GB801796A - Improvements in or relating to copolymerisation - Google Patents
Improvements in or relating to copolymerisationInfo
- Publication number
- GB801796A GB801796A GB4788/58A GB478858A GB801796A GB 801796 A GB801796 A GB 801796A GB 4788/58 A GB4788/58 A GB 4788/58A GB 478858 A GB478858 A GB 478858A GB 801796 A GB801796 A GB 801796A
- Authority
- GB
- United Kingdom
- Prior art keywords
- unsaturated
- polyesters
- glycols
- glycol
- acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 3
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 abstract 2
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004606 Fillers/Extenders Substances 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001279 adipic acids Chemical class 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 238000005266 casting Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- QAEKNCDIHIGLFI-UHFFFAOYSA-L cobalt(2+);2-ethylhexanoate Chemical compound [Co+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O QAEKNCDIHIGLFI-UHFFFAOYSA-L 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 abstract 1
- 229960001826 dimethylphthalate Drugs 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N fumaric acid group Chemical group C(\C=C\C(=O)O)(=O)O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 abstract 1
- 150000002334 glycols Chemical class 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid group Chemical group C(\C=C/C(=O)O)(=O)O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- TXXHDPDFNKHHGW-ZPUQHVIOSA-N muconic acid group Chemical group C(\C=C\C=C\C(=O)O)(=O)O TXXHDPDFNKHHGW-ZPUQHVIOSA-N 0.000 abstract 1
- 150000003022 phthalic acids Chemical class 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 150000003330 sebacic acids Chemical class 0.000 abstract 1
- 150000003442 suberic acids Chemical class 0.000 abstract 1
- 150000003444 succinic acids Chemical class 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 229920006305 unsaturated polyester Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
Unsaturated polyesters are copolymerized with unsaturated monomers, e.g. styrene, vinyl acetate and methyl methacrylate, in the presence of sufficient cobalt 2-ethyl-hexoate to inhibit surface tackiness of the resulting copolymer. The polyesters may be derived from dicarboxylic acids or anhydrides, e.g. maleic, fumaric, muconic, phthalic, succinic, adipic, sebacic and suberic acids, and glycols, e.g. ethylene glycol, polyethylene glycols, propylene glycol, trimethylene glycol, 1:2-, 1:3-, 2:3- and 1:4-butanediol and 1:4-butenediol, optionally mixed with higher polyhydric alcohols, e.g. glycerol and trimethylolpropane, at least one of the components being unsaturated. The polymerizable mixtures may contain pigments, fillers and extenders, and may be polymerized in the presence of catalysts, e.g. benzoyl peroxide and cyclohexanone peroxide which may be dissolved in dimethyl phthalate, to give films and castings.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE801796X | 1955-07-09 | ||
| DE801795X | 1955-07-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB801796A true GB801796A (en) | 1958-09-24 |
Family
ID=25948692
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB20728/56A Expired GB801795A (en) | 1955-07-09 | 1956-07-04 | Improvements in or relating to copolymerisation |
| GB4788/58A Expired GB801796A (en) | 1955-07-09 | 1956-07-04 | Improvements in or relating to copolymerisation |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB20728/56A Expired GB801795A (en) | 1955-07-09 | 1956-07-04 | Improvements in or relating to copolymerisation |
Country Status (1)
| Country | Link |
|---|---|
| GB (2) | GB801795A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3361845A (en) * | 1960-02-03 | 1968-01-02 | Toyo Koatsu Ind Inc | Process for gelling unsaturated polyester resins by addition of alcoholates of aluminum and titanium |
| US3398213A (en) * | 1965-04-12 | 1968-08-20 | Norac Co | Polymerization of cobalt containing unsaturated polyester resins |
| DE69427972T2 (en) * | 1993-04-23 | 2002-04-04 | Roche Diagnostics Corp., Indianapolis | EXTENSIONS CONTAINING POLYMER COMPOSITIONS AND THEIR USE |
-
1956
- 1956-07-04 GB GB20728/56A patent/GB801795A/en not_active Expired
- 1956-07-04 GB GB4788/58A patent/GB801796A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB801795A (en) | 1958-09-24 |
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