GB2018243A - Process for the production of thioxanthones - Google Patents
Process for the production of thioxanthonesInfo
- Publication number
- GB2018243A GB2018243A GB7911402A GB7911402A GB2018243A GB 2018243 A GB2018243 A GB 2018243A GB 7911402 A GB7911402 A GB 7911402A GB 7911402 A GB7911402 A GB 7911402A GB 2018243 A GB2018243 A GB 2018243A
- Authority
- GB
- United Kingdom
- Prior art keywords
- thioxanthones
- production
- metalhydrosulphide
- sulphur
- employed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Substances 0.000 abstract 2
- 229910052976 metal sulfide Inorganic materials 0.000 abstract 2
- 239000012965 benzophenone Substances 0.000 abstract 1
- 239000003444 phase transfer catalyst Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D335/00—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom
- C07D335/04—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
- C07D335/10—Dibenzothiopyrans; Hydrogenated dibenzothiopyrans
- C07D335/12—Thioxanthenes
- C07D335/14—Thioxanthenes with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 9
- C07D335/16—Oxygen atoms, e.g. thioxanthones
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
A process for the production of thioxanthones comprises reacting the corresponding o,o'-dihalogen- benzophenone with sulphur or with a metal sulphide or metalhydrosulphide with the proviso that when a metal sulphide or metalhydrosulphide is employed the reaction is carried out in a two-phase system in the presence of a phase transfer catalyst, and when the sulphur is employed the reaction is carried out in alkaline medium.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH377378A CH635583A5 (en) | 1978-04-07 | 1978-04-07 | METHOD FOR PRODUCING OPTIONALLY SUBSTITUTED THIOXANTHONES. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB2018243A true GB2018243A (en) | 1979-10-17 |
| GB2018243B GB2018243B (en) | 1982-10-20 |
Family
ID=4263176
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7911402A Expired GB2018243B (en) | 1978-04-07 | 1979-04-02 | Process for the production of thioxanthones |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS54148791A (en) |
| BE (1) | BE875359R (en) |
| CH (1) | CH635583A5 (en) |
| DE (1) | DE2912197A1 (en) |
| ES (1) | ES479408A1 (en) |
| FR (1) | FR2421898B2 (en) |
| GB (1) | GB2018243B (en) |
| NL (1) | NL7902588A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2161482A (en) * | 1984-07-12 | 1986-01-15 | Sandoz Ltd | Improvements in or relating to organic compounds |
| CN102863422A (en) * | 2012-09-07 | 2013-01-09 | 浙江工业大学 | A kind of preparation method of 2-isopropylthioxanthone |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH644362A5 (en) | 1980-05-06 | 1984-07-31 | Ciba Geigy Ag | 3,5-DISUBSTITUTED PHTHALIC ACID IMIDES. |
| CN108218831B (en) * | 2018-04-17 | 2020-07-07 | 吉林大学 | Thioxanthone compound crystal with room-temperature phosphorescence property and preparation method and application thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3767674A (en) * | 1971-10-01 | 1973-10-23 | Ostra Lakemedel Ab | Cyclohexeno thioxanthones |
| CH628343A5 (en) * | 1977-03-24 | 1982-02-26 | Sandoz Ag | Process for preparing thioxanthones |
-
1978
- 1978-04-07 CH CH377378A patent/CH635583A5/en not_active IP Right Cessation
-
1979
- 1979-03-28 DE DE19792912197 patent/DE2912197A1/en active Granted
- 1979-04-02 GB GB7911402A patent/GB2018243B/en not_active Expired
- 1979-04-03 FR FR7908377A patent/FR2421898B2/en not_active Expired
- 1979-04-03 NL NL7902588A patent/NL7902588A/en not_active Application Discontinuation
- 1979-04-05 BE BE0/194437A patent/BE875359R/en active
- 1979-04-05 JP JP4042179A patent/JPS54148791A/en active Granted
- 1979-04-06 ES ES479408A patent/ES479408A1/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2161482A (en) * | 1984-07-12 | 1986-01-15 | Sandoz Ltd | Improvements in or relating to organic compounds |
| FR2567516A1 (en) * | 1984-07-12 | 1986-01-17 | Sandoz Sa | PROCESS FOR PREPARING XANTHONES AND THIOXANTHONES AND USE THEREOF AS PHOTOPOLYMERIZATION INITIATORS |
| US4661595A (en) * | 1984-07-12 | 1987-04-28 | Sandoz Ltd. | Method for producing xanthone and thioxanthone compounds useful as photoinitiators |
| CN102863422A (en) * | 2012-09-07 | 2013-01-09 | 浙江工业大学 | A kind of preparation method of 2-isopropylthioxanthone |
| CN102863422B (en) * | 2012-09-07 | 2014-06-11 | 浙江工业大学 | Preparation method of 2-isopropylthioxanthone |
Also Published As
| Publication number | Publication date |
|---|---|
| ES479408A1 (en) | 1979-12-01 |
| BE875359R (en) | 1979-10-05 |
| CH635583A5 (en) | 1983-04-15 |
| JPH0134993B2 (en) | 1989-07-21 |
| DE2912197A1 (en) | 1979-10-18 |
| NL7902588A (en) | 1979-10-09 |
| DE2912197C2 (en) | 1988-12-29 |
| FR2421898A2 (en) | 1979-11-02 |
| JPS54148791A (en) | 1979-11-21 |
| FR2421898B2 (en) | 1987-12-24 |
| GB2018243B (en) | 1982-10-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |