JP2018178275A - Slide fabric and window glass stabilizer - Google Patents
Slide fabric and window glass stabilizer Download PDFInfo
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- JP2018178275A JP2018178275A JP2017075023A JP2017075023A JP2018178275A JP 2018178275 A JP2018178275 A JP 2018178275A JP 2017075023 A JP2017075023 A JP 2017075023A JP 2017075023 A JP2017075023 A JP 2017075023A JP 2018178275 A JP2018178275 A JP 2018178275A
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- sliding
- fabric
- ridges
- resin
- slide
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- 230000003068 static effect Effects 0.000 claims abstract description 24
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- 229910052731 fluorine Inorganic materials 0.000 claims description 22
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- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 21
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- 239000002759 woven fabric Substances 0.000 claims description 13
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- 239000000654 additive Substances 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
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- 239000003607 modifier Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
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- 239000004417 polycarbonate Substances 0.000 description 1
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- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
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- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Woven Fabrics (AREA)
- Window Of Vehicle (AREA)
Abstract
Description
本発明は、摺動材料として好適なフッ素樹脂繊維を含む摺動布帛に関する。また、前記摺動布帛を用いてなるウインドウガラススタビライザに関する。 TECHNICAL FIELD The present invention relates to a sliding cloth including a fluorocarbon resin fiber suitable as a sliding material. The present invention also relates to a window glass stabilizer made of the sliding fabric.
従来からフッ素樹脂はその低摩擦係数を生かして摺動部材の表層にラミネートやコーティングされて使用されている。しかしながら、フッ素樹脂のラミネートやコーティングではフッ素樹脂膜が薄く、かつ非接着性のため剥がれやすく、長期的に摺動性を維持するためにはラミネートやコーティングを繰り返す必要があった。このような欠点を解消するためにフッ素樹脂を繊維化し、織り編み物や不織布として摺動部材の表面に配置させることで摩擦耐久性を向上させ、さらに他素材と接着しやすい織り編み物と複合してより強固に接着する摺動材が開発されている。 Conventionally, a fluorine resin is used by being laminated or coated on the surface layer of a sliding member by making use of its low coefficient of friction. However, in the case of the lamination and coating of the fluorine resin, the fluorine resin film is thin and easily non-adhesive, so it is easy to peel off, and in order to maintain the slidability in the long term, the lamination and coating have to be repeated. In order to eliminate such a defect, the fluorocarbon resin is fiberized and disposed on the surface of the sliding member as a woven or non-woven fabric to improve the friction durability, and further to be combined with the woven or knitted fabric which is easily adhered to other materials. Sliding materials that bond more firmly have been developed.
例えば、特許文献1には、パイル部分をポリテトラフロロエチレン糸で構成し且つ特定の立毛密度を有するパイル織物を、ウインドウガラススタビライザ用の面接部材として用いることで、ガラス面との摩擦が小さくスムーズに摺動し、ガラスに痕を付けることがなく、また、パイル糸の体積弾性効果により、優れた振れ止め効果を奏することができるという技術が開示されている。 For example, Patent Document 1 discloses that a pile fabric made of polytetrafluoroethylene yarn and having a specific napping density is used as an interview member for a window glass stabilizer so that the friction with the glass surface is small and smooth. In addition, there is disclosed a technique in which the glass does not slide and the glass is not marked, and the bulk elastic effect of the pile yarn can provide an excellent steadying effect.
なお、ウインドウガラススタビライザは、ウインドウガラス開閉時における前記ガラスの振動を防止するために、ウインドウガラス格納庫本体内のウェスト開口部付近に取り付けられており、一般的には、ウインドウガラスの両側から前記ガラス面に摺接させる面接部材等から構成されている。 The window glass stabilizer is attached in the vicinity of the waist opening in the window glass storage body to prevent the vibration of the glass when the window glass is opened and closed. Generally, the glass is viewed from both sides of the window glass It is comprised from the interview member etc. which slide on a surface.
しかしながら、上記特許文献1記載のパイル織物をウインドウガラススタビライザ用の面接部材として用いた場合、降雨等によりウインドウガラスに水滴が付着してパイル糸が湿潤すると、ウインドウガラス開閉時に前記ガラス面とパイル糸が摺接する際に不快な異音が発生するという問題がある。 However, when the pile fabric described in Patent Document 1 is used as an interview member for a window glass stabilizer, when water droplets adhere to the window glass due to rainfall or the like and the pile yarn is wetted, the glass surface and the pile yarn are opened when the window glass is opened or closed. There is a problem that unpleasant noise is generated when sliding contact with each other.
本発明は、かかる従来技術の課題を解決し、湿潤状態においても静摩擦係数と動摩擦係数の差が小さく、かつ摺動面から効率よく水を排出できるように相手部材と摺接する際に不快な異音が発生することのない摺動布帛を提供することを課題とする。 The present invention solves the problems of the prior art, and the difference between the coefficient of static friction and the coefficient of dynamic friction is small even in a wet state, and water can be efficiently discharged from the sliding surface. It is an object of the present invention to provide a sliding fabric in which no sound is generated.
かかる課題を解決するため本発明は、次の構成を有する。 In order to solve the problems, the present invention has the following configuration.
(1)フッ素樹脂繊維を含む摺動布帛であって、摺動布帛は摺動面を有し、該摺動面に一方向に延在する複数の凸条部と基部が交互に形成されている摺動布帛。 (1) A sliding fabric containing fluorine resin fibers, the sliding fabric having a sliding surface, and a plurality of ridges and bases extending in one direction are alternately formed on the sliding surface. There is a sliding cloth.
(2)前記摺動面における凸条部と基部の面積比が、0.1〜2である(1)に記載の摺動布帛。 (2) The sliding fabric according to (1), wherein the area ratio of the ridges to the base in the sliding surface is 0.1 to 2.
(3)前記摺動面における凸条部は、高さが0.05〜2mmである(1)または(2)に記載の摺動布帛。 (3) The sliding fabric according to (1) or (2), wherein the ridges in the sliding surface have a height of 0.05 to 2 mm.
(4)前記摺動面における凸条部は、フッ素樹脂繊維が配されることにより形成されている(1)〜(3)のいずれかに記載の摺動布帛。 (4) The sliding cloth according to any one of (1) to (3), wherein the ridges on the sliding surface are formed by arranging fluorocarbon resin fibers.
(5)前記フッ素樹脂繊維の繊度が、他の繊維に対して、繊度比で10〜30倍である(4)に記載の摺動布帛。 (5) The sliding fabric according to (4), wherein the fineness of the fluorine resin fiber is 10 to 30 times the fineness ratio with respect to the other fibers.
(6)前記摺動面は、湿潤状態において凸条方向と直角方向に摺動した際の静摩擦係数と動摩擦係数の差が0.2以下である(1)〜(5)のいずれかに記載の摺動布帛。 (6) The sliding surface according to any one of (1) to (5), wherein the difference between the static friction coefficient and the dynamic friction coefficient when sliding in a direction perpendicular to the ridge direction in a wet state is 0.2 or less Sliding fabric.
(7)前記摺動布帛は、2重織物であることを特徴とする(1)〜(6)のいずれかに記載の摺動布帛。 (7) The sliding fabric according to any one of (1) to (6), wherein the sliding fabric is a double woven fabric.
(8)(1)〜(7)のいずれかに記載の摺動布帛を、面接部材の少なくとも一部に用いてなるウインドウガラススタビライザ。 (8) The window glass stabilizer which uses the sliding fabric in any one of (1)-(7) for at least one part of an interview member.
本発明によれば、フッ素樹脂繊維を含み、摺動面に一方向に延在する複数の凸条部と基部を交互に形成することにより、湿潤状態においても凸条方向の直角方向に静摩擦係数と動摩擦係数の差が小さく、かつ摺動面から効率よく水を排出でき、相手部材と摺接する際に不快な異音が発生することのない摺動布帛が提供される。 According to the present invention, by alternately forming a plurality of ridges and a base extending in one direction on the sliding surface, containing fluorine resin fibers, the coefficient of static friction in the direction perpendicular to the ridge direction also in the wet state Thus, a sliding cloth is provided which has a small difference in dynamic friction coefficient and can efficiently discharge water from the sliding surface and does not generate any unpleasant noise when sliding on a mating member.
そしてかかる摺動布帛は、ウインドウガラススタビライザ用の面接部材、複写機定着部摺動材、防振ゴム等に有用に用いることができ、なかでも特にウインドウガラススタビライザ用の面接部材に有用に用いることができる。 And such a sliding cloth can be usefully used as an interview member for a window glass stabilizer, a sliding member for a copying machine fixing portion, a vibration-proof rubber, etc., and in particular, usefully used as an interview member for a window glass stabilizer. Can.
本発明による摺動布帛は、フッ素樹脂繊維を含む摺動布帛であって、摺動布帛は摺動面を有し、該摺動面に一方向に延在する複数の凸条部と基部が交互に形成されていることを特徴とする。 The sliding fabric according to the present invention is a sliding fabric containing a fluorocarbon resin fiber, the sliding fabric having a sliding surface, and a plurality of ridges and a base extending in one direction on the sliding surface. It is characterized in that it is formed alternately.
なお、本発明において「凸条部」とは、布帛の厚地部分が筋状に形成された部分であり、「基部」は、凸条部以外の部分に形成される布帛の薄地部分である。また、「一方向に延在摺る複数の凸条部と基部が交互に形成されている」とは、筋状に形成される凸条部と凸条部間に形成される基部が代わる代わる配置され、いずれも一方向に配されていることをいう。ここで一方向とは、例えば凸条部と隣合う凸条部が厳密に平行で直線状に配列されている必要はなく、多少のゆがみはあってもよく、概ね平行で一方向に配されていればよい。 In the present invention, the “convex line portion” is a portion where the thick cloth portion of the fabric is formed in a streak shape, and the “base” is a thin cloth portion of the cloth formed in a portion other than the convex streak portion. In addition, “a plurality of ridges and a base extending alternately in one direction are alternately formed” means that the ridge formed in a streak and the base formed between the ridges are replaced with each other. And both are arranged in one direction. Here, in one direction, for example, the ridges adjacent to the ridges do not have to be strictly parallel and arranged in a straight line, and there may be some distortion, and they are generally parallel and arranged in one direction. It should just be.
上記摺動布帛は摺動面にフッ素樹脂繊維を含むものである。摺動布帛は摺動に供される摺動面を有し、摺動面には複数の凸条部が形成されている。凸条部は、フッ素樹脂繊維で構成されていることが好ましい。これにより、摺動面として相手材と接着する凸条部の低摩擦性を実現できる。また、基部は、フッ素樹脂繊維で構成されていてもよいが、他の繊維で構成されていることが好ましい。これにより、布帛自体の強度など機械性能を維持できる。 The above-mentioned sliding cloth contains a fluorocarbon resin fiber on the sliding surface. The sliding fabric has a sliding surface that is used for sliding, and a plurality of ridges are formed on the sliding surface. The ridges are preferably made of fluorocarbon resin fibers. As a result, the low friction of the ridge portion adhering to the mating material as the sliding surface can be realized. The base may be made of fluorocarbon resin fiber, but is preferably made of other fiber. Thereby, mechanical performance, such as strength of the fabric itself, can be maintained.
摺動面に凸条部を形成する方法としては、凸条部を形成する方向に他の構成糸よりも太くした糸を配する方法、例えば織物である場合タテ方向又はヨコ方向のどちらか一方方向のみに他の構成糸に対して太い糸あるいは複数本の糸を合糸して他の構成糸よりも太くした糸を織り込む方法、またエンボス加工により薄地部分を筋状に形成するとともに相対的に厚地となる筋状の部分を形成することで凸条部と基部を形成するエンボス加工方法等が適用できる。中でも、前記太い糸若しくは複数本の糸を合糸して他の構成糸よりも太くした糸として、太いフッ素樹脂繊維を配することにより凸条部を形成することが好ましい。これにより、凸条部と基部の面積比、また凸条部の高さを自由にコントロールできる。 As a method of forming the ridges on the sliding surface, a method of arranging a yarn thicker than other constituent yarns in the direction of forming the ridges, for example, in the case of a fabric, either the warp direction or the weft direction A method in which thick yarns or plural yarns are combined with other constituent yarns only in the direction and a yarn made thicker than the other constituent yarns is woven, and a thin portion is formed into streaks by embossing and relative The embossing method etc. which form a convex streak part and a base are applicable by forming the streaky part which becomes thick. Above all, it is preferable to form the ridges by arranging a thick fluorocarbon resin fiber as a yarn obtained by doubling the thick yarn or a plurality of yarns and making them thicker than other constituent yarns. Thereby, the area ratio between the ridges and the base, and the height of the ridges can be freely controlled.
そして、上記摺動面における凸条部と基部の面積比は、0.1〜2の範囲内が好ましく、さらに好ましくは0.3〜1の範囲内である。前記面積比が0.1以上であるとフッ素繊維の凸条部だけが相手材と接着し低摩擦性能を実現できる。2以下であれば凸条部だけが相手材と接着するので相手材との接圧が高く、静・動摩擦係数の差が小さくなり、また効率よく水を排出でき、相手部材と摺接する際に不快な異音が発生しない。 The area ratio of the ridge to the base on the sliding surface is preferably in the range of 0.1 to 2, more preferably in the range of 0.3 to 1. If the area ratio is 0.1 or more, only the ridges of the fluorine fiber can be bonded to the mating material to realize low friction performance. If it is 2 or less, only the ridges adhere to the mating material, so the contact pressure with the mating material is high, the difference in static / dynamic coefficient of friction is small, and water can be discharged efficiently, and when sliding contact with the mating member There is no unpleasant noise.
ここで、「凸条部の面積」とは、摺動界内に布帛の摺動面が相手材と100paの接圧で接触できる投影面積をいう。また、「基部の面積」とは、摺動界内に布帛の摺動面が相手材と100paの接圧で接触できない投影面積をいう。さらに、「凸条部と基部の面積比」とは、(凸条部の面積/基部の面積)をいう。 Here, "the area of the ridges" refers to a projected area in which the sliding surface of the fabric can be in contact with the mating material at a contact pressure of 100 pa within the sliding field. Moreover, "the area of the base" refers to a projected area in which the sliding surface of the fabric can not contact with the mating material at a contact pressure of 100 pa within the sliding field. Furthermore, "the area ratio of the ridges to the base" means (area of ridges / area of base).
また、上記摺動面における凸条部は、高さが0.05〜2mmの範囲内が好ましく、さらに好ましくは0.1〜1mmの範囲内である。前記高さが0.05mm以上であるとフッ素繊維の凸条部だけが相手材と接着し低摩擦性能を実現できる。2mm以下であれば凸条部が弾性変形しにくく、凸条部だけが相手材と接着し接触面積が小さくなることにより接圧が高くなり、静・動摩擦係数の差が小さくなるとともに効率よく水を排出でき、相手部材と摺接する際に不快な異音が発生しにくい。 The height of the ridges in the sliding surface is preferably in the range of 0.05 to 2 mm, and more preferably in the range of 0.1 to 1 mm. When the height is 0.05 mm or more, only the ridges of the fluorine fiber can be bonded to the mating material to realize low friction performance. If it is 2 mm or less, the ridges are unlikely to be elastically deformed, and only the ridges adhere to the mating member and the contact area is reduced, the contact pressure becomes high, and the difference between the static and dynamic friction coefficients becomes small and the water efficiently Can be discharged, and it is hard to generate unpleasant noise when sliding contact with the other member.
ここで、「凸条部の高さ」とは、基部の表面から凸条部の頂上までの距離をいう。 Here, "the height of the ridge" refers to the distance from the surface of the base to the top of the ridge.
さらに、上記摺動面は、湿潤状態において凸条方向と直角方向に摺動した際の静摩擦係数と動摩擦係数の差が0.2以下であることが好ましく、さらに好ましくは0.1以下の範囲内である。前記静摩擦係数と動摩擦係数の差が0.2以下であると相手部材と摺接する際に不快な異音が発生しない。 Furthermore, in the above sliding surface, the difference between the coefficient of static friction and the coefficient of dynamic friction when sliding in a direction perpendicular to the ridge direction in a wet state is preferably 0.2 or less, more preferably 0.1 or less It is inside. When the difference between the static friction coefficient and the dynamic friction coefficient is 0.2 or less, unpleasant noise does not occur when sliding contact with the other member.
ここで、「湿潤状態」とは、摩擦相手材を水に30秒浸漬することをいう。また、「静摩擦係数」と「動摩擦係数」とは、新東化学(株)製表面性測定機 トライボギア(TYPE:HEIDON−14DR)を用い、移動速度100mm/min、荷重2.0kgで、平面圧子(面積10×10mm)に布帛をビス固定し摺動織物の摺動面の凸条部の方向に対して摩擦相手材である表面粗さ0.8μmのガラス板を直角方向に摺動させて静・動摩擦係数を求めたことをいう。さらに、「静摩擦係数と動摩擦係数の差」とは、(静摩擦係数−動摩擦係数)をいう。 Here, the "wet state" refers to immersing the friction partner in water for 30 seconds. The "static coefficient of friction" and the "dynamic coefficient of friction" are surface indenters with a moving speed of 100 mm / min and a load of 2.0 kg using a Shinto Chemical Co., Ltd. surface property measuring device Tribogear (TYPE: HEIDON-14DR). (Aspect 10 × 10 mm) By screwing the fabric to the area 10 × 10 mm, slide the glass plate with a surface roughness of 0.8 μm, which is the friction partner, at right angles to the direction of the ridges of the sliding surface of the sliding fabric. It means that static and dynamic coefficient of friction was determined. Furthermore, "the difference between the static friction coefficient and the dynamic friction coefficient" means (static friction coefficient-dynamic friction coefficient).
以下、太いフッ素樹脂繊維を配することにより摺動面に凸条部を形成する方法について、詳しく説明する。 Hereinafter, the method of forming a convex part in a sliding face by arranging thick fluorocarbon resin fibers is explained in detail.
<フッ素樹脂繊維>
本発明において、フッ素樹脂繊維の成分であるフッ素樹脂としては、フッ素樹脂としては、主鎖または側鎖にフッ素原子を1個以上含む単量体単位で構成されたものであればよい。その中でも、フッ素原子数の多い単量体単位で構成されたものが好ましい。
<Fluororesin fiber>
In the present invention, as the fluorine resin which is a component of the fluorine resin fiber, any fluorine resin may be used as long as it is composed of a monomer unit containing one or more fluorine atoms in the main chain or side chain. Among them, those composed of monomer units having a large number of fluorine atoms are preferable.
上記フッ素原子を1個以上含む単量体単位は、重合体の繰り返し構造単位の70%以上含むことが好ましく、90%以上を含むことがより好ましく、95モル%以上含むことがさらに好ましい。 The monomer unit containing one or more fluorine atoms is preferably 70% or more of the repeating structural unit of the polymer, more preferably 90% or more, and still more preferably 95% by mol or more.
フッ素原子を1個以上含む単量体としては、テトラフルオロエチレン、ヘキサフルオロプロピレン、クロロトリフルオロエチレンなどのフッ素原子含有ビニル系単量体が挙げられ、中でも少なくともテトラフルオロエチレンを用いることが好ましい。 Examples of the monomer containing one or more fluorine atoms include fluorine atom-containing vinyl monomers such as tetrafluoroethylene, hexafluoropropylene, chlorotrifluoroethylene and the like, and it is preferable to use at least tetrafluoroethylene.
フッ素樹脂としては、例えば、ポリテトラフルオロエチレン(PTFE)、テトラフルオロエチレン−ヘキサフルオロプロピレン共重合体(FEP)、テトラフルオロエチレン−p−フルオロアルキルビニルエーテル共重合体(PFA)、ポリクロロトリフルオロエチレン(PCTFE)、エチレン−テトラフルオロエチレン共重合体(ETFE)等を単独または2種類以上ブレンドしたものを使用することができる。 As a fluorine resin, for example, polytetrafluoroethylene (PTFE), tetrafluoroethylene-hexafluoropropylene copolymer (FEP), tetrafluoroethylene-p-fluoroalkyl vinyl ether copolymer (PFA), polychlorotrifluoroethylene It is possible to use (PCTFE), an ethylene-tetrafluoroethylene copolymer (ETFE), etc. singly or in combination of two or more.
テトラフルオロエチレン単位を含むフッ素樹脂においては、摺動特性の点からテトラフルオロエチレン単位の含有量は多い方が好ましく、ホモポリマーとしてのPTFE繊維を用いるのが最も好ましい。 In the case of a fluorine resin containing tetrafluoroethylene units, the content of tetrafluoroethylene units is preferably as large as possible from the viewpoint of sliding properties, and it is most preferable to use a PTFE fiber as a homopolymer.
本発明のフッ素樹脂繊維の形態としては、1本のフィラメントで構成されるモノフィラメント、複数本のフィラメントで構成されるマルチフィラメントのいずれも用いることができる。 As a form of the fluorocarbon resin fiber of the present invention, any of a monofilament composed of one filament and a multifilament composed of a plurality of filaments can be used.
また、本発明の太いフッ素樹脂繊維を構成するモノフィラメントまたはマルチフィラメントからなる繊維の総繊度は、他の糸の繊度に対して、繊度比で10〜30倍の範囲内が好ましく、さらに好ましくは20〜30倍の範囲内である。前記繊度比が10倍以上であると布帛表に凸条部と基部が交互に形成されることができる。30倍以下であれば凸条部が弾性変形しにくく、凸条部だけが相手材と接着し接触面積が小さくなることにより接圧が高くなり、静・動摩擦係数の差が小さくなり、また効率よく水を排出でき、相手部材と摺接する際に不快な異音が発生しまい。 The total fineness of monofilaments or multifilaments constituting the thick fluorocarbon resin fiber of the present invention is preferably in the range of 10 to 30 times the fineness ratio with respect to the fineness of the other yarn, more preferably 20. It is in the range of -30 times. When the fineness ratio is 10 times or more, the ridges and the base can be alternately formed on the surface of the fabric. If it is 30 times or less, the ridges are unlikely to be elastically deformed, and only the ridges adhere to the mating member and the contact area becomes smaller, so the contact pressure becomes high, the difference in static and dynamic friction coefficients becomes small, and the efficiency Water can be drained well and unpleasant noise is generated when sliding contact with the other member.
ここで、「他の糸」とは、摺動布帛を構成する構成糸のうち、上記太いフッ素樹脂繊維以外の糸をいい、フッ素樹脂繊維であっても、後述する他の繊維であってもよい。 Here, the “other yarn” refers to yarns other than the thick fluorocarbon resin fibers among the constituent yarns constituting the sliding fabric, and may be fluorocarbon resin fibers or other fibers described later. Good.
なお、前記太いフッ素樹脂繊維を構成するモノフィラメントまたはマルチフィラメントからなる繊維の総繊度としては、具体的には、400dtex以上が好ましく、さらに好ましくは800〜15000dtexの範囲内である。これにより、製織時の糸毛羽、糸切れが低減でき工程通過性がよい。 In addition, as a total denier of the fiber which consists of a monofilament or a multifilament which comprises the said thick fluororesin fiber, specifically, 400 dtex or more is preferable, More preferably, it exists in the range of 800-15000 dtex. As a result, yarn fuzz and yarn breakage can be reduced during weaving, and process passability is good.
また、他の糸として使用するフッ素樹脂繊維を構成するモノフィラメントまたはマルチフィラメントからなる繊維の総繊度としては、具体的には、1000dtex以下であることが好ましく、さらに好ましくは500dtex以下の範囲内であって、太いフッ素樹脂繊維よりも相対的に細繊度のものである。これにより、製織時の糸毛羽、糸切れが低減でき工程通過性がよい。 The total fineness of monofilaments or multifilaments constituting the fluorocarbon resin fibers used as other yarns is preferably 1000 dtex or less, more preferably 500 dtex or less. It is relatively finer than thick fluorocarbon resin fibers. As a result, yarn fuzz and yarn breakage can be reduced during weaving, and process passability is good.
<他の繊維>
本発明においては、上記フッ素樹脂繊維以外に他の繊維を使用することができる。
<Other fibers>
In the present invention, other fibers can be used besides the above-mentioned fluororesin fiber.
本発明において、他の繊維としては、例えば、ポリフェニレンサルファイド(PPS)、ポリパラフェニレンテレフタルアミド、ポリメタフェニレンイソフタルアミド、ガラス、炭素、ナイロン、ポリエステル等の繊維を使用することができる。これらは1種または2種以上で用いることが好ましい。中でも引張弾性率が低く、連続使用耐高温特性が良いPPS繊維を用いるのが好ましい。また、非摺動面に接着性能が要求される場合は、ナイロン繊維を用いるのが好ましい。また、高荷重の使用環境で、高強度特性が良いポリパラフェニレンテレフタルアミド、ガラス繊維等を用いることが好ましい。 In the present invention, as other fibers, fibers such as polyphenylene sulfide (PPS), polyparaphenylene terephthalamide, polymetaphenylene isophthalamide, glass, carbon, nylon, polyester and the like can be used. It is preferable to use one or two or more of these. Among them, it is preferable to use a PPS fiber having a low tensile modulus and good continuous use high temperature resistance characteristics. When adhesion performance is required for the non-sliding surface, it is preferable to use nylon fiber. In addition, it is preferable to use polyparaphenylene terephthalamide, glass fiber or the like which has high strength characteristics in a high load use environment.
本発明の他の繊維の形態としては、1本のフィラメントで構成されるモノフィラメント、複数本のフィラメントで構成されるマルチフィラメントのいずれも用いることができる。 As a form of other fibers of the present invention, any of a monofilament composed of one filament and a multifilament composed of a plurality of filaments can be used.
また、本発明の他の繊維を構成するモノフィラメントまたはマルチフィラメントからなる繊維の総繊度としては、具体的には、1000dtex以下であることが好ましく、さらに好ましくは500dtex以下の範囲内であって、太いフッ素樹脂繊維よりも相対的に細繊度のものである。これにより、製織時の糸毛羽、糸切れが低減でき工程通過性がよい。 The total fineness of monofilament or multifilament fibers constituting other fibers of the present invention is specifically preferably 1000 dtex or less, more preferably 500 dtex or less, and thick It is relatively fine in size than fluoroplastic fibers. As a result, yarn fuzz and yarn breakage can be reduced during weaving, and process passability is good.
<摺動布帛>
本発明の一実施形態による摺動布帛は、布帛の摺動面において、タテ糸(またはヨコ糸)を構成する糸が、一方向に延在するフッ素樹脂繊維を含む凸条部と他の糸を含む基部とが交互に配置されている。
<Sliding cloth>
In the sliding fabric according to one embodiment of the present invention, in the sliding surface of the fabric, a yarn constituting the warp yarn (or weft yarn) includes a ridge and a yarn including a fluorocarbon resin fiber extending in one direction And the base including the two are alternately arranged.
ここで、布帛の摺動面の一方向に、フッ素樹脂繊維の凸条部と他の糸の基部とを交互に配置されている形態としては、太いフッ素樹脂繊維をA、他の糸をB及びCとした場合、例えば、
A1本/B1本
A1本/B6本、
A1本/B3本/C2本/A3本/B4本/C1本、
等とすることができる。
Here, as a form in which the ridges of the fluorocarbon resin fiber and the bases of other yarns are alternately arranged in one direction of the sliding surface of the fabric, thick fluorocarbon resin fibers A and other yarns B And C, for example,
A1 / B1 A1 / B6,
A1 / B3 / C2 / A3 / B4 / C1,
And so on.
そして、タテ糸として太いフッ素樹脂繊維と他の糸とを交互に配置し、ヨコ糸として「他の糸」又は「他の糸」のいずれかを配置することができる。また、タテ糸として「他の糸」又は「他の糸」のいずれかを配置し、ヨコ糸として太いフッ素樹脂繊維と他の糸とを交互に配置してもよい。 Then, thick fluororesin fibers and other yarns can be alternately arranged as warp yarns, and either “other yarns” or “other yarns” can be arranged as weft yarns. Alternatively, either “other yarn” or “other yarn” may be arranged as the warp yarn, and thick fluororesin fibers and other yarn may be alternately arranged as the weft yarn.
なお、本発明において「太いフッ素樹脂繊維と他の糸とを交互に配置する」とは、太いフッ素繊維と1種又は2種類以上の他の繊維が代わる代わる配置されていることをいう。 In the present invention, "a thick fluorine resin fiber and another yarn are alternately arranged" means that a thick fluorine fiber and one or more kinds of other fibers are alternately substituted.
また、本発明の摺動布帛を構成する他の糸は、1種類または2種類以上使用することができるが、1種類であることが好ましい。ここでいう1種類とは、繊維を構成する素材が同じである場合に1種類とする。同種のポリマーとは、ナイロン66同士、ポリエチレンテレフタレート同士等、ポリマーの主たる繰り返し単位が共通するポリマー同士を言い、例えばホモポリマーとその共重合ポリマーとの組み合わせも、本発明でいう同種のポリマーとして許容される。 Moreover, although other types of yarn constituting the sliding fabric of the present invention may be used alone or in combination of two or more, one type is preferable. Here, one kind is used when the material constituting the fiber is the same. Polymers of the same kind are polymers in which the main repeating units of the polymers are in common, such as nylon 66, polyethylene terephthalates, etc. For example, the combination of homopolymer and copolymer thereof is also acceptable as the same kind of polymer in the present invention Be done.
異なる繊維を使用した場合、伸縮性能に差があるため、使用する繊維の種類が少ないほど、製織時の条件設定がしやすく、また後加工時の布帛表面に収縮差によるシワがでにくく、工程通過性が向上する。 When different fibers are used, since there is a difference in expansion performance, it is easier to set the condition at the time of weaving as the type of fibers used is smaller, and wrinkles due to shrinkage difference are less likely to occur on the surface of the fabric during post-processing Passability improves.
また、本発明の該摺動布帛の形態としては、織物、編物及びこれらをエンボス加工するのいずれも適用できるが、緻密性等が高い方がよいことなどから織物が好ましい。織物としては、一重または二重以上の多重織物とすることができるが、2重織物であることが好ましい。太いフッ素樹脂繊維を含む摺動面とその他繊維、好適には非フッ素繊維で構成されるその他の面の二重織物であることがさらに好ましい。その他の面とは他材と接着性の良好な繊維を配することで接着面を使用することが出来る。これにより、ゴムなどの接着材との接着性、と摺動面としての摺動性を両立することができる。 Further, as the form of the sliding fabric of the present invention, although any of woven fabric, knitted fabric and embossing thereof can be applied, woven fabric is preferable because it is preferable that the denseness and the like are high. The fabric may be a single fabric or a double or more multiple fabric, but is preferably a double fabric. More preferably, it is a double woven fabric of a sliding surface including thick fluorocarbon resin fibers and other fibers, preferably other surfaces composed of non-fluorine fibers. The other side can use an adhesive side by arranging a fiber having good adhesion to other materials. Thereby, the adhesiveness with adhesive materials, such as rubber | gum, and the slidability as a sliding surface can be compatible.
特に多重織物として、2重織物等の多重織物とする場合、摺動面側の最外層の経糸又は緯糸を、太いフッ素樹脂繊維で構成し、摺動面側からみて最外層より下側の層に他の糸を配し、最外層の織密度を下側の層の織密度より小さくすることで、太いフッ素樹脂繊維で構成される凸条部の間に他の糸で構成される基部を形性することも好ましい態様である。 In particular, in the case of using multiple fabrics such as double fabrics as multiple fabrics, the outermost warp or weft of the sliding surface side is made of thick fluorocarbon resin fibers, and the layer below the outermost layer viewed from the sliding surface side By arranging the other yarn in the lower layer and making the weave density of the outermost layer smaller than the weave density of the lower layer, the base composed of another Forming is also a preferred embodiment.
また、本発明の摺動布帛の組織は、平織、綾織、サテンおよびその他組織が適用できるが、緻密性、強力等が高い方がよいことなどから平織、綾織が好ましい。 Further, as the structure of the sliding fabric of the present invention, plain weave, twill weave, satin and other weaves can be applied, however, plain weave and twill weave are preferable because the higher the compactness and the strength etc., the better.
さらに耐久性を高めるために、前記摺動布帛に樹脂を含浸して使用することも可能である。ここで、樹脂含浸する樹脂は、熱硬化性樹脂や熱可塑性樹脂を用いることができる。特に限定されるものではないが、熱硬化性樹脂としては、例えば、フェノール樹脂、メラミン樹脂、ユリア樹脂、不飽和ポリエステル樹脂、エポキシ樹脂、ポリウレタン樹脂、ジアリルフタレート樹脂、珪素樹脂、ポリイミド樹脂、ビニルエステル樹脂などやその変性樹脂など、熱可塑性樹脂であれば塩化ビニル樹脂、ポリスチレン、ABS樹脂、ポリエチレン、ポリプロピレン、フッ素樹脂、ポリアミド樹脂、ポリアセタール樹脂、ポリカーボネート樹脂、ポリエステル、ポリアミドなど、さらには熱可塑性ポリウレタン、ブタジエンゴム、ニトリルゴム、ネオプレン、ポリエステル等の合成ゴム又はエラストマーなどが好ましく使用できる。中でも、フェノール樹脂とポリビニルブチラール樹脂とを主成分とする樹脂、不飽和ポリエステル樹脂、ビニルエステル樹脂、ポリエチレン、ポリプロピレン等のポリオレフィン系樹脂、ポリエステル樹脂が、耐衝撃性、寸法安定性、強度、価格などから好ましく使用できる。かかる熱硬化性樹脂及び熱可塑性樹脂には、工業的にその目的、用途、製造工程や加工工程での生産性あるいは特性改善のため通常使用されている各種添加剤を含んでいてもよい。例えば、変性剤、可塑剤、充填剤、離型剤、着色剤、希釈剤などを含有せしめることができる。なお、ここでいう主成分とは、溶媒を除いた成分のうちで重量比率が一番大きい成分をいい、フェノール樹脂とポリビニルブチラール樹脂を主成分とする樹脂の場合では、これら2種類の樹脂の重量比率が1番目、2番目(順不同)に大きいことを意味する。 In order to further enhance the durability, it is possible to use the sliding fabric impregnated with a resin. Here, a thermosetting resin or a thermoplastic resin can be used as the resin impregnated. Although not particularly limited, examples of the thermosetting resin include phenol resin, melamine resin, urea resin, unsaturated polyester resin, epoxy resin, polyurethane resin, diallyl phthalate resin, silicon resin, polyimide resin, vinyl ester Resins, etc. and their modified resins, as long as they are thermoplastic resins, vinyl chloride resin, polystyrene, ABS resin, polyethylene, polypropylene, fluorine resin, polyamide resin, polyacetal resin, polycarbonate resin, polycarbonate, polyester, polyamide etc., and further thermoplastic polyurethane, Synthetic rubbers or elastomers such as butadiene rubber, nitrile rubber, neoprene, polyester and the like can be preferably used. Among them, resins mainly composed of phenol resin and polyvinyl butyral resin, unsaturated polyester resins, vinyl ester resins, polyolefin resins such as polyethylene and polypropylene, polyester resins are impact resistance, dimensional stability, strength, price etc. It can be preferably used. The thermosetting resin and the thermoplastic resin may contain various additives which are generally used industrially for the purpose, application, productivity in the manufacturing process or processing process, or property improvement. For example, modifiers, plasticizers, fillers, mold release agents, colorants, diluents and the like can be contained. The term "main component" as used herein refers to the component having the largest weight ratio among the components excluding the solvent, and in the case of a resin containing a phenol resin and a polyvinyl butyral resin as main components, It means that the weight ratio is the first and second (in random order) large.
前記摺動布帛に樹脂を含浸する方法としては、熱硬化性樹脂を用いる場合は、熱硬化性樹脂を溶剤に溶解してワニスに調整し、ナイフコート加工やロールコート加工、コンマコート加工、グラビアコート加工などで布帛に含浸コートする方法が一般的に用いられる。また、熱可塑性樹脂を用いる場合には溶融押し出しラミネートなどが一般的に用いられる。 In the case of using a thermosetting resin as a method of impregnating the sliding fabric with a resin, the thermosetting resin is dissolved in a solvent to prepare a varnish, and knife coating, roll coating, comma coating, gravure A method of impregnating the fabric by coating or the like is generally used. In the case of using a thermoplastic resin, a melt extrusion laminate is generally used.
本発明の摺動布帛に、必要に応じフッ素系潤滑剤などを添加することも可能である。 It is also possible to add a fluorine-based lubricant and the like to the sliding fabric of the present invention as required.
かくして得られる本発明の摺動布帛は、凸条部だけが相手材と接着し接触面積が小さくなることにより接圧が高くなり、静・動摩擦係数の差が小さくなり、相手部材と摺接する際に不快な異音が発生しない。 In the sliding fabric of the present invention thus obtained, only the ridges adhere to the mating member and the contact area is reduced, so that the contact pressure is increased, and the difference between the static and dynamic friction coefficients is reduced. No unpleasant noise is generated.
また、本発明のウインドウガラススタビライザは、上記の摺動布帛を、面接部材の少なくとも一部に用いてなることを特徴とする。なお、面接部材としては、摺動面における凸条部が延在する方向と、ウインドウガラスの移動方向とを直角にして配置することが好ましい。これによりウインドウガラス表面の水を効率よく排出でき、降雨等によりウインドウガラスに水滴が付着して面接部材が湿潤しても、ウインドウガラス開閉時に前記ガラス面と面接部材が摺接する際に不快な異音が発生しない。 The window glass stabilizer of the present invention is characterized by using the above-mentioned sliding cloth as at least a part of the interview member. As the interview member, it is preferable that the direction in which the ridges in the sliding surface extend and the moving direction of the window glass be at right angles. As a result, the water on the surface of the window glass can be efficiently drained, and even if water droplets adhere to the window glass due to rainfall etc. and the interview member gets wet, it is unpleasant when the glass surface and the interview member slide when opening and closing the window glass. There is no sound.
以下、本発明の実施例を比較例と共に説明する。 Hereinafter, examples of the present invention will be described together with comparative examples.
なお、本実施例で用いる各種特性の測定方法は、以下のとおりである。 In addition, the measuring method of the various characteristics used by a present Example is as follows.
(1)凸条部の面積
凸条部と基部が交互に形成された布帛表面に表面粗さ0.8μmの無色ガラス板を100paの接圧で置き、これをキーエンス製マイクロスコープVHX−2000にて30倍に拡大した写真をもとに、1cm×1cm範囲内のガラス板と接触する凸条部の面積を測定した。この操作を5回繰り返し、平均値を計算して凸条部の面積とした。
(1) Area of convex streaks A colorless glass plate with a surface roughness of 0.8 μm is placed on the surface of a cloth in which convex streaks and bases are alternately formed at a contact pressure of 100 pa, and this is placed on Microscience VHX-2000 made by Keyence. The area of the ridges in contact with the glass plate in the 1 cm × 1 cm range was measured based on the photograph magnified 30 times. This operation was repeated five times, and the average value was calculated to be the area of the ridges.
なお、表面粗さはJIS B0601−2001に準じてMITUTOYO SJ−201表面粗さ測定機で測定したRa値である(以下同じ)。 In addition, surface roughness is an Ra value measured by MITUTOYO SJ-201 surface roughness measuring device according to JIS B0601-2001 (the same applies to the following).
(2)基部の面積
凸条部と基部が交互に形成された布帛表面に表面粗さ0.8μmの無色ガラス板を100paの接圧で置き、これをキーエンス製マイクロスコープVHX−2000にて30倍に拡大した写真をもとに、1cm×1cm範囲内のガラス板と接触しない基部の投影面積を測定した。この操作を5回繰り返し平均値を計算して基部の面積とした。
(2) Area of base Place a colorless glass plate with a surface roughness of 0.8 μm under a contact pressure of 100 pa on the surface of the fabric in which the ridges and the base are alternately formed, and place this on a Keyence microscope VHX-2000 for 30 The projected area of the base not in contact with the glass plate in the 1 cm × 1 cm range was measured based on the double-magnified photograph. This operation was repeated 5 times and the average value was calculated to be the area of the base.
(3)凸条部の高さ
凸条部と基部が交互に形成された布帛表面に表面粗さ0.8μmの無色ガラス板を100pa置いており、これをキーエンス製マイクロスコープVHX−2000にて30倍に拡大した写真をもとに、1cm×1cm範囲内の基部の表面からガラス板までの距離をn=5測定し平均値を計算した。
(3) Height of ridges A colorless glass plate with a surface roughness of 0.8 μm is placed for 100 pas on the surface of the fabric in which ridges and bases are alternately formed, and this is used with Keyence Microscope VHX-2000. Based on a photograph magnified 30 times, the distance from the surface of the base to the glass plate in the 1 cm × 1 cm range was measured at n = 5 and the average value was calculated.
(4)繊維の繊度
JIS L1013:2010(化学繊維フィラメント糸試験方法)に準じて繊維の繊度を測定した。
(4) Fineness of fiber The fineness of the fiber was measured according to JIS L1013: 2010 (chemical fiber filament yarn test method).
(5)静・動摩擦係数差(トライボギア表面摩擦)
新東化学(株)製表面性測定機 トライボギア(TYPE:HEIDON−14DR)を用い、移動速度100mm/min、荷重2.0kgで、平面圧子(面積10×10mm)に湿潤状態における布帛をビス固定し摺動織物面と表面粗さ0.8μmのガラス板との摩擦係数を測定し、静・動摩擦係数差を求めた。測定は恒温恒湿環境下(20±2℃、60±5%RH)にて、織物の摺動面の凸条部の方向に対して直角方向に摺動させて測定した。
(5) Static and dynamic coefficient of friction difference (tribo gear surface friction)
Shinto Kagaku Co., Ltd. surface property measurement machine Tribo gear (TYPE: HEIDON-14DR), moving speed 100 mm / min, load 2.0 kg, fixed the cloth in the wet condition to the flat indenter (area 10 x 10 mm) The coefficient of friction between the sliding woven fabric surface and the glass plate with a surface roughness of 0.8 μm was measured to determine the difference between the static and dynamic friction coefficients. The measurement was made by sliding in a direction perpendicular to the direction of the ridges of the sliding surface of the fabric under a constant temperature and humidity environment (20 ± 2 ° C., 60 ± 5% RH).
(6)異音測定
凸条部と基部が交互に形成された摺動布帛表面を面接部材として、凸条方向に対し直角にガラス板が上下する態様で取り付けられたウインドウガラススタビライザをウインドウガラス格納庫本体内のウェスト開口部付近に取り付けたウインドウガラス開閉装置を用い、降水する環境下でウインドウガラスを上下し、10万回の期間、不快な異音程度を確認し、ほとんどないものを◎、わずかなものを○、顕著にあるものを△、耳障りであるものを×とした。
(6) Measurement of abnormal noise A window glass stabilizer attached to a window glass stabilizer attached in such a manner that a glass plate vertically moves in a direction perpendicular to the direction of a ridge as a sliding fabric surface in which ridges and bases are alternately formed as an interview member. Using the window glass opening and closing device attached near the waist opening in the main body, move the window glass up and down in a precipitation environment, check the degree of unpleasant noise for 100,000 times, and も の, little Those with ○ were marked, those marked with Δ, and those marked with ax were marked ×.
実施例1
摺動層として、1330dtexのPTFE繊維を4本合撚した糸をタテ糸に用い、440dtexPTFE繊維をヨコ糸に用いた。また、ベース層として220dtexのPPS繊維をタテ糸、及びヨコ糸に用いた。そして、摺動層の織り密度がタテ14+ヨコ62本/inch(2.54cm)、ベース層の織り密度がタテ84+ヨコ62本/inch(2.54cm)となるように、織機にて摺動層が綾織、ベース層が平織の2重織物を製作した。その後80℃の精練槽にて精練を行い、200℃でセットした。
Example 1
As a sliding layer, a yarn obtained by combining four 1330 dtex PTFE fibers is used as a warp yarn, and 440 dtex PTFE fiber is used as a weft yarn. In addition, 220 dtex PPS fiber was used for the warp yarn and the weft yarn as a base layer. And it slides with the loom so that the weave density of the sliding layer is 14 vertical + 62 horizontal / inch (2.54 cm), and the weave density of the base layer is vertical 84 + 62 horizontal / inch (2.54 cm) A double layer fabric with twill layer and plain layer was produced. Thereafter, scouring was performed in a scouring tank at 80 ° C., and set at 200 ° C.
この織物の凸条部と基部の面積比、凸条部の高さ、またトライボギア表面摩擦機で評価した静摩擦係数0.186、動摩擦係数0.146であり、静・動摩擦係数差結果とウインドウガラススタビライザの面接部材として異音評価した結果を表1にまとめた。 The area ratio of the ridge to the base of this fabric, the height of the ridge, the static coefficient of friction 0.186 and the dynamic coefficient of friction 0.146 evaluated with a tribo gear surface friction machine, the difference between static and dynamic coefficient of friction results and window glass Table 1 summarizes the results of the abnormal noise evaluation as an interview member for the stabilizer.
実施例2
110dtexのナイロン繊維をタテ糸に用い、10000dtexのPTFE繊維と、600dtexのPPS繊維を1(本):6(本)にて交互に配置してヨコ糸に用い、織り密度がタテ140+ヨコ42本/inch(2.54cm)となるように、織機にて一重平織物を製作した。その後80℃の精練槽にて精練を行い、200℃でセットした。その後、ロールコート加工方式でフッ素樹脂含浸加工した。
Example 2
110 dtex nylon fibers are used for the warp, 10000 dtex PTFE fibers and 600 dtex PPS fibers are alternately arranged in 1 (6): 6 (webs) for the weft yarn, and the weave density is 140 vertical + 42 horizontal A single flat woven fabric was produced with a loom so as to be / inch (2.54 cm). Thereafter, scouring was performed in a scouring tank at 80 ° C., and set at 200 ° C. Thereafter, a fluorine resin impregnation process was performed by a roll coat process method.
この織物の凸条部と基部の面積比、凸条部の高さ、またトライボギア表面摩擦機で評価した静・動摩擦係数差結果とウインドウガラススタビライザの面接部材として異音評価した結果を表1にまとめた。 Table 1 shows the area ratio between the ridges and the base of the woven fabric, the height of the ridges, and the difference between static and dynamic coefficient of friction evaluated with a tribo gear surface friction machine and the result of noise evaluation as an interview member of the window glass stabilizer. Summarized.
実施例3
110dtexのナイロン繊維をタテ糸に用い、10000dtexのPTFE繊維と、1000dtexのPET繊維と、440dtexPPS繊維を1(本):4(本):2(本)にて交互に配置してヨコ糸に用い、織り密度がタテ140+ヨコ42本/inch(2.54cm)となるように、織機にて一重平織物を製作した。その後80℃の精練槽にて精練を行い、200℃でセットした。その後、ロールコート加工方式でフッ素樹脂含浸加工した。
Example 3
A 110 dtex nylon fiber is used as a warp, and a 10000 dtex PTFE fiber, a 1000 dtex PET fiber, and a 440 dtex PPS fiber are alternately arranged at 1 (book): 4 (book): 2 (book) and used for the weft yarn , A single flat woven fabric was produced with a loom so that the weave density would be 140 vertical + 42 horizontal / inch (2.54 cm). Thereafter, scouring was performed in a scouring tank at 80 ° C., and set at 200 ° C. Thereafter, a fluorine resin impregnation process was performed by a roll coat process method.
この織物の凸条部と基部の面積比、凸条部の高さ、またトライボギア表面摩擦機で評価した静・動摩擦係数差結果とウインドウガラススタビライザの面接部材として異音評価した結果を表1にまとめた。 Table 1 shows the area ratio between the ridges and the base of the woven fabric, the height of the ridges, and the difference between static and dynamic coefficient of friction evaluated with a tribo gear surface friction machine and the result of noise evaluation as an interview member of the window glass stabilizer. Summarized.
実施例4
摺動層として、1330dtexのPTFE繊維を8本合撚する糸を表用タテ糸に用い、また、ベース層として220dtexのPPS繊維を裏用タテ糸に用いた。コース数10コース/inch(2.54cm)、ウェル数56ウェル/inch(2.54cm)となるように、タテ編み機にて2重編み物を製作した。その後80℃の精練槽にて精練を行い、200℃でセットした。その後、表面に軸径方向凸条模様高さ0.1mmのロールを使い、エンボス加工方式で摺動層表面にタテ糸方向と平行になるように延在した凸条部と基部に交互される形態を加工した。
Example 4
As a sliding layer, a yarn obtained by combining eight 1330 dtex PTFE fibers was used as a front warp, and as a base layer, 220 dtex PPS fibers were used as a back warp. A double-knitted fabric was manufactured with a warp knitting machine so that the number of courses was 10 courses / inch (2.54 cm) and the number of wells was 56 wells / inch (2.54 cm). Thereafter, scouring was performed in a scouring tank at 80 ° C., and set at 200 ° C. After that, using a roll with an axial radial direction ridged pattern height of 0.1 mm on the surface, alternating with a ridged portion and a base extending in parallel to the warp direction on the sliding layer surface by embossing method I processed the form.
この織物の凸条部と基部の面積比、凸条部の高さ、またトライボギア表面摩擦機で評価した静・動摩擦係数差結果とウインドウガラススタビライザの面接部材として異音評価した結果を表1にまとめた。 Table 1 shows the area ratio between the ridges and the base of the woven fabric, the height of the ridges, and the difference between static and dynamic coefficient of friction evaluated with a tribo gear surface friction machine and the result of noise evaluation as an interview member of the window glass stabilizer. Summarized.
比較例1
摺動層として、440dtexのPTFE繊維をパイル部分に用い、また、ベース層として600dtexのPET繊維をタテ糸、及びヨコ糸に用いた。そして、パイルの高さ3mm、ベース層の織り密度がタテ60+ヨコ60本/inch(2.54cm)となるように、一般的にパイル織機により製織された後、パイルの毛抜け止めるため、パイル面と反対の裏面に樹脂コーティングを行なった。
Comparative Example 1
As a sliding layer, 440 dtex PTFE fibers were used for the pile portion, and as a base layer, 600 dtex PET fibers were used for the warp yarn and the weft yarn. The pile is generally woven by a pile loom so that the height of the pile is 3 mm and the weave density of the base layer is 60 + 60 60 / inch (2.54 cm), and then the pile is prevented from falling off. The resin coating was applied to the back side opposite to the side.
この織物のトライボギア表面摩擦機で評価した静・動摩擦係数差結果とウインドウガラススタビライザ摺動材としての異音評価した結果を表2にまとめた。 The static and dynamic friction coefficient difference results of this woven fabric evaluated by the tribo gear surface friction machine and the results of the evaluation of abnormal noise as a window glass stabilizer sliding material are summarized in Table 2.
比較例2
摺動層として、440dtexのPTFE繊維をタテ糸、及びヨコ糸に用い、また、ベース層として220dtexのPPS繊維をタテ糸、及びヨコ糸に用いた。そして、摺動層の織り密度がタテ70+ヨコ64本/inch(2.54cm)、ベース層の織り密度がタテ70+ヨコ64本/inch(2.54cm)となるように、織機にて平織の2重織物を製作した。その後実施例1と同様の精練、セット処理を行なった。
Comparative example 2
As a sliding layer, 440 dtex PTFE fibers were used for the warp and weft yarns, and as a base layer, 220 dtex PPS fibers were used for the warp and weft yarns. And, the weaving density of the sliding layer is a plain weave with a loom so that the weave density of the slide layer is 70 + 64 sides / inch (2.54 cm) and the weave density of the base layer is 70% × 64 sides / inch (2.54 cm). I made a double fabric. Thereafter, the same scouring and setting process as in Example 1 was performed.
この織物の凸条部と基部の面積比、凸条部の高さ、またトライボギア表面摩擦機で評価した静・動摩擦係数差結果とウインドウガラススタビライザの面接部材としての異音評価した結果を表2にまとめた。 Table 2 shows the area ratio between the ridges and the base of the fabric, the height of the ridges, and the difference between the static and dynamic coefficient of friction results evaluated with a tribo gear surface friction machine and the noise evaluation results as an interview member of the window glass stabilizer. Summarized.
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|---|---|---|---|---|
| JPWO2022209961A1 (en) * | 2021-03-29 | 2022-10-06 | ||
| US11969987B2 (en) | 2019-03-18 | 2024-04-30 | Ricoh Company, Ltd. | Contacting member, drying device, and printing apparatus |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11969987B2 (en) | 2019-03-18 | 2024-04-30 | Ricoh Company, Ltd. | Contacting member, drying device, and printing apparatus |
| JPWO2022209961A1 (en) * | 2021-03-29 | 2022-10-06 | ||
| WO2022209961A1 (en) * | 2021-03-29 | 2022-10-06 | 東レ株式会社 | Woven fabric and sliding material |
| JP7794124B2 (en) | 2021-03-29 | 2026-01-06 | 東レ株式会社 | Fabrics and sliding materials |
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| JP6957943B2 (en) | 2021-11-02 |
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