GB861438A - Polymerisation of organic compounds - Google Patents
Polymerisation of organic compoundsInfo
- Publication number
- GB861438A GB861438A GB3600656A GB3600656A GB861438A GB 861438 A GB861438 A GB 861438A GB 3600656 A GB3600656 A GB 3600656A GB 3600656 A GB3600656 A GB 3600656A GB 861438 A GB861438 A GB 861438A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tert
- dodecyl
- polymerization
- mercaptans
- light
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002894 organic compounds Chemical class 0.000 title 1
- -1 C1-C4 alkyl methacrylates Chemical class 0.000 abstract 4
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 3
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 2
- PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 abstract 2
- 244000028419 Styrax benzoin Species 0.000 abstract 2
- 235000000126 Styrax benzoin Nutrition 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 235000008411 Sumatra benzointree Nutrition 0.000 abstract 2
- 229960002130 benzoin Drugs 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 235000019382 gum benzoic Nutrition 0.000 abstract 2
- 229910002007 uranyl nitrate Inorganic materials 0.000 abstract 2
- BOCJQSFSGAZAPQ-UHFFFAOYSA-N 1-chloroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2Cl BOCJQSFSGAZAPQ-UHFFFAOYSA-N 0.000 abstract 1
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 abstract 1
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 abstract 1
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical group CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical class CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 1
- 239000004159 Potassium persulphate Substances 0.000 abstract 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 abstract 1
- 150000004056 anthraquinones Chemical class 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical compound C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- ORTRWBYBJVGVQC-UHFFFAOYSA-N hexadecane-1-thiol Chemical class CCCCCCCCCCCCCCCCS ORTRWBYBJVGVQC-UHFFFAOYSA-N 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 238000005286 illumination Methods 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 159000000014 iron salts Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000002609 medium Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical class CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 abstract 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- PJBJJXCZRAHMCK-UHFFFAOYSA-N n,n-dichlorobenzenesulfonamide Chemical compound ClN(Cl)S(=O)(=O)C1=CC=CC=C1 PJBJJXCZRAHMCK-UHFFFAOYSA-N 0.000 abstract 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- OOAWCECZEHPMBX-UHFFFAOYSA-N oxygen(2-);uranium(4+) Chemical compound [O-2].[O-2].[U+4] OOAWCECZEHPMBX-UHFFFAOYSA-N 0.000 abstract 1
- 239000003504 photosensitizing agent Substances 0.000 abstract 1
- 229940096992 potassium oleate Drugs 0.000 abstract 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 abstract 1
- 235000019394 potassium persulphate Nutrition 0.000 abstract 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229950000244 sulfanilic acid Drugs 0.000 abstract 1
- FCTBKIHDJGHPPO-UHFFFAOYSA-N uranium dioxide Inorganic materials O=[U]=O FCTBKIHDJGHPPO-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Liquid homopolymers or copolymers are made by subjecting an aqueous medium containing one or more ethylenically unsaturated compounds and a mercaptan to the action of light. Unsaturated compounds specified are methyl and ethyl acrylates, C1-C4 alkyl methacrylates, butadiene and isoprene and mixtures of dienes with methyl acrylate, methacrylic acid or styrene. Mercaptans specified are octyl, decyl, n-dodecyl, tert-dodecyl, tetradecyl and hexadecyl mercaptans, including a mixture of tert.-dodecyl, tert.-tetradecyl and tert.-hexadecyl mercaptans. Polymerization is preferably carried in the presence of a photosensitizer, e.g. anthraquinone, 1-chloroanthraquinone, dichloramine B, N-bromosuccinimide, diazotized sulphanilic acid, azobisisobutyronitrile, diacetyl, benzil, benzoin, uranium dioxide, uranyl nitrate and iron salts, including mixtures of substances which absorb light of different wavelengths, e.g. benzoin and uranyl nitrate. Polymerization may also be carried out in the presence of potassium persulphate as an initiator. The illumination used may consist of light having a wavelength in the region of 2,000-7,000 . The aqueous polymerization medium may contain an emulsifier such as potassium oleate, sulphated methyl oleate or the sodium salts of higher secondary alkyl sulphates.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3600656A GB861438A (en) | 1956-11-24 | 1956-11-24 | Polymerisation of organic compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3600656A GB861438A (en) | 1956-11-24 | 1956-11-24 | Polymerisation of organic compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB861438A true GB861438A (en) | 1961-02-22 |
Family
ID=10383927
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3600656A Expired GB861438A (en) | 1956-11-24 | 1956-11-24 | Polymerisation of organic compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB861438A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2283491A (en) * | 1993-10-20 | 1995-05-10 | Nat Starch Chem Corp | Monoacrylate ester coating compositions |
| GB2283975A (en) * | 1993-10-20 | 1995-05-24 | Nat Starch Chem Corp | Monoacrylate ester coating compositions |
| WO1998037104A1 (en) * | 1997-02-19 | 1998-08-27 | E.I. Du Pont De Nemours And Company | Molecular weight controlled polymers by photopolymerization |
-
1956
- 1956-11-24 GB GB3600656A patent/GB861438A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2283491A (en) * | 1993-10-20 | 1995-05-10 | Nat Starch Chem Corp | Monoacrylate ester coating compositions |
| GB2283975A (en) * | 1993-10-20 | 1995-05-24 | Nat Starch Chem Corp | Monoacrylate ester coating compositions |
| GB2283975B (en) * | 1993-10-20 | 1998-05-06 | Nat Starch Chem Corp | Method of forming adhesive bond |
| WO1998037104A1 (en) * | 1997-02-19 | 1998-08-27 | E.I. Du Pont De Nemours And Company | Molecular weight controlled polymers by photopolymerization |
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