JP2009173768A - Sterilizing detergent composition for toilet seat, sterilizing cleaning material containing the same, and sterilizing cleaning method using them - Google Patents
Sterilizing detergent composition for toilet seat, sterilizing cleaning material containing the same, and sterilizing cleaning method using them Download PDFInfo
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- JP2009173768A JP2009173768A JP2008013785A JP2008013785A JP2009173768A JP 2009173768 A JP2009173768 A JP 2009173768A JP 2008013785 A JP2008013785 A JP 2008013785A JP 2008013785 A JP2008013785 A JP 2008013785A JP 2009173768 A JP2009173768 A JP 2009173768A
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- fatty acid
- acid ester
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- acid
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- 239000000203 mixture Substances 0.000 title claims abstract description 68
- 239000003599 detergent Substances 0.000 title claims abstract description 36
- 238000004140 cleaning Methods 0.000 title claims abstract description 33
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 23
- 239000011538 cleaning material Substances 0.000 title claims abstract description 12
- -1 alkali metal salt Chemical class 0.000 claims abstract description 88
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- 150000007524 organic acids Chemical class 0.000 claims abstract description 7
- 235000019441 ethanol Nutrition 0.000 claims description 27
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 24
- 238000004659 sterilization and disinfection Methods 0.000 claims description 23
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- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
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- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 8
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- 230000007850 degeneration Effects 0.000 description 1
- VWTINHYPRWEBQY-UHFFFAOYSA-N denatonium Chemical compound [O-]C(=O)C1=CC=CC=C1.C=1C=CC=CC=1C[N+](CC)(CC)CC(=O)NC1=C(C)C=CC=C1C VWTINHYPRWEBQY-UHFFFAOYSA-N 0.000 description 1
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- 239000011928 denatured alcohol Substances 0.000 description 1
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- 230000000741 diarrhetic effect Effects 0.000 description 1
- 229960004670 didecyldimethylammonium chloride Drugs 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- TUCSOESCAKHLJM-UHFFFAOYSA-L dipotassium carbonic acid carbonate Chemical compound [K+].[K+].OC(O)=O.OC(O)=O.[O-]C([O-])=O TUCSOESCAKHLJM-UHFFFAOYSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- KOWVMYVNEXNXDF-UHFFFAOYSA-N dodecanoic acid propane-1,2,3-triol Chemical compound OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.CCCCCCCCCCCC(O)=O KOWVMYVNEXNXDF-UHFFFAOYSA-N 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
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- 239000003112 inhibitor Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
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- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 150000004701 malic acid derivatives Chemical class 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- SQABAALQCGKFFO-UHFFFAOYSA-N octanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CCCCCCCC(O)=O SQABAALQCGKFFO-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
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- 239000000467 phytic acid Substances 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
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- 229920001155 polypropylene Polymers 0.000 description 1
- 239000004224 potassium gluconate Substances 0.000 description 1
- 235000013926 potassium gluconate Nutrition 0.000 description 1
- 229960003189 potassium gluconate Drugs 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- DGPCSURYVBYWAT-UHFFFAOYSA-N propane-1,2,3-triol;tetradecanoic acid Chemical compound OCC(O)CO.CCCCCCCCCCCCCC(O)=O DGPCSURYVBYWAT-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229940112950 sage extract Drugs 0.000 description 1
- 235000020752 sage extract Nutrition 0.000 description 1
- 238000013207 serial dilution Methods 0.000 description 1
- 229960001790 sodium citrate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
- 229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- XFLNVMPCPRLYBE-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate;tetrahydrate Chemical compound O.O.O.O.[Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XFLNVMPCPRLYBE-UHFFFAOYSA-J 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
本発明は、ウイルスおよび細菌の双方に効果を発現する便座用除菌洗浄剤組成物およびこれを含有する除菌洗浄材、ならびにこれらを用いた除菌洗浄方法に関する。 The present invention relates to a toilet seat sanitizing detergent composition that exhibits effects on both viruses and bacteria, a sanitizing detergent containing the composition, and a disinfecting washing method using the same.
近年、ノロウイルスによる食中毒の増加が問題になっている。平成１８年度は発生件数、患者数共にノロウイルスによる食中毒の発生率が最も高く、その発生件数は約５００件であり、その患者数は約２７６００人と非常に多く、その感染力の強さに起因して大規模な食中毒の発生につながっている。また、ノロウイルスによる食中毒の原因は、カキなどの２枚貝を食することにあるといわれていたが、最近では、食品、糞便や嘔吐物に含まれるノロウイルスが、人から人へ感染すること、さらに、汚染された食品や水を介して清浄な表面に接触することなどにより広がってしまうといった二次汚染が主原因であることがわかってきた。 In recent years, an increase in food poisoning caused by norovirus has been a problem. In FY2006, the incidence of food poisoning due to norovirus was the highest in both the number of cases and the number of patients, the number of occurrences was about 500, and the number of patients was very high at about 27600, resulting from the strong infectivity. This has led to the occurrence of large-scale food poisoning. In addition, the cause of food poisoning due to norovirus was said to be eating bivalves such as oysters, but recently, norovirus contained in food, feces and vomit is infected from person to person, Furthermore, it has been found that secondary contamination, such as spreading through contact with a clean surface via contaminated food or water, is the main cause.
ノロウイルスに感染すると、糞便や嘔吐物にはかなりの量のノロウイルスが存在することになる。トイレで嘔吐したり、下痢の糞便を排出した際には、その多くは浄化槽等へと流れていくが、その一部は多量のノロウイルスとともに便器や便座に付着することになる。また、ノロウイルスは小さいので、トイレットペーパーをすり抜けて手指にも大量に付着することになり、ノロウイルスの付着した手でトイレのドアノブや洗面化粧台の水道の蛇口等を握ることになり、ノロウイルスによる汚染の範囲は拡大することになる。これらを防ぐためには、トイレ使用後の手洗いの徹底はもとより、トイレの便座やドアノブ等に付着したウイルスの除去を行うことが二次感染を防ぐ上で重要となる。 When infected with norovirus, a significant amount of norovirus is present in feces and vomit. When vomiting in the toilet or excretion of diarrheal stool, most of it flows to the septic tank, etc., but part of it adheres to the toilet and toilet seat along with a large amount of norovirus. In addition, since norovirus is small, it passes through toilet paper and adheres to the fingers in large quantities, and the norovirus-attached hand grips the toilet doorknob and the faucet of the bathroom vanity. The range of will be expanded. In order to prevent these problems, it is important to remove viruses attached to toilet seats, door knobs, etc., as well as thoroughly washing hands after using the toilet, in order to prevent secondary infection.
ところで、「ノロウイルス」とは、以前はノーウォークウイルスや小型球形ウイルスと呼ばれていたが、国際ウイルス学会でカリシウイルス科のノロウイルス属と決定された。つまり、ノロウイルスは、ＲＮＡのみを持ったＲＮＡ型ウイルスで、ＲＮＡの周りをカプシドと呼ばれるたんぱく質の殻で覆われており、エンベロープと呼ばれる糖と脂質からなる膜を持っていない。 By the way, “Norovirus” was previously called Norwalk virus or small spherical virus, but it was determined by the International Virological Society as the Norovirus genus of the Caliciviridae family. In other words, Norovirus is an RNA-type virus that has only RNA, and the RNA is covered with a protein shell called capsid and does not have a sugar-and-lipid membrane called an envelope.
一般的にエンベロープを持っているウイルスは、薬剤により簡単にエンベロープが破壊され、宿主細胞のレセプターと結合できなくなるので不活化できる。しかし、ノロウイルスはこのエンベロープを持っていないために、薬剤に対しての抵抗性を有している。 In general, a virus having an envelope can be inactivated because the envelope is easily destroyed by a drug and cannot bind to a host cell receptor. However, because norovirus does not have this envelope, it is resistant to drugs.
ノロウイルスの不活化の方法としては、次亜塩素酸ナトリウム溶液を用いる方法や、熱湯消毒による方法が知られている（非特許文献１を参照）。しかし、熱湯消毒では、８５℃以上の温度を保持することが望ましいが、被消毒物に熱湯をかけると、被消毒物との接触によって温度が低下してしまい、所望の温度を保持することが困難であることや、被消毒物の材質への影響、作業時におけるやけどの危険性等から作業性に乏しいものとなる。 As a method for inactivating norovirus, a method using a sodium hypochlorite solution and a method using hot water disinfection are known (see Non-Patent Document 1). However, in hot water disinfection, it is desirable to maintain a temperature of 85 ° C. or higher. However, if hot water is applied to the object to be disinfected, the temperature decreases due to contact with the object to be disinfected, and the desired temperature can be maintained. The workability is poor due to difficulties, the influence on the material of the disinfectant, and the risk of burns during work.
また、次亜塩素酸ナトリウム溶液による消毒方法では、被消毒物が金属硬表面やプラスチック硬表面である場合には、さび、劣化および腐蝕等が生じることがある。さらに被消毒物によっては、次亜塩素酸ナトリウムの漂白作用・効果により脱色されてしまうといった問題がある。また、トイレ内等に次亜塩素酸ナトリウムの臭いが蔓延してしまうといった問題や、万が一、誤ってトイレ用酸性洗剤等と併用して用いてしまった場合には、毒性の高い塩素ガスが発生し、最悪の場合は死に至るという恐れもある。 Further, in the disinfection method using a sodium hypochlorite solution, rust, deterioration, corrosion, and the like may occur when the object to be disinfected is a hard metal surface or a hard plastic surface. Furthermore, depending on the disinfectant, there is a problem that decolorization occurs due to the bleaching action / effect of sodium hypochlorite. In addition, the problem that sodium hypochlorite odor spreads in the toilet, etc., or if it is accidentally used in combination with an acidic detergent for toilets, highly toxic chlorine gas is generated. In the worst case, there is a risk of death.
そこで、通常、トイレの便座等の除菌洗浄には、アルコールを主成分とする除菌洗浄剤が用いられている。 Therefore, a sterilization detergent mainly composed of alcohol is usually used for sterilization and washing of toilet seats and the like.
アルコールは、ノロウイルスの代替ウイルスであるネコカリシウイルスＦ９株に対しての不活化効果に乏しいことが知られている（非特許文献２および３を参照）。なお、ノロウイルスは培養細胞や動物実験への感染が成功していないために、アメリカ合衆国環境保護庁（ＥＰＡ）のノロウイルス試験法では、ネコカリシウイルスＦ９株が代替ウイルスとして用いられているのが現状であり、抗ウイルス試験や実験等の場合には、日本国内外でノロウイルスの代替ウイルスとしてネコカリシウイルスが用いられている。 Alcohol is known to have a poor inactivation effect on feline calicivirus F9 strain, which is a substitute virus for Norovirus (see Non-Patent Documents 2 and 3). Since norovirus has not been successfully infected into cultured cells or animal experiments, the feline calicivirus F9 strain is currently used as an alternative virus in the US Environmental Protection Agency (EPA) norovirus test method. In the case of antiviral tests and experiments, feline calicivirus is used as a substitute virus for norovirus both in Japan and abroad.
特開平９−２０２９００号公報には、（Ａ）非イオン界面活性剤及び両性界面活性剤の中から選ばれる１種又は２種以上の界面活性剤０．０１重量％〜５．０重量％、（Ｂ）２０℃における蒸気圧が２ｍｍＨｇ以上の１価アルコール、多価アルコール及びその誘導体の中から選ばれる１種又は２種以上の溶剤、１０〜５０重量％、（Ｃ）リン酸、炭酸、ホウ酸、クエン酸、リンゴ酸、コハク酸、グルタル酸、安息香酸、酢酸からなる酸及びそれらの塩の中から選ばれる１種又は２種以上の化合物０．０００２〜２．０重量％、及び（Ｄ）水残部を含有し、硬表面に吹きかけて、トイレットペーパー等の紙により手軽にふきとることによって、汚れの除去ができ、硬表面に使用後の残存感や光沢を残すことなく洗浄面自体が本来有している色彩を鮮やかに回復させる液体洗浄剤組成物が開示されている（特許文献１を参照）。 JP-A-9-202900 discloses (A) 0.01% by weight to 5.0% by weight of one or more surfactants selected from nonionic surfactants and amphoteric surfactants, (B) One or more solvents selected from monohydric alcohol, polyhydric alcohol and derivatives thereof having a vapor pressure of 2 mmHg or higher at 20 ° C., 10 to 50% by weight, (C) phosphoric acid, carbonic acid, 0.0002 to 2.0% by weight of one or more compounds selected from boric acid, citric acid, malic acid, succinic acid, glutaric acid, benzoic acid, acetic acid and salts thereof, and (D) Containing water residue, spraying on hard surface, and easily wiping with paper such as toilet paper, dirt can be removed, cleaning surface itself without leaving a residual feeling and gloss after use on the hard surface Colors originally possessed by Liquid detergent compositions which vividly recovery has been disclosed (see Patent Document 1).
また、特開平１０−１６９７号公報には、（Ａ）エチレンオキサイド平均付加モル数１〜５０のポリオキシエチレンＣ８〜２０アルキルエ−テル硫酸、Ｃ８〜２０アルキル硫酸エステル等のアニオン界面活性剤（Ａ１）と、特定の両性界面活性剤（Ａ２）を、Ａ１／Ａ２の重量比で９９／１〜２５／７５の割合で含有させてなる界面活性剤混合物０．０１〜２０（重量）％、及び（Ｂ）１〜３価Ｃ１〜５アルコール、そのアルキルエーテル化合物等の水溶性溶剤０．１〜２０％、場合により、さらに（Ｃ）シュウ酸、エチレンジアミン四酢酸等のキレート剤０．１〜１０％、を含有し、高い洗浄力と便の付着を防止する防汚性を有し、かつ便器周りの洗浄時に便座等に使用されている樹脂を損傷する事のないトイレ用洗浄剤組成物が開示されている（特許文献２を参照）。 Further, JP-A-10-1697 discloses (A) anionic surfactants (A1) such as (A) polyoxyethylene C8-20 alkyl ether sulfuric acid, C8-20 alkyl sulfuric acid ester having an average added mole number of ethylene oxide of 1-50. ) And a specific amphoteric surfactant (A2) in a ratio of 99/1 to 25/75 in a weight ratio of A1 / A2 of 0.01 to 20 (weight)%, and (B) 0.1 to 20% of a water-soluble solvent such as 1 to 3 valent C1 to 5 alcohol and its alkyl ether compound, and optionally (C) a chelating agent such as oxalic acid and ethylenediaminetetraacetic acid 0.1 to 10 Is a toilet cleaner composition that has a high detergency and antifouling property that prevents stool adhesion and that does not damage the resin used in the toilet seat, etc. Disclosed Are (see Patent Document 2).
特開平１１−１７００号公報には、低分子量で脱アセチル化度が８０％以上のキトサン０．０１〜１重量％、第４級アンモニウム塩０．０１〜０．５重量％、及びアルコール系溶媒を局方精製水に対して０．５〜２容量部を含有して座席クリーナー用薬剤組成物と、この組成物を紙、ガーゼ、脱脂綿、不織布等の担体に対し、担体乾燥重量の５倍以下の量を含浸させて、ポリ袋または缶などの容器に収めて便座クリーナー用ウエットティッシュとして用いる方法やアルコール等の有機溶媒と共に噴霧容器に収容して、便座表面に直接噴霧したり、ティッシュペーパー等に噴霧して清拭したりする便座クリーナー用殺菌スプレーとして用いる方法が開示されている（特許文献３を参照）。 Japanese Patent Laid-Open No. 11-1700 discloses 0.01 to 1% by weight of chitosan having a low molecular weight and a deacetylation degree of 80% or more, 0.01 to 0.5% by weight of a quaternary ammonium salt, and an alcohol solvent. A pharmaceutical composition for seat cleaner containing 0.5 to 2 parts by volume relative to pharmacopoeia purified water, and this composition is 5 times the dry weight of the carrier with respect to a carrier such as paper, gauze, absorbent cotton or nonwoven fabric. Impregnate the following amount, put it in a container such as a plastic bag or can and use it as a wet tissue for toilet seat cleaner or store it in a spray container with an organic solvent such as alcohol and spray it directly on the toilet seat surface, or tissue paper A method of using it as a sterilizing spray for toilet seat cleaner that is sprayed and wiped on the surface is disclosed (see Patent Document 3).
特開平１１−６１１９９号公報には、（Ａ）ポリオキシアルキレン鎖を有しない、糖脂肪酸エステル等の非イオン界面活性剤及び、アルキルベタイン型等の両性界面活性剤の中から選ばれる１種または２種以上の界面活性剤の好ましくは０．１〜２．０（重量）％、（Ｂ）２０°Ｃにおける蒸気圧が２ｍｍＨｇ以上の、エチルアルコール等の１価アルコール、エチレングリコール等の多価アルコールから選ばれる１種または２種以上の溶剤の好ましくは２０．０％以上、（Ｃ）リン酸等の酸及びそれらの塩の中から選ばれる１種または２種以上の化合物の好ましくは０．０００１〜５．０％、及び（Ｄ）塩化ベンザルコニウム等の殺菌剤の好ましくは０．００１〜５．０％を含有し、住宅内の器具、機器類の汚れの除去性、細菌の繁殖を抑制及び保存安定性を有する液体洗浄剤組成物が開示されている（特許文献４を参照）。 JP-A-11-61199 discloses (A) a nonionic surfactant such as a sugar fatty acid ester that does not have a polyoxyalkylene chain and an amphoteric surfactant such as an alkylbetaine type, Two or more surfactants, preferably 0.1 to 2.0 (weight)%, (B) a monohydric alcohol such as ethyl alcohol having a vapor pressure of 2 mmHg or more at 20 ° C., and a polyvalent such as ethylene glycol. Preferably 10.0% or more of one or more solvents selected from alcohols, (C) One or more compounds selected from (C) acids such as phosphoric acid and their salts, preferably 0 0.001 to 5.0%, and (D) preferably contains 0.001 to 5.0% of a sterilizing agent such as benzalkonium chloride. Suppress breeding Liquid detergent compositions with finely storage stability is disclosed (see Patent Document 4).
特開平１１−２０９２０２号公報には、除菌成分としてエタノール、増粘剤としてカルボキシビニルポリマー、中和剤としてトリエタノールアミン、そのほかに保湿性と消炎のためにカミツレ抽出液を配合し、イオン交換水に溶解してなる便座用粘稠性除菌剤組成物が開示されている（特許文献５を参照）。 JP-A-11-209202 contains ethanol as a sterilizing component, carboxyvinyl polymer as a thickener, triethanolamine as a neutralizing agent, and chamomile extract for moisturizing and extinguishing, and ion exchange. A toilet sanitary viscous disinfectant composition dissolved in water has been disclosed (see Patent Document 5).
特開２００７−４５７３２号公報には、ポリヘキサメチレンビグアナイド系化合物を０．０５〜０．５重量％、アルコールを４０〜８０重量％、更に塩化ベンザルコニウム、塩化セチルビリジニウム、フエノキシエタノール、グルコン酸クロロヘキシジン、ラウリル硫酸塩等の他の抗菌成分を含有し、且つｐＨが９〜１２の範囲にある消毒液および消毒用物品が開示されている（特許文献６を参照）。 Japanese Patent Application Laid-Open No. 2007-45732 discloses a polyhexamethylene biguanide compound in an amount of 0.05 to 0.5% by weight, an alcohol in an amount of 40 to 80% by weight, benzalkonium chloride, cetylviridinium chloride, phenoxy. Disinfecting liquids and disinfecting articles containing other antibacterial components such as ethanol, chlorohexidine gluconate, lauryl sulfate and the like and having a pH in the range of 9 to 12 have been disclosed (see Patent Document 6).
特開２００７−３２０９２４号公報には、グレープフルーツ種子抽出液を水に溶かし、フイチン酸を加えた上で、醸造用アルコールを加えてなり、且つ、ｐＨが５．８乃至６．４の範囲に調整されたノロウイルスの不活化効果を有する除菌液及びその製造方法が開示されている（特許文献７を参照）。 Japanese Patent Application Laid-Open No. 2007-320924 discloses that a grapefruit seed extract is dissolved in water, phytic acid is added, brewing alcohol is added, and the pH is adjusted to a range of 5.8 to 6.4. Disclosed are a sterilizing solution having an inactivating effect on norovirus and a method for producing the same (see Patent Document 7).
しかしながら、これらの文献に記載された技術内容や組成物は、それぞれが特定の性能を満たすに過ぎず、総合的に満足のいくものが得られていないのが実情である。 However, the technical contents and compositions described in these documents only satisfy specific performances, and it is a fact that comprehensively satisfactory products are not obtained.
本発明は、このような事情に鑑みなされたもので、ウイルスおよび細菌の双方に効果を発現する便座用除菌洗浄剤組成物およびこれを含有する除菌洗浄材、ならびにこれらを用いた除菌洗浄方法の提供を目的とする。なかでも、組成物の安全性、毒性等の点から、食品添加物で構成される便座用除菌洗浄剤組成物の提供を目的とする。 The present invention has been made in view of such circumstances, and is a sanitary detergent composition for toilet seats that exhibits effects on both viruses and bacteria, a disinfecting cleaning material containing the same, and disinfecting using these The purpose is to provide a cleaning method. In particular, an object of the present invention is to provide a sanitary detergent composition for toilet seats composed of food additives from the viewpoint of safety and toxicity of the composition.
上記の目的を達成するため、本発明は、下記の（Ａ）〜（Ｃ）成分を、組成物全体に対し下記の割合で含有するとともに、（Ｄ）成分として水を含有し、且つ組成物の原液のｐＨ（ＪＩＳ Ｚ−８８０２：１９８４「ｐＨ測定方法」）が、２５℃で８〜１２の範囲に設定されている便座用除菌洗浄剤組成物を第１の要旨とする。
（Ａ）低級アルコール３５〜７５質量％
（Ｂ）（ｂ１）有機酸およびそのアルカリ金属塩、および／または（ｂ２）無機酸およびそのアルカリ金属塩０．０５〜１０質量％
（Ｃ）モノグリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ショ糖脂肪酸エステルから選ばれる少なくとも一種の非イオン界面活性剤０．０５〜５質量％。
In order to achieve the above object, the present invention contains the following components (A) to (C) in the following proportion with respect to the whole composition, and also contains water as the component (D), The first gist is a sanitary sanitizing composition for toilet seats in which the pH of the stock solution (JIS Z-8802: 1984 “pH measurement method”) is set in the range of 8 to 12 at 25 ° C.
(A) 35-75 mass% of lower alcohol
(B) (b1) Organic acid and alkali metal salt thereof, and / or (b2) Inorganic acid and alkali metal salt thereof 0.05 to 10% by mass
(C) 0.05-5 mass% of at least one nonionic surfactant selected from monoglycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, and sucrose fatty acid ester.
このうち、上記（Ａ）成分がエチルアルコールである上記便座用除菌洗浄剤組成物を第２の要旨とする。 Among these, the said sterilization detergent composition for toilet seats whose said (A) component is ethyl alcohol makes a 2nd summary.
また、上記（Ｂ）成分のうちの（ｂ１）成分が、クエン酸、リンゴ酸、グルコン酸、コハク酸、酒石酸、乳酸およびこれらのアルカリ金属塩から選ばれる少なくとも一種である上記便座用除菌洗浄剤組成物を第３の要旨とし、さらに、上記（Ｂ）成分のうちの（ｂ２）成分が、重炭酸ナトリウム、重炭酸カリウム、炭酸ナトリウム、炭酸カリウムから選ばれる少なくとも一種である上記便座用除菌洗浄剤組成物を第４の要旨とする。 In addition, (B1) component of the component (B) is at least one selected from citric acid, malic acid, gluconic acid, succinic acid, tartaric acid, lactic acid and alkali metal salts thereof. The composition for the toilet seat according to the third aspect, wherein the component (b2) of the component (B) is at least one selected from sodium bicarbonate, potassium bicarbonate, sodium carbonate, and potassium carbonate. The fungus detergent composition is the fourth gist.
なかでも、上記（Ａ）〜（Ｃ）成分のいずれもが、食品添加物から選択されるものである上記便座用除菌洗浄剤組成物を第５の要旨とする。 Especially, let the said disinfectant | cleaning agent composition for toilet seats which all of said (A)-(C) component is selected from a food additive make a 5th summary.
そして、上記要旨１〜５のいずれか一項の便座用除菌洗浄剤組成物を、不織布に含浸させてなる除菌洗浄材を第６の要旨とする。また、当該除菌洗浄材を用いて除菌洗浄するものである除菌洗浄方法を第７の要旨とする。 And let the disinfection cleaning material formed by impregnating the nonwoven fabric cleaning composition for toilet seats of any one of the said summaries 1-5 into a 6th summary. Moreover, let the disinfection washing | cleaning method which is disinfecting washing | cleaning using the said disinfection cleaning material be the 7th summary.
また、上記要旨１〜５のいずれか一項の便座用除菌洗浄剤組成物を、被除菌洗浄物の表面に噴霧させてなる除菌洗浄方法を第８の要旨とする。 Moreover, let the disinfection washing | cleaning method formed by spraying the sanitization washing | cleaning composition composition for toilet seats of any one of the said summaries 1-5 on the surface of the to-be-disinfected washing | cleaning object be the 8th summary.
すなわち、本発明の便座用除菌洗浄剤組成物は、ウイルスおよび細菌の双方に効果を発現する便座用除菌洗浄剤組成物およびこれを含有する除菌洗浄材、ならびにこれらを用いた除菌洗浄方法を提供することができる。なかでも、組成物の安全性、毒性等の点から、食品添加物で構成される便座用除菌洗浄剤組成物を提供することができる。 That is, the sanitary detergent composition for toilet seats of the present invention includes a sanitary detergent composition for toilet seats that exhibits effects on both viruses and bacteria, a disinfecting cleaning material containing the composition, and a disinfectant using the same. A cleaning method can be provided. Among these, from the viewpoint of the safety and toxicity of the composition, it is possible to provide a sanitary detergent composition for toilet seats composed of food additives.
更に詳しくは、本発明の便座用除菌洗浄剤組成物は、特に、トイレの便座、便器、ドアノブ等の硬表面の除菌洗浄に好適であり、これら便座用除菌洗浄剤組成物はスプレー等に内填され、トイレの便房、洗面化粧台等に配置されて使用される。例えば、使用時毎に、約６〜１２ｍｌ／ｍ２の割合でトイレの便座、便器、ドアノブ等に直接噴霧し、放置乾燥あるいはトイレットペーパー等で適宜拭き取ることによりトイレの便座、便器、ドアノブ等の硬表面のに対して、除菌洗浄を行うことができる。また、便座用除菌洗浄剤組成物をスプレーしたトイレットペーパーにより、トイレの便座を拭き取ることで除菌洗浄をおこなうことができる。 More specifically, the disinfectant cleaning composition for toilet seats of the present invention is particularly suitable for disinfecting and cleaning hard surfaces such as toilet seats, toilet bowls, doorknobs, etc. in toilet seats. Etc., and is used by being placed in a toilet toilet, a vanity, etc. For example, each time it is used, it is sprayed directly on the toilet seat, toilet bowl, door knob, etc. at a rate of about 6-12 ml / m 2 Bactericidal cleaning can be performed on the hard surface. Moreover, sterilization washing can be performed by wiping the toilet seat of the toilet with toilet paper sprayed with the sanitizing detergent composition for toilet seat.
このほか、本発明の便座用除菌洗浄剤組成物を不織布に含浸させた除菌洗浄材は、トイレの便座、便器、ドアノブ等の硬表面に対して、拭き取り作業による除菌洗浄をおこなうことができる。 In addition, the disinfecting cleaning material impregnated with the sanitizing detergent composition for toilet seats of the present invention is to disinfect and clean the hard surfaces of toilet seats, toilet bowls, door knobs, etc. Can do.
つぎに、本発明を実施するための最良の形態について詳細に説明する。 Next, the best mode for carrying out the present invention will be described in detail.
本発明の便座用除菌洗浄剤組成物は、（Ａ）低級アルコールと、（Ｂ）（ｂ１）有機酸およびそのアルカリ金属塩、および／または（ｂ２）無機酸およびそのアルカリ金属塩と、（Ｃ）モノグリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ショ糖脂肪酸エステルから選ばれる少なくとも一種の非イオン界面活性剤と、（Ｄ）水とを用いて得られる。 The sanitary detergent composition for toilet seats of the present invention comprises (A) a lower alcohol, (B) (b1) an organic acid and an alkali metal salt thereof, and / or (b2) an inorganic acid and an alkali metal salt thereof ( C) Obtained using at least one nonionic surfactant selected from monoglycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, and sucrose fatty acid ester, and (D) water. .
本発明の便座用除菌洗浄剤組成物に用いられる（Ａ）成分の低級アルコールとしては、エチルアルコール、イソプロピルアルコール、変性アルコール等が挙げられる。このうち、変性アルコールとしては、例えば、ゲラニオール，八アセチル化ショ糖，フェニルエチルアルコール，ブルシン，リナノール，ジエチルフタレート，リナリールアセテート，ベンジルアセテート，１０質量％安息香酸デナトニウムアルコール溶液，フレーバーＨ−Ｎｏ．１１やＨ−１３等の変性剤により変性された各種変性エチルアルコール等が挙げられる。これらは単独で用いても、または２種以上を組み合わせて用いてもよい。なお、市販品であれば、アルコール濃度が６０〜１００質量％のものが好ましく用いられる。特に、安全性、毒性の点から、エチルアルコールが好適に用いられる。 Examples of the lower alcohol of the component (A) used in the toilet seat sanitizing detergent composition of the present invention include ethyl alcohol, isopropyl alcohol, and denatured alcohol. Among these, examples of the modified alcohol include geraniol, octaacetylated sucrose, phenylethyl alcohol, brucine, linanol, diethyl phthalate, linalyl acetate, benzyl acetate, 10% by mass denatonium benzoate alcohol solution, and flavor H-No. . And various modified ethyl alcohols modified with a modifier such as 11 or H-13. These may be used alone or in combination of two or more. In addition, if it is a commercial item, a thing with an alcohol concentration of 60-100 mass% is used preferably. In particular, ethyl alcohol is preferably used from the viewpoint of safety and toxicity.
上記（Ａ）成分の低級アルコールは、便座用除菌洗浄剤組成物中に、３５〜７５質量％、好ましくは、皮膚刺激、貯蔵安定性の観点から、４５〜７０質量％の範囲に設定することが好ましい。３５質量％未満では、細菌に対する除菌力に乏しく、特にウイルスの不活化効果に乏しい。７５質量％を超えて配合した場合には、他の配合成分とのバランスから、沈殿、析出または分離し、貯蔵安定性が得らないことに起因して、ウイルスの不活化力に欠けることにつながるだけでなく、洗浄力の低下も起こしやすくなり好ましくない。 The lower alcohol as the component (A) is set in the range of 35 to 75% by mass, preferably 45 to 70% by mass from the viewpoint of skin irritation and storage stability, in the sanitary detergent composition for toilet seats. It is preferable. If it is less than 35% by mass, the sterilizing power against bacteria is poor, and the inactivating effect of viruses is particularly poor. When blended in excess of 75% by mass, the virus inactivates its ability to inactivate due to precipitation, precipitation or separation from the balance with other blending components, and lack of storage stability. Not only is it connected, but it also tends to cause a decrease in cleaning power, which is not preferable.
本発明の便座用除菌洗浄剤組成物に用いられる（Ｂ）成分は、（ｂ１）有機酸およびそのアルカリ金属塩、および／または（ｂ２）無機酸およびそのアルカリ金属塩である。 The component (B) used in the toilet seat sanitizing detergent composition of the present invention is (b1) an organic acid and its alkali metal salt, and / or (b2) an inorganic acid and its alkali metal salt.
上記（ｂ１）成分である有機酸およびそのアルカリ金属塩としては、クエン酸、リンゴ酸、グルコン酸、コハク酸、酒石酸、乳酸およびこれらのアルカリ金属塩から選ばれる少なくとも一種であって、アルカリ金属塩としては、ナトリウム塩、カリウム塩等が挙げられる。さらに詳しくは、クエン酸、リンゴ酸、グルコン酸、コハク酸、酒石酸、乳酸、クエン酸ナトリウム、クエン酸カリウム、リンゴ酸ナトリウム、グルコン酸ナトリウム、グルコン酸カリウム、コハク酸ナトリウム、酒石酸ナトリウム、乳酸ナトリウム等が挙げられる。これらは単独で用いても、または２種以上を組み合わせて用いてもよい。なかでも、殺菌、消毒の効果の点、入手の容易さの点から、特にクエン酸、クエン酸ナトリウム、クエン酸カリウム、グルコン酸ナトリウム、リンゴ酸ナトリウム、酒石酸ナトリウム、乳酸ナトリウムが好ましい。 The organic acid which is the component (b1) and the alkali metal salt thereof are at least one selected from citric acid, malic acid, gluconic acid, succinic acid, tartaric acid, lactic acid and alkali metal salts thereof, Examples thereof include sodium salts and potassium salts. More specifically, citric acid, malic acid, gluconic acid, succinic acid, tartaric acid, lactic acid, sodium citrate, potassium citrate, sodium malate, sodium gluconate, potassium gluconate, sodium succinate, sodium tartrate, sodium lactate, etc. Is mentioned. These may be used alone or in combination of two or more. Of these, citric acid, sodium citrate, potassium citrate, sodium gluconate, sodium malate, sodium tartrate, and sodium lactate are particularly preferred from the viewpoints of sterilization and disinfection effects and availability.
また、（ｂ２）成分である無機酸およびそのアルカリ金属塩としては、重炭酸ナトリウム、重炭酸カリウム、セスキ炭酸ナトリウム、セスキ炭酸カリウム、炭酸ナトリウム、炭酸カリウム等が挙げられる。これらは単独で用いても、または２種以上を組み合わせて用いてもよい。なかでも、炭酸ナトリウム、重炭酸ナトリウムが好ましく、特に皮膚刺激を緩和させる点から、重炭酸ナトリウムが好ましい。 Examples of the inorganic acid and alkali metal salt thereof as component (b2) include sodium bicarbonate, potassium bicarbonate, sodium sesquicarbonate, potassium sesquicarbonate, sodium carbonate, and potassium carbonate. These may be used alone or in combination of two or more. Of these, sodium carbonate and sodium bicarbonate are preferable, and sodium bicarbonate is particularly preferable in terms of alleviating skin irritation.
上記（Ｂ）成分の（ｂ１）有機酸およびそのアルカリ金属塩、および／または（ｂ２）無機酸およびそのアルカリ金属塩は、便座用除菌洗浄剤組成物中に、０．０５〜１０質量％、好ましくは、細菌に対する除菌力、洗浄効果および貯蔵安定性の観点から、０．５〜２質量％の範囲に設定することが好ましい。０．０５質量％未満では、ウイルスに対する不活化力に欠けるばかりでなく、洗浄力の乏しいものとなる。また、１０質量％を超えて配合した場合には、他の配合成分とのバランスから貯蔵安定性に欠け、沈殿、析出または分離するなどして好ましくない。 The component (B1) (b1) organic acid and its alkali metal salt, and / or (b2) inorganic acid and its alkali metal salt are contained in an amount of 0.05 to 10% by mass in the toilet seat sanitizing detergent composition. Preferably, it is preferably set in the range of 0.5 to 2% by mass from the viewpoints of sterilizing power against bacteria, cleaning effect and storage stability. If it is less than 0.05% by mass, not only the inactivation ability against viruses is lacking, but also the washing ability is poor. Moreover, when it mix | blends exceeding 10 mass%, it lacks in storage stability from the balance with another compounding component, and is unpreferable because it precipitates, precipitates, or isolate | separates.
本発明に用いられる（Ｃ）成分としては、モノグリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ショ糖脂肪酸エステルから選ばれる少なくとも一種の非イオン界面活性剤が挙げられる。詳しくは、モノグリセリンカプリル酸モノエステル，モノグリセリンカプリル酸ジエステル，モノグリセリンカプリン酸モノエステル，モノグリセリンカプリン酸ジエステル，モノグリセリンラウリン酸モノエステル，モノグリセリンラウリン酸ジエステル，モノグリセリンミリスチン酸モノエステル，モノグリセリンミリスチン酸ジエステル等のモノグリセリン脂肪酸エステル、ジグリセリンカプリル酸モノエステル，ジグリセリンカプリル酸ジエステル，ジグリセリンカプリン酸モノエステル，ジグリセリンカプリン酸ジエステル，ジグリセリンラウリン酸モノエステル，ジグリセリンラウリン酸ジエステル，ジグリセリンミリスチン酸モノエステル，ジグリセリンミリスチン酸ジエステル，トリグリセリンカプリル酸モノエステル，トリグリセリンカプリル酸ジエステル，トリグリセリンカプリン酸モノエステル，トリグリセリンカプリン酸ジエステル，トリグリセリンラウリン酸モノエステル，トリグリセリンラウリン酸ジエステル，ペンタグリセリンカプリル酸モノエステル，ペンタグリセリンカプリル酸ジエステル，ペンタグリセリンカプリン酸モノエステル，ペンタグリセリンカプリン酸ジエステル，ペンタグリセリンラウリン酸モノエステル，ペンタグリセリンラウリン酸ジエステル，ペンタグリセリンミリスチン酸モノエステル，ペンタグリセリンミリスチン酸ジエステル等のポリグリセリン脂肪酸エステル、ソルビタンカプリル酸モノエステル，ソルビタンカプリル酸ジエステル，ソルビタンカプロン酸モノエステル，ソルビタンカプロン酸ジエステル，ソルビタンカプリン酸モノエステル，ソルビタンカプリン酸ジエステル，ソルビタンラウリン酸モノエステル，ソルビタンラウリン酸ジエステル，ソルビタンミリスチン酸モノエステル，ソルビタンミリスチン酸ジエステル等のソルビタン脂肪酸エステル、ポリエチレングリコール（１０Ｅｏ）モノラウリン酸エステル，ポリエチレングリコール（１０〜５５Ｅｏ）モノステアリン酸エステル等のポリエチレングリコール脂肪酸エステル、ショ糖ラウリン酸エステル等のショ糖脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステルが挙げられる。これらは単独で用いても、または２種以上を組み合わせて用いてもよい。なかでも、モノグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステルおよびポリオキシエチレン脂肪酸エステルが好ましく、特に殺菌・消毒効果の点からは、モノグリセリンカプリン酸エステル，モノグリセリンラウリン酸エステル等のモノグリセリン脂肪酸エステルが好ましい。 Component (C) used in the present invention includes at least one nonionic surfactant selected from monoglycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, and sucrose fatty acid ester. It is done. Specifically, monoglycerol caprylic acid monoester, monoglycerol caprylic acid diester, monoglycerol capric acid monoester, monoglycerol capric acid diester, monoglycerol lauric acid monoester, monoglycerol lauric acid diester, monoglycerol myristic acid monoester, mono Monoglycerol fatty acid esters such as glycerol myristic acid diester, diglycerol caprylic acid monoester, diglycerol caprylic acid diester, diglycerol capric acid monoester, diglycerol capric acid diester, diglycerol lauric acid monoester, diglycerol lauric acid diester, Diglyceryl myristic acid monoester, Diglyceryl myristic acid diester, Triglycerin caprylic acid monoester, G Glycerin caprylic acid diester, triglycerin capric acid monoester, triglycerine capric acid diester, triglycerin lauric acid monoester, triglycerin lauric acid diester, pentaglycerin caprylic acid monoester, pentaglycerin caprylic acid diester, pentaglycerin capric acid monoester , Pentaglycerin capric acid diester, pentaglycerin lauric acid monoester, pentaglycerin lauric acid diester, pentaglyceryl myristic acid monoester, pentaglyceryl myristic acid diester, glycerin fatty acid ester, sorbitan caprylic acid monoester, sorbitan caprylic acid diester, Sorbitan caproic acid monoester, sorbitan caproic acid diester, sol Tancapric acid monoester, sorbitan capric acid diester, sorbitan lauric acid monoester, sorbitan lauric acid diester, sorbitan myristic acid monoester, sorbitan fatty acid ester such as sorbitan myristic acid diester, polyethylene glycol (10Eo) monolauric acid ester, polyethylene glycol ( 10-55Eo) Polyethylene glycol fatty acid ester such as monostearic acid ester, sucrose fatty acid ester such as sucrose lauric acid ester, and polyoxyethylene sorbitan fatty acid ester. These may be used alone or in combination of two or more. Of these, monoglycerin fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester and polyoxyethylene fatty acid ester are preferable, and monoglycerin capric acid ester and monoglycerin lauric acid are particularly preferable in terms of bactericidal and disinfecting effects. Monoglycerol fatty acid esters such as esters are preferred.
上記（Ｃ）成分の非イオン界面活性剤は、便座用除菌洗浄剤組成物中に、０．０５〜５質量％、好ましくは、洗浄力の観点から、０．１〜３質量％の範囲に設定することが好ましく、なかでも、洗浄力、他の配合成分とのバランスによる被除菌洗浄物へのヌルつきの観点から、０．１〜１質量％の範囲とすることが特に好ましい。０．０５質量％未満では、洗浄力に欠け、５質量％を超えて配合した場合には、被除菌洗浄物にヌルつき、べたつきが生じて好ましくない。 The nonionic surfactant as the component (C) is in the range of 0.05 to 5% by mass, preferably 0.1 to 3% by mass from the viewpoint of detergency, in the sanitary detergent composition for toilet seats. It is preferable to set to 0.1 to 1 mass% especially from a viewpoint of the detergency washing | cleaning thing by the balance with a detergency and another compounding component, and a null attached to it. If it is less than 0.05% by mass, the detergency is lacking, and if it exceeds 5% by mass, the sterilized washed product becomes null and sticky, which is not preferable.
本発明の便座用除菌洗浄剤組成物に用いられる（Ｄ）成分の水としては、水道水、軟水、イオン交換水、純水、精製水等があげられるが、組成物の貯蔵安定性の点から、軟水、イオン交換水、純水、精製水等の使用が好ましい。 Examples of the water of component (D) used in the toilet seat sanitizing detergent composition of the present invention include tap water, soft water, ion-exchanged water, pure water, purified water, and the like. From the viewpoint, use of soft water, ion exchange water, pure water, purified water or the like is preferable.
上記（Ｄ）成分の水は、本発明の便座用除菌洗浄剤組成物中において、他の配合成分との総和が１００質量％になるのに必要な量として残質量％配合される。 In the disinfectant cleaning composition for toilet seats of the present invention, the water of component (D) is blended in the remaining mass% as an amount necessary for the total amount with other blending components to be 100 mass%.
また、本発明の便座用除菌洗浄剤組成物においては、必要に応じて他の添加剤、例えば、皮膚刺激緩和剤、水溶性溶剤、染料、香料、防腐剤、金属腐食抑制剤、ホップ抽出物，ポリリジン等の殺菌剤、他の界面活性剤を本発明の効果を損わない範囲で、適宜、配合することができる。なお、皮膚刺激緩和剤としては、保湿効果のある抽出液等が挙げられ、例えば、アロエ抽出液、ヘチマ抽出液、シソ抽出液、セージ抽出液、グリセリン、ソルビトール等が挙げられる。 Further, in the toilet seat disinfectant cleaning composition of the present invention, other additives as necessary, for example, skin irritation relieving agents, water-soluble solvents, dyes, fragrances, preservatives, metal corrosion inhibitors, hop extraction An antibacterial agent such as polylysine and other surfactants and other surfactants can be appropriately blended within a range not impairing the effects of the present invention. Examples of the skin irritation mitigating agent include an extract having a moisturizing effect, and examples include aloe extract, loofah extract, perilla extract, sage extract, glycerin, sorbitol and the like.
本発明の便座用除菌洗浄剤組成物の製造は、各成分が液体である場合には混合攪拌する方法によりおこなうことができる。このとき、固形成分を含む場合には水等に溶解後、他の液体成分を添加し混合攪拌することといった一般的手法を取ることができる。なお、各成分の添加順序、溶解順序、必要に応じて行われる加温／冷却等の製造手順については、特段の制限を受けるものではない。 Manufacture of the toilet seat sanitizing detergent composition of this invention can be performed by the method of mixing and stirring, when each component is a liquid. At this time, when a solid component is contained, a general method of adding another liquid component and mixing and stirring after dissolving in water or the like can be taken. In addition, about the addition procedure of each component, a melt | dissolution order, and manufacturing procedures, such as heating / cooling performed as needed, do not receive a special restriction | limiting.
そして、本発明の便座用除菌洗浄剤組成物の原液のｐＨ(ＪＩＳＺ−８８０２：１９８４「ｐＨ測定方法」) は、２５℃で、８〜１２の範囲であることが好ましく、特に、作業時における取り扱い性、すすぎ性等の点から、８〜１１の範囲であることが好ましい。 And the pH (JISZ-8802: 1984 “pH measurement method”) of the stock solution of the disinfectant cleaning composition for toilet seat according to the present invention is preferably in the range of 8 to 12 at 25 ° C. It is preferable that it is the range of 8-11 from points, such as the handleability in a and rinsing property.
また、本発明の便座用除菌洗浄剤組成物が食品添加物のみで構成されるとき、特に、皮膚が直接触れるトイレの便座等において、水拭き等による拭き取り（すすぎ作業）を行うことなく用いることができるため、組成物の安全性や毒性はもとより、簡便な作業性を提供できるため特に好ましい。 In addition, when the sanitary detergent composition for toilet seats of the present invention is composed of only food additives, it is used without performing wiping (rinsing work) by wiping with water or the like, particularly in a toilet seat or the like that is in direct contact with the skin. Therefore, it is particularly preferable because it can provide easy workability as well as safety and toxicity of the composition.
本発明の便座用除菌洗浄剤組成物を用い、ウイルスや細菌の付着した被除菌洗浄物を除菌洗浄することができる。このとき、除菌洗浄方法は以下の方法により行うことができる。 Using the sanitary detergent composition for toilet seats of the present invention, it is possible to disinfect and wash the sterilized washed product to which viruses and bacteria adhere. At this time, the sterilization washing method can be performed by the following method.
（１）本発明の便座用除菌洗浄剤組成物は不織布に含浸させて除菌洗浄材とすることができ、これを殺菌消毒を行う被殺菌消毒物に対してふき取り作業を行うことにより、除菌洗浄することができる。被除菌洗浄物としては、例えば、トイレの便座、便器、ドアノブ等の硬表面を有するもの等があげられる。また、本発明の除菌洗浄材は、除菌洗浄のためのウエットティッシュ等としても使用可能である。 (1) The disinfectant cleaning composition for toilet seats of the present invention can be impregnated into a non-woven fabric to be a disinfecting cleaning material, and by performing a wiping operation on a disinfectant to be sterilized, It can be sterilized and washed. Examples of the sterilized washed product include those having a hard surface such as a toilet seat, toilet, and door knob. The disinfecting cleaning material of the present invention can also be used as a wet tissue for disinfecting cleaning.
また、本発明の除菌洗浄材を構成する不織布の原材料としては、木綿のようなセルロース系材料、羊毛または絹のようなタンパク質系材料、レーヨン、ポリエステル、アクリル等の化学重合系材料等があげられる。なかでも、セルロース系材料、化学重合系材料が好ましい。 Examples of the raw material of the nonwoven fabric constituting the disinfectant cleaning material of the present invention include cellulose-based materials such as cotton, protein-based materials such as wool or silk, chemical polymerization-based materials such as rayon, polyester, and acrylic. It is done. Of these, cellulosic materials and chemical polymerization materials are preferred.
（２）本発明の便座用除菌洗浄剤組成物は、上記のほか、適宜の方法により使用することができ、例えばスプレー等により被殺菌物の表面に噴霧し、所定時間後、概ね１〜５分間程度放置し、適宜、水ですすいだ後に、乾燥させる。
具体的には、本発明の便座用除菌洗浄剤組成物の原液を内填した専用のディスペンサーを、トイレの便房、洗面化粧台等に配置されて使用される。そして、使用時毎に、約６〜１２ｍｌ／ｍ２の割合でトイレの便座、便器、ドアノブ等に直接噴霧し、放置乾燥あるいはトイレットペーパー等で、適宜、拭き取ることによりトイレの便座、便器、ドアノブ等の硬表面に対して、除菌洗浄を行うことができる。
また、便座用除菌洗浄剤組成物をスプレーしたトイレットペーパーにより、トイレの便座を拭き取ることで除菌洗浄をおこなうこともできる。
(2) The toilet seat sanitizing detergent composition of the present invention can be used by an appropriate method in addition to the above, for example, sprayed on the surface of an object to be sterilized by, for example, spraying, Let stand for about 5 minutes, rinse with water as appropriate, then dry.
Specifically, a dedicated dispenser in which the stock solution of the toilet seat disinfectant cleaning composition of the present invention is placed and used in a toilet bowl, a bathroom vanity, or the like is used. Each time it is used, it is sprayed directly on the toilet seat, toilet bowl, door knob, etc. at a rate of about 6-12 ml / m 2 and left to dry or toilet paper, etc., to wipe off the toilet seat, toilet bowl, door knob. It is possible to perform sterilization washing on hard surfaces such as.
Further, sterilization and cleaning can be performed by wiping the toilet seat with a toilet paper sprayed with a toilet sanitizing detergent composition.
そして、本発明の便座用除菌洗浄剤組成物は、プラスチック容器、ポンプ付き容器、パウチ、チューブ等に充填されて提供される。また、１回毎に使用される相当量で、個包装し、携帯性をもたせて提供することもできる。 The toilet seat sanitizing detergent composition of the present invention is provided by being filled in a plastic container, a container with a pump, a pouch, a tube, or the like. Moreover, it can also be individually packaged and provided with portability in a considerable amount used each time.
つぎに、本発明の実施例および比較例を説明するが、本発明は、これらの実施例に限定されるものではない。 Next, examples and comparative examples of the present invention will be described, but the present invention is not limited to these examples.
後記の表１〜表８に示す組成により、実施例１〜１８および比較例１〜１８の便座用除菌洗浄剤組成物（以下、供試薬剤ともいう。）を調製した。そして、得られた各種供試薬剤毎について、ウイルスに対する不活化力、細菌に対する除菌力、ｐＨ、貯蔵安定性、洗浄力、材質への影響性の試験項目について、以下の試験方法と判定基準により評価し、その結果を後記の表１〜表８に併せて示した。 Using the compositions shown in Tables 1 to 8 below, disinfectant cleaning compositions for toilet seats (hereinafter also referred to as reagent reagents) of Examples 1 to 18 and Comparative Examples 1 to 18 were prepared. And, for each of the various reagent reagents obtained, the following test methods and criteria for the test items of inactivation ability against viruses, sterilization ability against bacteria, pH, storage stability, detergency, and influence on materials The results are shown in Tables 1 to 8 below.
（１）ウイルスに対する不活化力
〔試験方法〕
各種供試薬剤の原液２７０μＬとネコカリシウイルスＦ９株（ＦＣＶ）３０μＬを６０秒間接触させた後、α−Ｍｉｎｉｍｕｍ Ｅｓｓｅｎｔｉａｌ Ｍｅｄｉｕｍ（α−ＭＥＭ）（和光純薬社製）で１０倍に希釈し、更に段階的に１０倍希釈を行った。あらかじめ９６穴マイクロプレートに培養しておいた猫腎臓細胞（ＣＲＦＫ）に、５０μＬのα−ＭＥＭを加え、そこに先に段階希釈した液を加える。３７℃、５％ＣＯ２存在下で４日間培養し、細胞変性有無を確認した。
供試薬剤の代わりに超純水を用いたものをブランクとし、これらの差から各種供試薬剤によるＦＣＶのＬｏｇＲｅｄｕｃｔｉｏｎを算出し、以下の判定基準で評価した。
〔判定基準〕
◎：ＬｏｇＲｅｄｕｃｔｉｏｎが４以上
○：ＬｏｇＲｅｄｕｃｔｉｏｎが３以上、４未満
×：ＬｏｇＲｅｄｕｃｔｉｏｎが３未満
なお、◎と○を実用性のあるものと判断した。
(1) Inactivation ability against viruses [Test method]
After contacting 270 μL of various reagent stock solutions and 30 μL of feline calicivirus F9 strain (FCV) for 60 seconds, it was diluted 10-fold with α-Minimum Essential Medium (α-MEM) (manufactured by Wako Pure Chemical Industries, Ltd.), and A 10-fold dilution was performed stepwise. To cat kidney cells (CRFK) previously cultured in a 96-well microplate, 50 μL of α-MEM is added, and the previously diluted solution is added thereto. The cells were cultured for 4 days at 37 ° C. in the presence of 5% CO 2 to confirm the presence or absence of cell degeneration.
A blank using ultrapure water instead of the reagent was used, and from these differences, the FCV Log Reduction for each reagent was calculated and evaluated according to the following criteria.
[Criteria]
：: Log Reduction is 4 or more ○: Log Reduction is 3 or more and less than 4 ×: Log Reduction is less than 3 Note that ◎ and ○ are judged to be practical.
（２）細菌に対する除菌力
〔試験方法〕
Ａｓｓｏｃｉａｔｉｏｎ ｏｆ Ｏｆｆｉｃｉａｌ Ａｇｒｉｃｕｌｔｕｒａｌ Ｃｈｅｍｉｓｔｓ（ＡＯＡＣ）のサニタイザー試験法に準じて行なった。詳しくは、各種供試薬剤の原液９．９ｍｌに、Ｎｕｔｒｉｅｎｔ Ｂｒｏｔｈ（ＮＢ）培地（ＭＥＲＣＫ社製）に１０８〜１０９個の菌数になるよう調整した菌液を０．１ｍｌ加える。３０秒接触させた後、その１ｍｌを不活化剤入りリン酸緩衝液９ｍｌに加え、その後すぐに段階希釈を行う。Ｐｌａｔｅ Ｃｏｕｎｔ Ａｇａｒ（ＰＣＡ）培地（ＭＥＲＣＫ社製）で混釈し、３７℃で４８時間培養後に生存菌数を測定した。接種菌数と生存菌数の対数差からＬｏｇＲｅｄｕｃｔｉｏｎを算出し、以下の判定基準で評価した。
なお、供試菌としては、大腸菌（Ｅｓｃｈｅｒｉｃｈｉａ ｃｏｌｉ ＩＦＯ−１２７３４）と黄色ブドウ球菌（Ｓｔａｐｈｙｌｏｃｏｃｕｓ ａｕｒｅｕｓ ＩＦＯ−１２７３２）を用いた。
〔判定基準〕
○：ＬｏｇＲｅｄｕｃｔｉｏｎが５以上
×：ＬｏｇＲｅｄｕｃｔｉｏｎが５未満
(2) Bactericidal power against bacteria [test method]
It was performed according to the sanitizer test method of Association of Official Agricultural Chemists (AOAC). Specifically, 0.1 ml of a bacterial solution adjusted to 10 8 to 10 9 bacteria in Nutrient Broth (NB) medium (manufactured by MERCK) is added to 9.9 ml of stock solutions of various reagent reagents. After contact for 30 seconds, 1 ml of the solution is added to 9 ml of a phosphate buffer containing an inactivating agent, and then serial dilution is performed immediately thereafter. The cells were mixed with a plate count agar (PCA) medium (manufactured by MERCK) and cultured at 37 ° C. for 48 hours, and then the number of viable bacteria was measured. Log Reduction was calculated from the logarithmic difference between the number of inoculated bacteria and the number of living bacteria, and evaluated according to the following criteria.
As test bacteria, Escherichia coli IFO-12734 and Staphylococcus aureus IFO-12732 were used.
[Criteria]
○: Log Reduction is 5 or more ×: Log Reduction is less than 5
（３）ｐＨ
ｐＨメーター（型式：ｐＨ ＭＥＴＥＲ Ｆ−１２、堀場製作所社製）を用いて、ＪＩＳ Ｚ−８８０２：１９８４「ｐＨ測定方法」にしたがって、各種供試薬剤の原液のｐＨを測定し、以下の判定基準で評価した。
〔判定基準〕
○：ｐＨが８以上、１２以下
×：ｐＨが８未満或いは１２を超える
(3) pH
Using a pH meter (model: pH METER F-12, manufactured by HORIBA, Ltd.), the pH of the stock solutions of various reagent reagents was measured according to JIS Z-8802: 1984 “pH measurement method”, and the following criteria were determined: It was evaluated with.
[Criteria]
○: pH is 8 or more and 12 or less ×: pH is less than 8 or more than 12
（４）貯蔵安定性
〔試験方法〕
各種供試薬剤の原液８０ｍＬを、１００ｍＬ容量の透明プラスチック瓶に入れ、恒温槽（形式：冷凍冷蔵庫ＨＲＦ、ホシザキ社製）により、５℃の雰囲気下に２週間保管後、その外観を目視により観察し、以下の判定基準で評価した。
〔判定基準〕
○：沈殿、析出、分離が生じない
×：沈殿、析出、分離のいずれかが多く生じる。
(4) Storage stability [Test method]
80 mL of stock solutions of various reagents are placed in a 100 mL transparent plastic bottle, stored in a constant temperature bath (model: freezer refrigerator HRF, manufactured by Hoshizaki) for 2 weeks in an atmosphere of 5 ° C., and the appearance is visually observed. Then, the following criteria were evaluated.
[Criteria]
○: Precipitation, precipitation and separation do not occur
X: A lot of precipitation, precipitation, or separation occurs.
（５）洗浄力
〔試験方法〕
ポリプロピレン製のプラスチック板（縦７．６ｃｍ×横２．６ｃｍ）に、Ｓｙｎｔｈｅｔｉｃ Ｓｅｂｕｍ１０ｇ、クロロホルム９０ｇを調整して作成した人工皮脂汚れ０．０５ｇを付着させ、室温にて１時間乾燥させたものを試験片とした。
この試験片の表面を、各種供試薬剤の原液を染み込ませたキムワイプ（登録商標）で拭き取ったときの汚れの除去度合いを、目視にて以下の判定基準で評価した。
〔判定基準〕
○：きれいに落ちた
△：僅かに汚れが残るが、ほぼ落ちた。
×：ほとんど汚れが落ちない
なお、○と△を実用性のあるものと評価した。
(5) Detergency [Test method]
A test was conducted by attaching 0.05 g of artificial sebum soil prepared by adjusting 10 g of Synthetic Sebum and 90 g of chloroform to a plastic plate made of polypropylene (length: 7.6 cm × width: 2.6 cm) and drying at room temperature for 1 hour. A piece.
The degree of stain removal when the surface of this test piece was wiped with Kimwipe (registered trademark) soaked with stock solutions of various reagent reagents was visually evaluated according to the following criteria.
[Criteria]
○: It fell clean. △: Slight dirt remained, but almost dropped.
X: Soil was hardly removed, and ○ and Δ were evaluated as practical.
（６）材質への影響性
〔試験方法〕
ＡＢＳ製樹脂板を、幅１ｃｍ×長さ１４ｃｍに切断したものを試験片とした。この試験片が弓なりになるように設置する。そして、試験片全体に対して、各種供試薬剤の原液を染み込ませたキムワイプ（登録商標）をのせ、５０℃のインキュベーターに１分間配置してから取りだすといった一連の操作を、各種供試薬剤の原液を染み込ませたキムワイプ（登録商標）を交換しながら２０回繰り返す。その後、水拭きし、３０分間の放置乾燥後に、試験片の状態を目視で観察して、以下の判定基準で評価した。
〔判定基準〕
○：ほとんど影響が見られない
△：ひび割れがわずかに表面に生じている
×：ひび割れが顕著に生じている
××：試験片が割れている
なお、○と△を実用性のあるものと評価した。
(6) Influence on material [Test method]
A specimen obtained by cutting an ABS resin plate into a width of 1 cm and a length of 14 cm was used as a test piece. The test piece is placed in a bow. Then, a series of operations such as placing Kimwipe (registered trademark) soaked with stock solutions of various reagent reagents on the entire test piece, placing them in a 50 ° C. incubator for 1 minute, and then removing them were performed. Repeat 20 times while changing Kimwipe (registered trademark) soaked with stock solution. Thereafter, the sample was wiped with water and allowed to dry for 30 minutes. The state of the test piece was visually observed and evaluated according to the following criteria.
[Criteria]
○: Almost no effect is observed Δ: Slight cracks are generated on the surface ×: Cracks are remarkably generated XX: The test piece is cracked Note that ○ and Δ are evaluated as practical did.
後記の表１〜表８に示す便座用除菌洗浄剤組成物における各成分の配合量は、有り姿で示した。また、各成分の有効成分量（質量％。以下、％と略す）について以下の通り示した。 The compounding amount of each component in the toilet seat sanitizing detergent composition shown in Tables 1 to 8 below is shown as it is. Moreover, it showed as follows about the amount of active ingredients (mass%. Hereinafter, it abbreviates as%) of each component.
〔（Ａ）成分〕
・エチルアルコール
製品名：「特定アルコール９５度１級発酵」、日本アルコール販売株式会社製、有効成分量９５％
・イソプロピルアルコール
製品名：「イソプロピルアルコール」、関東化学社製（試薬１級）、有効成分量９５％
[Component (A)]
-Ethyl alcohol Product name: "Specific alcohol 95 degree 1st grade fermentation", manufactured by Nippon Alcohol Sales Co., Ltd., active ingredient amount 95%
・ Isopropyl alcohol Product name: “Isopropyl alcohol”, manufactured by Kanto Chemical Co., Ltd. (reagent grade 1), active ingredient content 95%
〔（Ｂ）成分のうちの（ｂ１）成分〕
・クエン酸
製品名：「クエン酸（結晶）」、磐田化学社製、有効成分量１００％
・クエン酸三ナトリウム
製品名：「クエン酸三ナトリウム」、磐田化学社製、有効成分量１００％
・クエン酸三カリウム
製品名：「クエン酸三カリウム」、磐田化学社製、有効成分量１００％
・リンゴ酸ナトリウム
製品名：「リンゴ酸ソルト １２０」、扶桑化学工業社製、有効成分量８０％
・乳酸ナトリウム
製品名：「乳酸ナトリウム ６０％」、扶桑化学工業社製、有効成分量６０％
・グルコン酸ナトリウム
製品名：「ヘクシャスＡ」、扶桑化学工業社製、有効成分量１００％
・酒石酸ナトリウム
製品名：「Ｌ−酒石酸ナトリウム」、扶桑化学工業社製、有効成分量１００％
・エチレンジアミン四酢酸四ナトリウム（比較例用）
製品名：「ＴｒｉｌｏｎＢ ｐｏｗｄｅｒ」、ＢＡＳＦ社製、有効成分量１００％
[Component (b1) of Component (B)]
・ Citric acid Product name: “Citric acid (crystal)”, manufactured by Iwata Chemical Co., Ltd., 100% active ingredient
・ Trisodium citrate Product name: “Trisodium citrate”, manufactured by Iwata Chemical Co., Ltd., 100% active ingredient
・ Tripotassium citrate Product name: “Tripotassium citrate”, manufactured by Iwata Chemical Co., Ltd., 100% active ingredient
-Sodium malate Product name: “Malic acid salt 120”, manufactured by Fuso Chemical Industry Co., Ltd., active ingredient amount 80%
-Sodium lactate Product name: “Sodium lactate 60%”, manufactured by Fuso Chemical Industry Co., Ltd., active ingredient amount 60%
・ Sodium gluconate Product name: “Hexcious A”, manufactured by Fuso Chemical Industries, 100% active ingredient
・ Sodium tartrate Product name: “L-sodium tartrate”, manufactured by Fuso Chemical Industry Co., Ltd., 100% active ingredient
・ Ethylenediaminetetraacetic acid tetrasodium (for comparative example)
Product name: “TrilonB powder”, manufactured by BASF, 100% active ingredient
〔（Ｂ）成分のうちの（ｂ２）成分〕
・重炭酸ナトリウム
製品名：「重曹（食品添加物）」、株式会社トクヤマ社製、有効成分量１００％
・炭酸ナトリウム
製品名：「ソーダ灰（デンス）」、株式会社トクヤマ社製、有効成分量１００％
・メタ珪酸ナトリウム（比較例用）
製品名：「メタ珪酸ナトリウム・９水塩」、ＡＤＥＫＡ社製、有効成分量１００％
[Component (b2) of component (B)]
・ Sodium bicarbonate Product name: “Baking soda (food additive)”, manufactured by Tokuyama Corporation, 100% active ingredient
・ Sodium carbonate Product name: “Soda ash (Dense)”, manufactured by Tokuyama Corporation, 100% active ingredient
・ Sodium metasilicate (for comparative example)
Product name: “Sodium metasilicate 9 hydrate”, manufactured by ADEKA, 100% active ingredient
〔（Ｃ）成分〕
・モノグリセリン脂肪酸エステル
製品名：「サンソフト Ｎｏ７００Ｐ２」、太陽化学社製、有効成分量１００％
・ポリグリセリン脂肪酸エステル
製品名：「サンソフト Ｍ−１２Ｊ」、太陽化学社製、有効成分量１００％
・ソルビタン脂肪酸エステル
製品名：「サンソフト Ｎｏ．８１Ｓ」、太陽化学社製、有効成分量１００％
・ポリオキシエチレンソルビタン脂肪酸エステル
製品名：「レオドール ＴＷ−Ｌ１２０」、花王社製、有効成分量１００％
・ショ糖脂肪酸エステル
製品名：「リョートーシュガーエステル Ｏ−１５７０」、三菱化学フーズ社製、有効成分１００％
[Component (C)]
・ Monoglycerin fatty acid ester Product name: “Sunsoft No700P2”, manufactured by Taiyo Chemical Co., Ltd., 100% active ingredient
・ Polyglycerin fatty acid ester Product name: “Sunsoft M-12J”, manufactured by Taiyo Chemical Co., Ltd., 100% active ingredient
・ Sorbitan fatty acid ester Product name: “Sunsoft No. 81S”, Taiyo Kagaku Co., Ltd., 100% active ingredient
・ Polyoxyethylene sorbitan fatty acid ester Product name: “Leodol TW-L120”, manufactured by Kao Corporation, 100% active ingredient
-Sucrose fatty acid ester Product name: “Ryoto Sugar Ester O-1570”, manufactured by Mitsubishi Chemical Foods, Inc., 100% active ingredient
〔任意成分〕
・ポリリジン
ε−ポリリジン
製品名：「ポリリジン ２５％水溶液」、チッソ社製、有効成分量２５％
・ＳＴＰＰ
：トリポリリン酸ナトリウム
製品名：「ワンデットＢ」、日本化学社製、有効成分量１００％
・ポリオキシエチレンアルキルエーテル
：炭素数１２〜１５高級アルコールのエチレンオキサイド９モル付加物
製品名：「サンノニック ＳＳ９０」、三洋化成工業社製、有効成分量１００％
[Optional ingredients]
・ Polylysine ε-Polylysine Product name: “Polylysine 25% aqueous solution”, manufactured by Chisso Corporation, active ingredient amount 25%
・ STPP
: Sodium tripolyphosphate Product name: “One Det B”, manufactured by Nippon Chemical Co., Ltd., 100% active ingredient
・ Polyoxyethylene alkyl ether: 9 mol adduct of higher alcohols with 12-15 carbon atoms Product name: “Sannonic SS90”, manufactured by Sanyo Chemical Industries, 100% active ingredient
〔その他の成分〕
・水酸化ナトリウム
製品名：「トーソーパールカセイソーダ（食品添加物）」、東ソー株式会社製、有効成分量９９％
・ＤＤＡＣ
ジデシルジメチルアンモニウムクロライド
製品名：「Ａｒｑｕａｒｄ ２１０−８０Ｅ」、ライオンアクゾ社製、有効成分量８０％
[Other ingredients]
・ Sodium hydroxide Product name: “Tosoh Pearl caustic soda (food additive)” manufactured by Tosoh Corporation, 99% active ingredient
・ DDAC
Didecyldimethylammonium chloride Product name: “Arquard 210-80E”, manufactured by Lion Akzo, 80% active ingredient
上記実施例１〜１８から、各種便座用除菌洗浄剤組成物において、ウイルスに対する不活化力、細菌に対する殺菌力、ｐＨ、貯蔵安定性、洗浄力、材質への影響性のすべての試験項目において良好な結果が得られていることがわかる。 From the above Examples 1 to 18, in various toilet seat sterilization detergent compositions, in all test items of inactivation power against viruses, bactericidal power against bacteria, pH, storage stability, cleaning power, influence on materials It can be seen that good results are obtained.
Claims (8)
（Ａ）低級アルコール３５〜７５質量％
（Ｂ）（ｂ１）有機酸およびそのアルカリ金属塩、および／または（ｂ２）無機酸およびそのアルカリ金属塩０．０５〜１０質量％
（Ｃ）モノグリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ショ糖脂肪酸エステルから選ばれる少なくとも一種の非イオン界面活性剤０．０５〜５質量％。 The following components (A) to (C) are contained in the following ratio with respect to the entire composition, water is contained as the component (D), and the pH of the composition stock solution (JIS Z-8802: 1984 “ The sterilization detergent composition for toilet seats characterized in that the pH measurement method ") is set in the range of 8 to 12 at 25 ° C.
(A) 35-75 mass% of lower alcohol
(B) (b1) Organic acid and alkali metal salt thereof, and / or (b2) Inorganic acid and alkali metal salt thereof 0.05 to 10% by mass
(C) 0.05-5 mass% of at least one nonionic surfactant selected from monoglycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, and sucrose fatty acid ester.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008013785A JP2009173768A (en) | 2008-01-24 | 2008-01-24 | Sterilizing detergent composition for toilet seat, sterilizing cleaning material containing the same, and sterilizing cleaning method using them |
| PCT/JP2009/000280 WO2009093476A1 (en) | 2008-01-24 | 2009-01-26 | Antibacterial cleaner composition for toilet seat, antibacterial cleaning material comprising the same, and antibacterial cleaning method using the composition or the material |
| CN200980106196XA CN101952407B (en) | 2008-01-24 | 2009-01-26 | Antibacterial cleaner composition for toilet seat, antibacterial cleaning material comprising the same, and application thereof |
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| JP2008013785A JP2009173768A (en) | 2008-01-24 | 2008-01-24 | Sterilizing detergent composition for toilet seat, sterilizing cleaning material containing the same, and sterilizing cleaning method using them |
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| JP2009173768A true JP2009173768A (en) | 2009-08-06 |
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|---|---|
| JP (1) | JP2009173768A (en) |
| CN (1) | CN101952407B (en) |
| WO (1) | WO2009093476A1 (en) |
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| JP2011236204A (en) * | 2010-04-12 | 2011-11-24 | Kao Corp | Bactericidal composition |
| WO2012035751A1 (en) * | 2010-09-14 | 2012-03-22 | 日油株式会社 | Antibacterial cleaning composition |
| JP2014019659A (en) * | 2012-07-13 | 2014-02-03 | Niitaka:Kk | Disinfection liquid and disinfection method |
| WO2020066570A1 (en) * | 2018-09-28 | 2020-04-02 | 富士フイルム株式会社 | Composition, spray, wiper |
| JP2021191747A (en) * | 2020-06-02 | 2021-12-16 | 日本化薬株式会社 | Pest control composition |
| JP2022008087A (en) * | 2013-05-02 | 2022-01-13 | ネクスト サイエンス アイピー ホールディングス ピーティワイ エルティーディ | Liquid cleaning composition |
| JP2022091699A (en) * | 2020-12-09 | 2022-06-21 | ミヨシ油脂株式会社 | Paper treatment agent, paper using the same, and method for promoting inactivation of virus using the same |
| JP2022182504A (en) * | 2021-05-28 | 2022-12-08 | エステー株式会社 | Cleaning composition and cleaning aerosol product |
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|---|---|---|---|---|
| JP2010248452A (en) * | 2009-04-20 | 2010-11-04 | Soft99 Corporation | Detergent composition and cleaning tool |
| CN102010804B (en) * | 2010-12-08 | 2011-11-09 | 胡志焕 | Method for producing washing products with towel gourd as raw material |
| JP5964170B2 (en) * | 2012-08-03 | 2016-08-03 | 花王株式会社 | Ethanol preparation |
| CN106854581A (en) * | 2017-01-05 | 2017-06-16 | 长沙协浩吉生物工程有限公司 | A kind of compound method of biological toilet bowl cleaning agent |
| CN107099398A (en) * | 2017-04-22 | 2017-08-29 | 河南工业大学 | A kind of permanently-effective toilet-cleaning spray |
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| JPH09202900A (en) * | 1996-01-26 | 1997-08-05 | Lion Corp | Liquid detergent composition |
| JP2003183105A (en) * | 2001-12-20 | 2003-07-03 | Ueno Seiyaku Oyo Kenkyusho:Kk | Fungicide composition |
| JP2006206558A (en) * | 2005-01-25 | 2006-08-10 | Arutan Kk | Antimicrobial composition for preventing food poisoning |
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- 2009-01-26 WO PCT/JP2009/000280 patent/WO2009093476A1/en not_active Ceased
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| JPH09202900A (en) * | 1996-01-26 | 1997-08-05 | Lion Corp | Liquid detergent composition |
| JP2003183105A (en) * | 2001-12-20 | 2003-07-03 | Ueno Seiyaku Oyo Kenkyusho:Kk | Fungicide composition |
| JP2006206558A (en) * | 2005-01-25 | 2006-08-10 | Arutan Kk | Antimicrobial composition for preventing food poisoning |
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| JP2011236204A (en) * | 2010-04-12 | 2011-11-24 | Kao Corp | Bactericidal composition |
| WO2012035751A1 (en) * | 2010-09-14 | 2012-03-22 | 日油株式会社 | Antibacterial cleaning composition |
| JP2013018952A (en) * | 2010-09-14 | 2013-01-31 | Nof Corp | Sterilizing detergent composition |
| CN103119144A (en) * | 2010-09-14 | 2013-05-22 | 日油株式会社 | A kind of antibacterial detergent composition |
| CN103119144B (en) * | 2010-09-14 | 2014-08-27 | 日油株式会社 | A kind of antibacterial detergent composition |
| US9288977B2 (en) | 2010-09-14 | 2016-03-22 | Nof Corporation | Disinfectant detergent composition |
| JP2014019659A (en) * | 2012-07-13 | 2014-02-03 | Niitaka:Kk | Disinfection liquid and disinfection method |
| JP7286707B2 (en) | 2013-05-02 | 2023-06-05 | ネクスト サイエンス アイピー ホールディングス ピーティワイ エルティーディ | liquid cleaning composition |
| JP2022008087A (en) * | 2013-05-02 | 2022-01-13 | ネクスト サイエンス アイピー ホールディングス ピーティワイ エルティーディ | Liquid cleaning composition |
| JP2023111924A (en) * | 2013-05-02 | 2023-08-10 | ネクスト サイエンス アイピー ホールディングス ピーティワイ エルティーディ | liquid cleaning composition |
| JP7650318B2 (en) | 2013-05-02 | 2025-03-24 | ネクスト サイエンス アイピー ホールディングス ピーティワイ エルティーディ | Liquid cleaning composition |
| WO2020066570A1 (en) * | 2018-09-28 | 2020-04-02 | 富士フイルム株式会社 | Composition, spray, wiper |
| JP2021191747A (en) * | 2020-06-02 | 2021-12-16 | 日本化薬株式会社 | Pest control composition |
| JP7684093B2 (en) | 2020-06-02 | 2025-05-27 | 日本化薬株式会社 | Pest control compositions |
| JP2025107490A (en) * | 2020-06-02 | 2025-07-17 | 日本化薬株式会社 | Pest control compositions |
| JP2022091699A (en) * | 2020-12-09 | 2022-06-21 | ミヨシ油脂株式会社 | Paper treatment agent, paper using the same, and method for promoting inactivation of virus using the same |
| JP7805760B2 (en) | 2020-12-09 | 2026-01-26 | ミヨシ油脂株式会社 | Paper treatment agent and method for promoting paper and virus inactivation using the same |
| JP2022182504A (en) * | 2021-05-28 | 2022-12-08 | エステー株式会社 | Cleaning composition and cleaning aerosol product |
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Also Published As
| Publication number | Publication date |
|---|---|
| CN101952407A (en) | 2011-01-19 |
| WO2009093476A1 (en) | 2009-07-30 |
| CN101952407B (en) | 2012-10-10 |
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