JP2018109228A - Steel plate for can and manufacturing method thereof - Google Patents
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本発明は、飲料品や食品の容器材料として用いられる3ピース缶の素材に適した缶用鋼板およびその製造方法に関するものである。詳しくは、ロールフォーム加工して、溶接した後の缶胴部の軸方向断面が真円に近い、すなわち、軸方向断面の真円度が小さい缶胴部を形成できる缶用鋼板およびその製造方法に関するものである。 The present invention relates to a steel plate for a can suitable for a three-piece can used as a container material for beverages and foods, and a method for producing the same. More specifically, the steel sheet for cans that can form a can body portion having a small roundness in the axial direction cross section, that is, the axial section of the can body portion after roll forming and welding is close to a perfect circle, that is, a manufacturing method thereof It is about.
近年、スチール缶の製造コスト削減の観点から、缶用鋼板の薄肉化が進められている。しかしながら、鋼板の薄肉化、すなわち、鋼板板厚の低減に伴って、ロールフォーム加工後溶接する時に、缶胴部が変形しやすくなる。その結果、缶胴部の軸方向断面の真円度が大きくなり、缶強度が低下するおそれがある。 In recent years, thinning of steel plates for cans has been promoted from the viewpoint of reducing manufacturing costs of steel cans. However, as the thickness of the steel sheet is reduced, that is, as the thickness of the steel sheet is reduced, the can body easily deforms when welding after roll forming. As a result, the roundness of the axial cross section of the can body increases, and the strength of the can may be reduced.
上記問題を解決するために多くの研究が行われてきた。例えば、缶胴部の変形、真円度を改善する技術が、特許文献1に開示されている。この方法ではC:0.01〜0.10質量%、Mn:0.1〜1.0質量%を含有し、ヤング率が170GPa以下であることを特徴とし、熱延条件の制御と二次冷間圧延することが開示されている。特許文献1に記載の発明では、缶胴部の上記真円度が変わりにくく、形状維持性に優れた缶用鋼板が得られる。 Many studies have been conducted to solve the above problems. For example, Patent Document 1 discloses a technique for improving the deformation and roundness of a can body portion. This method contains C: 0.01 to 0.10% by mass, Mn: 0.1 to 1.0% by mass, and has a Young's modulus of 170 GPa or less. Cold rolling is disclosed. In the invention described in Patent Literature 1, the roundness of the can body portion is hardly changed, and a steel plate for cans excellent in shape maintenance is obtained.
特許文献2には、C:0.020〜0.100質量%、N:0.0130〜0.0200質量%とし、その他成分も限定した、降伏強度が440MPa以上、全伸びが12%以上の鋼板を、3ピース缶成形後の缶胴部の上記真円度が0.34mm以下となるようにする技術が開示されている。 In Patent Document 2, C: 0.020 to 0.100 mass%, N: 0.0130 to 0.0200 mass%, and other components are also limited. The yield strength is 440 MPa or more and the total elongation is 12% or more. A technique is disclosed in which the roundness of the can body after forming a three-piece can is 0.34 mm or less.
特許文献3には、鋼板を薄肉化する技術が開示されており、具体的には、C:0.001〜0.080質量%、N:0.0150超え0.0200質量%以下とし、その他成分も限定した、引張強度が550MPa以上でかつ破断伸びが7%以上である高強度高加工性缶用鋼板が開示され、二次冷間圧延を行うことが記載されている。 Patent Document 3 discloses a technique for thinning a steel sheet. Specifically, C: 0.001 to 0.080 mass%, N: more than 0.0150 and 0.0200 mass% or less, and others A high-strength, high-workability steel sheet for cans having a limited component and a tensile strength of 550 MPa or more and a breaking elongation of 7% or more is disclosed, and it is described that secondary cold rolling is performed.
しかしながら、上記従来技術は、以下の通り、いずれも改善の余地がある。 However, there is room for improvement in any of the conventional techniques as described below.
ヤング率は縦軸に応力、横軸に歪みをとった応力−歪曲線の直線部の傾きに相当する。特許文献1の技術ではヤング率を小さくするが、ヤング率が小さくなるほど、歪みが大きくなり、材料の形状は元に戻りにくくなる。また、熱延時の仕上げ圧延で変態点以下での圧延をする必要があり、製造が容易ではない。さらに、2次冷間圧延で、コスト増が避けられないという問題がある。 The Young's modulus corresponds to the slope of the straight line portion of the stress-strain curve with stress on the vertical axis and strain on the horizontal axis. In the technique of Patent Document 1, the Young's modulus is decreased. However, as the Young's modulus decreases, the distortion increases and the shape of the material becomes difficult to return. In addition, it is necessary to perform rolling below the transformation point in finish rolling during hot rolling, and manufacturing is not easy. Furthermore, there is a problem that cost increase is unavoidable in secondary cold rolling.
特許文献2の技術によって得られた鋼板は、Nが多量に含まれるため、過剰な窒化物が生成し、加工性が劣化するという問題がある。 Since the steel sheet obtained by the technique of Patent Document 2 contains a large amount of N, there is a problem that excessive nitride is generated and workability is deteriorated.
特許文献3の技術では、Nが多量に含まれるため、過剰な窒化物が生成し、加工性が劣化し、製缶性が低下する可能性がある。また、2次冷間圧延での、硬度の上昇でロールフォーム加工性が低下する。さらに、コスト増が避けられないという問題がある。 In the technique of Patent Document 3, since a large amount of N is contained, excessive nitride is generated, workability is deteriorated, and can manufacturing ability may be lowered. Moreover, roll foam workability falls with the raise in hardness in secondary cold rolling. Furthermore, there is a problem that an increase in cost is inevitable.
本発明は、かかる事情に鑑みなされたもので、上述した従来技術の問題を解決し、溶接後の缶胴部の軸方向断面を真円に近づけられる缶用鋼板およびその製造方法を提供することを目的とする。 The present invention has been made in view of such circumstances, and provides a steel plate for a can that can solve the above-described problems of the prior art and can make the axial cross section of the can body portion after welding close to a perfect circle, and a method for manufacturing the same. With the goal.
本発明者らは、上記課題を解決するために鋭意研究を行った。その結果、以下の事実に基づいて課題を解決するための知見を得た。 The inventors of the present invention have intensively studied to solve the above problems. As a result, we obtained knowledge to solve the problem based on the following facts.
第一に、缶の缶胴部は長方形平板を筒状に丸めて端部を接合したものであるため、真円度は成形後の製品の重要な形状因子であり、缶強度にも大きく影響している。 First, since the can body of the can is a rectangular flat plate rolled into a cylindrical shape and joined at the end, roundness is an important form factor of the product after molding and has a significant effect on can strength. doing.
第二に、鋼板板厚の低減に伴う缶強度の維持には、缶胴部の軸方向断面の真円度はできる限り小さいことが望ましい。YPが高くなるほど、ロールフォーム加工性(ロールフォーム加工のしやすさ)が改善され、溶接時に缶体が拘束される際にも缶胴部は変形しにくくなり、上記真円度が小さくなる。したがって、YPを高くすることが、上記真円度を制御する有効手段である。 Second, in order to maintain the can strength accompanying the reduction of the steel plate thickness, it is desirable that the roundness of the axial cross section of the can body portion be as small as possible. As YP increases, roll foam processability (ease of roll foam processing) is improved, and the can body is less likely to be deformed even when the can body is restrained during welding, and the roundness is reduced. Therefore, increasing YP is an effective means for controlling the roundness.
第三に、ロールフォーム加工で与える歪までの応力が、缶用鋼板の弾性限(σ0)または上降伏点(U−YP)以上になると、加工中の歪みを分散させることができ、座屈による缶胴部の変形を防ぎ、缶胴部の形状を良好に維持できる。 Thirdly, when the stress up to the strain applied by the roll foam processing is equal to or higher than the elastic limit (σ 0 ) or upper yield point (U-YP) of the steel plate for cans, the strain during processing can be dispersed, The deformation of the can body due to bending can be prevented, and the shape of the can body can be maintained well.
上記に基づき、さらなる検討を行った結果、弾性限(σ0)または上降伏点(U−YP)を特定の範囲に規定しつつ、かつ、弾性限(σ0)または上降伏点(U−YP)と、ロールフォーム加工の際に鋼板に与えられる歪みまでの応力との関係を規定することが、溶接後の缶胴部の上記真円度を小さくするために重要であることを知見した。 Based on the above, as a result of further studies, while defined elastic limit (sigma 0) or upper yield point (U-YP) to a specific range, and an elastic limit (sigma 0) or upper yield point (U- YP) and the relationship between the stress up to the strain imparted to the steel sheet during roll forming, and it has been found that it is important to reduce the roundness of the can body after welding. .
また、上記関係を満たす缶用鋼板を得るためには、調質圧延条件を含めた製造条件の最適化が有効であることを見出した。 Moreover, in order to obtain the steel plate for cans which satisfy | fills the said relationship, it discovered that optimization of manufacturing conditions including temper rolling conditions was effective.
本発明は、以上の知見に基づきなされたもので、その要旨は以下のとおりである。 The present invention has been made based on the above findings, and the gist thereof is as follows.
[1]缶用鋼板であって、連続降伏する場合は弾性限(σ0)が、連続降伏しない場合は上降伏点(U−YP)が300MPa以上600MPa以下であり、応力−歪曲線が連続降伏する場合は下記(1)式を、連続降伏しない場合は下記(2)式を満たし、下降伏点(L−YP)が存在しないか又は下降伏点がσ1よりも低歪み側に存在することを特徴とする缶用鋼板。
σ0≦0.98×σ1 (1)
U−YP≦0.98×σ1 (2)
ここで、σ0:弾性限、U−YP:上降伏点とし、σ1:応力−歪曲線の弾性域の傾きと平行な直線であり、応力=0(MPa)、かつ、歪み=ロールフォーム加工して缶胴部を成形する際に缶用鋼板に与えられる塑性歪み量(%)の点を通る直線と、応力−歪曲線との交点の応力とする。
[1] Steel plate for cans, elastic limit (σ 0 ) when continuously yielding, and upper yield point (U-YP) when not yielding continuously is 300 MPa or more and 600 MPa or less, and the stress-strain curve is continuous. When yielding, the following formula (1) is satisfied, and when not yielding continuously, the following formula (2) is satisfied, and the falling yield point (L-YP) does not exist or the falling yield point exists on the lower strain side than σ 1 A steel plate for cans characterized by that.
σ 0 ≦ 0.98 × σ 1 (1)
U-YP ≦ 0.98 × σ 1 (2)
Where σ 0 is the elastic limit, U-YP is the upper yield point, σ 1 is a straight line parallel to the slope of the elastic region of the stress-strain curve, stress = 0 (MPa), and strain = roll foam. The stress at the intersection of the straight line passing through the point of the plastic strain amount (%) given to the steel plate for cans when the can body part is formed by processing, and the stress-strain curve.
[2]質量%で、C:0.0010〜0.0100%、Si:0.01〜0.10%、Mn:0.10〜1.00%、P:0.020%以下、N:0.0050%以下、S:0.03%以下、Al:0.02〜0.10%を含有し、残部がFeおよび不可避的不純物からなることを特徴とする[1]に記載の缶用鋼板。 [2] By mass%, C: 0.0010 to 0.0100%, Si: 0.01 to 0.10%, Mn: 0.10 to 1.00%, P: 0.020% or less, N: For cans according to [1], containing 0.0050% or less, S: 0.03% or less, Al: 0.02 to 0.10%, the balance being Fe and inevitable impurities steel sheet.
[3]さらに、質量%で、Nb:0.10%以下、Ti:0.10%以下、B:0.008%以下のいずれか一種以上を含有することを特徴とする[2]に記載の缶用鋼板。 [3] The composition according to [2], further comprising at least one of Nb: 0.10% or less, Ti: 0.10% or less, and B: 0.008% or less in mass%. Steel plate for cans.
[4][1]〜[3]のいずれかに記載の缶用鋼板の製造方法であって、鋼スラブを、850℃以上の仕上げ圧延温度で圧延し、550℃以上の巻取温度で巻き取る熱間圧延工程と、前記熱間圧延工程後の鋼板を80%以上の圧下率で圧延する冷間圧延工程と、前記冷間圧延工程後の鋼板を焼鈍温度700〜900℃で焼鈍する焼鈍工程と、前記焼鈍工程後に、下記の調質圧延伸張率、張力:10〜26kg/mm2の条件で調質圧延を行う調質圧延工程と、を有することを特徴とする缶用鋼板の製造方法。
(調質圧延伸張率)
(I)Nbおよび/またはTiが合計で0.01%未満の場合:C含有量が0.0050%以下のときは、調質圧延伸長率を2〜5%とし、C含有量が0.0050%超〜0.0100%のときは、調質圧延伸長率を5%超〜10%とする。
(II)Nbおよび/またはTiが合計で0.01%以上の場合:C含有量、Nb含有量およびTi含有量が下記式(A)を満たすときは、調質圧延伸張率を2〜5%とし、C含有量、Nb含有量およびTi含有量が下記式(B)を満たすときは、調質圧延伸長率を5%超〜10%とする。
1.0<(Nb/C)×(12/93)+((Ti/C)×(12/48)≦4.5 (A)
0.1≦(Nb/C)×(12/93)+((Ti/C)×(12/48)≦1.0 (B)
式(A)、(B)の元素記号は各元素の含有量(質量%)を意味する。
[4] A method for producing a steel plate for cans according to any one of [1] to [3], wherein the steel slab is rolled at a finish rolling temperature of 850 ° C. or higher and wound at a winding temperature of 550 ° C. or higher. A hot rolling step to be taken, a cold rolling step for rolling the steel plate after the hot rolling step at a reduction rate of 80% or more, and an annealing for annealing the steel plate after the cold rolling step at an annealing temperature of 700 to 900 ° C. And a temper rolling step of performing temper rolling under conditions of the following temper rolling elongation ratio and tension: 10 to 26 kg / mm 2 after the annealing step. Method.
(Temper rolling elongation)
(I) When Nb and / or Ti are less than 0.01% in total: When the C content is 0.0050% or less, the temper rolling elongation is set to 2 to 5%, and the C content is 0.00. When it is more than 0050% to 0.0100%, the temper rolling elongation is made more than 5% to 10%.
(II) When Nb and / or Ti is 0.01% or more in total: When the C content, Nb content and Ti content satisfy the following formula (A), the temper rolling elongation is set to 2 to 5 %, And when the C content, the Nb content, and the Ti content satisfy the following formula (B), the temper rolling elongation is set to more than 5% to 10%.
1.0 <(Nb / C) × (12/93) + ((Ti / C) × (12/48) ≦ 4.5 (A)
0.1 ≦ (Nb / C) × (12/93) + ((Ti / C) × (12/48) ≦ 1.0 (B)
The element symbols in the formulas (A) and (B) mean the content (% by mass) of each element.
本発明によれば、溶接後の缶胴部の軸方向断面を真円に近づけられる缶用鋼板が得られる。 ADVANTAGE OF THE INVENTION According to this invention, the steel plate for cans which can make the axial direction cross section of the can body part after welding approximate a perfect circle is obtained.
以下、本発明の実施形態について説明する。なお、本発明は以下の実施形態に限定されない。 Hereinafter, embodiments of the present invention will be described. In addition, this invention is not limited to the following embodiment.
本発明の缶用鋼板(以下、「本発明の鋼板」という場合がある。)は、連続降伏する場合は弾性限(σ0)が、連続降伏しない場合は上降伏点(U−YP)が300MPa以上600MPa以下である。また、本発明の鋼板の応力−歪曲線が連続降伏する場合は下記(1)式を満たす。また、本発明の鋼板の応力−歪曲線において連続降伏しない場合は下記(2)式を満たし、下降伏点(L−YP)が存在しないか又は下降伏点がσ1よりも低歪み側に存在する。
σ0≦0.98×σ1 (1)
U−YP≦0.98×σ1 (2)
連続降伏する場合は弾性限(σ0)、連続降伏しない場合は上降伏点(U−YP):300MPa以上600MPa以下
本発明の缶用鋼板では、連続降伏する場合は弾性限(σ0)を、連続降伏しない場合は上降伏点(U−YP)を、300MPa以上600MPa以下とする。連続降伏する場合は弾性限(σ0)を、連続降伏しない場合は上降伏点(U−YP)を300MPa以上とすることで、溶接時に缶体が拘束される際にも缶胴部が変形しにくくなり、缶胴部の軸方向断面の真円度が小さくなり、缶強度が維持できるとともに缶形状を良好に維持できる。好ましくは連続降伏する場合は弾性限(σ0)が、連続降伏しない場合は上降伏点(U−YP)が380MPa以上である。一方、連続降伏する場合は弾性限(σ0)が、連続降伏しない場合は上降伏点(U−YP)が600MPaを超えると、板厚の低減に伴って、ロールフォーム加工性が劣化する。ここで、YPは圧延方向によりJIS5号引張試験片を切り出し、JIS Z 2241に基準した引張試験によって測定することができる。
The steel plate for cans of the present invention (hereinafter sometimes referred to as “the steel plate of the present invention”) has an elastic limit (σ 0 ) when yielding continuously, and an upper yield point (U-YP) when not yielding continuously. It is 300 MPa or more and 600 MPa or less. Moreover, when the stress-strain curve of the steel plate of this invention yields continuously, following (1) Formula is satisfy | filled. Moreover, when the continuous yield does not occur in the stress-strain curve of the steel sheet of the present invention, the following equation (2) is satisfied, and the lower yield point (L-YP) does not exist or the lower yield point is on the lower strain side than σ 1. Exists.
σ 0 ≦ 0.98 × σ 1 (1)
U-YP ≦ 0.98 × σ 1 (2)
In the case of continuous yielding, the elastic limit (σ 0 ), in the case of no continuous yielding, the upper yield point (U-YP): 300 MPa to 600 MPa, the steel plate for cans of the present invention has an elastic limit (σ 0 ) for continuous yielding. When not yielding continuously, the upper yield point (U-YP) is set to 300 MPa or more and 600 MPa or less. The elastic limit (σ 0 ) is set for continuous yielding, and the upper yield point (U-YP) is set to 300 MPa or more for non-continuous yielding, so that the can body deforms even when the can is restrained during welding. The roundness of the axial cross section of the can body portion is reduced, the can strength can be maintained, and the can shape can be maintained well. Preferably, in the case of continuous yielding, the elastic limit (σ 0 ) is 380 MPa or more, and in the case of no continuous yielding, the upper yield point (U-YP) is 380 MPa or more. On the other hand, if the yield limit is (σ 0 ) in the case of continuous yielding and the upper yield point (U-YP) exceeds 600 MPa in the case of no continuous yielding, the roll form workability deteriorates as the plate thickness decreases. Here, YP can be measured by a tensile test based on JIS Z 2241 by cutting out a JIS No. 5 tensile test piece in the rolling direction.
σ0≦0.98×σ1 (1)
U−YP≦0.98×σ1 (2)
上記の通り、連続降伏する場合は弾性限(σ0)を、連続降伏しない場合は上降伏点(U−YP)を高めることで、缶胴部が変形しにくくなり、上記真円度が小さくなり、缶強度を維持できる一方で、連続降伏する場合は弾性限(σ0)が、連続降伏しない場合は上降伏点(U−YP)が高すぎるとロールフォーム加工性が劣化する。本発明では、連続降伏する場合は弾性限(σ0)を、連続降伏しない場合は上降伏点(U−YP)を600MPa以下にするとともに、0.98×σ1以下を満たすようにすることが特徴の一つである。
σ 0 ≦ 0.98 × σ 1 (1)
U-YP ≦ 0.98 × σ 1 (2)
As described above, the elastic limit (σ 0 ) is increased in the case of continuous yielding, and the upper yield point (U-YP) is increased in the case of no continuous yielding. Thus, while the can strength can be maintained, the roll foam processability deteriorates if the elastic limit (σ 0 ) is continuous yielding and the upper yield point (U-YP) is too high when continuous yielding is not achieved. In the present invention, the elastic limit (σ 0 ) is set for continuous yielding, and the upper yield point (U-YP) is set to 600 MPa or less and 0.98 × σ 1 or less is satisfied if no continuous yielding occurs. Is one of the features.
σ1とは、応力−歪曲線Lの弾性域の傾きL1と平行で、応力=0(MPa)かつ歪み=ロールフォーム加工して缶胴部を成形する際に缶用鋼板に与えられる塑性歪み量x1である点を通る直線L2と、応力−歪曲線Lとの交点の応力である。弾性域の傾きは、JIS Z 2241の記載に従い特定する。図1、図2にLとL1とL2との関係を示した。図1は連続降伏する場合、図2は、連続降伏しない場合を示した。 σ 1 is a plastic strain applied to the steel plate for can when parallel to the slope L1 of the elastic region of the stress-strain curve L, when stress = 0 (MPa) and strain = roll foam processing to form the can body The stress at the intersection of the straight line L2 passing through the point of the quantity x1 and the stress-strain curve L. The inclination of the elastic region is specified according to the description of JIS Z 2241. FIG. 1 and FIG. 2 show the relationship among L, L1, and L2. FIG. 1 shows the case of continuous yielding, and FIG. 2 shows the case of no continuous yielding.
塑性歪み量x1は、缶を製造するにあたって、[缶の板厚]/[2×缶の直径(缶胴部の軸方向断面の円の直径)]×100(%)で定義できる。 The plastic strain amount x1 can be defined by [can thickness] / [2 × can diameter (diameter of the cross section in the axial direction of the can body)] × 100 (%) in manufacturing the can.
σ1はロールフォーム加工される際に、缶用鋼板に加わる最大の歪みでの応力に相当するものであり、弾性歪み量に塑性歪み量x1を加えた歪み量に対する応力となる。ロールフォーム加工中では、この応力σ1までの応力−歪み曲線の挙動が重要となる。したがって、連続降伏する場合はσ0≦0.98×σ1を、連続降伏しない場合はU−YP≦0.98×σ1を満たすようにすることで、ロールフォーム加工中の歪みが分散されて、座屈による缶胴部の局所的な変形を防ぐことができ、溶接時に缶胴部は変形しにくくなり、良好な形状が維持できると考えられる。 σ 1 corresponds to the stress at the maximum strain applied to the steel plate for cans during roll forming, and is a stress with respect to the strain amount obtained by adding the plastic strain amount x1 to the elastic strain amount. During roll forming, the behavior of the stress-strain curve up to this stress σ 1 is important. Therefore, the σ 0 ≦ 0.98 × σ 1 If continuous yielding, if not continuous yielding it to meet the U-YP ≦ 0.98 × σ 1 , strain in the roll form process is distributed Thus, local deformation of the can body due to buckling can be prevented, and the can body can hardly be deformed during welding, and a good shape can be maintained.
なお、下降伏点(L−YP)がσ1よりも高歪み側に存在すると、ロールフォーム加工時に缶胴部の変形が不均一となる、すなわち、歪みが分散せずに集中するため缶胴部の形状が劣化する。そのため本発明の缶用鋼板の応力−歪曲線には、下降伏点が存在しないか又は下降伏点がσ1よりも低歪み側に存在する必要がある(図2参照)。 If the lower yield point (L-YP) is on the higher strain side than σ 1 , the deformation of the can body becomes non-uniform at the time of roll forming, that is, the strain is concentrated without being dispersed. The shape of the part deteriorates. Therefore, in the stress-strain curve of the steel sheet for cans of the present invention, there is no need for a lower yield point or a lower yield point on the lower strain side than σ 1 (see FIG. 2).
成分組成
本発明の鋼板の成分組成について説明する。以下の説明において、成分の含有量を表す「%」は「質量%」を意味する。
Component composition The component composition of the steel sheet of the present invention will be described. In the following description, “%” representing the content of a component means “mass%”.
C:0.0010〜0.0100%
Cは微細炭化物を形成し、鋼板のYPを増加させる作用を有する。連続降伏する場合は弾性限(σ0)を、連続降伏しない場合は上降伏点(U−YP)を300MPa以上にするためには、C含有量を0.0010%以上とすることが好ましい。一方、C含有量が0.0100%を超えると、ロールフォーム加工で与える歪みまでの応力(σ1)がYPより低くなる場合があり、応力が一点で集中し、缶胴部の軸方向断面の真円度が上昇する場合がある。このため、C含有量は0.0010〜0.0100%の範囲が好ましい。なお、より好ましいC含有量は0.0020〜0.0060%である。
C: 0.0010 to 0.0100%
C has the effect of forming fine carbides and increasing the YP of the steel sheet. In order to make the elastic limit (σ 0 ) in the case of continuous yielding and the upper yield point (U-YP) in the case of no continuous yielding of 300 MPa or more, the C content is preferably made 0.0010% or more. On the other hand, when the C content exceeds 0.0100%, the stress (σ 1 ) up to the strain given by roll forming may be lower than YP, the stress is concentrated at one point, and the axial section of the can body part The roundness of may increase. For this reason, the C content is preferably in the range of 0.0010 to 0.0100%. A more preferable C content is 0.0020 to 0.0060%.
Si:0.01〜0.10%
Siは固溶強化により鋼板のYPを高める作用を有する元素である。YPを安定的に確保するために、Si含有量を0.01%以上にすることが好ましい。一方、Siは缶用としての耐食性に有害な元素であるので、その上限を0.10%とすることが好ましい。
Si: 0.01-0.10%
Si is an element having an effect of increasing YP of a steel sheet by solid solution strengthening. In order to ensure YP stably, the Si content is preferably 0.01% or more. On the other hand, since Si is an element harmful to corrosion resistance for cans, the upper limit is preferably set to 0.10%.
Mn:0.10〜1.00%
Mnは固溶強化により鋼板のYPを高める作用を有する元素である。YPを安定的に確保するため、Mn含有量は0.10%以上が好ましい。一方、Mn含有量が多くなると、鋼板の強度が過剰に高くなり、適正な弾性限(σ0)または上降伏点(U−YP)とσ1の関係が得られない。加えて、原料のコストが上昇するので、Mn含有量の上限は1.00%が好ましい。ただし、食品容器に用いられるブリキ原板のMn含有量の上限は0.6%以下と規定されているので、食品容器として用いる場合、好ましくは0.6%以下である。
Mn: 0.10 to 1.00%
Mn is an element having an effect of increasing YP of a steel sheet by solid solution strengthening. In order to ensure YP stably, the Mn content is preferably 0.10% or more. On the other hand, when the Mn content increases, the strength of the steel sheet becomes excessively high, and the relationship between the appropriate elastic limit (σ 0 ) or upper yield point (U-YP) and σ 1 cannot be obtained. In addition, since the cost of the raw material increases, the upper limit of the Mn content is preferably 1.00%. However, since the upper limit of the Mn content of the tin plate used for the food container is defined as 0.6% or less, it is preferably 0.6% or less when used as a food container.
P:0.020%以下
Pは固溶強化により鋼板のYPを高める作用を有する元素である。Pは粒界に偏析して、鋼板の延性および靱性を低下させる。また、Pは耐食性を低下させる有害な元素でもあり、その含有量の上限は0.020%が好ましい。なお、より好ましくは0.010%以下である。
P: 0.020% or less P is an element having an effect of increasing YP of a steel sheet by solid solution strengthening. P segregates at the grain boundaries and lowers the ductility and toughness of the steel sheet. P is also a harmful element that lowers corrosion resistance, and the upper limit of its content is preferably 0.020%. In addition, More preferably, it is 0.010% or less.
N:0.0050%以下
Nは多量に含まれると、過剰な窒化物が生成し、鋼板の延性や靱性が低下する。また、Nは加工性を劣化させるため、N含有量の上限を0.0050%とすることが好ましい。
N: 0.0050% or less When N is contained in a large amount, excess nitride is generated, and the ductility and toughness of the steel sheet are lowered. Moreover, since N deteriorates workability, the upper limit of the N content is preferably set to 0.0050%.
S:0.03%以下
Sは、Mn、Tiを含有することが好ましい本発明では、Tiと結合してTiSを、Mnと結合してMnSを形成する。これらの硫化物は、表面性状を劣化させるとともに、熱間圧延での延性を低下させるため、S含有量の上限を0.03%とすることが好ましい。より好ましくは0.01%以下である。
S: 0.03% or less S preferably contains Mn and Ti. In the present invention, Ti combines with Ti to form TiS and Mn to form MnS. Since these sulfides deteriorate surface properties and reduce ductility in hot rolling, the upper limit of the S content is preferably 0.03%. More preferably, it is 0.01% or less.
Al:0.02〜0.10%
Alは脱酸剤として作用する有用な元素である。その効果を得るために、Al含有量を0.02%以上にすることが好ましい。一方、Al含有量が0.10%を超えると、鋼板の表面欠陥を誘発するので、上限は0.10%とすることが好ましい。
Al: 0.02-0.10%
Al is a useful element that acts as a deoxidizer. In order to obtain the effect, the Al content is preferably 0.02% or more. On the other hand, if the Al content exceeds 0.10%, surface defects of the steel sheet are induced, so the upper limit is preferably 0.10%.
Nb:0.10%以下、Ti:0.10%以下、B:0.008%以下のいずれか一種以上
NbはCと結合し、Nbの微細な炭化物を形成する。この炭化物にはYPを上昇させる効果がある。この効果を得るため、Nbを含有する場合には、その含有量は0.01%以上にすることが好ましい。一方、Nb含有量が0.10%を超えると、YPが600MPaを超えて、強度が高くなり、所望のロールフォーム加工性が得られない場合がある。また、圧延負荷を高めるため、安定した鋼板製造が困難になる場合がある。そのため、Nbを含有する場合には、Nb含有量は0.01〜0.10%の範囲に限定することが好ましい。
Nb: 0.10% or less, Ti: 0.10% or less, B: 0.008% or less Any one or more of Nb combines with C to form a fine carbide of Nb. This carbide has the effect of increasing YP. In order to obtain this effect, when Nb is contained, the content is preferably 0.01% or more. On the other hand, if the Nb content exceeds 0.10%, YP exceeds 600 MPa, the strength increases, and the desired roll foam processability may not be obtained. Moreover, since the rolling load is increased, it may be difficult to produce a stable steel sheet. Therefore, when Nb is contained, the Nb content is preferably limited to a range of 0.01 to 0.10%.
また、TiはNbと同様、Cと結合し、Tiの微細な炭化物を形成する。この炭化物はYPを上昇させる効果がある。この効果を得るため、Tiを含有する場合には、その含有量は0.01%以上にすることが好ましい。一方、Ti含有量が0.10%を超えると、YPが高くなり、所望のロールフォーム加工性が得られない場合がある。また、Ti含有量の増加により、合金のコストの増加だけではなく、再結晶終了温度が上昇する。さらに、Ti含有量が増加すると、圧延負荷を高める必要があり、安定した鋼板製造が困難になる。そのため、Tiを含有する場合には、Ti含有量は0.01〜0.10%の範囲に限定することが好ましい。 Ti, like Nb, combines with C to form fine carbides of Ti. This carbide has the effect of increasing YP. In order to obtain this effect, when Ti is contained, the content is preferably 0.01% or more. On the other hand, if the Ti content exceeds 0.10%, YP increases and the desired roll foam processability may not be obtained. Further, the increase in Ti content not only increases the cost of the alloy, but also increases the recrystallization end temperature. Furthermore, when the Ti content increases, it is necessary to increase the rolling load, which makes it difficult to produce a stable steel sheet. Therefore, when Ti is contained, the Ti content is preferably limited to a range of 0.01 to 0.10%.
BはNと結合し、熱間延性を害するNをBNとして固定する効果がある。また、固溶Bが結晶粒界に偏析し、結晶粒微細化効果を発揮させ、YPの上昇に効果があるため、その含有量は0.0005%以上にすることが好ましい。一方、B含有量が0.008%を超えると、固溶B増加により連続焼鈍工程における再結晶完了温度を過度に上昇させ、炉内破断が発生する危険がある。そのため、Bを含有する場合には、B含有量は0.0005〜0.008%の範囲に限定することが好ましい。 B combines with N and has the effect of fixing N, which impairs hot ductility, as BN. Further, since the solid solution B segregates at the crystal grain boundaries and exhibits the effect of refining the crystal grains and is effective in increasing YP, the content is preferably 0.0005% or more. On the other hand, when the B content exceeds 0.008%, the recrystallization completion temperature in the continuous annealing process is excessively increased due to an increase in the solid solution B, and there is a risk that the in-furnace fracture occurs. Therefore, when it contains B, it is preferable to limit B content to 0.0005 to 0.008% of range.
残部はFeおよび不可避的不純物とする。不可避的不純物としてはCu、Ni、Cr、Co、Mo、Sb、W、As、Pb、Mg、Ca、Sn、Ta、V、REM、Cs、Zr、Hfのいずれか1種以上を合計0.2%以下が挙げられる。 The balance is Fe and inevitable impurities. Inevitable impurities include Cu, Ni, Cr, Co, Mo, Sb, W, As, Pb, Mg, Ca, Sn, Ta, V, REM, Cs, Zr, and Hf. 2% or less is mentioned.
厚み
本発明の缶用鋼板の厚みは特に限定されないが、厚みが0.1〜0.3mmで、溶接後の缶胴部の軸方向断面を真円に近づけられる点が本発明の特徴の一つである。
Thickness Although the thickness of the steel plate for cans of the present invention is not particularly limited, one feature of the present invention is that the thickness is 0.1 to 0.3 mm and the axial cross section of the can body portion after welding can be made close to a perfect circle. One.
本発明の缶用鋼板は、3ピース缶用の鋼板として好ましく用いることができる。なお、ロールフォーム加工により成形される缶の製造に用いれば本発明の効果を奏するので、必ずしも3ピース缶用に限定されない。 The steel plate for cans of the present invention can be preferably used as a steel plate for 3-piece cans. In addition, since it will have the effect of this invention if it uses for manufacture of the can shape | molded by roll-form processing, it is not necessarily limited to 3 piece cans.
製造方法
次に、本発明の缶用鋼板の製造方法の一例について説明する。本発明の缶用鋼板の製造方法は、熱間圧延工程と、冷間圧延工程と、焼鈍工程と、調質圧延工程とを有する。
Manufacturing method Next, an example of the manufacturing method of the steel plate for cans of this invention is demonstrated. The manufacturing method of the steel plate for cans of this invention has a hot rolling process, a cold rolling process, an annealing process, and a temper rolling process.
熱間圧延工程
熱間圧延工程として、鋼スラブを、850℃以上の仕上げ圧延温度で圧延し、550℃以上の巻取温度で巻き取る。
Hot rolling process As a hot rolling process, a steel slab is rolled at a finish rolling temperature of 850 ° C or higher and wound at a winding temperature of 550 ° C or higher.
仕上げ圧延温度が850℃を下回ると、未結晶粒が多くなり、鋼板が硬質化し、適正な弾性限(σ0)または上降伏点(U−YP)とσ1の関係が得られない。また、板厚が薄い缶用鋼板とする場合、コイルのエッジ側の温度が下がりやすいため、仕上げ圧延温度は850℃以上とする。なお、仕上げ圧延温度は高すぎると、粒成長が過剰となり鋼板強度が下がるという理由で950℃以下が好ましい。 When the finish rolling temperature is lower than 850 ° C., the number of uncrystallized grains increases, the steel plate becomes hard, and an appropriate elastic limit (σ 0 ) or upper yield point (U-YP) and σ 1 relationship cannot be obtained. Moreover, when it is set as the steel plate for cans with thin plate | board thickness, since the temperature of the edge side of a coil tends to fall, finish rolling temperature shall be 850 degreeC or more. In addition, if the finish rolling temperature is too high, 950 ° C. or lower is preferable because the grain growth becomes excessive and the steel sheet strength decreases.
巻取温度が550℃を下回ると、ベイナイトやマルテンサイトなど硬質な低温変態相の生成により、鋼板が硬質化し、その後の冷延時における荷重も高くなってしまうことから、操業が困難となる場合がある。そのため、巻取温度は550℃以上とする。一方、巻取温度が700℃を超えると熱延板段階でのフェライト粒が粗大となり、YPが低下する。そこで、巻取温度は700℃以下が好ましい。 When the coiling temperature is lower than 550 ° C, the steel sheet becomes hard due to the generation of a hard low-temperature transformation phase such as bainite and martensite, and the load at the time of cold rolling thereafter becomes high, which may make operation difficult. is there. Therefore, the winding temperature is set to 550 ° C. or higher. On the other hand, when the coiling temperature exceeds 700 ° C., the ferrite grains in the hot-rolled sheet stage become coarse, and YP decreases. Therefore, the winding temperature is preferably 700 ° C. or lower.
冷間圧延工程
冷間圧延工程として、熱間圧延工程後の鋼板を80%以上の圧下率で圧延する。なお、熱間圧延工程後、必要に応じて酸化皮膜を除去する。酸化皮膜の除去方法としては、酸洗や機械的除去などがあげられる。
Cold rolling process As a cold rolling process, the steel sheet after the hot rolling process is rolled at a rolling reduction of 80% or more. In addition, an oxide film is removed as needed after a hot rolling process. Examples of the method for removing the oxide film include pickling and mechanical removal.
冷間圧延工程の圧下率を80%以上とすることにより、所望の降伏強度が得られる。冷間圧延における圧下率が80%に満たないと、結晶粒が粗大化して材質が軟化する。そのため、冷間圧延における圧下率は80%以上とする。 A desired yield strength can be obtained by setting the rolling reduction in the cold rolling step to 80% or more. If the rolling reduction in cold rolling is less than 80%, the crystal grains are coarsened and the material is softened. Therefore, the rolling reduction in cold rolling is 80% or more.
焼鈍工程
焼鈍工程として、上記冷間圧延工程後の鋼板を焼鈍する。
Annealing Step As the annealing step, the steel sheet after the cold rolling step is annealed.
焼鈍温度は特に限定しないが、焼鈍温度が再結晶温度を下回ると延性が大きく低下し、鋼板が破断する可能性があるため、焼鈍温度は再結晶が完了する温度以上とすることが好ましい。一方、焼鈍温度が高過ぎると、結晶粒が粗大化し、YPが低下する。薄鋼板の焼鈍中の破断防止と微細粒強化の観点から均熱温度(焼鈍温度)は700℃以上900℃以下とすることが好ましい。 The annealing temperature is not particularly limited. However, when the annealing temperature is lower than the recrystallization temperature, the ductility is greatly reduced and the steel sheet may be broken. Therefore, the annealing temperature is preferably equal to or higher than the temperature at which recrystallization is completed. On the other hand, if the annealing temperature is too high, the crystal grains become coarse and YP decreases. It is preferable that the soaking temperature (annealing temperature) is 700 ° C. or more and 900 ° C. or less from the viewpoint of preventing breakage during annealing of the thin steel plate and strengthening the fine grains.
調質圧延工程
調質圧延工程として、上記焼鈍工程後に、下記の調質圧延伸張率、張力:10〜26kg/mm2の条件で調質圧延を行う。
Temper rolling step As the temper rolling step, after the annealing step, temper rolling is performed under the following conditions of temper rolling elongation and tension: 10 to 26 kg / mm 2 .
調質圧延の条件は、本発明の製造方法において重要な条件である。鋼板の炭素含有量に応じて、適当な条件の下で調質圧延を行う。 The condition of temper rolling is an important condition in the production method of the present invention. Depending on the carbon content of the steel sheet, temper rolling is performed under appropriate conditions.
まず、調質圧延の際の張力が10kg/mm2未満になると、鋼板表面の欠陥が発生しやすくなる。特に板厚が薄い缶用鋼板では、小さい表面欠陥でも、その後の缶の成形性が劣化し、円筒部の軸方向断面の真円度が大きくなるので、調質圧延張力を10kg/mm2以上にする。一方、調質圧延の際の張力が大きすぎて、材料の破壊応力を超えると材料が圧延中に破断する可能性がある。そこで、調質圧延の際の張力を26kg/mm2以下とする。 First, when the tension during temper rolling is less than 10 kg / mm 2 , defects on the steel sheet surface tend to occur. Particularly in steel sheets for cans with a small plate thickness, even if the surface defects are small, the subsequent formability of the can deteriorates and the roundness of the axial cross section of the cylindrical portion increases, so the temper rolling tension is 10 kg / mm 2 or more. To. On the other hand, if the tension during temper rolling is too high and exceeds the fracture stress of the material, the material may break during rolling. Therefore, the tension during temper rolling is set to 26 kg / mm 2 or less.
また、ストレッチャーストレインの発生を抑え、ロールフォーム加工が完了するまでの応力の低下を抑え、座屈による変形を避けるために、炭素含有量に応じて、調質圧延条件を調整する。炭素の含有量が少量な場合、高伸長率で圧延すると、鋼板が硬質化することによる加工性の低下と伸びの低下を引き起こす。一方、炭素の含有量が多量な場合、低伸長率で圧延すると、降伏伸びが残り、ロールフォーム加工で与える歪の応力が低下し、座屈による変形が避けられず、真円度が上昇する。以上から、本発明者らが行った種々の試験の結果から、
(I)Nbおよび/またはTiが合計で0.01%未満の場合:C含有量が0.0050%以下のときは、調質圧延伸長率を2〜5%とし、C含有量が0.0050%超〜0.0100%のときは、調質圧延伸長率を5%超〜10%とする。
(II)Nbおよび/またはTiが合計で0.01%以上の場合:C含有量、Nb含有量およびTi含有量が下記式(A)を満たすときは、調質圧延伸張率を2〜5%とし、C含有量、Nb含有量およびTi含有量が下記式(B)を満たすときは、調質圧延伸長率を5%超〜10%とする。
1.0<(Nb/C)×(12/93)+((Ti/C)×(12/48)≦4.5 (A)
0.1≦(Nb/C)×(12/93)+((Ti/C)×(12/48)≦1.0 (B)
式(A),(B)の元素記号は各元素の含有量(質量%)を意味する。
In addition, the temper rolling conditions are adjusted according to the carbon content in order to suppress the occurrence of stretcher strain, suppress the decrease in stress until the roll foam processing is completed, and avoid deformation due to buckling. When the carbon content is small, rolling at a high elongation rate causes deterioration in workability and elongation due to hardening of the steel sheet. On the other hand, when the carbon content is large, when rolling at a low elongation rate, yield elongation remains, the stress of strain given by roll forming decreases, deformation due to buckling is inevitable, and roundness increases. . From the above, from the results of various tests conducted by the inventors,
(I) When Nb and / or Ti are less than 0.01% in total: When the C content is 0.0050% or less, the temper rolling elongation is set to 2 to 5%, and the C content is 0.00. When it is more than 0050% to 0.0100%, the temper rolling elongation is made more than 5% to 10%.
(II) When Nb and / or Ti is 0.01% or more in total: When the C content, Nb content and Ti content satisfy the following formula (A), the temper rolling elongation is set to 2 to 5 %, And when the C content, the Nb content, and the Ti content satisfy the following formula (B), the temper rolling elongation is set to more than 5% to 10%.
1.0 <(Nb / C) × (12/93) + ((Ti / C) × (12/48) ≦ 4.5 (A)
0.1 ≦ (Nb / C) × (12/93) + ((Ti / C) × (12/48) ≦ 1.0 (B)
The element symbols in the formulas (A) and (B) mean the content (% by mass) of each element.
上記のようにして得た鋼板は、その後、必要に応じて、鋼板に、例えば電気めっきにより、錫めっき、クロムめっき、ニッケルめっき等のめっき処理を施したり、樹脂被膜を施したりする表面処理を行い、缶用鋼板とする。なお、めっきや樹脂皮膜等の表面処理の膜厚は、板厚に対して十分に小さいので、缶用鋼板の機械特性への影響は無視できるレベルである。 The steel plate obtained as described above is then subjected to surface treatment such as electroplating, such as tin plating, chromium plating, nickel plating, or a resin coating, if necessary. To make a steel plate for cans. In addition, since the film thickness of surface treatments, such as plating and a resin film, is sufficiently small with respect to plate | board thickness, the influence on the mechanical characteristic of the steel plate for cans is a level which can be disregarded.
表1に示す成分組成のスラブを表2に示す条件で、熱間圧延、酸洗、冷間圧延、焼鈍、調質圧延を施し、板厚が0.15mmの缶用鋼板を製造した。なお、これらの缶用鋼板は缶の直径が52.5mmになることを想定して製造された。No.1〜28の缶用鋼板について以下の評価を行った。評価方法は次の通りであり、評価結果は表3に示した。 Hot rolling, pickling, cold rolling, annealing and temper rolling were performed on the slab having the composition shown in Table 1 under the conditions shown in Table 2 to produce a steel plate for cans having a plate thickness of 0.15 mm. In addition, these steel plates for cans were manufactured on the assumption that the diameter of the can was 52.5 mm. No. The following evaluation was performed on the steel plates for cans 1 to 28. The evaluation method is as follows, and the evaluation results are shown in Table 3.
引張試験
得られた缶用鋼板から、圧延方向に対して平行方向を引張方向とするJIS 5号引張試験片(JIS Z 2201)を採取し、JIS Z 2241の規定に準拠した引張試験を行って、連続降伏した場合は弾性限(σ0)を、連続降伏しない場合(降伏点降下を示した場合)は上降伏点(U−YP)を測定した。また、σ1とσ0またはU−YPの関係が、
0.97×σ1<(σ0またはU−YP)≦0.98×σ1を(○)、
(σ0またはU−YP)≦0.97×σ1を(◎)、
σ0>σ1 または U−YP>σ1の場合を(×)と表記した。
Tensile test JIS No. 5 tensile test piece (JIS Z 2201) having a tensile direction parallel to the rolling direction was taken from the obtained steel plate for cans and subjected to a tensile test in accordance with the provisions of JIS Z 2241. The elastic limit (σ 0 ) was measured when continuous yielding occurred, and the upper yield point (U-YP) was measured when continuous yielding did not occur (when yield point drop was indicated). Also, the relationship between σ 1 and σ 0 or U-YP is
0.97 × σ 1 <(σ 0 or U-YP) ≦ 0.98 × σ 1 (◯),
(Σ 0 or U-YP) ≦ 0.97 × σ 1 is (◎),
The case of σ 0 > σ 1 or U-YP> σ 1 was expressed as (×).
真円度の測定
真円度を測定するために、鋼板に対して、3ピース缶ロールフォーム成形を行った後、溶接を行った。具体的には、上記鋼板の表面に錫をメッキした鋼板を長方形平板ブランク(長さ:160mm、横:140mm)にせん断した。圧延方向を曲げ方向として、巻幅が5〜10mmになるようにロールフォーマを調整し、0.3%の歪を与えたロールフォーム加工を行った。成形した円筒状の両端を電気抵抗溶接のシーム溶接により接合し、「JIS B 7451」で規定された真円度測定装置を用い、缶高さ方向の中心部の真円度を測定した。本発明における缶体の真円度は、「JIS B 0621」で示されるように、円形形体を2つの同心の幾何学的円で挟んだとき、平行2円の間隔が最小となる場合の、二円の半径の差で表した。真円度0.20mm以下の場合をより一層優れるとして合格(◎)、真円度0.21mm以上〜0.30mm未満の場合を合格(○)、真円度0.30mm以上の場合を不合格(×)とした。
Measurement of roundness In order to measure the roundness, a three-piece can roll form was formed on a steel plate and then welded. Specifically, the steel plate plated with tin on the surface of the steel plate was sheared into a rectangular flat plate blank (length: 160 mm, width: 140 mm). With the rolling direction as the bending direction, the roll former was adjusted so that the winding width was 5 to 10 mm, and roll forming was performed with a strain of 0.3%. Both ends of the formed cylindrical shape were joined by seam welding of electric resistance welding, and the roundness of the central portion in the can height direction was measured using a roundness measuring device defined in “JIS B 7451”. The roundness of the can body in the present invention is, as shown by “JIS B 0621”, when the circular shape is sandwiched between two concentric geometric circles, the interval between the two parallel circles is minimized. Expressed by the difference in radius between two circles. The case where the roundness is 0.20 mm or less is considered to be even better (◎), the case where the roundness is 0.21 mm or more to less than 0.30 mm is passed (O), and the case where the roundness is 0.30 mm or more is not acceptable. It was set as a pass (x).
Claims (4)
連続降伏する場合は弾性限(σ0)が、連続降伏しない場合は上降伏点(U−YP)が300MPa以上600MPa以下であり、
応力−歪曲線が連続降伏する場合は下記(1)式を、連続降伏しない場合は下記(2)式を満たし、下降伏点(L−YP)が存在しないか又は下降伏点がσ1よりも低歪み側に存在することを特徴とする缶用鋼板。
σ0≦0.98×σ1 (1)
U−YP≦0.98×σ1 (2)
ここで、σ0:弾性限、U−YP:上降伏点とし、σ1:応力−歪曲線の弾性域の傾きと平行な直線であり、応力=0(MPa)、かつ、歪み=ロールフォーム加工して缶胴部を成形する際に缶用鋼板に与えられる塑性歪み量(%)の点を通る直線と、応力−歪曲線との交点の応力とする。 A steel plate for cans,
In the case of continuous yielding, the elastic limit (σ 0 ) is, and in the case of no continuous yielding, the upper yield point (U-YP) is 300 MPa or more and 600 MPa or less,
When the stress-strain curve yields continuously, the following equation (1) is satisfied. When the stress-strain curve does not yield continuously, the following equation (2) is satisfied, and there is no lower yield point (L-YP) or the lower yield point is σ 1 Steel plate for cans characterized by being present on the low strain side.
σ 0 ≦ 0.98 × σ 1 (1)
U-YP ≦ 0.98 × σ 1 (2)
Where σ 0 is the elastic limit, U-YP is the upper yield point, σ 1 is a straight line parallel to the slope of the elastic region of the stress-strain curve, stress = 0 (MPa), and strain = roll foam. The stress at the intersection of the straight line passing through the point of the plastic strain amount (%) given to the steel plate for cans when the can body part is formed by processing, and the stress-strain curve.
鋼スラブを、850℃以上の仕上げ圧延温度で圧延し、550℃以上の巻取温度で巻き取る熱間圧延工程と、
前記熱間圧延工程後の鋼板を80%以上の圧下率で圧延する冷間圧延工程と、
前記冷間圧延工程後の鋼板を焼鈍温度700〜900℃で焼鈍する焼鈍工程と、
前記焼鈍工程後に、下記の調質圧延伸張率、張力:10〜26kg/mm2の条件で調質圧延を行う調質圧延工程と、を有することを特徴とする缶用鋼板の製造方法。
(調質圧延伸張率)
(I)Nbおよび/またはTiが合計で0.01%未満の場合:C含有量が0.0050%以下のときは、調質圧延伸長率を2〜5%とし、C含有量が0.0050%超〜0.0100%のときは、調質圧延伸長率を5%超〜10%とする。
(II)Nbおよび/またはTiが合計で0.01%以上の場合:C含有量、Nb含有量およびTi含有量が下記式(A)を満たすときは、調質圧延伸張率を2〜5%とし、C含有量、Nb含有量およびTi含有量が下記式(B)を満たすときは、調質圧延伸長率を5%超〜10%とする。
1.0<(Nb/C)×(12/93)+((Ti/C)×(12/48)≦4.5 (A)
0.1≦(Nb/C)×(12/93)+((Ti/C)×(12/48)≦1.0 (B)
式(A)、(B)の元素記号は各元素の含有量(質量%)を意味する。 It is a manufacturing method of the steel plate for cans in any one of Claims 1-3,
Rolling a steel slab at a finish rolling temperature of 850 ° C. or higher and winding at a winding temperature of 550 ° C. or higher;
A cold rolling step of rolling the steel sheet after the hot rolling step at a reduction rate of 80% or more;
An annealing step of annealing the steel sheet after the cold rolling step at an annealing temperature of 700 to 900 ° C;
A temper rolling step of performing temper rolling under the following conditions of temper rolling elongation and tension: 10 to 26 kg / mm 2 after the annealing step, a method for producing a steel plate for cans.
(Temper rolling elongation)
(I) When Nb and / or Ti are less than 0.01% in total: When the C content is 0.0050% or less, the temper rolling elongation is set to 2 to 5%, and the C content is 0.00. When it is more than 0050% to 0.0100%, the temper rolling elongation is made more than 5% to 10%.
(II) When Nb and / or Ti is 0.01% or more in total: When the C content, Nb content and Ti content satisfy the following formula (A), the temper rolling elongation is set to 2 to 5 %, And when the C content, the Nb content, and the Ti content satisfy the following formula (B), the temper rolling elongation is set to more than 5% to 10%.
1.0 <(Nb / C) × (12/93) + ((Ti / C) × (12/48) ≦ 4.5 (A)
0.1 ≦ (Nb / C) × (12/93) + ((Ti / C) × (12/48) ≦ 1.0 (B)
The element symbols in the formulas (A) and (B) mean the content (% by mass) of each element.
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| JPH08269567A (en) * | 1995-03-30 | 1996-10-15 | Kawasaki Steel Corp | Manufacturing method of steel plate for Si-added can with excellent surface properties |
| JPH09104919A (en) * | 1995-10-05 | 1997-04-22 | Kawasaki Steel Corp | Manufacturing method of steel sheet for can having excellent draw formability |
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