GB974892A - Polyester compositions - Google Patents
Polyester compositionsInfo
- Publication number
- GB974892A GB974892A GB4429259A GB4429259A GB974892A GB 974892 A GB974892 A GB 974892A GB 4429259 A GB4429259 A GB 4429259A GB 4429259 A GB4429259 A GB 4429259A GB 974892 A GB974892 A GB 974892A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ether
- composition
- polyallyl
- unsaturated
- partial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- 229920000728 polyester Polymers 0.000 title abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 3
- -1 diallyl glycerol Chemical compound 0.000 abstract 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- VEZUQRBDRNJBJY-UHFFFAOYSA-N cyclohexanone oxime Chemical compound ON=C1CCCCC1 VEZUQRBDRNJBJY-UHFFFAOYSA-N 0.000 abstract 2
- 150000002170 ethers Chemical class 0.000 abstract 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 abstract 2
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 abstract 2
- 150000002978 peroxides Chemical class 0.000 abstract 2
- 239000000600 sorbitol Substances 0.000 abstract 2
- 150000005846 sugar alcohols Polymers 0.000 abstract 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 2
- JQGGYGKXKWTXTF-UHFFFAOYSA-N 1-ethenoxy-3-prop-2-enoxy-2,2-bis(prop-2-enoxymethyl)propane Chemical compound C=CCOCC(COCC=C)(COCC=C)COC=C JQGGYGKXKWTXTF-UHFFFAOYSA-N 0.000 abstract 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical group CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 abstract 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 abstract 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- PXAJQJMDEXJWFB-UHFFFAOYSA-N acetone oxime Chemical compound CC(C)=NO PXAJQJMDEXJWFB-UHFFFAOYSA-N 0.000 abstract 1
- 235000011037 adipic acid Nutrition 0.000 abstract 1
- 150000001279 adipic acids Chemical class 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001733 carboxylic acid esters Chemical class 0.000 abstract 1
- 235000015165 citric acid Nutrition 0.000 abstract 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 125000001033 ether group Chemical group 0.000 abstract 1
- 239000001530 fumaric acid Substances 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 239000011976 maleic acid Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 150000002923 oximes Chemical class 0.000 abstract 1
- 229920006337 unsaturated polyester resin Polymers 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
A surface coating composition comprises (A) a linear unsaturated polyester resin obtained by condensation of a glycol with both an unsaturated and a saturated dicarboxylic acid or anhydride and (B) not less than 35% by weight of the composition of a normally liquid polyallyl ether having a boiling point not less than 150 DEG C. and a viscosity not above 5 poises at 20 DEG C. and which is either (i) a partial or complete polyallyl ether of a polyhydric alcohol or (ii) a carboxylic ester of a partial polyallyl ether of a polyhydric alcohol; the composition being otherwise free of vinyl monomers. Specified polyallyl ethers (i) are triallyl glycerol, tetra-allyl pentaerythritol or sorbitol and hexa-allyl sorbitol, and specified ether esters, (ii) are the esters of diallyl glycerol with crotonic, phthalic, pyromellitic, citric and adipic acids. The compositions may also contain a peroxide catalyst, an accelerator or drier e.g. cobalt naphthenate, and an inhibitor, preferably an oxime of a C6 or lower aldehyde or ketone e.g. acetaldoxine, butyraldoxine, acetoxime, methyl ethyl hetoxime and cyclohexanone oxime. In the examples the polyester is derived from propylene glycol, maleic or fumaric acid, and phthalic anhydride or isophthalic acid and the peroxide catalyst is MEK peroxide except in Example 3 wherein cobalt naphthenate alone is used to cure the composition. According to the Provisional Specifications (B) may be any compound containing at least two beta-gamma unsaturated ether groups which is neither too volatile or too viscous, several examples of such being given. Specifications 928,801 and 939,939 are referred to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4429259A GB974892A (en) | 1959-12-30 | 1959-12-30 | Polyester compositions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4429259A GB974892A (en) | 1959-12-30 | 1959-12-30 | Polyester compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB974892A true GB974892A (en) | 1964-11-11 |
Family
ID=10432616
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4429259A Expired GB974892A (en) | 1959-12-30 | 1959-12-30 | Polyester compositions |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB974892A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011023583A1 (en) * | 2009-08-26 | 2011-03-03 | Basf Se | Coating material comprising unsaturated polyester resins and vinyl ethers |
| WO2016161387A1 (en) | 2015-04-01 | 2016-10-06 | Valspar Sourcing, Inc. | Pigment dispersion |
-
1959
- 1959-12-30 GB GB4429259A patent/GB974892A/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011023583A1 (en) * | 2009-08-26 | 2011-03-03 | Basf Se | Coating material comprising unsaturated polyester resins and vinyl ethers |
| US8999512B2 (en) | 2009-08-26 | 2015-04-07 | Basf Se | Coating material comprising unsaturated polyester resins and vinyl ethers |
| WO2016161387A1 (en) | 2015-04-01 | 2016-10-06 | Valspar Sourcing, Inc. | Pigment dispersion |
| US10836910B2 (en) | 2015-04-01 | 2020-11-17 | Swimc Llc | Pigment dispersion |
| US11655372B2 (en) | 2015-04-01 | 2023-05-23 | Swimc Llc | Pigment dispersion |
| US12297356B2 (en) | 2015-04-01 | 2025-05-13 | Swimc Llc | Pigment dispersion |
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