GB680409A - Light stable compositions comprising polymeric vinylidene chloride or vinyl chloride - Google Patents
Light stable compositions comprising polymeric vinylidene chloride or vinyl chlorideInfo
- Publication number
- GB680409A GB680409A GB387351A GB387351A GB680409A GB 680409 A GB680409 A GB 680409A GB 387351 A GB387351 A GB 387351A GB 387351 A GB387351 A GB 387351A GB 680409 A GB680409 A GB 680409A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydroxy
- chloride
- benzophenone
- vinyl
- vinylidene chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 title abstract 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title 1
- 229920000642 polymer Polymers 0.000 abstract 3
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- OQERFUGURPLBQH-UHFFFAOYSA-N (2-hydroxy-5-methylphenyl)-phenylmethanone Chemical class CC1=CC=C(O)C(C(=O)C=2C=CC=CC=2)=C1 OQERFUGURPLBQH-UHFFFAOYSA-N 0.000 abstract 1
- KOFBTLHXBSQDBI-UHFFFAOYSA-N (2-hydroxy-5-propylphenyl)-phenylmethanone Chemical class CCCC1=CC=C(O)C(C(=O)C=2C=CC=CC=2)=C1 KOFBTLHXBSQDBI-UHFFFAOYSA-N 0.000 abstract 1
- KPWRYNMNBGTWDW-UHFFFAOYSA-N (5-butyl-2-hydroxyphenyl)-phenylmethanone Chemical class CCCCC1=CC=C(O)C(C(=O)C=2C=CC=CC=2)=C1 KPWRYNMNBGTWDW-UHFFFAOYSA-N 0.000 abstract 1
- OMWSZDODENFLSV-UHFFFAOYSA-N (5-chloro-2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=C(Cl)C=C1C(=O)C1=CC=CC=C1 OMWSZDODENFLSV-UHFFFAOYSA-N 0.000 abstract 1
- FEFKJJOFHLOEGX-UHFFFAOYSA-N (5-ethyl-2-hydroxyphenyl)-phenylmethanone Chemical class CCC1=CC=C(O)C(C(=O)C=2C=CC=CC=2)=C1 FEFKJJOFHLOEGX-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 abstract 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 159000000007 calcium salts Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000000460 chlorine Chemical group 0.000 abstract 1
- 229910052801 chlorine Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 159000000003 magnesium salts Chemical class 0.000 abstract 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- 239000005033 polyvinylidene chloride Substances 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/138—Phenolates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Polymers containing at least 10 per cent vinyl chloride or vinylidene chloride are stabilized by incorporating therein a salt of the formula <FORM:0680409/IV (a)/1> where M is an alkaline earth metal and X is hydrogen or chlorine or an alkyl radical containing from 1 to 4 carbon atoms. The polymers may be polyvinyl chloride, polyvinylidene chloride, copolymers of vinyl and vinylidene chloride and copolymers of vinyl chloride or vinylidene chloride with acrylonitrile, ethyl acrylate, methyl acrylate, vinyl acetate, styrene and butadiene. Specified salts are the calcium, barium, strontium and magnesium salts of 2-hydroxy-5-chlorobenzophenone, and the calcium salts of 2-hydroxy-benzophenone, 2-hydroxy-5-methylbenzophenone, 2-hydroxy-5-ethyl - benzophenone, 2 - hydroxy - 5 - propyl-benzophenone and 2-hydroxy-5-butyl-benzophenone. The polymer may contain a plasticizer, e.g. dioctyl phthalate.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB387351A GB680409A (en) | 1951-02-16 | 1951-02-16 | Light stable compositions comprising polymeric vinylidene chloride or vinyl chloride |
| FR1033808D FR1033808A (en) | 1951-02-16 | 1951-03-09 | Enhancements to light stable compositions containing vinylidene chloride or polymerized vinyl chloride |
| DED8205A DE894770C (en) | 1951-02-16 | 1951-03-16 | Plastic mass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB387351A GB680409A (en) | 1951-02-16 | 1951-02-16 | Light stable compositions comprising polymeric vinylidene chloride or vinyl chloride |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB680409A true GB680409A (en) | 1952-10-01 |
Family
ID=9766487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB387351A Expired GB680409A (en) | 1951-02-16 | 1951-02-16 | Light stable compositions comprising polymeric vinylidene chloride or vinyl chloride |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR1033808A (en) |
| GB (1) | GB680409A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2824854A (en) * | 1955-12-01 | 1958-02-25 | Dow Chemical Co | Bis(salicyloyl) benzene derivatives and compositions containing the same |
| US2879258A (en) * | 1955-12-01 | 1959-03-24 | Dow Chemical Co | Bis(salicyloyl) benzene derivatives and compositions containing the same |
| DE1187369B (en) * | 1955-12-27 | 1965-02-18 | Monsanto Co | Stabilization of halogen-containing polymers and copolymers against exposure to light |
-
1951
- 1951-02-16 GB GB387351A patent/GB680409A/en not_active Expired
- 1951-03-09 FR FR1033808D patent/FR1033808A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2824854A (en) * | 1955-12-01 | 1958-02-25 | Dow Chemical Co | Bis(salicyloyl) benzene derivatives and compositions containing the same |
| US2879258A (en) * | 1955-12-01 | 1959-03-24 | Dow Chemical Co | Bis(salicyloyl) benzene derivatives and compositions containing the same |
| DE1187369B (en) * | 1955-12-27 | 1965-02-18 | Monsanto Co | Stabilization of halogen-containing polymers and copolymers against exposure to light |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1033808A (en) | 1953-07-16 |
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