。しかし、一方で、摩耗性やロール研磨負荷、焼付きの発生を考慮すると、工業的に最も有効なのは円筒方向への研磨仕上げである。   Note that the polishing direction and the processing method are not particularly limited in building the surface roughness of the high roughness roll and the low roughness roll. For example, the same effect can be obtained even with circumferential polishing and dull roll. However, on the other hand, considering the wearability, roll polishing load, and occurrence of seizure, the most industrially effective polishing finish is in the cylindrical direction.

また、圧延時の速度については格段限定せずとも一定の効果が得られ、生産性の許す範囲で速度を制御すれば良い。   Further, the rolling speed is not particularly limited, and a certain effect can be obtained, and the speed may be controlled within the range allowed by productivity.

また、冷間圧延に用いる圧延油は、特に限定されず、エマルション、ニート油などから任意に選択できる。また、基油も限定されず、鉱油、エステル油、水溶性ポリマーなどから任意に選択できる。しかし、高光沢および光沢ムラの解消というニーズに対しては、低粘度ニート油が最も引き込み油量を低減しやすく、引き込み量のロール幅方向ムラも生じにくいことから推奨される。なお、低粘度ニート油の粘度(50℃における動粘度)としては、4〜20mm/sが好ましい。 Moreover, the rolling oil used for cold rolling is not specifically limited, It can select arbitrarily from an emulsion, neat oil, etc. Further, the base oil is not limited and can be arbitrarily selected from mineral oil, ester oil, water-soluble polymer and the like. However, for the need to eliminate high gloss and gloss unevenness, low-viscosity neat oil is recommended because it is the easiest to reduce the amount of oil drawn, and unevenness in the roll width direction of the pull-in amount is recommended. In addition, as a viscosity (kinematic viscosity in 50 degreeC) of low-viscosity neat oil, 4-20 mm < 2 > / s is preferable.

上記冷間圧延を施した後、さらに焼鈍を施し、調質圧延を施してフェライト系ステンレス冷延鋼帯を製造する。   After the cold rolling, annealing is further performed and temper rolling is performed to produce a ferritic stainless steel cold rolled steel strip.

一例として、上記冷間圧延では板厚0.5〜2.0mmになるように冷間圧延を行った後、700〜1100℃の温度で焼鈍(冷延板焼鈍)を行う。そして、焼鈍後に、伸び率0.3〜2.0%の調質圧延を施してフェライト系ステンレス冷延鋼帯を製造する。前記伸び率の範囲の調質圧延を施すことで、より表面光沢に優れるフェライト系ステンレス冷延鋼帯を製造することができる。伸び率が0.3%未満では優れた表面光沢が得られず、伸び率が2.0%を超えるとヒートスクラッチが発生しやすくなる。   As an example, after performing cold rolling so that the sheet thickness is 0.5 to 2.0 mm in the cold rolling, annealing (cold rolling sheet annealing) is performed at a temperature of 700 to 1100 ° C. And after annealing, temper rolling with an elongation of 0.3 to 2.0% is performed to produce a ferritic stainless steel cold-rolled steel strip. By performing temper rolling in the range of the elongation rate, a ferritic stainless steel cold-rolled steel strip having more excellent surface gloss can be produced. If the elongation is less than 0.3%, excellent surface gloss cannot be obtained, and if the elongation exceeds 2.0%, heat scratches are likely to occur.

また、前記調質圧延では、ロール径(直径)400mm以上1000mm以下のロールを用いて、1パス以上の圧延を施すことが好ましい。また、上記焼鈍後、調質圧延前に、必要に応じて酸洗を行ってもよい。好ましくは、酸化性雰囲気で焼鈍を行った場合は酸洗を行い、還元性雰囲気での焼鈍(光輝焼鈍)を行った場合は酸洗を行わずそのまま調質圧延を行う。   Further, in the temper rolling, it is preferable to perform rolling of one pass or more using a roll having a roll diameter (diameter) of 400 mm or more and 1000 mm or less. Moreover, you may perform pickling as needed before the temper rolling after the said annealing. Preferably, when annealing is performed in an oxidizing atmosphere, pickling is performed, and when annealing in a reducing atmosphere (bright annealing) is performed, temper rolling is performed without performing pickling.

また、本発明の製造方法が適用される鋼種は、特に限定されない。前記鋼種としては、例えば日本工業規格JIS G 4305に規定されたSUS410L、SUS430、SUS430LX、SUS430J1L、SUS434、SUS436L、SUS436J1L、SUS436J1L、SUS443J1、SUS444、SUS445J1、SUS445J2等が挙げられる。   Moreover, the steel type to which the production method of the present invention is applied is not particularly limited. Examples of the steel types include SUS410L, SUS430, SUS430LX, SUS430J1L, SUS434, SUS436L, SUS436J1L, SUS436J1L, SUS443J1, SUS444, SUS445J2, and SUS445J2 defined in Japanese Industrial Standard JIS G 4305.

また、本発明の冷間圧延を施す被圧延材(フェライト系ステンレス熱延鋼帯)の製造方法も、特に限定されない。一例として、所定の成分組成を有する鋼スラブを1100〜1300℃に加熱後、仕上温度を700〜1100℃、巻取温度を400〜850℃として板厚2.0〜5.0mmになるように熱間圧延を施した後、酸洗して製造する。前記熱間圧延の後に、800〜1100℃の温度で焼鈍(熱延板焼鈍)を行ってもよい。また、前記酸洗の前に、ショットブラストを施してもよい。本発明の製造方法によれば、ショットブラストによる深い凹み部に起因するオイルピットも除去することができる。   Moreover, the manufacturing method of the to-be-rolled material (ferritic stainless steel hot-rolled steel strip) which performs the cold rolling of this invention is not specifically limited. As an example, after heating a steel slab having a predetermined composition to 1100 to 1300 ° C., the finishing temperature is 700 to 1100 ° C., the winding temperature is 400 to 850 ° C., and the plate thickness is 2.0 to 5.0 mm. After hot rolling, it is pickled and manufactured. After the hot rolling, annealing (hot rolled sheet annealing) may be performed at a temperature of 800 to 1100 ° C. Further, shot blasting may be performed before the pickling. According to the manufacturing method of the present invention, oil pits caused by deep dents by shot blasting can also be removed.

また、本発明の製造方法を実施するフェライト系ステンレス冷延鋼帯の製造設備は、ロール径が40mm以上150mm以下、表面の算術平均粗さRaが0.20μm以上0.45μm以下の高粗度のワークロールと、ロール径が40mm以上150mm以下、表面の算術平均粗さRaが0.03μm以上0.15μm以下の低粗度のワークロールを有し、最終パス以外のパスを前記高粗度のワークロールで圧延し、最終パスを前記低粗度のワークロールで圧延する冷間圧延機と、前記冷間圧延機で圧延された冷延鋼帯に、伸び率0.3〜2.0%の調質圧延を施す調質圧延機と、を備える。前記冷間圧延機は、リバース圧延機でもタンデム圧延機でもよい。リバース圧延機の場合には、1パス目から最終パス手前までのパスを高粗度のワークロールで圧延した後、ワークロールを交換して、最終パスを低粗度のワークロールで圧延すればよい。
また、鋼帯の搬送方向で、前記冷間圧延機と調質圧延機との間には、焼鈍装置が設けられてもよい。さらに前記焼鈍装置の下流に、酸洗装置が設けられてもよい。
In addition, the ferritic stainless steel cold-rolled steel strip manufacturing equipment for carrying out the manufacturing method of the present invention has a high roughness with a roll diameter of 40 mm to 150 mm and an arithmetic average roughness Ra of 0.20 μm to 0.45 μm. A work roll having a low roughness with a roll diameter of 40 mm or more and 150 mm or less, and an arithmetic average roughness Ra of 0.03 μm or more and 0.15 μm or less on the surface. A cold rolling mill that rolls with a work roll having a low roughness, and a cold rolled steel strip that has been rolled with the cold rolling mill. And a temper rolling mill for performing temper rolling at a%. The cold rolling mill may be a reverse rolling mill or a tandem rolling mill. In the case of a reverse rolling mill, after rolling the first pass to the last pass with a high-roughness work roll, replacing the work roll and rolling the final pass with a low-roughness work roll Good.
Moreover, an annealing apparatus may be provided between the cold rolling mill and the temper rolling mill in the conveying direction of the steel strip. Furthermore, a pickling apparatus may be provided downstream of the annealing apparatus.

以下、本発明の実施例について述べる。ただし、本発明は、以下の実施例に限定されない。   Examples of the present invention will be described below. However, the present invention is not limited to the following examples.

日本工業規格JIS G 4305に規定されたSUS430鋼(本実施例で用いた鋼の成分組成(質量%)は、C:0.03〜0.05%、Si:0.2〜0.5%、Mn:0.4〜0.7%、P:0.02〜0.04%、Cr:16.0〜16.7%、N:0.04〜0.05%)を、転炉で溶製し、さらにVODで脱炭処理を施した。得られた溶鋼を連続鋳造法によってスラブとした。続いて、質量12〜18tのスラブを1150℃で1時間加熱し、900〜1100℃の仕上げ温度で熱間圧延して板厚3.0mmt、幅980〜1020mmwのフェライト系ステンレス熱延鋼帯を製造した。製造した熱延鋼帯はバッチ炉で830℃で8時間の熱延板焼鈍を行った後、ショットブラストを行い、酸洗(脱スケール)を実施した。前記酸洗は、最初に硫酸で酸洗を行い、次に硝酸とフッ酸の混酸で酸洗を行った。   SUS430 steel defined in Japanese Industrial Standard JIS G 4305 (component composition (mass%) of steel used in this example is C: 0.03-0.05%, Si: 0.2-0.5%, Mn: 0.4-0.7%, P: 0.02 to 0.04%, Cr: 16.0 to 16.7%, N: 0.04 to 0.05%) were melted in a converter and further decarburized with VOD. The obtained molten steel was made into a slab by a continuous casting method. Subsequently, a slab having a mass of 12 to 18 t was heated at 1150 ° C. for 1 hour and hot-rolled at a finishing temperature of 900 to 1100 ° C. to obtain a ferritic stainless hot rolled steel strip having a thickness of 3.0 mmt and a width of 980 to 1020 mmw. Manufactured. The manufactured hot-rolled steel strip was subjected to hot-rolled sheet annealing at 830 ° C. for 8 hours in a batch furnace, then shot blasted and pickled (descaled). The pickling was first pickled with sulfuric acid and then pickled with a mixed acid of nitric acid and hydrofluoric acid.

上記のようにして酸洗まで実施した熱延鋼帯に対して、12段式のクラスター型リバース圧延機にて冷間圧延を施した。冷間圧延は、ロール径(直径)90〜110mmの冷間ダイス鋼ワークロールを用い、40℃以上60℃以下に管理された鉱油(50℃での動粘度:8cSt)をロールと供試材(熱延鋼帯)に循環供給しながら行った。   The hot-rolled steel strip that had been subjected to pickling as described above was cold-rolled with a 12-stage cluster type reverse rolling mill. Cold rolling uses a cold die steel work roll having a roll diameter (diameter) of 90 to 110 mm, and a mineral oil (kinematic viscosity at 50 ° C .: 8 cSt) controlled to 40 ° C. or more and 60 ° C. or less and a test material. (Hot rolled steel strip) was performed while being circulated.

その際、冷間圧延の各パスにおけるワークロールの表面粗さ(算術平均粗さRa)を、表1に示すように変更して、0.8mmtのコイルを10コイルずつ製造した。なお、本実施例で冷間圧延に用いたワークロールは、いずれも円周方向に沿う研磨仕上げで表面粗さを調整したものである。また、表1に示すワークロールの表面粗さは、鋼帯に対して各パスでの圧延を施す前に測定したものである。同じワークロールを2パス以上続けて使用した場合も、各パスでの圧延を施す前に、毎回ワークロールの表面粗さを測定した。圧延速度は、1パス目は供試材の板厚が厚く形状が不安定なため80〜100mpmで圧延を行い、2パス目以降は最高速度を250mpmとして圧延を行った。   At that time, the surface roughness (arithmetic mean roughness Ra) of the work roll in each cold rolling pass was changed as shown in Table 1, and 10 0.8 mmt coils were manufactured. In addition, as for the work roll used for the cold rolling in a present Example, all surface roughness was adjusted by the grinding | polishing finishing along the circumferential direction. Moreover, the surface roughness of the work roll shown in Table 1 is measured before rolling the steel strip in each pass. Even when the same work roll was continuously used for two or more passes, the surface roughness of the work roll was measured every time before rolling in each pass. In the first pass, rolling was performed at 80 to 100 mpm because the plate thickness of the specimen was thick and the shape was unstable in the first pass, and rolling was performed at a maximum speed of 250 mpm after the second pass.

冷間圧延後の鋼帯は、4〜7vol%の酸素濃度下で830℃で5分間の焼鈍(冷延板焼鈍)を実施した後、中性塩電解酸洗および硝酸電解酸洗を実施して脱スケールを行った。最後にロール径700mmの2スタンド調質圧延機にて伸び率0.8〜1.2%の範囲で、無潤滑で調質圧延を施して、10コイルずつのフェライト系ステンレス冷延鋼帯を製造した。   The steel strip after cold rolling is annealed at 830 ° C. for 5 minutes under an oxygen concentration of 4-7 vol% (cold rolled plate annealing), and then subjected to neutral salt electrolytic pickling and nitric acid electrolytic pickling. And descaling. Finally, temper rolling is performed without lubrication in a 2-stand temper rolling mill with a roll diameter of 700 mm in an elongation range of 0.8 to 1.2%, and ferritic stainless cold-rolled steel strips of 10 coils each are formed. Manufactured.

<表面光沢の評価>
調質圧延後のフェライト系ステンレス冷延鋼帯(コイル)の、先端部(最先端から5mの位置)、中央部、尾端部(最後端から5mの位置)の長手3箇所から、サンプル(約幅1000mm×長手方向長さ300mm)を採取し、前記各サンプルの幅方向中央部の位置の光沢度(Gs20°)を、圧延方向(光沢度を測定する際の入射光が圧延方向と平行)と幅方向(光沢度を測定する際の入射光が幅方向と平行)でそれぞれ5点測定し、その平均値を代表値とし、3サンプルの代表値の平均値を各コイルの光沢度とした。光沢度はスガ試験機製グロスメーター(UGV−6P)を用いて測定した。
表面光沢の判定は、コイルの光沢度が、850未満の場合を不合格(×)、850以上1000未満の場合を合格(○)、1000以上の場合を合格かつ特に優れる(◎)とした。
<Evaluation of surface gloss>
Samples (from the longitudinal part of the ferritic stainless steel cold-rolled steel strip (coil) after temper rolling from the longitudinal part of the tip (position 5 m from the forefront), the center, and the tail end (position 5 m from the end) About 1000 mm wide × 300 mm long in the longitudinal direction) is collected, and the glossiness (Gs20 °) at the center of the widthwise direction of each sample is measured in the rolling direction (incident light when measuring glossiness is parallel to the rolling direction). ) And the width direction (incident light when measuring glossiness is parallel to the width direction), respectively, and the average value is the representative value, and the average value of the representative values of the three samples is the glossiness of each coil. did. The glossiness was measured using a gloss meter (UGV-6P) manufactured by Suga Test Instruments.
The surface gloss was judged as rejected (x) when the glossiness of the coil was less than 850, passed (◯) when the coil glossiness was less than 850 and less than 1000, and passed and particularly excellent when it was 1000 or more (◎).

<光沢ムラの評価>
調質圧延後のフェライト系ステンレス冷延鋼帯(コイル)の、先端部(最先端から5mの位置)、中央部、尾端部(最後端から5mの位置)の長手3箇所から、サンプル(約幅1000mm×長手方向長さ300mm)を採取し、前記各サンプルの両幅端部から15mmまでの領域を除いた幅方向に等間隔で10箇所の位置の光沢度(Gs20°)を、圧延方向(光沢度を測定する際の入射光が圧延方向と平行)でそれぞれ5点測定し、その平均値をその位置の代表値とした。そして、同一サンプルにおいて、前記各位置の代表値の最高値と最低値との差が50ポイント以上であったものは、光沢ムラが発生していると判断し、前記の差が50ポイント未満のものは、光沢ムラが発生していないと判断した。
光沢ムラの判定は、前記コイルの長手3箇所から採取したサンプルのうち、いずれのサンプルにおいても光沢ムラが発生していないと判断された場合を合格(○)、前記サンプルのうち1つでも光沢ムラが発生していると判断された場合を不合格(×)とした。
<Evaluation of uneven gloss>
Samples (from the longitudinal part of the ferritic stainless steel cold-rolled steel strip (coil) after temper rolling from the longitudinal part of the tip (position 5 m from the forefront), the center, and the tail end (position 5 m from the end) Gloss (Gs20 °) at 10 positions at regular intervals in the width direction excluding the region from both width ends of each sample to 15 mm is rolled. Five points were measured in each direction (incident light when measuring glossiness was parallel to the rolling direction), and the average value was used as the representative value of the position. In the same sample, if the difference between the maximum value and the minimum value of the representative value at each position is 50 points or more, it is determined that uneven gloss has occurred, and the difference is less than 50 points. The product was judged to have no gloss unevenness.
Judgment of gloss unevenness passes (○) when it is judged that gloss unevenness does not occur in any of the samples taken from the three longitudinal positions of the coil, and gloss of even one of the samples is glossy. A case where it was determined that unevenness occurred was regarded as a failure (x).

総合評価は、上記表面光沢の判定結果および光沢ムラの判定結果が共に合格であったものを合格(○)、上記表面光沢の判定結果および光沢ムラの判定結果のうち、少なくとも一方が不合格であったものを不合格(×)と判定した。そして、総合評価が合格と判定されたコイルの割合[(総合評価が合格と判定されたコイルの個数/製造したコイルの個数)×100]を合格率とした。各判定結果および合格率を、表1に示す。   Comprehensive evaluation is that the surface gloss determination result and the gloss unevenness determination result are both passed (◯), and at least one of the surface gloss determination result and the gloss unevenness determination result is rejected. What was there was determined to be rejected (x). And the ratio [(the number of coils in which the comprehensive evaluation was determined to be passed / the number of manufactured coils) × 100] of the coils in which the comprehensive evaluation was determined to be the pass was defined as the pass rate. Table 1 shows each determination result and pass rate.

Figure 2019034325
Figure 2019034325

表1中、No.A1〜A10は、本発明の製造方法により製造したコイルである。No.A1〜A10の全コイルで、表面光沢が合格し、さらに光沢ムラも発生しなかった。その結果、合格率は100%であった。   In Table 1, No. A1 to A10 are coils manufactured by the manufacturing method of the present invention. No. In all the coils A1 to A10, the surface gloss passed and no gloss unevenness occurred. As a result, the pass rate was 100%.

No.B1〜B10は、最終パス以外のパス(1パス目〜7パス目)を本発明の高粗度ロールよりも表面粗さの小さい表面粗さ0.20μmRa未満のロールで圧延して製造したコイルである。従来の考えでは、表面粗さの小さいロールを用いるほど表面光沢に優れるとされてきたが、ショットブラスト痕の不均一な残存を促すことになり、3コイルで表面光沢が不合格になったほか、製造したコイルの半数で光沢ムラが不合格となった。その結果、合格率は40%であった。   No. B1 to B10 are coils manufactured by rolling paths other than the final path (first to seventh paths) with a roll having a surface roughness smaller than 0.20 μmRa, which is smaller than the high roughness roll of the present invention. It is. According to the conventional idea, it has been said that the surface gloss is better as the roll having a smaller surface roughness is used. However, the non-uniform remaining of shot blast marks is promoted, and the surface gloss is rejected with 3 coils. The gloss unevenness was rejected in half of the manufactured coils. As a result, the pass rate was 40%.

No.C1〜C10は、1パス目の圧延を本発明の高粗度ロールよりも表面粗さの小さい表面粗さ0.20μmRa未満のロールで圧延して製造したコイルである。1パス目の圧延を本発明の高粗度ロールよりも表面粗さの小さいロールで圧延したことにより、ショットブラストによって既に母材(被圧延材)に形成されている深い凹みが残存する傾向となり、1パス目よりも後のパス(2パス目〜7パス目)で表面粗さが0.20μmRa以上のロールを用いてもオイルピットを除去しきれず、7コイルで光沢ムラが不合格となった。その結果、合格率は30%であった。   No. C1 to C10 are coils manufactured by rolling the first pass with a roll having a surface roughness of less than 0.20 μmRa, which is smaller than the high roughness roll of the present invention. By rolling the first pass with a roll having a surface roughness smaller than that of the high roughness roll of the present invention, deep dents already formed in the base material (rolled material) by shot blasting tend to remain. Even if a roll with a surface roughness of 0.20 μm Ra or more is used in the passes after the first pass (second pass to seventh pass), the oil pits cannot be completely removed, and gloss unevenness is rejected with 7 coils. It was. As a result, the pass rate was 30%.

No.D1〜D10は、最終パスの圧延を本発明の低粗度ロールよりも表面粗さの大きいロールで圧延して製造したコイルである。最終手前パスまでは本発明例と同じ考え方のため、光沢ムラの発生率は30%と低かったが、一方で、最終パスでロール研磨目の転写痕を平滑化する効果が小さく、いずれのコイルも表面光沢が不合格であった。その結果、合格率は0%であった。   No. D1 to D10 are coils manufactured by rolling the final pass with a roll having a surface roughness larger than that of the low roughness roll of the present invention. Since the same concept as the present invention example up to the last pass, the occurrence rate of gloss unevenness was as low as 30%, but on the other hand, the effect of smoothing the transfer marks of the roll polishing eyes in the final pass was small, and any coil The surface gloss was also unacceptable. As a result, the pass rate was 0%.

No.E1〜E10は、最終手前パス(7パス目)とその手前パス(6パス目)の圧延を本発明の高粗度ロールよりも表面粗さの小さい表面粗さ0.20μmRa未満のロールで圧延して製造したコイルである。平滑化により表面光沢を向上させる効果がある一方で、表面粗さの小さいロールを早い段階で用いることにより、ショットブラスト痕を起点とするのではなく、圧延油の鋼帯表面への封入により偶発的に生じるオイルピットの生成と残存を助長する弊害があった。そのため、製造されたコイルに、オイルピットの残存により表面光沢が不合格のもの、最終手前パス、あるいは最終パスで新たな光沢ムラが生じて光沢ムラが不合格になったものがあった。その結果、合格率は0%であった。   No. E1 to E10 are rolling in the final front pass (seventh pass) and the front pass (sixth pass) with a roll having a surface roughness of less than 0.20 μmRa which is smaller than the high roughness roll of the present invention. It is a coil manufactured as described above. While smoothing has the effect of improving the surface gloss, by using a roll with low surface roughness at an early stage, it does not start from shot blast marks, but accidentally occurs by enclosing rolling oil on the surface of the steel strip. There is an adverse effect that promotes the generation and survival of oil pits. For this reason, some of the manufactured coils failed in the surface gloss due to the remaining oil pits, and some had a new gloss unevenness in the last pass or the final pass, resulting in a failure in the gloss unevenness. As a result, the pass rate was 0%.

以上より、本発明の製造方法によれば、表面光沢に優れ、かつ、光沢ムラの発生が抑制されたフェライト系ステンレス鋼板を効率良く製造できることを確認できた。   From the above, according to the production method of the present invention, it was confirmed that a ferritic stainless steel sheet excellent in surface gloss and suppressed in occurrence of gloss unevenness can be efficiently produced.

Claims (1)

酸洗後のフェライト系ステンレス熱延鋼帯に対して、
最終パス以外のパスでは、ロール径が40mm以上150mm以下、表面の算術平均粗さRaが0.20μm以上0.45μm以下のワークロールを用いて圧延し、最終パスでは、ロール径が40mm以上150mm以下、表面の算術平均粗さRaが0.03μm以上0.15μm以下のワークロールを用いて圧延する冷間圧延を施し、
焼鈍を施した後、
伸び率0.3〜2.0%の調質圧延を施すことを特徴とするフェライト系ステンレス冷延鋼帯の製造方法。
For ferritic stainless steel hot rolled steel strip after pickling,
Rolls other than the final pass are rolled using a work roll having a roll diameter of 40 mm to 150 mm and an arithmetic average roughness Ra of 0.20 μm to 0.45 μm. In the final pass, the roll diameter is 40 mm to 150 mm. Hereinafter, the surface arithmetic mean roughness Ra is cold-rolled to roll using a work roll of 0.03 μm to 0.15 μm,
After annealing,
A method for producing a ferritic stainless steel cold-rolled steel strip, characterized by performing temper rolling with an elongation of 0.3 to 2.0%.
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