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JP2001064866A - Salt shrinking method - Google Patents

Salt shrinking method

Info

Publication number
JP2001064866A
JP2001064866A JP23372599A JP23372599A JP2001064866A JP 2001064866 A JP2001064866 A JP 2001064866A JP 23372599 A JP23372599 A JP 23372599A JP 23372599 A JP23372599 A JP 23372599A JP 2001064866 A JP2001064866 A JP 2001064866A
Authority
JP
Japan
Prior art keywords
salt
solution
silk
yarn
silk thread
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP23372599A
Other languages
Japanese (ja)
Other versions
JP3274109B2 (en
Inventor
Makoto Utada
誠 歌田
Makoto Watanabe
渡辺  誠
Kazuhiro Watanabe
和裕 渡辺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yamanashi Prefecture
Original Assignee
Yamanashi Prefecture
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yamanashi Prefecture filed Critical Yamanashi Prefecture
Priority to JP23372599A priority Critical patent/JP3274109B2/en
Publication of JP2001064866A publication Critical patent/JP2001064866A/en
Application granted granted Critical
Publication of JP3274109B2 publication Critical patent/JP3274109B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Treatment Of Fiber Materials (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a salt shrinkage treatment that can shrink silk yarn uniformly. SOLUTION: Silk yarn is brought into contact with a salt shrinkage solution in the form of thread to carry out the salt shrinkage treatment. In a preferred embodiment, the salt shrinkage solution is a calcium nitrate solution with a specific gravity of 1.45-1.50 and the silk yarn is brought into contact with the shrinkage solution at 50-70 deg.C for >=30 minutes.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、塩縮加工方法に関
する。
TECHNICAL FIELD The present invention relates to a salt shrinking method.

【0002】[0002]

【従来の技術】従来から、絹織物などの絹を織り込んだ
布を、硝酸カルシウム、塩化カルシウム、塩化亜鉛など
の中性塩の濃厚溶液中に浸し、所定の処理条件(所定の
溶液濃度、所定の溶液温度、所定の浸漬時間)のもとで
保持し絹使用部分を収縮させる、いわゆる塩縮加工が知
られており、かかる従来方法においては、一般的には比
重が約1.45に調整された硝酸カルシウム溶液の中に
布を入れ85〜95℃の温度で、0.5〜2分漬け込
み、収縮させていた。
2. Description of the Related Art Conventionally, a cloth woven with silk, such as silk fabric, is immersed in a concentrated solution of a neutral salt such as calcium nitrate, calcium chloride, zinc chloride, and the like, under predetermined processing conditions (a predetermined solution concentration, a predetermined solution concentration, a predetermined concentration). (A solution temperature, a predetermined immersion time), and shrinking a portion using silk is known. In such a conventional method, the specific gravity is generally adjusted to about 1.45. The cloth was put in the prepared calcium nitrate solution, soaked at 85 to 95 ° C. for 0.5 to 2 minutes, and shrunk.

【0003】[0003]

【発明が解決しようとする課題】しかし、かかる従来方
法においては、織物となった状態で塩縮加工を施すた
め、収縮の際に、絹糸が相互に若しくは他の糸によって
様々な方向に拘束されることによって不規則な張力を受
けるようになり、そのため、特に収縮量を均一化するの
は困難である。
However, in such a conventional method, since the fabric is subjected to salt-shrinking processing, the silk yarns are restrained mutually or in various directions by shrinkage during shrinkage. As a result, irregular tension is applied, and therefore, it is particularly difficult to equalize the amount of shrinkage.

【0004】また、そのため従来方法は、皺模様等の変
化に富んだ風合いを織物に与える場合には好適である
が、そのような風合いを与えない場合、例えば単に絹糸
の収縮による嵩高化またはソフト化を図りたい場合には
不向きである。
[0004] For this reason, the conventional method is suitable for imparting a texture rich in changes such as wrinkles to a woven fabric. It is unsuitable when it is desired to make the conversion.

【0005】したがって、本発明の主たる課題は、絹糸
の収縮を制御できるようにすることにある。
Accordingly, a main object of the present invention is to make it possible to control shrinkage of a silk thread.

【0006】[0006]

【課題を解決するための手段】上記課題を解決した本発
明は、絹糸を、織物とされていない糸の状態で塩縮溶液
と接触させ、塩縮処理することを特徴とする塩縮加工方
法である。絹糸は、織物とされていない糸の状態で処理
されるので、絹糸に不規則な張力を与えずに済むため、
収縮の制御を容易に行うことができる。
According to the present invention, there is provided a salt-shrinking method comprising the steps of: bringing a silk thread into contact with a salt-condensed solution in a state of a non-woven yarn to perform a salt-shrinking treatment. It is. Since silk yarn is processed in the state of yarn that is not woven, it is not necessary to apply irregular tension to silk yarn,
Control of shrinkage can be easily performed.

【0007】他方、本発明者らは、織物とされていない
糸の状態での絹糸の塩縮加工を、布の状態での塩縮加工
と同様な方法で行うと、再現性が乏しいなど、実施化を
図る上では困難であることを知見しており、この点につ
いて鋭意研究を重ねた結果、硝酸カルシウム溶液の比重
を高くし、溶液温度を低くし、また浸漬時間を長くする
ことにより、再現性が高くなることが判明した。
On the other hand, the inventors of the present invention have found that if salt shrinking of silk yarn in the state of a non-woven yarn is performed in the same manner as salt shrinking in the state of cloth, reproducibility is poor. We know that it is difficult to implement it, and as a result of intensive research on this point, by increasing the specific gravity of the calcium nitrate solution, lowering the solution temperature, and lengthening the immersion time, It was found that the reproducibility was high.

【0008】したがって、本発明をより好適に実施する
上では、前記塩縮溶液は比重が1.45〜1.50の硝
酸カルシウム溶液であり、且つ前記絹糸を50〜70℃
の前記塩縮溶液と30分以上接触させることを推奨す
る。かかる条件下では、後述の実施例に示すように糸の
状態での塩縮加工を良好に行うことが可能となる。
Therefore, in order to more preferably carry out the present invention, the salted solution is a calcium nitrate solution having a specific gravity of 1.45 to 1.50, and the silk thread is heated to 50 to 70 ° C.
It is recommended to contact with the above-mentioned salted solution for 30 minutes or more. Under such conditions, salt shrinking in the state of a yarn can be favorably performed as shown in Examples described later.

【0009】[0009]

【発明の実施の形態】前述のとおり本発明においては、
絹糸を、糸の状態で塩縮溶液と接触させ、所定の溶液温
度条件および浸漬条件のもとで塩縮処理を行う。
DESCRIPTION OF THE PREFERRED EMBODIMENTS As described above, in the present invention,
The silk thread is brought into contact with a salt-condensed solution in the state of a thread, and salt-condensed under a predetermined solution temperature condition and immersion condition.

【0010】使用する塩縮溶液としては特に限定されな
いが、硝酸カルシウム溶液が入手し易く、且つ再現性も
十分高いものとできるので好ましい。
The salt-condensed solution to be used is not particularly limited, but a calcium nitrate solution is preferred because it is easily available and can have sufficiently high reproducibility.

【0011】本発明を実施する上では、実施塩縮溶液の
比重は1.45〜1.50とするのが好ましく、特に
1.48〜1.50とすると更に好ましい。また、塩縮
溶液の温度は50〜70℃とするのが好ましく、特に5
0〜60℃とすると再現性が非常に高くなるので好まし
い。さらに、浸漬時間は30分以上、特に30〜60分
とするのが好ましい。
In practicing the present invention, the specific gravity of the salted solution is preferably from 1.45 to 1.50, and more preferably from 1.48 to 1.50. The temperature of the salted solution is preferably 50 to 70 ° C., and particularly preferably 5 to 70 ° C.
A temperature of 0 to 60 ° C. is preferable because reproducibility becomes very high. Further, the immersion time is preferably 30 minutes or more, particularly preferably 30 to 60 minutes.

【0012】また本発明における絹糸と塩縮溶液とを接
触処理するための具体例として、次記(イ)〜(ハ)に
示す方法を提案する。 (イ)第1の処理方法は、絹糸を、フリーの状態で塩縮
溶液を満たした恒温水槽中に入れ、所定の溶液温度で所
定時間浸漬し、その後脱液水洗(絹糸を塩縮溶液から取
出した後に水洗)することにより絹糸を収縮させる方法
である。本方法においては、絹糸を、無張力状態すなわ
ち収縮が妨げられない自由な状態で処理するので、絹糸
を最大限収縮させることができる利点がある。また、絹
糸の仕立て状態にかかわらず、処理できる利点もある。
Further, the following methods (a) to (c) are proposed as specific examples of the contact treatment between the silk thread and the salted solution in the present invention. (A) The first treatment method is to put a silk thread in a free state into a thermostatic water bath filled with a salted solution, immerse the silk thread at a given solution temperature for a given time, and then wash with de-water and wash the silk thread from the salted solution. This is a method of shrinking the silk thread by washing it with water after taking it out. In the present method, the silk yarn is treated in a non-tension state, that is, in a free state in which the shrinkage is not hindered, and thus there is an advantage that the silk yarn can be shrunk to the maximum. There is also an advantage that the treatment can be performed regardless of the tailoring state of the silk thread.

【0013】(ロ)第2の処理方法は、かせ状とした絹
糸を、噴射型染色機を利用して塩縮加工する方法であ
る。具体的には、かせ状とした絹糸を噴射型染色機に入
れ、シフターを回転させながら所定温度の塩縮溶液を所
定時間、投入した絹糸に噴射させる。本法の絹糸は、か
せ状となっているものの、実質的には無張力状態で処理
されるので、前述第1の方法と同程度絹糸を収縮させる
ことができる。
(B) The second processing method is a method of subjecting a skein-shaped silk thread to salt shrinkage using a jet dyeing machine. Specifically, the skein-shaped silk yarn is put into a jet dyeing machine, and a salted solution at a predetermined temperature is jetted onto the inputted silk yarn for a predetermined time while rotating the shifter. Although the silk yarn of the present method has a skein shape, it is processed in a substantially tensionless state, so that the silk yarn can be shrunk to the same extent as in the first method.

【0014】(ハ)第3の処理方法は、絹糸を巻取りチ
ーズに巻付けたままの状態でチーズ染色機を利用して塩
縮処理する方法である。具体的には、生糸をチーズに巻
き、これを染色機の中に入れて最初に精練を行い、次い
で水洗脱水、乾燥を行った後、所定比重の塩縮溶液をチ
ーズ染色機内に満たし、所定溶液温度で所定時間チーズ
染色と同様な方法で塩縮溶液を流し、その後脱液、水洗
する。生糸は精練することにより、表面のセリシンが約
25%溶解する。かかる表面セリシンが溶解した絹糸を
塩縮加工すると、絹糸がチーズに巻かれていることもあ
って、絹糸自身が収縮しようとして強い張力が発生し、
結果的に絹糸は収縮とともに細くなる。一方、絹糸の単
位長さ当たりの重量は増加するため、本方法によれば塩
縮加工により増量加工糸を製造できる。
(C) A third processing method is a method of subjecting a silk thread to a cheese-dyeing machine while the silk thread is wound on the wound cheese, and subjecting the silk thread to salt shrinkage. Specifically, raw silk is wound around a cheese, put into a dyeing machine, first scoured, then washed, dehydrated, and dried, and then filled with a salted solution having a predetermined specific gravity into the cheese dyeing machine, and The salted solution is allowed to flow at a solution temperature for a predetermined period of time in the same manner as in the cheese dyeing, and thereafter, deliquored and washed with water. By refining raw silk, sericin on the surface is dissolved by about 25%. When the silk thread in which such surface sericin is dissolved is subjected to salt-shrink processing, the silk thread itself is wound around the cheese, so that the silk thread itself tends to contract and a strong tension is generated,
As a result, the silk thread becomes thinner with shrinkage. On the other hand, since the weight per unit length of the silk yarn increases, according to the present method, an increased amount of processed yarn can be produced by salt shrinking.

【0015】<その他>以上に述べた本発明方法により
製造した絹糸を、たて糸のみ、よこ糸のみ、またはたて
糸およびよこ糸の両方に使用して織物を製造すことによ
って、従来の塩縮絹織物の装飾効果とは異なる、ソフト
で嵩高感のある織物を製造することができるようにな
る。
<Others> Decoration of a conventional salt-shrink silk fabric by producing a woven fabric using the silk yarn produced by the above-described method of the present invention for only the warp yarn, only the weft yarn, or both the warp yarn and the weft yarn. It is possible to produce a soft and bulky fabric having a different effect.

【0016】前述の第3の処理方法では、絹糸自身の収
縮作用により絹糸に張力が発生するが、本発明では例え
ば適宜の引っ張り手段によって機械的に絹糸に張力を発
生させるようにしても良い。
In the above-mentioned third processing method, tension is generated in the silk thread by the contraction action of the silk thread itself. In the present invention, for example, tension may be mechanically generated in the silk thread by an appropriate pulling means.

【0017】[0017]

【実施例】他方、種々の条件下における本発明方法の実
施例を表1に示す。
EXAMPLES On the other hand, Table 1 shows examples of the method of the present invention under various conditions.

【0018】[0018]

【表1】 [Table 1]

【0019】表1から、収縮率が処理時間に比例するこ
とが判る。また、この結果から、本発明方法が再現性が
非常に高い加工方法であることも判る。また、チーズに
巻いたり、かせ状態としたりしていないもの、すなわち
仕立てられていない状態の絹糸の方が収縮性が高いこと
も判る。さらに、かかる糸状態で塩縮加工された絹糸を
使用すれば、皺模様等を有しないソフトな織物を製造で
きるようになる。
From Table 1, it can be seen that the shrinkage ratio is proportional to the processing time. The results also show that the method of the present invention is a processing method with extremely high reproducibility. It can also be seen that those not wound or skeined on cheese, that is, silk yarn in an untailored state, has higher shrinkage. Furthermore, if a silk thread subjected to salt-shrink processing in such a thread state is used, a soft woven fabric having no wrinkle pattern or the like can be manufactured.

【0020】[0020]

【発明の効果】以上のとおり、本発明によれば、絹糸を
均一に収縮させることが可能となる。
As described above, according to the present invention, it is possible to uniformly shrink a silk thread.

───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 3B154 AA01 AB02 AB10 AB11 BA22 BB32 BB33 BD17 BE05 BF01 BF04 BF11 DA09 4L031 AA04 AB21 AB32 BA13 CA07 DA00  ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 3B154 AA01 AB02 AB10 AB11 BA22 BB32 BB33 BD17 BE05 BF01 BF04 BF11 DA09 4L031 AA04 AB21 AB32 BA13 CA07 DA00

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】絹糸を、織物とされていない糸の状態で塩
縮溶液と接触させ、塩縮処理することを特徴とする塩縮
加工方法。
1. A salt-shrinking method comprising: bringing a silk thread into contact with a salt-condensation solution in a state of a non-woven thread to perform a salt-shrink treatment.
【請求項2】前記塩縮溶液は比重が1.45〜1.50
の硝酸カルシウム溶液であり、且つ前記絹糸を50〜7
0℃の前記塩縮溶液と30分以上接触させる、請求項1
記載の塩縮加工方法。
2. The salted solution has a specific gravity of 1.45 to 1.50.
Calcium nitrate solution, and the silk yarn is 50 to 7
The contact with the salted solution at 0 ° C. for 30 minutes or more.
The salt shrinking method according to the above.
JP23372599A 1999-08-20 1999-08-20 Salt shrinking method Expired - Fee Related JP3274109B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP23372599A JP3274109B2 (en) 1999-08-20 1999-08-20 Salt shrinking method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23372599A JP3274109B2 (en) 1999-08-20 1999-08-20 Salt shrinking method

Publications (2)

Publication Number Publication Date
JP2001064866A true JP2001064866A (en) 2001-03-13
JP3274109B2 JP3274109B2 (en) 2002-04-15

Family

ID=16959601

Family Applications (1)

Application Number Title Priority Date Filing Date
JP23372599A Expired - Fee Related JP3274109B2 (en) 1999-08-20 1999-08-20 Salt shrinking method

Country Status (1)

Country Link
JP (1) JP3274109B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009038321A1 (en) * 2007-09-17 2009-03-26 Woo Youl Lee Apparatus and method for manufacturing shape retention silk
WO2019194245A1 (en) 2018-04-03 2019-10-10 Spiber株式会社 High-shrinkage artificial fibroin spun yarn, method for manufacturing same, artificial fibroin spun yarn, and method for shrinking same
WO2021060481A1 (en) * 2019-09-27 2021-04-01 Spiber株式会社 Method for manufacturing protein fiber, method for manufacturing protein fiber fabric, and shrink-proofing method for protein fiber
JP2021080575A (en) * 2018-01-31 2021-05-27 Spiber株式会社 Method of manufacturing protein spun yarn

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009038321A1 (en) * 2007-09-17 2009-03-26 Woo Youl Lee Apparatus and method for manufacturing shape retention silk
JP2021080575A (en) * 2018-01-31 2021-05-27 Spiber株式会社 Method of manufacturing protein spun yarn
JP7223984B2 (en) 2018-01-31 2023-02-17 Spiber株式会社 Method for producing protein spun yarn
WO2019194245A1 (en) 2018-04-03 2019-10-10 Spiber株式会社 High-shrinkage artificial fibroin spun yarn, method for manufacturing same, artificial fibroin spun yarn, and method for shrinking same
WO2021060481A1 (en) * 2019-09-27 2021-04-01 Spiber株式会社 Method for manufacturing protein fiber, method for manufacturing protein fiber fabric, and shrink-proofing method for protein fiber

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