GB992736A - Polyamides - Google Patents
PolyamidesInfo
- Publication number
- GB992736A GB992736A GB4876763A GB4876763A GB992736A GB 992736 A GB992736 A GB 992736A GB 4876763 A GB4876763 A GB 4876763A GB 4876763 A GB4876763 A GB 4876763A GB 992736 A GB992736 A GB 992736A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- carbon atoms
- group
- hydrogen
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004952 Polyamide Substances 0.000 title abstract 2
- 229920002647 polyamide Polymers 0.000 title abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- 150000003008 phosphonic acid esters Chemical class 0.000 abstract 2
- YUDRVAHLXDBKSR-UHFFFAOYSA-N [CH]1CCCCC1 Chemical compound [CH]1CCCCC1 YUDRVAHLXDBKSR-UHFFFAOYSA-N 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 1
- 150000004985 diamines Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/42—Polyamides containing atoms other than carbon, hydrogen, oxygen, and nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
- C08K5/5333—Esters of phosphonic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
Abstract
A process for the production of linear fibre-forming polyamides having improved colour stability and resistance to oxidation comprises reacting, at a temperature of 200 DEG to 300 DEG C. a compound of formula H2N-A-NH2, where A is an a : o -alkylene radical having 4 to 6 carbon atoms or an o : o 1-m-xylylene radical, a dicarboxylic acid of the formula HOOC-B-COOH, where B is an a : o -alkylene radical having 2 to 10 carbon atoms, and a phosphonic acid ester of the formula <FORM:0992736/C3/1> where X1 and X2 are the same or different and each represent an alkyl group having 1 to 10 carbon atoms, a hydroxy alkyl or halogen alkyl having 2 to 4 carbon atoms or a cyclohexyl radical, R1 and R2 are the same or different and each represent hydrogen, or an alkyl, cyclohexyl or 1-methylcyclohexyl-(1) group, at least one of R1 and R2 being a secondary or tertiary alkyl or cycloalkyl group, R3 is hydrogen or a methyl group and R4 is hydrogen, or a methyl, ethyl or phenyl group, to form a polymeric amide, the proportion of said phosphonic ester being 0.001 to 5% by weight of the final polymer. In a modification of the process, a precondensate of the diamine and dicarboxylic acid is reacted with the phosphonic acid ester.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1449062A CH433743A (en) | 1962-12-11 | 1962-12-11 | Process for the production of polyamides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB992736A true GB992736A (en) | 1965-05-19 |
Family
ID=4401267
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4876763A Expired GB992736A (en) | 1962-12-11 | 1963-12-10 | Polyamides |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE641075A (en) |
| CH (2) | CH433745A (en) |
| DE (2) | DE1795554A1 (en) |
| GB (1) | GB992736A (en) |
| NL (2) | NL301602A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002102885A1 (en) * | 2001-06-14 | 2002-12-27 | Basf Corporation | Light-stabilized polymers comprising light-stabilizing moieties, articles therefrom and a method of making the same |
-
0
- NL NL137487D patent/NL137487C/xx active
- NL NL301602D patent/NL301602A/xx unknown
-
1962
- 1962-12-11 CH CH363767A patent/CH433745A/en unknown
- 1962-12-11 CH CH1449062A patent/CH433743A/en unknown
-
1963
- 1963-12-10 DE DE19631795554 patent/DE1795554A1/en active Pending
- 1963-12-10 GB GB4876763A patent/GB992736A/en not_active Expired
- 1963-12-10 BE BE641075A patent/BE641075A/xx unknown
- 1963-12-10 DE DE19631495945 patent/DE1495945A1/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002102885A1 (en) * | 2001-06-14 | 2002-12-27 | Basf Corporation | Light-stabilized polymers comprising light-stabilizing moieties, articles therefrom and a method of making the same |
| US6867266B2 (en) | 2001-06-14 | 2005-03-15 | Basf Corporation | Light-stabilized polymeric articles and methods of making the same |
Also Published As
| Publication number | Publication date |
|---|---|
| NL137487C (en) | |
| NL301602A (en) | |
| CH433743A (en) | 1967-04-15 |
| BE641075A (en) | 1964-06-10 |
| DE1495945A1 (en) | 1970-02-05 |
| CH433745A (en) | 1967-04-15 |
| DE1795554A1 (en) | 1972-01-13 |
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