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GB2018774A - Process of preparation of 2- mercaptobenzthiazole - Google Patents

Process of preparation of 2- mercaptobenzthiazole

Info

Publication number
GB2018774A
GB2018774A GB7913139A GB7913139A GB2018774A GB 2018774 A GB2018774 A GB 2018774A GB 7913139 A GB7913139 A GB 7913139A GB 7913139 A GB7913139 A GB 7913139A GB 2018774 A GB2018774 A GB 2018774A
Authority
GB
United Kingdom
Prior art keywords
molar ratio
nitrosobenzene
reacted
nitrobenzene
specified molar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB7913139A
Other versions
GB2018774B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Akzo NV
Original Assignee
Akzo NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19782816503 external-priority patent/DE2816503C3/en
Priority claimed from DE2816407A external-priority patent/DE2816407C3/en
Application filed by Akzo NV filed Critical Akzo NV
Publication of GB2018774A publication Critical patent/GB2018774A/en
Application granted granted Critical
Publication of GB2018774B publication Critical patent/GB2018774B/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
    • C07D277/62—Benzothiazoles
    • C07D277/68—Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
    • C07D277/70—Sulfur atoms
    • C07D277/72—2-Mercaptobenzothiazole

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Thiazole And Isothizaole Compounds (AREA)

Abstract

A process for the preparation of 2- mercaptobenzthiazole which comprises reacting nitrobenzene or nitrosobenzene, hydrogen sulphide and carbon disulphide, the molar ratio of nitrobenzene or nitrosobenzene: hydrogen sulphide being from 1:3 to 1:6 or from 1:1.5 to 1:4, the molar ratio of nitrobenzene or nitrosobenzene: carbon disulphide being from 1:1 to 1:3 and the final reaction temperature being from 200 to 300 DEG C, is disclosed. Embodiments are disclosed wherein (a) nitrobenzene and H25 are reacted in a specified molar ratio under elevated temperature and pressure and the resulting reaction mixture is reacted with CS2 in a specified molar ratio at 200 to 300 DEG C; (b) nitrosobenzene, H25 and C52 are reacted in a specified molar ratio at 200 to 300 DEG C; and (c) nitrosobenzene and H25 are reacted in a specified molar ratio at 20 to 100 DEG C and the resulting reaction mixture is reacted with C52 in a specified molar ratio at 200 to 300 DEG C.
GB7913139A 1978-04-15 1979-04-12 Process for the preparation of 2-mercaptobenzthiazole Expired GB2018774B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19782816503 DE2816503C3 (en) 1978-04-15 1978-04-15 Process for the preparation of 2-mercaptobenzothiazole
DE2816407A DE2816407C3 (en) 1978-04-15 1978-04-15 Process for the preparation of 2-mercaptobenzothiazole

Publications (2)

Publication Number Publication Date
GB2018774A true GB2018774A (en) 1979-10-24
GB2018774B GB2018774B (en) 1982-12-01

Family

ID=25774251

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7913139A Expired GB2018774B (en) 1978-04-15 1979-04-12 Process for the preparation of 2-mercaptobenzthiazole

Country Status (13)

Country Link
JP (1) JPS54138555A (en)
BR (1) BR7902252A (en)
CS (1) CS209920B2 (en)
DD (1) DD142879A5 (en)
ES (1) ES479380A1 (en)
FR (1) FR2432514A1 (en)
GB (1) GB2018774B (en)
HU (1) HU179918B (en)
IT (1) IT1117172B (en)
NL (1) NL7902705A (en)
PL (1) PL119658B1 (en)
RO (1) RO77250A (en)
SU (1) SU1005661A3 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997046544A1 (en) * 1996-06-03 1997-12-11 Akzo Nobel N.V. Acid catalysed process for preparing 2-mercaptobenzothiazole and derivatives thereof
US6222041B1 (en) 2000-02-24 2001-04-24 Uniroyal Chemical Company, Inc. Method for the production of 2-mercaptobenzothiazole

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997046544A1 (en) * 1996-06-03 1997-12-11 Akzo Nobel N.V. Acid catalysed process for preparing 2-mercaptobenzothiazole and derivatives thereof
US6222041B1 (en) 2000-02-24 2001-04-24 Uniroyal Chemical Company, Inc. Method for the production of 2-mercaptobenzothiazole
WO2001062748A1 (en) * 2000-02-24 2001-08-30 Uniroyal Chemical Company, Inc. Method for the production of 2-mercaptobenzothiazole

Also Published As

Publication number Publication date
HU179918B (en) 1983-01-28
IT7948697A0 (en) 1979-04-11
GB2018774B (en) 1982-12-01
IT1117172B (en) 1986-02-17
FR2432514B1 (en) 1983-07-29
PL214829A1 (en) 1980-01-14
RO77250A (en) 1981-08-17
ES479380A1 (en) 1979-07-16
NL7902705A (en) 1979-10-17
FR2432514A1 (en) 1980-02-29
SU1005661A3 (en) 1983-03-15
BR7902252A (en) 1979-12-04
PL119658B1 (en) 1982-01-30
CS209920B2 (en) 1981-12-31
JPS54138555A (en) 1979-10-27
DD142879A5 (en) 1980-07-16

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee