GB803121A - Improvements in or relating to the manufacture of hydrogen peroxide - Google Patents
Improvements in or relating to the manufacture of hydrogen peroxideInfo
- Publication number
- GB803121A GB803121A GB2971355A GB2971355A GB803121A GB 803121 A GB803121 A GB 803121A GB 2971355 A GB2971355 A GB 2971355A GB 2971355 A GB2971355 A GB 2971355A GB 803121 A GB803121 A GB 803121A
- Authority
- GB
- United Kingdom
- Prior art keywords
- anthraquinone
- methyl
- sulphonate
- butyl
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title abstract 6
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- -1 anthraquinone sulphonic acid ester Chemical class 0.000 abstract 8
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 abstract 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- 239000007864 aqueous solution Substances 0.000 abstract 3
- 238000006701 autoxidation reaction Methods 0.000 abstract 3
- 150000002148 esters Chemical class 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- KVGOXGQSTGQXDD-UHFFFAOYSA-N 1-decane-sulfonic-acid Chemical compound CCCCCCCCCCS(O)(=O)=O KVGOXGQSTGQXDD-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 abstract 2
- 150000004056 anthraquinones Chemical class 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000009903 catalytic hydrogenation reaction Methods 0.000 abstract 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 abstract 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 abstract 2
- 235000019341 magnesium sulphate Nutrition 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 2
- 229910052763 palladium Inorganic materials 0.000 abstract 2
- RBGUKBSLNOTVCD-UHFFFAOYSA-N 1-methylanthracene-9,10-dione Chemical class O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C RBGUKBSLNOTVCD-UHFFFAOYSA-N 0.000 abstract 1
- MMNWSHJJPDXKCH-UHFFFAOYSA-N 9,10-dioxoanthracene-2-sulfonic acid Chemical compound C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 MMNWSHJJPDXKCH-UHFFFAOYSA-N 0.000 abstract 1
- UDFCHANCMRCOQT-UHFFFAOYSA-N 9,10-dioxoanthracene-2-sulfonyl chloride Chemical compound C1=CC=C2C(=O)C3=CC(S(=O)(=O)Cl)=CC=C3C(=O)C2=C1 UDFCHANCMRCOQT-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- ZRTHDHYYZUCESV-UHFFFAOYSA-N acetic acid;1,2-xylene Chemical group CC(O)=O.CC1=CC=CC=C1C ZRTHDHYYZUCESV-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- QPUYECUOLPXSFR-UHFFFAOYSA-N alpha-methyl-naphthalene Natural products C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- IMXBRVLCKXGWSS-UHFFFAOYSA-N methyl 2-cyclohexylacetate Chemical compound COC(=O)CC1CCCCC1 IMXBRVLCKXGWSS-UHFFFAOYSA-N 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 abstract 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Hydrogen peroxide is produced by the successive catalytic hydrogenation and antoxidation of an anthraquinone sulphonic acid ester in a solvent medium. Esters specified are anthraquinone - 1 - methyl sulphonate, and anthraquinone - 2 - methyl, ethyl, n - propyl, n - butyl, iso - butyl, n - amyl, n - hexyl, n-heptyl, and n - decyl sulphonate,. The catalyst may be 2 per cent of palladium supported on activated alumina. The solvent may be a 1 to 1 methyl cyclohexy acetate-xylene or a 3 to 7 methyl cyclohexyl acetate-1-methyl-naphthalene mixture. An aqueous solution of magnesium sulphate may be present during the autoxidation step. Specifications 465,070 and 686,572 are referred to.ALSO:An anthraquinone sulphonic acid ester is used in a successive catalytic hydrogenation and autoxidation process for the production of hydrogen peroxide. Esters specified are anthraquinone-1-methyl sulphonate, and anthraquinone-2-methyl, ethyl, n-propyl, n-butyl, isobutyl, n-amyl, n-hexyl, n-heptyl and n-decyl sulphonate. The catalyst may be 2 per cent of palladium supported on activated alumina. The solvent may be a 1 to 1 methyl cyclohexyl acetate-xylene or a 3 to 7 methyl cyclohexyl acetate - 1 - methylnaphthalene mixture. An aqueous solution of magnesium sulphate may be present during the autoxidation step. Esters of anthraquinone-2-sulphonic acid and primary saturated alcohols containing 3-10 carbon atoms may be prepared by slowly introducing a concentrated aqueous solution of sodium hydroxide, in the theoretical amount, into a suspension of anthraquinone-2-sulphonyl chloride in an excess of the appropriate alcohol. Specifications 465,070, [Group IV], and 686,572, [Group III], are referred to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2971355A GB803121A (en) | 1955-10-18 | 1955-10-18 | Improvements in or relating to the manufacture of hydrogen peroxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2971355A GB803121A (en) | 1955-10-18 | 1955-10-18 | Improvements in or relating to the manufacture of hydrogen peroxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB803121A true GB803121A (en) | 1958-10-15 |
Family
ID=10295917
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2971355A Expired GB803121A (en) | 1955-10-18 | 1955-10-18 | Improvements in or relating to the manufacture of hydrogen peroxide |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB803121A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3098715A (en) * | 1959-07-08 | 1963-07-23 | Fmc Corp | Process for the manufacture of hydrogen peroxide |
| US3311453A (en) * | 1962-10-27 | 1967-03-28 | Canadian Ind | Manufacture of hydrogen peroxide |
| US5463090A (en) * | 1994-10-27 | 1995-10-31 | Arco Chemical Technology, L.P. | Integrated process for epoxide production |
| US5540906A (en) * | 1994-09-28 | 1996-07-30 | Arco Chemical Technology, L.P. | Hydrogen peroxide process |
-
1955
- 1955-10-18 GB GB2971355A patent/GB803121A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3098715A (en) * | 1959-07-08 | 1963-07-23 | Fmc Corp | Process for the manufacture of hydrogen peroxide |
| US3311453A (en) * | 1962-10-27 | 1967-03-28 | Canadian Ind | Manufacture of hydrogen peroxide |
| US5540906A (en) * | 1994-09-28 | 1996-07-30 | Arco Chemical Technology, L.P. | Hydrogen peroxide process |
| US5581000A (en) * | 1994-09-28 | 1996-12-03 | Arco Chemical Technology, L.P. | Sulfonic acid-substituted anthrahydroquinone alkylammonium salts |
| US5463090A (en) * | 1994-10-27 | 1995-10-31 | Arco Chemical Technology, L.P. | Integrated process for epoxide production |
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