JP2018131670A - Ferritic free-cutting stainless wire - Google Patents
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Abstract
【課題】熱間加工性に優れ、且つ、切削加工における表面精度に優れたPb無添加のフェライト系快削ステンレス線材を安価に提供する。【解決手段】質量%で、C:0.005〜0.050%、Si:0.10〜1.0%、Mn:0.10〜0.50%、P:0.005〜0.05%、S:0.25〜0.60%、Cr:10.5〜19.5%、Te:0.002〜0.024%、Al:0.001〜0.010%、N:0.005〜0.050%、O:0.001〜0.020%、Ca:0〜0.010%、B:0〜0.02%、Ni:0〜3.0%、Mo:0〜3.0%、Nb:0〜1.00%、Ti:0〜1.00%、V:0〜0.50%、Ta:0〜0.5%、W:0〜0.5%、Co:0〜1.00%、Zr:0〜0.020%、Cu:0〜3.0%、Sn:0〜0.5%、Mg:0〜0.050%、REM:0〜0.200%、残部がFeおよび不可避的不純物からなり、Te/Sが0.040以下である、フェライト系快削ステンレス線材。【選択図】 なしPROBLEM TO BE SOLVED: To provide a Pb-free ferrite-based free-cutting stainless steel wire having excellent hot workability and excellent surface accuracy in cutting at low cost. SOLUTION: In mass%, C: 0.005 to 0.050%, Si: 0.10 to 1.0%, Mn: 0.10 to 0.50%, P: 0.005 to 0.05%, S: 0.25 to 0.60%, Cr: 10.5 to 19.5%, Te: 0.002 to 0.024%, Al: 0.001 to 0.010%, N: 0.005 to 0.050%, O: 0.001 to 0.020%, Ca: 0 to 0.010%, B: 0 to 0.02%, Ni: 0 to 3.0%, Mo : 0 to 3.0%, Nb: 0 to 1.00%, Ti: 0 to 1.00%, V: 0 to 0.50%, Ta: 0 to 0.5%, W: 0 to 0.5%, Co: 0 to 1.00%, Zr: 0 to 0.020%, Cu: 0 to 3.0%, Sn: 0 to 0.5%, Mg: 0 to 0.050%, REM: 0 to 0.200%, the balance consists of Fe and unavoidable impurities, and Te / S is 0.040 or less. There is a ferritic free-cutting stainless steel wire. [Selection diagram] None
Description
本発明は、フェライト系快削ステンレス線材に関する。 The present invention relates to a ferritic free-cutting stainless steel wire.
OA機器、電子機器等の鋼部品のうち、切削で製造される部品には、切削時の切屑処理性に加え、切削加工面に高い寸法精度、および良好な表面性状が求められる。これらの要求に応える鋼素材として、Sを0.15%以上添加したSUS430F、または切削性を更に向上させるためPb、Se、Teを単独もしくは複合添加したフェライト系快削ステンレス鋼がある(特許文献1)。 Among steel parts such as OA equipment and electronic equipment, parts manufactured by cutting are required to have high dimensional accuracy and good surface properties on the cut surface in addition to chip disposal at the time of cutting. As steel materials that meet these requirements, there are SUS430F with 0.15% or more of S added, or ferritic free-cutting stainless steel with Pb, Se, Te added alone or in combination to further improve machinability (Patent Literature). 1).
一方、Pb添加廃止の市場要求に対して、BiまたはSn添加、ならびにCuを主体とする第2相を分散させたフェライト系快削ステンレス鋼が提案されている(特許文献2、3、4)。 On the other hand, ferritic free-cutting stainless steel in which a second phase mainly composed of Bi or Sn and Cu as a main component is dispersed has been proposed in response to market requirements for the abolition of Pb (Patent Documents 2, 3, and 4). .
しかしながら、特許文献1〜4の発明では、熱間加工性などの製造性、および切削後の表面性状において満足なものが得られていない。具体的には、上記部品は、切削速度≧20m/min、切込み≧0.05mm、送り≧0.005mm/rev、の工業的な切削条件において、表面粗さRa≦0.5μmの精度と優れた耐工具摩耗性が要求されるが、その際の表面性状については、特許文献1〜4のいずれにおいても開示されていない。 However, in the inventions of Patent Documents 1 to 4, satisfactory products are not obtained in terms of manufacturability such as hot workability and surface properties after cutting. Specifically, the above parts have excellent accuracy and surface roughness Ra ≦ 0.5 μm under industrial cutting conditions of cutting speed ≧ 20 m / min, cutting depth ≧ 0.05 mm, feed ≧ 0.005 mm / rev. However, the surface properties at that time are not disclosed in any of Patent Documents 1 to 4.
本発明の目的は、上記課題を解決し、熱間加工性が良好で、かつ通常の精密部品の切削加工条件下において、表面粗さ(Ra):0.5μm以下の優れた表面精度を得ることが可能な、Pb、およびSeを含まないフェライト系快削ステンレス線材を提供することにある。 The object of the present invention is to solve the above-mentioned problems, to obtain excellent surface accuracy with good hot workability and surface roughness (Ra): 0.5 μm or less under the cutting conditions of ordinary precision parts. An object of the present invention is to provide a ferritic free-cutting stainless steel wire containing no Pb and Se.
本発明者らは、上記課題を解決するために種々検討した結果、Pb、およびSeを含まないS含有フェライト系ステンレス快削鋼において、微量のTeを含有させることで硫化物の形態を制御し、優れた表面精度を確保できることを知見した。詳細な知見は以下の(a)〜(d)の通りである。 As a result of various studies to solve the above problems, the present inventors have controlled the form of sulfide in a S-containing ferritic stainless steel free-cutting steel that does not contain Pb and Se by containing a small amount of Te. It was found that excellent surface accuracy can be secured. Detailed findings are as follows (a) to (d).
(a)表面粗さを改善するためには、切削中に工具の刃先に形成される構成刃先を小さくすることが有効である。これは、構成刃先が発生すると、切削の際、工具の切刃の輪郭と異なった凹凸が生じるためである。本発明では、線材中の硫化物のアスペクト比を小さくすることで構成刃先の形成を抑制する。 (A) In order to improve the surface roughness, it is effective to reduce the constituent cutting edge formed on the cutting edge of the tool during cutting. This is because when the constituent cutting edge is generated, irregularities different from the contour of the cutting edge of the tool are generated during cutting. In the present invention, the formation of the constituent cutting edge is suppressed by reducing the aspect ratio of the sulfide in the wire.
(b)Teを含有させると、その硫化物の周囲に低融点のMnのTe化合物(MnTe)が形成され、その潤滑作用によって熱間圧延後の加工(例えば、温間伸線加工や冷間伸線加工など)においても展伸しにくくなる。このため、硫化物のアスペクト比が小さくなる。しかし、MnTeは熱間延性を低下させるので、部品の加工性が確保できなくなる。 (B) When Te is contained, a low melting point Mn Te compound (MnTe) is formed around the sulfide, and the lubricating action causes processing after hot rolling (for example, warm drawing or cold drawing). It becomes difficult to stretch even in wire drawing. For this reason, the aspect ratio of sulfide becomes small. However, since MnTe lowers the hot ductility, the workability of the parts cannot be ensured.
(c)一方で、MnTeが形成しない程度の微量のTeを含有させても、そのTeが硫化物中に固溶することで、硫化物の変形抵抗が高まり、その結果、アスペクト比が小さくなる。 (C) On the other hand, even if a very small amount of Te that does not form MnTe is contained, the Te is dissolved in the sulfide, whereby the deformation resistance of the sulfide is increased, and as a result, the aspect ratio is reduced. .
(d)線材中のMn、Crの含有量を調整することで、線材中に形成する硫化物中のMn、Crの組成比も変化し、変形抵抗の向上に寄与する。 (D) By adjusting the contents of Mn and Cr in the wire, the composition ratio of Mn and Cr in the sulfide formed in the wire also changes, which contributes to improvement in deformation resistance.
本発明は、上記知見に基づいてなされたものであり、その要旨とするところは以下の通りである。 This invention is made | formed based on the said knowledge, The place made into the summary is as follows.
(1)質量%で、
C:0.005〜0.050%、
Si:0.10〜1.0%、
Mn:0.10〜0.50%、
P:0.005〜0.05%、
S:0.25〜0.60%、
Cr:10.5〜19.5%、
Te:0.002〜0.024%、
Al:0.001〜0.010%、
N:0.005〜0.050%、
O:0.001〜0.020%、
Ca:0〜0.010%、
B:0〜0.02%、
Ni:0〜3.0%、
Mo:0〜3.0%、
Nb:0〜1.00%、
Ti:0〜1.00%、
V:0〜0.50%、
Ta:0〜0.5%、
W:0〜0.5%、
Co:0〜1.00%、
Zr:0〜0.020%、
Cu:0〜3.0%、
Sn:0〜0.5%、
Mg:0〜0.050%、
REM:0〜0.200%、
残部がFeおよび不可避的不純物からなり、
Te/Sが0.040以下である、フェライト系快削ステンレス線材。
(1) In mass%,
C: 0.005 to 0.050%,
Si: 0.10 to 1.0%,
Mn: 0.10 to 0.50%,
P: 0.005 to 0.05%,
S: 0.25 to 0.60%,
Cr: 10.5 to 19.5%
Te: 0.002 to 0.024%,
Al: 0.001 to 0.010%,
N: 0.005 to 0.050%,
O: 0.001 to 0.020%,
Ca: 0 to 0.010%,
B: 0 to 0.02%,
Ni: 0 to 3.0%,
Mo: 0 to 3.0%,
Nb: 0 to 1.00%,
Ti: 0 to 1.00%,
V: 0 to 0.50%,
Ta: 0 to 0.5%
W: 0 to 0.5%
Co: 0 to 1.00%,
Zr: 0 to 0.020%,
Cu: 0 to 3.0%,
Sn: 0 to 0.5%,
Mg: 0 to 0.050%,
REM: 0 to 0.200%,
The balance consists of Fe and inevitable impurities,
A ferritic free-cutting stainless steel wire having a Te / S of 0.040 or less.
(2)前記化学組成を有する、フェライト系快削ステンレス線材であって、
硫化物中のMnとCrの組成比であるMn/Crが0.1〜0.5、硫化物の外接する圧延方向に平行な径と圧延方向に垂直な径との比をアスペクト比とするとき、硫化物のアスペクト比が8.0以下である、(1)に記載のフェライト系快削ステンレス線材。
(2) A ferritic free-cutting stainless steel wire having the chemical composition,
The Mn / Cr composition ratio of Mn and Cr in the sulfide is 0.1 to 0.5, and the aspect ratio is the ratio of the diameter parallel to the rolling direction circumscribed by the sulfide and the diameter perpendicular to the rolling direction. The ferritic free-cutting stainless steel wire according to (1), wherein the sulfide has an aspect ratio of 8.0 or less.
(3)質量%で、さらに、
Ca:0.0005〜0.010%、
B:0.0001〜0.02%、
Ni:0.1〜3.0%、
Mo:0.1〜3.0%、
Nb:0.05〜1.00%、
Ti:0.05〜1.00%、
V:0.05〜0.50%、
Ta:0.1〜0.5%、
W:0.1〜0.5%、
Co:0.05〜1.00%、
Zr:0.001〜0.020%、
Cu:0.1〜3.0%、
Sn:0.03〜0.5%、
Mg:0.0005〜0.050%、
REM:0.0005〜0.200%、
から選択される1種以上を含有する、(1)または(2)に記載のフェライト系快削ステンレス線材。
(3) In mass%,
Ca: 0.0005 to 0.010%,
B: 0.0001 to 0.02%,
Ni: 0.1 to 3.0%,
Mo: 0.1 to 3.0%,
Nb: 0.05-1.00%
Ti: 0.05-1.00%,
V: 0.05 to 0.50%,
Ta: 0.1 to 0.5%
W: 0.1-0.5%
Co: 0.05 to 1.00%
Zr: 0.001 to 0.020%,
Cu: 0.1 to 3.0%,
Sn: 0.03-0.5%,
Mg: 0.0005 to 0.050%,
REM: 0.0005 to 0.200%,
The ferritic free-cutting stainless steel wire according to (1) or (2), which contains one or more selected from:
本発明では、環境に悪影響を与えるPb、およびSeを含有することなく、熱間加工性が良好で、かつ通常の精密部品の切削加工条件において、切削加工後の部品に、表面粗さ(Ra):0.5μm以下の優れた表面精度を有する、フェライト系快削ステンレス線材を得ることができる。 In the present invention, the hot-workability is good without containing Pb and Se, which adversely affect the environment, and the surface roughness (Ra ): A ferritic free-cutting stainless steel wire having excellent surface accuracy of 0.5 μm or less can be obtained.
以下に、本発明の各要件について説明する。 Below, each requirement of this invention is demonstrated.
1.化学組成
各元素の限定理由は下記の通りである。なお、以下の説明において化学組成についての「%」は「質量%」を意味する。
1. Chemical composition The reasons for limiting each element are as follows. In the following description, “%” for chemical composition means “mass%”.
C:0.005〜0.050%
Cは、炭化物を生成し、強度を得るために必要である。このため、C含有量は、0.005%以上とし、C含有量は、0.010%以上であるのが好ましい。一方、過剰な炭化物は、切削加工時に構成刃先の生成を促進して切削面精度を劣化させるため、C含有量は、0.050%以下とし、C含有量は0.030%以下であるのが好ましい。
C: 0.005 to 0.050%
C is necessary for producing carbide and obtaining strength. For this reason, the C content is preferably 0.005% or more, and the C content is preferably 0.010% or more. On the other hand, excessive carbide accelerates the generation of the constituent cutting edge during cutting and degrades the cutting surface accuracy. Therefore, the C content is 0.050% or less, and the C content is 0.030% or less. Is preferred.
Si:0.10〜1.0%
Siは、脱酸のために使用される。このため、Si含有量は0.10%以上とし、Si含有量は、0.30%以上であるのが好ましい。一方で、1.0%超含有させると、棒線熱間圧延時のスケール生成を抑制し、熱間圧延疵の生成を助長する。そのため、Si含有量は、1.0%以下とする。
Si: 0.10 to 1.0%
Si is used for deoxidation. For this reason, the Si content is preferably 0.10% or more, and the Si content is preferably 0.30% or more. On the other hand, when it contains more than 1.0%, the scale production | generation at the time of bar wire hot rolling is suppressed, and the production | generation of a hot rolling mill is promoted. Therefore, the Si content is 1.0% or less.
Mn:0.10〜0.50%
Mnは、Crと共に硫化物を生成し、被削性、特に切削面精度を向上させる元素である。このため、Mn含有量は、0.10%以上とする。一方、Mn含有量が0.50%を超えると、硫化物におけるMn/Crが高くなり、硫化物が展伸してアスペクト比が大きくなる。そのため、Mn含有量は、0.50%以下とし、Mn含有量は、0.40%以下であるのが好ましい。
Mn: 0.10 to 0.50%
Mn is an element that generates sulfide together with Cr and improves machinability, particularly cutting surface accuracy. For this reason, Mn content shall be 0.10% or more. On the other hand, if the Mn content exceeds 0.50%, Mn / Cr in the sulfide increases, the sulfide expands, and the aspect ratio increases. Therefore, the Mn content is preferably 0.50% or less, and the Mn content is preferably 0.40% or less.
P:0.005〜0.05%
Pは、粒界偏析して切削加工時の材料延性を低下させて、表面精度を向上させる。このため、P含有量は、0.005%以上とし、P含有量は、0.01%以上であるのが好ましい。しかしながら、0.05%を超えて含有させると、その効果は飽和するばかりか、製造性が著しく劣化する。そのため、P含有量は、0.05%以下とする。
P: 0.005 to 0.05%
P segregates at the grain boundaries to lower the material ductility during the cutting process and improve the surface accuracy. For this reason, the P content is preferably 0.005% or more, and the P content is preferably 0.01% or more. However, if the content exceeds 0.05%, the effect is not only saturated, but the productivity is significantly deteriorated. Therefore, the P content is 0.05% or less.
S:0.25〜0.60%
Sは、硫化物を形成し、硫化物には切削加工時に応力が集中する。そして、切りくず生成時におけるせん断変形域で硫化物を起点にき裂が発生し、構成刃先の成長が抑制される。このため、線材の切削面精度が向上する。この効果を得るために、S含有量は、0.25%以上とし、S含有量は、0.28%以上であるのが好ましい。一方で、0.60%を超えて含有させると、熱間加工性が著しく劣化する。そのため、S含有量は、0.60%以下とし、S含有量は、0.55%以下であるのが好ましい。
S: 0.25 to 0.60%
S forms sulfides, and stress concentrates on the sulfides during cutting. A crack is generated starting from sulfide in the shear deformation region at the time of chip generation, and the growth of the constituent cutting edge is suppressed. For this reason, the cutting surface precision of a wire improves. In order to obtain this effect, the S content is preferably 0.25% or more, and the S content is preferably 0.28% or more. On the other hand, when it contains exceeding 0.60%, hot workability will deteriorate remarkably. Therefore, the S content is preferably 0.60% or less, and the S content is preferably 0.55% or less.
Cr:10.5〜19.5%
Crは、Mnと共に硫化物を形成し、特に硫化物中のMnとCrの組成比(Mn/Cr)を適正化することで、硫化物のアスペクト比を小さくすることができる。アスペクト比を小さくし、切削面精度を向上させるためには、Cr含有量は、10.5%以上とし、Cr含有量は、15.0%以上であるのが好ましく、16.0%以上であるのがより好ましい。しかしながら、多量に含有させると、硫化物中のMn/Crが小さくなりすぎて、却って硫化物が展伸しやすくなり、アスペクト比が大きくなる。そのため、Cr含有量は19.5%以下とし、Cr含有量は18.5%以下であるのが好ましい。
Cr: 10.5 to 19.5%
Cr forms a sulfide together with Mn. Particularly, by optimizing the composition ratio (Mn / Cr) of Mn and Cr in the sulfide, the aspect ratio of the sulfide can be reduced. In order to reduce the aspect ratio and improve the cutting surface accuracy, the Cr content is 10.5% or more, and the Cr content is preferably 15.0% or more, and 16.0% or more. More preferably. However, if it is contained in a large amount, Mn / Cr in the sulfide becomes too small, and on the contrary, the sulfide is easily spread and the aspect ratio is increased. Therefore, the Cr content is preferably 19.5% or less, and the Cr content is preferably 18.5% or less.
Te:0.002〜0.024%
Teは、本発明において被削性、特に切削面精度を向上させるために重要な元素である。Teは、硫化物中への固溶により変形を抑制して、アスペクト比を小さくする。その結果、構成刃先の成長を抑制し、切削面精度を向上させる。このため、Te含有量は、0.002%以上とし、Te含有量は、0.003%以上であるのが好ましい。一方で、Teを、0.024%を超えて含有させると、その効果は飽和するばかりか、硫化物周囲のMnTeの形成により、却って製造性が著しく劣化する。そのため、Te含有量は0.024%以下とし、Te含有量は、0.015%以下であるのが好ましく、0.010%以下であるのがより好ましい。
Te: 0.002 to 0.024%
Te is an important element in the present invention for improving machinability, particularly the accuracy of the cut surface. Te suppresses deformation by solid solution in sulfide and reduces the aspect ratio. As a result, the growth of the constituent cutting edges is suppressed and the cutting surface accuracy is improved. For this reason, the Te content is preferably 0.002% or more, and the Te content is preferably 0.003% or more. On the other hand, when Te is contained in excess of 0.024%, not only the effect is saturated, but also the productivity is significantly deteriorated due to the formation of MnTe around the sulfide. Therefore, the Te content is set to 0.024% or less, and the Te content is preferably 0.015% or less, and more preferably 0.010% or less.
Al:0.001〜0.010%
Alは、脱酸元素として使用する。そのため、Al含有量は、0.001%以上とする。一方で、0.010%を超えて含有させると、硬質なAl系の酸化物を形成し、被削性を劣化させ、工具寿命を低下させる。そのため、Al含有量は、0.010%以下とし、Al含有量は、0.008%以下であるのが好ましい。
Al: 0.001 to 0.010%
Al is used as a deoxidizing element. Therefore, the Al content is set to 0.001% or more. On the other hand, if the content exceeds 0.010%, a hard Al-based oxide is formed, the machinability is deteriorated, and the tool life is shortened. Therefore, the Al content is preferably 0.010% or less, and the Al content is preferably 0.008% or less.
N:0.005〜0.050%
Nは、マトリックスのフェライト強度を高める。このため、N含有量は、0.005%以上とし、N含有量は、0.008%以上であるのが好ましい。しかし、N含有量を、0.050%を超えて含有させると、過度の強度上昇により工具寿命を劣化させる。そのため、N含有量は、0.050%以下とし、N含有量は0.030%以下であるのが好ましい。
N: 0.005 to 0.050%
N increases the ferrite strength of the matrix. For this reason, the N content is preferably 0.005% or more, and the N content is preferably 0.008% or more. However, when the N content exceeds 0.050%, the tool life is deteriorated due to an excessive increase in strength. Therefore, the N content is preferably 0.050% or less, and the N content is preferably 0.030% or less.
さらに本発明は、以下に記載する選択元素を含有させてもよい。 Furthermore, the present invention may contain the selective elements described below.
O:0.001〜0.020%
Oは、凝固時の脱酸生成物を粗大化させることで被削性を向上させる。このため、O含有量は0.001%以上とし、O含有量は、0.003%以上であるのが好ましく、0.005%以上であるのがより好ましい。しかし、0.020%を超えて含有させると、硬質な介在物が増加し、被削性を劣化させる。そのため、O含有量は、0.020%以下とする。
O: 0.001 to 0.020%
O improves machinability by coarsening the deoxidation product during solidification. For this reason, the O content is 0.001% or more, and the O content is preferably 0.003% or more, and more preferably 0.005% or more. However, if the content exceeds 0.020%, hard inclusions increase and the machinability deteriorates. Therefore, the O content is 0.020% or less.
Ca:0〜0.010%
Caは、酸化物系介在物を軟質化し、被削性を向上させ、工具寿命を改善する効果があるため、含有させてもよい。しかしながら、0.010%を超えて含有させると、効果が飽和し、熱間加工性が低下する。このため、Ca含有量は、0.010%以下とし、Ca含有量は、0.008%以下であるのが好ましい。一方、上記効果を得るためには、Ca含有量は、0.0005%以上であるのが好ましく、0.0010%以上がより好ましい。またCa含有量が、0.003%以上であるのが最も好ましい。
Ca: 0 to 0.010%
Ca has an effect of softening oxide inclusions, improving machinability, and improving the tool life, so Ca may be contained. However, if it exceeds 0.010%, the effect is saturated and hot workability is reduced. For this reason, the Ca content is preferably 0.010% or less, and the Ca content is preferably 0.008% or less. On the other hand, in order to acquire the said effect, it is preferable that Ca content is 0.0005% or more, and 0.0010% or more is more preferable. Further, the Ca content is most preferably 0.003% or more.
B:0〜0.02%
Bは、熱間加工性を改善するために使用する元素であり、安定した効果を得るために、含有させてもよい。しかしながら、過剰に含有させると、Bの化合物が析出し、熱間加工性を劣化させるので、B含有量は0.02%以下とし、B含有量は、0.015%以下であるのが好ましい。一方で、上記効果を得るためには、B含有量は0.0001%以上であるのが好ましく、B含有量は0.0002%以上であるのがより好ましい。
B: 0 to 0.02%
B is an element used for improving hot workability, and may be contained in order to obtain a stable effect. However, if excessively contained, the B compound precipitates and deteriorates the hot workability, so the B content is preferably 0.02% or less, and the B content is preferably 0.015% or less. . On the other hand, in order to acquire the said effect, it is preferable that B content is 0.0001% or more, and it is more preferable that B content is 0.0002% or more.
Ni:0〜3.0%
Niは、固溶強化により材料の硬さを高めて構成刃先の生成を防止し、切削加工時の表面精度を向上させるため、含有させてもよい。しかしながら、3.0%を超えて含有させてもその効果は飽和し、また、線材が過度に硬質化して、工具寿命劣化を引き起こす。そのため、Ni含有量は、3.0%以下とし、Ni含有量は、1.5%以下であるのが好ましい。一方で、上記効果を得るためには、Ni含有量は、0.1%以上であるのが好ましく、Ni含有量は、0.15%以上であるのがより好ましい。
Ni: 0 to 3.0%
Ni may be contained in order to increase the hardness of the material by solid solution strengthening to prevent the formation of the constituent cutting edge and improve the surface accuracy during cutting. However, even if the content exceeds 3.0%, the effect is saturated, and the wire is excessively hardened to cause tool life deterioration. Therefore, the Ni content is preferably 3.0% or less, and the Ni content is preferably 1.5% or less. On the other hand, in order to acquire the said effect, it is preferable that Ni content is 0.1% or more, and it is more preferable that Ni content is 0.15% or more.
Mo:0〜3.0%
Moは、耐食性を向上させる元素であり、含有させてもよい。しかしながら、Moを多量に含有させると、靭性を低下させる。このため、Mo含有量は、3.0%以下とし、Mo含有量は2.0%以下であるのが好ましい。一方で、上記効果を得るためには、Mo含有量は0.1%以上であるのが好ましい。
Mo: 0 to 3.0%
Mo is an element that improves the corrosion resistance, and may be contained. However, when Mo is contained in a large amount, the toughness is lowered. For this reason, the Mo content is preferably 3.0% or less, and the Mo content is preferably 2.0% or less. On the other hand, in order to acquire the said effect, it is preferable that Mo content is 0.1% or more.
Nb:0〜1.00%
Ti:0〜1.00%
V:0〜0.50%
Ta:0〜0.5%
W:0〜0.5%
Nb、Ti、V、Ta、Wは炭窒化物を形成し、耐食性を改善する効果があるため、含有させてもよい。しかしながら、多量の含有は、被削性が劣化することから、Nb含有量は、1.00%以下とし、Ti含有量は、1.00%以下とする。また、V含有量は、0.50%以下とし、Ta含有量は、0.5%以下とし、W含有量は、0.5%以下とする。一方で、上記効果を得るためには、Nb含有量は、0.05%以上であるのが好ましく、Ti含有量は、0.05%以上であるのが好ましく、V含有量は、0.05%以上であるのが好ましい。また、Ta含有量は、0.1%以上であるのが好ましく、W含有量は、0.1%以上であるのが好ましい。
Nb: 0 to 1.00%
Ti: 0 to 1.00%
V: 0 to 0.50%
Ta: 0 to 0.5%
W: 0 to 0.5%
Nb, Ti, V, Ta, and W may form carbonitride and have an effect of improving corrosion resistance, and thus may be contained. However, since a machinability deteriorates machinability, the Nb content is 1.00% or less and the Ti content is 1.00% or less. Further, the V content is 0.50% or less, the Ta content is 0.5% or less, and the W content is 0.5% or less. On the other hand, in order to obtain the above effect, the Nb content is preferably 0.05% or more, the Ti content is preferably 0.05% or more, and the V content is 0.00%. It is preferably at least 05%. The Ta content is preferably 0.1% or more, and the W content is preferably 0.1% or more.
Co:0〜1.00%
Coは、マトリックスの靭性を高めるため、含有させてもよい。しかしながら、過剰に含有させると、マルテンサイト組織が析出し、被削性を劣化させるため、Co含有量は1.00%以下とし、Co含有量は、0.60%以下であるのが好ましい。一方で、上記効果を得るためには、Co含有量は、0.05%以上であるのが好ましい。
Co: 0 to 1.00%
Co may be contained in order to increase the toughness of the matrix. However, if it is excessively contained, a martensite structure is precipitated and the machinability is deteriorated. Therefore, the Co content is preferably 1.00% or less, and the Co content is preferably 0.60% or less. On the other hand, in order to acquire the said effect, it is preferable that Co content is 0.05% or more.
Zr:0〜0.020%
Zrは、強度を向上させる効果があるので、含有させてもよい。しかしながら、多量の含有は靭性を低下させるため、Zr含有量は、0.020%以下とする。一方で、強度効果を十分に得るためには、Zr含有量は、0.001%以上であるのが好ましい。
Zr: 0 to 0.020%
Zr has the effect of improving the strength and may be contained. However, since a large content reduces toughness, the Zr content is set to 0.020% or less. On the other hand, in order to sufficiently obtain the strength effect, the Zr content is preferably 0.001% or more.
Cu:0〜3.0%
Cuは、固溶強化により材料の硬さを高めて構成刃先の生成を防止し、切削加工時の表面精度を向上させるため、含有させてもよい。しかしながら、3.0%を超えて含有させても、その効果は飽和し、鋳片割れが発生するなど、製造性が劣化するため、Cu含有量は、3.0%以下とする。一方で、上記効果を得るためには、Cu含有量は、0.1%以上であるのが好ましい。
Cu: 0 to 3.0%
Cu may be contained in order to increase the hardness of the material by solid solution strengthening to prevent the formation of the constituent cutting edge and to improve the surface accuracy during the cutting process. However, even if the content exceeds 3.0%, the effect is saturated and manufacturability deteriorates such as occurrence of cracks in the slab, so the Cu content is 3.0% or less. On the other hand, in order to acquire the said effect, it is preferable that Cu content is 0.1% or more.
Sn:0〜0.5%
Snは、耐食性を劣化させる硫化物と共存させることで、耐食性劣化を抑制するため、含有させてもよい。しかしながら、0.5%を超えて含有させると、製造性を劣化させるため、Sn含有量は0.5%以下とし、Sn含有量は0.3%以下であるのが好ましい。一方で、上記効果を得るためには、Sn含有量は、0.03%以上であるのが好ましく、Sn含有量は、0.05%以上であるのが好ましい。
Sn: 0 to 0.5%
Sn may be contained in order to suppress deterioration of corrosion resistance by coexisting with a sulfide that deteriorates corrosion resistance. However, if the content exceeds 0.5%, the manufacturability is deteriorated. Therefore, the Sn content is preferably 0.5% or less, and the Sn content is preferably 0.3% or less. On the other hand, in order to acquire the said effect, it is preferable that Sn content is 0.03% or more, and it is preferable that Sn content is 0.05% or more.
Mg:0〜0.050%
Mgは、熱間加工性を向上させるため、含有させてもよい。しかしながら、0.050%を超えて含有させると、却って熱間加工性を劣化させるため、Mg含有量は、0.050%以下とする。一方で、上記効果を得るためには、Mg含有量は、0.0005%以上であるのが好ましい。
Mg: 0 to 0.050%
Mg may be contained in order to improve hot workability. However, if the content exceeds 0.050%, hot workability is deteriorated on the contrary, so the Mg content is 0.050% or less. On the other hand, in order to acquire the said effect, it is preferable that Mg content is 0.0005% or more.
REM:0〜0.200%
REMは、熱間加工性の劣化を防止するのに有効な元素であり、含有させてもよい。しかしながら、0.200%を超えて含有させると却って熱間加工性を劣化させるため、REM含有量は、0.200%以下とする。一方で、上記効果を得るためには、REM含有量は、0.0005%以上であるのが好ましい。
REM: 0 to 0.200%
REM is an element effective for preventing deterioration of hot workability, and may be contained. However, if the content exceeds 0.200%, the hot workability is deteriorated. Therefore, the REM content is set to 0.200% or less. On the other hand, in order to acquire the said effect, it is preferable that REM content is 0.0005% or more.
REM(希土類元素)は、一般的な定義に従い、スカンジウム (Sc)、イットリウム (Y)の2元素と、ランタン(La)からルテチウム(Lu) までの15元素(ランタノイド)の総称を指す。単独で含有させてもよいし、混合物であってもよい。 REM (rare earth element) refers to a generic name of two elements of scandium (Sc) and yttrium (Y) and 15 elements (lanthanoid) from lanthanum (La) to lutetium (Lu) according to a general definition. You may make it contain independently and a mixture may be sufficient.
本発明の線材は、上記した元素以外は、Feおよび不可避的不純物から成る。但し、本発明の効果を損なわない範囲で、上記以外の元素を含有させても良い。また、PbとSeは不可避的に混入する場合もあるが、Pbは0.03%未満、Seは0.02%未満に制御する必要がある。 The wire rod of the present invention comprises Fe and unavoidable impurities other than the above-described elements. However, elements other than those described above may be included as long as the effects of the present invention are not impaired. Pb and Se may be inevitably mixed, but it is necessary to control Pb to be less than 0.03% and Se to be less than 0.02%.
不可避的不純物とは、鋼材を工業的に製造する際に、原料としての鉱石、スクラップ、または製造環境などから混入されるものであって、本発明の鋼材に悪影響を与えない範囲で許容されるものを意味する。 Inevitable impurities are mixed from ore as a raw material, scrap, or production environment when industrially producing steel materials, and are allowed within a range that does not adversely affect the steel materials of the present invention. Means things.
2.Te/S
後述する硫化物中のMn/Crが0.1〜0.5の範囲にある時、さらに、鋼材のTe/Sが小さい場合に、製造性(熱間加工性)を維持しつつ、硫化物を効果的に球状化し、アスペクト比を8.0以下に小さくすることができる。このような効果を得るために、TeおよびSの組成比である、Te/Sは0.040以下とする。Te/Sは0.040未満であるのが好ましく、0.030以下であるのがより好ましい。
2. Te / S
When Mn / Cr in the sulfide described later is in the range of 0.1 to 0.5, and further when the Te / S of the steel material is small, the sulfide is maintained while maintaining the manufacturability (hot workability). Can be effectively spheroidized and the aspect ratio can be reduced to 8.0 or less. In order to obtain such an effect, Te / S, which is the composition ratio of Te and S, is set to 0.040 or less. Te / S is preferably less than 0.040, and more preferably 0.030 or less.
3.硫化物中のMn/Cr
S含有のフェライト系快削ステンレス線材は、一般に、鋳造から最終圧延までの総減面率が95%以上となるため、MnS系硫化物は、線材長手方向に展伸する。展伸したMnS系硫化物は、切削加工した際の、表面精度低下の原因となる。そのため本発明では、硫化物にCrを固溶させて、硫化物中のMn/Crを0.5以下にすることで、圧延中の硫化物変形を抑制し、アスペクト比を小さく維持する。また硫化物中のMn/Crは0.4以下であるのが好ましい。一方、過剰な固溶は、却って変形能を大きくするので、硫化物中のMn/Crは0.1以上とし、0.2以上であるのが好ましい。
3. Mn / Cr in sulfide
Since S-containing ferritic free-cutting stainless steel wire generally has a total area reduction of 95% or more from casting to final rolling, the MnS-based sulfide extends in the longitudinal direction of the wire. The expanded MnS-based sulfide causes a reduction in surface accuracy when it is cut. Therefore, in the present invention, Cr is solid-solved in the sulfide, and Mn / Cr in the sulfide is made 0.5 or less to suppress sulfide deformation during rolling and keep the aspect ratio small. The Mn / Cr in the sulfide is preferably 0.4 or less. On the other hand, excessive solid solution increases the deformability, so Mn / Cr in the sulfide is 0.1 or more and preferably 0.2 or more.
4.硫化物のアスペクト比
S含有のフェライト系快削ステンレス線材は、MnS系硫化物は線材長手方向に展伸するため、アスペクト比も通常の鋼板と比較し、大きくなる。しかしながら、硫化物のアスペクト比の値が大きくなりすぎると、切削加工した際の表面精度の低下原因となる。このため、硫化物のアスペクト比を、8.0以下とする。また、加工粗さを安定して低減するため、アスペクト比は5.0以下とすることが好ましい。尚、ここで、アスペクト比とは、硫化物に外接する圧延方向に平行な径、つまり水平フェレ径と、圧延方向に垂直な径、つまり垂直フェレ径との比であり、硫化物の水平フェレ径/垂直フェレ径で表される。
4). Aspect ratio of sulfide In the ferritic free-cutting stainless steel wire containing S, the MnS sulfide expands in the longitudinal direction of the wire, and therefore the aspect ratio becomes larger than that of a normal steel plate. However, if the value of the aspect ratio of the sulfide becomes too large, it will cause a reduction in surface accuracy when cutting. For this reason, the aspect ratio of the sulfide is set to 8.0 or less. Moreover, in order to reduce processing roughness stably, it is preferable that an aspect ratio shall be 5.0 or less. Here, the aspect ratio is a ratio of a diameter parallel to the rolling direction circumscribing the sulfide, that is, a horizontal ferret diameter, to a diameter perpendicular to the rolling direction, that is, a vertical ferret diameter. It is expressed as diameter / vertical ferret diameter
5.製造条件
本発明の線材の製造工程については、例えば(1)製鋼⇒(2)熱延⇒(3)線材への加工(伸線、切削等)⇒(4)焼鈍の工程よりなる。必要に応じて、製鋼工程後に熱間鍛造を施しても良い。製鋼においては、本発明の必須元素、および/または選択元素を含む鋼を、溶製・精錬し、溶製した溶鋼は、連続鋳造で鋳片とする。その後、鋳片は、熱間圧延される。この際の好ましい条件は、900℃以上の仕上げ圧延温度で、熱間圧延を施すことである。続いて、伸線、切削が行われる。この際の好ましい条件は室温から100℃程度である。最後に、焼鈍工程が行われる。
5. Manufacturing conditions The manufacturing process of the wire rod according to the present invention includes, for example, a process of (1) steelmaking → (2) hot rolling → (3) processing to wire (drawing, cutting, etc.) → (4) annealing. If necessary, hot forging may be performed after the steel making process. In steelmaking, steel containing the essential elements and / or selective elements of the present invention is melted and refined, and the molten steel is made into a slab by continuous casting. Thereafter, the slab is hot-rolled. A preferable condition in this case is to perform hot rolling at a finish rolling temperature of 900 ° C. or higher. Subsequently, wire drawing and cutting are performed. The preferable conditions in this case are from room temperature to about 100 ° C. Finally, an annealing process is performed.
線材圧延後の焼鈍条件は、特に規定するものではないが、140Hv以上の硬さを得るために、650〜850℃以下にするのが望ましい。また、焼鈍時間についても十分確保する必要があるが、300分を超えると140Hv以上が得られなくなる。組織の均質化の点からも、焼鈍時間を2〜300分とすることが望ましい。さらに好ましくは、5〜120分である。 The annealing condition after the wire rolling is not particularly specified, but it is desirable to set it to 650 to 850 ° C. or less in order to obtain a hardness of 140 Hv or more. Moreover, although it is necessary to ensure sufficient also about annealing time, when it exceeds 300 minutes, 140 Hv or more will no longer be obtained. Also from the point of homogenization of the structure, the annealing time is preferably 2 to 300 minutes. More preferably, it is 5 to 120 minutes.
なお、線材とは棒状に圧延した鋼で、断面が円、楕円、正方形、長方形、六角形等であり、コイル状に巻かれた鋼材を指す。 The wire rod is steel rolled into a rod shape, and the cross section is a circle, an ellipse, a square, a rectangle, a hexagon, or the like, and refers to a steel material wound in a coil shape.
表1及び表2に実施例の鋼の化学組成を示す。 Tables 1 and 2 show the chemical compositions of the steels of the examples.
これらの化学組成の鋼は、150kgの真空溶解炉にて溶解し、直径200mmの鋳片に鋳造し、その後、1200℃加熱で、直径70mmに鍛造した。続いて、直径66mmにピーリング後、棒鋼圧延に相当する熱間押出しにより直径18mmに加工し、780℃で1時間焼鈍した。最後に直径15mmの線材に機械加工で仕上げ、評価用素材とし各評価試験を実施した。 Steels having these chemical compositions were melted in a 150 kg vacuum melting furnace, cast into a slab having a diameter of 200 mm, and then forged to a diameter of 70 mm by heating at 1200 ° C. Subsequently, after peeling to a diameter of 66 mm, it was processed to a diameter of 18 mm by hot extrusion corresponding to steel bar rolling, and annealed at 780 ° C. for 1 hour. Finally, a wire having a diameter of 15 mm was finished by machining, and each evaluation test was performed as a material for evaluation.
前記線材を、その中心線を含む長手方向の断面上を観察するように樹脂に埋め込み、鏡面研磨を行って、硫化物の組成を走査型電子顕微鏡(SEM)付属のEDS分析装置により分析し、硫化物中のMn/Crを算出した。 The wire is embedded in a resin so as to observe a cross section in the longitudinal direction including the center line, mirror-polished, and the sulfide composition is analyzed with an EDS analyzer attached to a scanning electron microscope (SEM). Mn / Cr in the sulfide was calculated.
硫化物のアスペクト比は、SEM−EDSに供したのと同じ試料を使用し、光学顕微鏡観察により、100倍の倍率で10視野撮影し、全硫化物に外接する圧延方向に平行な径(水平フェレ径)と、圧延方向に垂直な径(垂直フェレ径)とを画像解析法により測定した。各硫化物の水平フェレ径/垂直フェレ径をアスペクト比として算出し、全硫化物のアスペクト比の平均値を当該試料のアスペクト比とした。 The aspect ratio of the sulfide was the same sample as that used for SEM-EDS, and was observed with an optical microscope at 10 magnifications at 10 magnifications. The diameter parallel to the rolling direction circumscribing all sulfides (horizontal Ferret diameter) and a diameter perpendicular to the rolling direction (vertical ferret diameter) were measured by an image analysis method. The horizontal ferret diameter / vertical ferret diameter of each sulfide was calculated as an aspect ratio, and the average value of the aspect ratios of all sulfides was taken as the aspect ratio of the sample.
製造性、すなわち熱間延性は、高温引張試験により評価した。具体的には、上記直径70mmの鍛造材の中心と、表面との中間部より丸棒長手方向に直径10mmの熱間延性評価試験片を採取し、試験温度1000℃、歪み速度0.001/sの条件で引張破断した後の絞り値で評価した。この際の試験片形状はJIS Z 2241に記載の2号試験片に準拠し、φ10mm×100mmの試験片とした。熱間延性の評価は、通電により試験片を加熱し、所定の温度で引張り破断が可能な評価装置であるDymanic systm社製のグリーブル試験機を用いる。 Manufacturability, that is, hot ductility was evaluated by a high temperature tensile test. Specifically, a hot ductility evaluation test piece having a diameter of 10 mm is collected in the longitudinal direction of the round bar from the center between the forged material having a diameter of 70 mm and the surface, and the test temperature is 1000 ° C. and the strain rate is 0.001 /. Evaluation was made by the drawing value after the tensile fracture under the condition of s. The shape of the test piece at this time was based on a No. 2 test piece described in JIS Z 2241 and was a test piece of φ10 mm × 100 mm. For evaluation of hot ductility, a Gleeble test machine manufactured by Dynamic system, which is an evaluation device that heats a test piece by energization and can be pulled and broken at a predetermined temperature, is used.
ビッカース硬さは素材の横断面に鏡面研磨を行ったものについて、表層1mm部をマイクロビッカース(荷重1kgf)により測定した。本発明鋼の硬さは140Hv以上であった。 The Vickers hardness was measured by micro-Vickers (load 1 kgf) for a surface layer of 1 mm with a mirror-polished cross section of the material. The hardness of the steel of the present invention was 140 Hv or more.
線材の外周切削後の表面粗さは、切削表面の中心線平均粗さ(Ra)で評価した。
切削は旋削加工であり、材質が超硬P種、刃先Rが0.4mmの工具を用い、切削速度50m/min、送り量0.02mm/rev、切込み0.1mm、切削油(鉱物油)塗布の条件下で行った。
The surface roughness after the outer periphery cutting of the wire was evaluated by the center line average roughness (Ra) of the cutting surface.
Cutting is a turning process, using a tool of carbide P type and cutting edge R of 0.4 mm, cutting speed 50 m / min, feed rate 0.02 mm / rev, cutting depth 0.1 mm, cutting oil (mineral oil) It was performed under the conditions of application.
表面粗さRaは、15分旋削加工後の試料で測定した。測定には接触式の粗さ測定機を用い、基準長さ2.5mmで、各5点ずつ測定して、その平均値を測定値とした。
本発明では表面粗さRaが0.5μm以下の場合に良好と判断した。
The surface roughness Ra was measured on the sample after 15-minute turning. For the measurement, a contact-type roughness measuring machine was used, and the average length was measured at 5 points each with a reference length of 2.5 mm.
In the present invention, it was judged that the surface roughness Ra was good when it was 0.5 μm or less.
また工具寿命は逃げ面の平均摩耗量が0.2mmに達するまでの時間で評価し、15分の加工で0.2mm未満であれば寿命達成とした。製造性の指標である熱間延性(1000℃での絞り値)は、70%以上で良好とした。 The tool life was evaluated by the time until the average wear amount of the flank surface reached 0.2 mm, and if it was less than 0.2 mm after 15 minutes of machining, the life was achieved. The hot ductility (drawing value at 1000 ° C.), which is an index of manufacturability, was good at 70% or more.
結果を表3にまとめて示す。 The results are summarized in Table 3.
発明例のNo.1からNo.49は、成分及び硫化物の組成も規定の範囲を満たしており良好な表面粗さ、工具寿命、熱間加工性の全てにおいて所望の特性が得られている。一方で比較鋼のNo.50からNo.78は規定範囲を満たしておらず、いずれかの特性を満足していないことがわかる。 Invention Example No. 1 to No. In No. 49, the composition of the components and sulfides also satisfy the prescribed ranges, and desired characteristics are obtained in all of good surface roughness, tool life, and hot workability. On the other hand, No. of comparative steel. 50 to No. It can be seen that 78 does not satisfy the specified range and does not satisfy any of the characteristics.
実施例から明らかなように、本発明により、Pb等の毒性の高い重金属を含有させることなく、熱間加工性、切削加工後の表面精度、さらには工具寿命に優れた安価なフェライト系快削ステンレス鋼棒線を製造することができる。
As is clear from the examples, according to the present invention, an inexpensive ferritic free cutting excellent in hot workability, surface accuracy after cutting, and tool life without containing a highly toxic heavy metal such as Pb. Stainless steel rods can be manufactured.
Claims (3)
C:0.005〜0.050%、
Si:0.10〜1.0%、
Mn:0.10〜0.50%、
P:0.005〜0.05%、
S:0.25〜0.60%、
Cr:10.5〜19.5%、
Te:0.002〜0.024%、
Al:0.001〜0.010%、
N:0.005〜0.050%、
O:0.001〜0.020%、
Ca:0〜0.010%、
B:0〜0.02%、
Ni:0〜3.0%、
Mo:0〜3.0%、
Nb:0〜1.00%、
Ti:0〜1.00%、
V:0〜0.50%、
Ta:0〜0.5%、
W:0〜0.5%、
Co:0〜1.00%、
Zr:0〜0.020%、
Cu:0〜3.0%、
Sn:0〜0.5%、
Mg:0〜0.050%、
REM:0〜0.200%、
残部がFeおよび不可避的不純物からなり、
Te/Sが0.040以下である、フェライト系快削ステンレス線材。 % By mass
C: 0.005 to 0.050%,
Si: 0.10 to 1.0%,
Mn: 0.10 to 0.50%,
P: 0.005 to 0.05%,
S: 0.25 to 0.60%,
Cr: 10.5 to 19.5%
Te: 0.002 to 0.024%,
Al: 0.001 to 0.010%,
N: 0.005 to 0.050%,
O: 0.001 to 0.020%,
Ca: 0 to 0.010%,
B: 0 to 0.02%,
Ni: 0 to 3.0%,
Mo: 0 to 3.0%,
Nb: 0 to 1.00%,
Ti: 0 to 1.00%,
V: 0 to 0.50%,
Ta: 0 to 0.5%
W: 0 to 0.5%
Co: 0 to 1.00%,
Zr: 0 to 0.020%,
Cu: 0 to 3.0%,
Sn: 0 to 0.5%,
Mg: 0 to 0.050%,
REM: 0 to 0.200%,
The balance consists of Fe and inevitable impurities,
A ferritic free-cutting stainless steel wire having a Te / S of 0.040 or less.
硫化物中のMnとCrの組成比であるMn/Crが0.1〜0.5、
硫化物の外接する圧延方向に平行な径と圧延方向に垂直な径との比をアスペクト比とするとき、硫化物のアスペクト比が8.0以下である、請求項1記載のフェライト系快削ステンレス線材。 A ferritic free-cutting stainless steel wire having the chemical composition,
Mn / Cr which is the composition ratio of Mn and Cr in the sulfide is 0.1 to 0.5,
The ferrite-based free-cutting according to claim 1, wherein the aspect ratio of the sulfide is 8.0 or less when the ratio of the diameter parallel to the rolling direction circumscribed by the sulfide and the diameter perpendicular to the rolling direction is defined as the aspect ratio. Stainless wire.
Ca:0.0005〜0.010%、
B:0.0001〜0.02%、
Ni:0.1〜3.0%、
Mo:0.1〜3.0%、
Nb:0.05〜1.00%、
Ti:0.05〜1.00%、
V:0.05〜0.50%、
Ta:0.1〜0.5%、
W:0.1〜0.5%、
Co:0.05〜1.00%、
Zr:0.001〜0.020%、
Cu:0.1〜3.0%、
Sn:0.03〜0.5%、
Mg:0.0005〜0.050%、
REM:0.0005〜0.200%、
から選択される1種以上を含有する、請求項1または請求項2に記載のフェライト系快削ステンレス線材。
In mass%,
Ca: 0.0005 to 0.010%,
B: 0.0001 to 0.02%,
Ni: 0.1 to 3.0%,
Mo: 0.1 to 3.0%,
Nb: 0.05-1.00%
Ti: 0.05-1.00%,
V: 0.05 to 0.50%,
Ta: 0.1 to 0.5%
W: 0.1-0.5%
Co: 0.05 to 1.00%
Zr: 0.001 to 0.020%,
Cu: 0.1 to 3.0%,
Sn: 0.03-0.5%,
Mg: 0.0005 to 0.050%,
REM: 0.0005 to 0.200%,
The ferritic free-cutting stainless steel wire according to claim 1 or 2, comprising at least one selected from the group consisting of
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