JP2001199850A - Hair dressing cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a hair dressing cosmetic excellent in setting ability, giving the hair favorable touch and gloss such as wiriness and nonstickiness with their effects sustainable for a long period of time, and excellent in the ability to dress the hair again. SOLUTION: This hair dressing cosmetic comprises (A) at least one-kind of extract or squeezed product from a plant belonging Compositae family, (B) at least one kind of extract or squeezed product from a plant belonging to Gentianaceae family, Araceae or Rutaceae, (C) at least one kind of extract or squeezed product from a plant belonging to Equisetaceae, Malvaceae, Saxifragaceae, Tiliaceae or Caryophyllaceae, and (D) at least one kind of a film-forming polymer, and also, as appropriate, at least one kind of ingredient selected from the group consisting of siloxane compounds, peptide derivatives, and royal jelly and extract therefrom.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair styling cosmetic, and more particularly to a hair styling cosmetic, which is excellent in setting power, has a good feeling such as suppleness and non-stickiness and gloss, and its effect lasts for a long time. The present invention relates to a hair styling cosmetic having excellent hair styling properties.

[0002]

2. Description of the Related Art Conventionally, various film-forming polymers have been used in hair styling cosmetics for the purpose of setting hair. However, hair styling cosmetics using these film-forming polymers alone may feel sticky when dried,
There are drawbacks such as a feeling of stiffness after drying and flaking to cause peeling and a decrease in luster. In order to improve these drawbacks, attempts have been made to combine a plasticizer or an oil agent with a film-forming polymer.However, in many cases, an adverse effect such as a feeling of oiliness or a decrease in setting force is caused. .

[0003] On the other hand, extracts of various plants are incorporated into hairdressing cosmetics for the purpose of protecting and moisturizing hair. Also,
Attempts have been made to reduce the sticky feeling and the stiffness by using these plant extracts and the above-mentioned film-forming polymer in combination, but there are drawbacks such as poor re-shaping properties.

[0004]

In the above circumstances, there has been a demand for a technique for solving the above-mentioned disadvantages. That is, an object of the present invention is to provide a hair styling cosmetic composition which is excellent in setting force, supple, has a good feeling such as non-stickiness and luster, maintains its effect for a long time, and has excellent re-styling properties. It is in.

[0005]

Means for Solving the Problems The present inventors have conducted intensive studies in order to achieve the object of the present invention. As a result, (A) one kind of an extract or a pressed product obtained from an Asteraceae plant or 2
At least one species; (B) one or more of extracts or pressed products obtained from plants belonging to the Gentianaceae, Araceae or Rutaceae; and (C) Euphorbiaceae, Malvaceae, Saxifragaceae, Lindenidae or It contains one or more kinds of extracts or squeezed products obtained from plants belonging to the family Coleoptera and one or more kinds of (D) film-forming polymers, and in some cases, further contains a siloxane compound or peptide Derivatives,
The present inventors have found that the above-mentioned drawbacks can be improved by a hair styling composition characterized by containing one or more selected from the group consisting of royal jelly or an extract thereof, and completed the present invention.

That is, claim 1 of the present invention relates to (A) one or two kinds of extracts or compressed products obtained from asteraceae plants.
At least one species; (B) one or more of extracts or pressed products obtained from plants belonging to the Gentianaceae, Araceae or Rutaceae; and (C) Euphorbiaceae, Malvaceae, Saxifragaceae, Lindenidae or A hairdressing cosmetic comprising: one or more extracts or compressed products obtained from a plant belonging to the family Polygonaceae; and (D) a film-forming polymer.

A second aspect of the present invention is the hairdressing cosmetic composition according to the first aspect, further comprising one or more members selected from the group consisting of a siloxane compound, a peptide derivative, royal jelly and an extract thereof. is there.

[0008]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The configuration of the present invention will be described below in detail.

The plant extracts or squeezed products listed as the component (A), the component (B) and the component (C) used in the present invention include leaves, roots, stems, flowers, skins, branches, fruits, It can be obtained by extracting or directly pressing from one or more sites such as the skin with an appropriate solvent, and may be performed by a combination of pressing and extraction.

Examples of the extraction solvent include alcohols such as ethanol, methanol, 1,3-butylene glycol, propylene glycol and glycerin; waters such as cold water and hot water;
One or more mixed liquids selected from oils such as squalane, sunflower oil, paraffin oil and ester oil, acetone, ethyl acetate and the like can be used. Among these, polar solvents such as water and alcohols can be used. One or a mixture of two or more selected from the following is desirable.

[0011] As another method, an extract obtained by fractionating the above-mentioned extract by means of adsorption chromatography such as silica gel chromatography can also be used. The solvent in the extract may be further dissolved in a suitable solvent after distillation, or a concentrate or dry powder of the extract may be dissolved in the extract.
It can also be used in the present invention.

These plant extracts or squeezed products are incorporated in the composition of the present invention in a total amount of 0.0001 to 5% by mass (hereinafter simply referred to as%) as an extract component (corresponding to a dry residue). And more preferably 0.001 to 1
%. If the amount is less than 0.0001%, the effect of the present invention may not be sufficiently exhibited even if it is blended, and if it exceeds 5%, it is not preferable in the production process of the final product. In order to obtain a good effect, the mixing ratio of these components in the extract is (A) / ((B) + (C)) = 1/100 to 100/1.
It is desirable that

The Asteraceae plants used in the present invention include Arnica, Artemisia, Artemisia, Artemisia,
Chamomile, Roman chamomile, burdock, Achillea millefolium, Calendula officinalis, coltsfoot, safflower, cornflower, lettuce, yarrow, sycamore, yabu tobacco, Fujibama, dandelion, takasaburo and the like.

Gentians include plants of the Gentian family.
Examples of plants of the family Araceae, such as assembly, purple clover, honeywort, and the like include shobu and mizubasho.

[0015] Plants of the Rutaceae family include yellowfin, orange, salamander, unshiu mandarin, daidai, yuzu,
Lemon, grapefruit and the like can be mentioned.

Examples of the plants belonging to the family Aesculaceae include horseshoe and horsetail, and examples of a plant belonging to the family Malvaceae include below-flowered mallow and Usbania mallow.

Examples of plants of the family Saxifragaceae include saxifraga, amaturea and hydrangea.

Examples of plants of the linden family include linden (Tinosa edulis, Aedes aegypti) and the like.

As the plants of the family Dipterocarpaceae, saponaria,
Chickweed and the like.

As the extract obtained from these plants, those which conform to or comply with the standard for cosmetic components (cosmetic regulation) are preferably used. As the component (A),
"Kawarai mugwort extract" (listed under Cosmetic Regulations; the same applies hereinafter),
"Gourd extract", "cornflower extract", and component (B) include "gentian extract", "purple extract", "shobu root extract", "salmon extract", "lemon extract", and component (C). Is
It is particularly preferable to be selected from the “sugar extract”, the “mallow mallow extract”, the “salt safflower extract”, the “linden extract”, and the “bonsai extract”.

The film-forming polymer used in the present invention is not particularly limited as long as it can adhere to hair to form a film, and is an anionic, cationic, amphoteric or nonionic synthetic polymer or a synthetic polymer thereof. , Natural polymers or derivatives thereof can be used.

Specific examples of the anionic polymer include a methyl vinyl ether / alkyl maleic anhydride half ester copolymer (trade name: Gantrez ES-225,
ES-425, SP-215 (manufactured by ISP), etc.), vinyl acetate / crotonic acid copolymer (trade name: Resin 28-1)
310 [National Starch], Rubiset CA
[BASF] etc.), vinyl acetate / crotonic acid / vinyl neodecanoate copolymer (trade name: Resin 28-293)
0 (manufactured by National Starch), vinyl acetate / crotonic acid / vinyl propionate copolymer (trade name: Rubiset CAP (manufactured by BASF), etc.), vinyl acetate / monobutyl ester maleate / isoboronyl acrylate Copolymer (trade name: ADVANTAGE CP [ISP
Co., Ltd.), (meth) acrylic acid / (meth) acrylate copolymer (trade name: Plus Size L53PB)
[Manufactured by Mutual Chemical Company], diamond hold [manufactured by Mitsubishi Chemical Corporation]
Rubimer 100P [manufactured by BASF] etc.), acrylic acid /
Acrylic acid alkyl ester / alkyl acrylamide copolymer (trade name: Ultrahold 8, Ultrahold Strong [manufactured by BASF], Amphomer V-
42 [National Starch] etc.), acrylic acid /
Acrylic acid hydroxyester copolymer (Acdine 258 [Rohm & Haas]), polyvinylpyrrolidone / acrylate / (meth) acrylic acid copolymer (trade name: Rubiflex VBM35 [BASF])
Carboxyvinyl polymer (Carbopol 98)
0, 981 [manufactured by BF GOODRICH]), cross-linked polyacrylic acid (PEMULENTR-1, TR-2)
[BF GOODRICH], etc.), acrylic acid / polyoxyethylene methacrylate (20) stearyl ether copolymer (Aculin 22 [Rohm & Haas]), silicone-modified acrylic polymer (trade name:
FZ-3148 [manufactured by Nippon Unicar], KP-545
[Shin-Etsu Chemical Co., Ltd.] etc.).

Specific examples of the cationic polymer include vinyl imidazolium trichloride / vinyl pyrrolidone copolymer (trade names: Rubicut FC370, FC55)
0, FC905, HM552, [manufactured by BASF], etc.),
Hydroxyethylcellulose / dimethyldiallylammonium chloride (trade names: Cellcoat H-100, L-
200 [manufactured by National Starch Co., Ltd.], and vinylpyrrolidone / quaternized dimethylaminoethyl methacrylate copolymer (trade names: Guffcut 734, 755N [ISP]
Co., Ltd.), polyvinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer (trade name:
Copolymer VC-713 (manufactured by ISP), vinylpyrrolidone / methacrylamidopropyl trimethylammonium chloride copolymer (trade name: Guffcut HS-100)
[Made by ISP] etc.), and an alkylacrylamide / acrylate / alkylaminoalkylacrylamide / polyethylene glycol methacrylate copolymer.

Specific examples of the amphoteric polymer include a monoalkylacetic acid amphoteric product of a dialkylaminoethyl methacrylate / alkyl methacrylate copolymer (trade name:
Yuka Former 301, AM-75, SM (manufactured by Mitsubishi Chemical Corporation), hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymer (trade names: Amphomer 28-4910, LV-7)
1 [manufactured by National Starch] and the like.

As a specific example of the nonionic polymer, polyvinylpyrrolidone (trade name: Rubiscol K-12,
17, 30, 60, 80, 90 [manufactured by BASF], PV
PK-15, 30, 60, 90 [manufactured by ISP], etc.), polyvinylpyrrolidone / vinyl acetate copolymer (trade names: Luviscol VA28E, 37E, 55E, 64E, 73)
E [manufactured by BASF], PVP / VA E-735, E-
635, E-535, E-335, S-630, W-7
35 [manufactured by ISP], etc.), polyvinylpyrrolidone / alkylaminoacrylate copolymer (trade name: Copolymer 845, 937, 958 [manufactured by ISP], etc.), vinyl acetate / N-vinyl-5-methyl-2-oxazoline Copolymer (trade name: Dowlex [Dow Chemical Co., Ltd.])
Etc.), water-dispersible polyester resin (trade name: Eastm)
an AQ 38S, 55S (manufactured by Eastman Chemical Products) and the like.

Specific examples of natural polymers and derivatives thereof include natural polysaccharides such as guar gum, locust bean gum, gum arabic, xanthan gum, pullulan and carrageenan; chitosan salts; chitin derivatives such as carboxymethyl chitin and hydroxypropyl chitosan; Carboxymethyl starch, starch-based polymer compounds such as methylhydroxypropyl starch, methylcellulose, nitrocellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate, hydroxypropylcellulose,
Cellulose-based polymer compounds such as sodium carboxymethylcellulose, crystalline cellulose, and cellulose powder; alginic acid-based polymer compounds such as sodium alginate and propylene glycol alginate;

Among these film-forming polymers, those having an ionic group may be those obtained by neutralizing a part or all of the ionic group and converting it into a salt. The above film-forming polymers may be used alone or
A mixture of more than one species can be used.

These film-forming polymers are preferably incorporated in the composition of the present invention in an amount of 0.05 to 15%.
More desirably, 0.1 to 10% is blended. 0.05
%, It is difficult to obtain a sufficient set retention property.
If the content exceeds 5%, a stiff feeling may be caused.

The siloxane compound used in the present invention is
For example, dimethylpolysiloxane, methylphenylpolysiloxane, amino-modified silicone, fatty acid-modified silicone, alcohol-modified silicone, aliphatic alcohol-modified silicone, polyether-modified silicone, epoxy-modified silicone, fluorine-containing modified silicone, cyclic silicone, alkyl-modified silicone, A betaine group-containing modified silicone (a siloxane compound or the like obtained according to the method described in JP-A-3-130294) or a co-modified silicone thereof is exemplified. In order to impart an excellent conditioning effect, among these siloxane compounds, nonvolatile ones, especially dimethylpolysiloxane, methylphenylpolysiloxane, polyether-modified silicone, amino-modified silicone, alkyl-modified silicone, fluorine-containing modified silicone and Alkoxy-modified silicones and the like are desirable, and among them, perfluoropolyoxyalkylene-modified silicones or kinematic viscosities at 25 ° C. of 1,000 mm ² / s to 10,000,000 mm ² /
More preferably, the dimethylpolysiloxane is s.

These siloxane compounds can be used alone or in admixture of two or more. In order to provide a sufficient conditioning effect within a range that does not impair the usability, the siloxane compound should be present in the composition of the present invention in an amount of from 0.01 to 0.01%. It is desirable to be blended by 25%.

The peptide derivatives used in the present invention include natural peptides, synthetic peptides, and protein hydrolysates obtained by partially hydrolyzing proteins (proteins) with acids, alkalis or enzymes. Derivatives such as cationized, acylated, alkylesterified, and silylated peptides can also be used. Examples of the natural peptide include glutathione, bacitracin A, insulin, glucagon, oxytocin, vasopressin, and the like, and examples of the synthetic peptide include polyglycine, polylysine, polyglutamic acid, and polyserine.

Examples of the protein serving as the protein source of the protein hydrolyzate include animal-derived proteins such as collagen, gelatin, keratin, silk fibroin, sericin, casein, conchiolin, elastin, egg yolk proteins of chickens and the like, and egg white proteins. Stuff, soy, almonds, wheat,
Beer lees, corn, rice, plant-derived proteins such as potatoes, and yeasts of the genera Saccharomyces, Candita, Endomycopsis, yeast proteins isolated from brewer's yeast, sake yeast, mushrooms (Basidiomycetes)
And proteins derived from microorganisms such as proteins isolated from Chlorella.

In order for these peptide derivatives to provide a sufficient conditioning effect as long as the usability is not impaired, collagen, keratin, conchiolin, silk fibroin, wheat, and wheat obtained from animals or plants are particularly desirable among these peptide derivatives. Protein, protein hydrolyzate such as soybean protein or cationized product thereof, acylated product,
Derivatives such as alkyl esterified products and silylated products are desirable, and the molecular weight is not particularly limited, but the average molecular weight is preferably from 50 to 50,000, more preferably from 200 to 10,000. The preferable amount of these peptide derivatives is 0.0001 to 10%, more preferably 0.001 to 5% in terms of dry matter in the hair styling cosmetic composition of the present invention. If it is less than 0.0001%,
Even if it is blended, the effect of the present invention may not be exhibited.
If it exceeds 0%, a stiff feeling may occur after drying, which is not preferable.

The royal jelly used in the present invention is a secretion of European honey bee or European honeybee, and an extract of royal jelly can be obtained by extracting royal jelly with a suitable solvent. As extraction solvents, ethanol, methanol, 1,
1 selected from alcohols such as 3-butylene glycol, propylene glycol, glycerin, etc., cold water, hot water, etc.
Species or a mixture of two or more can be used. As these royal jellies or extracts thereof, those listed in “Cosmetic Regulations” as “royal jelly”, “royal jelly extract”, and “oil-soluble royal jelly extract” or those similar thereto are preferably used. The preferred blending amount of these royal jelly or its extract is 0.00001 to 5%, more preferably 0.0001 to 1% in terms of dry matter in the hair styling cosmetic composition of the present invention. 0.0000
If the amount is less than 1%, the effect of the present invention may not be exhibited even when blended, and if it exceeds 5%, a sticky feeling may occur after drying, which is not preferable.

The hair styling cosmetic composition of the present invention may use, in addition to the above-mentioned essential ingredients, if necessary, any components commonly used in hair styling cosmetic compositions as long as the effects of the present invention are not impaired. These components include anionic surfactants, cationic surfactants, nonionic surfactants, amphoteric surfactants, oils, ultraviolet absorbers, preservatives, moisturizers, extracts from other animals and plants, fragrances, water , Alcohol, thickeners,
Propellants, coloring agents, sequestering agents, antioxidants, chemicals and the like.

The hair styling cosmetic composition of the present invention broadly refers to a hair styling cosmetic composition, for example, hair styling such as hair lotion, hair liquid, hair milk, hair cream, hair foam, hair spray, hair gel and the like. In addition to those, the hair styling cosmetics of the present invention include shampoo,
When used as a hair rinse, hair treatment, perm agent, hair dye, and the like, the intended effects of the present invention can be obtained.

[0037]

Next, the present invention will be described in detail with reference to examples, but the present invention is not limited thereto.

Prior to the Examples, each Example and Comparative Examples 1 to
The test method and evaluation method adopted in Section 8 will be described.

In Examples 13 to 22, the following were used as plant extracts. Japanese pearl mud extract: “Inchinko extract BG” (manufactured by Maruzen Pharmaceutical) Burdock extract: “burdock extract BG” (manufactured by Maruzen Pharmaceutical) Cornflower extract: “cornflower extract BG” (manufactured by Maruzen Pharmaceutical) Product: "Kamizore extract BG" (manufactured by Maruzen Pharmaceutical Co., Ltd.) Gentian extract: "Gentian extract BG" (manufactured by Maruzen Pharmaceutical Co., Ltd.) Extract) Shobu root extract: "Shobu extract" (Maruzen Pharmaceutical) Sansho extract: "Sansha extract BG" (Maruzen Pharmaceutical) Lemon fruit extract: "Lemon extract BG" (Maruzen) Pharmaceutical company) Horsetail extract: “Brownia extract BG” (manufactured by Maruzen Pharmaceutical Co., Ltd.) Usvenia oil extract: “Usvenia oil extract BG”
(Maruzen Pharmaceutical Co., Ltd.) Saxifraga extract: "Sakinoshita extract BG" (Maruzen Pharmaceutical Co., Ltd.) Shinoki extract: "Shinoki extract BG" (Maruzen Pharmaceutical Co., Ltd.) Sabonso extract: "Sabonso extract BG" (Maruzen Grape extract: “Red grape extract BG” (manufactured by Maruzen Pharmaceutical Co., Ltd.) Panax ginseng extract: “carrot extract BG” (manufactured by Maruzen Pharmaceutical) Mulberry extract: “Sohakuhi extract BG” (Maruzen Pharmaceutical) Apple fruit extract: "Apple extract BG-J" (Maruzen Pharmaceutical) Aloe extract: "Aloe vera extract-JC" (Maruzen Pharmaceutical) Chanoki extract: "Oolong tea extract BG" (Maruzen) Pharmaceutical company) Licorice extract: "Glycine extract BG" (Maruzen Pharmaceutical Co., Ltd.)
J "(Maruzen Pharmaceutical Co., Ltd.) Luffa extract:" Luffa extract BG "(Maruzen Pharmaceutical Co., Ltd.) Hop extract:" Hop extract BG "(Maruzen Pharmaceutical Co., Ltd.) Horse chestnut extract:" Maloney extract BG " -J "
(Maruzen Pharmaceutical)

(1) Set force test method 0.5 g of a hairdressing cosmetic sample was evenly applied to a hair bundle having a length of 15 cm and a weight of 1 g, and wound on a rod having a diameter of 2 cm.
It was left in a high-temperature room at 45 ° C. for 6 hours and completely dried. After drying, the rod was removed and the apparent length (L) of the hair bundle was measured. Next, the hair bundle was suspended in a thermo-hygrostat at a temperature of 25 ° C. and a humidity of 90%, taken out 30 minutes later, and the apparent length (L ₀ ) of the hair bundle was measured again.

The set force was determined by the following equation. Set force (%) = (15−L ₀ ) ÷ (15−L) × 10
0 (The closer this value is to 100, the higher the setting force.)

The evaluation criteria are as follows. ◎: Very good setting force 80% or more ○: Good Setting force 50% or more and less than 80% △: Somewhat bad Setting force 30% or more and less than 50% ×: Poor setting force less than 30%

(2) Sensory Test Hairdressing was performed on 20 subjects using a hairdressing cosmetic sample. Thereafter, the subject himself performed a sensory evaluation on flexibility (no stiffness) and non-stickiness. The evaluation criteria are as follows.

Suppleness ：: Very good The number of subjects who answered that there is no stiffness is 18 or more ：: Good The number of subjects who answered that there is no stiffness is 12 or more and less than 18 △: Slightly bad There is no stiffness 8 or more and less than 12 ×: Poor Less than 8 subjects who answered no stiffness

No stickiness A: Very good The number of subjects who answered that they were not sticky was 1
8 or more ○: Good The number of subjects who answered that it was not sticky was 1
2 or more and less than 18 △: Slightly bad The number of subjects who answered that they were not sticky was 8
More than 12 and less than 12 ×: Bad Number of subjects who answered that they were not sticky was 8
Less than people

(3) Gloss Test Method A hair styling cosmetic sample of 0.5 g is evenly applied to a hair bundle having a length of 15 cm and a weight of 1 g, and air-dried. After drying, five hairs were arbitrarily selected, and the reflectance of light was determined using a goniophotometer (manufactured by Murakami Color Research Laboratory Co., Ltd.). And compared. The evaluation criteria are as follows.

：: very good light reflectance of 150 compared to blank
% Or more ：: good 100% light reflectance compared to blank
% Or more and less than 150% △: Slightly bad 80% light reflectance compared to blank
Above, less than 100% ×: Poor 80% light reflectance compared to blank
Less than

(4) Hair redressing property A hairdressing cosmetic sample was used for 20 subjects to perform hairdressing. After 3 hours, the hair was passed through a comb again to perform hair styling, and the hair styling properties were evaluated. The evaluation criteria are as follows.

A: Very good The number of subjects who answered that the hair was easy to fix was 1
8 or more ○: Good The number of subjects who answered that hair was easy to fix was 1
2 or more and less than 18 △: Slightly poor The number of subjects who answered that hair was easy to fix was 8
No less than 12 people ×: bad 8 subjects answered that hair was easy
Less than people

Examples 1 to 12 and Comparative Examples 1 to 8

[0051]

[Table 1]

(1) Monochloroacetic acid amphoteric product of dialkylaminoethyl methacrylate / alkyl methacrylate copolymer (30% pure content) (trade name: Yuka Former 301 [manufactured by Mitsubishi Chemical Corporation]) (2) Dimethylpolysiloxane Viscosity 100000m
m ² / s; 25 ° C.) (50% pure) (trade name:
Silicon BY22-029 [manufactured by Dow Corning Toray Silicone Co., Ltd.]) (3) Trade name: Promois WK [manufactured by Seiwa Kasei Co., Ltd.] (4) Trade name: royal jelly extract [manufactured by Maruzen Pharmaceutical Co., Ltd.]

[0053]

[Table 2]

(1) Monochloroacetic acid amphoteric product of dialkylaminoethyl methacrylate / alkyl methacrylate copolymer (30% pure) (trade name: Yuka Former 301 (manufactured by Mitsubishi Chemical Corporation)) (2) Dimethyl polysiloxane Viscosity 100000m
m ² / s; 25 ° C.) (50% pure) (trade name:
Silicon BY22-029 [manufactured by Dow Corning Toray Silicone Co., Ltd.]) (3) Trade name: Promois WK [manufactured by Seiwa Kasei Co., Ltd.] (4) Trade name: royal jelly extract [manufactured by Maruzen Pharmaceutical Co., Ltd.]

A hair styling cosmetic composition (hair lotion) having the composition shown in Tables 1 and 2 was prepared by a conventional method, and evaluated for setting power, suppleness, non-stickiness, luster, and re-styling properties. As shown in Table 1, the hair styling cosmetics of Examples 1 to 12 using the essential components of the present invention all showed excellent performance. Further, as shown in Table 2, the hair styling cosmetics of Comparative Examples 1 to 8, which lacked any of the essential components, were inferior in set power, suppleness, non-stickiness, luster, and re-styling properties.

Example 13 Hair Cream (%) Beeswax 3.0 Vaseline 5.0 Stearyl Alcohol 5.0 Liquid Paraffin 30.0 Squalane 10.0 POE (60) Cetyl Ether 2.5 Vinylpyrrolidone / Vinyl Acetate Copolymer (Trade name: PVP / VA S-630 [manufactured by ISP]) 0.5 Burdock extract 0.02 Purple extract 0.02 Salamander extract 0.02 Horsetail extract 0.02 Lindwood extract 0.0 1 dimethylpolysiloxane ^{(10mm 2 / s; 25 ℃} ) 2.0 dimethylpolysiloxane ^{(500000mm 2 / s; 25 ℃} ) 1.0 EDTA-2Na 0.1 preservative Appropriate amount perfume Appropriate amount purified water Balance

A hair cream having the above composition is prepared by a conventional method, and the setting power, flexibility, non-stickiness, gloss,
When evaluated for hair re-shaping properties, all properties were excellent, and good results were obtained.

Example 14 Hair set lotion (%) Polyvinyl pyrrolidone (trade name: PVP K-60 [manufactured by ISP]) 1.0 Vinyl pyrrolidone / quaternized dimethylamino ethyl methacrylate copolymer (trade name: Guffcut 755N) [Manufactured by ISP]) 2.0 POE (60) hydrogenated castor oil 1.0 dipropylene glycol 3.0 burdock extract 1.0 sunshaw extract 1.0 saxifrage extract 0.5 wheat hydrolyzate (product Name: GLUADIN W40 [manufactured by Henkel]) 1.0 Ethanol 30.0 Perfume Appropriate amount Purified water residue

A hair set lotion having the above composition was prepared by a conventional method and evaluated for setting power, suppleness, non-stickiness, luster, and re-styling properties. All the properties were excellent and good results were obtained. Was.

Example 15 Hair Foam (Undiluted Solution) (%) Monoarylacetic acid amphoteric product of stearyltrimethylammonium chloride 0.5 dialkylaminoethyl methacrylate / alkyl methacrylate copolymer (trade name: Yuka Former SM [manufactured by Mitsubishi Chemical Corporation] ) 10.0 Liquid paraffin 1.0 Polyether-modified silicone (trade name: SILWET L-7001 [manufactured by Nippon Unicar Co., Ltd.]) 2.0 Kawamurai extract 0.2 Knapweed extract 0.2 Purple mushroom extract 0.2 Lemon fruit extract 0.2 Usniaia oil extract 0.2 Lindwood extract 0.2 Soap extract 0.2 Ethanol 10.0 POE (80) hydrogenated castor oil 1.0 Perfume Appropriate amount Purified water residue (propellant) Liquefied petroleum gas 5.0

A hair foam having the above composition is prepared by a conventional method, and the setting power, suppleness, non-stickiness, gloss,
When evaluated for hair re-shaping properties, all properties were excellent, and good results were obtained.

Example 16 Hair Liquid (%) Polyoxypropylene (60) butyl ether 20.0 Ethanol 50.0 Hydroxypropyl acrylate / butyl methacrylate aminoethyl / octylamide acrylate copolymer (trade name: Amphomer 28- 4910 [manufactured by National Starch Co., Ltd.]) 2.0 Aminomethylpropanol 0.35 Kawamurai extract 0.01 Burdock extract 0.0 Cornflower extract 0.2 gentian extract 0.01 purple maize extract 0.2 scab root extract 0.1 salmon extract 0.1 lemon fruit extract 0.1 horsetail extract 0.1 .1 Saxifrage extract 0.01 Lindwood extract 0.02 Soap extract 0.5 Perfluoroalkylpolyoxyalkylene-modified silicone (substance obtained in Reaction Example 1 described in JP-A-8-12536) 2.0 POE ( 80) Hardened castor oil 1.0 Appropriate amount of fragrance Purified water residue

A hair liquid having the above composition was prepared by a conventional method, and the setting power, suppleness, non-stickiness, gloss,
When evaluated for hair re-shaping properties, all properties were excellent, and good results were obtained.

Example 17 Hair gel (%) Polyoxyethylene (20) acrylic acid / methacrylic acid stearyl ether copolymer (trade name: Aculin 22 [manufactured by Rohm & Haas]) 5.0 aminomethylpropanol 2.0 acrylic acid Alkyl ester copolymer (trade name: Rubimer 100P [manufactured by BASF]) 1.0 Monoalkyl acetic acid amphoteric product of dialkylaminoethyl methacrylate / methacrylic acid alkyl ester copolymer (trade name: Yuka Former 301 [manufactured by Mitsubishi Chemical Corporation]) 3.0 Artemisia extract 0.01 Burdock extract 0.1 Cornflower extract 0.2 Gentian extract 0.01 Purple mackerel extract 0.2 Shobu root extract 0.1 Sansho extract 0.1 Lemon fruit Extract 0.1 Horsetail extract 0.1 Usvenia oil extract 0.1 Saxifraga extract 0.01 Hydrolyzed silk liquid (trade name: Crosil 10000 [manufactured by Croda]) 0.1 methylphenylpolysiloxane (trade name: KF-56 [manufactured by Shin-Etsu Chemical Co., Ltd.]) 1.0 Silicone powder (trade name: Trefil E505C [manufactured by Dow Corning Toray Silicone Co., Ltd.]) 0.5 Ethanol 20.0 Purified water balance

A hair gel having the above composition was prepared by a conventional method and evaluated for setting power, suppleness, non-stickiness, luster, and re-shaping property. All the properties were excellent and good results were obtained. .

Example 18 Hair milk (%) Crosslinked polyacrylic acid (trade name: PEMULEN TR-1 [manufactured by BF GOODRICH]) 0.3 Carboxyvinyl polymer (trade name: Carbopol 981 [manufactured by BF GOODRICH]] ) 0.1 diisopropanolamine 0.35 glycerin 5.0 cornflower extract 0.1 chamomile extract 0.1 salmon extract 0.1 horsetail extract 0.1 liquid paraffin 2.0 isononyl isononanoate 1.0 Silicone-modified acrylic polymer (trade name: FZ-3148 [manufactured by Nippon Unicar]) 1.0 EDTA-2Na 0.05 Purified water balance

A hair milk having the above composition was prepared by a conventional method and evaluated for setting power, suppleness, non-stickiness, luster, and re-shaping property. All the properties were excellent, and good results were obtained. .

Example 19 Hair Spray (Undiluted Solution) (%) Ethanol 20.0 Acrylic Acid / Acrylic Acid Hydroxyester Copolymer (trade name: Accudine 258 [Rohm & Haas]) 2.0 Aminomethylpropanol 0.5 Extract 0.1 burdock extract 0.05 cornflower extract 0.0 gentian extract 0.1 purple extract 0.1 scab root extract 0.05 salamander extract 0.1 lemon fruit extract 0. 2 Horsetail extract 0.05 Usbena oyster extract 0.5 Saxifraga extract 0.1 Polyether-modified silicone (trade name: SS2804 [manufactured by Nippon Unicar]) 0.5 Purified water 45.6 (propellant) dimethyl ether 30. 0

A hair spray having the above composition was prepared by a conventional method, and the setting power, suppleness, non-stickiness, gloss,
When evaluated for hair re-shaping properties, all properties were excellent, and good results were obtained.

Example 20 Styling Shampoo (%) POE (3) Sodium Lauryl Ether Sulfate 4.0 Lauroyl-N-methyl-β-alanine Sodium 2.0 Coconut Oil Fatty Acid Acylglutamate Triethanolamine 2.0 Palm Kernel Oil Fatty Acid Amidopropyl betaine 6.0 N-Lauroyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine 5.0 Lauric acid diethanolamide 2.0 Lauric acid isopropanolamide 1.0 Ethylene glycol distearate 2.0 Polyoxy Ethylene (7) coconut oil fatty acid glycerin 1.0 Red sagebrush extract 0.02 Burdock extract 0.02 Knapweed extract 0.02 Gentian extract 0.02 Purple mackerel extract 0.02 Shobu root extract 0 02 Salmon extract 0.02 Lemon fruit extract 0.02 Japanese horse chestnut extract 0.02 Usvenia oyster extract 0.02 Saxifrage extract 0.02 Shinanoki extract 0.02 Saponosa extract 0.02 Grape extract 0.0 1 Panax ginseng extract 0.01 Mulberry extract 0.01 Apple fruit extract 0.2 Aloe extract 1.0 Tea tree extract 0.5 Licorice extract 0.05 Horseshoe extract 0.001 Loofah extract 0.0 1 Hop extract 0.1 Horse chestnut extract 0.1 Seaweed extract (trade name: Kaisou extract [manufactured by Maruzen Pharmaceutical Co., Ltd.]) 0.5 Polyvinylpyrrolidone (trade name: Rubiscol K-90 [manufactured by BASF] ) 1.0 Vinylpyrrolidone / quaternized dimethylaminoethyl methacrylate copolymer (trade name: Guffcut 755N) [Made by ISP]) 3.0 Silicone emulsion (trade name: BY22-029 [manufactured by Dow Corning Toray Silicone Co., Ltd.]) 2.0 silylated peptide derivative (trade name: Promois W-52SIG [made by Seiwa Chemical Co., Ltd.]] 0.1) Cationized cellulose derivative (trade name: Polymer JR-400 [manufactured by UCC]) 0.3 1,3-butylene glycol 2.0 hydrolyzed conchiolin solution (trade name: pearl protein extract [Maruzen Pharmaceutical Co., Ltd.] 0.2) Hydrolyzed silk liquid (trade name: Promois Silk-1000 [manufactured by Seiwa Kasei Co., Ltd.]) 0.1 L-serine 0.01 D-panthenol 0.1 Trehalose undecylenate 0.1 Preservative qs perfume qs Purified water residue

A styling shampoo having the above composition was prepared by a conventional method, and the hair was washed. When the easiness of cohesion (setting force), suppleness, non-stickiness, gloss, and re-shaping property of the washed hair were evaluated by sensory evaluation, all properties were excellent, and good results were obtained.

Example 21 Hair rinse (%) Cetyltrimethylammonium chloride 1.5 Arginine derivative (trade name: Amisafe LMA-60 [manufactured by Ajinomoto Co.]) 3.0 Cetanol 2.5 Squalane 2.0 POE (5) Stearyl Ether 1.0 1,3-butylene glycol 5.0 Amino-modified silicone (trade name: FZ-3710 [manufactured by Nippon Unicar Co., Ltd.]) 1.0 Dimethylpolysiloxane (100 mm ² / s; 25 ° C.) 1.0 Polyvinylpyrrolidone (Product name: Rubiscol K-60 [manufactured by BASF]) 0.5 Perfluoroalkylpolyoxyalkylene-modified silicone (substance obtained in Reaction Example 1 described in JP-A-8-12536) 2.0 Burdock extract 0 .1 Shoubu root extract 0.05 Saxifraga extract 0.05 Kiolin liquid (trade name: Pearl protein extract [Maruzen Pharmaceutical Co., Ltd.]) 1.0 Hydrolyzed silk liquid (trade name: Promois Silk-1000 [Seiwa Kasei Co., Ltd.]) 1.0 Preservatives Appropriate amount Fragrance Appropriate amount Purified water balance

A hair rinse having the above composition was prepared by a conventional method, applied to the hair, and immediately rinsed with warm water. When the hair was easily rinsed after rinsing (setting power), supple, non-sticky, shiny, and hair re-formability were evaluated organoleptically, all properties were excellent, and good results were obtained.

Example 22 Hair Treatment (%) Stearyltrimethylammonium Chloride 2.5 Distearyldimethylammonium Chloride 1.5 Cetanol 5.0 Liquid Paraffin 2.0 Octyldodecanol 2.0 Methylphenylpolysiloxane 1.0 Dimethylpoly Siloxane (500,000 mm ² / s; 25 ° C.) 1.0 POE (60) hydrogenated castor oil 0.5 Vinyl imidazolium trichloride / vinyl pyrrolidone copolymer (trade name: Rubicut FC905 [manufactured by BASF]) 1.0 Extract 0.1 cornflower extract 0.1 gentian extract 0.1 purple mackerel extract 0.1 salmon extract 0.1 lemon fruit extract 0.1 russian oyster extract 0.1 yukinoshita extract 0.1 Linden extract 0.1 Soap extract 0.1 Propylene glycol 5.0 Preservative qs perfume qs Purified water residue

A hair treatment of the above composition was prepared by a conventional method, applied to the hair, and rinsed with warm water three minutes later. Ease of hair after rinsing (set power), suppleness,
Sensory evaluation of non-stickiness, gloss, and re-styling properties showed that all properties were excellent and good results were obtained.

[0076]

As described above, according to the present invention, a hair styling cosmetic composition which is excellent in setting power, has a good feeling such as suppleness and non-stickiness and gloss, maintains its effects for a long time, and is excellent in hair redressing properties. Can be provided.

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Claims (2)

[Claims] 1. An extract or a compressed product obtained from a plant of the Asteraceae family (A), and (B) a gentian family,
One or more extracts or compressed products obtained from plants belonging to the family Araceae or Rutaceae; and (C) Rhododaceae,
One or two of extracts or squeezed products obtained from plants belonging to the family Malvaceae, Saxifragaceae, Lindenidae, or Papilionidae
A hairdressing cosmetic comprising: at least one kind; and (D) one or more kinds of film-forming polymers. 2. The hairdressing cosmetic according to claim 1, further comprising one or more selected from the group consisting of a siloxane compound, a peptide derivative, royal jelly or an extract thereof.