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GB779814A - Improvements in or relating to liquid hydrocarbon fuels containing antiknock agents - Google Patents

Improvements in or relating to liquid hydrocarbon fuels containing antiknock agents

Info

Publication number
GB779814A
GB779814A GB18099/53A GB1809953A GB779814A GB 779814 A GB779814 A GB 779814A GB 18099/53 A GB18099/53 A GB 18099/53A GB 1809953 A GB1809953 A GB 1809953A GB 779814 A GB779814 A GB 779814A
Authority
GB
United Kingdom
Prior art keywords
cyclopentadienyl
gasoline
organic
indenyl
catalytically
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB18099/53A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ethyl Corp
Original Assignee
Ethyl Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ethyl Corp filed Critical Ethyl Corp
Publication of GB779814A publication Critical patent/GB779814A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/10—Use of additives to fuels or fires for particular purposes for improving the octane number
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/28—Organic compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/301—Organic compounds compounds not mentioned before (complexes) derived from metals
    • C10L1/303—Organic compounds compounds not mentioned before (complexes) derived from metals boron compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)

Abstract

A liquid hydrocarbon fuel for internal combustion engines contains, as an anti-knock ingredient, a metallic cyclopentadienyl-containing compound other than di(cyclopentadienyl) iron. The liquid hydrocarbon fuel may comprise straight-run, thermally or catalytically cracked, reformed or hydroformed hydrocarbons of the gasoline boiling range. The cyclopentadienyl compound may have the formula MRn where M is a metal, R is a cyclopentadienyl radicle (which may carry alkyl, aryl, aralkyl, alkaryl or other organic substituents) or a radicle in which the cyclopentadienyl group is fuzed to one or two alicyclic or aromatic rings (in which case both the cyclopentadienyl group and the alicyclic or aromatic rings may carry organic substituents), and n is an integer from 1 to 4. The metal M may be chosen from Groups I-VIII of the Periodic Table and the list of metals given includes boron, silicon, arsenic, antimony, selenium and tellurium. Many examples of radicles R and organic substituents therefor, and of compounds MRn are given. The fuel may also contain scavengers (e.g. halohydrocarbons), wear inhibitors (e.g. organic phosphates, such as tricresyl orthophosphate, and organic arsenides), antioxidants and organic dyes. In the examples, gasoline compositions are described which contain cyclopentadienyl thallium, fluorenyl thallium 4, 5, 6, 7 - tetrahydroindenyl thallium, di - indenyl iron, di - indenyl osmium, di - indenyl ruthenium, 3 - methyl fluorenyl gallium, 5 - phenyl indenyl indium, tri(2, 4 - diethyl cyclopentadienyl)-scandium or tetra(cyclopentadienyl) dysprosium. Specific liquid hydrocarbons mentioned as being present in the gasolines of the examples are diisobutylene, toluene, isooctane, n - heptane, isopentane, butane, solvent oil straight run gasoline, catalytically and thermally cracked gasoline, catalytically and thermally reformed gasoline, catalytic polymer gasoline, and hydroaromatic catalytically cracked gasoline.
GB18099/53A 1952-07-05 1953-06-30 Improvements in or relating to liquid hydrocarbon fuels containing antiknock agents Expired GB779814A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US297392A US3328440A (en) 1952-07-05 1952-07-05 Antiknock compounds for gasoline fuels

Publications (1)

Publication Number Publication Date
GB779814A true GB779814A (en) 1957-07-24

Family

ID=23146129

Family Applications (2)

Application Number Title Priority Date Filing Date
GB18099/53A Expired GB779814A (en) 1952-07-05 1953-06-30 Improvements in or relating to liquid hydrocarbon fuels containing antiknock agents
GB18587/56A Expired GB786626A (en) 1952-07-05 1953-06-30 Improvements in or relating to antiknock agents for liquid hydrocarbon fuels

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB18587/56A Expired GB786626A (en) 1952-07-05 1953-06-30 Improvements in or relating to antiknock agents for liquid hydrocarbon fuels

Country Status (3)

Country Link
US (1) US3328440A (en)
DE (2) DE1177637B (en)
GB (2) GB779814A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3001858A (en) * 1958-12-15 1961-09-26 Sun Oil Co Motor fuel compositions
US3240576A (en) * 1958-03-31 1966-03-15 Chevron Res Fuel for spark-ignition engines

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1241449B (en) 1957-06-07 1967-06-01 Basf Ag Process for the production of indium cyclopentadienylene
BE587379A (en) * 1959-02-09
US3926580A (en) * 1974-06-27 1975-12-16 Ethyl Corp Fuel compositions and additive mixtures for alleviation of exhaust gas catalyst plugging
US3926581A (en) * 1974-06-27 1975-12-16 Ethyl Corp Fuel compositions and additive mixtures for reducing the plugging of exhaust gas catalysts
US4052171A (en) * 1975-06-05 1977-10-04 Ethyl Corporation Fuel compositions and additive mixtures containing methanetricarboxylates for reducing exhaust gas catalyst plugging
US4082517A (en) * 1975-12-15 1978-04-04 Ethyl Corporation Fuel composition for reducing exhaust gas catalyst plugging
US4140491A (en) * 1977-11-21 1979-02-20 Nalco Chemical Company Gasoline additive comprising a blend of methylcyclopentadienyl manganese tricarbonyl and certain methylcyclopentadiene dimer compounds
US4863892A (en) * 1983-08-16 1989-09-05 Phillips Petroleum Company Antifoulants comprising tin, antimony and aluminum for thermal cracking processes
DE3432762A1 (en) * 1984-09-06 1986-03-20 Busse, Felix, 5300 Bonn Additive mixture for carburettor fuels
US5749928A (en) * 1984-12-04 1998-05-12 Platinum Plus, Inc. Method for reducing emissions from or increasing the utilizable energy of fuel for powering internal combustion engines
US4699987A (en) * 1986-06-03 1987-10-13 Regents Of The University Of Minnesota (Perfluoroalkyl)-cyclopentadienylthallium
ATE66957T1 (en) * 1986-09-19 1991-09-15 Rhone Poulenc Chimie USE OF RARE EARTH MIXTURES TO STABILIZE FUELS FOR DIESEL ENGINES.
US4992305A (en) * 1988-06-22 1991-02-12 Georgia Tech Research Corporation Chemical vapor deposition of transistion metals
US4915988A (en) * 1988-06-22 1990-04-10 Georgia Tech Research Corporation Chemical vapor deposition of group IIA metals and precursors therefor
US5266083A (en) * 1988-12-28 1993-11-30 Platinum Plus, Inc. Method for reducing pollution emissions from a diesel engine
US5034020A (en) * 1988-12-28 1991-07-23 Platinum Plus, Inc. Method for catalyzing fuel for powering internal combustion engines
CA1340871C (en) * 1988-12-28 2000-01-04 Robert W. Epperly Method for reducing emissions from or increasing the utilizable energy of fuel for powering internal combustion engines
WO2005087901A2 (en) * 2004-03-09 2005-09-22 Innospec Limited Fuel additive composition having antiknock properties

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1938180A (en) * 1931-06-23 1933-12-05 Shell Dev Process for the manufacture of organic metallo compounds
US2247821A (en) * 1939-12-04 1941-07-01 Chempats Inc Manufacture of trialkyl borons
US2356476A (en) * 1941-06-28 1944-08-22 Shappirio Sol Motor fuels
US2552676A (en) * 1946-11-27 1951-05-15 Cincinnati Milling Machine Co Method of manufacturing organometallic compounds
GB746036A (en) * 1952-03-19 1956-03-07 Du Pont Hydrocarbon motor fuel and antiknock agent therefor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3240576A (en) * 1958-03-31 1966-03-15 Chevron Res Fuel for spark-ignition engines
US3001858A (en) * 1958-12-15 1961-09-26 Sun Oil Co Motor fuel compositions

Also Published As

Publication number Publication date
DE1177637B (en) 1964-09-10
US3328440A (en) 1967-06-27
DE1052742B (en) 1959-03-12
GB786626A (en) 1957-11-20

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