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JP2000348958A - Manufacture of resin-bonded magnet - Google Patents

Manufacture of resin-bonded magnet

Info

Publication number
JP2000348958A
JP2000348958A JP11155832A JP15583299A JP2000348958A JP 2000348958 A JP2000348958 A JP 2000348958A JP 11155832 A JP11155832 A JP 11155832A JP 15583299 A JP15583299 A JP 15583299A JP 2000348958 A JP2000348958 A JP 2000348958A
Authority
JP
Japan
Prior art keywords
resin
magnetic powder
shape
bonded magnet
magnet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11155832A
Other languages
Japanese (ja)
Inventor
Noboru Ito
登 伊藤
Masaaki Suzuki
正明 鈴木
Kunio Oshima
國雄 大島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP11155832A priority Critical patent/JP2000348958A/en
Publication of JP2000348958A publication Critical patent/JP2000348958A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/032Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
    • H01F1/04Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
    • H01F1/06Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder
    • H01F1/08Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together
    • H01F1/083Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together in a bonding agent

Landscapes

  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Hard Magnetic Materials (AREA)
  • Manufacturing Cores, Coils, And Magnets (AREA)

Abstract

PROBLEM TO BE SOLVED: To enable a resin-bonded magnet to be naturally decomposed even if it is thrown away as it is and to prevent dioxins from originating from the magnet even if it is incinerated, by a method wherein a thermoplastic resin such as a biodegradable plastic or a non-halogen resin is mixed as a binder into magnetic powder, and the mixture is heated, softened, molded into a rod, and magnetized through a kneader-rooter. SOLUTION: Thermoplastic resin such as a biodegradable plastic and/or a non-halogen resin which contains no chlorine is mixed as binder into magnetic powder such as ferrite magnetic powder. The weight ratio of thermoplastic resin to the total weight is set at about 45 or less: 100 in a stage where a resin- bonded magnet is molded. The biodegradable plastic formed by the use of natural products is used as a biodegradable plastic, and a polyolefin resin is used as a non-halogen resin. A mixture of thermoplastic resin and magnetic powder is heated, softened, molded into rods, pellets, and sheets, and magnetized through a kneader-rooter, by which a resin-bonded magnet can be obtained.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、地球環境に配慮し
た樹脂結合型磁石に係り、特に使用後に廃棄した場合、
自然分解するまたは焼却時にダイオキシンが発生しない
樹脂結合型磁石の成形に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a resin-bonded magnet that considers the global environment,
The present invention relates to molding of a resin-bonded magnet that does not decompose spontaneously or does not generate dioxin when incinerated.

【0002】[0002]

【従来の技術】樹脂結合型磁石は、熱可塑性樹脂剤に磁
性粉を混入し、加熱軟化して成形するため柔軟性があり
加工性に富んだ磁石として有効性を有している。
2. Description of the Related Art Resin-bonded magnets are effective as magnets which are flexible and have good workability because magnetic powder is mixed into a thermoplastic resin material and heat-softened for molding.

【0003】また、樹脂結合型磁石の利用範囲は、家庭
では冷蔵庫や洗濯機などのスチール面、会社ではホワイ
トボードやスチール製のロッカー、机、壁面などの磁性
体面に対して、マグネットボタンやマグネットバーなど
の磁石製品として、または自動車の初心者マークやモー
ター用マグネットとして一般的に広範囲に利用されてい
る。
[0003] The range of use of the resin-bonded magnet is as follows: at home, a steel surface such as a refrigerator or a washing machine; and at a company, a magnetic button or magnet is used for a magnetic surface such as a whiteboard or a steel locker, a desk, or a wall surface. It is generally widely used as a magnet product such as a bar, or as a beginner's mark of a car or a magnet for a motor.

【0004】[0004]

【発明が解決しようとする課題】このように会社や家庭
など私たちの生活の中で磁性体面であれば自由に貼った
り剥がしたりできる便利な樹脂結合型磁石製品も、その
利用が済めば廃棄しなければならず、焼却によるダイオ
キシン問題が大きな社会現象になっている。
As described above, a convenient resin-bonded magnet product that can be freely attached and detached on a magnetic surface in our daily lives such as a company or a home is discarded once its use is completed. The dioxin problem caused by incineration has become a major social phenomenon.

【0005】そこで本発明は、マグネットとしての利用
が済んだあとの廃棄について、そのまま廃棄しても自然
分解する、または焼却しても塩素が入っていないためダ
イオキシンが発生しない樹脂結合型磁石を製造すること
を目的とする。
Accordingly, the present invention provides a resin-bonded magnet which does not generate dioxin because it does not decompose spontaneously when discarded as it is after being used as a magnet, or does not contain chlorine even when incinerated. The purpose is to do.

【0006】[0006]

【課題を解決するための手段】前述の目的を達成するた
め、本発明の樹脂結合型磁石の製造方法は、熱可塑性樹
脂として生分解性プラスチックや塩素を含まないノンハ
ロゲン系樹脂を結合剤として磁性粉に混入したものをニ
ーダールーダーにて加熱軟化させ棒状または粒状および
シート状に成形し、着磁することで樹脂結合型磁石とな
ることを特徴とするものである。
In order to achieve the above-mentioned object, a method for producing a resin-bonded magnet according to the present invention is characterized in that a biodegradable plastic or a chlorine-free non-halogen resin is used as a thermoplastic resin. It is characterized in that the mixture in the powder is heated and softened by a kneader-ruder, formed into a rod shape or a granular shape and a sheet shape, and magnetized to form a resin-bonded magnet.

【0007】また、磁性粉に混入する熱可塑性樹脂は、
成形性をよくするため生分解性プラスチックと塩素を含
まないノンハロゲン系樹脂を適宜混合し、結合剤として
使用してもよい。
The thermoplastic resin mixed into the magnetic powder is
In order to improve the moldability, a biodegradable plastic and a non-halogen resin containing no chlorine may be appropriately mixed and used as a binder.

【0008】また、熱可塑性樹脂と混入する磁性粉は、
磁力の強弱によりフェライト磁性粉やサマリウム(S
m)・ネオジウム(Nd)・セリウム(Ce)・プラセ
ジウム(Pr)などの希土類元素を含む合成磁性粉を適
宜混合し、使用目的により磁力の単位であるB・Hma
xを0.2からその配合割合により段階的に強磁性体に
する樹脂結合型磁石を成形してもよい。
The magnetic powder mixed with the thermoplastic resin is:
Ferrite magnetic powder or samarium (S
m) A synthetic magnetic powder containing a rare earth element such as neodymium (Nd), cerium (Ce), or prasedium (Pr) is appropriately mixed, and B · Hma, which is a unit of magnetic force, depending on the purpose of use.
A resin-coupled magnet may be formed into a ferromagnetic material in a stepwise manner depending on the mixing ratio of x from 0.2.

【0009】[0009]

【発明の実施形態】本発明の樹脂結合型磁石は、環境問
題に対応した熱可塑性樹脂として生分解性プラスチック
や塩素を含まないノンハロゲン系樹脂またはこれらを混
合した熱可塑性樹脂を結合剤として磁性粉に混入する。
BEST MODE FOR CARRYING OUT THE INVENTION The resin-bonded magnet of the present invention uses a biodegradable plastic, a chlorine-free non-halogen resin or a thermoplastic resin obtained by mixing these as a binder as a thermoplastic resin as a thermoplastic resin corresponding to environmental problems. Mixed in.

【0010】この熱可塑性樹脂と磁性粉の混入比は、少
なくとも結合剤である熱可塑性樹脂が樹脂結合型磁石を
成形する段階で、磁力の単位であるB・Hmax0.2
以上を保持するため、総重量の45%以下とする。
The mixing ratio of the thermoplastic resin and the magnetic powder is determined at least when the thermoplastic resin as a binder is used to form a resin-bonded magnet at the stage of molding B.Hmax 0.2 which is a unit of magnetic force.
In order to maintain the above, it is set to 45% or less of the total weight.

【0011】この磁性粉に混入する熱可塑性樹脂である
生分解性プラスチックは、天然物利用系生分解性プラス
チックであるでんぷんやセルロースおよびキチン・キト
サン・海産多糖類などの天然高分子、微生物産生系生分
解性プラスチックであるバイオポリエステル・カードラ
ン・プルラン・バクテリアセルロース・ポリアミノ酸な
どの高分子、化学合成系生分解性プラスチックである脂
肪族ポリエステルおよび共重合体・ポリウレタン樹脂・
ポリアミド系樹脂・ポリビニルアルコール・ポリエテー
ルなどの合成高分子、およびこれらの天然物利用系・微
生物産生系・化学合成系を複合した合成高分子、または
光分解性プラスチックがある。
The biodegradable plastic, which is a thermoplastic resin mixed into the magnetic powder, is a natural product-based biodegradable plastic such as starch and cellulose, natural polymers such as chitin, chitosan, and marine polysaccharides, and microorganism-producing plastics. Biodegradable plastics such as biopolyesters, curdlan, pullulan, bacterial cellulose, polyamino acids, etc., and chemically synthesized biodegradable plastics such as aliphatic polyesters and copolymers, polyurethane resins,
There are synthetic polymers such as polyamide resin, polyvinyl alcohol, and polyether, and synthetic polymers or photodegradable plastics that combine these natural product utilization systems, microbial production systems, and chemical synthesis systems.

【0012】また、この磁性粉に混入する熱可塑性樹脂
である塩素を含まないノンハロゲン系樹脂は、ポリオレ
フィン系樹脂・ポリアミド系樹脂・ポリエステル系樹脂
・スチレン系樹脂・ウレタン系樹脂などの合成樹脂およ
びこれらを共重合した合成樹脂がある。
Further, chlorine-free non-halogen resin which is a thermoplastic resin mixed into the magnetic powder includes synthetic resins such as polyolefin resin, polyamide resin, polyester resin, styrene resin, urethane resin and the like. There is a synthetic resin obtained by copolymerizing

【0013】また、磁性粉末としてフェライト磁性粉や
サマリウム(Sm)・ネオジウム(Nd)・セリウム
(Ce)・プラセジウム(Pr)などの希土類元素を含
む合金磁性粉およびこれらの磁性粉を混合した磁性粉が
ある。
Further, as magnetic powder, ferrite magnetic powder, alloy magnetic powder containing a rare earth element such as samarium (Sm), neodymium (Nd), cerium (Ce), prasedium (Pr), and magnetic powder obtained by mixing these magnetic powders There is.

【0014】この磁性粉を使用目的により磁力の単位で
あるB・Hmax0.2からその配合割合により段階的
に強磁性体にすることができるものである。
The magnetic powder can be made into a ferromagnetic material stepwise from B.Hmax 0.2, which is a unit of magnetic force, depending on the purpose of use, depending on the mixing ratio.

【0015】これらの熱可塑性樹脂と磁性粉を混入した
ものをニーダールーダーにて加熱軟化させ棒状または粒
状およびシート状に成形し、着磁することにより樹脂結
合型磁石とするものである。
A mixture of the thermoplastic resin and the magnetic powder is heated and softened by a kneader-ruder, formed into a rod shape, a granular shape and a sheet shape, and magnetized to obtain a resin-bonded magnet.

【0016】そして、この成形される樹脂結合型磁石
は、地球環境に配慮したものであり、使用後廃棄した場
合、自然分解するまたは焼却時にダイオキシンが発生し
ない樹脂結合型磁石ができるものである。
The molded resin-bonded magnet is made in consideration of the global environment, and when discarded after use, a resin-bonded magnet that does not decompose spontaneously or does not generate dioxin when incinerated can be obtained.

【0017】[0017]

【発明の効果】以上詳述の如く、本発明の樹脂結合型磁
石の製造方法によれば、通常使用する場合は、磁性体面
に自由に貼ったり剥がしたりする樹脂結合型磁石がで
き、かつ使用後に廃棄した場合も自然分解するまたは焼
却してもダイオキシンが発生しない環境に配慮した極め
て有効的なものである。
As described in detail above, according to the method of manufacturing a resin-bonded magnet of the present invention, a resin-bonded magnet that can be freely attached to and detached from a magnetic material surface when used normally can be formed and used. It is extremely effective in consideration of the environment where dioxin is not generated even if it is later disposed of by natural decomposition or incineration.

【0018】また、自然分解することを利用してマグネ
ットの磁力と製造段階でトルマリンまたは肥料成分およ
び土壌活性剤を混入することで、バイオ肥料とすること
もできる。
Further, biofertilizer can also be obtained by mixing tourmaline or a fertilizer component and a soil activator in the production stage with the magnetic force of the magnet utilizing natural decomposition.

【0019】また、熱可塑性樹脂に混入する磁性粉末と
してフェライト磁性粉やサマリウム(Sm)・ネオジウ
ム(Nd)・セリウム(Ce)・プラセジウム(Pr)
などの希土類元素を含む合金磁性粉を混合することで、
使用目的により磁力の単位であるB・Hmax0.2か
らその配合割合により段階的に強磁性体にすることがで
きるものである。
Ferrite magnetic powder, samarium (Sm), neodymium (Nd), cerium (Ce), and prasedium (Pr) may be used as magnetic powder mixed in the thermoplastic resin.
By mixing alloy magnetic powder containing rare earth elements such as
Depending on the purpose of use, the ferromagnetic material can be made into a ferromagnetic material stepwise from B.Hmax 0.2, which is the unit of magnetic force, according to its blending ratio.

Claims (10)

【特許請求の範囲】[Claims] 【請求項1】 熱可塑性樹脂として自然分解する生分
解性プラスチックを結合剤として使用し、磁性粉末に混
入したものをニーダールーダーにて加熱軟化させ棒状ま
たは粒状およびシート状に成形し、着磁することを特徴
とする樹脂結合型磁石の製造方法。
1. A biodegradable plastic which naturally decomposes as a thermoplastic resin is used as a binder, and a mixture mixed with a magnetic powder is heated and softened by a kneader-ruder to form a bar, a granule, and a sheet and magnetized. A method of manufacturing a resin-bonded magnet.
【請求項2】 熱可塑性樹脂として塩素を含まないノ
ンハロゲン系樹脂を結合剤として使用し、磁性粉末に混
入したものをニーダールーダーにて加熱軟化させ棒状ま
たは粒状およびシート状に成形し、着磁することを特徴
とする樹脂結合型磁石の製造方法。
2. A non-halogen resin containing no chlorine as a thermoplastic resin is used as a binder, and the mixture mixed with the magnetic powder is heated and softened by a kneader-ruder to be shaped into a rod shape or a granular shape and a sheet shape and magnetized. A method of manufacturing a resin-bonded magnet.
【請求項3】 熱可塑性樹脂として自然分解する生分
解性プラスチックと塩素を含まないノンハロゲン系樹脂
とを混合し結合剤として使用し、磁性粉末に混入したも
のをニーダールーダーにて加熱軟化させ棒状または粒状
およびシート状に成形し、着磁することを特徴とする樹
脂結合型磁石の製造方法。
3. A biodegradable plastic which naturally decomposes as a thermoplastic resin and a non-halogen resin containing no chlorine are mixed and used as a binder. A method for producing a resin-bonded magnet, which is formed into a granular shape and a sheet shape and magnetized.
【請求項4】 成形した樹脂結合型磁石の形を整形す
るために遠心分離器またはヘンシェルミキサーおよび振
動装置を使用し、球状にすることを特徴とする請求項1
から3記載の製造方法。
4. A centrifugal separator or a Henschel mixer and a vibrating device are used to shape the molded resin-bonded magnet, and the magnet is formed into a spherical shape.
4. The production method according to 3.
【請求項5】 製造段階では着磁しないで棒状または
粒状およびシート状に成形し、形を整形した後着磁をす
ることを特徴とする請求項1から4記載の製造方法。
5. The manufacturing method according to claim 1, wherein in a manufacturing stage, the magnet is formed into a rod shape, a granular shape and a sheet shape without magnetizing, and the shape is shaped and then magnetized.
【請求項6】 生分解性プラスチックは、天然物利用
系生分解性プラスチックであるでんぷんやセルロースお
よびキチン・キトサン・海産多糖類などの天然高分子、
微生物産生系生分解性プラスチックであるバイオポリエ
ステル・カードラン・プルラン・バクテリアセルロース
・ポリアミノ酸などの高分子、化学合成系生分解性プラ
スチックである脂肪族ポリエステルおよび共重合体・ポ
リウレタン樹脂・ポリアミド系樹脂・ポリビニルアルコ
ール・ポリエテールなどの合成高分子、およびこれらの
天然物利用系・微生物産生系・化学合成系を複合した合
成高分子、または光分解性プラスチックを使用すること
を特徴とする請求項1および3記載の製造方法。
6. The biodegradable plastic is a natural polymer based on a natural product such as starch, cellulose, chitin, chitosan, and marine polysaccharide, which are biodegradable plastics based on natural products.
Polymers such as biopolyester, curdlan, pullulan, bacterial cellulose, and polyamino acids, which are microbial biodegradable plastics; aliphatic polyesters and copolymers, polyurethane resins, and polyamide resins, which are biosynthetic plastics that are chemically synthesized 2. A synthetic polymer, such as polyvinyl alcohol or polyether, or a synthetic polymer obtained by combining these natural products, a microorganism producing system, or a chemically synthesized system, or a photo-degradable plastic. 3. The production method according to 3.
【請求項7】 熱可塑性合成樹脂として塩素を含まな
いノンハロゲン系樹脂は、ポリオレフィン系樹脂・ポリ
アミド系樹脂・ポリエステル系樹脂・スチレン系樹脂・
ウレタン系樹脂などの合成樹脂およびこれらを共重合し
た合成樹脂を使用することを特徴とする請求項2および
3記載の製造方法。
7. A non-halogen resin containing no chlorine as a thermoplastic synthetic resin is a polyolefin resin, a polyamide resin, a polyester resin, a styrene resin, or the like.
4. The method according to claim 2, wherein a synthetic resin such as a urethane resin and a synthetic resin obtained by copolymerizing the synthetic resin are used.
【請求項8】 磁性粉末としてフェライト磁性粉やサ
マリウム(Sm)・ネオジウム(Nd)・セリウム(C
e)・プラセジウム(Pr)などの希土類元素を含む合
金磁性粉およびこれらの磁性粉を混合した磁性粉を使用
することを特徴とする請求項1から3記載の製造方法。
8. Ferrite magnetic powder, samarium (Sm), neodymium (Nd), cerium (C)
4. The method according to claim 1, wherein e) an alloy magnetic powder containing a rare earth element such as prasedium (Pr) and a magnetic powder obtained by mixing these magnetic powders are used.
【請求項9】 樹脂結合型磁石の重量比は、少なくと
も結合剤である熱可塑性樹脂が、樹脂結合型磁石を成形
する段階で磁性粉末に対し、総重量の45%以下である
ことを特徴とする請求項1から3記載の製造方法。
9. The weight ratio of the resin-bonded magnet is at least 45% or less of the total weight of the thermoplastic powder as a binder with respect to the magnetic powder at the stage of molding the resin-bonded magnet. The method according to claim 1, wherein:
【請求項10】 製造段階でトルマリンまたは肥料成分
および土壌活性剤を混入し、棒状・粒状・シート状に成
形することを特徴とする請求項1から3記載の製造方
法。
10. The production method according to claim 1, wherein tourmaline or a fertilizer component and a soil activator are mixed in the production stage, and the mixture is formed into a rod shape, a granular shape, and a sheet shape.
JP11155832A 1999-06-03 1999-06-03 Manufacture of resin-bonded magnet Pending JP2000348958A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11155832A JP2000348958A (en) 1999-06-03 1999-06-03 Manufacture of resin-bonded magnet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11155832A JP2000348958A (en) 1999-06-03 1999-06-03 Manufacture of resin-bonded magnet

Publications (1)

Publication Number Publication Date
JP2000348958A true JP2000348958A (en) 2000-12-15

Family

ID=15614483

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11155832A Pending JP2000348958A (en) 1999-06-03 1999-06-03 Manufacture of resin-bonded magnet

Country Status (1)

Country Link
JP (1) JP2000348958A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7128798B2 (en) 2000-11-26 2006-10-31 Magaetnotes, Ltd. Magnetic substrates, composition and method for making the same
US7338573B2 (en) 2000-11-26 2008-03-04 Magnetnotes, Ltd. Magnetic substrates with high magnetic loading
US9028951B2 (en) 2013-09-10 2015-05-12 Magnetnotes, Ltd. Magnetic receptive printable media
US10568839B2 (en) 2011-01-11 2020-02-25 Capsugel Belgium Nv Hard capsules
US11319566B2 (en) 2017-04-14 2022-05-03 Capsugel Belgium Nv Process for making pullulan
US11576870B2 (en) 2017-04-14 2023-02-14 Capsugel Belgium Nv Pullulan capsules

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JPS55160042A (en) * 1979-05-30 1980-12-12 Sumitomo Chem Co Ltd Thermoplastic resin composition
JPS59135705A (en) * 1983-01-24 1984-08-04 Dainippon Ink & Chem Inc Resin magnet material
JPH05251222A (en) * 1992-03-05 1993-09-28 Seiko Epson Corp Resin-bonded magnet
JPH0817614A (en) * 1994-07-01 1996-01-19 Japan Steel Works Ltd:The Polylactic acid plastic magnet molding material and method for manufacturing magnet product
JPH1081815A (en) * 1996-09-04 1998-03-31 Mitsui Petrochem Ind Ltd Resin composition
JPH10237324A (en) * 1996-12-27 1998-09-08 Kanegafuchi Chem Ind Co Ltd Flame retardant resin material, flame retardant resin magnet material, and electron beam adjusting device using the flame retardant resin magnet material
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7128798B2 (en) 2000-11-26 2006-10-31 Magaetnotes, Ltd. Magnetic substrates, composition and method for making the same
US7338573B2 (en) 2000-11-26 2008-03-04 Magnetnotes, Ltd. Magnetic substrates with high magnetic loading
US10568839B2 (en) 2011-01-11 2020-02-25 Capsugel Belgium Nv Hard capsules
US9028951B2 (en) 2013-09-10 2015-05-12 Magnetnotes, Ltd. Magnetic receptive printable media
US11319566B2 (en) 2017-04-14 2022-05-03 Capsugel Belgium Nv Process for making pullulan
US11576870B2 (en) 2017-04-14 2023-02-14 Capsugel Belgium Nv Pullulan capsules
US11878079B2 (en) 2017-04-14 2024-01-23 Capsugel Belgium Nv Pullulan capsules

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