IT1110745B - PROCEDURE FOR THE SYNTHESIS OF SEC-BUTANOL FROM LINEAR BUTENI - Google Patents
PROCEDURE FOR THE SYNTHESIS OF SEC-BUTANOL FROM LINEAR BUTENIInfo
- Publication number
- IT1110745B IT1110745B IT19706/79A IT1970679A IT1110745B IT 1110745 B IT1110745 B IT 1110745B IT 19706/79 A IT19706/79 A IT 19706/79A IT 1970679 A IT1970679 A IT 1970679A IT 1110745 B IT1110745 B IT 1110745B
- Authority
- IT
- Italy
- Prior art keywords
- butanol
- sec
- linear
- buteni
- synthesis
- Prior art date
Links
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 2
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 2
- 239000003729 cation exchange resin Substances 0.000 abstract 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 1
- 238000010533 azeotropic distillation Methods 0.000 abstract 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
- C07C29/82—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation by azeotropic distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
- C07C29/095—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of organic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/86—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by liquid-liquid treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
The process comprises the steps of esterifying one or more linear butene in the liquid phase with an organic acid in the presence of a cation exchange resin; hydrolyzing the resulting ester to sec-butanol in the presence of a cation exchange resin; and recovering the sec-butanol by azeotropic distillation.
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT19706/79A IT1110745B (en) | 1979-01-30 | 1979-01-30 | PROCEDURE FOR THE SYNTHESIS OF SEC-BUTANOL FROM LINEAR BUTENI |
| GB8001408A GB2041364B (en) | 1979-01-30 | 1980-01-16 | Producing secbutanol from linear butenes |
| FR8001798A FR2447896A1 (en) | 1979-01-30 | 1980-01-28 | METHOD FOR SYNTHESIS OF SECONDARY BUTANOL FROM RIGHT CHAIN BUTENES |
| DK35080A DK35080A (en) | 1979-01-30 | 1980-01-28 | PROCEDURE FOR SYNTHESIS OF SEC-BUTANOL FROM LINEAR BUTENES |
| NO800215A NO800215L (en) | 1979-01-30 | 1980-01-29 | PROCEDURE FOR SYNTHETIZING SEC.BUTANOL. |
| ES488741A ES488741A0 (en) | 1979-01-30 | 1980-01-29 | PROCEDURE FOR THE SYNTHESIS OF SEC-BUTANOL FROM LINEAR BUTENES |
| JP837480A JPS55102530A (en) | 1979-01-30 | 1980-01-29 | Manufacture of secondary butylalcohol |
| DE19803003126 DE3003126A1 (en) | 1979-01-30 | 1980-01-29 | METHOD FOR PRODUCING SEC. BUTANOL |
| BE0/199176A BE881437A (en) | 1979-01-30 | 1980-01-30 | METHOD FOR SYNTHESIS OF SECONDARY BUTANOL FROM RIGHT CHAIN BUTENES |
| SE8000742A SE8000742L (en) | 1979-01-30 | 1980-01-30 | SET TO SYNTHETIZE SEC-BUTANOL OF LINEAR BUTENES |
| NL8000580A NL8000580A (en) | 1979-01-30 | 1980-01-30 | PROCESS FOR THE PREPARATION OF SEC-BUTANOL FROM LINEAR BUTES |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT19706/79A IT1110745B (en) | 1979-01-30 | 1979-01-30 | PROCEDURE FOR THE SYNTHESIS OF SEC-BUTANOL FROM LINEAR BUTENI |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IT7919706A0 IT7919706A0 (en) | 1979-01-30 |
| IT1110745B true IT1110745B (en) | 1986-01-06 |
Family
ID=11160539
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IT19706/79A IT1110745B (en) | 1979-01-30 | 1979-01-30 | PROCEDURE FOR THE SYNTHESIS OF SEC-BUTANOL FROM LINEAR BUTENI |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS55102530A (en) |
| BE (1) | BE881437A (en) |
| DE (1) | DE3003126A1 (en) |
| DK (1) | DK35080A (en) |
| ES (1) | ES488741A0 (en) |
| FR (1) | FR2447896A1 (en) |
| GB (1) | GB2041364B (en) |
| IT (1) | IT1110745B (en) |
| NL (1) | NL8000580A (en) |
| NO (1) | NO800215L (en) |
| SE (1) | SE8000742L (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0054576B2 (en) * | 1980-12-18 | 1988-07-13 | Union Explosivos Rio Tinto, S.A. | Process for producing esters from olefins |
| US4384148A (en) * | 1982-02-26 | 1983-05-17 | Uop Inc. | Hydration of olefins |
| US4927954A (en) * | 1983-06-28 | 1990-05-22 | Union Carbide Chemicals And Plastics Company, Inc. | Continuous process for producing secondary alcohols and carboxylic acid esters |
| DE69117871T2 (en) * | 1990-10-31 | 1996-11-07 | Daicel Chem | Process for the preparation of a lower alkyl acetate |
| RU2206560C1 (en) * | 2001-12-27 | 2003-06-20 | Закрытое акционерное общество фирма "Альен" | Method for preparing secondary butyl alcohol |
| EP2046706A1 (en) * | 2006-07-20 | 2009-04-15 | Basf Se | Process for preparing isopropanol and 2-butanol from the corresponding alkanes |
| JPWO2010071011A1 (en) * | 2008-12-15 | 2012-05-24 | Jx日鉱日石エネルギー株式会社 | Method for producing acetate ester |
| CN104311390A (en) * | 2014-10-17 | 2015-01-28 | 深圳市飞扬实业有限公司 | Method for synthesizing sec-butyl alcohol |
| RU2570818C1 (en) | 2015-01-12 | 2015-12-10 | Открытое акционерное общество "Газпромнефть - Московский НПЗ" | Method of obtaining carbonyl compounds c2-c4 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1374368A (en) * | 1972-08-15 | 1974-11-20 | Bp Chem Int Ltd | Production of secbutanol |
-
1979
- 1979-01-30 IT IT19706/79A patent/IT1110745B/en active
-
1980
- 1980-01-16 GB GB8001408A patent/GB2041364B/en not_active Expired
- 1980-01-28 FR FR8001798A patent/FR2447896A1/en not_active Withdrawn
- 1980-01-28 DK DK35080A patent/DK35080A/en not_active Application Discontinuation
- 1980-01-29 ES ES488741A patent/ES488741A0/en active Granted
- 1980-01-29 DE DE19803003126 patent/DE3003126A1/en not_active Ceased
- 1980-01-29 JP JP837480A patent/JPS55102530A/en active Pending
- 1980-01-29 NO NO800215A patent/NO800215L/en unknown
- 1980-01-30 SE SE8000742A patent/SE8000742L/en not_active Application Discontinuation
- 1980-01-30 BE BE0/199176A patent/BE881437A/en not_active IP Right Cessation
- 1980-01-30 NL NL8000580A patent/NL8000580A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55102530A (en) | 1980-08-05 |
| BE881437A (en) | 1980-07-30 |
| GB2041364B (en) | 1983-03-23 |
| IT7919706A0 (en) | 1979-01-30 |
| DE3003126A1 (en) | 1980-07-31 |
| FR2447896A1 (en) | 1980-08-29 |
| DK35080A (en) | 1980-07-31 |
| GB2041364A (en) | 1980-09-10 |
| NO800215L (en) | 1980-07-31 |
| SE8000742L (en) | 1980-07-31 |
| NL8000580A (en) | 1980-08-01 |
| ES8103006A1 (en) | 1981-02-16 |
| ES488741A0 (en) | 1981-02-16 |
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