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GB850116A - Improvements relating to the production of dyeable polymeric materials from polymerscontaining nitrile groups - Google Patents

Improvements relating to the production of dyeable polymeric materials from polymerscontaining nitrile groups

Info

Publication number
GB850116A
GB850116A GB7683/58A GB768358A GB850116A GB 850116 A GB850116 A GB 850116A GB 7683/58 A GB7683/58 A GB 7683/58A GB 768358 A GB768358 A GB 768358A GB 850116 A GB850116 A GB 850116A
Authority
GB
United Kingdom
Prior art keywords
nitrile groups
specified
treated
diamino
ethane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB7683/58A
Inventor
Ferdinand Leonard Schouteden
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gevaert Photo Producten NV
Original Assignee
Gevaert Photo Producten NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB9305/55A external-priority patent/GB833204A/en
Application filed by Gevaert Photo Producten NV filed Critical Gevaert Photo Producten NV
Publication of GB850116A publication Critical patent/GB850116A/en
Expired legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/388—Processes for the incorporation in the emulsion of substances liberating photographically active agents or colour-coupling substances; Solvents therefor
    • G03C7/3882—Processes for the incorporation in the emulsion of substances liberating photographically active agents or colour-coupling substances; Solvents therefor characterised by the use of a specific polymer or latex
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/18—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/38—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated nitriles as the major constituent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/63—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with hydroxylamine or hydrazine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/376—Oximes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67308—Hydroxylamine or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/70—Material containing nitrile groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
    • D21H17/44—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups cationic
    • D21H17/45—Nitrogen-containing groups
    • D21H17/455—Nitrogen-containing groups comprising tertiary amine or being at least partially quaternised
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/04—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with macromolecular additives; with layer-forming substances
    • G03C1/053—Polymers obtained by reactions involving only carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/775—Photosensitive materials characterised by the base or auxiliary layers the base being of paper
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/795—Photosensitive materials characterised by the base or auxiliary layers the base being of macromolecular substances
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/825—Photosensitive materials characterised by the base or auxiliary layers characterised by antireflection means or visible-light filtering means, e.g. antihalation
    • G03C1/835—Macromolecular substances therefor, e.g. mordants
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/22—Subtractive cinematographic processes; Materials therefor; Preparing or processing such materials
    • G03C7/25—Dye-imbibition processes; Materials therefor; Preparing or processing such materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/06—Resin bleach
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/93—Pretreatment before dyeing
    • Y10S8/931—Washing or bleaching

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Artificial Filaments (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)
  • Optical Filters (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A polymer containing nitrile groups is treated with hydroxylamine until at least a part of the nitrile groups has reacted and the resulting product is then further treated successively with an acid and a base. Polymers containing nitrile groups specified are those of acrylonitrile, methacrylonitrile and vinylidene cyanide and copolymers thereof with vinyl chloride, vinyl acetate, acrylic or methacrylic esters and vinyl pyridine, cyanoethylated polyvinyl alcohol and cyanoethylated cellulose. Acids specified are sulphuric, hydrochloric, phosphoric, formic, acetic and oxalic acids. Bases specified are sodium and potassium hydroxides, hydrazine, di- and tri-ethylamine, diamino-1,2-ethane, diethyl-N1-N1-amino)-1-diamino-1,2-ethane and brucine. The polymers may be treated whilst in solution or in powder, film or fibre form. The resulting products show good dyability. Specification 833,204 also is referred to.
GB7683/58A 1955-03-30 1958-03-10 Improvements relating to the production of dyeable polymeric materials from polymerscontaining nitrile groups Expired GB850116A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB9305/55A GB833204A (en) 1957-03-08 1955-03-30 Improvements in or relating to the dyeability of treated polymeric material
NL852483X 1957-03-08
NL850116X 1957-03-08
BE2038176 1959-07-01

Publications (1)

Publication Number Publication Date
GB850116A true GB850116A (en) 1960-09-28

Family

ID=32475440

Family Applications (6)

Application Number Title Priority Date Filing Date
GB27702/54A Expired GB786960A (en) 1954-09-24 1954-09-24 Polymeric amidoximes
GB15885/55A Expired GB840797A (en) 1955-03-30 1955-06-02 Improvements in or relating to new synthetic fibres, filaments and other shaped articles
GB15859/56A Expired GB838296A (en) 1955-03-30 1956-05-22 Improvements in or relating to the dyeability of treated polymeric material
GB7684/58A Expired GB852483A (en) 1955-03-30 1958-03-10 Improvements in or relating to mordants for acid organic materials, and photographicand other materials incorporating such mordants
GB7683/58A Expired GB850116A (en) 1955-03-30 1958-03-10 Improvements relating to the production of dyeable polymeric materials from polymerscontaining nitrile groups
GB22611/59A Expired GB863533A (en) 1955-03-30 1959-07-01 Polymeric amidoximes

Family Applications Before (4)

Application Number Title Priority Date Filing Date
GB27702/54A Expired GB786960A (en) 1954-09-24 1954-09-24 Polymeric amidoximes
GB15885/55A Expired GB840797A (en) 1955-03-30 1955-06-02 Improvements in or relating to new synthetic fibres, filaments and other shaped articles
GB15859/56A Expired GB838296A (en) 1955-03-30 1956-05-22 Improvements in or relating to the dyeability of treated polymeric material
GB7684/58A Expired GB852483A (en) 1955-03-30 1958-03-10 Improvements in or relating to mordants for acid organic materials, and photographicand other materials incorporating such mordants

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB22611/59A Expired GB863533A (en) 1955-03-30 1959-07-01 Polymeric amidoximes

Country Status (8)

Country Link
US (1) US3083070A (en)
BE (5) BE565400A (en)
CH (2) CH334656A (en)
DE (3) DE1149169B (en)
FR (2) FR1147427A (en)
GB (6) GB786960A (en)
LU (1) LU33836A1 (en)
NL (4) NL200690A (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2959574A (en) * 1958-02-17 1960-11-08 American Cyanamid Co Water-soluble reaction composition of hydroxylamine with acrylamide-acrylonitrile copolymer
US3087914A (en) * 1958-07-01 1963-04-30 Gevaert Photo Prod Nv Process for the preparation of polymers containing amidoxime groups
GB1010058A (en) * 1961-07-18 1965-11-17 Toho Rayon Kk Process for manufacturing imidazolines or polyimidazolines
BE627161A (en) * 1962-01-17
US3145073A (en) * 1962-04-18 1964-08-18 Gagliardi Domenick Donald Treatment of polyolefin articles and resulting products
CH464524A (en) * 1963-07-17 1968-10-31 Nippon Rayon Kk Process for improving the dyeability of fibers and molded articles made of polypropylene
US3383240A (en) * 1964-06-19 1968-05-14 Monsanto Co Flame resistant composition and method of treating acrylic containing textile fibers therewith and the resulting product
US3462238A (en) * 1966-04-07 1969-08-19 Monsanto Co Process of whitening acrylic fibers
EP0025973B1 (en) * 1979-09-19 1985-01-23 Aligena Ag Porous semipermeable membrane based on polyacrylonitrile modified by amidoxime groups, process for its preparation and their use
US4247615A (en) 1980-03-06 1981-01-27 Eastman Kodak Company Continuous-tone dyed diazo imaging process
CH649718A5 (en) * 1981-03-25 1985-06-14 Aligena Ag METHOD FOR PRODUCING SEMIPERMEABLED MEMBRANES FROM POLYMERS BASED ON ACRYLNITRILE, THE MEMBRANES PRODUCED BY THIS METHOD, AND THEIR USE.
JPS5941307A (en) * 1982-09-01 1984-03-07 Sumitomo Chem Co Ltd Chelate resin and its preparation
JPS61254603A (en) * 1985-05-02 1986-11-12 Kyoritsu Yuki Kogyo Kenkyusho:Kk Production of cationic starch
AU586246B2 (en) * 1985-05-16 1989-07-06 Ge Chemicals, Inc Hydroxylamine coagulant for acrylonitrile removal
DE3630192A1 (en) * 1986-09-04 1988-03-10 Michail Petrovic Zverev METHOD FOR PRODUCING ANION EXCHANGE FIBERS
US10570027B2 (en) * 2016-06-10 2020-02-25 Battelle Memorial Institute Converting acrylic fibers to amidoxime-carboxylate containing polymer adsorbents for sequestering uranium and other elements from water
CN118184317B (en) * 2022-12-13 2025-12-23 中国科学院化学研究所 Method for preparing Al-Mg complex-phase oxide ceramic precursor

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2893812A (en) * 1959-07-07 Dyeing of mixed textile materials
US2792276A (en) * 1954-01-28 1957-05-14 Pacific Mills Treatment of polyacrylonitrile material with hydroxylamine salts
US2785003A (en) * 1954-11-15 1957-03-12 Louis J Zaravsey Hold-down clip devices for vehicle convertible top covers

Also Published As

Publication number Publication date
DE1149169B (en) 1963-05-22
FR1147427A (en) 1957-11-25
BE541496A (en)
NL92192C (en)
GB863533A (en) 1961-03-22
NL215200A (en)
GB852483A (en) 1960-10-26
US3083070A (en) 1963-03-26
DE1148072B (en) 1963-05-02
LU33836A1 (en)
CH334656A (en) 1958-12-15
FR1153961A (en) 1958-03-31
BE565400A (en)
NL200690A (en)
BE569039A (en)
CH344844A (en) 1960-02-29
BE565402A (en)
NL88955C (en)
BE546321A (en)
GB786960A (en) 1957-11-27
DE1130593B (en) 1962-05-30
GB840797A (en) 1960-07-13
GB838296A (en) 1960-06-22

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