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JP2011110594A - Method of manufacturing cold-rolled ferritic stainless steel strip excellent in surface gloss - Google Patents

Method of manufacturing cold-rolled ferritic stainless steel strip excellent in surface gloss Download PDF

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JP2011110594A
JP2011110594A JP2009270981A JP2009270981A JP2011110594A JP 2011110594 A JP2011110594 A JP 2011110594A JP 2009270981 A JP2009270981 A JP 2009270981A JP 2009270981 A JP2009270981 A JP 2009270981A JP 2011110594 A JP2011110594 A JP 2011110594A
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Yukihiro Matsubara
行宏 松原
Ayako Miura
彩子 三浦
Yukio Kimura
幸雄 木村
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JFE Steel Corp
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Abstract

【課題】表面光沢に優れたフェライト系ステンレス鋼帯を安定して製造する方法を提供する。
【解決手段】冷間圧延、焼鈍、あるいはさらに酸洗をこの順に施した鋼帯を、調質圧延により表面仕上げするステンレス冷延鋼帯の製造方法において、鋼ロールの表面にCrめっきを施した後、ロール幅方向の平均粗さRaが0.003μm以上0.010μm以下に研磨したロールを用い、無潤滑にて、伸び率が0.8%以上2.0%以下となるように前記調質圧延を行う。
【選択図】なし
A method for stably producing a ferritic stainless steel strip having excellent surface gloss is provided.
In a method for producing a stainless cold-rolled steel strip in which steel strips subjected to cold rolling, annealing, or further pickling in this order are surface-finished by temper rolling, Cr plating is applied to the surface of the steel roll. Thereafter, the temper rolling is performed using a roll polished to have an average roughness Ra in the roll width direction of 0.003 μm or more and 0.010 μm or less so that the elongation is 0.8% or more and 2.0% or less without lubrication.
[Selection figure] None

Description

本発明は、表面光沢に優れたフェライト系ステンレス冷延鋼帯の製造方法に関するものである。   The present invention relates to a method for producing a ferritic stainless steel cold-rolled steel strip excellent in surface gloss.

フェライト系ステンレス冷延鋼帯は、家電製品、厨房製品、洋食器などに使用される場合が多く、表面光沢は重要な特性である。フェライト系ステンレス冷延鋼帯は、通常、連続鋳造により精製されたスラブを熱間圧延して熱延鋼帯を製造し、焼鈍(場合によって省略)、酸洗した後、冷間圧延し、この鋼帯を、焼鈍、(場合によって、酸洗)、調質圧延することにより製造される。表面光沢を向上するためには、酸洗、冷間圧延、調質圧延の各工程で表面を平滑にすることが重要となる。   Ferritic stainless steel cold-rolled steel strip is often used for home appliances, kitchen products, Western dishes, etc., and surface gloss is an important characteristic. Ferritic stainless steel cold-rolled steel strip is usually produced by hot rolling a slab refined by continuous casting to produce a hot-rolled steel strip, annealing (may be omitted in some cases), pickling, and cold rolling. The steel strip is manufactured by annealing (in some cases pickling) and temper rolling. In order to improve the surface gloss, it is important to smooth the surface in each step of pickling, cold rolling and temper rolling.

従来、フェライト系ステンレス冷延鋼帯の表面光沢向上については、多くの技術が開示されており、冷間圧延に関しては、例えば、特許文献1には、冷間圧延のロール粗さ、及び、潤滑状態を規定することにより、高光沢の冷延鋼帯を製造する方法が記載されている。一方、調質圧延に関しては、例えば、特許文献2には、調質圧延のロール粗さを規定することにより、あるいは、特許文献3には、調質圧延の伸び率を、圧下による伸び率と張力による伸び率の比で規定することにより、それぞれ、高光沢の冷延鋼帯を製造する方法が記載されている。   Conventionally, many techniques have been disclosed for improving the surface gloss of a ferritic stainless steel cold rolled steel strip. Regarding cold rolling, for example, Patent Document 1 discloses roll roughness and lubrication of cold rolling. A method for producing a high-gloss cold-rolled steel strip by defining the state is described. On the other hand, regarding temper rolling, for example, Patent Document 2 defines roll roughness of temper rolling, or Patent Document 3 describes elongation of temper rolling as elongation by rolling. A method of manufacturing a high-gloss cold-rolled steel strip by specifying the ratio of the elongation rate by tension is described.

特開平2−92402号公報JP-A-2-92402 特開平7−32004号公報Japanese Unexamined Patent Publication No. 7-32004 特開2005−230857号公報JP-A-2005-230857

しかしながら、特許文献1に記載の方法では、冷間圧延時に圧延油が鋼板表面に押し込まれたオイルピット、あるいは、ロール研磨目が鋼板に転写したスクラッチ痕を調質圧延で完全に平滑化することは困難であり、光沢度(GS20°)が1100を超えるような鏡面に近い高光沢の冷延鋼帯を得ることが困難である。特許文献2に記載の方法では、高光沢の冷延鋼帯が得られるものの、調質圧延の圧延距離が伸びるとともにロール粗さが増加して調質圧延後の光沢が低下するため、安定して高光沢の冷延鋼帯を得ることは困難であった。特許文献3に記載の方法では、調質圧延の圧下による伸び率と張力による伸び率の比を規定するだけでは、表面光沢の向上には十分でない場合が多かった。   However, in the method described in Patent Document 1, the oil pit in which the rolling oil is pushed into the surface of the steel sheet during cold rolling or the scratch marks transferred to the steel sheet by roll polishing are completely smoothed by temper rolling. Is difficult, and it is difficult to obtain a high-gloss cold-rolled steel strip close to a mirror surface with a glossiness (GS20 °) exceeding 1100. In the method described in Patent Document 2, although a high-gloss cold-rolled steel strip is obtained, the rolling distance of the temper rolling is increased and the roll roughness is increased to reduce the gloss after the temper rolling. Therefore, it was difficult to obtain a high-gloss cold-rolled steel strip. In the method described in Patent Document 3, it is often not sufficient to improve the surface gloss only by defining the ratio of the elongation rate due to temper rolling reduction and the elongation rate due to tension.

上述のように、従来の技術では、表面光沢に優れたフェライト系ステンレス鋼帯を安定して製造することができないという課題があった。   As described above, the conventional technique has a problem that a ferritic stainless steel strip excellent in surface gloss cannot be stably produced.

本発明は、上記課題を解決し、表面光沢に優れたフェライト系ステンレス冷延鋼帯を安定して製造する方法を提供するためになされたものであり、その要旨構成は以下のとおりである。   The present invention has been made to solve the above-mentioned problems and to provide a method for stably producing a ferritic stainless steel cold-rolled steel strip excellent in surface gloss, and the gist of the invention is as follows.

1. 冷間圧延、焼鈍、あるいはさらに酸洗をこの順に施した鋼帯を、調質圧延により表面仕上げするステンレス冷延鋼帯の製造方法において、
鋼ロールの表面にCrめっきを施した後、ロール幅方向の平均粗さRaが0.003μm以上0.010μm以下に研磨したロールを用い、無潤滑にて、伸び率が0.8%以上2.0%以下となるように前記調質圧延を行うことを特徴とする、表面光沢に優れたフェライト系ステンレス冷延鋼帯の製造方法。
1. In the method for producing a stainless steel cold-rolled steel strip, the steel strip that has been subjected to cold rolling, annealing, or further pickling in this order is subjected to surface finishing by temper rolling.
After applying Cr plating to the surface of the steel roll, using a roll whose average roughness Ra in the roll width direction is polished to 0.003 μm or more and 0.010 μm or less, and without lubrication, the elongation becomes 0.8% or more and 2.0% or less. The method for producing a ferritic stainless steel cold-rolled steel strip excellent in surface gloss, wherein the temper rolling is performed as described above.

本発明によれば、従来に比べ、表面光沢に優れたフェライト系ステンレス冷延鋼帯を、安定して製造することができる。   According to the present invention, it is possible to stably produce a ferritic stainless steel cold-rolled steel strip that is superior in surface gloss as compared with the prior art.

調質圧延のロール粗さ、伸び率が鋼帯表面の光沢度に及ぼす影響を示すグラフGraph showing the effect of roll roughness and elongation of temper rolling on the glossiness of the steel strip surface 調質圧延の圧延距離と鋼帯表面の光沢度の関係におよぼす本発明の効果を示すグラフGraph showing the effect of the present invention on the relationship between the rolling distance of temper rolling and the glossiness of the steel strip surface

本発明者らは、冷延鋼帯の表面品質を最終的に決定する、調質圧延のロールに着目し、鋭意検討した結果、調質圧延ロールをCrめっきした後、ロール幅方向の平均粗さRaが0.003μm以上0.010μm以下となるように研磨することにより、表面光沢に優れたフェライト系ステンレス冷延鋼帯を安定して製造することができることを知見し、本発明を完成させた。   The inventors of the present invention have finally determined the surface quality of the cold-rolled steel strip, paying attention to the roll of temper rolling, and as a result of intensive studies, after the temper roll was Cr plated, the average roughness in the roll width direction The inventors have found that a ferritic stainless steel cold-rolled steel strip excellent in surface gloss can be stably produced by polishing so that the thickness Ra is 0.003 μm or more and 0.010 μm or less, and the present invention has been completed.

すなわち、0.003μm以上0.010μm以下の平均粗さRaに研磨された、ハイス鋼、ダイス鋼などの一般的な鋼製ロールを用い、無潤滑の調質圧延を行った場合、圧延距離が10kmを超えると、ロールの摩耗が顕著であるとともに、ロールと鋼帯が焼き付いたヒートスクラッチと称する疵が発生する場合があり、安定的に高光沢のステンレス冷延鋼帯を得られなかった。これに対し、本発明では、ダイス鋼などの鋼製ロールに硬質Crめっきを施し、その後、0.003μm以上0.010μm以下の平均粗さRaに研磨したロールを用いることにより、無潤滑の調質圧延で、圧延距離が20kmを超える場合も、ロールの摩耗などによるロール粗さの変化がごくわずかになり、かつ、ヒートスクラッチが発生することもないため、安定して高光沢のステンレス冷延鋼帯を得ることができることを知見した。これは、硬質Crめっき層が鋼に比べ、耐摩耗性、耐ヒートスクラッチ性に優れる特徴を利用したものである。   That is, when a non-lubricating temper rolling is performed using a general steel roll such as high-speed steel or die steel polished to an average roughness Ra of 0.003 μm or more and 0.010 μm or less, the rolling distance is 10 km. If it exceeds the limit, the wear of the roll is remarkable, and a flaw called heat scratch in which the roll and the steel strip are baked may occur, and a high-gloss stainless cold-rolled steel strip cannot be stably obtained. On the other hand, in the present invention, a non-lubricated temper rolling is performed by applying a hard Cr plating to a steel roll such as a die steel and then polishing to a mean roughness Ra of 0.003 μm or more and 0.010 μm or less. Even when the rolling distance exceeds 20 km, the change in roll roughness due to roll wear is negligible and heat scratches do not occur. It was found that can be obtained. This utilizes the feature that the hard Cr plating layer is more excellent in wear resistance and heat scratch resistance than steel.

本発明の効果を検証した実験について示す。本実験では、表1に示す、2種の条件で製造したSUS430冷延鋼帯を用いて、調質圧延に供した。   An experiment for verifying the effect of the present invention will be described. In this experiment, SUS430 cold-rolled steel strip manufactured under two conditions shown in Table 1 was used for temper rolling.

Figure 2011110594
Figure 2011110594

調質圧延の前の段階で鋼板表面を比較すると、冷間圧延時のロール径の小さい条件Bの表面光沢は高く、冷間圧延時のロール径が大きい条件Aの表面光沢は低い。いずれの条件においても、40℃で10cStの鉱油を用いて冷間圧延を行ったものである。また、冷間圧延の後、条件Aの鋼帯は大気焼鈍し、硝酸酸洗を施し、条件Bの鋼帯は光輝焼鈍を施した。   When the steel sheet surfaces are compared at the stage before temper rolling, the surface gloss of condition B with a small roll diameter during cold rolling is high, and the surface gloss of condition A with a large roll diameter during cold rolling is low. In any condition, cold rolling was performed using 10 cSt mineral oil at 40 ° C. In addition, after cold rolling, the steel strip of condition A was annealed in the atmosphere and subjected to nitric acid pickling, and the steel strip of condition B was brightly annealed.

なお、冷間圧延後および調質圧延後の鋼板表面の光沢度は、JIS Z8741の方法5に準じて、光沢度(Gs20°)を圧延方向、圧延方向と直角な方向でそれぞれ5点測定し、その平均値とした。また、ロールの表面粗さは、JIS B0601に準じて、カットオフ値0.25mm、評価長さ4mmの条件において測定し、Ra(算術平均粗さ)を求めた。   In addition, the glossiness of the steel sheet surface after cold rolling and temper rolling was measured according to JIS Z8741 Method 5, with the glossiness (Gs20 °) measured at 5 points in the rolling direction and in the direction perpendicular to the rolling direction. The average value was used. The surface roughness of the roll was measured in accordance with JIS B0601 under the conditions of a cutoff value of 0.25 mm and an evaluation length of 4 mm, and Ra (arithmetic average roughness) was obtained.

上記2種の鋼帯を供試材とし、ロール表面にCrめっきした後、研磨により、ロール粗さを変更した直径340mmのロールを用い、伸び率を0.3%から2.4%の範囲で変化させた調質圧延を行い、得られた鋼板の表面光沢を評価した。図1に結果を示す。伸び率は、調質圧延前後の鋼板の長さ変化から求めた。   Using the above-mentioned two types of steel strips as a test material, after Cr plating on the roll surface, using a roll with a diameter of 340 mm whose roll roughness was changed by polishing, the elongation was in the range of 0.3% to 2.4% The temper rolling was carried out with changing the surface, and the surface gloss of the obtained steel sheet was evaluated. The results are shown in FIG. The elongation was determined from the change in length of the steel sheet before and after temper rolling.

図1に示されるように、0.003μm以上0.010μm以下の平均粗さRaに研磨したロールを用いた場合、調質圧延前の鋼板表面品質に関わらず、伸び率が0.8%以上の条件で、光沢度(Gs20°)が1100以上の、非常に優れた表面光沢が得られることが分かった。   As shown in FIG. 1, when a roll polished to an average roughness Ra of 0.003 μm or more and 0.010 μm or less is used, the elongation is 0.8% or more regardless of the surface quality of the steel sheet before temper rolling. It was found that a very excellent surface gloss with a glossiness (Gs of 20 °) of 1100 or more can be obtained under the above conditions.

本発明において、ロール幅方向の平均粗さRaを0.003μm以上0.010μm以下に限定した理由は以下の通りである。調質圧延ロールを平均粗さ0.003μm未満に研磨することは実用上困難であるとともに、0.003μm未満に研磨した場合、0.003μmの場合に比べて光沢はほぼ同等なためである。一方、0.010μmよりも大きい場合、光沢度(Gs20°)1100以上を得ることはできなかった。   In the present invention, the reason why the average roughness Ra in the roll width direction is limited to 0.003 μm or more and 0.010 μm or less is as follows. This is because it is practically difficult to polish the temper rolling roll to an average roughness of less than 0.003 μm, and when polished to less than 0.003 μm, the gloss is almost the same as that of 0.003 μm. On the other hand, when it was larger than 0.010 μm, glossiness (Gs20 °) of 1100 or more could not be obtained.

また、調質圧延の伸び率を0.8%以上2.0%以下に限定した理由は以下の通りである。0.8%未満の伸び率では、光沢度(Gs20°)1100以上を得ることはできなかった。2.0%を超える伸び率とすると、ヒートスクラッチが発生しやすくて、しかもこれ以上伸び率を増加させても光沢はほぼ同等なためである。なお、伸び率増加を張力でなく圧下で行うと、ロール平滑面が鋼帯表面に転写し易く、光沢向上に有効であるので、圧下による伸び率が大きい方が好ましい。   The reason for limiting the elongation of temper rolling to 0.8% or more and 2.0% or less is as follows. With an elongation of less than 0.8%, a glossiness (Gs20 °) of 1100 or more could not be obtained. If the elongation exceeds 2.0%, heat scratches are likely to occur, and even if the elongation is further increased, the gloss is almost the same. In addition, since the roll smooth surface is easily transferred onto the steel strip surface and effective in improving the gloss when the elongation rate is increased under tension, it is preferable that the elongation rate due to reduction is large.

本発明において、冷間圧延、焼鈍、酸洗条件は、特に限定するものではない。冷間圧延は、ロール径、圧下率などの条件により、圧延後の鋼板表面光沢は変化するが、本発明は、従来から実施されている光沢の優れたステンレス冷延鋼帯を製造する条件、すなわち、ロールバイトへの圧延油の引き込みを抑制するような適正なロール径、ロール粗さ、圧延油を用いた製造条件であれば、適用可能である。同様に、焼鈍、酸洗条件も、光輝焼鈍、大気焼鈍・酸洗のいずれでも良い。   In the present invention, cold rolling, annealing, and pickling conditions are not particularly limited. In cold rolling, the steel sheet surface gloss after rolling changes depending on conditions such as roll diameter and rolling reduction, but the present invention is a condition for producing a stainless steel cold-rolled steel strip with excellent gloss, That is, any suitable roll diameter, roll roughness, and production conditions using rolled oil that suppress the drawing of rolled oil into the roll bite are applicable. Similarly, the annealing and pickling conditions may be bright annealing, atmospheric annealing, or pickling.

光輝焼鈍の場合は、テンパーカラーが付かないよう、不活性雰囲気、もしくは、還元雰囲気にて、鋼種や用途に応じ、適正な温度範囲、時間で焼鈍すれば良く、大気焼鈍・酸洗の場合は、焼鈍により生成した表面の酸化皮膜を除去できるよう、適正な酸、濃度、温度、浸漬時間で酸化皮膜を除去するようにすれば良い。   In the case of bright annealing, annealing can be performed in an appropriate temperature range and time in an inert atmosphere or reducing atmosphere according to the steel type and application so that no temper color is attached. The oxide film may be removed with an appropriate acid, concentration, temperature, and immersion time so that the oxide film on the surface generated by annealing can be removed.

本発明例の効果を従来例と比較して示すため、同一条件で冷間圧延、光輝焼鈍された、板厚0.8mm、板幅1250mmのSUS430冷延鋼帯を、本発明例用、従来例用にそれぞれ10コイルずつ用意した。それぞれ、以下に示す条件にて、連続的に調質圧延を施し、得られた鋼帯の表面光沢を調質圧延の距離とともに整理した。   In order to show the effect of the present invention in comparison with the conventional example, a SUS430 cold-rolled steel strip having a thickness of 0.8 mm and a width of 1250 mm, cold-rolled and bright-annealed under the same conditions, Ten coils were prepared for each example. Each was subjected to continuous temper rolling under the following conditions, and the surface gloss of the obtained steel strip was arranged together with the distance of temper rolling.

調質圧延は、ロール径570mmのロールを用い、50〜80MPaの張力を付与しながら、無潤滑、伸び率1.0%以上1.2%以下の条件で行った。本発明例では、ダイス鋼に硬質Crめっきした後、幅方向の平均粗さRaが0.005μmになるように研磨したロールを用い、従来例では、ダイス鋼をRaが0.005μmになるように研磨したロールを用いた。   The temper rolling was performed using a roll having a roll diameter of 570 mm under conditions of no lubrication and an elongation of 1.0% to 1.2% while applying a tension of 50 to 80 MPa. In the example of the present invention, a roll obtained by applying hard Cr plating to the die steel and then polishing so that the average roughness Ra in the width direction becomes 0.005 μm. In the conventional example, the die steel is set so that Ra becomes 0.005 μm. A polished roll was used.

鋼帯の表面光沢は、各調質圧延距離の位置から鋼帯を切り出し、表裏面それぞれについて板幅方向に7箇所、前記方法にて光沢度を測定し、その平均値を代表値とした。   For the surface gloss of the steel strip, the steel strip was cut out from the position of each temper rolling distance, the glossiness was measured by the above method at seven locations in the plate width direction for each of the front and back surfaces, and the average value was taken as the representative value.

図2に得られた結果を示すように、本発明例では、従来例に比べ、調質圧延距離が長い場合も、安定して1100以上の高い光沢度が得られることが分かる。通常、調質圧延では、20本以上のコイル(圧延距離に換算すると40km以上)を1サイクルとしており、1組のロールで調質圧延を行いたい。しかし、従来例の鋼ロールを用いた方法では、頻繁にロール交換をせざるを得ず、安定的に高光沢を得ることができないが、本発明の方法では、この長距離に亘る調質圧延を行っても高光沢を得ることができる。   As can be seen from the results obtained in FIG. 2, in the present invention example, even when the temper rolling distance is longer than in the conventional example, a high glossiness of 1100 or more can be stably obtained. Normally, in temper rolling, 20 or more coils (40 km or more in terms of rolling distance) are set as one cycle, and it is desired to perform temper rolling with one set of rolls. However, in the method using the steel roll of the conventional example, it is necessary to frequently change the roll, and high gloss cannot be stably obtained. However, in the method of the present invention, the temper rolling over this long distance is performed. High gloss can be obtained even if the process is performed.

Claims (1)

冷間圧延、焼鈍、あるいはさらに酸洗をこの順に施した鋼帯を、調質圧延により表面仕上げするステンレス冷延鋼帯の製造方法において、
鋼ロールの表面にCrめっきを施した後、ロール幅方向の平均粗さRaが0.003μm以上0.010μm以下に研磨したロールを用い、無潤滑にて、伸び率が0.8%以上2.0%以下となるように前記調質圧延を行うことを特徴とする、表面光沢に優れたフェライト系ステンレス冷延鋼帯の製造方法。
In the method for producing a stainless steel cold-rolled steel strip, the steel strip that has been subjected to cold rolling, annealing, or further pickling in this order is subjected to surface finishing by temper rolling.
After applying Cr plating to the surface of the steel roll, using a roll whose average roughness Ra in the roll width direction is polished to 0.003 μm or more and 0.010 μm or less, and without lubrication, the elongation becomes 0.8% or more and 2.0% or less. The method for producing a ferritic stainless steel cold-rolled steel strip excellent in surface gloss, wherein the temper rolling is performed as described above.
JP2009270981A 2009-11-30 2009-11-30 Method of manufacturing cold-rolled ferritic stainless steel strip excellent in surface gloss Pending JP2011110594A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013212514A (en) * 2012-04-01 2013-10-17 Nisshin Steel Co Ltd Bright steel sheet excellent in point-rust resistance
CN103506381A (en) * 2012-06-28 2014-01-15 宝钢不锈钢有限公司 Rolling method for solving surface wrinkling problem of ferritic stainless steel
EP3095882A1 (en) 2015-05-18 2016-11-23 Outokumpu Oyj Method for producing a stainless steel sheet with modified visual characteristics
CN113477741A (en) * 2021-07-14 2021-10-08 永鑫精密材料(无锡)有限公司 Production method of double-optical-surface low-carbon steel strip

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013212514A (en) * 2012-04-01 2013-10-17 Nisshin Steel Co Ltd Bright steel sheet excellent in point-rust resistance
CN103506381A (en) * 2012-06-28 2014-01-15 宝钢不锈钢有限公司 Rolling method for solving surface wrinkling problem of ferritic stainless steel
EP3095882A1 (en) 2015-05-18 2016-11-23 Outokumpu Oyj Method for producing a stainless steel sheet with modified visual characteristics
WO2016184891A1 (en) 2015-05-18 2016-11-24 Outokumpu Oyj Method for producing a stainless steel sheet with modified visual characteristics
US11155892B2 (en) 2015-05-18 2021-10-26 Outokumpu Oyj Method for producing a stainless steel sheet with modified visual characteristics
US11834726B2 (en) 2015-05-18 2023-12-05 Outokumpu Oyj Method for producing a stainless steel sheet with modified visual characteristics
CN113477741A (en) * 2021-07-14 2021-10-08 永鑫精密材料(无锡)有限公司 Production method of double-optical-surface low-carbon steel strip
CN113477741B (en) * 2021-07-14 2023-03-10 永鑫精密材料(无锡)有限公司 Production method of double-optical-surface low-carbon steel strip

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