GB830054A - Improvements in or relating to detergent preparations - Google Patents
Improvements in or relating to detergent preparationsInfo
- Publication number
- GB830054A GB830054A GB22304/57A GB2230457A GB830054A GB 830054 A GB830054 A GB 830054A GB 22304/57 A GB22304/57 A GB 22304/57A GB 2230457 A GB2230457 A GB 2230457A GB 830054 A GB830054 A GB 830054A
- Authority
- GB
- United Kingdom
- Prior art keywords
- soap
- fatty
- amide
- fatty acid
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003599 detergent Substances 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- 239000000344 soap Substances 0.000 abstract 7
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 5
- 239000000194 fatty acid Substances 0.000 abstract 5
- 229930195729 fatty acid Natural products 0.000 abstract 5
- 150000004665 fatty acids Chemical class 0.000 abstract 5
- 239000000203 mixture Substances 0.000 abstract 5
- 150000002193 fatty amides Chemical class 0.000 abstract 4
- 150000001408 amides Chemical class 0.000 abstract 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- 239000003240 coconut oil Substances 0.000 abstract 2
- 235000019864 coconut oil Nutrition 0.000 abstract 2
- -1 fatty acyl aminomethane sulphonates Chemical class 0.000 abstract 2
- 235000019865 palm kernel oil Nutrition 0.000 abstract 2
- 239000003346 palm kernel oil Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 244000060011 Cocos nucifera Species 0.000 abstract 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical class C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 235000019482 Palm oil Nutrition 0.000 abstract 1
- 235000019483 Peanut oil Nutrition 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 1
- 210000000988 bone and bone Anatomy 0.000 abstract 1
- 239000012267 brine Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000002385 cottonseed oil Substances 0.000 abstract 1
- 235000012343 cottonseed oil Nutrition 0.000 abstract 1
- 230000002939 deleterious effect Effects 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 235000021588 free fatty acids Nutrition 0.000 abstract 1
- 239000004519 grease Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 239000002540 palm oil Substances 0.000 abstract 1
- 239000000312 peanut oil Substances 0.000 abstract 1
- ALVGPPOPGPCDCG-UHFFFAOYSA-M potassium;formaldehyde;hydrogen sulfite Chemical compound [K+].O=C.OS([O-])=O ALVGPPOPGPCDCG-UHFFFAOYSA-M 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 abstract 1
- SIXNTGDWLSRMIC-UHFFFAOYSA-N sodium;toluene Chemical compound [Na].CC1=CC=CC=C1 SIXNTGDWLSRMIC-UHFFFAOYSA-N 0.000 abstract 1
- 239000003760 tallow Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Compositions containing fatty acyl aminomethane sulphonates and soap are made by a process in which fatty amides are reacted with 0.8-1.5, preferably 0.9-1.2, molecular proportions of sodium or potassium formaldehyde bisulphite in the presence of soap and free fatty acid, the free acid being subsequently neutralized. The fatty amide, fatty acid and soap all preferably contain 10-18 carbon atoms and the fatty acid and soap are suitably derived from the mixed fatty acids of palm, palm kernel, coconut, cottonseed, or groundnut oil, or from tallow or bone grease; the amide is preferably derived from palm-kernel or coconut oil. The amount of fatty acid present is 15-40% by weight of the fatty amide, and the amount of soap is at least 1% of the weight of the amide but is not more than the amount by which the fatty acid present exceeds 14% by weight of the amide. The reaction is carried out in an inert atmosphere at 150-210 DEG C., preferably 170-190 DEG C., and the mixture remains fluid throughout the process, after which it is fully or partially neutralized, for example with sodium carbonate or hydroxide. If preferred, however, the soap may be present as an ammonium or organic base salt, such as the dicyclohexyl-ammonium salt, or as the salt of another alkali metal. After being neutralized, the composition may be purified by adding additional soap, dissolving or slurrying with hot water and graining it out by the addition of brine. The grained-out mixture will contain some salt, the deleterious effects of which may be counteracted by the addition of a small amount of sodium toluene or xylene sulphonate. The compositions may be made up into tablet form, particularly if some unconverted fatty amide is present.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL229598D NL229598A (en) | 1957-07-15 | ||
| DENDAT1074797D DE1074797B (en) | 1957-07-15 | Process for the preparation of mixtures of sulfonates and soaps | |
| GB22304/57A GB830054A (en) | 1957-07-15 | 1957-07-15 | Improvements in or relating to detergent preparations |
| US747844A US3047509A (en) | 1957-07-15 | 1958-07-11 | Process for preparing a mixture of soap and fatty-acyl-aminomethane sulfonate |
| FR1199892D FR1199892A (en) | 1957-07-15 | 1958-07-15 | Improvements to detergent compositions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB22304/57A GB830054A (en) | 1957-07-15 | 1957-07-15 | Improvements in or relating to detergent preparations |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB830054A true GB830054A (en) | 1960-03-09 |
Family
ID=10177217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB22304/57A Expired GB830054A (en) | 1957-07-15 | 1957-07-15 | Improvements in or relating to detergent preparations |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3047509A (en) |
| DE (1) | DE1074797B (en) |
| FR (1) | FR1199892A (en) |
| GB (1) | GB830054A (en) |
| NL (1) | NL229598A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2181739A (en) * | 1985-10-16 | 1987-04-29 | Unilever Plc | Detergent bar comprising soap and a rosin derivative or synthetic anionic surfactant |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3344174A (en) * | 1962-08-21 | 1967-09-26 | Monsanto Co | Vicinal acylamido sulfonate compounds |
| US3494869A (en) * | 1966-07-11 | 1970-02-10 | Lever Brothers Ltd | Superfatted soap bars and process for their preparation |
| US4618450A (en) * | 1984-11-07 | 1986-10-21 | The Lubrizol Corporation | Aqueous systems containing amino sulfonic acid derivatives of carboxylic acids |
| US4786720A (en) * | 1986-07-25 | 1988-11-22 | Westvaco Corporation | Sulfomethylated lignin amines |
| US4859362A (en) * | 1986-07-25 | 1989-08-22 | Westvaco Corporation | Sulfomethylated lignin amines |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2313695A (en) * | 1937-06-10 | 1943-03-09 | Gen Aniline & Film Corp | Process of preparing amino-sulphonic acids substituted in the amino group by acyl radicals of fatty acids |
| US2366452A (en) * | 1939-08-02 | 1945-01-02 | Gen Aniline & Film Corp | Process of preparing condensation products |
| US2857370A (en) * | 1954-11-22 | 1958-10-21 | Gen Aniline & Film Corp | Process of preparing ester and amide type anionic surface active agents |
| NL95122C (en) * | 1954-11-22 |
-
0
- NL NL229598D patent/NL229598A/xx unknown
- DE DENDAT1074797D patent/DE1074797B/en active Pending
-
1957
- 1957-07-15 GB GB22304/57A patent/GB830054A/en not_active Expired
-
1958
- 1958-07-11 US US747844A patent/US3047509A/en not_active Expired - Lifetime
- 1958-07-15 FR FR1199892D patent/FR1199892A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2181739A (en) * | 1985-10-16 | 1987-04-29 | Unilever Plc | Detergent bar comprising soap and a rosin derivative or synthetic anionic surfactant |
| GB2181739B (en) * | 1985-10-16 | 1989-09-13 | Unilever Plc | Detergent component and process for making a detergent component |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1199892A (en) | 1959-12-16 |
| US3047509A (en) | 1962-07-31 |
| DE1074797B (en) | 1960-02-04 |
| NL229598A (en) |
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