ES386920A1 - Process for the preparation of straight-chain fatty acids - Google Patents
Process for the preparation of straight-chain fatty acidsInfo
- Publication number
- ES386920A1 ES386920A1 ES386920A ES386920A ES386920A1 ES 386920 A1 ES386920 A1 ES 386920A1 ES 386920 A ES386920 A ES 386920A ES 386920 A ES386920 A ES 386920A ES 386920 A1 ES386920 A1 ES 386920A1
- Authority
- ES
- Spain
- Prior art keywords
- acid
- prepare
- hydrogen peroxide
- straight
- alkali melt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000005480 straight-chain fatty acid group Chemical group 0.000 title 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 4
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- 239000003513 alkali Substances 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 abstract 2
- 235000019253 formic acid Nutrition 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 2
- 150000000180 1,2-diols Chemical class 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 238000006356 dehydrogenation reaction Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 150000004965 peroxy acids Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C1/00—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/295—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with inorganic bases, e.g. by alkali fusion
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Straight-chain aliphatic carboxylic acids (more than 4C) are prepared by forming an alkali melt of an unbranched 1, 2-diol (6-30 C) and/or its complete or partial ester with an aliphatic carboxylic acid( 1-4 C) and forming a free acid from the salt. Unbranched [alpha]-olefines (6-30 C) may be hydroxylated with per-acids (e.g. peracetic acid or a solution thereof, formic acid/hydrogen peroxide mixtures, or acetic acid/sulphuric acid/hydrogen peroxide mixtures) followed by alkali melt treatment. The alkali melt treatment, preferably with sodium or potassium hydroxide, may be under pressure with up to 50% of water and at 170-360 C. Examples describe the treatment ofn-dodecanediol-1,2 to prepare n-undecanoic acid, n-hexanediol-1,2 to prepare n-valeric, a C 12 -C 19 -nalkandiol-1,2 mixture to prepare the corresponding acid and the oxidation of n-dodecene- 1 with hydrogen peroxide and formic acid followed by the oxidation dehydrogenation to n-undecanoic acid.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19691965645 DE1965645A1 (en) | 1969-12-31 | 1969-12-31 | Process for the production of straight-chain fatty acids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES386920A1 true ES386920A1 (en) | 1973-04-16 |
Family
ID=5755344
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES386920A Expired ES386920A1 (en) | 1969-12-31 | 1970-12-30 | Process for the preparation of straight-chain fatty acids |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS5012407B1 (en) |
| AT (1) | AT305233B (en) |
| BE (1) | BE760961A (en) |
| CH (1) | CH558320A (en) |
| DE (1) | DE1965645A1 (en) |
| ES (1) | ES386920A1 (en) |
| FR (1) | FR2080398A5 (en) |
| GB (1) | GB1274619A (en) |
| NL (1) | NL7017316A (en) |
| RO (1) | RO56877A (en) |
| SE (1) | SE374737B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5252215U (en) * | 1975-10-13 | 1977-04-14 |
-
1969
- 1969-12-31 DE DE19691965645 patent/DE1965645A1/en active Pending
-
1970
- 1970-10-23 RO RO6476870A patent/RO56877A/ro unknown
- 1970-11-26 SE SE1605170A patent/SE374737B/xx unknown
- 1970-11-26 NL NL7017316A patent/NL7017316A/xx unknown
- 1970-12-16 GB GB5961970A patent/GB1274619A/en not_active Expired
- 1970-12-28 CH CH1919570A patent/CH558320A/en not_active IP Right Cessation
- 1970-12-29 BE BE760961A patent/BE760961A/en unknown
- 1970-12-29 JP JP12194570A patent/JPS5012407B1/ja active Pending
- 1970-12-30 FR FR7047359A patent/FR2080398A5/fr not_active Expired
- 1970-12-30 AT AT1175270A patent/AT305233B/en not_active IP Right Cessation
- 1970-12-30 ES ES386920A patent/ES386920A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| SE374737B (en) | 1975-03-17 |
| GB1274619A (en) | 1972-05-17 |
| AT305233B (en) | 1973-02-12 |
| CH558320A (en) | 1975-01-31 |
| NL7017316A (en) | 1971-07-02 |
| JPS5012407B1 (en) | 1975-05-12 |
| DE1965645A1 (en) | 1971-07-15 |
| FR2080398A5 (en) | 1971-11-12 |
| BE760961A (en) | 1971-06-29 |
| RO56877A (en) | 1974-08-01 |
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