JP2016008175A - Oxidizing agent-containing emulsion composition - Google Patents
Oxidizing agent-containing emulsion composition Download PDFInfo
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- JP2016008175A JP2016008175A JP2014127525A JP2014127525A JP2016008175A JP 2016008175 A JP2016008175 A JP 2016008175A JP 2014127525 A JP2014127525 A JP 2014127525A JP 2014127525 A JP2014127525 A JP 2014127525A JP 2016008175 A JP2016008175 A JP 2016008175A
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- Prior art keywords
- emulsion composition
- containing emulsion
- hair
- oxidant
- agent
- Prior art date
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Landscapes
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Abstract
Description
本発明は、染毛剤で用いられる酸化剤含有乳化組成物に関するものである。 The present invention relates to an oxidant-containing emulsion composition used in a hair dye.
染毛剤としては、染毛剤、脱染剤、脱色剤、脱染・脱色剤などが知られており、２種類以上の剤を用時混合して調合される。染毛剤は一般的に第２剤として、毛髪の色を変化させるために酸化染料を毛髪中で化学反応（酸化重合）させ、色素を形成し毛髪内部に固定させたり、毛髪自身が持つメラニン色素を酸化反応によって分解して、毛髪を明るく見せる目的として、酸化剤含有組成物を用いられる。 As hair dyes, hair dyes, decoloring agents, decoloring agents, decoloring / decoloring agents and the like are known, and two or more kinds of agents are mixed at the time of use. Hair dyes are generally used as the second agent. In order to change the color of the hair, an oxidation dye is chemically reacted (oxidation polymerization) in the hair to form a pigment and fix it inside the hair, or the melanin that the hair itself has. An oxidant-containing composition is used for the purpose of degrading the pigment by an oxidation reaction and making hair look brighter.
従来、酸化剤含有組成物には酸化剤として過酸化水素が用いられる。過酸化水素は、不安定で酸素を放出して分解しやすく、この分解を抑えるため安定化剤として、フェナセチン、１−ヒドロキシエタン−１，１−ジホスホン酸、スズ酸ナトリウム、アセトアニリドなどが用いられる（例えば特許文献１および２）。 Conventionally, hydrogen peroxide is used as an oxidizing agent in an oxidizing agent-containing composition. Hydrogen peroxide is unstable and easily decomposes by releasing oxygen, and phenacetin, 1-hydroxyethane-1,1-diphosphonic acid, sodium stannate, acetanilide, etc. are used as stabilizers to suppress this decomposition. (For example, Patent Documents 1 and 2).
しかしながら、従来の技術では、過酸化水素の分解を抑制することが十分でなく、特に夏場の高温になる車内や、海外などへの運搬に用いられるコンテナ中で高温条件下に長時間さらされた場合、過酸化水素の安定性が低下してしまう問題があった。 However, the conventional technology is not sufficient to suppress the decomposition of hydrogen peroxide, and has been exposed to high temperature conditions for a long time in vehicles used for transportation to high temperatures in summer and overseas. In this case, there is a problem that the stability of hydrogen peroxide is lowered.
また、染毛剤に用いる酸化剤の酸化反応は、毛髪のメラニン色素だけでなく他の成分にも影響を及ぼすため毛髪が損傷してしまう問題があった。 In addition, the oxidation reaction of the oxidizing agent used for the hair dye has a problem that the hair is damaged because it affects not only the melanin pigment of the hair but also other components.
本発明は、上記問題を解決するため鋭意検討した結果、アルカリ剤を含有する第１剤と用時混合して使用される酸化剤含有乳化組成物であって、（Ａ）過酸化水素、（Ｂ）水、（Ｃ）アルカリ金属の水酸化物、（Ｄ）１−ヒドロキシエタン−１，１−ジホスホン酸、（Ｅ）油性成分および（Ｆ）界面活性剤を含有し、ｐＨ４．５以下である酸化剤含有乳化組成物を提供することによって本発明を完成させるに至った。 As a result of intensive studies to solve the above problems, the present invention is an oxidant-containing emulsion composition that is used by mixing with a first agent containing an alkaline agent, and comprises (A) hydrogen peroxide, ( B) Water, (C) Alkali metal hydroxide, (D) 1-hydroxyethane-1,1-diphosphonic acid, (E) oil component and (F) surfactant, pH 4.5 or less The present invention has been completed by providing a certain oxidizing agent-containing emulsion composition.
本発明は、保管条件や運搬条件を考慮する必要がなく、高温条件下に長時間さらされても、過酸化水素の安定性に優れた酸化剤含有乳化組成物であり、なおかつ染毛操作後のトリートメント性が高い染毛剤を提供することができる。 The present invention does not require consideration of storage conditions and transport conditions, and is an oxidant-containing emulsion composition that is excellent in hydrogen peroxide stability even after being exposed to high temperature conditions for a long time. It is possible to provide a hair dye with high treatment properties.
以下、本発明を詳細に説明する。本発明は、アルカリ剤を含有する第１剤と用時混合して使用される酸化剤含有乳化組成物であって、（Ａ）過酸化水素、（Ｂ）水、（Ｃ）アルカリ金属の水酸化物、（Ｄ）１−ヒドロキシエタン−１，１−ジホスホン酸、（Ｅ）油性成分および（Ｆ）界面活性剤を含有し、ｐＨ４．５以下である酸化剤含有乳化組成物である。 Hereinafter, the present invention will be described in detail. The present invention is an emulsifying agent-containing emulsified composition used by mixing with a first agent containing an alkali agent at the time of use, wherein (A) hydrogen peroxide, (B) water, (C) alkali metal water An oxidizing agent-containing emulsion composition containing an oxide, (D) 1-hydroxyethane-1,1-diphosphonic acid, (E) an oil component and (F) a surfactant, and having a pH of 4.5 or less.
本発明による酸化剤含有乳化組成物は（Ａ）過酸化水素を含有する。（Ａ）過酸化水素はアルカリ剤を含有する第１剤中に含有する酸化染料を毛髪中で化学反応（酸化重合）させ、色素を形成し毛髪内部に固定させ毛髪を染毛したり、毛髪自身が持つメラニン色素を酸化反応によって分解して、毛髪を明るく見せることができる。 The oxidizing agent-containing emulsion composition according to the present invention contains (A) hydrogen peroxide. (A) Hydrogen peroxide is a chemical reaction (oxidative polymerization) of the oxidative dye contained in the first agent containing an alkaline agent in the hair to form a pigment and fix it inside the hair to dye the hair, It can decompose the melanin pigment that it has by oxidation reaction and make hair look brighter.
本発明に用いる（Ａ）過酸化水素は酸化剤含有乳化組成物中に含有されていればよい。好ましくは１〜６重量％がよい。（Ａ）過酸化水素が１重量％未満の場合、酸化染料を十分に酸化重合することができないか、メラニンを十分に分解することができない恐れがある。また、（Ａ）過酸化水素が６重量％を超える場合、酸化剤含有乳化組成物を使用したとしても毛髪に負担がかかり毛髪を損傷する恐れがある。 (A) Hydrogen peroxide used for this invention should just be contained in the oxidizing agent containing emulsion composition. Preferably 1 to 6 weight% is good. (A) When hydrogen peroxide is less than 1% by weight, there is a possibility that the oxidative dye cannot be sufficiently oxidized and the melanin cannot be decomposed sufficiently. Moreover, when (A) hydrogen peroxide exceeds 6 weight%, even if it uses an oxidizing agent containing emulsion composition, there exists a possibility that a burden may be placed on hair and hair may be damaged.
本発明による酸化剤含有乳化組成物は（Ｂ）水を含有する。（Ｂ）水は各種成分の溶剤や分散溶媒として用いられる。また、（Ｂ）水は各種成分の溶剤として働くとともに、毛髪中での酸化染料の反応溶媒や、メラニン色素の分解反応溶媒として働く。製剤として適量含有される。 The oxidizing agent-containing emulsion composition according to the present invention contains (B) water. (B) Water is used as a solvent or dispersion solvent for various components. In addition, (B) water acts as a solvent for various components, and also acts as a reaction solvent for oxidative dyes in hair and a decomposition reaction solvent for melanin pigments. It is contained in an appropriate amount as a preparation.
本発明に用いる（Ｂ）水は酸化剤含有乳化組成物中に含有されていればよい。好ましくは４０重量％以上、さらに好ましくは６０重量％以上がよい。（Ｂ）水が４０重量％未満の場合、酸化剤含有乳化組成物を安定して形成することができない恐れがある。 (B) water used for this invention should just be contained in the oxidizing agent containing emulsion composition. Preferably it is 40 weight% or more, More preferably, 60 weight% or more is good. (B) When water is less than 40 weight%, there exists a possibility that an oxidizing agent containing emulsion composition cannot be formed stably.
本発明による酸化剤含有乳化組成物は（Ｃ）アルカリ金属の水酸化物を含有する。（Ｃ）アルカリ金属の水酸化物はｐＨ調整剤として用いられ、（Ａ）過酸化水素の安定性を向上する特筆すべき効果がある。 The oxidant-containing emulsion composition according to the present invention contains (C) an alkali metal hydroxide. (C) Alkali metal hydroxide is used as a pH adjuster, and (A) has a remarkable effect of improving the stability of hydrogen peroxide.
本発明に用いる（Ｃ）アルカリ金属の水酸化物は、特に限定されないが、水酸化リチウム、水酸化ナトリウム、水酸化カリウム、水酸化ルビジウム、水酸化セシウムが挙げられる。これら（Ｃ）アルカリ金属の水酸化物のうち、好ましくは水酸化ナトリウム、水酸化カリウムがよい。より好ましくは、水酸化カリウムがよい。これら（Ｃ）アルカリ金属の水酸化物は１または２種以上を含有してよい。 The (C) alkali metal hydroxide used in the present invention is not particularly limited, and examples thereof include lithium hydroxide, sodium hydroxide, potassium hydroxide, rubidium hydroxide, and cesium hydroxide. Of these (C) alkali metal hydroxides, sodium hydroxide and potassium hydroxide are preferred. More preferably, potassium hydroxide is good. These (C) alkali metal hydroxides may contain one or more.
本発明に用いる（Ｃ）アルカリ金属の水酸化物は酸化剤含有乳化組成物中に含有されていればよい。好ましくは０．００４〜１重量％、より好ましくは０．０２〜０．５重量％がよい。（Ｃ）アルカリ金属の水酸化物が０．００４％未満の場合、ｐＨ調整作用が十分に得られず（Ａ）過酸化水素を安定化することができない恐れがある。１重量％を超える場合、これ以上のｐＨ調整作用を得ることはできず、製剤の安定性に悪影響を及ぼす恐れがある。 The (C) alkali metal hydroxide used in the present invention may be contained in the oxidant-containing emulsion composition. Preferably it is 0.004-1 weight%, More preferably, 0.02-0.5 weight% is good. (C) When the alkali metal hydroxide is less than 0.004%, the pH adjusting action is not sufficiently obtained, and (A) hydrogen peroxide may not be stabilized. If it exceeds 1% by weight, no further pH adjustment effect can be obtained, and the stability of the preparation may be adversely affected.
本発明による酸化剤含有乳化組成物は（Ｄ）１−ヒドロキシエタン−１，１−ジホスホン酸を含有する。（Ｄ）１−ヒドロキシエタン−１，１−ジホスホン酸は（Ａ）過酸化水素の安定化剤として優れた金属封鎖作用、ｐＨ調整作用および（Ａ）過酸化水素の安定性向上作用がある。 The oxidizing agent-containing emulsion composition according to the present invention contains (D) 1-hydroxyethane-1,1-diphosphonic acid. (D) 1-hydroxyethane-1,1-diphosphonic acid has (A) an excellent metal sequestering action, pH adjusting action and (A) hydrogen peroxide stability improving action as a hydrogen peroxide stabilizer.
本発明に用いる（Ｄ）１−ヒドロキシエタン−１，１−ジホスホン酸は酸化剤含有乳化組成物中に含有されていればよい。好ましくは０．０１〜２重量％、より好ましくは０．０５〜１重量％がよい。（Ｄ）１−ヒドロキシエタン−１，１−ジホスホン酸が０．０１重量％未満の場合、ｐＨ調整作用が十分に得られず（Ａ）過酸化水素を安定化することができない恐れがあり、２重量％を超える場合、これ以上の金属封鎖作用やｐＨ調整作用を得ることはできず、かえって製剤の安定性に悪影響を及ぼす恐れがある。 The (D) 1-hydroxyethane-1,1-diphosphonic acid used in the present invention may be contained in the oxidant-containing emulsion composition. Preferably it is 0.01 to 2 weight%, More preferably, 0.05 to 1 weight% is good. (D) If 1-hydroxyethane-1,1-diphosphonic acid is less than 0.01% by weight, the pH adjustment action may not be sufficiently obtained, and (A) hydrogen peroxide may not be stabilized. If it exceeds 2% by weight, it is not possible to obtain a sequestering action or pH adjustment action beyond this, and the stability of the preparation may be adversely affected.
本発明による酸化剤含有乳化組成物は（Ｅ）油性成分を含有する。（Ｅ）油性成分は、毛髪を保護し（Ａ）過酸化水素の酸化反応によって引き起こされる毛髪の損傷を最小限に抑えることにより、染毛操作後のトリートメント性が高い染毛剤を得ることができる。 The oxidizing agent-containing emulsion composition according to the present invention contains (E) an oily component. (E) The oily component protects the hair and (A) minimizes hair damage caused by the oxidation reaction of hydrogen peroxide, thereby obtaining a hair dye having a high treatment property after the hair dyeing operation. it can.
本発明に用いる（Ｅ）油性成分は、特に限定されないが、炭化水素、油脂、ロウ類、高級アルコール、高級脂肪酸、エステル類、シリコーン類などが挙げられる。これら、（Ｅ）油性成分のうち、好ましくは炭化水素、高級アルコール、エステル類、シリコーン類がよい。これら（Ｅ）油性成分は１または２種以上を含有してよい。 The (E) oil component used in the present invention is not particularly limited, and examples thereof include hydrocarbons, fats and oils, waxes, higher alcohols, higher fatty acids, esters, and silicones. Of these (E) oily components, hydrocarbons, higher alcohols, esters and silicones are preferred. These (E) oily components may contain 1 or 2 or more types.
上記（Ｅ）油性成分である炭化水素の具体例としては、特に限定されないが、α−オレフィンオリゴマー、パラフィン、流動パラフィン、軽質イソパラフィン、軽質流動イソパラフィン、流動イソパラフィン、ワセリン、ポリエチレン末、オゾケライト、ポリブテン、セレシンなどが挙げられる。これら炭化水素のうち、好ましくはパラフィン、流動パラフィン、軽質イソパラフィン、軽質流動イソパラフィン、流動イソパラフィン、ワセリン、ポリブテンがよい。これにより（Ａ）過酸化水素の酸化反応によって引き起こされる毛髪の損傷を最小限に抑えることにより、染毛操作後のトリートメント性が高い染毛剤を得ることができる。これら炭化水素は１または２種以上を含有してよい。 Specific examples of the hydrocarbon which is the (E) oil component include, but are not limited to, α-olefin oligomer, paraffin, liquid paraffin, light isoparaffin, light liquid isoparaffin, liquid isoparaffin, petrolatum, polyethylene powder, ozokerite, polybutene, Examples include ceresin. Of these hydrocarbons, paraffin, liquid paraffin, light isoparaffin, light liquid isoparaffin, liquid isoparaffin, petrolatum, and polybutene are preferable. Accordingly, (A) a hair dye having a high treatment property after the hair dyeing operation can be obtained by minimizing hair damage caused by the oxidation reaction of hydrogen peroxide. These hydrocarbons may contain 1 or 2 or more types.
上記（Ｅ）油性成分である油脂の具体例としては、特に限定されないが、ヤシ油、パーム油、オリーブ油、アボカド油、ヒマシ油、ゴマ油、ローズヒップ油、メドウフォーム油、月見草油、マカデミアナッツ油、ハッカ油、トウモロコシ油、ナタネ油、コメヌカ油、シア脂などの植物油脂類、 牛脂、乳脂、馬脂、ミンク油、ラノリンなどの動物性油脂類などが挙げられる。これら油脂は１または２種以上を含有してよい。 Specific examples of the oil and fat as the (E) oil component include, but are not limited to, palm oil, palm oil, olive oil, avocado oil, castor oil, sesame oil, rosehip oil, meadow foam oil, evening primrose oil, macadamia nut oil, Examples include vegetable oils such as mint oil, corn oil, rapeseed oil, rice bran oil, and shea fat, and animal fats such as beef tallow, milk fat, horse fat, mink oil, and lanolin. These fats and oils may contain 1 or 2 or more types.
上記（Ｅ）油性成分であるロウ類の具体例としては、特に限定されないが、ホホバ油、ミツロウ、キャンデリラロウ、コメヌカロウ、セラック、カルナウバロウなどが挙げられる。これらロウ類は１または２種以上を含有してよい。 Specific examples of waxes that are the (E) oily component include, but are not limited to, jojoba oil, beeswax, candelilla wax, rice bran wax, shellac, carnauba wax, and the like. These waxes may contain 1 or 2 or more types.
上記（Ｅ）油性成分である高級アルコールの具体例としては、特に限定されないが、ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、アラキルアルコール、ベヘニルアルコール、２−ヘキシルデカノール、イソステアリルアルコール、２−オクチルドデカノール、デシルテトラデカノール、オレイルアルコール、リノレイルアルコール、リノレニルアルコール、ラノリンアルコールなどが挙げられる。これら高級アルコールのうち、好ましくはミリスチルアルコール、セチルアルコール、ステアリルアルコール、アラキルアルコール、ベヘニルアルコール、イソステアリルアルコール、２−オクチルドデカノール、オレイルアルコールがよい。好ましくは、炭素数が１６から２２である高級アルコールを１または２種以上含有するとよい。これにより（Ａ）過酸化水素の酸化反応によって引き起こされる毛髪の損傷を最小限に抑えることにより、染毛操作後のトリートメント性が高い染毛剤を得ることができる。これら高級アルコールは１または２種以上を含有してよい。 Specific examples of the higher alcohol as the (E) oil component are not particularly limited, but include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, 2-hexyldecanol, isostearyl alcohol, 2-octyl. Examples include dodecanol, decyltetradecanol, oleyl alcohol, linoleyl alcohol, linolenyl alcohol, and lanolin alcohol. Among these higher alcohols, myristyl alcohol, cetyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, isostearyl alcohol, 2-octyldodecanol, and oleyl alcohol are preferable. Preferably, one or more higher alcohols having 16 to 22 carbon atoms may be contained. Accordingly, (A) a hair dye having a high treatment property after the hair dyeing operation can be obtained by minimizing hair damage caused by the oxidation reaction of hydrogen peroxide. These higher alcohols may contain 1 or 2 or more types.
上記（Ｅ）油性成分である高級脂肪酸の具体例としては、特に限定されないが、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘニン酸、イソステアリン酸、ヒドロキシステアリン酸、オレイン酸、ウンデシレン酸、リノール酸、リシノール酸、ラノリン脂肪酸などが挙げられる。これら高級脂肪酸は１または２種以上を含有してよい。 Specific examples of the higher fatty acid (E) as the oil component are not particularly limited, but lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, hydroxystearic acid, oleic acid, undecylenic acid, linol Acid, ricinoleic acid, lanolin fatty acid and the like. These higher fatty acids may contain 1 or 2 or more types.
上記（Ｅ）油性成分であるエステル類の具体例としては、特に限定されないが、アジピン酸ジイソプロピル、アジピン酸ジイソブチル、アジピン酸ジオクチル、アジピン酸−２−ヘキシルデシル、アジピン酸ジイソステアリル、ミリスチン酸イソプロピル、オクタン酸セチル、イソオクタン酸セチル、イソノナン酸イソノニル、イソノナン酸イソデシル、イソノナン酸イソトリデシル、セバシン酸ジイソプロピル、ミリスチン酸オクチルドデシル、パルミチン酸イソプロピル、ステアリン酸ステアリル、ラウリン酸ヘキシル、ミリスチン酸ミリスチル、オレイン酸デシル、ジメチルオクタン酸ヘキシルデシル、ミリスチン酸トリイソデシル、ミリスチン酸イソステアリル、パルミチン酸２−エチルヘキシル、乳酸ラウリル、乳酸ミリスチル、乳酸セチル、乳酸オクチルドデシル、酢酸ラノリン、ステアリン酸イソセチル、イソステアリン酸イソセチル、１２−ヒドロキシステアリン酸コレステリル、ジ−２−エチルヘキシル酸エチレングリコール、ジペンタエリスリット脂肪酸エステル、カプリン酸セチル、トリカプリル酸グリセリル、ジカプリン酸ネオペンチルグリコール、リンゴ酸ジイソステアリルなどが挙げられる。これらエステル類のうち、好ましくは、ミリスチン酸イソプロピル、ミリスチン酸オクチルドデシル、ミリスチン酸イソステアリル、パルミチン酸２−エチルヘキシルがよい。これらエステル類は１または２種以上を含有してよい。 Specific examples of the esters which are the (E) oil component include, but are not limited to, diisopropyl adipate, diisobutyl adipate, dioctyl adipate, 2-hexyldecyl adipate, diisostearyl adipate, isopropyl myristate , Cetyl octanoate, cetyl isooctanoate, isononyl isononanoate, isodecyl isononanoate, isotridecyl isononanoate, diisopropyl sebacate, octyldodecyl myristate, isopropyl palmitate, stearyl stearate, hexyl laurate, myristyl myristate, decyl oleate, Hexyldecyl dimethyloctanoate, triisodecyl myristate, isostearyl myristate, 2-ethylhexyl palmitate, lauryl lactate, myristyl lactate, Cetyl acid, octyldodecyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexylate, dipentaerythritol fatty acid ester, cetyl caprate, glyceryl tricaprylate, dicaprin Examples include acid neopentyl glycol and diisostearyl malate. Of these esters, isopropyl myristate, octyldodecyl myristate, isostearyl myristate, and 2-ethylhexyl palmitate are preferable. These esters may contain 1 or 2 or more types.
上記（Ｅ）油性成分であるシリコーン類の具体例としては、特に限定されないが、メチルポリシロキサン、高重合メチルポリシロキサン、メチルフェニルポリシロキサン、デカメチルシクロペンタシロキサン、ポリエーテル変性シリコーン、アミノ変性シリコーン、ベタイン変性シリコーン、アルキル変性シリコーン、アルコキシ変性シリコーンなどが挙げられる。これらシリコーン類のうち、好ましくは、メチルポリシロキサン、高重合メチルポリシロキサン、メチルフェニルポリシロキサンがよい。これらシリコーン類は１または２種以上を含有してよい。 Specific examples of the silicone as the oil component (E) are not particularly limited, but include methylpolysiloxane, highly polymerized methylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, polyether-modified silicone, amino-modified silicone. , Betaine-modified silicone, alkyl-modified silicone, alkoxy-modified silicone, and the like. Among these silicones, methylpolysiloxane, highly polymerized methylpolysiloxane, and methylphenylpolysiloxane are preferable. These silicones may contain 1 or 2 or more types.
本発明に用いる（Ｅ）油性成分は酸化剤含有乳化組成物中に含有されていればよい。好ましくは０．５〜４０重量％がよい。（Ｅ）油性成分が０．５重量％未満の場合、毛髪を保護する効果を十分に発揮することができないため毛髪を損傷する恐れがある。（Ｅ）油性成分が４０重量％を超える場合、酸化剤含有組成物を安定して形成することができない恐れがある。 The (E) oil component used for this invention should just be contained in the oxidizing agent containing emulsion composition. Preferably it is 0.5 to 40% by weight. (E) When the oil component is less than 0.5% by weight, the effect of protecting the hair cannot be sufficiently exhibited, and thus the hair may be damaged. (E) When an oil-based component exceeds 40 weight%, there exists a possibility that an oxidizing agent containing composition cannot be formed stably.
本発明による酸化剤含有乳化組成物は（Ｆ）界面活性剤を含有する。（Ｆ）界面活性剤は（Ｅ）油性成分を乳化することができ、毛髪を保護し（Ａ）過酸化水素の酸化反応によって引き起こされる毛髪の損傷を最小限に抑えることにより、染毛操作後のトリートメント性が高い染毛剤を得ることができる。 The oxidant-containing emulsion composition according to the present invention contains (F) a surfactant. (F) Surfactant can emulsify (E) oil component, protect hair and (A) minimize hair damage caused by hydrogen peroxide oxidation reaction, after hair dyeing operation A hair dye with high treatment properties can be obtained.
上記（Ｆ）界面活性剤としては、特に限定されないが、アニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤などのイオン性界面活性剤および、非イオン性界面活性剤が挙げられる。好ましくは、非イオン系界面活性剤またはカチオン性界面活性剤がよい。非イオン系界面活性剤またはカチオン性界面活性剤はより安定に（Ｅ）油性成分を乳化することができ、毛髪を保護し（Ａ）過酸化水素の酸化反応によって引き起こされる毛髪の損傷を最小限に抑えることにより、染毛操作後のトリートメント性が高い染毛剤を得ることができる。これら界面活性剤は１または２種以上を含有してよい。 The surfactant (F) is not particularly limited, and examples thereof include ionic surfactants such as anionic surfactants, cationic surfactants, and amphoteric surfactants, and nonionic surfactants. A nonionic surfactant or a cationic surfactant is preferable. Nonionic surfactants or cationic surfactants can more stably emulsify (E) oily components, protect hair and (A) minimize hair damage caused by hydrogen peroxide oxidation reaction By suppressing the hair color, it is possible to obtain a hair dye having high treatment properties after the hair dyeing operation. These surfactants may contain 1 or 2 or more types.
上記（Ｆ）界面活性剤であるアニオン性界面活性剤の具体例としては、特に限定されないが、ラウリル硫酸ナトリウム、ポリオキシエチレン（以下、ＰＯＥという）ラウリルエーテル硫酸ナトリウム、ステアロイルメチルタウリンナトリウム、ドデシルベンゼンスルホン酸トリエタノールアミン、テトラデセンスルホン酸ナトリウム、ＰＯＥラウリルエーテルリン酸およびそれらの塩類などが挙げられる。これらアニオン性界面活性剤のうち、好ましくはラウリル硫酸ナトリウム、ＰＯＥラウリルエーテル硫酸ナトリウム、ステアロイルメチルタウリンナトリウムから選択されるアニオン性界面活性剤がよい。これらのアニオン性界面活性剤は、少なくとも１または２種以上を含有してもよい。 Specific examples of the anionic surfactant which is the surfactant (F) are not particularly limited, but sodium lauryl sulfate, polyoxyethylene (hereinafter referred to as POE) sodium lauryl ether sulfate, stearoylmethyl taurine sodium, dodecylbenzene Examples thereof include triethanolamine sulfonate, sodium tetradecenesulfonate, POE lauryl ether phosphate, and salts thereof. Among these anionic surfactants, an anionic surfactant selected from sodium lauryl sulfate, sodium POE lauryl ether sulfate, and sodium stearoylmethyl taurate is preferable. These anionic surfactants may contain at least one or two or more kinds.
上記（Ｆ）界面活性剤であるカチオン性界面活性剤の具体例としては、特に限定されないが、塩化ラウリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化アルキルトリメチルアンモニウム、塩化ジステアリルジメチルアンモニウム、臭化ラウリルトリメチルアンモニウム、臭化セチルトリメチルアンモニウム、臭化ステアリルトリメチルアンモニウム、塩化ジセチルジメチルアンモニウム、塩化ジココイルジメチルアンモニウム、塩化ドデシルジメチルエチルアンモニウム、塩化ポリオキシプロピレンメチルジエチルアンモニウム、塩化ベンザルコニウム、エチル硫酸ラノリン脂肪酸アミノプロピルエチルジメチルアンモニウム、セチルトリメチルアンモニウムサッカリン、ステアリルトリメチルアンモニウムサッカリンなどが挙げられる。これらカチオン性界面活性剤のうち、好ましくは塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化アルキルトリメチルアンモニウム、塩化ジセチルジメチルアンモニウム、塩化ジステアリルジメチルアンモニウム、セチルトリメチルアンモニウムサッカリン、ステアリルトリメチルアンモニウムサッカリンから選択されるカチオン性界面活性剤がよい。これらのカチオン性界面活性剤は、少なくとも１または２種以上を含有してもよい。 Specific examples of the cationic surfactant which is the surfactant (F) are not particularly limited, but include lauryltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, alkyltrimethylammonium chloride, distearyldimethylammonium chloride. , Lauryl trimethyl ammonium bromide, cetyl trimethyl ammonium bromide, stearyl trimethyl ammonium bromide, dicetyl dimethyl ammonium chloride, dicocoyl dimethyl ammonium chloride, dodecyl dimethyl ethyl ammonium chloride, polyoxypropylene methyl diethyl ammonium chloride, benzalkonium chloride, Ethanol sulfate lanolin fatty acid aminopropylethyldimethylammonium, cetyltrimethylammonium saccharin, Allyl trimethyl ammonium saccharin. Of these cationic surfactants, preferably selected from cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, alkyltrimethylammonium chloride, dicetyldimethylammonium chloride, distearyldimethylammonium chloride, cetyltrimethylammonium saccharin, and stearyltrimethylammonium saccharin. A cationic surfactant is preferred. These cationic surfactants may contain at least one or two or more kinds.
上記（Ｆ）界面活性剤である両性界面活性剤の具体例としては、特に限定されないが、２−ウンデシル−Ｎ，Ｎ，Ｎ−（ヒドロキシエチルカルボキシメチル）−２−イミダゾリンナトリウムなどのイミダゾリン系両性界面活性剤、２−ヘプタデシル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタインなどのベタイン系界面活性剤、アルキルアミンオキシドなどが挙げられる。これら両性界面活性剤のうち好ましくはイミダゾリン系両性界面活性剤、ベタイン系両性界面活性剤から選択される両性界面活性剤がよい。これらの両性界面活性剤は、少なくとも１または２種以上を含有してもよい。 Although it does not specifically limit as a specific example of the amphoteric surfactant which is the said (F) surfactant, Impazoline system amphoteric, such as 2-undecyl-N, N, N- (hydroxyethyl carboxymethyl) -2-imidazoline sodium Surfactants, betaine surfactants such as 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, alkylamine oxides and the like can be mentioned. Among these amphoteric surfactants, amphoteric surfactants selected from imidazoline amphoteric surfactants and betaine amphoteric surfactants are preferable. These amphoteric surfactants may contain at least one or more.
上記（Ｆ）界面活性剤である非イオン性界面活性剤の具体例としては、特に限定されないが、ＰＯＥアルキルエーテル類、ＰＯＥアルキルフェニルエーテル類、ＰＯＥ・ポリオキシプロピレン（以下、ＰＯＰという）アルキルエーテル類、ＰＯＥ脂肪酸類、ＰＯＥソルビタン脂肪酸エステル類、ＰＯＥヒマシ油類、ＰＯＥ硬化ヒマシ油類、ＰＯＥソルビトールテトラ脂肪酸エステル類、グリセリン脂肪酸エステル類、ソルビタン脂肪酸エステル類、ポリグリセリン脂肪酸エステル類、Ｎ−アルキルジメチルアミンオキシド類、ＰＯＥプロピレングリコール脂肪酸エステル類、糖系非イオン性界面活性剤類などが挙げられる。これら非イオン性界面活性剤のうち、好ましくはＰＯＥアルキルエーテル類、ＰＯＥアルキルフェニルエーテル類、ＰＯＥ・ＰＯＰアルキルエーテル類、ＰＯＥソルビタン脂肪酸エステル類、グリセリン脂肪酸エステル類、糖系非イオン性界面活性剤類から選択される非イオン性界面活性剤がよく、より好ましくはＰＯＥアルキルエーテル類、グリセリン脂肪酸エステル類、糖系非イオン性界面活性剤類から選択される非イオン性界面活性剤がよい。これらの非イオン性界面活性剤は、少なくとも１または２種以上を含有してもよい。 Specific examples of the nonionic surfactant as the surfactant (F) are not particularly limited, but include POE alkyl ethers, POE alkylphenyl ethers, POE / polyoxypropylene (hereinafter referred to as POP) alkyl ethers. , POE fatty acids, POE sorbitan fatty acid esters, POE castor oil, POE hydrogenated castor oil, POE sorbitol tetra fatty acid esters, glycerin fatty acid esters, sorbitan fatty acid esters, polyglycerin fatty acid esters, N-alkyldimethyl Examples include amine oxides, POE propylene glycol fatty acid esters, and sugar-based nonionic surfactants. Among these nonionic surfactants, preferably POE alkyl ethers, POE alkylphenyl ethers, POE / POP alkyl ethers, POE sorbitan fatty acid esters, glycerin fatty acid esters, sugar-based nonionic surfactants A nonionic surfactant selected from the group consisting of POE alkyl ethers, glycerin fatty acid esters, and sugar-based nonionic surfactants is more preferable. These nonionic surfactants may contain at least one or two or more kinds.
本発明に用いる（Ｆ）界面活性剤は酸化剤含有乳化組成物中に含有されていればよい。好ましくは０．１〜１５重量％がよい。（Ｆ）界面活性剤が０．１重量％未満の場合、（Ｅ）油性成分を安定に乳化することができず、酸化剤含有乳化組成物を安定して形成することができない恐れがある。（Ｆ）界面活性剤が１５重量％を超える場合、酸化剤含有乳化組成物を安定して形成することができない恐れがある。 (F) surfactant used for this invention should just be contained in the oxidizing agent containing emulsion composition. Preferably 0.1 to 15 weight% is good. When the surfactant (F) is less than 0.1% by weight, the (E) oil component cannot be stably emulsified, and the oxidizing agent-containing emulsion composition may not be stably formed. (F) When surfactant exceeds 15 weight%, there exists a possibility that an oxidizing agent containing emulsion composition cannot be formed stably.
本発明による酸化剤含有乳化組成物のｐＨは、４．５以下である。好ましくは３．５以下がよい。ｐＨが４．５を超える場合、（Ａ）過酸化水素を安定化することができない恐れがある。 The pH of the oxidant-containing emulsion composition according to the present invention is 4.5 or less. Preferably it is 3.5 or less. When pH exceeds 4.5, there exists a possibility that (A) hydrogen peroxide cannot be stabilized.
本発明による酸化剤含有乳化組成物には、水以外の溶剤、増粘剤などを含有することができる。これらの成分は、少なくとも１または２種以上を含有してもよい。 The oxidizing agent-containing emulsion composition according to the present invention can contain a solvent other than water, a thickener, and the like. These components may contain at least one or more kinds.
上記水以外の溶剤の具体例としては、エタノール、イソプロパノール、ｎ―プロパノール、ｎ―ブタノール、イソブタノール、エチレングリコール、プロピレングリコール、グリセリン、１，３−ブチレングリコール、ジプロピレングリコール、３−メチル−１，３−ブタンジオール、ヘキシレングリコール、ジグリセリン、メチルカルビトール、ジエチレングリコールモノエチルエーテル、プロピルカルビトール、ブチルカルビトール、トリエチレングリコールモノエチルエーテル、トリエチレングリコールモノブチルエーテル、Ｎ−メチルピロリドン、Ｎ−オクチルピロリドン、Ｎ−ラウリルピロリドン、炭酸プロピレン、炭酸エチレン、ポリエチレングリコール、ポリプロピレングリコールなどが挙げられる。これらの水以外の溶剤は、少なくとも１または２種以上を含有してもよい。 Specific examples of the solvent other than water include ethanol, isopropanol, n-propanol, n-butanol, isobutanol, ethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, dipropylene glycol, and 3-methyl-1. , 3-butanediol, hexylene glycol, diglycerin, methyl carbitol, diethylene glycol monoethyl ether, propyl carbitol, butyl carbitol, triethylene glycol monoethyl ether, triethylene glycol monobutyl ether, N-methylpyrrolidone, N- Examples include octyl pyrrolidone, N-lauryl pyrrolidone, propylene carbonate, ethylene carbonate, polyethylene glycol, and polypropylene glycol. These solvents other than water may contain at least one or two or more kinds.
上記増粘剤の具体例としては、カルボキシメチルセルロース、カルボキシビニルポリマー、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、メチルセルロース、キサンタンガム、カラギーナン、アルギン酸塩、ペクチン、フェラーセン、アラビアガム、ガッチガム、カラヤガム、トラガカントガム、カンテン末、ベントナイト、架橋性ポリアルキル酸塩などの増粘剤などが挙げられる。これらの増粘剤は、少なくとも１または２種以上を含有してもよい。 Specific examples of the thickener include carboxymethyl cellulose, carboxy vinyl polymer, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose, xanthan gum, carrageenan, alginate, pectin, ferrersen, gum arabic, gatch gum, caraya gum, gum tragacanth, agar powder, Examples thereof include thickeners such as bentonite and crosslinkable polyalkyl acid salts. These thickeners may contain at least one or two or more.
本発明による酸化剤含有乳化組成物には、その他添加成分としてコラーゲン、ケラチン、エラスチン、フィブロイン、コンキオリン、大豆タンパク、カゼイン、ゼラチンなどの蛋白質、酸やアルカリや酵素などにより加水分解した加水分解物およびこれらを４級化したカチオン変性蛋白質などのポリペプタイド、ピロリドンカルボン酸ナトリウム、ヒアルロン酸などの保湿剤、パラベンなどの防腐剤、アミノ酸、植物抽出液、生薬抽出物、ビタミン類、色素、香料、顔料、紫外線吸収剤などから選ばれる１または２種以上を含有してもよい。 The oxidant-containing emulsion composition according to the present invention includes collagen, keratin, elastin, fibroin, conchiolin, soy protein, casein, gelatin and other hydrolysates hydrolyzed with acids, alkalis, enzymes, etc. Polypeptides such as cation-modified proteins quaternized with these, moisturizers such as sodium pyrrolidonecarboxylate and hyaluronic acid, preservatives such as parabens, amino acids, plant extracts, herbal extracts, vitamins, dyes, fragrances, pigments In addition, one or more selected from ultraviolet absorbers and the like may be contained.
本発明による酸化剤含有乳化組成物の剤型は、乳液状、クリーム状、ジェルクリーム状、泡状、エアゾールフォーム状が挙げられる。本発明による酸化剤含有乳化組成物は、ポリ容器、チューブ容器、エアゾール容器などの各種容器に充填され、使用時まで保存される。 Examples of the dosage form of the oxidant-containing emulsion composition according to the present invention include emulsions, creams, gel creams, foams, and aerosol foams. The oxidant-containing emulsion composition according to the present invention is filled in various containers such as a plastic container, a tube container, and an aerosol container and stored until use.
本発明による酸化剤含有乳化組成物は、アルカリを含有する剤と用時混合され使用される。このアルカリを含有する剤には、脱色剤および脱染剤ではアルカリ剤、染毛剤ではアルカリ剤および酸化染料などが含有される。アルカリ剤は、（Ａ）過酸化水素の成分の酸化反応を促進することによって髪を明るく見せることができ、染毛剤では酸化染料の重合反応を促し、毛髪を染毛することができる。 The oxidant-containing emulsion composition according to the present invention is used by mixing with an agent containing an alkali at the time of use. The agent containing an alkali includes an alkali agent for a decoloring agent and a decoloring agent, and an alkali agent and an oxidation dye for a hair dye. The alkaline agent (A) can make the hair look brighter by promoting the oxidation reaction of the hydrogen peroxide component, and the hair dye can promote the polymerization reaction of the oxidation dye and dye the hair.
本発明による酸化剤含有乳化組成物と、用時混合され使用される剤に用いられるアルカリ剤は、特に限定されないが、モノエタノールアミン、ジエタノールアミンなどのアルカノールアミン類、モルホリン、グアニジンなどの有機アミン類、アンモニア、炭酸アンモニウム、炭酸水素アンモニウムなどの無機アルカリ、アルギニン、リジンなどの塩基性アミノ酸およびそれらの塩などが挙げられる。これらアルカリ剤のうち、モノエタノールアミン、ジエタノールアミンなどのアルカノールアミン類、アンモニア、炭酸アンモニウム、炭酸水素アンモニウムなどの無機アルカリから選択されるアルカリ剤がよい。これらのアルカリ剤は、少なくとも１または２種以上を含有してもよい。 The oxidant-containing emulsion composition according to the present invention and the alkali agent used in the agent mixed and used at the time of use are not particularly limited, but alkanolamines such as monoethanolamine and diethanolamine, and organic amines such as morpholine and guanidine. Inorganic alkalis such as ammonia, ammonium carbonate and ammonium hydrogen carbonate, basic amino acids such as arginine and lysine, and salts thereof. Of these alkali agents, alkali agents selected from alkanolamines such as monoethanolamine and diethanolamine, and inorganic alkalis such as ammonia, ammonium carbonate, and ammonium hydrogen carbonate are preferable. These alkaline agents may contain at least one or two or more.
本発明による酸化剤含有乳化組成物と、用時混合され使用される剤に用いられる酸化染料は、特に限定されないが、パラフェニレンジアミン、トルエン２，５−ジアミン、オルトアミノフェノール、パラアミノフェノール、メタアミノフェノール、５−アミノオルトクレゾール、２，６−ジアミノピリジン、塩酸２，４−ジアミノフェノキシエタノール、１−ナフトールおよびそれらの塩類などが挙げられる。その他、「医薬部外品原料規格」（１９９１年６月発行、薬事日報社）に収載されたものも適宜用いることができる。これらの酸化染料は、少なくとも１または２種以上を含有してもよい。 The oxidation dye-containing emulsion composition according to the present invention and the oxidation dye used in the agent mixed and used at the time of use are not particularly limited, but paraphenylenediamine, toluene 2,5-diamine, orthoaminophenol, paraaminophenol, meta Examples include aminophenol, 5-aminoorthocresol, 2,6-diaminopyridine, 2,4-diaminophenoxyethanol hydrochloride, 1-naphthol, and salts thereof. In addition, those listed in "Quasi-drug raw material standards" (issued in June 1991, Yakuji Nippo) can be used as appropriate. These oxidation dyes may contain at least one or two or more.
本発明による酸化剤含有乳化組成物と、用時混合され使用される剤には直接染料を用いてもよい。直接染料は特に限定されないが、４−ニトロ−ｍ−フェニレンジアミン、４−ニトロ−ｏ−フェニレンジアミン、２−ニトロ−ｐ−フェニレンジアミンおよびそれらの塩類、黄色２０２号（１）、８−アミノ−２−ブロム−５−ヒドロキシ−４−イミノ−６−［（３−（トリメチルアンモニオ）フェニル）アミノ］−１（４Ｈ）−ナフタリノン−クロライド（ＣＩ５６０５９；ベーシック・ブルーＮｏ．９９）などが挙げられる。その他、直接染料や「医薬品等に使用することができるタール色素を定める省令」（昭和４１年厚生省告示）により定められた酸性染料や塩基性染料も適宜用いることができる。これらの染料は少なくとも１または２種以上を含有してもよい。 Direct dyes may be used in the oxidizing agent-containing emulsion composition according to the present invention and the agent mixed and used at the time of use. Although the direct dye is not particularly limited, 4-nitro-m-phenylenediamine, 4-nitro-o-phenylenediamine, 2-nitro-p-phenylenediamine and salts thereof, Yellow No. 202 (1), 8-amino- And 2-bromo-5-hydroxy-4-imino-6-[(3- (trimethylammonio) phenyl) amino] -1 (4H) -naphthalinone-chloride (CI 56059; Basic Blue No. 99). . In addition, direct dyes and acid dyes and basic dyes determined by “Ministerial Ordinance for Determining Tar Colors that can be Used in Pharmaceuticals” (Ministry of Health and Welfare 1960 notification) can be used as appropriate. These dyes may contain at least one or two or more.
以上、詳述した本発明のアルカリ剤を含有する第１剤と用時混合して使用される酸化剤含有乳化組成物であって、（Ａ）過酸化水素、（Ｂ）水、（Ｃ）アルカリ金属の水酸化物、（Ｄ）１−ヒドロキシエタン−１，１−ジホスホン酸、（Ｅ）油性成分および（Ｆ）界面活性剤を含有して、ｐＨ４．５以下である酸化剤含有乳化組成物は、高温条件下にさらされても安定な酸化剤含有乳化組成物が得られるため、酸化剤含有乳化組成物を用いる染毛剤の保管、運搬を容易にすることができる。また、染毛剤の酸化剤として用いることによって、脱色効果や染毛効果を低下することがなく、なおかつ染毛操作後のトリートメント性が高い染毛剤を提供できる。 The oxidant-containing emulsion composition used by mixing with the first agent containing the alkali agent of the present invention described above in detail, comprising (A) hydrogen peroxide, (B) water, (C) An oxidant-containing emulsion composition containing an alkali metal hydroxide, (D) 1-hydroxyethane-1,1-diphosphonic acid, (E) an oil component and (F) a surfactant and having a pH of 4.5 or less Since the product can obtain a stable oxidant-containing emulsion composition even when exposed to high temperature conditions, the hair dye using the oxidant-containing emulsion composition can be easily stored and transported. Moreover, by using it as an oxidizing agent for a hair dye, it is possible to provide a hair dye that does not deteriorate the decoloring effect or the hair dyeing effect and has high treatment properties after the hair dyeing operation.
以下に実施例を挙げて本発明を詳細に説明するが、本発明はこれらの実施例にのみ限定されるものではない。 EXAMPLES Hereinafter, the present invention will be described in detail with reference to examples, but the present invention is not limited only to these examples.
本明細書に示す評価試験において、酸化剤含有乳化組成物に含まれる成分およびその含有量を種々変更しながら実施した各種の実験結果を以下に示す。ここで、酸化剤含有乳化組成物の各成分の配合量を示す単位は全て重量％であり、これを常法にて調製した。 In the evaluation test shown in the present specification, various experimental results carried out while variously changing the components contained in the oxidant-containing emulsion composition and the contents thereof are shown below. Here, the unit which shows the compounding quantity of each component of an oxidizing agent containing emulsion composition is all weight%, and this was prepared by the conventional method.
本明細書に示す評価試験において、「（Ａ）過酸化水素の安定性」、「毛髪の染毛性」、「毛髪の明度」および「毛髪のトリートメント性」について評価した。 In the evaluation test shown in this specification, “(A) hydrogen peroxide stability”, “hair dyeing property”, “lightness of hair”, and “treatment property of hair” were evaluated.
本明細書に示す評価試験において、「（Ａ）過酸化水素の安定性」は得られた酸化剤含有乳化組成物をポリエチレン製の密閉容器に充填し、５０℃条件下で３ヵ月間保存、並びに、６０℃条件下で２４時間保存した後、（Ａ）過酸化水素の残存率を測定した。（Ａ）過酸化水素の定量方法は、酸化還元滴定法を用いた。 In the evaluation test shown in this specification, “(A) hydrogen peroxide stability” is obtained by filling the obtained oxidant-containing emulsion composition into a polyethylene sealed container and storing it at 50 ° C. for 3 months. In addition, after being stored for 24 hours at 60 ° C., (A) the residual rate of hydrogen peroxide was measured. (A) The oxidation-reduction titration method was used for the determination method of hydrogen peroxide.
本明細書に示す評価試験において、「毛髪の染毛性」、「毛髪の明度」および「毛髪のトリートメント性」は得られた酸化剤含有乳化組成物をポリエチレン製の密閉容器に充填し、５０℃条件下で３ヵ月間保存した酸化剤含有乳化組成物と染毛試験当日に調製した酸化剤含有乳化組成物とを用いて同時に染毛し比較評価した。 In the evaluation test shown in this specification, “hair dyeability”, “lightness of hair” and “hair treatment properties” were obtained by filling the obtained oxidant-containing emulsion composition into a polyethylene sealed container, Using an oxidant-containing emulsion composition stored for 3 months under the condition of ° C and an oxidant-containing emulsion composition prepared on the day of the hair dyeing test, hair was simultaneously dyed and evaluated.
「毛髪の染毛性」、「毛髪の明度」および「毛髪のトリートメント性」の評価で用いた「アルカリ剤を含有する脱色剤」および「アルカリ剤と酸化染料を含有する染毛剤」の成分および配合量は後述する。「アルカリ剤を含有する脱色剤」および「アルカリ剤と酸化染料を含有する染毛剤」とを記載の混合比で混合し、得られた染毛剤組成物を２５℃条件下で、毛髪試験用ドール（株式会社ビューラックス社製「カットマネキンＮＯ．７７５Ｎ」）の毛髪全体に１２０ｇを塗布し１５分間放置後洗い流す染毛操作を行ない、乾かした毛髪を目視で確認するとともに、毛髪の手触り感を確認して評価した。 Components of “decolorizing agent containing alkali agent” and “hair dye containing alkali agent and oxidation dye” used in the evaluation of “hair coloring”, “lightness of hair” and “hair treatment” The blending amount will be described later. “Decolorizing agent containing alkali agent” and “hair dye containing alkali agent and oxidative dye” were mixed in the mixing ratio described above, and the obtained hair dye composition was subjected to a hair test under the condition of 25 ° C. 120g is applied to the entire hair of a doll for hair (Beaulux Co., Ltd. “Cut Mannequin No. 775N”), left for 15 minutes, then washed to wash, visually confirm the dried hair, and feel to the hair Was confirmed and evaluated.
「過酸化水素の残存率」の評価基準
５０℃条件下で３ヵ月間保存、並びに、６０℃条件下で２４時間保存での過酸化水素の残存率
◎：９９％以上
○：９６％以上９９％未満
△：９４％以上９６％未満
×：９４％未満
Evaluation criteria of “hydrogen peroxide remaining ratio” Hydrogen peroxide remaining ratio after storage for 3 months under 50 ° C. condition and for 24 hours under 60 ° C. condition: 99% or more ○: 96% or more 99 Less than% △: 94% or more and less than 96% ×: less than 94%
「毛髪の染毛性」または「毛髪の明度」の評価基準
◎：染毛性または明度に全く変化なし
○：染毛性または明度に変化があるが問題ない程度
△：染毛性または明度に変化がある
×：染毛性または明度に明らかに異なる変化がある
Evaluation criteria for “hair dyeability” or “lightness of hair” ◎: No change in hair dyeing or lightness ○: No change in hair dyeing or lightness Δ: Hair dyeing or lightness There is a change ×: There is a clearly different change in hair dyeing or lightness
「毛髪のトリートメント性」の評価基準
◎：毛髪の指通りに全く引掛かりがなく手触り感が非常に良い
○：毛髪の指通りにやや引掛かりがあるが問題ない程度で手触り感が良い
△：毛髪の指通りに引掛かりがあり手触り感が悪い
×：毛髪の指通りに非常に引掛かりがあり非常に手触り感が悪い
Evaluation criteria for “hair treatment properties” ◎: There is no catch on the finger of the hair and the touch feeling is very good ○: There is a slight catch on the finger of the hair but there is no problem △: There is a catch on the finger of the hair and the touch feeling is bad ×: There is a very catch on the finger of the hair and the feel is very bad
表１はアルカリ剤と酸化染料を含有する染毛剤第１剤の成分と配合量を示す。この染毛剤第１剤と得られた酸化剤含有乳化組成物を「染毛剤第１剤：酸化剤含有乳化組成物（第２剤）＝１：１」の混合比で混合し、これを用いて「毛髪の染毛性」を評価した。 Table 1 shows the components and blending amounts of the first hair dye containing an alkaline agent and an oxidation dye. The hair dye first agent and the obtained oxidizing agent-containing emulsion composition were mixed at a mixing ratio of “hair dye first agent: oxidizing agent-containing emulsion composition (second agent) = 1: 1”. Was used to evaluate the "hair dyeability".
表２はアルカリ剤を含有する脱色剤第１剤の成分と配合量を示す。この脱色剤第１剤と得られた酸化剤含有乳化組成物を「脱色剤第１剤：酸化剤含有乳化組成物（第２剤）＝１：２」の混合比で混合し、これを用いて「毛髪の明度」を評価した。 Table 2 shows the components and blending amounts of the first bleaching agent containing an alkaline agent. The decolorizer first agent and the resulting oxidant-containing emulsion composition were mixed at a mixing ratio of “decolorizer first agent: oxidant-containing emulsion composition (second agent) = 1: 2” and used. The “lightness of the hair” was evaluated.
第１評価試験
第１評価試験では、各成分の配合量を変えた酸化剤含有乳化組成物に関して評価した。表３は酸化剤含有乳化組成物の成分とその配合量、物性値（ｐＨ）、および第１評価試験の結果を示す。
1st evaluation test In the 1st evaluation test, it evaluated regarding the oxidizing agent containing emulsion composition which changed the compounding quantity of each component. Table 3 shows the components of the oxidizing agent-containing emulsion composition, the blending amount thereof, the physical property value (pH), and the results of the first evaluation test.
（実施例１〜５）
実施例１〜５では（Ｃ）アルカリ金属の水酸化物の種類を様々に代えた酸化剤含有乳化組成物に関し評価した。
(Examples 1-5)
In Examples 1-5, (C) the oxidizing agent containing emulsion composition which changed the kind of alkali metal hydroxide variously was evaluated.
第１評価試験の実施例１〜５の結果から、（Ｃ）アルカリ金属の水酸化物の種類を代えたとしても良好な結果が得られた。また、実施例１および２と実施例３〜５の結果から、（Ｃ）アルカリ金属の水酸化物は、好ましくは水酸化ナトリウム、水酸化カリウムがよく、さらに好ましくは水酸化カリウムがよかった。 From the results of Examples 1 to 5 of the first evaluation test, good results were obtained even if the type of (C) alkali metal hydroxide was changed. Further, from the results of Examples 1 and 2 and Examples 3 to 5, (C) alkali metal hydroxide was preferably sodium hydroxide or potassium hydroxide, more preferably potassium hydroxide.
（比較例１）
比較例１では（Ｃ）アルカリ金属の水酸化物を配合せずアルカリ土類金属の水酸化物である水酸化カルシウムを配合した酸化剤含有乳化組成物について評価した。この結果、（Ａ）過酸化水素の高温条件下での良好な安定性は得られなかった。
(Comparative Example 1)
In Comparative Example 1, (C) an oxidant-containing emulsion composition in which calcium hydroxide, which is an alkaline earth metal hydroxide, was not blended with an alkali metal hydroxide, was evaluated. As a result, (A) good stability of hydrogen peroxide under high temperature conditions could not be obtained.
（比較例２および３）
比較例２では（Ｄ）１−ヒドロキシエタン−１，１−ジホスホン酸を含有せず、従来技術からあるクエン酸をｐＨ調整剤として用いて評価し、比較例３では（Ｃ）アルカリ金属の水酸化物を配合せず、従来技術からあるクエン酸ナトリウムをｐＨ調整剤として用いて評価した。この結果、（Ａ）過酸化水素の高温条件下での良好な安定性は得られなかった。
(Comparative Examples 2 and 3)
In Comparative Example 2, (D) 1-hydroxyethane-1,1-diphosphonic acid was not contained, and citric acid from the prior art was evaluated as a pH adjuster. In Comparative Example 3, (C) alkali metal water Evaluation was made using sodium citrate from the prior art as a pH adjuster without any oxide. As a result, (A) good stability of hydrogen peroxide under high temperature conditions could not be obtained.
（比較例４および５）
比較例４では、従来技術で（Ａ）過酸化水素の安定化剤であるスズ酸ナトリウムを配合し、さらに、比較例５ではクエン酸およびクエン酸ナトリウムを用いて実施例１と同じｐＨに調整して評価した。この結果、（Ａ）過酸化水素の高温条件下での良好な安定性は得られなかった。
(Comparative Examples 4 and 5)
In Comparative Example 4, (A) sodium stannate, which is a stabilizer of hydrogen peroxide, was blended in the prior art, and in Comparative Example 5, the same pH as in Example 1 was adjusted using citric acid and sodium citrate. And evaluated. As a result, (A) good stability of hydrogen peroxide under high temperature conditions could not be obtained.
第２評価試験
第２評価試験では、（Ｃ）アルカリ金属の水酸化物である水酸化カリウムおよび（Ｄ）１−ヒドロキシエタン−１，１−ジホスホン酸の配合量を様々に変えるが、酸化剤含有乳化組成物のｐＨを一定に保ち評価した。表４は酸化剤含有乳化組成物の成分とその配合量、物性値（ｐＨ）および第２評価試験の結果を示す。
Second Evaluation Test In the second evaluation test, the amount of (C) potassium hydroxide, which is an alkali metal hydroxide, and (D) 1-hydroxyethane-1,1-diphosphonic acid is variously changed. The pH of the contained emulsion composition was kept constant for evaluation. Table 4 shows the components of the oxidizing agent-containing emulsion composition, the blending amount thereof, the physical property value (pH), and the results of the second evaluation test.
（実施例６〜１１）
第２評価試験の実施例６〜１１の結果から、（Ｃ）アルカリ金属の水酸化物は酸化剤含有乳化組成物中に含有されていればよいが、好ましくは０．００４〜１重量％、より好ましくは０．０２〜０．５重量％がよかった。また、（Ｄ）１−ヒドロキシエタン−１，１−ジホスホン酸は酸化剤含有乳化組成物中に含有されていればよいが、好ましくは０．０１〜２重量％、より好ましくは０．０５〜１重量％がよかった。
(Examples 6 to 11)
From the results of Examples 6 to 11 of the second evaluation test, (C) the alkali metal hydroxide may be contained in the oxidant-containing emulsion composition, preferably 0.004 to 1% by weight, More preferably, it was 0.02 to 0.5% by weight. Further, (D) 1-hydroxyethane-1,1-diphosphonic acid may be contained in the oxidizing agent-containing emulsion composition, preferably 0.01 to 2% by weight, more preferably 0.05 to 1% by weight was good.
第３評価試験
第３評価試験では、（Ｃ）アルカリ金属の水酸化物である水酸化カリウムおよび、（Ｄ）１−ヒドロキシエタン−１，１−ジホスホン酸の配合量を様々に変えることにより、酸化剤含有乳化組成物のｐＨを様々に変え評価した。表５は酸化剤含有乳化組成物の成分とその配合量、物性値（ｐＨ）および第３評価試験の結果を示す。
Third Evaluation Test In the third evaluation test, (C) potassium hydroxide, which is an alkali metal hydroxide, and (D) various amounts of 1-hydroxyethane-1,1-diphosphonic acid are changed, The pH of the oxidant-containing emulsion composition was varied and evaluated. Table 5 shows the components of the oxidizing agent-containing emulsion composition, the blending amount, the physical property value (pH), and the results of the third evaluation test.
第３評価試験における実施例１２〜１６および比較例６結果から、酸化剤含有乳化組成物のｐＨは４．５以下がよく、より好ましくは３．５以下がよかった。 From the results of Examples 12 to 16 and Comparative Example 6 in the third evaluation test, the pH of the oxidant-containing emulsion composition was preferably 4.5 or less, more preferably 3.5 or less.
第４評価試験
第４評価試験では、発明者は、（Ｅ）油性成分の含有量および種類を様々に変えた酸化剤含有乳化組成物に関して評価した。表６および表７は酸化剤含有乳化組成物の成分とその配合量、物性値（ｐＨ）、（Ｅ）油性成分の含有量、（Ｆ）界面活性剤の含有量および第４評価試験の結果を示す。
Fourth Evaluation Test In the fourth evaluation test, the inventor evaluated (E) an oxidant-containing emulsion composition in which the content and type of the oil component were variously changed. Tables 6 and 7 show the components of the oxidant-containing emulsion composition and the blending amount thereof, physical property values (pH), (E) the content of the oil component, (F) the content of the surfactant, and the results of the fourth evaluation test. Indicates.
（実施例１７〜３３）
第４評価試験の実施例１７〜３３の結果から、（Ｅ）油性成分の含有量や種類を様々に変えたとしても、酸化剤含有乳化組成物として用いることにより良好な結果が得られた。
(Examples 17 to 33)
From the results of Examples 17 to 33 of the fourth evaluation test, even when the content and type of the (E) oily component were variously changed, good results were obtained by using them as an oxidant-containing emulsion composition.
第５評価試験
第５評価試験では、発明者は、（Ｆ）界面活性剤の含有量および種類を様々に変えた酸化剤含有乳化組成物に関して評価した。表８は酸化剤含有乳化組成物の成分とその配合量、物性値（ｐＨ）、（Ｅ）油性成分の含有量、（Ｆ）界面活性剤の含有量および第４評価試験の結果を示す。
Fifth Evaluation Test In the fifth evaluation test, the inventor evaluated the oxidant-containing emulsion composition in which the content and type of (F) surfactant were variously changed. Table 8 shows the components of the oxidant-containing emulsion composition, the blending amount thereof, the physical property value (pH), the content of (E) the oil component, the content of (F) the surfactant, and the results of the fourth evaluation test.
（実施例３４〜４０）
第５評価試験の実施例３４〜４０の結果から、（Ｆ）界面活性剤の含有量や種類を様々に変えたとしても、酸化剤含有乳化組成物として用いることにより良好な結果が得られた。
(Examples 34 to 40)
From the results of Examples 34 to 40 of the fifth evaluation test, even when the content and type of the surfactant (F) were variously changed, good results were obtained by using them as an oxidizing agent-containing emulsion composition. .
（比較例８）
第５評価試験の比較例８の結果から、（Ａ）過酸化水素、（Ｂ）水、（Ｃ）アルカリ金属の水酸化物、（Ｄ）１−ヒドロキシエタン−１，１−ジホスホン酸を含有するものの、（Ｅ）油性成分および（Ｆ）界面活性剤を含有しない製剤では、（Ａ）過酸化水素の安定性は確保されているものの、染毛後の毛髪のトリートメント性では良好な結果が得られなかった。
(Comparative Example 8)
From the result of Comparative Example 8 of the fifth evaluation test, it contains (A) hydrogen peroxide, (B) water, (C) alkali metal hydroxide, and (D) 1-hydroxyethane-1,1-diphosphonic acid. Although (E) oil-based ingredients and (F) preparations that do not contain a surfactant, (A) the stability of hydrogen peroxide is ensured, but the hair treatment properties after dyeing have good results. It was not obtained.
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| WO2017115820A1 (en) * | 2015-12-28 | 2017-07-06 | 花王株式会社 | Second preparation composition for aerosol-type hair dye or hair bleaching agent |
| WO2019003957A1 (en) * | 2017-06-30 | 2019-01-03 | ホーユー株式会社 | Oxidant-containing composition and method for using same |
| JP2019081710A (en) * | 2017-10-27 | 2019-05-30 | ホーユー株式会社 | Hair decoloring/breaching agent composition or hair dye composition |
| US12515587B2 (en) | 2021-09-29 | 2026-01-06 | Subaru Corporation | Mirror position registration control apparatus |
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| JP2010235578A (en) * | 2009-03-11 | 2010-10-21 | Kao Corp | Two-component hair dye |
| US20140170223A1 (en) * | 2012-12-19 | 2014-06-19 | Henkel Ag & Co. Kgaa | Post oxidative hair treatment agent with silicone |
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| JP2010235578A (en) * | 2009-03-11 | 2010-10-21 | Kao Corp | Two-component hair dye |
| US20140170223A1 (en) * | 2012-12-19 | 2014-06-19 | Henkel Ag & Co. Kgaa | Post oxidative hair treatment agent with silicone |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2017115820A1 (en) * | 2015-12-28 | 2017-07-06 | 花王株式会社 | Second preparation composition for aerosol-type hair dye or hair bleaching agent |
| JP2017119694A (en) * | 2015-12-28 | 2017-07-06 | 花王株式会社 | Second agent composition of aerosol type hair dyeing or hair decolorizing agent |
| WO2019003957A1 (en) * | 2017-06-30 | 2019-01-03 | ホーユー株式会社 | Oxidant-containing composition and method for using same |
| JP2019011291A (en) * | 2017-06-30 | 2019-01-24 | ホーユー株式会社 | Oxidizing agent-containing composition and method of using the same |
| JP2019081710A (en) * | 2017-10-27 | 2019-05-30 | ホーユー株式会社 | Hair decoloring/breaching agent composition or hair dye composition |
| JP7134454B2 (en) | 2017-10-27 | 2022-09-12 | ホーユー株式会社 | Hair bleaching / destaining composition or hair dye composition |
| US12515587B2 (en) | 2021-09-29 | 2026-01-06 | Subaru Corporation | Mirror position registration control apparatus |
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