JP2010201410A - Producing method of reducing solution and reducing solution generated by the producing method - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a producing method of a reducing solution which is generated by mixing potassium carbonate, sodium hydrogen carbonate, L-cysteine hydrochloride, glycine, citric acid-hydrate and calcium chloride 2 hydrate, and by dissolving it into water; and which is capable of producing a large amount of reducing solution with low oxidation-reduction potential having sufficient reducibility for a long time just by a pure chemical reaction, without operating an auxiliary facility such as a hydrogen pressurizing device and the like, with only a simple work schedule, quite easily and whenever and wherever. <P>SOLUTION: The reducing solution is generated after mixing 0.15-0.3 wt.% of potassium carbonate, 0.15-0.4 wt.% of sodium hydrogen carbonate, 0.8-1.2 wt.% of L-cysteine hydrochloride, 2.0-8.0 wt.% of glycine, 0.08-0.2 wt.% of citric acid-hydrate and 1.5-5.0 wt.% of calcium chloride 2 hydrate for 100 ml of water; and dissolving it into the water. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

  The present invention relates to a reducing solution manufacturing method and a reducing solution produced by the manufacturing method. More specifically, in view of the fact that carbonate ions react with hydrogen to produce water, carbon dioxide gas, and electrons. By adding many electrons only by chemical reaction without having any electrolyzer, pressurizer or contact solid material, the antioxidant power declines for a long time at room temperature, that is, a solution containing a lot of negative electric energy. The present invention relates to a method for producing a remarkably excellent reducing solution and a reducing solution produced by the method.

Conventionally, as a method for producing a reducing solution (generally also referred to as antioxidant water or reduced water), for example, those described in JP-A-2005-40765 and those described in JP-A-2004-351399 And those described in Japanese Patent Laid-Open No. 2006-68640.
JP 2005-40765 A JP 2004-351399 A JP 2006-68640 A

  Patent Documents 1 and 2 both require a hydrogen gas pressurizer when producing antioxidant water (reduced water), and the reduced water of Patent Document 3 is a contact with activated carbon, medicinal stones, or the like. Solid materials and the like are required, and all can produce reduced water having a negative oxidation-reduction potential. However, such a method for producing reduced water has the following problems. .

  That is, in the above-described method for producing reduced water, for example, in Patent Documents 1 and 2, a hydrogen pressurizing device and other incidental equipment for melting hydrogen gas into water are required. As a result, the facility operation cost increases.

  Moreover, in patent document 3, activated carbon, a medicinal stone, and a shell which are natural materials are required, and a period and material costs necessary for securing and securing the materials will inevitably arise.

  Therefore, in the case of producing antioxidant water (reduced water) using any of the production methods described in Patent Documents 1 to 3, the production cost inevitably increases, and the production cost is low and for a long time. There has been a problem in actual production that it is extremely difficult to produce a large amount of antioxidant water (reduced water) having a sufficient redox potential and low oxidation-reduction potential (antioxidant power).

  However, the present invention solves the above-mentioned problems, and the invention according to claim 1 includes potassium carbonate, sodium bicarbonate, L-cysteine hydrochloride, glycine, citric acid monohydrate and calcium chloride dihydrate. Since a product is mixed and then dissolved in water, a reducing solution with a low oxidation-reduction potential having sufficient reducibility over a long period of time only by a pure chemical reaction is applied to a hydrogen pressurizing device. Thus, it has a production advantage that a large amount of reducing solution can be produced anytime and anywhere with a simple operation process without operating any incidental equipment.

  Furthermore, according to the first aspect of the present invention, since ancillary equipment such as a hydrogen pressurization apparatus is unnecessary, it is possible to solve a management problem such as high equipment costs and increased equipment operation costs during production. In addition to having the advantage of being able to produce natural materials, there is no need for the time and material costs required to secure and prepare natural materials, thus producing a large amount of extremely low-cost reducing solutions that are inexpensive and explosive in the market. There is a great advantage in sales force that can be spread.

  Next, in the invention according to claim 2, calcium chloride dihydrate is mixed with the potassium carbonate, sodium bicarbonate, L-cysteine hydrochloride, glycine and citric acid monohydrate and dissolved in the water. Thereafter, when it is produced by dissolving in water after a predetermined time has elapsed, potassium carbonate, sodium bicarbonate, L-cysteine hydrochloride, glycine and citric acid monohydrate are mixed and dissolved in the water. By dissolving the calcium chloride dihydrate at the end of generation of the carbon dioxide gas generated at the time of introduction, there is an advantage that a further reduction in oxidation-reduction potential and stability can be caused.

  Furthermore, the invention according to claim 3 is not only extremely inexpensive and easy to handle when using tap water (tap water) as water, but also neutralizes residual chlorine contained in tap water, There is an advantage in use that it can be changed into a harmless component.

  According to the invention described in claim 1, after the reducing solution is mixed with potassium carbonate, sodium bicarbonate, L-cysteine hydrochloride, glycine, citric acid monohydrate and calcium chloride dihydrate, According to the reducing solution obtained by this production method, potassium carbonate contained in the reducing solution can be used as a source of carbon dioxide, and sodium hydrogen carbonate is carbon dioxide. Not only as a source of hydrogen but also with potassium carbonate alone can suppress the PH value from becoming too high, and L-cysteine hydrochloride generates hydrogen when hydrogen is generated when cysteine is oxidized in solution to produce cystine. Can be used as a source, glycine can eliminate the odor peculiar to reducing solutions, citric acid monohydrate can adjust pH value, calcium chloride Not only can dihydrate further reduce the redox potential of the reducing solution, but the water is not only easy to handle, but the residual chlorine in the water is immediately neutralized and turned into a harmless component. Each has a unique effect of being able to be made.

  Therefore, it is produced by mixing potassium carbonate, sodium hydrogen carbonate, L-cysteine hydrochloride, glycine, citric acid monohydrate and calcium chloride dihydrate having the specific effects described above, and then dissolving them in water. According to the reducing solution, residual chlorine in tap water (tap water) can be instantaneously reduced as reducing (antioxidant).

  Furthermore, foodstuffs such as vegetables, fruits, meats, etc., sprayed with the reducing solution or washed with the reducing solution should retain their freshness longer than in the general management state of each normal foodstuff. There is an effect that can be done.

  Furthermore, when the above reducing solution is drunk, it reacts with the active oxygen, which is generally said to be the cause of illness, to produce harmless water. Even if the solution is used by adding it to various beverages, foods, etc., it produces an effect that it reacts with active oxygen to become harmless water as described above.

  In addition, by adding the reducing solution to clean water when kneading wheat flour during bread production such as bread, there is an effect that the generation of mold can be significantly delayed.

  Furthermore, according to the reducing solution, since the water cluster is small, the permeability to the cells is inevitably improved, and the water-retaining power of the skin can be increased to give the skin tension. .

  Moreover, since the cluster of water becomes small as described above, for example, even when cooking rice, the permeability to rice is improved, and it is possible to cook plump and delicious rice.

  Furthermore, since this reducing solution does not decrease the ability of the antioxidative substance of the internal enzyme, that is, it can improve the activity of the enzyme, it can be decomposed, digested and absorbed when consumed. Since all the enzymes work in a place where water exists, a reducing solution that improves the action of the enzyme can not only increase immunity but also increase physical strength as a result.

  Furthermore, since the reducing solution has an extremely high surface activity, when it is drunk, it accumulates in the adipose tissue in the body, for example, the action of washing away poisons such as PCB and dioxin residual agricultural chemicals, so-called A detox effect can also be obtained.

  Further, by immersing vegetables, fruits and the like in the reducing solution for a predetermined time, there is an effect that agricultural chemicals attached to the vegetables, fruits and the like can be removed.

Hereinafter, an embodiment of a method for producing a reducing solution in the present invention will be described.
First, 2 g of potassium carbonate, 3 g of sodium bicarbonate, 10 g of L-cysteine hydrochloride, 40 g of glycine, 1 g of citric acid monohydrate and 20 g of calcium chloride dihydrate are prepared for 1000 ml of clean water (tap water). .

  Next, after mixing 2 g of the above potassium carbonate, 3 g of sodium bicarbonate, 10 g of L-cysteine hydrochloride, 40 g of glycine and 1 g of citric acid monohydrate in a predetermined container (not shown), Add and melt.

  At this time, carbon dioxide gas is generated from the container by a chemical reaction. Therefore, the container is left for a predetermined time until the carbon dioxide gas stops.

  Then, after confirming that carbon dioxide gas stops, a reducing solution can be produced | generated by adding and mixing 20 g of calcium chloride dihydrate in the said container.

  The reducing solution produced by the above production method was prepared by mixing 2 g of potassium carbonate, 3 g of sodium bicarbonate, 10 g of L-cysteine hydrochloride, 40 g of glycine, 1 g of citric acid monohydrate and 20 g of calcium chloride dihydrate. , And is generated by dissolving in 1000 ml of tap water (tap water).

  Therefore, a reductive solution having a low redox potential having sufficient reducibility over a long period of time only by a pure chemical reaction can be very easily and simply performed without operating ancillary equipment such as a hydrogen pressurization apparatus. It has come to have a production advantage that a large amount of reducing solution can be produced anytime and anywhere.

  Next, in order to investigate the stability and antioxidant properties of the reducing solution (sealed and stored at room temperature) produced in the above embodiment, 1 ml of the reducing solution is added to 100 ml of tap water to obtain oxidation-reduction. The potential (ORP) and pea etch (pH) were measured.

※ ＯＲＰ値：水素電極基準の値（Ｅｈ）に換算した値である。
酸化還元電位の測定には、東亜電波工業（株）製ＨＭ５０Ｖ型ｐＨメータ付属の ＯＲＰ同時測定装置（図示せず）を使用又ｐＨ測定には、東亜電波工業（株）製 ＨＭ５０Ｖ型ｐＨメータ（図示せず）を使用した。
上記表１によれば、酸化還元電位もｐＨも極端な変化を有することなく約６カ月間安定した値を示した。尚、その後も安定性試験を継続中である。

* ORP value: A value converted into a value (Eh) based on the hydrogen electrode.
For the measurement of the oxidation-reduction potential, an ORP simultaneous measurement device (not shown) attached to the HM50V type pH meter manufactured by Toa Denpa Kogyo Co., Ltd. is used. For the pH measurement, the HM50V type pH meter (manufactured by Toa Denpa Kogyo Co., Ltd.) (Not shown) was used.
According to Table 1, the oxidation-reduction potential and the pH showed stable values for about 6 months without having an extreme change. After that, the stability test is ongoing.

  Therefore, according to the reducing solution generated in the above-described embodiment, there is no need for incidental equipment such as a hydrogen pressurization device, compared to the conventional manufacturing method, so that the equipment operation at the time of expensive equipment costs and production is high. Not only does it have the advantage that it can solve management problems such as high costs, but it also eliminates the time and material costs necessary to secure and prepare natural materials, thus reducing the cost of reducing solutions. It has a great effect on sales force that it can be manufactured in large quantities and can be spread cheaply and explosively in the market.

  Further, after the calcium chloride dihydrate is mixed with the potassium carbonate, sodium bicarbonate, L-cysteine hydrochloride, glycine and citric acid monohydrate and dissolved in clean water, the calcium chloride dihydrate is dissolved after a predetermined time. Carbon dioxide gas generated when potassium carbonate, sodium hydrogen carbonate, L-cysteine hydrochloride, glycine, and citric acid monohydrate are mixed and dissolved in the water when generated by dissolving in water. When calcium chloride dihydrate is dissolved at the end of the generation, there is an effect that the oxidation-reduction potential can be further lowered and stabilized.

  Furthermore, when using clean water (tap water) as water, not only is it inexpensive and easy to handle, it is also possible to neutralize residual chlorine contained in clean water and change it into harmless components. There is an effect on use that can be done.

  The reducing solution produced in the above embodiment is composed of 2 g of potassium carbonate, 3 g of sodium bicarbonate, 10 g of L-cysteine hydrochloride, 40 g of glycine, and citric acid monohydrate with respect to 1000 ml of clean water (tap water). Although 1 g and 20 g of calcium chloride dihydrate were used, it is not necessarily limited to this value.

  That is, in the case of producing a reducing solution, 0.15 to 0.3% by weight of potassium carbonate, 0.15 to 0.4% by weight of sodium bicarbonate, 0.8 to 1.2% per 100 ml of water. Wt-% L-cysteine hydrochloride, 2.0-8.0 wt% glycine, 0.08-0.2 wt% citric acid monohydrate and 1.5-5.0 wt% calcium chloride If it is produced by mixing the dihydrate and then dissolving it in the water, the ORP and pH values will remain stable for about 6 months without any extreme changes in the ORP or pH. There is a special effect that you can.

  The reducing solution in the present invention can be applied to various foods such as sports drinks, fruit drinks, milk drinks, tea drinks, vegetable juices, alcoholic drinks, carbonated drinks, soft and hard drinking water, etc. The present invention relates to a method for producing a reducing solution that can be produced only by a chemical reaction, and a reducing solution produced by the production method.

Claims (4)

  1. 0.15-0.3 wt% potassium carbonate, 0.15-0.4 wt% sodium bicarbonate, 0.8-1.2 wt% L-cysteine hydrochloride per 100 ml water After mixing 0-8.0 wt% glycine, 0.08-0.2 wt% citric acid monohydrate and 1.5-5.0 wt% calcium chloride dihydrate, the water A method for producing a reducing solution, characterized in that the reducing solution is produced by dissolving in water.   The calcium chloride dihydrate is mixed with the potassium carbonate, sodium hydrogen carbonate, L-cysteine hydrochloride, glycine and citric acid monohydrate and dissolved in the water. The method for producing a reducing solution according to claim 1, wherein the reducing solution is produced by being dissolved in an aqueous solution.   3. The method for producing a reducing solution according to claim 1, wherein clean water is used as the water.   A reducing solution produced by the production method according to claim 1.